Two Benzene Rings Bonded Directly To The Same Nitrogen Patents (Class 564/433)
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Patent number: 4832697Abstract: This invention encompasses compounds of the formula: ##STR1## wherein: one of R.sup.1 or R.sup.2 is nitro and the other is --SO.sub.3 H or COOH; andone of R.sup.3 or R.sup.4 is hydrogen and the other is --NR.sup.5 R.sup.6, where R.sup.5 and R.sup.6 independently are hydrogen, C.sub.1-4 alkyl, or C.sub.2-4 hydroxyalkyl;or a water soluble salt thereof; hair dye preparations containing the above compounds as substantive hair dyes; and methods for dyeing hair using such preparations.Type: GrantFiled: February 26, 1988Date of Patent: May 23, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: David Rose, Edgar Lieske, Norbert Maak
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Patent number: 4814504Abstract: Diphenylamine is produced by contacting aniline with an alumina catalyst having at least about 30 percent by volume of its total porosity in the form of pores having a diameter of between about 120 and about 200 Angstroms and a sulfur content, as measured in the form of SO.sub.4, of less than about 0.02 percent by weight at between about 380.degree. and 475.degree. C.Type: GrantFiled: September 3, 1986Date of Patent: March 21, 1989Assignee: Uniroyal Chemical Company, Inc.Inventor: Russell E. Malz, Jr.
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Patent number: 4804783Abstract: Diphenylamines or N,N'-diphenyl-phenylenediamines can be obtained by heat-reacting an aniline or a phenylenediamine with preferably an excess of a phenol in an amount of 4 to 20 moles per mole of the aniline or phenylenediamine in the presence of a hydrogen transfer catalyst and a cyclohexanone corresponding to said phenol.The excess phenol used in the reaction undergoes reduction in the reaction system to form a cyclohexanone, which in turn reacts with the aniline or phenylenediamine to form a Schiff base and is thus consumed. The Schiff base forms the intended product by means of a dehydrogenation reaction, and the hydrogen evolved at this time reduces the phenol to form a cyclohexanone.The phenol present in excess thus becomes in the system a solvent, a starting material for the cyclohexanone, and an acceptor of the hydrogen that forms as a by-product at the time of formation of the intended product.Type: GrantFiled: July 31, 1987Date of Patent: February 14, 1989Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Teruyuki Nagata, Akihiro Tamaki, Nobuyuki Kajimoto, Masaru Wada
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Patent number: 4792563Abstract: Insecticidally active compounds of the formula (I): ##STR1## wherein R.sup.4 represents a group selected from those groups represented by R.sup.5 in insecticidally active compounds of formula: ##STR2## R.sup.3 is selected from fluoromethyl and difluoromethyl, and either (a) R.sup.1 and R.sup.2 represent alkyl of one, two, three or four carbon atoms, or (b) R.sup.1 and R.sup.2 taken together with the adjacent carbon atom form a cycloalkyl ring of four, five or six carbon atoms.Type: GrantFiled: October 6, 1987Date of Patent: December 20, 1988Assignee: Imperial Chemical Industries PLCInventor: Alan J. Whittle
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Patent number: 4788336Abstract: In accordance with the present invention there is provided an organic compound having the formula selected from the group consisting of: ##STR1## wherein x is an integer from 0 to 2, y is an integer from 1 to 6, and z is an integer from 0 to 2; ##STR2## wherein L is aliphatic, alicyclic or aromatic and a is an integer from 2 to 6; and wherein G has the formula ##STR3## wherein n is an integer from 0 to 6 and Q.sub.1, Q.sub.2, Q.sub.3, Q.sub.5, Q.sub.6, and Q.sub.7, which may be the same or different, represent H or CH.sub.3, and Q.sub.4 represents H or CH.sub.3 when x and z are 0 or n is greater than 0, or Q.sub.4 represents CH.sub.3 when x or z are 1 or 2 and n is 0.The compounds, which exhibit unexpectedly high T.sub.g and unexpectedly high resistance to oxidation, are useful in electrophotographic elements.Type: GrantFiled: January 23, 1987Date of Patent: November 29, 1988Assignee: Eastman Kodak CompanyInventor: Norman G. Rule
