Polyoxyalkylene Patents (Class 564/294)
  • Patent number: 9236159
    Abstract: Provided is a polyether rubber that contains a specific proportion of a specific unit containing an onium ion. According to the present invention, a conductive member and a cross-linked rubber that constitutes part of the conductive member can be provided, in which the conductive member has low electrical resistance value and little variation in electrical resistance, and suppressed increases in the electrical resistance value even if used continuously.
    Type: Grant
    Filed: December 27, 2010
    Date of Patent: January 12, 2016
    Assignee: ZEON CORPORATION
    Inventors: Hiroyuki Yonemaru, Shigetaka Hayano
  • Patent number: 9012365
    Abstract: The present invention generally relates to a method for minimizing the formation of insoluble salts of phenoxy herbicides. The method comprises (1) mixing a compatibility agent, amine salts of phenoxy acid herbicides, and a chemical containing non-amine cations in a aqueous system to form a stable and non-nozzle plugging solution; and (2) application of said stable and non-nozzle plugging solution onto target plants.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: April 21, 2015
    Assignee: Akzo Nobel N.V.
    Inventors: Jinxia Susan Sun, Shawn Zhu, Shuaib A. Khan
  • Publication number: 20150104401
    Abstract: Provided are polyglyceryl compositions comprising one or more polyglyceryl compounds having: (a) a node structure comprising at least three contiguous glyceryl remnant units; (b) one or more cationic groups each linked to the node structure by an independently selected linking group; and (c) one or more hydrophobic moieties each independently (i) linked to the node structure by a linking group, or (ii) constituting a portion of one of the one or more cationic groups, wherein the composition has an average degree of polymerization determined by hydroxyl value testing (DPOH) of from about 3 to about 20. Also provided are polyglyceryl compounds which may compose such compositions, and uses of the polyglyceryl compositions and compounds.
    Type: Application
    Filed: December 18, 2014
    Publication date: April 16, 2015
    Inventors: Michael J. Fevola, Frank C. Sun, Stacey E. York
  • Publication number: 20140084206
    Abstract: There is provided, in one form, a method for at least partially deactivating a sulfur species from a stream, such as but not limited to a hydrocarbon stream, an aqueous stream, and mixtures thereof. A treating mixture may be introduced into the stream in an amount effective to at least partially deactivate the sulfur species from the stream. The treating mixture may include a compound having the general formula: and combinations thereof. R1 may be a C1-C4 hydrocarbyl group. R2 may be a C1-C4 hydrocarbyl group that is the same or different as R1. R3 may be an ethanol or an isopropanol moiety. R4 may be an ethylene oxide moiety, propylene oxide moiety, butylene oxide moiety, and combinations thereof. n may be an integer from 1 to 100. M may be a hydrogen or a metal ion.
    Type: Application
    Filed: September 27, 2012
    Publication date: March 27, 2014
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Jianzhong Yang, James Michael Brown
  • Patent number: 8618179
    Abstract: The present invention relates to a composition comprising a pesticide and an alkoxylate. Moreover, the invention relates to the alkoxylate, to a process for its preparation and to its use as adjuvant in pesticide-comprising spray mixtures. The invention furthermore relates to a method of controlling phytopathogenic fungi and/or undesired vegetation and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the plants to be protected from the respective pest, on the soil and/or on undesirable plants and/or the crop plants and/or their environment. Furthermore, the invention relates to seed comprising the composition.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: December 31, 2013
    Assignee: BASF SE
    Inventors: Paul Klingelhoefer, Arend Jouke Kingma, Sophie Vogel, Kevin Huyghe, Gerd Haderlein, Gerhard Schnabel, Marc Nolte, Richard Roger Evans
  • Publication number: 20130003259
    Abstract: To provide an electrolyte solution, which contains an electrolyte compound, a molecular structure of which contains a molecular chain containing a repeating unit of alkylene oxide, and contains quaternary ammonium cations at both terminals of the molecular chain.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 3, 2013
    Applicant: FUJITSU LIMITED
    Inventors: Masaaki SASA, Tamotsu YAMAMOTO, Tsutomu TANAKA, Kensuke YOSHIDA
  • Publication number: 20120295983
    Abstract: Stabilized cationic ammonium compounds are described. The compounds are stabilized with metal chelators that impede the generation of nitrogen comprising groups from the cationic ammonium compounds.
