Processes For Formation Of An Ether Group (e.g., Cyanoethylation Of Alcohols, Etc.) Patents (Class 558/450)
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Patent number: 11767379Abstract: A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX2?CY(—CZ2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C—C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO3M, or —OSO3M, wherein M is —H, a metal atom, —NR74, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.Type: GrantFiled: March 1, 2019Date of Patent: September 26, 2023Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yoshinori Nanba, Kenji Ichikawa, Yohei Fujimoto, Hirotoshi Yoshida, Hiroyuki Sato, Taketo Kato, Kengo Ito, Sumi Ishihara, Masahiro Higashi, Satoru Yoneda, Hirokazu Aoyama, Masamichi Sukegawa, Yosuke Kishikawa, Takahiro Taira, Chiaki Okui, Taku Yamanaka
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Publication number: 20140018567Abstract: Disclosed is a method for preparing a dinitrile compound. The method includes reacting an alcohol compound with a nitrile compound having a terminal carbon-carbon unsaturated bond under anhydrous conditions. A potassium alkoxide having 1 to 5 carbon atoms is used as a catalyst in the course of the reaction. According to the method, a high-purity dinitrile compound can be prepared in a simple manner within a short reaction time indicating high productivity.Type: ApplicationFiled: September 13, 2013Publication date: January 16, 2014Applicant: LG CHEM, LTD.Inventors: Byoung-Bae LEE, Jae-Seung OH, You-Jin SHIM, Yeon-Suk HONG
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Patent number: 6794530Abstract: A process for preparing &bgr;-alkoxynitriles by reacting &agr;,&bgr;-unsaturated nitriles with monohydric, dihydric or trihydric alcohols in the presence of basic catalysts at from −20 to +200° C. comprises using a diazabicycloalkene catalyst of the formula I where from 1 to 4 hydrogen atoms may be independently replaced by the radicals R1 to R4, in which case R1, R2, R3, R4 are each C1-20-alkyl, C6-20-aryl or C7-20-arylalkyl, and n and m are each an integer from 1 to 6.Type: GrantFiled: January 22, 1999Date of Patent: September 21, 2004Assignee: BASF AktiengesellschaftInventors: Wolfgang Friedrich, Heinz-Josef Kneuper, Karsten Eller, Andreas Henne, Rolf Lebkücher
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Patent number: 5869732Abstract: An imporved process for producing tricyanoethylated pentaerythritol by selectively cyanoethylating only three hydroxy groups of pentaerythritol in a high yield such as 90 to 95%, involves reacting one mole of pentaerythritol with three mole of acrylonitrile by Micheal Addition Reaction in an alkaline aqueous solution in coexistence with an extraction solvent. The tricyanoethylated pentaerythritol has a high purity and is useful for production of a high dielectric polymer.Type: GrantFiled: July 10, 1997Date of Patent: February 9, 1999Assignees: Sunstar Giken Kabushiki Kaisha, Uni-Sunstar B.V.Inventors: Satoshi Nishikawa, Shinji Bessho
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Patent number: 5294602Abstract: The 3-(hexenyloxy)-propane-nitriles of general formula A, in which R.sup.1 and R.sup.2 are optionally a hydrogen atom or a methyl group and R.sup.3 is an unbranched hexenyl group, are new and are useful as odour materials such as ingredients for perfume compositions. Their production is carried out through the base catalysed addition of acrylonitrile or methyl substituted acrylonitrile to the unbranched hexenol, in which the reaction temperature is between 0.degree. and 50.degree. C. (for acrylonitrile especially between 0.degree. and 10.degree. C., for crotonitrile especially between 15.degree. and 25.degree. C. and for methacrylonitrile, especially between 30.degree. and 40.degree. C.), and the aforesaid base is benzyl trimethylammonium hydroxide (Triton B).Type: GrantFiled: November 20, 1991Date of Patent: March 15, 1994Inventors: Ernst-Joachim Brunke, Karl-Georg Fahlbusch