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Patent number: 4777296Abstract: Styryl derivatives of the formula ##STR1## and an electrophotographic photoconductor comprising an electroconductive support material and a photosensitive layer comprising at least one styryl derivative of the same formula are disclosed, in which R.sup.1 is selected from the group consisting of an alkyl group, a substituted alkyl group, an aryl group and substituted aryl group; R.sup.2 is selected from the group consisting of hydrogen, an alkyl group, a substituted alkyl group, an aryl group and a substituted aryl group; and Ar represents an aryl group or a substituted aryl group.Type: GrantFiled: April 29, 1986Date of Patent: October 11, 1988Assignee: Ricoh Company, Ltd.Inventor: Masaomi Sasaki
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Patent number: 4772633Abstract: This invention relates to a novel compound represented by the following general formula (I), its production, and an insecticidal and acaricidal composition containing it as an active ingredient: ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, are a hydrogen atom, a halogen atom, a lower alkyl group, a trifluoromethyl group, a lower alkoxyl group, a lower alkenyloxy group or a halogenated lower alkoxyl group or are, taken together, a methylenedioxy group; R.sub.3 is a vinyl group or a ethynyl group; R.sub.4 is a hydrogen atom or a lower alkyl group; R.sub.5 is a hydrogen atom or a fluorine atom; R.sub.6 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxyl group or a trifluoromethyl group; Z is a nitrogen atom or a group represented by the formula --CH.dbd.; when Z is a nitrogen atom, Y is an oxygen atom; and when Z is a group of the formula --CH.dbd., Y is an oxygen atom, a sulfur atom, a methylene group or a group represented by the formula --NH--.Type: GrantFiled: February 20, 1986Date of Patent: September 20, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Noritada Matsuo, Kazunori Tsushima, Sumio Nishida, Toshihiko Yano, Masachika Hirano
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Patent number: 4769302Abstract: A photosensitive member according to the present invention comprises an electrically conductive substrate and a photosensitive layer comprising a binder resin and a styryl compound dispersed therein and represented by the general formula (I), ##STR1## wherein R.sub.1, R.sub.3 and R.sub.5 each represent hydrogen or an alkyl, aryl, aralkyl or heterocyclic group, the aryl, aralkyl and heterocyclic groups having or not having a substituent, R.sub.2, R.sub.4 and R.sub.6 each represent a substituted or unsubstituted aryl, aralkyl or heterocyclic group, R.sub.1 and R.sub.2, R.sub.3 and R.sub.4, and R.sub.5 and R.sub.6 taken together form a ring, and R.sub.7, R.sub.8 and R.sub.9 each represent hydrogen or an alkyl, alkoxyl, aralkyl or aryl group.A photosensitive member of this structure exhibits high sensitivity, is outstanding in the ability to retain charges and in charge transporting ability and less prone to deterioration when repeatedly used.Type: GrantFiled: May 7, 1987Date of Patent: September 6, 1988Assignee: Minolta Camera Kabushiki KaishaInventor: Hideaki Ueda
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Patent number: 4756715Abstract: Novel substituted nitrodiphenylamines and substantive hair dye preparations containing them or containing nitrodiphenylamines with different substituents. The dyes result in yellow to copper-colored shades of high intensity and fastness and are more soluble in water than known nitroanilines dyes.Type: GrantFiled: October 24, 1986Date of Patent: July 12, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: David Rose, Edgar Lieske, Norbert Maak
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Patent number: 4731484Abstract: New compounds which are 4,4'-bis(trihaloacetyl) derivatives of aromatic compounds have been prepared by reacting an aromatic compound with a haloacetyl halide in the presence of a Friedel-Crafts catalyst, e.g. AlCl.sub.3, in a suitable solvent. The compounds are useful in preparing polycarbonates, polyesters, polyamides, polyketones and polyurethanes.Type: GrantFiled: April 30, 1986Date of Patent: March 15, 1988Assignee: The Dow Chemical CompanyInventor: Marlin E. Walters
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Patent number: 4724267Abstract: Bis(haloacylaromatic) compounds have been made by a new process in which monohaloacylated aromatic compounds have been reacted by a coupling reaction. These bis(haloacylaromatic) compounds can be employed as monomers in the preparation of polyesters and polyamides which have easy processability. The monohaloacylated compound is coupled by reacting two moles of the monomer with a carbon or sulfur compound containing at least two halogen atoms in the presence of a Friedel-Crafts catalyst.Type: GrantFiled: May 23, 1986Date of Patent: February 9, 1988Assignee: The Dow Chemical CompanyInventors: George M. St. George, Marlin E. Walters