    Type: Application
    Filed: July 31, 2012
    Publication date: November 22, 2012
    Applicant: Conopco, Inc., d/b/a Unilever
    Inventors: Van Au, Stephen Alan Madison, Katherine Mary Thompson
  • Patent number: 8283496
    Abstract: Aminoalkyl vinyl ethers comprising alkylenimine units and of the formula H2C?CH—O—X—NH—[Al—]n—H??(I), in which [Al—]n is a linear or branched oligoalkylenimine chain having n alkylenimine units, n is a number of at least 1 and X is a straight-chain or branched C2- to C6-alkylene group, and salts of the monomers I with mineral acids or organic acids and quaternization products of the monomers I with alkyl halides or dialkyl sulfates, processes for the preparation of the compounds of the formula I by addition reaction of alkylenimines with amino-C2- to C6-alkyl vinyl ethers and use of the aminoalkyl vinyl ethers comprising alkylenimine units and of the formula I as monomers for the preparation of polymers for use in the paper industry, as antimicrobial coating materials, in detergents and for the treatment of metal surfaces.
    Type: Grant
    Filed: October 1, 2008
    Date of Patent: October 9, 2012
    Assignee: BASF SE
    Inventors: Robert Feuerhake, Daniel Schoenfelder, Hans-Joachim Haehnle, Bernd Bruchmann, Paola Uribe Arocha, Alexander Kraus, Christian Huebsch, Bastiaan Bram Pieter Staal, Ralph Baumgaertner
  • Patent number: 8273920
    Abstract: The surfactants of this invention are quaternary ammonium compounds based upon 2,4,7,9-tetramethyl-5-decyne-4,7-diol. These surfactants, not only decrease the surface tension of aqueous systems, but by virtue of the cationic nitrogen containing moiety have outstanding substantivity for hair, skin and textile fibers, lacking in the parent non-ionic.
    Type: Grant
    Filed: September 3, 2010
    Date of Patent: September 25, 2012
    Assignee: SurfaTech Corporation
    Inventors: Kevin O'Lenick, Anthony J. O'Lenick, Jr.
  • Publication number: 20120238717
    Abstract: A composition is provided that contains an intermediate for a water-soluble monomer, wherein this intermediate is suitable for producing a water-soluble polyalkylene glycol-type monomer that has a polymerizable terminal double bond, and suitable for the production of water-soluble polymer, and moreover allows the high-yield production of water-soluble polymer. A process of producing this composition and a water-soluble monomer-containing composition obtained therefrom are also provided. A water-soluble monomer is also provided that can be used as a starting material for a water-soluble polymer that even at high hardnesses exhibits an excellent capacity to capture metal ions such as the calcium ion and magnesium ion, an excellent anti-gelation performance, an excellent anti-soil redeposition performance, a better anti-dye transfer performance than in the past, and also an excellent compatibility with surfactants.
    Type: Application
    Filed: December 3, 2010
    Publication date: September 20, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Atsuro Yoneda, Makoto Saito, Aki Tsukajima, Daisuke Michitaka, Mitsuaki Makino
  • Publication number: 20120208736
    Abstract: Hard surfaces can be treated to improve soil resistance, particularly resistance to oily soils, by applying a composition of a quaternised, polyamine, polypropoxylate, polyethoxylate. The polyamine can be a polyethyleneimme, desirably having a molecular weight of from 10 to 50 kDa. The average length of the polypropylenoxy chains is desirably from 10 to 100 and the polyethylenoxy chains from 5 to 50 (each per NH group in the polyamine), particularly at a molar ratio of PO:EO of about 3:1. The degree of quaternisation of the nitrogen atoms in the polyamine is desirably from 70 to 100%. The polymer will usually be used in solution in water or an aqueous formulation, which may include detergent and other detergent formulation components.
    Type: Application
    Filed: October 4, 2010
    Publication date: August 16, 2012
    Applicant: Croda International PLC
    Inventors: Alan Geoffrey Waite, Trevor Graham Blease, Sean Robins
  • Patent number: 8076434
    Abstract: The present invention has an object to provide an amphoteric polymer having high anti-soil redeposition ability and solubility with surfactants, and a process for producing the same. The amphoteric polymer includes: a structure unit (a) derived from a cationic group-containing monomer (A); and a structure unit (b) derived from a carboxyl group-containing monomer (B). The structure unit (a) is present at a level of 1 to 99% by mass based on 100% by mass of all structure units derived from all monomers in the amphoteric polymer, and the structure unit (b) is present at a level of 1 to 99% by mass based on 100% by mass of all the structure units derived from all the monomers in the amphoteric polymer.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: December 13, 2011
    Assignee: Nippon Shokubai Co., Ltd
    Inventors: Atsuro Yoneda, Daisuke Michitaka
  • Patent number: 8034977
    Abstract: Cationic lipid compositions are provided that are useful for efficient delivery of macromolecules, such as nucleic acids, into a wide variety of eukaryotic cell types. Methods for using the compositions also are provided.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: October 11, 2011
    Assignee: Molecular Transfer, Inc.
