Acyclic Divalent Chalcogen Single Bonded Directly To The Ring Phosphorus (e.g., Cyclic Phosphites, Etc.) Patents (Class 558/85)
  • Patent number: 8722595
    Abstract: The present invention provides a lubricating oil composition capable of achieving a lubricating property, a thermal stability, an oxidation stability, an anti-discoloring property and an anti-varnishing performance with a higher level by compounding a phosphorus compound having a specific structure in a base oil, as well as a lubricating oil composition for internal combustion engines which is excellent in wear resistance, high-temperature detergency and base number retention property although it has a low phosphorus content, a low sulfur content and a low sulfated ash content.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: May 13, 2014
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hideki Kamano, Junichi Yagi, Hideto Kamimura
  • Publication number: 20130143984
    Abstract: The invention relates to curable compositions which comprise epoxy resins, amino hardeners, and a phosphonate of the formula I. Addition of phosphonate of the formula I can give cured epoxy resins which have not only improved flame retardants but also an increased glass transition temperature when comparison is made with the corresponding resins without said addition.
    Type: Application
    Filed: June 7, 2012
    Publication date: June 6, 2013
    Applicant: BASF SE
    Inventors: Michael Henningsen, Achim Kaffee, Jean-Francois Stumbe, Manfred Doering, Alexander Schmidt, Lin Zang, Volker Altstaedt, Johannes Kraemer
  • Publication number: 20120252943
    Abstract: A resin composition comprising an ethylene/vinyl alcohol copolymer and a phosphite compound. A method of producing a resin composition, comprising the step of mixing an ethylene/vinyl alcohol copolymer with a phosphite compound. A molded article obtained by heat-molding the above-described resin composition.
    Type: Application
    Filed: December 15, 2010
    Publication date: October 4, 2012
    Inventor: Yoshikazu Kimura
  • Patent number: 8097748
    Abstract: An amorphous compound of the formula (1): wherein the temperature showing an endothermic peak by differential scanning calorimetry (DSC) is 40 to 80° C. and the solution rate into n-hexane at 25° C. in the following test system is 1.5 mg/sec or more. <Test System Regarding Solution Rate> At 25° C., 1 g of a specimen is charged into a vessel containing 50 g of n-hexane (capacity: 100 ml, outer diameter: 55 mm, height: 70 mm), a 38 mm diameter fan type stirring blade is rotated at a revolution of 100 rpm, and the time until dissolution of the specimen is measured.
    Type: Grant
    Filed: April 2, 2010
    Date of Patent: January 17, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Kimura, Kazuhiro Kitamura, Hideaki Awa
  • Patent number: 7883642
    Abstract: An antioxidant composition containing an antioxidant represented by the following formula (I) and a metal salt of fatty acid of a carbon number of 4 to 18, wherein a weight ratio of the antioxidant (I) and the metal salt of fatty acid is in a range of (100:0.1) to (100:200).
    Type: Grant
    Filed: November 16, 2006
    Date of Patent: February 8, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Kenji Kimura
  • Patent number: 7728162
    Abstract: A novel process for preparing in a high purity and in a high yield phosphorus compounds having a phosphate-phosphonate bond within one molecule, along with only a small amount of a by-product, without being restricted by the kind of a phosphonate having an alcoholic hydroxyl group which is a raw material, without using a catalyst such as magnesium chloride, but only using a nitrogen-containing basic compound.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: June 1, 2010
    Assignee: Daihachi Chemical Industry Co., Ltd.
    Inventors: Kazuo Fujimoto, Sakiko Tanaka
  • Patent number: 7098197
    Abstract: The present invention relates to phosphonate compounds, compositions containing them, processes for obtaining them, and their use for treating a variety of medical disorders, e.g., osteoporosis and other disorders of bone metabolism, cancer, viral infections, and the like.
    Type: Grant
    Filed: April 6, 2005
    Date of Patent: August 29, 2006
    Assignee: The Regents of the University of California
    Inventors: Karl Y. Hostetler, James R. Beadle, Ganesh D. Kini
  • Patent number: 7094772
    Abstract: The present invention relates to phosphonate compounds, compositions containing them, processes for obtaining them, and their use for treating a variety of medical disorders, e.g., osteoporosis and other disorders of bone metabolism, cancer, viral infections, and the like.
