Sulfonate Group And Alkyl Group Of At Least Four Carbons Bonded Directly To The Same Benzene Ring Patents (Class 562/91)
  • Publication number: 20150140906
    Abstract: A cleaning agent for an alloy material is provided. The cleaning agent has a pH in a range between 1.5 and 4, inclusive, and contains an anionic surfactant having an SO3M group (where M represents a counter ion). It is preferable that the cleaning agent for an alloy material further contains an organic acid. A method for producing an alloy material is also provided. The method includes a step for cleaning the alloy material using the cleaning agent for an alloy material.
    Type: Application
    Filed: April 24, 2013
    Publication date: May 21, 2015
    Applicant: FUJIMI INCORPORATED
    Inventors: Hitoshi Morinaga, Maiko Asai, Yuuichi Ito
  • Publication number: 20150073176
    Abstract: A linear alkylbenzene product and a linear alkylbenzene sulfonate product from a natural oil are provided. The linear alkylbenzene product comprises alkylbenzenes having the formula C6H5CnH2n+1 wherein n is from 12 to 13; wherein the alkylbenzenes have at least 7 mass % modern carbon as measured by ASTM Method 6866; and wherein the alkyl group is a linear alkyl group for at least 80 mass % of the alkylbenzenes having the formula C6H5CnH2n+1 wherein n is from 12 to 13.
    Type: Application
    Filed: June 6, 2014
    Publication date: March 12, 2015
    Inventors: Stanley J. Frey, Daniel L. Ellig, Andrea G. Bozzano, Geoffrey W. Fichtl, Debarshi Majumder
  • Publication number: 20150072916
    Abstract: The production of linear alkylbenzene from a natural oil is provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
    Type: Application
    Filed: June 6, 2014
    Publication date: March 12, 2015
    Applicant: UOP LLC
    Inventors: Stanley J. Frey, Daniel L. Ellig, Andrea G. Bozzano, Geoffrey W. Fichtl, Debarshi Majumder
  • Patent number: 8962233
    Abstract: According to one embodiment, an actinic-ray- or radiation-sensitive resin composition includes an arylsulfonium salt that when exposed to actinic rays or radiation, generates an acid, the arylsulfonium salt containing at least one aryl ring on which there are a total of one or more electron donating groups, the acid generated upon exposure to actinic rays or radiation having a volume of 240 ?3 or greater.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: February 24, 2015
    Assignee: FUJIFILM Corporation
    Inventors: Takeshi Kawabata, Tomotaka Tsuchimura, Takayuki Ito
  • Patent number: 8936659
    Abstract: A substance includes diamond particles having a maximum linear dimension of less than about 1 ?m and an organic compound attached to surfaces of the diamond particles. The organic compound may include a surfactant or a polymer. A method of forming a substance includes exposing diamond particles to an organic compound, and exposing the diamond particles in the presence of the organic compound to ultrasonic energy. The diamond particles may have a maximum linear dimension of less than about 1 ?m. A composition includes a liquid, a plurality of diamond nanoparticles dispersed within the liquid, and an organic compound attached to surfaces of the diamond nanoparticles. A method includes mixing a plurality of diamond particles with a solution comprising a liquid solvent and an organic compound, and exposing the mixture including the plurality of diamond nanoparticles and the solution to ultrasonic energy.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: January 20, 2015
    Assignee: Baker Hughes Incorporated
    Inventors: Soma Chakraborty, Gaurav Agrawal, Anthony A. DiGiovanni
  • Publication number: 20140274857
    Abstract: The present invention relates to the field of membrane separation processes and clean in place compositions for cleaning such membranes. The cleaning compositions can remove proteins, fats, and other food, beverage, and brewery based soils and offer an environmentally friendly alternative surfactant system to NPE. According to the invention, surfactants and polymers useful for this process are unpredictable and specific surfactants, polymers, and combinations of the same are disclosed for use alone, as part of a cleaning composition. Methods of use of the same are also included.
    Type: Application
    Filed: March 12, 2013
    Publication date: September 18, 2014
    Applicant: ECOLAB USA INC.
