Nitrogen In Alcohol Moiety Patents (Class 560/110)
  • Patent number: 4260811
    Abstract: The level of 2-oxazoline or an oxazine impurity in an isocyanatoalkyl ester of an organic carboxylic acid is reduced by (i) reacting the impurity with an organic acid chloride, a chloroformate, a thiochloroformate, a sulfonyl chloride, phosphoryl chloride, sulfuryl chloride or thionyl chloride and (ii) fractionally distilling the reaction mixture to recover the isocyanatoalkyl ester. As an example, crude 2-isocyanatoethyl methacrylate (IEM) containing 0.19 weight percent 2-isopropenyl-2-oxazoline (IPO) is contacted with terephthaloyl chloride for 0.5 hour at 90.degree. C. The reaction mixture is fractionally distilled to recover 97 weight percent of the IEM containing only 0.02 weight percent IPO.
    Type: Grant
    Filed: January 14, 1980
    Date of Patent: April 7, 1981
    Assignee: The Dow Chemical Company
    Inventor: Abel Mendoza
  • Patent number: 4250324
    Abstract: Water-degradable compounds formed from amine-type compounds, aldehydes and aromatic carboxylic acids, the respective components reacting to form a complex ester which upon contact with water slowly degrades to release, at least, the original carboxylic acid.
    Type: Grant
    Filed: November 18, 1977
    Date of Patent: February 10, 1981
    Inventors: Marvin L. Beasley, Norman G. Rhode
  • Patent number: 4239855
    Abstract: Covers compounds of the formula ##STR1## where R is lower alkyl, lower alkenyl or phenyl and R' and R" are either lower alkyl or form a morpholine ring when taken with the adjacent nitrogen atom. Also covers a method of producing a polyurethane foam and elastomer by utilizing said above compounds as catalysts in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst.
    Type: Grant
    Filed: July 21, 1978
    Date of Patent: December 16, 1980
    Assignee: Texaco Development Corp.
    Inventor: Robert L. Zimmerman
  • Patent number: 4219660
    Abstract: There are disclosed herein derivatives of bisfunctionalized compounds, wherein said compounds have been formed by the introduction of a nitro group and a hydroxyl group in the form of an ester into a conjugated diene molecule by treatment of said conjugated dienes with nitric acid in the presence of a carboxylic acid anhydride. The novel compounds produced by this process are useful as bactericides, fungicides and valuable organic synthesis intermediates.
    Type: Grant
    Filed: June 24, 1977
    Date of Patent: August 26, 1980
    Assignee: Hoffmann-La Roche Inc.
    Inventor: Pius A. Wehrli
  • Patent number: 4173706
    Abstract: A novel process for producing fluorinated organic compounds containing a difluoromethylene group, essentially characterized by reacting organic compounds containing a carbonyl function with molybdenum hexafluoride at room temperature and under atmospheric pressure.
    Type: Grant
    Filed: April 6, 1978
    Date of Patent: November 6, 1979
    Assignee: Institute National de Recherche Chimique Appliquee
    Inventors: Francois Mathey, Jean Bensoam
  • Patent number: 4173574
    Abstract: Phenolic age resistors such as 4-(3,5-ditertiary butyl-4-hydroxyphenyl)-2-butyl 2-methyl-4-thia-6-octanoyloxyhexanoate are used as antioxidants in diene rubbers, such as butadiene-styrene types and in polyolefins, such as polypropylene.
    Type: Grant
    Filed: October 11, 1977
    Date of Patent: November 6, 1979
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Richard H. Kline
  • Patent number: 4160099
    Abstract: Labile quaternary ammonium salts of the following formula (I) and (II) are provided: ##STR1## wherein ##STR2## represents a tertiary aliphatic amine; wherein ##STR3## represents an unsaturated amine; wherein R represents a member selected from the group consisting of a hydrogen atom, a C.sub.1 -C.sub.8 open chain or cyclo alkyl group, a C.sub.1 -C.sub.8 alkoxyalkyl group, a C.sub.1 -C.sub.8 acyloxyalkyl group, a C.sub.1 -C.sub.8 haloalkyl group, a C.sub.1 -C.sub.8 carboxyalkyl group, a C.sub.2 -C.sub.8 alkenylphenyl group, an aryl group, and a substituted aryl group, whose substituents are selected from the group consisting of a halogen atom, an O-lower alkyl (C.sub.1 -C.sub.4) group, an O-acyl group, a nitro group, a carboxyl group, and a carboethoxy group; wherein R.sub.1 which may be the same or different, represents any member defined by R above with the proviso that R.sub.