    Inventors: Gulilat Gebeyehu, Taysir M. Jaouni, Joel Jessee
  • Patent number: 7939683
    Abstract: Phospholipid-analogous compounds of the general formula (I) in which A is where R1 and R2 are, independently of one another, hydrogen, a saturated or unsaturated acyl or alkyl radical which can optionally be branched or/and substituted, where the total of the carbon atoms in the acyl and alkyl is 16 to 44 carbon atoms, s is an integer from 0 to 8, c is a radical of a primary or secondary alcohol of the formula RO—, where R is a saturated or unsaturated alkyl radical, mainly with cis double bond, of from 12 to 30 carbon atoms, n is an integer from 2 to 8, R3— a can be 1,2-dihydroxypropyl or b can be alkyl with 1 to 3 carbon atoms when z is >0 or c can be alkyl with 1 to 3 carbon atoms when n?2, and z=0, m is 1 or 2, x is an integer from 0 to 8, y is 1 for z=1 to 5 or is 1 to 4 for z=1, z is an integer from 0 to 5, are novel and are suitable as liposome constituents, solubilizers and pharmaceuticals.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: May 10, 2011
    Assignee: Max-Planck-Gesellschaft zur Forderung der Wissenschaften e.V.
    Inventor: Hans-Jörg Eibl
  • Publication number: 20100183705
    Abstract: Phospholipid-analogous compounds of the general formula (I) in which A where R1 and R2 are, independently of one another, hydrogen, a saturated or unsaturated acyl or alkyl radical which can optionally be branched or/and substituted, where the total of the carbon atoms in the acyl and alkyl is 16 to 44 C atoms, s is an integer from 0 to 8, c is a radical of a primary or secondary alcohol of the formula RO—, where R is a saturated or unsaturated alkyl radical, mainly with cis double bond, of from 12 to 30 carbon atoms, n is an integer from 2 to 8, R3 a can be 1,2-dihydroxypropyl or b can be alkyl with 1 to 3 C atoms when z is >0 or c can be alkyl with 1 to 3 carbon atoms when n?2 and z=0, m is 1 or 2, x is an integer from 0 to 8, y is 1 for z=1 to S? or is 1 to 4 for z=1 z is an integer from 0 to 5, are novel and are suitable as liposome constituents, solubilizers and pharmaceuticals.
    Type: Application
    Filed: September 28, 2009
    Publication date: July 22, 2010
    Applicant: Max-Planck-Gesellschaft zur Förderung du Wissenschaften e.V.
    Inventor: Hans-Jörg EIBL
  • Patent number: 7678941
    Abstract: The present invention provides polyoxyalkylene ammonium imide or methide salts and their use as antistatic agents. Another embodiment provides articles comprising these salts, and processes for making and using these salts.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: March 16, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Patricia M. Savu, William M. Lamanna, Thomas P. Klun
  • Patent number: 7601872
    Abstract: Disclosed are compounds capable of facilitating transport of biologically active agents or substances into cells having the general structure: wherein Q is selected from the group consisting of N, O and S; L is any bivalent organic radical capable of linking each Q, such as C, CH, (CH2)l, or {(CH2)i-Y—(CH2)j}k, wherein Y is selected from the group consisting of CH2, an ether, a polyether, an amide, a polyamide, an ester, a sulfide, a urea, a thiourea, a guanidyl, a carbamoyl, a carbonate, a phosphate, a sulfate, a sulfoxide, an imine, a carbonyl, and a secondary amino group and wherein Y is optionally substituted by —X1-L?-X2-Z or -Z; R1-R6, independently of one another, are selected from the group consisting of H, —(CH2)p-D-Z, an alkyl, an alkenyl, an aryl, and an alkyl or alkyl ether optionally substituted by one or more of an alcohol, an aminoalcohol, an amine, an amide, an ether, a polyether, a polyamide, an ester, a mercaptan, an alkylthio, a urea, a thiourea, a guanidyl, or a carbamoyl group, and w
    Type: Grant
    Filed: January 21, 2005
    Date of Patent: October 13, 2009
    Assignee: Life Technologies Corporation
    Inventors: Yongliang Chu, Malek Masoud, Gulilat Gebeyehu
  • Patent number: 7598421
    Abstract: The invention provides a lipid of general formula (I) or (II): wherein X1, X2 and R1 to R5 are as defined herein. Such lipids are used to form complexes with a biologically-active material such as a nucleic acid, peptide or small molecule for delivering the biologically-active material to cells. The complexes may incorporate an integrin-binding peptide and, when the biologically-active material is DNA, thereby constitute a LID complex.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: October 6, 2009
    Assignee: UCL Biomedica PLC
    Inventors: Helen C. Hailes, Alethea B. Tabor, John B. Wong, Michael Pilkington-Miksa, Stephen L. Hart, Christopher A. Hurley
  • Publication number: 20090191227
    Abstract: The disclosure provides adjuvants, immunogenic compositions, and methods useful for vaccination and immune response. In particular, the disclosure provides a class of adjuvants comprising cationic lipid:co-lipid mixtures and methods for delivering formulated compositions.
