Plural Nonsulfonate Chalcogens Attached Indirectly To The Sulfonate Groups By Nonionic Bonding Patents (Class 562/103)
  • Patent number: 9790606
    Abstract: To provide a surface treatment solution and treatment method for gold or gold alloy plating that effectively suppresses corrosion of underlying metal or substrate metal from pinholes that develop on the gold or gold alloy plating film. [Solution] A surface treatment solution containing a disulfide compound is brought into contact with a gold or gold alloy plating film. A compound represented by the following formula (2) is preferred as the disulfide compound. X1O3S—R3—S—S—R4—SO3X2??(2) in the formula, R3 and R4 independently represent a linear or branched alkylene group having from 1 to 10 carbon atoms, cyclic alkylene group having from 3 to 10 carbon atoms, or phenylene group, R3 and R4 independently may be substituted by one or more substituents selected from an alkyl group, halogen atom, hydroxyl group, or alkoxy group, and X1 and X2 represent monovalent cations.
    Type: Grant
    Filed: November 30, 2014
    Date of Patent: October 17, 2017
    Assignee: Rohm and Haas Electronics Materials LLC
    Inventor: Koichi Yomogida
  • Publication number: 20140363507
    Abstract: The present invention relates to the novel compound classes of dendritic polyglycerol sulfates and sulfonates as well as to their production and use for the treatment of diseases, particularly inflammatory diseases, and to their use as selectin inhibitors and selectin indicators. The dendritic polyglycerol sulfates and sulfonates are also suitable for imaging diagnostics, particularly with respect to inflammatory diseases.
    Type: Application
    Filed: August 26, 2014
    Publication date: December 11, 2014
    Applicant: FREIE UNIVERSITAT BERLIN
    Inventors: Rainer HAAG, Jens DERNEDDE, Rudolf TAUBER, Gesche BERNHARD, Sven ENDERS, Heidemarie WEINHART, Arne VON BONIN, Ulrich ZÜGEL, Holger TÜRK
  • Patent number: 8900794
    Abstract: A photoacid generator compound has the formula (I): [A-(CHR1)p]k-(L)-(CH2)m—(C(R2)2)n—SO3?Z+??(I) wherein A is a substituted or unsubstituted, monocyclic, polycyclic, or fused polycyclic C5 or greater cycloaliphatic group optionally comprising O, S, N, F, or a combination comprising at least one of the foregoing, R1 is H, a single bond, or a substituted or unsubstituted C1-30 alkyl group, wherein when R1 is a single bond, R1 is covalently bonded to a carbon atom of A, each R2 is independently H, F, or C1-4 fluoroalkyl, wherein at least one R2 is not hydrogen, L is a linking group comprising a sulfonate group, a sulfonamide group, or a C1-30 sulfonate or sulfonamide-containing group, Z is an organic or inorganic cation, p is an integer of 0 to 10,k is 1 or 2, m is an integer of 0 or greater, and n is an integer of 1 or greater.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: December 2, 2014
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Emad Aqad, Cheng-Bai Xu, Mingqi Li, Shintaro Yamada, William Williams, III
  • Patent number: 8557474
    Abstract: A fluorosulfonyl group-containing monomer having a high polymerization reactivity and plural fluorosulfonyl groups, a fluorosulfonyl group-containing polymer and a sulfonic acid group-containing polymer, obtained by using the monomer.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: October 15, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Atsushi Watakabe, Hiromasa Yamamoto, Masao Iwaya, Susumu Saito
  • Patent number: 8440857
    Abstract: Sulfonate- or sulfate-capped, alkoxylated anti-misting agents having the structures: R((AO)nX)m((AO)nH)p and R3C(O)NH(CH2)zN+(CH3)2CH2CHR4CH2SO3?, and to methods of suppressing mist from electrolyte solutions by adding a mist-suppressing amount of one or more of said compounds to electrolyte solutions.