    Type: Grant
    Filed: April 6, 2005
    Date of Patent: August 22, 2006
    Assignee: The Regents of the University of California
    Inventors: Karl Y. Hostetler, James R. Beadle, Ganesh D. Kini
  • Patent number: 7081533
    Abstract: The present invention concerns novel unsymmetrical chiral diphosphines of a mixed aliphatic-aromatic type and processes for synthesizing them, complexes of these compounds and their use as catalysts.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: July 25, 2006
    Assignee: Degussa AG
    Inventors: Boris E Bosch, Axel Monsees, Uwe Dingerdissen, Paul Knochel, Eike Hupe
  • Patent number: 7057061
    Abstract: The present invention relates to catalysts comprising chiral monophosphorus compounds and their use, the chiral monophosphorus compounds themselves and also their precursors.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: June 6, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Claus Dreisbach, Benjamin Meseguer, Thomas Prinz, Ulrich Scholz, Hans-Christian Militzer, Friederike Agel, Birgit Drieβen-Hölscher
  • Patent number: 7034014
    Abstract: The present invention relates to phosphonate compounds, compositions containing them, processes for obtaining them, and their use for treating a variety of medical disorders, e.g., osteoporosis and other disorders of bone metabolism, cancer, viral infections, and the like.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: April 25, 2006
    Assignee: The Regents of the University of California
    Inventors: Karl Y. Hostetler, James R. Beadle, Ganesh D. Kini
  • Patent number: 6800778
    Abstract: The present invention provides a method of producing an optically active form of a compound represented by the formula (I) having a steroid C17,20-lyase inhibitory activity and is useful as an agent for the prophylaxis or treatment of prostatism, tumor such as breast cancer, and the like or a salt thereof, which method includes reacting a mixture of optically active compounds of a naphthalene derivative represented by the formula: wherein R is a nitrogen-containing heterocyclic group, R1 is a hydrogen atom, a hydrocarbon group or an aromatic heteromonocyclic group, R2 is a hydrogen atom or a lower alkyl group, * shows the position of an asymmetric carbon, R3, R4, R5, R6, R7, R8 and R9 are each independently a hydrogen atom, a hydrocarbon group, a hydroxy group, a thiol group, an amino group, a carbamoyl group, an acyl group or a halogen atom, and R7 is bonded with R6 or R8 to form, together with a carbon atom on a naphthalene ring, a 5 or 6-membered ring containing an oxygen atom, with an op
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: October 5, 2004
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Isao Aoki, Mari Adachi, Mitsuru Kawada, Toru Yamano, Naohiro Taya
  • Patent number: 6790928
    Abstract: 100 parts by weight of the polycarbonate produce by melt polycondensation of a carbonic acid diester and a dihydroxy compound and 0.0001 to 0.1 part by weight of a phosphite compound represented by following Formula (I) are formulated: wherein Rs are each one of a hydrogen atom, an alkyl group, an aryl group, and an oxyalkyl group, where the two Rs are not concurrently hydrogen atoms. The process of the invention can yield polycarbonate molding materials that have satisfactory hue and can be used in a wide variety of applications such for optical materials.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: September 14, 2004
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Shu Yoshida, Hiroaki Tanaka
  • Patent number: 6756402
    Abstract: The invention relates to compounds of formula I in which R1, R2, E, X1, X2, and X3 have the meaning as described in the specification and claims, obtained by culturing Streptomyces species HAG 004107 (DSM 13381), and their physiologically tolerable salts and chemical equivalents. The invention furthermore relates to a process for the preparation of the cyclipostins, the microorganism HAG 004107 (DSM 13381), the use of the cyclipostins and their physiologically tolerable salts and chemical equivalents as pharmaceuticals, in particular as inhibitors of lipases, and pharmaceutical preparations which contain cyclipostin or a physiologically tolerable salt or equivalent thereof.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: June 29, 2004
    Assignee: Aventis Pharma Deutschland GmbH
    Inventors: Laszlo Vertesy, Klaus Ehrlich, Michael Kurz, Joachim Wink
  • Publication number: 20020193620
    Abstract: A process to produce organic phosphites from the group consisting of: 1
    Type: Application
    Filed: June 12, 2002
    Publication date: December 19, 2002
    Applicant: General Electric Co.
    Inventor: Gary Vincent Marlin
  • Patent number: 6440891
    Abstract: The catalyst comprises at least one bi- or more highly dentate phosphonite ligand of the general formula I or salts and mixtures thereof and is useful in a process for hydroformylating compounds containing at least one ethylenically unsaturated double bond by reaction with carbon monoxide and hydrogen.