    Type: Application
    Filed: May 23, 2008
    Publication date: July 30, 2009
    Applicant: Vical Incorporated
    Inventors: Jukka Hartikka, Sean M. Sullivan, Joel D. Enas, Alain Rolland
  • Patent number: 7531693
    Abstract: Cationic lipid compositions are provided that are useful for efficient delivery of macromolecules, such as nucleic acids, into a wide variety of eukaryotic cell types. Methods for using the compositions also are provided.
    Type: Grant
    Filed: May 24, 2004
    Date of Patent: May 12, 2009
    Assignee: Molecular Transfer, Inc.
    Inventors: Gulilat Gebeyehu, Taysir M. Jaouni, Joel Jessee
  • Patent number: 7501542
    Abstract: The present invention discloses highly packed polycationic ammonium, sulfonium and phosphonium lipid compounds useful for making lipid aggregates for delivery of macromolecules and other compounds into cells. They are especially useful for the DNA-dependent transformation of cells. Methods for their preparation and use as intracellular delivery agents are also disclosed.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: March 10, 2009
    Assignee: Invitrogen Corporation
    Inventors: Alberto Haces, Valentina C. Ciccarone
  • Patent number: 7411092
    Abstract: A quatemary ammonium salt of the following formula (1): {(R1)a(R2)b(R3)c(R4OCH2CH2OCH2CH2)dN}+.A???(1) [wherein, R1, R2 and R3 may be mutually the same or different and represent an alkyl group having 1 to 4 carbon atoms or analkyloxyethyl group of the formula (2): R5OCH2CH2—??(2) (wherein, R5 represents a methyl group or ethyl group), R4 represents a methyl group or ethyl group, and any two of R1, R2 and R3 may mutually bond at the end to form an alkylene chain, a, b and c represent an integer of 0 to 3, d represents an integer of 1 to 4, the sum of a, b and c is 3 or less, the sum of a, b, c and d is 4, and A? represents a bis(trifluoromethylsulfonyl)imidate ion [N(SO2CF3)2?], tetrafluoroborate ion (BF4?) or hexafluorophosphate ion (PF6?)].
    Type: Grant
    Filed: February 6, 2004
    Date of Patent: August 12, 2008
    Assignee: Koei Chemical Company, Limited
    Inventors: Nobuaki Honma, Yoshimi Yamada
  • Patent number: 7238230
    Abstract: Asphalt-based coating compositions and surfactants. The asphalt-based coating compositions have improved performance and comprise asphalt, clay, and a propoxylated alcohol-based ether amine salt surfactant.
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: July 3, 2007
    Assignee: Tomah Products, Inc.
    Inventors: David Kelly Moss, James A. Krogh
  • Patent number: 7226501
    Abstract: The present invention relates to an aqueous quick-setting bitumen-aggregate mix suitable for cold pavement of roads, parking places, sidewalks and the like. The bitumen-aggregate mix is manufactured by mixing a mineral aggregate, water, a de-emulsifier, containing hydraulic cement, and a cationic oil-in-water bitumen emulsion, containing, as an emulsifier, a salt of a tertiary diamine and a phosphoric acid. The diamine has the formula (I), where one or two of the groups R1, R2, R4 and R5 designate a hydrocarbon group of 6–22, preferably 8–20 carbon atoms, and the remaining R1, R2, R4 and R5 groups are an alkyl group with 1–4 carbon atoms, and/or a group —(A)2H, where A is an alkyleneoxy group with 2–3 carbon atoms, and s is a number from 1–4, R3 is an alkylene group with 2–4 carbon atoms and n is a number from 0–2.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: June 5, 2007
    Assignee: Akzo Nobel N.V.