    Type: Grant
    Filed: September 19, 2007
    Date of Patent: May 14, 2013
    Assignee: BASF Corporation
    Inventors: Michael Virnig, Jack Bender, Louis Rebrovic
  • Patent number: 8435717
    Abstract: A sulfonic acid onium salt represented by the following formula (1) can be used as a superior radiosensitive acid generator for resist compositions. It is possible to form a good pattern by using a resist composition containing this sulfonic acid onium salt. In formula (1), R1 represents a monovalent organic group, and Q+ represents a sulfonium cation or iodonium cation.
    Type: Grant
    Filed: February 14, 2008
    Date of Patent: May 7, 2013
    Assignee: Central Glass Company, Limited
    Inventors: Yuji Hagiwara, Jonathan Joachim Jodry, Satoru Narizuka, Kazuhiko Maeda
  • Patent number: 8343326
    Abstract: Sulfonate-, sulfate-, or carboxylate-capped, alkoxylated anti-misting agents having the structure: R((AO)nX)m((AO)nH)p, and methods of suppressing mist from electrolyte solutions by adding a mist-suppressing amount of one or more compounds selected from the group consisting of compounds of the Formulas R((AO)nX)m((AO)nH)p and R3N+(CH3)2R4, and mixtures thereof, to electrolyte solutions.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: January 1, 2013
    Assignee: BASF Corporation
    Inventors: Michael Virnig, Jack Bender, Louis Rebrovic
  • Publication number: 20120053057
    Abstract: The present invention provides an amphiphile of the formula (I) as described hereinafter. The invention further relates to a process for preparing the amphiphile and to a composition comprising the amphiphile and a sparingly water-soluble active ingredient. It further relates to a process for producing the composition by contacting the amphiphile and the active ingredient, and to the use of the amphiphile for solubilizing a sparingly water-soluble active ingredient in aqueous solutions. The invention also relates to the use of the amphiphile in an agrochemical formulation comprising the amphiphile and a pesticide for controlling phytopathogenic fungi and/or unwanted vegetation and/or unwanted insect or mite infestation and/or for regulating the growth of plants, and finally to plant propagation material comprising the amphiphile.
    Type: Application
    Filed: August 31, 2011
    Publication date: March 1, 2012
    Applicant: BASF SE
    Inventors: Anna CRISTADORO, Holger TÜRK, Michael ISHAQUE, Rabie AL-HELLANI
  • Publication number: 20110269652
    Abstract: The invention relates to gemini surfactants of formula IA wherein A is a core derived from an organic polyhydroxy compound; R1 and R2 are each independently a hydrophobic group; and R3 and R4 are each independently a surfactant head group. Such surfactants can be used as components of fluids used in the petroleum industry or used in formulating cleansing compositions or detergent compositions.
    Type: Application
    Filed: October 29, 2009
    Publication date: November 3, 2011
    Applicant: ST. FRANCIS XAVIER UNIVERSITY
    Inventors: D. Gerrard Marangoni, T. Bruce Grindley, Nusrat Jahan, Christian Petropolis, Thomas Tran, Nawal Paul
  • Patent number: 7282602
    Abstract: This invention relates to novel salts of medicinal disulfides. The compounds include a terminal sulfonate or phosphonate moiety, and have many uses, such as toxicity reducing agents when administered with many antineoplastic agents.