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Patent number: 4709096Abstract: Stilbene derivatives of the formula (I) ##STR1## and distyryl derivatives of the formula (II), ##STR2## as defined in the specification, and an electrophotographic photoconductor comprising an electroconductive support material and a photosensitive layer overlayed thereon comprising at least one of the above derivatives, are disclosed.Type: GrantFiled: February 22, 1985Date of Patent: November 24, 1987Assignee: Ricoh Company, Ltd.Inventor: Masaomi Sasaki
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Patent number: 4704219Abstract: A composition useful in organic materials subject to degradation comprising a mixture of para-butylated and octylated, ortho-ethylated diphenylamines. The composition is liquid at ambient temperature, and is particularly useful as an antioxidant for rubber and latexes and petroleum based and synthetic lubricants.Type: GrantFiled: September 19, 1986Date of Patent: November 3, 1987Assignee: The B. F. Goodrich CompanyInventor: Chong-Kuang Shaw
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Patent number: 4683332Abstract: There is disclosed a process for the synthesis of para-nitrodiphenylamines via the Formanilide Process wherein the improvement is characterized in that a specific catalyst is utilized. More specifically, a zinc (II) compound (zinc in the plus two oxidation or valence state), is used as a catalyst in the preparation of para-nitrodiphenylamines via the formanilide process.Type: GrantFiled: May 20, 1985Date of Patent: July 28, 1987Assignee: The Goodyear Tire & Rubber CompanyInventor: Budd H. Sturm
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Patent number: 4677185Abstract: This invention relates to a new process for the preparation of bifunctional polyphenylene oxides.Type: GrantFiled: September 25, 1985Date of Patent: June 30, 1987Assignee: Bayer AktiengesellschaftInventors: Walter Heitz, Wilhelm Risse
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Patent number: 4670596Abstract: Novel alkyl-dinitrodiphenylamine compounds are useful in controlling insects and arachnids. These compounds are useful especially in the control of citrus rust mite.Type: GrantFiled: August 14, 1985Date of Patent: June 2, 1987Assignee: Eli Lilly and CompanyInventors: Barry A. Dreikorn, Kenneth E. Kramer
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Patent number: 4602111Abstract: N,N-Bis(polybromophenyl)organoamines are useful flame retardants which may be admixed with polymers to impart flame retardancy to the resulting compositions. Examples of such flame retardants include N,N-bis(2,4,6-tribromophenyl)methylamine, N,N-bis(2,4,6-tribromophenyl)ethylamine, N,N-bis(2,4,6-tribromophenyl)-allylamine, and N,N-bis(2,4,6-tribromophenyl)benzylamine.Type: GrantFiled: December 29, 1983Date of Patent: July 22, 1986Assignee: PPG Industries, Inc.Inventors: Kenneth J. Sienkowski, Ralph B. Thompson
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Patent number: 4600798Abstract: Aryl-diethers are provided which are produced by reacting a halogenated xylene compound, preferably 4-chloro-ortho-xylene, and an alkali metal salt of a bisphenol compound, preferably bisphenol-A. These aryl-diethers serve as precursors in a process for producing polyetherimide polymers.Type: GrantFiled: March 18, 1985Date of Patent: July 15, 1986Assignee: General Electric CompanyInventor: James A. Cella
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Patent number: 4599450Abstract: Acid nitro dyestuffs are prepared by treating aminonitrodiphenylaminesulfonic acids with an oxidizing agent in an aqueous medium, the oxidizing agent employed being a manganese-(VI) or manganese-(VII) compound and the reaction being carried out at a pH higher than 5 and at a temperature between 20.degree. and 100.degree. C. The dyestuffs thus obtainable dye even fresh full-grained chrome leather in full shades.Type: GrantFiled: May 10, 1984Date of Patent: July 8, 1986Assignee: Hoechst AktiengesellschaftInventor: Hasso Hertel