    Inventors: Paul Schacht, Jeffrey Weilage, Eric Schmidt, Joseph P. Curran, Ralf Krack, Victor Fuk-Pong Man, Charles Allen Hodge
  • Publication number: 20140148372
    Abstract: Acidic viscoelastic cleaning compositions are disclosed which use non polymer thickening agents. According to the invention, cleaning compositions have been developed using viscoelastic surfactants in acidic cleaning formulations. These provide the dual benefit of thickening as well as an additional cleaning, thereby improving performance. Applicants have also identified several pseudo linking agents which when, used with viscoelastic surfactants provide enhanced viscoelasticity and cleaning.
    Type: Application
    Filed: November 28, 2012
    Publication date: May 29, 2014
    Applicant: ECOLAB USA INC.
    Inventors: Victor Fuk-Pong Man, Michael Charles Denoma, Yvonne Marie Killeen, Susan Maloney Viall
  • Publication number: 20140148371
    Abstract: Alkaline or neutral viscoelastic cleaning compositions are disclosed which use non polymer thickening agents. According to the invention, cleaning compositions have been developed using viscoelastic surfactants in a neutral, acidic or alkaline cleaning formulations. These provide the dual benefit of thickening as well as an additional cleaning, thereby improving performance. Applicants have also identified several pseudo linking agents which when, used with viscoelastic surfactants provide viscoelasticity in alkaline cleaning compositions.
    Type: Application
    Filed: November 28, 2012
    Publication date: May 29, 2014
    Applicant: ECOLAB USA INC.
    Inventors: Victor Fuk-Pong Man, Michael Charles DeNoma, Yvonne Marie Killeen, Susan Maloney Viall
  • Publication number: 20130078198
    Abstract: This invention relates to the use of sodium dodecylbenzene sulphonate (SDDBS) for helping to prevent or remove surface deposited stains from natural teeth and dental prostheses and oral care compositions comprising SDDBS for such use.
    Type: Application
    Filed: March 22, 2011
    Publication date: March 28, 2013
    Applicant: GLAXO GROUP LIMITED
    Inventors: Gail Cameron Aitken, David Raymond Churchley
  • Publication number: 20120213726
    Abstract: The invention is directed to mixtures comprising C10-C14 linear alkylphenyl sulfonates with alkyl groups having a biobased content of at least 50%. These C10-C14 linear alkylphenyl sulfonates are used in consumer product cleaning and personal care compositions (e.g., dishcare, laundry, hard surface cleaners, shampoos, conditioners, and soaps). The invention is further directed to a method of making a mixture of partially or wholly bio-based C10-C14 linear alkylphenyl sulfonates with alkyl groups having a particular bio-based content.
    Type: Application
    Filed: February 17, 2012
    Publication date: August 23, 2012
    Inventors: Phillip Richard Green, Jeffrey John Scheibel, Dimitris Ioannis Collias
  • Publication number: 20120034464
    Abstract: A substance includes diamond particles having a maximum linear dimension of less than about 1 ?m and an organic compound attached to surfaces of the diamond particles. The organic compound may include a surfactant or a polymer. A method of forming a substance includes exposing diamond particles to an organic compound, and exposing the diamond particles in the presence of the organic compound to ultrasonic energy. The diamond particles may have a maximum linear dimension of less than about 1 ?m. A composition includes a liquid, a plurality of diamond nanoparticles dispersed within the liquid, and an organic compound attached to surfaces of the diamond nanoparticles. A method includes mixing a plurality of diamond particles with a solution comprising a liquid solvent and an organic compound, and exposing the mixture including the plurality of diamond nanoparticles and the solution to ultrasonic energy.
    Type: Application
    Filed: October 18, 2011
    Publication date: February 9, 2012
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Soma Chakraborty, Gaurav Agrawal, Anthony A. DiGiovanni
  • Publication number: 20110189609
    Abstract: According to one embodiment, an actinic-ray- or radiation-sensitive resin composition includes an arylsulfonium salt that when exposed to actinic rays or radiation, generates an acid, the arylsulfonium salt containing at least one aryl ring on which there are a total of one or more electron donating groups, the acid generated upon exposure to actinic rays or radiation having a volume of 240 ?3 or greater.