    Type: Grant
    Filed: September 21, 2004
    Date of Patent: October 16, 2007
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventors: Qiuli Huang, Harry Kochat, Xinghai Chen
  • Patent number: 7189798
    Abstract: This invention relates to new cyclodextrin derivatives, processes for producing these cyclodextrin derivatives, and inclusion complexes comprised of the new cyclodextrin derivatives and guest molecules, as well as methods of making such materials and related materials and methods of using the same.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: March 13, 2007
    Assignee: Eastman Chemical Company
    Inventors: Charles M. Buchanan, Steven N. Falling, Juanelle L. Lambert, Shannon E. Large, Jozsef Szejtli, Lajos Szente, Laszlo Jicsinszky
  • Patent number: 7053240
    Abstract: This invention relates to a process for producing a substantially pure disulfide compound of Formula II as disclosed herein, such as disodium 2,2?-dithiobis ethane sulfonate, by an efficient procedure from available, relatively inexpensive raw materials.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: May 30, 2006
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventors: Koh Kawami, Osamu Tokuda, Yoshihide Niimoto
  • Patent number: 6951954
    Abstract: A process for the continuous production of at least one of bis(3-hydroxypropyl) terephthalate and low molecular weight oligomers of 1,3-propanediol and terephthalic acid is disclosed. According to the process, preheated 1,3-propanediol (about 150° C. to about 200° C.) and preheated lower dialkyl esters of terephthalic acid (about 150° C. to about 220° C.) are combined in a mole ratio of about 1.2:1 to about 2.3:1 and fed to an ester exchange vessel where the mixture undergoes a continuous transesterification reaction. The liquid reaction mixture is continuously heated and mixed, at a temperature of about 215° C. to about 250° C., and a pressure of about 800 mm Hg to about 1,000 mm Hg. Gaseous reaction products are continuously separated from the liquid reaction mixture, and a stream of liquid reaction products containing bis(3-hydoxypropyl) terephthalate and low molecular weight oligomers of 1,3-propanediol and terephthalic acid is continuously removed from a base portion of the ester exchange vessel.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: October 4, 2005
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Carl J. Giardino, David B. Griffith, Chungfah Howard Ho, James M. Howell, Michelle Hoyt Watkins
  • Patent number: 6936733
    Abstract: The invention concerns a novel method for industrial preparation of disodium 2,2?-dithiobis(alkylsulphonates), and in particular disodium 2,2?-dithiobis(ethanesulphate) (dimesna). Said novel method is summarized by the reaction diagram (A). In diagram (A), Hal represents a halogen atom, and preferably a bromine atom; M represents a sodium or potassium atom; and n represents an integer ranging between 0 and 2.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: August 30, 2005
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventors: Jean-Bernard Cazaux, Eric Manginot, Marc Veyrat
  • Patent number: 6504049
    Abstract: A process for synthesizing pharmaceutically active disulfides, particularly Dimesna and certain derivatives thereof. The process includes reacting an alkylene salt with a sulfurating reagent, then alkalizing the intermediate and flowing oxygen through the mixture to produce the final compound in high yield.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: January 7, 2003
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventor: Harry Kochat
  • Patent number: 6160167
    Abstract: This invention relates to novel compositions of matter which either terminate in a sulfhydryl moiety or are disulfides. The compounds also include a terminal sulfonate or phosphonate moiety, and have many uses, such as toxicity reducing agents when administered with many antineoplastic agents.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: December 12, 2000
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventors: Frederick H. Hausheer, Kochat Haridas, Qiuli Huang
  • Patent number: 6133474
    Abstract: The present invention is directed to novel alkyl glyceryl ether disulfonate compositions (ADEDS), alkylphenol polyethoxy sulfate-sulfonates, and ethoxylated alkylphenol sulfonates, and novel methods of preparation and uses thereof.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: October 17, 2000
    Assignee: Witco Corporation
    Inventors: Khalid Rasheed, John Gray, Jeffrey J. Fulton
  • Patent number: 6121222
    Abstract: A novel class of anionic surfactants with improved surfact active properties is comprised of two hydrophilic and two hydrophobic groups represented by the formula: ##STR1## The surfactants exhibit unusually low critical micelle concentration (cmc) and pC-20 values in aqueous media.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: September 19, 2000
    Assignee: Rhodia Inc.