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Patent number: 4591359Abstract: Acid nitrodyestuffs are prepared by treating aminonitrodiphenylaminesulfonic acids with an oxidizing agent in an aqueous medium, the oxidizing agent being hypochlorous acid or its alkali metal or alkaline earth metal salts and the reaction taking place at above pH 4 and at a temperature between 0.degree. and 100.degree. C. The dyestuffs thus obtainable dye even fresh full chrome grained leather in deep shades.Type: GrantFiled: August 23, 1984Date of Patent: May 27, 1986Assignee: Hoechst AktiengesellschaftInventor: Hasso Hertel
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Patent number: 4548976Abstract: Bis-(norbornyl or substituted norbornyl) derivatives of a phenol or phenylamine of the following formula: ##STR1## wherein each A is O or NH; M is a bivalent radical such as the residue of an aldehyde, ammonia, water or H.sub.2 S; each R is a hydrocarbyl or an inertly substituted hydrocarbyl group; each R.sub.1 is independently a hydrocarbyl or an inertly substituted hydrocarbyl group and each n is independently an integer from 0 to 3 are useful as antioxidants for a variety of materials including latex compositions for preparing latex foam backed carpets.Type: GrantFiled: May 18, 1984Date of Patent: October 22, 1985Assignee: The Dow Chemical CompanyInventors: Pierre DeRoche, Neil V. Kirby
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Patent number: 4539429Abstract: Novel lower-alkyl 2-(hydroxyphenylamino)phenyl ketones, useful as inhibitors of lipoxygenase activity, are of the formula ##STR1## wherein R is hydrogen, lower-alkyl, lower-alkoxy or halo; R' is hydrogen or lower-alkyl; R" is hydrogen, lower-alkyl or halo; and Alk is lower-alkyl. The compounds are prepared by de-etherification of the corresponding alkyl or benzyl ethers which are in turn prepared by reacting a 2-(alkoxy- or benzyloxyphenylamino)benzoic acid with an alkyllithium.Type: GrantFiled: July 11, 1983Date of Patent: September 3, 1985Assignee: Sterling Drug Inc.Inventor: Denis M. Bailey
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Patent number: 4522647Abstract: Substituted phenoxyalkanediones and intermediates therefor, and the use of said compounds for the control of weeds.Type: GrantFiled: June 29, 1983Date of Patent: June 11, 1985Assignee: Zoecon CorporationInventors: Richard J. Anderson, Shy-Fuh Lee
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Patent number: 4518803Abstract: A process is disclosed for the preparation of p-nitrosodiphenylamine hydrochloride comprising reacting diphenylamine, C.sub.5 -C.sub.10 alkyl nitrite and anhydrous HCl in the presence of a C.sub.5 -C.sub.10 aliphatic alcohol and essentially in the absence of an aromatic solvent.Type: GrantFiled: September 30, 1982Date of Patent: May 21, 1985Assignee: Uniroyal, Inc.Inventors: Wadim Batorewicz, Edward L. Wheeler
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Patent number: 4504663Abstract: The present invention concerns novel heterocyclic aminoalcoyl derivatives having the formula: ##STR1## wherein n=1, 2 or 3; A represents a nitrogen atom or the CH group, X=CH.sub.2 or CH.sub.2 O; R represents a phenyl nucleus possibly substituted; NR.sub.1 R.sub.2 =amino, methylamino, N,N-dialkylamino or an heterocyclic radical; and R.sub.3 =H, halogen, alkyl, alkyloxy or methoxy.These derivatives are useful as drugs, especially as analgesics and antidepressants.Type: GrantFiled: November 15, 1983Date of Patent: March 12, 1985Assignee: Delalande S.A.Inventors: Gerard H. Moinet, Philippe L. Dostert, Guy R. Bourgery
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Patent number: 4500737Abstract: Novel substituted cycloalkanediones and their use for the control of weeds.Type: GrantFiled: March 2, 1984Date of Patent: February 19, 1985Assignee: Zoecon CorporationInventor: Clive A. Henrick
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Patent number: 4497965Abstract: Substituted phenoxyalkanetriones and the use thereof for the control of weeds.Type: GrantFiled: March 1, 1984Date of Patent: February 5, 1985Assignee: Zoecon CorporationInventor: Shy-Fuh Lee
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Patent number: 4496590Abstract: Novel hydroxyphenylaminobenzenealkanols, useful as antiasthmatic agents, are of the formula ##STR1## wherein R is hydrogen, lower-alkyl, lower-alkoxy or halo; R' is hydrogen or lower-alkyl; R" is hydrogen, lower-alkyl or halo; and Y is C.sub.n H.sub.2n wherein n is 1-2. The compounds are prepared by de-etherification of the corresponding phenol alkyl or benzyl ethers; by reduction of the corresponding benzoic acids or esters thereof; or by reduction of ketones wherein --Y--OH is replaced by --COCH.sub.3.Type: GrantFiled: April 18, 1983Date of Patent: January 29, 1985Assignee: Sterling Drug Inc.Inventors: Donald C. Schlegel, Malcolm R. Bell