    Type: Grant
    Filed: August 29, 2000
    Date of Patent: August 27, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Heiko Maas, Rocco Paciello, Michael Röper, Jakob Fischer, Wolfgang Siegel
  • Patent number: 6426429
    Abstract: A process to produce organic phosphites from the group consisting of: wherein each R1 , R2, and R3 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl; and wherein each R1, R2, and R3 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl and each R4 and R5 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl using a metal phenolate where each R1, R2, and R3 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl, and Q is a metal cation having a valence x, i.e.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: July 30, 2002
    Assignee: General Electric Company
    Inventor: Gary Vincent Marlin
  • Patent number: 6310260
    Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: October 30, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John Nicholas Argyropoulos, Jeffrey Scott Kanel, Michael Leo Tulchinsky, David James Miller, Donald Lee Morrison, Paul Foley, David Robert Bryant, Ailene Gardner Phillips, Brian Michael Roesch, John Robert Briggs, Max Min Lee, John Michael Maher
  • Patent number: 6307110
    Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: October 23, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John Nicholas Argyropoulos, Jeffrey Scott Kanel, Michael Leo Tulchinsky, David James Miller, Donald Lee Morrison, Paul Foley, David Robert Bryant, Ailene Gardner Phillips, Brian Michael Roesch, John Robert Briggs, Max Min Lee, John Michael Maher
  • Patent number: 6307108
    Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophoshorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a nonpolar solvent and a polar solvent by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5 (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: October 23, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John Nicholas Argyropoulos, Jeffrey Scott Kanel, Michael Leo Tulchinsky, David James Miller, Donald Lee Morrison, Paul Foley, David Robert Bryant
  • Patent number: 6307109
    Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more products, one or more nonpolar reaction solvents and one or more polar reaction solvents, in which said reaction product fluid exhibits phase behavior depicted by FIG. 1, wherein said process comprises (1) supplying said reaction product fluid from a reaction zone to a separation zone, (2) controlling concentration of said one or more nonpolar reaction solvents and said one or more polar reaction solvents, temperature and pressure in said separation zone sufficient to obtain by phase separation two immiscible liquid phases depicted by regions 2, 4 and 6 of FIG. 1 comprising a polar phase and a nonpolar phase and to prevent or minimize formation of three immiscible liquid phases depicted by region 5 of FIG. 1 and one homogeneous liquid phase depicted by regions 1, 3 and 7 of FIG.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: October 23, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Jeffrey Scott Kanel, David Robert Bryant, Brian Michael Roesch, Ailene Gardner Phillips
  • Patent number: 6303830
    Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: October 16, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John Nicholas Argyropoulos, Jeffrey Scott Kanel, Michael Leo Tulchinsky, David James Miller, Donald Lee Morrison, Paul Foley, David Robert Bryant
  • Patent number: 6303829
    Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more products, one or more nonpolar reaction solvents and one or more polar reaction solvents, wherein said process comprises (1) subjecting said reaction product fluid to fractional countercurrent extraction with at least two immiscible extraction solvents, said at least two immiscible extraction solvents comprising at least one nonpolar extraction solvent and at least one polar extraction solvent, to obtain a nonpolar phase comprising said metal-organophosphorus ligand complex catalyst, said optionally free organophosphorus ligand, said one or more nonpolar reaction solvents and said at least one nonpolar extraction solvent and a polar phase comprising said one or more products, said one or more polar reaction solvents and said at least one polar extraction solvent, and (2) recovering said polar
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: October 16, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Jeffrey Scott Kanel, John Nicholas Argyropoulos, Ailene Gardner Phillips, Brian Michael Roesch, John Robert Briggs, Max Min Lee, John Michael Maher, David Robert Bryant
  • Patent number: 6294700
    Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more products, one or more polar reaction solvents and one or more nonpolar reaction solvents, wherein said process comprises (1) subjecting said reaction product fluid to fractional countercurrent extraction with at least two immiscible extraction solvents, said at least two immiscible extraction solvents comprising at least one polar extraction solvent and at least one nonpolar extraction solvent, to obtain a polar phase comprising said metal-organophosphorus ligand complex catalyst, said optionally free organophosphorus ligand, said one or more polar reaction solvents and said at least one polar extraction solvent and a nonpolar phase comprising said one or more products, said one or more nonpolar reaction solvents and said at least one nonpolar extraction solvent, and (2) recovering said nonpo
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: September 25, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Jeffrey Scott Kanel, John Nicholas Argyropoulos, Ailene Gardner Phillips, Brian Michael Roesch, John Robert Briggs, Max Min Lee, John Michael Maher, David Robert Bryant
  • Patent number: 6294680
    Abstract: A process has been provided to produce semi synthetic statins, as for instance simvastatin with a high yield, for another statin, preferably a naturally occurring statin, as for instance lovastatin. Also a number of novel intermediate compounds, prepared during said process, has been provided.