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Patent number: 5196589Abstract: The present invention relates to novel methods of stabilizing polymers of acrylonitrile. The polymers are stabilized by the inclusion of small amounts of stable free radicals compounds which act to inhibit the homopolymerization of the acrylonitrile while promoting the reaction of the acrylonitrile with nucleophilic species such as amines and alcohols.Type: GrantFiled: September 16, 1991Date of Patent: March 23, 1993Assignee: LCE PartnershipInventors: Anthony J. O'Lenick, Jr., J. Michael Clumpner
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Patent number: 5159101Abstract: Disclosed is a process wherein cyanoethylation is accomplished by reacting a compound of the formula: ##STR1## where R=H or CH.sub.3, n=1 to 3 and m=0 to 50, and acrylonitrile over a heterogeneous catalyst comprising, potassium fluoride or cesium fluoride supported on an oxide of an element from the group consisting of Group IA, IIA or IIIA of the Periodic Table.Type: GrantFiled: February 10, 1992Date of Patent: October 27, 1992Assignee: Texaco Chemical CompanyInventors: Donald H. Champion, George P. Speranza
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Patent number: 5099042Abstract: Polymers are produced from 4 and 5 member cyclic ethers, which polymers have hydroxyl functionalities of 4.Type: GrantFiled: March 14, 1989Date of Patent: March 24, 1992Assignee: Thiokol CorporationInventors: Robert B. Wardle, Jerald C. Hinshaw
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Patent number: 5081305Abstract: This invention relates to a process for the separation of acrylonitrile used in the cyanoethylation of glycols to produce a bis(cyanoethylated) aliphatic glycol from the resulting glycol which is then reduced with hydrogen to produce the corresponding bis(aminopropoxy) alkane. In this process, acrylonitrile or methacrylonitrile is reacted with an aliphatic glycol in stoichiometric excess and the acrylonitrile removed from the cyanoethylated glycol by reaction with aliphatic primary or secondary alcohol prior to effecting the hydrogenation of the cyanoethylated aliphatic glycol in the presence of the acrylonitrile-amine reaction product. The reaction product then can be separated by conventional techniques such as distillation.Type: GrantFiled: October 13, 1988Date of Patent: January 14, 1992Assignee: Air Products and Chemicals, Inc.Inventors: Richard V. C. Carr, Steven M. Galaton, Thomas A. Johnson, Thomas A. Albanese
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Patent number: 4965362Abstract: 3-Dialkylaminopropionitriles ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl which may furthermore be bonded to form a 5-membered or 6-membered ring, bis-(2-cyanoethyl) ether IINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN IIand, if desired, ethylenecyanohydrin IIIHO--CH.sub.2 --CH.sub.2 --CN IIIare prepared jointly by a process in which(a) acrylonitrile and water are reacted in the presence of a base at from 60.degree. to 150.degree. C. to give a mixture of acrylonitrile, water and bis-(2-cyanoethyl) ether II, the base being a mineral base, a quaternary nitrogen base or a mixture of these,(b) this mixture is reacted at about 0.degree.-50.degree. C.Type: GrantFiled: July 6, 1989Date of Patent: October 23, 1990Inventors: Franz Merger, Wolfgang Harder, Peter Hettinger, Claus-Ulrich Priester, Dieter Franz, Dieter Voges
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Patent number: 4709072Abstract: Ethylene cyanohydrin (Ia) and its ethersR--O--CH.sub.2 --CH.sub.2 --CN Ib(where R is an organic radical) are prepared jointly by reacting an alcohol R--OH (II) with 2,2'-dicyanodiethyl ether (III) in the presence of a base.Type: GrantFiled: June 11, 1986Date of Patent: November 24, 1987Assignee: BASF AktiengesellschaftInventors: Franz Merger, Hans-Martin Hutmacher, Peter Hettinger, Dieter Voges, Wolfgang Lengsfeld
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Patent number: 4617154Abstract: A process for the production of (1) an ether or (2) a second amine comprises reacting an activated olefin with respectively an alcohol or first amine in the presence of a catalyst which is either (a) an amidine or (b) a Lewis base and epoxide. The same catalyst may also be used to carry out the reverse reaction in which an activated olefin and an alcohol or first amine are produced from the appropriate ether or second amine.Type: GrantFiled: September 4, 1984Date of Patent: October 14, 1986Assignee: BP Chemicals LimitedInventor: Michael J. Green