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Patent number: 4485114Abstract: Arylglyoxals which are new compounds, which are active as hypoglycemic agents.Type: GrantFiled: January 20, 1983Date of Patent: November 27, 1984Assignee: American Cyanamid CompanyInventors: Middleton B. Floyd, Jr., Vern G. DeVries
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Patent number: 4479008Abstract: A process for preparing p-nitrosodiphenylamine hydrochloride is provided from N-nitrosodiphenylamine and hydrogen chloride. The product is prepared in the absence of an aromatic solvent and using a solvent consisting essentially of aliphatic C.sub.5 -C.sub.10 alcohol.Type: GrantFiled: September 30, 1982Date of Patent: October 23, 1984Assignee: Uniroyal, Inc.Inventors: Wadim Batorewicz, Edward L. Wheeler
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Patent number: 4459304Abstract: 2-Anilino-3,5-dinitro-benzotrifluorides of the formula ##STR1## in which X is O, S, SO or SO.sub.2,n is 1, 2, 3 or 4,R.sup.1 is haloalkyl, haloalkoxyalkyl, phenyl, halophenyl, haloalkylphenyl, haloalkoxyphenyl, haloalkylmercaptophenyl or haloalkylsulphonyl, andR.sup.2 each independently is hydrogen, halogen, cyano, nitro, alkyl, haloalkyl or haloalkoxyalkyl, orXR.sup.1 and R.sup.2, when in the ortho-position relative to one another, together with the two adjacent carbon atoms of the phenyl nucleus, form an optionally halogen-substituted dioxanyl ring, orprovided X represents S, SO or SO.sub.2, R.sup.1 can represent unsubstituted alkyl in addition to the aforementioned radicals,which possess arthropodicidal, nematicidal, fungicidal and bactericidal properties.Type: GrantFiled: March 28, 1979Date of Patent: July 10, 1984Assignee: Bayer AktiengesellschaftInventors: Alfons Hartmann, Erich Klauke, Ingeborg Hammann, Peter Roessler, Volker Paul
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Patent number: 4448965Abstract: Novel substituted cycloalkanediones and their use for the control of weeds.Type: GrantFiled: August 16, 1982Date of Patent: May 15, 1984Assignee: Zoecon CorporationInventor: Clive A. Henrick
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Patent number: 4435599Abstract: There is disclosed a process for the synthesis of para-nitrodiphenylamines wherein the improvement is characterized in that a specific co-catalyst system is utilized. More specifically, a zinc (II) compound (zinc in the plus two oxidation or valence state), is used in conjunction with copper or a copper compound as a co-catalyst system in the preparation of para-nitrodiphenylamines.Type: GrantFiled: November 26, 1982Date of Patent: March 6, 1984Assignee: The Goodyear Tire & Rubber CompanyInventor: Budd H. Sturm
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Patent number: 4431851Abstract: The present invention concerns compounds of the formula ##STR1## wherein n=1, 2 or 3; and R' represents phenyl or orthofluorophenyl. Said compounds are used as intermediates in the preparation of heterocyclic aminoalkyl derivatives which are useful as analgesics and antidepressants.Type: GrantFiled: March 8, 1983Date of Patent: February 14, 1984Assignee: Delalande S.A.Inventors: Gerard H. Moinet, Philippe L. Dostert, Guy R. Bourgery
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Patent number: 4407820Abstract: The present invention is directed to the use of a class of N-alkyldiphenylamines as insecticides and arachnicides, and also as ectoparasiticides. The invention is also directed to a class of novel fluorinated N-alkyldiphenylamines.Type: GrantFiled: September 8, 1981Date of Patent: October 4, 1983Assignee: Eli Lilly and CompanyInventors: Barry A. Dreikorn, Kenneth E. Kramer
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Patent number: 4362893Abstract: C-Nitrosodiarylamines may be prepared in a single stage from diarylamines by adding alcoholic solutions of a hydrogen halide below the surface of a stirred mixture of the diphenylamine in an organic liquid containing water. The amount of water contained is critical, and amounts from about 1 to about 3 g per mole of diarylamine are preferred.Type: GrantFiled: June 3, 1981Date of Patent: December 7, 1982Assignee: UOP Inc.Inventor: Paul R. Kurek