    Type: Application
    Filed: January 28, 2011
    Publication date: August 4, 2011
    Applicant: FUJIFILM Corporation
    Inventors: Takeshi Kawabata, Tomotaka Tsuchimura, Takayuki Ito
  • Patent number: 7704376
    Abstract: The use of water-soluble aromatic polysulfonic acid salts for inhibiting fouling in process equipment used in the thermal treatment of heavy oils.
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: April 27, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ramesh Varadaraj, Michael Siskin, Leo D. Brown, Maa S. Maa
  • Patent number: 7598414
    Abstract: A process for preparing a synthetic petroleum sulfonate comprising (a) reacting a first amount of at least one aromatic compound with a first amount of a mixture of olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst; (b) reacting the product of (a) with an additional amount of at least one aromatic compound and an additional amount of strong acid catalyst and, optionally, with an additional amount of a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst, wherein the resulting product comprises at least about 80 weight percent of a 1,2,4-trialkylsubstituted aromatic compound; (c) sulfonating the product of (b); and (c) neutralizing the product of (b) with an alkali or alkaline earth metal hydroxide or ammonia.
    Type: Grant
    Filed: June 1, 2006
    Date of Patent: October 6, 2009
    Assignee: Chevron Oronite Company LLC
    Inventors: Curt B. Campbell, Gilles Sinquin
  • Patent number: 7594989
    Abstract: A method for upgrading heavy oils by contacting the heavy oil with a water-soluble aromatic polysulfonic acid salt and then thermally treating the contacted heavy oil. The polysulfonic acid salt can be recovered and recycled from contacting the heavy oil. The polysulfonic acid salt is recovered and recycled. The invention also relates to the upgraded product from the enhanced thermal treatment process.
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: September 29, 2009
    Assignee: ExxonMobile Research and Engineering Company
    Inventors: Ramesh Varadaraj, Leo D. Brown
  • Patent number: 7468343
    Abstract: The present invention is directed to a method for enhancing the recovery of oil from a subterranean reservoir which method employs an alkylxylene sulfonate that contains a high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and a high percentage of alkyl group attachment to the xylene ring at positions higher than the 2-position on the alkyl carbon chain in an aqueous media, since it has surprisingly been discovered that the high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and the high percentage alkyl group attachment to the xylene moiety at positions higher than the 2-position along the alkyl carbon chain on the alkylxylene sulfonate provides an enhanced oil recovery surfactant having low Interfacial Tension. The method optionally employs co-surfactants.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: December 23, 2008
    Assignee: Chevron Oronite Company LLC
    Inventors: Curt B. Campbell, Gilles P. Sinquin
  • Patent number: 7332460
    Abstract: The present invention is directed to alkylxylene sulfonate for enhanced oil recovery processes. The alkylxylene moiety in the alkylxylene sulfonate contains a high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and a high percentage of alkyl group attachment to the xylene ring at positions higher than the 2-position on the alkyl carbon chain. The present invention is also directed to a method for enhancing the recovery of oil from a subterranean reservoir which method employs the alkylxylene sulfonate of the present invention. The alkylxylene sulfonate is employed in an aqueous media. The method optionally employs co-surfactants.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: February 19, 2008
    Assignee: Chevron Oronite Company LLC
    Inventors: Curt B. Campbell, Gilles P. Sinquin
  • Publication number: 20070287088
    Abstract: A Brønsted acid is a compound represented by formula (I): wherein n represents an integer of from 1 to 4, RHL('s) each independently represents Cl or F, and R1 represents an alkyl group having from 8 to 20 carbon atoms.