    Inventors: Bengt-Arne Thorstensson, Keith Shaw, Thomas Wallin, Leif-Göran Ståhlgren
  • Patent number: 7145039
    Abstract: Disclosed are compounds capable of facilitating transport of biologically active agents or substances into cells having the general structure: wherein Q is selected from the group consisting of N, O and S; L is any bivalent organic radical capable of linking each Q, such as C, CH, (CH2)l, or {(CH2)i-Y—(CH2)j}k, wherein Y is selected from the group consisting of CH2, an ether, a polyether, an amide, a polyamide, an ester, a sulfide, a urea, a thiourea, a guanidyl, a carbamoyl, a carbonate, a phosphate, a sulfate, a sulfoxide, an imine, a carbonyl, and a secondary amino group and wherein Y is optionally substituted by —X1—L?—X2—Z or —Z; R1–R6, independently of one another, are selected from the group consisting of H, —(CH2)p-D—Z, an alkyl, an alkenyl, an aryl, and an alkyl or alkyl ether optionally substituted by one or more of an alcohol, an aminoalcohol, an amine, an amide, an ether, a polyether, a polyamide, an ester, a mercaptan, an alkylthio, a urea, a thiourea, a guanidyl, or a carbamoyl group, and
    Type: Grant
    Filed: January 21, 2005
    Date of Patent: December 5, 2006
    Assignee: Invitrogen Corp.
    Inventors: Yongliang Chu, Malek Masoud, Gulilat Gebeyehu
  • Patent number: 6972338
    Abstract: The invention relates to a series of novel alkoxylated mono alkyl glyceryl ester phosphobetaine compounds, which are exceptional surface active agents that provide outstanding foam and are very mild to the hair and skin, in addition because of the presence of the ester linkage these materials are not persistent in the aquatic environment. This lack of persistence in the aquatic environment makes these materials greener and environmentally friendly than other non-ester containing compounds. The compounds, because they contain a pendant ionizable phosphate group and a quaternary amine compound are amphoteric surfactants that is they contain both a positive and negative charge in the same molecule. This combination of properties makes these polymers ideally suited for use in personal care applications.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: December 6, 2005
    Assignee: Phoenix Research Corp
    Inventors: John Imperante, Anthony J. O'Lenick, Jr.
  • Publication number: 20040185090
    Abstract: The present invention relates to cationic lipids, methods for preparing some and methods for effectively transporting anionic molecular substances into cell by using said cationic lipids. The present lipids are compatible to the gene therapy due to their stability and highly transporting effects.
    Type: Application
    Filed: August 14, 2003
    Publication date: September 23, 2004
    Inventors: Woo-chul Moon, Chul-so Moon, Byung-gu Kim, Chan-jae Shin, Hyeung-jae Kim, Young-ho Moon, Dong-hwan Kim, Tae-han Um, Hwa-su Kim, Mi-kyung Song, Seok-beom Song
  • Patent number: 6794524
    Abstract: The invention relates to a series of novel ester containing phosphobetaine compounds, which are exceptional surface active agents that provide outstanding foam and are very mild to the hair and skin, in addition because of the presence of the ester linkage these materials are not persistent in the aquatic environment. This lack of persistence in the aquatic environment makes these materials greener and environmentally friendly than other non-ester containing compounds. The compounds, because they contain a pendant ionizable phosphate group and a quaternary amine compound are amphoteric surfactants that is they contain both a positive and negative charge in the same molecule. This combination of properties makes these polymers ideally suited for use in personal care applications.
    Type: Grant
    Filed: August 18, 2003
    Date of Patent: September 21, 2004
    Assignee: Phoenix Research Corporation
    Inventors: John Imperante, Anthony J. O'Lenick, Jr.
  • Patent number: 6727387
    Abstract: A compound of formula I:
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: April 27, 2004
    Assignee: Rohm and Haas Company
    Inventors: Ravindranath Mukkamala, Rajiv Monohar Banavali
  • Publication number: 20020137825
    Abstract: An antistatic composition comprises (a) at least one ionic salt consisting of a nonpolymeric nitrogen onium cation and a weakly coordinating fluoroorganic anion, the conjugate acid of the anion being a superacid; and (b) at least one thermoplastic polymer. The composition exhibits good antistatic performance over a wide range of humidity levels.