    Type: Grant
    Filed: January 5, 2000
    Date of Patent: September 25, 2001
    Assignee: Plus Chemicals, B.V.
    Inventors: Ton Rene Vries, Hans Wijnberg, Wijnand Sjourd Faber, Venetka Ivanova Kalkman-Agayn, Mieke Ivanova Sibeyn
  • Patent number: 5962744
    Abstract: A process comprising subjecting at least one compound containing at least one carbon--carbon double bond or at least one carbon--carbon triple bond, hydrogen and carbon monoxide, to a hydrocarbonylation reaction in supercritical carbon dioxide, in the presence of a Group VIII transition metal catalyst precursor, and a phosphite ligand.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: October 5, 1999
    Assignees: The Research Foundation of State University of New York, Mitsubishi Chemical Corporation
    Inventors: Iwao Ojima, Hisao Urata
  • Patent number: 5952530
    Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: September 14, 1999
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John N. Argyropoulos, David Robert Bryant, Donald Lee Morrison, Kenneth Elwood Stockman
  • Patent number: 5932772
    Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and a nonpolar phase comprising said one or more products and nonpolar solvent, and (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: August 3, 1999
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John N. Argyropoulos, David Robert Bryant, Donald Lee Morrison, Kenneth Elwood Stockman, Anthony George Abatjoglou
  • Patent number: 5891939
    Abstract: Phosphites inhibitors for organic material represented by the formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 is hydrogen atom or alkyl; X is a direct bond, sulfur atom, or methylene group which may optionally be substituted with alkyl or cycloalkyl; A represents a dihydric alcohol residue; B is a direct bond or alkylene; and one of Y and Z represents an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group; and a process for producing the same are provided.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: April 6, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Taketoshi Kikuchi, Naoki Inui, Kanako Fukuda, Takashi Sanada
  • Patent number: 5889095
    Abstract: A phosphite stabilizer for organic material is represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 is hydrogen, alkyl, cycloalkyl, alkyl, cycloalkyl, aralkyl or phenyl; R is hydrogen or alkyl; X is a direct bond, sulfur atom or a --CHR.sup.6 group in which R.sup.6 represents hydrogen, alkyl or cycloalkyl; A is an alkylene group having 2 to 8 carbon atoms or *--COR.sup.7 -- in which R.sup.7 is a direct bond or alkyl group, and * represents the bond to the oxygen atom of the phenoxy radical; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkoxy group and the other one represents atom or an alkyl group.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: March 30, 1999
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Naoki Inui, Taketoshi Kikuchi, Kanako Fukuda, Takashi Sanada
  • Patent number: 5874494
    Abstract: Phosphites which are useful as a deterioration inhibitor for organic material and are represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group;R.sup.3 represents hydrogen atom or an alkyl group;R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 together form a direct bond, a group represented by --S-- or an optionally substituted methylene group;A represents an alkylene group;W represents a group represented by --O-- or a group represented by --NR.sup.7wherein R.sup.7 represents a hydrogen atom, an alkyl group, etc.;B represents an alkylene group;and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: February 23, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Naoki Inui, Taketoshi Kikuchi, Kanako Fukuda, Takashi Sanada
  • Patent number: 5843339
    Abstract: Phosphites represented by the general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, an alkylcycloalkyl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms or a phenyl group; R.sup.3 and R.sup.6 independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; X.sub.1 is a dihydric alcohol residue, wherein HO--X.sub.1 --OH defines the corresponding dihydric alcohol from which residue X.sub.1, is obtained; and X.sub.2 is a direct bond or an alkylene group having 1 to 8 carbon atoms; and the phosphites are useful as stabilizers for organic materials.