    Type: Application
    Filed: November 14, 2006
    Publication date: December 13, 2007
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Yuki Sasaki, Hirotaka Matsuoka, Satoshi Hiraoka, Fumiaki Mera, Yasuo Matsumura
  • Publication number: 20070282125
    Abstract: A process for preparing a synthetic petroleum sulfonate comprising (a) reacting a first amount of at least one aromatic compound with a first amount of a mixture of olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst; (b) reacting the product of (a) with an additional amount of at least one aromatic compound and an additional amount of strong acid catalyst and, optionally, with an additional amount of a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst, wherein the resulting product comprises at least about 80 weight percent of a 1,2,4-trialkylsubstituted aromatic compound; (c) sulfonating the product of (b); and (c) neutralizing the product of (b) with an alkali or alkaline earth metal hydroxide or ammonia.
    Type: Application
    Filed: June 1, 2006
    Publication date: December 6, 2007
    Inventors: Curt B. Campbell, Gilles Sinquin
  • Patent number: 7094924
    Abstract: Disclosed is a method for decreasing the surface defects of a patterned photoresist layer on a substrate surface obtained by the procedure comprising the steps of (a) forming a photoresist layer of a positive-working chemical-amplification photoresist composition on the substrate surface, (b) patternwise exposing the photoresist layer to actinic rays, (c) subjecting the patternwise-exposed photoresist layer to a post-exposure baking treatment and (d) a development treatment. The improvement can be accomplished by bringing the photoresist layer after the post-exposure baking treatment into contact with an aqueous acidic solution having a pH of 3.5 or lower for 1 to 90 seconds. The acid contained in the aqueous acidic solution is preferably an aromatic sulfonic acid or, more preferably, a diphenyl ether sulfonic acid such as dodecyl(diphenyl ether) disulfonic acids.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: August 22, 2006
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Kazuyuki Nitta, Taku Nakao, Satoshi Maemori, Tatsuya Matsumi
  • Patent number: 7060852
    Abstract: The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C10-12-olefins, and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: June 13, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Heiko Maas, Thomas Narbeshuber, Michael Roeper
  • Patent number: 6989355
    Abstract: The present invention is directed to an under-neutralized alkylxylene sulfonic acid composition for enhanced oil recovery processes. The present invention is also directed to a method for enhancing the recovery of oil from a subterranean reservoir which method employs the under-neutralized alkylxylene sulfonic acid compositions of the present invention. The under-neutralized alkylxylene sulfonic acid compositions are employed in an aqueous media. The method optionally employs suitable co-surfactants, such as alcohols, alcohol ethers, polyalkylene glycols, poly(oxyalkylene)glycols and/or poly(oxyalkylene)glycol ethers.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: January 24, 2006
    Assignee: Chevron Oronite Company LLC
    Inventors: Curt B. Campbell, Gilles P. Sinquin
  • Patent number: 6673961
    Abstract: Processes for making particularly branched, especially monomethyl-branched or nongeminal dimethyl-branched surfactants used in cleaning products; preferred processes comprising particular combinations of two or more adsorptive separation steps and, more preferably, particular alkylation steps; products of such processes, including certain modified alkylbenzenes, modified alkylbenzenesulfonate surfactants, and consumer cleaning products, especially laundry detergents, containing them. Preferred processes herein more specifically use specific, unconventional sequences of sorptive separation steps to secure certain branched hydrocarbon fractions which are used in further process steps as alkylating agents for arenes or for other useful surfactant-making purposes. Surprisingly, such fractions can even be derived from effluents from current linear alkylbenzene manufacture.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: January 6, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Daniel Stedman Connor, Jeffrey John Scheibel, James Charles Theophile Roger Burckett-St. Laurent, Thomas Anthony Cripe, Kevin Lee Kott, Phillip Kyle Vinson
  • Patent number: 6521785
    Abstract: The present invention relates to surfactants useful in life science and industrial formulations. More particularly, the invention relates to surfactants of alkoxylated amine neutralized by aromatic sulfonic acid and pesticide formulations containing the same.