    Type: Application
    Filed: December 28, 2001
    Publication date: September 26, 2002
    Applicant: 3M Innovative Properties Company
    Inventors: William M. Lamanna, Thomas P. Klun, Kathleen A. Hachey, Alan D. Fanta
  • Patent number: 6426436
    Abstract: The present invention is related to a series of derivatives of novel ether diamine compounds prepared by the cynobutylation reaction of an alcohol having 3 to 22 carbon atoms with 2-pentenenitrile to form a branched alkyl ether nitrile. The etheraminonitriles formed by the process are hydrogenated to form alkylether amines. The resulting product can be reacted with 2-pentenenitrile and or acrylonitrile and in subsequent step, hydrogenated to yield a diamine. Specifically, the present invention deals with two types of tertiary amines one made by the reaction of novel ether diamines compounds with ethylene oxide, propylene oxide or butylene oxide or mixtures thereof, producing alkoxylated tertiary amines and the other made by the reaction of novel ether amine compounds with formaldehyde and hydrogen producing methylated tertiary amines. The invention also disclosed novel amine oxides, and quaternary compounds made from said tertiary amines.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: July 30, 2002
    Assignee: Nova Molecular Technologies Inc.
    Inventors: Thomas J. Daly, Michael Clumpner, Anthony J. O'Lenick, Jr.
  • Patent number: 6362370
    Abstract: Wood preservatives having biocidal properties which include quaternary ammonium compounds of general formula (I): wherein R1 is a C8-18-alkyl group or an optionally substituted benzyl group, R2 is a C8-18-alkyl group, R3 is a C1-4-alkyl group or a group of the formula —[CH2—CH2—O]n—H, R4 is a C1-4-alkyl group, n is a number from 0.5 to 8, preferably from 1 to 5, and A31 is the anion of an organic carboxylic acid which contains 2 to 12 C atoms and carries at least one hydroxyl, amino or sulfonic acid group. The wood preservatives also penetrate deeply into the wood without the use of pressure, and have only a mild corrosive action on metals. Furthermore, a process for treating timbers with these compositions, concentrates for the preparation thereof, the use of new and known quaternary ammonium compounds in wood preservatives and new quaternary ammonium compounds and their use as biocides.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: March 26, 2002
    Assignee: Lonza AG
    Inventors: Florian Lichtenberg, Joachim Fritschi, Volker Ranft
  • Patent number: 6221954
    Abstract: The preparation and use of quarternized bis hydroxy alkyl amines by the reaction of a tertiary amine and an alkylene oxide in a strong acid system are disclosed. Cationic polyurethane compositions containing pendent hydroxy alkyl groups and methods for their preparation are also disclosed.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 24, 2001
    Assignee: Witco Corporation
    Inventors: Ibrahim Bechara, Thomas R. Baranowski
  • Patent number: 5846907
    Abstract: Pyrazol-4-ylbenzoyl compounds of the formula I ##STR1## where Z is a 5- or 6-membered heterocyclic saturated or unsaturated radical, Q is a pyrazole ring and L and M are as defined in the specification, their use as herbicidal compounds and to processes for preparing the compounds.
    Type: Grant
    Filed: July 30, 1997
    Date of Patent: December 8, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang von Deyn, Regina Luise Hill, Uwe Kardorff, Stefan Engel, Martina Otten, Marcus Vossen, Peter Plath, Harald Rang, Albrecht Harreus, Hartmann Konig, Helmut Walter, Karl-Otto Westphalen, Ulf Misslizt
  • Patent number: 5798310
    Abstract: The present invention relates to an alkoxylated quaternary ammonium surfactant of Formula I and its utility as a tank mix adjuvant for glyphosate compositions. ##STR1## wherein: Z is: --O--(PO).sub.x --(EO).sub.y --R is: ##STR2## a is an integer from 1 to 8, provided the total number of C atoms is from 3-8R.sup.1 is: --C.sub.1-5 alkylR.sup.2 and R.sup.3 are defined in the specification and claims.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: August 25, 1998
    Assignee: Monsanto Europe S.A.