    Type: Grant
    Filed: October 1, 1996
    Date of Patent: December 1, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kanako Fukuda, Naoki Inui
  • Patent number: 5830936
    Abstract: Phosphites which are a deterioration inhibitors for organic material represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom, or certain hydrocarbyl radicals; X represents a direct bond, a sulfur atom or a methylene group which may optionally be substituted; Z is --A.sup.1 --CO--O--Y.sup.1 or --A.sup.2 --O--CO--Y.sup.2 wherein A.sup.1 is a direct bond or an alkylene group; Y.sup.1 is aralkyl or aryl; A.sup.2 is a residue of a dihydric alcohol; and Y.sup.2 is alkyl, aralkyl or a phenyl group, and a process for producing the same are provided.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: November 3, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Taketoshi Kikuchi, Naoki Inui, Kanako Fukuda, Takashi Sanada
  • Patent number: 5786497
    Abstract: A process for producing organo-phosphites is described that involves heating a di-substituted phosphorohalidite, a phenolic compound, and a polymeric amine. An especially useful polymeric amine is N,N,N'N'-tetraethyl-1,3-propanediamine. Conversions in excess of about 97% are obtained.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: July 28, 1998
    Assignee: General Electric Company
    Inventors: James A. Mahood, Matthew S. Scott
  • Patent number: 5736599
    Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: April 7, 1998
    Assignee: General Electric Company
    Inventor: James A. Mahood
  • Patent number: 5677432
    Abstract: A compound useful for forming immunoconjugates used in the detection of organophosphate pesticides is provided. The compound has the formula ##STR1## wherein X is selected from the group consisting of R--O--, R--S-- and R--NH--, where R is an optionally substituted aromatic or heterocyclic group, or an optionally substituted alkyl or alkenyl group;Y is O or S;R.sup.1 is H or alkyl; andR.sup.2 is a group of the formula --(CH.sub.2).sub.n -- wherein n is an integer of from 1 to 10, or branched chain alkylene, or a group of the formula R.sup.3 --O--R.sup.4 wherein R.sup.3 and R.sup.4 are both or straight or branched chain alkylene;or a salt or ester thereof.
    Type: Grant
    Filed: August 19, 1994
    Date of Patent: October 14, 1997
    Assignee: The Horticulture and Food Research Institute of New Zealand Limited
    Inventors: William Thomas Jones, Hans Wynberg, Wolter Ten Hoeve
  • Patent number: 5623009
    Abstract: A phosphite is provided having the formula: ##STR1## wherein Y.sup.1 is an alkyl group and Y.sup.2 is selected from the group consisting of sec-butyl and tert-butyl. The phosphite exhibits enhanced stability including hydrolytic and UV stability, and is useful in stabilizing thermoplastic compositions.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: April 22, 1997
    Assignee: General Electric Company
    Inventor: James A. Mahood
  • Patent number: 5618961
    Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: April 8, 1997
    Assignee: General Electric Company
    Inventor: James A. Mahood
  • Patent number: 5618962
    Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: April 8, 1997
    Assignee: General Electric Company
    Inventor: James A. Mahood
  • Patent number: 5600032
    Abstract: A method for producing an unsaturated alcohol having a chain structure formed by oligomerization of a conjugated alkadiene, which comprises reacting a conjugated alkadiene and water in the presence of carbon dioxide by means of a palladium compound and a phosphorus compound having at least one trivalent phosphorus-oxygen single bond, as catalyst.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 4, 1997
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Keiichi Sato, Yoko Seto, Iwao Nakajima
  • Patent number: 5576365
    Abstract: An organic phosphorus compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2 independently represent alkyl having 1-8 carbon atoms, cycloalkyl having 5-8 carbon atoms, alkylcycloalkyl having 6-12 carbon atoms, arylalkyl having 7-12 carbon atoms or phenyl; R.sup.3 represents hydrogen or alkyl having 1-8 carbon atoms, X represents a direct bond or --CH(R.sup.4)-- wherein R.sup.4 represents hydrogen or alkyl having 1-8 carbon atoms; a phosphorus type stabilizer for various organic materials such as synthetic resins or synthetic rubbers or an organic material composition comprising the same.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: November 19, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kanako Fukuda, Tetsuo Yamaguchi, Shinya Tanaka, Manji Sasaki
  • Patent number: 5523448
    Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: June 4, 1996
    Assignee: General Electric Company
    Inventor: James A. Mahood
  • Patent number: 5464889
    Abstract: Neoalkyl phosphite provided which exhibit improved levels of stability. The phosphites are hindered and are useful in stabilizing thermoplastic compositions.