    Type: Grant
    Filed: February 5, 2001
    Date of Patent: February 18, 2003
    Assignee: Syngenta Participations AG
    Inventors: Tammy Tyler Shannon, Carolyn Estep Moore, Victor Shui-Chiu Chow
  • Patent number: 6515169
    Abstract: The present invention is a process for producing aryl-alkanes by paraffin isomerization followed by paraffin dehydrogenation and then by alkylation of an aryl compound by a lightly branched olefin. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: February 4, 2003
    Assignee: UOP LLC
    Inventors: Richard E. Marinangeli, R. Joe Lawson, Leonid B. Galperin, Thomas R. Fritsch
  • Patent number: 6048904
    Abstract: The present invention is an asphaltene dispersant containing an aromatic, a sulfonic acid head, and an alkyl tail containing 16 carbons or more and at least one branch of a methyl or longer alkyl. Preferably, the aromatic is a fused two ring aromatic and the tail is a two, branched alkyl tail of 30 carbons or longer.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: April 11, 2000
    Assignee: Exxon Research and Engineering Co.
    Inventors: Irwin A. Wiehe, Ramesh Varadaraj, Torris G. Jermansen, Raymond J. Kennedy, Cornelius H. Brons
  • Patent number: 6046355
    Abstract: This invention pertains to improved antiviral activity of 6,6-disubstituted-5,6-dihydropyran-2-ones caused by judicious placement of certain polar substituents at the 3 and/or 6 positions.The same substituents which enhance the cellular activity also diminish cytotoxicity further enhancing the desirable properties of these agents as antivirals.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: April 4, 2000
    Assignee: Warner-Lambert Company
    Inventors: Frederick Earl Boyer, Jr., John Michael Domagala, Edmund Lee Ellsworth, Christopher Andrew Gajda, Susan Elizabeth Hagen, Harriet Wall Hamilton, Elizabeth Ann Lunney, Larry James Markoski, Josyula Venkata Nagendra Vara Prasad, Bradley Dean Tait
  • Patent number: 5596128
    Abstract: A sulfonating agent represented by the general formula ##STR1## wherein the groups R.sup.1 are the same or different and are each a lower alkyl group having 1 to 3 carbon atoms, n is an integer of 3, 4 or 5, m is an integer of 1 or 2, and n+m.ltoreq.6, and a process for sulfonating an aromatic compound with use of the sulfonating agent.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: January 21, 1997
    Assignee: Konishi Chemical Ind. Co., Ltd.
    Inventors: Eiji Ogata, Norio Yanase, Takayuki Kitahara
  • Patent number: 5468407
    Abstract: A composition comprising a mixture of dialkylbenzene monosulfonic acids or salts thereof containing greater than about 60 weight percent of the para dialkylbenzene isomer and greater than about 80 weight percent of the combined di(2-alkyl)benzene and di(3-alkyl)benzene isomers. The composition exhibits improved properties as a mineral collector in ore flotation.
    Type: Grant
    Filed: November 3, 1994
    Date of Patent: November 21, 1995
    Assignee: The Dow Chemical Company
    Inventors: Kevin A. Frazier, Juan M. Garces, Guo-shuh J. Lee
  • Patent number: 5434301
    Abstract: A process for recovering sulfuric acid from a mixture containing sulfuric acid and organic sulfonation products is provided. The process comprises contacting a mixture comprised of sulfuric acid and (i) a naphthalene-based material selected from the group consisting of naphthalenesulfonic acids, lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials, or (ii) an aromatic-based carbonyl condensate (preferably a material selected from the group consisting of formaldehyde condensates of naphthalenesulfonic acids, formaldehyde condensates of lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials), with a basic anion exchange resin in essentially the sulfate form (and preferably in the form of essentially non-porous particles) to provide a raffinate liquid phase enriched with respect to said mixture in said naphthalene-based material and depleted with respect to said mixture in sulfuric acid.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: July 18, 1995
    Assignee: Henkel Corporation
    Inventor: William G. Kozak
  • Patent number: 5368776
    Abstract: A method for improving the corrosion inhibition of lubricating oils especially those of vegetable origin which comprises adding an efficient amount of the reaction product of an epoxidized fatty acid ester, especially an epoxidized methyl ester of an unsaturated fatty acid and a sulphonic acid and a process for producing these reaction products.