    Inventors: Marc Emile Toussaint, Robert William Mitchell
  • Patent number: 5783534
    Abstract: A process for the production of a solid esterquat free from solvents comprising the steps ofA) forming a mixture comprising(i) at least one fatty acid triethanolamine ester corresponding to formula (I) ##STR1## in which R.sup.1 CO is a saturated and/or unsaturated acyl radical containing 6 to 22 carbon atoms, R.sup.2 and R.sup.3 independently of one another represent hydrogen or have the same meaning as R.sup.1 CO, and n, m and p together stand for O or for a number of from 1 to 10;(ii) at least one fatty alcohol polyglycol ether, and(iii) at least one fatty acid partial glyceride; andB) adding an alkylating agent to the above mixture to form said solid esterquat.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: July 21, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernd Wahle, Joaquim Bigorra Llosas, Rafael Pi, Antoni Soler Codina, Emili Brau Balague, Yvonne Reichert, Peter Waltenberger
  • Patent number: 5705663
    Abstract: The invention relates to quaternized triethanolamine difatty acid esters prepared from triethanolamine, fatty acid, fatty acid ester and a quaternizing agent and to a process for their preparation and to their use. The quaternized triethanolamine difatty acid esters thus prepared can be used to produce particularly storage-, temperature- and viscosity-stable rinse cycle laundry softeners having a high active content.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: January 6, 1998
    Assignee: Servo Delden B.V.
    Inventors: Michael Brock, Meinolf Enneking, Kurt Kosswig
  • Patent number: 5696291
    Abstract: The preparation and use of quarternized bis hydroxy alkyl amines by the reaction of a tertiary amine and an alkylene oxide in a strong acid system are disclosed. Cationic polyurethane compositions containing pendent hydroxy alkyl groups and methods for their preparation are also disclosed.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: December 9, 1997
    Assignee: Witco Corporation
    Inventors: Ibrahim Bechara, Thomas R. Baranowski
  • Patent number: 5578234
    Abstract: The present invention relates to dryer-activated fabric softening compositions and articles, having improved antistatic and/or softening effects, for use in an automatic clothes dryer, especially those comprising, as essential ingredients: (A) fabric softener consisting essentially of: (1) from about 5% to about 95% of preferably biodegradable quaternary ammonium compound selected from the group consisting of the compounds of Formulas I, II, III, and mixtures thereof; (2) from 0% to about 95% highly ethoxylated and/or propoxylated, preferably at least 5 ethylene oxide (EO) and/or propylene oxide (PO) groups per molecule, sugar derivative containing at least one long hydrophobic moiety per molecule; and (3) from 0% to about 95% of carboxylic acid salt of tertiary amine; and (B) from about 1% to about 15%, unsaturated fatty acid having an IV of from about 3 to about 60. The amount of (A) present is at least sufficient to provide softening and/or antistatic effects.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: November 26, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Alessandro Corona, III, Clyde D. Palmer, John R. Rusche, Stephanie Lin-Lin Sung
  • Patent number: 5475119
    Abstract: Ionic monomeric diallylammonium compounds having a targeted combination of diallylammonium cations with selected anions have particularly high and constant charge control properties and very good heat stabilities and dispersibilities.The compounds according to the invention are outstandingly suitable for use as colorless charge control agents in toners and developers for electrophotographic recording processes and for use as charge-improving agents in powders and paints for surface coating, in particular in triboelectrically or electrokinetically sprayed powder paints.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: December 12, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudiger Baur, Hans-Tobias Macholdt
  • Patent number: 5463094
    Abstract: A process for a high temperature, solvent free quaternization of certain tertiary amines using dimethylsulfate to produce quaternary ammonium methyl sulfates which may be used in fabric softening and other applications, is disclosed.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: October 31, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: David M. Brown, Erich M. Gatter, Cheryl A. Littau
  • Patent number: 5424438
    Abstract: Polishes for metal surfaces, based on dispersions of waxes, fluorinated polymers and perfluoropolyoxyalkylene oils acquire high gloss characteristics combined with improved water-repellency and resistance to soiling of 0.1-5% by weight of at least a cationic emulsifier comprised in the general formula(I) R-L-Q.sup.+ X.sup.-where:R=a chain of perfluoropolyoxyalkylene units;L=a divalent organic group;Q=a polar group;X=a halogen, or a group of formulaCH.sub.3 -Phenylene-SO.sub.3.sup.-R"SO.sub.3.sup.-R"=F-(CF.sub.2).sub.m -;t=1 or 2;m=1-4.The polished containing the emulsifiers of formula (I) as well as the compounds comprised in said formula are claimed as new products.
    Type: Grant
    Filed: January 6, 1994
    Date of Patent: June 13, 1995
    Assignee: Ausimont S.p.A.
