Sulfur Or Halogen In Alcohol Moiety Patents (Class 560/87)
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Patent number: 4340749Abstract: An ester of a fluoroaliphatic radical- and aliphatic chlorine-containing alcohol and a mono or polycarboxylic acid useful in carpet treatment.Type: GrantFiled: December 8, 1980Date of Patent: July 20, 1982Assignee: Minnesota Mining and Manufacturing CompanyInventor: Kalyanji U. Patel
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Patent number: 4329489Abstract: Preparation of a fluorocarbon compound used to make a soil-resistant yarn is improved by removing most of the impurities from the fluoro-carbon compound mass with heat and vacuum after the final washing step and then adding an emulsifier to the fluorocarbon compound mass so that the mass can be handled as a liquid concentrate rather than a tacky solid.Type: GrantFiled: May 19, 1980Date of Patent: May 11, 1982Assignee: Allied Chemical CorporationInventors: Peter R. Saunders, Raymond J. Biron
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Patent number: 4321403Abstract: An anhydride of a carboxybenzene is esterified in solution by a fluorinated alcohol, using N-methylpyrrolidone solvent. In particular, pyromellitic dianhydride in N-methylpyrrolidone solvent is esterified to the diester/diacid by 2-(n-perfluoroalkyl)ethanols having six to twelve carbon atoms in the perfluoroalkyl groups, and the reaction mixture containing the dissolved diester/diacid is admixed with an oxirane compound of the group ethylene oxide, epichlorohydrin and glycidol whereby the carboxyl groups are esterified in the N-methylpyrrolidone solvent by reaction with oxirane groups.Type: GrantFiled: June 4, 1979Date of Patent: March 23, 1982Assignee: Allied CorporationInventors: Bruce C. Oxenrider, Frank Mares
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Patent number: 4304921Abstract: Beta-halo esters, such as .beta.-haloalkyl benzoates or terephthalates, are prepared by halogenative cleavage of cyclic acetals using trimethyl phosphate (TMP) or borate to mediate the reaction. The .beta.-halo esters, which are obtained in high yields, can be used to form polymers or plasticizers. Neuromuscular blocking agents such as succinylcholine and related compounds can also be prepared.Type: GrantFiled: August 8, 1980Date of Patent: December 8, 1981Assignee: Vanderbilt UniversityInventors: Donald E. Pearson, Sidhaghatta D. Venkataramu, James H. Cleveland, Jr.
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Patent number: 4283292Abstract: Emulsion and several spin finishes are disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. The emulsions and spin finishes all include a yarn finish composition which comprises (a) a solution of a salt of dioctyl sulfosuccinate, propylene glycol and water, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: December 12, 1979Date of Patent: August 11, 1981Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4282138Abstract: Esters of tetracarboxylic acids having the following general formula:(RO.sub.2 C').sub.2 .dbd.X.dbd.(C"O.sub.2 R').sub.2wherein .dbd.X.dbd. is selected from tetravalent 5 or 6 membered or a double 6 membered ring system and wherein C' and C" carbons are attached to separate pairs of vicinal carbons and R and R' are selected from halogenated organic radicals containing at least 2 atoms of chlorine or bromine and the other of each R and R' is selected from --H, --CH.sub.2 CH(OH)CH.sub.2 O.sub.2 CCR".dbd.CH.sub.2, and --CH[CH.sub.2 (OH)]CH.sub.2 O.sub.2 CCR".dbd.CH.sub.2 are useful in the preparations of high molecular weight polymers and copolymers which are improved in fire retardance and strength.Type: GrantFiled: October 26, 1978Date of Patent: August 4, 1981Assignee: ICI Americas Inc.Inventor: Erich Kuehn
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Patent number: 4252982Abstract: An anhydride of a carboxybenzene is esterified in solution by a fluorinated alcohol, using an aliphatic ester having a boiling point between about 50.degree. C. and about 150.degree. C. as solvent. In particular, pyromellitic dianhydride is esterified in an ester such as ethyl acetate or butyl acetate to the diester/diacid by reaction with 2-(n-perfluoroalkyl)ethanols having six to twelve carbon atoms in the perfluoroalkyl groups, and the reaction mixture containing the dissolved diester/diacid is admixed with an oxirane compound of the group ethylene oxide, epichlorohydrin and glycidol whereby the carboxyl groups are esterified in the solvent by reaction with oxirane groups. The product is recovered by evaporating off the solvent and unreacted oxirane compound. The product imparts oil and/or water repellency to textiles.Type: GrantFiled: October 29, 1979Date of Patent: February 24, 1981Assignee: Allied Chemical CorporationInventor: Bryce C. Oxenrider