    Inventors: Ruoxin Li, David James Tracy, Jiang Yang, Manilal S. Dahanayake
  • Patent number: 5922902
    Abstract: A process for synthesizing disulfides and sulfhydryl compounds which are useful pharmaceuticals. The process includes a two step, single pot process for preparing disulfides from an alkenyl sulfonate salt. The disulfides are useful as toxicity mitigating agents of chemotherapeutic drugs, such as certain platinum complexes, and as use therapeutic drugs for a variety of conditions in mammals.The two step process involves first the conversion of the starting reagent to a mercaptane sulfonate, then an oxidation to the desired disulfide.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: July 13, 1999
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventor: Kochat Haridas
  • Patent number: 5919975
    Abstract: The present invention is directed to novel alkyl glyceryl ether disulfonate compositions (ADEDS), alkylphenol polyethoxy sulfate-sulfonates, and ethoxylated alkylphenol sulfonates, and novel methods of preparation and uses thereof.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: July 6, 1999
    Assignee: Witco Corporation
    Inventor: Khalid Rasheed
  • Patent number: 5808140
    Abstract: A process for synthesizing disulfides and sulfhydryl compounds which are useful pharmaceuticals. The process includes a two step, single pot process for preparing disulfides from an alkenyl sulfonate salt. The disulfides are useful as toxicity mitigating agents of chemotherapeutic drugs, such as certain platinum complexes, and as use therapeutic drugs for a variety of conditions in mammals.The two step process involves first the conversion of the starting reagent to a mercaptane sulfonate, then an oxidation to the desired disulfide.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: September 15, 1998
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventor: Kochat Haridas
  • Patent number: 5801270
    Abstract: The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, Y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, Y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: September 1, 1998
    Assignee: Kao Corporation
    Inventors: Mitsuru Uno, Tomohito Kitsuki, Katsumi Kita, Yoshiaki Fujikura, Akiko Okutsu
  • Patent number: 5298650
    Abstract: The present invention is a process for producing organic esters wherein a dialkyl ether and a carboxylic acid are reacted in the presence of a solid phase acidic catalyst having an acidity factor of at least 0.30, preferably at least 1, under reaction conditions sufficient to form a reaction mixture comprising the desired organic ester and an alcohol and recovering the organic ester. For example, methyl acetate can be prepared by reacting dimethyl ether and acetic acid in the presence of montmorillonite, amorphous silica-alumina or .kappa.-alumina under conditions sufficient to form methyl acetate. While typical processes produce an azeotropic mixture of the desired organic ester and water, the claimed process utilizes a combination or reactants and catalysts wherein water is not produced in appreciable amounts. Therefore, the organic ester product can be separated conveniently thereby avoiding a cumbersome azeotropic distillation step as required in prior art processes.
    Type: Grant
    Filed: April 15, 1992
    Date of Patent: March 29, 1994
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Francis J. Waller, William F. Burgoyne, Jr.
  • Patent number: 5138095
    Abstract: Bisulfite addition products, which exhibit surface active properties, prepared by reacting a ketone-terminated polyoxyalkylene compound, such as a diketone of a polyoxypropylene glycol, a monoketone of a polyoxyalkylene alcohol, etc. with an ammonium or alkali metal bisulfite are disclosed.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: August 11, 1992
    Assignee: Texaco Chemical Company
    Inventors: George P. Speranza, John R. Sanderson
  • Patent number: 4985591
    Abstract: Preparation of a semi-crystalline catalyst for curing coating compositions wherein an isocyanate-sulfonate or -phosphonate is made by a Michael addition followed by chain extension with an isocyanate.
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: January 15, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jozef T. Huybrechts, Werner Zimmt
  • Patent number: 4927961
    Abstract: Polyoxylalkylene ether with an average molecular weight of 400 to 10,000 with at least one terminal hydroxyl group and at least one lateral --SO.sub.3 X group (X=hydrogen, alkali metal or ammonium ion) is disclosed. The polyoxyalkylene ether is obtainable byThe statistical or blockwise addition reaction of (a) .alpha.-alkylene oxides with 2 to 14 carbon atoms or mixtures hereof and (b) allyl and/or methallyl glycidyl ethers to monohydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule,reacting the polymer by a known reaction with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO.sub.3 Y (Y=alkali or ammonium ion) andif necessary, exchanging the cation Y against a hydrogen ion also by a known procedure.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: May 22, 1990
    Assignee: Th. Goldschmidt AG
    Inventors: Jurgen Fock, Dietmar Schedlitzki