    Inventors: Alba Chittofrati, Viviana Boselli, Giovanni Gavazzi, Ezio Strepparola, Renato Spiti, Silvia Tresoldi
  • Patent number: 5352833
    Abstract: What is provided herein are active antimicrobial polymeric quaternary ammonium compounds which are capped with defined C.sub.12 /C.sub.14 alkyl groups optionally coprecipitated with polyvinylpyrrolidone (PVP). The compounds of the invention have the formula: ##STR1## where n is at least 2, e.g. 2-30, and C.sub.12 /C.sub.14 alkyl preferably is 50:50 wt. % of dodecyl/tetradecyl alkyl.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: October 4, 1994
    Assignee: ISP Investments Inc.
    Inventor: John J. Merianos
  • Patent number: 5284650
    Abstract: A process is disclosed for making substantially solvent free quaternary ammonium compounds using fatty acids, amines and quaternizing agents without side reactions that would produce esters of fatty acids. A relatively small amount of a water-alcohol solvent is used in the quaternizing reaction after which a fatty acid is added and the solvent removed by sparging and/or vacuum.
    Type: Grant
    Filed: November 5, 1992
    Date of Patent: February 8, 1994
    Assignee: Sherex Chemical Co., Inc.
    Inventor: David E. Whittlinger
  • Patent number: 5242684
    Abstract: An antimicrobial, low toxicity, non-irritating composition comprises a blend of several bis-quaternary ammonium compounds coprecipitated with a copolymer of vinylpyrrolidone and an acrylamido or vinyl quaternary ammonium monomer.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: September 7, 1993
    Assignee: ISP Investments Inc.
    Inventor: John J. Merianos
  • Patent number: 5223628
    Abstract: A process is disclosed for making substantially solvent free quaternary ammonium compounds using fatty acids, amines and quaternizing agents without side reactions that would produce esters of fatty acids. A relatively small amount of a water-alcohol solvent is used in the quaternizing reaction after which a fatty acid is added and the solvent removed by sparging and/or vacuum.
    Type: Grant
    Filed: November 7, 1991
    Date of Patent: June 29, 1993
    Assignee: Sherex Chemical Company, Inc.
    Inventor: David E. Whittlinger
  • Patent number: 5221794
    Abstract: The invention relates to a method of producing a mixture of a quaternary ammonium compound, fatty acid, fatty acid ester and tertiary amine salt in situ which is a highly functional mixture that is manufactured in a single step reaction whereby quaternization is completed without the aid of solvents, especially flammable solvents. The single step reaction process eliminates separate blending of individual components. The compositions obtained can be used as fabric softeners, in modified clays, as hair treating compounds and as disinfectants.
    Type: Grant
    Filed: November 7, 1991
    Date of Patent: June 22, 1993
    Assignee: Sherex Chemical Company, Inc.
    Inventors: Jeannene A. Ackerman, Michael Miller, David E. Whittlinger
  • Patent number: 5196582
    Abstract: Quaternary ammonium halides are prepared in solid form by reacting an alkyl or aralkyl halide with ammonia or an amine in a liquefied gas as the solvent.
    Type: Grant
    Filed: July 1, 1991
    Date of Patent: March 23, 1993
    Assignee: Ethyl Corporation
    Inventors: Kim R. Smith, James E. Borland, Jeffrey W. Perine, Joe D. Sauer
  • Patent number: 5152916
    Abstract: Aqueous aldehyde solutions for trapping hydrogen sulfide comprising 5 to 50% by weight of an aldehyde and 1 to 5% by weight, relative to the aldehyde solution of a formulation comprising10 to 80% by weight of an ester of oxalkylated alkylalkylenediamines, which may be quaternized and 20 to 90% by weight of water or of a C.sub.1 -C.sub.4 -alcohol.
    Type: Grant
    Filed: August 21, 1990
    Date of Patent: October 6, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hermann Hoffmann, Frederic Mabire
  • Patent number: RE37555
    Abstract: The invention relates to a method of producing a mixture of a quaternary ammonium compound, fatty acid, fatty acid ester and tertiary amine salt in situ which is a highly functional mixture that is manufactured in a single step reaction whereby quaternization is completed without the aid of solvents, especially flammable solvents. The single step reaction process eliminates separate blending of individual components. The compositions obtained can be used as fabric softeners, in modified clays, as hair treating compounds and as disinfectants.
    Type: Grant
    Filed: June 11, 1999
    Date of Patent: February 19, 2002
    Assignee: Goldschmidt Chemical Company
    Inventors: Jeannene A. Ackerman, Michael Miller, David E. Whittlinger