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Patent number: 4229207Abstract: Esters of 1,2-diphenyl-cyclohex-1-ene-4-carboxylic-acid are effective plant growth regulating agents. They are useful for controlling wild oats in cereal cultures and for growth inhibition in different cultures, e.g. for the inhibition of suckers in tobacco plants.Type: GrantFiled: June 22, 1978Date of Patent: October 21, 1980Assignee: Ciba-Geigy CorporationInventors: Verena Laanio, Werner Fory, Rolf Schurter
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Patent number: 4221916Abstract: Saturated vicinal esters produced by reacting olefins with carboxylic acid and anhydrides thereof in the presence of oxygen and a vanadium- or ruthenium-containing catalyst.Type: GrantFiled: August 25, 1978Date of Patent: September 9, 1980Assignee: Phillips Petroleum CompanyInventor: Paul R. Stapp
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Patent number: 4221917Abstract: Monoolefins and diolefins are converted to corresponding esters in a process by contacting together at least one monoolefin, diolefin or mixture thereof, oxygen, at least one iodosoaryl dicarboxylate and at least one carboxylic acid, carboxylic acid anhydride or mixture thereof.Type: GrantFiled: March 3, 1978Date of Patent: September 9, 1980Assignee: Phillips Petroleum CompanyInventor: Paul R. Stapp
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Patent number: 4219625Abstract: As an additive imparting oil and water repellency, durable against laundering and abrasion, to PET fibers: a partially or fully acylated polyol, especially pentaerythritol, glycerol, hydroquinone or ethylene glycol, acylated with a phthalic or terephthalic monoester having a perfluorinated alkyl or alkoxyalkyl C.sub.2 to C.sub.20 radical, especially C.sub.5 to C.sub.10 n-alkyl or (CF.sub.2).sub.n OR.sub.f where R.sub.f is C.sub.1 to C.sub.6 perfluoroalkyl, especially perfluoroisopropyl and (CF.sub.2).sub.n is a straight chain C.sub.2 to C.sub.10 diradical.Type: GrantFiled: December 16, 1977Date of Patent: August 26, 1980Assignee: Allied Chemical CorporationInventors: Frank Mares, Bryce C. Oxenrider, Cyril Woolf
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Patent number: 4193880Abstract: A yarn finish composition is disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. The composition comprises (a) a nonhomogeneous mixture of a salt of dinonyl sulfosuccinate, a salt of dimethyl naphthalene sulfonate, and ammonium perfluoroalkyl carboxylate, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: March 30, 1979Date of Patent: March 18, 1980Assignee: Allied Chemical CorporationInventor: Robert M. Marshall
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Patent number: 4194052Abstract: A sulfonic acid salt of an acyloxyalkylamine is prepared by reaction of an organic acid or amino-acid with a sulfonic acid salt of an alkanolamine. Isocyanates are prepared therefrom by reaction with phosgene.Type: GrantFiled: May 1, 1969Date of Patent: March 18, 1980Assignee: Rohm and Haas CompanyInventors: Sheldon N. Lewis, Jerome F. Levy
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Patent number: 4192754Abstract: A yarn finish composition is disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. The composition comprises (a) a solution of a salt of dioctyl sulfosuccinate, propylene glycol and water, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: December 28, 1978Date of Patent: March 11, 1980Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4190545Abstract: Several spin finishes are disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. All of the spin finishes include a yarn finish composition which comprises (a) a nonhomogeneous mixture of a salt of dinonyl sulfosuccinate, a salt of dimethyl naphthalene sulfonate, and ammonium perfluoroalkyl carboxylate, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxy-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: March 30, 1979Date of Patent: February 26, 1980Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4176232Abstract: A sulfonic acid salt of an acyloxyalkylamine is prepared by reaction of an organic acid or amino-acid with a sulfonic acid salt of an alkanolamine. Isocyanates are prepared therefrom by reaction with phosgene.Type: GrantFiled: June 27, 1968Date of Patent: November 27, 1979Assignee: Rohm and Haas CompanyInventors: Sheldon N. Lewis, Jerome F. Levy
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Patent number: 4165432Abstract: Compounds containing peroxy linkages connecting similar polyol ester constituents are described. These peroxy di-ester polyols are prepared by the direct esterification of peroxy diacids with polyols, in the presence of a strong mineral acid catalyst. The peroxy di-ester polyol products function as free radical initiators and grafting bases in the graft copolymerization of unsaturated monomers with polyols. These graft copolymers are useful in the formulation of polyurethanes.Type: GrantFiled: October 18, 1977Date of Patent: August 21, 1979Assignee: Olin CorporationInventors: Frank J. Preston, Theodore C. Kraus, Kiran B. Chandalia