    Type: Grant
    Filed: September 20, 1976
    Date of Patent: July 3, 1979
    Assignee: Interx Research Corporation
    Inventor: Nicolae S. Bodor
  • Patent number: 4159991
    Abstract: .alpha.-Acyloxy-N,N'-diacylmalonamides of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, straight chain or branched alkyl radicals having from one to eleven carbon atoms, or hydrocarbon radicals with six to twelve carbon atoms and comprising at least one aromatic ring, are novel compounds prepared by the action of a mixture of carboxylic acids R.sub.3 COOH and R.sub.4 COOH upon an .alpha.-acyloxymalononitrile, R.sub.1 COO--C(CN).sub.2 --R.sub.2, in the presence of an acid catalyst and are useful as intermediates in organic synthesis and low temperature activators in bleaching or scouring compositions.
    Type: Grant
    Filed: August 22, 1977
    Date of Patent: July 3, 1979
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventors: Bernard Dubreux, Serve Y. Delavarenne, Jean-Pierre Schirmann
  • Patent number: 4158672
    Abstract: Polyfluoroalkylthio alcohols and esters thereof are disclosed with utility as intermediates for the synthesis of fluorochemicals with low free surface energies having oil and water repellent properties. The novel alcohols and esters are obtained by a free radical catalyzed addition of polyfluoroalkylthiols to acetylenic alcohols or esters thereof. The alcohols are employed in preparation of fluorine containing polyurethanes which are useful as finishes to provide oil and water repellency to textiles and as additives to plastics to provide mold release and other desirable properties.
    Type: Grant
    Filed: December 23, 1977
    Date of Patent: June 19, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Robert E. A. Dear, Neal O. Brace
  • Patent number: 4137417
    Abstract: Enamides are prepared by hydrogenating oximes having at least one hydrogen atom at the .alpha.-position in the presence of a carboxylic anhydride using a ruthenium catalyst. These enamides are important to obtain amino group-containing compounds by reduction or polymerization.
    Type: Grant
    Filed: April 26, 1977
    Date of Patent: January 30, 1979
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Motoo Hazama
  • Patent number: 4113463
    Abstract: A method for regulating the elongation of plants so as to increase their resistance to lodging by applying a plant regulating effective amount of a plant growth regulator containing as active ingredient a benzenesulfonamide compound of the formula ##STR1## wherein X, R.sub.1, R.sub.2 and n are as defined hereinbelow.
    Type: Grant
    Filed: March 11, 1977
    Date of Patent: September 12, 1978
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiromichi Oshio, Hiroyuki Konishi, Shiunzi Matsumura, Kikuichi Ishikawa, Eiichi Yoneyama
  • Patent number: 4091006
    Abstract: A new series of substituted esters of 3-hydroxyindone compounds have been found to have exceptional miticidal and herbicidal activity.
    Type: Grant
    Filed: October 1, 1975
    Date of Patent: May 23, 1978
    Assignee: Union Carbide Corporation
    Inventors: John A. Durden, Jr., Anthony A. Sousa, John F. Stephen
  • Patent number: 4088674
    Abstract: This invention concerns novel ester isocyanates derived from acyloxyalkylamine hydrochlorides. The novel compounds may contain a hetero atom in either the acid or alkanolamine moiety and may contain oxalic acid as the acyl moiety.
    Type: Grant
    Filed: May 12, 1972
    Date of Patent: May 9, 1978
    Assignee: Rohm and Haas Company
    Inventors: William D. Emmons, Jerome F. Levy