    Type: Grant
    Filed: August 3, 1994
    Date of Patent: November 7, 1995
    Assignee: General Electric Company
    Inventor: James A. Mahood
  • Patent number: 5451623
    Abstract: Neoalkyl alkylidene-2,2'-bisphenyl phosphite esters are provided. The phosphites exhibit enhanced thermal and hydrolytic stability, and are useful as additives in thermoplastic resin compositions to enhance the thermal oxidative stability thereof.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: September 19, 1995
    Assignee: General Electric Company
    Inventors: James A. Mahood, Carloss L. Gray
  • Patent number: 5424348
    Abstract: A phosphite is provided having the formula: ##STR1## wherein Y.sup.1 is an alkyl group and Y.sup.2 is selected from the group consisting of sec-butyl and tert-butyl. The phosphite exhibits enhanced stability including hydrolytic and UV stability, and is useful in stabilizing thermoplastic compositions.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: June 13, 1995
    Assignee: General Electric Company
    Inventor: James Mahood
  • Patent number: 5414033
    Abstract: Novel compounds of the formula I and formula II ##STR1## in which R and R.sub.1, independently of one another, are hydrogen or C.sub.1 -C.sub.4 alkyl or together with the carbon atom to which they are attached form a 3,4-dehydrocyclohexylidene ring,R.sub.2 is hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.5 -C.sub.6 cycloalkyl,R.sub.3 is C.sub.1 -C.sub.8 alkyl or C.sub.5 -C.sub.6 cycloalkyl,R.sub.4, R.sub.5 and R.sub.6, independently of one another, are hydrogen or C.sub.1 -C.sub.4 alkyl, when alkyl, R.sub.4, R.sub.5 and R.sub.6 together containing 1 to 4 carbon atoms, andR.sub.7 and R.sub.8 are hydrogen or together an additional direct bond, are described for use as stabilizers for organic materials against thermal, oxidative or light-induced degradation.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: May 9, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Nesvadba
  • Patent number: 5362898
    Abstract: A bis(pentaerythritol phosphate alcohol) alkylphosphonate compound, such as one comprising an alkyl group of from about one to four carbon atoms, preferably bis(pentaerythritol phosphate alcohol) methylphosphonate, is a flame retardant compound. Such a compound can be prepared by the transesterification of a diphenyl alkyl phosphonate carrying the desired alkyl group with pentaerythritol phosphate alcohol. An alternative process of preparation comprises the reaction of pentaerythritol phosphate alcohol, a trialkylamine, and an alkylphosphonic dihalide.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: November 8, 1994
    Assignee: Akzo Nobel nv
    Inventor: Jeffrey E. Telschow
  • Patent number: 5308902
    Abstract: Biphosphites of formula I ##STR1## wherein m is 0, 1 or 2,n is 1 to 4 or 6,R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different, and A is the radical of an at least n-hydric alcohol or phenol, which radical is attached to the P atom or atoms through the alcoholic or phenolic O atom or atoms, obtainable by reacting a compound of formula II ##STR2## wherein m is 0, 1 or 2, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different and R.sub.2 ' is phenyl, C.sub.1 -C.sub.12 alkylphenyl or C.sub.1 -C.sub.4 alkyl, with a polyether polyol or polyether/ester polyol, the hydroxy functions of said polyether polyol or polyether/ester polyol being partially or completely esterified with the ##STR3## are suitable for use as stabilizers, especially processing stabilizers, for organic polymers, preferably PVC resins, high density polyethylene and propylene.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: May 3, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Holger Andreas, Alfred Renner, Horst Zinke
  • Patent number: 5210259
    Abstract: A process for the preparation of diesters of carboxymethylphosphonic acid of the formula: (RO).sub.2 P(O)CH.sub.2 CO.sub.2 H, in which R is a straight-chain or branched alkyl radical having 1 to 20 carbon atoms, a cycloaliphatic radical having 5 to 8 carbon atoms, a phenyl or naphthyl radical which can be substituted, an aralkyl radical having 7 to 10 carbon atoms, or in which the (RO).sub.2 P group forms a ring having 2 to 5 carbon atoms which can be substituted, characterized in that dialkyl ester of 2-hydroxyethylphosphonic acid of the formula (RO).sub.2 P(O)CH.sub.2 CH.sub.2 OH, in which R has the abovementioned meaning, is reacted with oxygen in the presence of water and a catalyst which contains at least one metal selected from the platinum metals group.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: May 11, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst I. Leupold, Gunter Roscher
  • Patent number: 5142083
    Abstract: Hydrolytically stable phosphite compositions for melt flow and color stabilization of thermoplastics may be prepared from crude tetrahydroabietyl alcohol. The phosphites may be prepared by reacting said alcohol with an organophosphite, such as by transesterification. Other synthesis techniques may also be used.
    Type: Grant
    Filed: July 16, 1991
    Date of Patent: August 25, 1992
    Assignee: General Electric Company
    Inventor: William P. Enlow