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Patent number: 4164615Abstract: A catalyst comprising a titanium compound, an alkali metal ion, and a halide, is effective for the conversion of conjugated diolefins to diacyloxy olefins.Type: GrantFiled: August 25, 1977Date of Patent: August 14, 1979Assignee: Phillips Petroleum CompanyInventor: Paul R. Stapp
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Patent number: 4162363Abstract: Conjugated dienes or monoolefins are converted to diesters in a process utilizing a catalyst system comprising an alkali metal compound and a sulfur source comprising elemental sulfur or a sulfur halide, optionally with a halide source, in carboxylic acid media.Type: GrantFiled: August 25, 1977Date of Patent: July 24, 1979Assignee: Phillips Petroleum CompanyInventor: Paul R. Stapp
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Patent number: 4134839Abstract: A soil resistant spin finish particularly for polyamide feeder yarn to be processed at high temperature into bulked textile yarn, comprising a first oil in water emulsion wherein the oil portion consists essentially of sorbitan monooleate, polyoxyethylene tallow amine, and an alkyl stearate, said first oil in water emulsion being mixed with a second oil in water emulsion wherein the oil portion consists essentially of an alkanol amide which is a reaction product of coco fatty acid and diethanol amine, and a fluorochemical compound consisting of a polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as glyceryl, 2-hydroxyethyl, chlorohydryl or bromohydryl. Textiles prepared from the bulked yarn show excellent resistance to soiling by oily materials.Type: GrantFiled: February 2, 1978Date of Patent: January 16, 1979Assignee: Allied Chemical CorporationInventor: Robert M. Marshall
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Patent number: 4125733Abstract: A compound of the formula ##STR1## is provided that is useful for imparting soil release properties and durable flame retardancy to textiles such as all-polyester fabric either alone or in combination with other textile chemicals.Type: GrantFiled: September 26, 1977Date of Patent: November 14, 1978Assignee: Pennwalt CorporationInventor: Stanley R. Sandler
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Patent number: 4095029Abstract: 2-Hydroxy-3-alkylsulfoxypropyl-1 esters of arene polycarboxylic acids.Type: GrantFiled: January 17, 1977Date of Patent: June 13, 1978Assignee: Standard Oil Company (Indiana)Inventor: Ellis K. Fields
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Patent number: 4088674Abstract: This invention concerns novel ester isocyanates derived from acyloxyalkylamine hydrochlorides. The novel compounds may contain a hetero atom in either the acid or alkanolamine moiety and may contain oxalic acid as the acyl moiety.Type: GrantFiled: May 12, 1972Date of Patent: May 9, 1978Assignee: Rohm and Haas CompanyInventors: William D. Emmons, Jerome F. Levy
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Patent number: 4084059Abstract: A 2-hydroxy-1,1,2,3,3-pentahydroperfluoroalkyl derivative of either one of the formulae:[RfCH.sub.2 CH(OH)CH.sub.2 OOC].sub.m QandQ'(NR.sub.1 R.sub.2).sub.m'wherein Rf is a perfluoroalkyl, an .omega.-hydro-perfluoroalkyl or an .omega.-chloro-perfluoroalkyl group having 4 to 20 carbon atoms, Q is a hydrocarbon residue having a valency corresponding to m which may contain one or more of --O--, --COO-- and --OH in and/or on the chain, Q' is a hydrogen atom or a hydrocarbon residue having a valency corresponding to m' which may contain one or more of --O--, --COO--, --NH--, --N.dbd. and ##STR1## IN THE CHAIN, R.sub.1 and R.sub.2 are each a hydrogen atom or a group of the formula: --CH.sub.2 CH(OH)CH.sub.2 Rf, at least one of R.sub.1 and R.sub.2 being --CH.sub.2 CH(OH)CH.sub.2 Rf, m is an integer of not less than 2 and m' is an integer of not less than 1, which is useful as an oil-repellent agent or an anti-soiling agent for fibrous materials.Type: GrantFiled: January 6, 1975Date of Patent: April 11, 1978Assignee: Daikin Kogyo Co., Ltd.Inventors: Atsuo Katsushima, Iwao Hisamoto, Shoshin Fukui, Chiaki Maeda, Akitoshi Iwatani, Takahisa Kato, Masayuki Nagai, Hiroyuki Shinkai, Masayuki Asaoka
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Patent number: 4063024Abstract: Novel polyoxyalkylene fluoroalkyltrimellitate compounds are disclosed that are useful for improving the soil release properties of textiles. These compounds may be conveniently prepared by reacting a fluorinated alkyl thiol or amine with trimellitic anhydride monoacid chloride to form a fluorinated trimellitic anhydride intermediate product which is then reacted with a polyoxyalkylene derivative.Type: GrantFiled: September 10, 1976Date of Patent: December 13, 1977Assignee: Pennwalt CorporationInventor: Stanley Robert Sandler