    Type: Grant
    Filed: October 20, 1993
    Date of Patent: November 29, 1994
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Volker Schafer, Robert Kohler, Alfred Pauli, Achim Fessenbecker
  • Patent number: 5344997
    Abstract: A fluorided silica-alumina catalyst, particularly one with a silica:alumina ratio in the range of 1:1-9:1 containing from 1 to 6 weight percent fluoride, is particularly effective in the liquid phase alkylation of benzene by linear olefins to produce linear alkyl benzenes at temperatures no greater than 140.degree. C. These catalysts also are effective in the liquid phase alkylation of alkylatable aromatics generally with a variety of alkylating agents, including olefins, alcohols, and alkyl halides.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: September 6, 1994
    Assignee: UOP
    Inventor: Joseph A. Kocal
  • Patent number: 5344967
    Abstract: The present invention describes treating an organic sulfonic acid with an olefin to obtain an improvement in color of the resultant salts and to lessen the amount of inactive components in the composition.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: September 6, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Eric R. Schnur, David L. Westfall
  • Patent number: 5302732
    Abstract: Silica-aluminas having a sodium content less than about 0.1 weight percent show increased stability when used as a catalyst for the alkylation of aromatic compounds. Where such silica-aluminas are used as the catalyst in detergent alkylation their increased stability permits continuous alkylation to be performed at lower temperatures, as a result of which the detergent alkylate product shows an incrementally higher linearity. Fluorided silica-aluminas having a sodium content of under 0.05 weight percent are particularly advantageous.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: April 12, 1994
    Assignee: UOP
    Inventors: Karl Z. Steigleder, Christine M. Conway, David M. Baldwin, Diane C. Dierking
  • Patent number: 5154754
    Abstract: Oil-in-water emulsions (microemulsions) containing 0.01-80% by weight of at least one agrochemical active substance of low water-solubility, one active substance for combating pests in the domestic and hygiene sector and/or one pharmacologically active substance, 1% to 30% by weight of an emulsifier mixture of non, ionic and anionic compounds and at least one alkylarylsulfonic acid salt, as defined in the description, as well as water and, if appropriate, 1% to 30% by weight of at least one solvent of low water-miscibility and/or one solubilizer, and if appropriate 0.05% to 15% by weight of additives, the sum of the components in each case being 100% by weight, a process for the preparation of these aqueous microemulsions and their use.
    Type: Grant
    Filed: May 2, 1990
    Date of Patent: October 13, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Zoltan Damo, Gerhard Frisch, Hans Rochling, Heinz-Josef Niessen, Wolfgang Wirth
  • Patent number: 5105006
    Abstract: The invention is a novel phosphonium salt, useful as an initiator or catalyst in the reaction of oxirane groups in an epoxy resin with aromatic carbonate and/or ester linkages in monomeric, oligomeric, or polymeric carbonates, esters, or estercarbonates.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: April 14, 1992
    Assignee: The Dow Chemical Company
    Inventor: Theodore L. Parker
  • Patent number: 5045632
    Abstract: The invention is a novel bis(phosphoranylidene) ammonium salt useful as an initiator/catalyst in the reaction of oxirane groups in an epoxy resin with aromatic carbonate and/or ester linkages in monomeric, oligomeric, or polymeric carbonates, esters, or estercarbonates.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: September 3, 1991
    Assignee: The Dow Chemical Company
    Inventor: Theodore L. Parker
  • Patent number: 4873025
    Abstract: Compositions comprising alkylxylene sulfonate compounds of the formula ##STR1## wherein R' represents a C.sub.6 to C.sub.20 alkyl group and wherein M represents a hydrogen, a metal, an ammonium or an amine ion, are useful as surfactants, particularly in enhanced oil recovery techniques.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: October 10, 1989
    Assignee: Shell Oil Company
    Inventor: Theodorus A. B. M. Bolsman