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Patent number: 4316988Abstract: A series of new diphenylamines have small alkyl substituents on the amino nitrogen and are useful as intermediates for the preparation of rodenticidal diphenylamines. One phenyl ring has 2,4-dinitro-6-trifluoromethyl substitution, and the other is substituted with no more than one methyl or trifluoromethyl group. The invention is particularly directed to N-alkyl-2,4-dinitro-3'-6-bis(trifluoromethyl)diphenylamines, which are additionally useful as insecticides and arachnicides.Type: GrantFiled: December 24, 1980Date of Patent: February 23, 1982Assignee: Eli Lilly and CompanyInventors: Albert J. Clinton, deceased, George O. P. O'Doherty
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Patent number: 4304791Abstract: N-Nitrophenyl-(tetrafluoroethoxy)-benzenamines are useful as fungicides, anticoccidials and ectoparasiticides, in addition to being insecticidal agents.Type: GrantFiled: January 8, 1980Date of Patent: December 8, 1981Assignee: Eli Lilly and CompanyInventor: Albert J. Clinton, deceased
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Patent number: 4299983Abstract: A process for the production of symmetrical and unsymmetrical substituted diarylamines is disclosed. The process provides said diarylamines in high yield and purity by the reaction of a salt of an arylsulfonic acid and an alkali metal salt of a primary arylamine in the presence of an inorganic alkali metal salt.Type: GrantFiled: October 3, 1979Date of Patent: November 10, 1981Assignee: Xerox CorporationInventors: Trevor I. Martin, John M. Lennon
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Patent number: 4298522Abstract: A diphenylamine derivative of the general formula ##STR1## wherein R represents a hydrogen atom or a methyl group, R.sub.1 and R.sub.2, independently from each other, represent a hydrogen atom, a chlorine atom, a bromine atom, or a hydrocarbon radical having 1 to 12 carbon atoms, and A represents ##STR2## and a degradation inhibitor for rubbery polymers comprising the aforesaid diphenylamine derivative as an active ingredient.Type: GrantFiled: June 19, 1980Date of Patent: November 3, 1981Assignee: Nippon Zeon Co. Ltd.Inventors: Mitsuhiro Tamura, Tetsuo Ohishi, Hiroshi Sakurai
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Patent number: 4287336Abstract: Chromogenic compounds of the formula ##STR1## wherein each of Y.sub.1 and Y.sub.2 independently represents an amino-substituted phenyl radical of the formula ##STR2## a 3-indolyl radical of the formula ##STR3## or a 3-carbazolyl radical of the formula ##STR4## and Q represents alkyl of 1 to 12 carbon atoms or unsubstituted or substituted aryl or aralkyl, while each of X.sub.1 and X.sub.2 independently represents hydrogen, alkyl containing not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or represents cycloalkyl, phenyl, benzyl, or phenyl or benzyl which is substituted by halogen, lower alkyl or lower alkoxy, or X.sub.1 and X.sub.2 together with the nitrogen atom to which they are attached represent a 5- or 6-membered heterocyclic radical, X.sub.3 represents hydrogen, halogen, nitro, lower alkyl or lower alkoxy, each of R and Z.sub.Type: GrantFiled: September 10, 1979Date of Patent: September 1, 1981Assignee: Ciba-Geigy CorporationInventor: Jean C. Petitpierre
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Patent number: 4269720Abstract: Organic material such as lubricating oil is stabilized against oxidative degradation by addition of an alkyl aniline (e.g. 2,4,6-triethylaniline; 2-sec-butyl-6-ethylaniline), monoethyldiphenylamine and/or N-(2-amino-3-ethyl-.alpha.-methylbenzylidene)-2,6-diethylaniline or mixtures thereof.Type: GrantFiled: May 29, 1979Date of Patent: May 26, 1981Assignee: Ethyl CorporationInventors: John D. Bartleson, John C. Wollensak
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Patent number: 4263455Abstract: The invention relates to novel ortho-aminoacetophenones of the formula I ##STR1## and their tautomers, in which Z is hydrogen, halogen, lower alkyl, cycloalkyl, lower alkoxy, trifluoromethyl, nitro or substituted or unsubstituted sulphamoyl, m is 1 or 2, R is hydrogen, aryl or lower alkyl, R.sub.1 is hydrogen or lower alkyl, R.sub.2 is lower alkyl, cycloalkyl, aryl, cycloalkyl-lower alkyl, aryl-lower alkyl or substituted or unsubstituted pyridyl, R.sub.Type: GrantFiled: September 27, 1979Date of Patent: April 21, 1981Assignee: Ciba-Geigy CorporationInventors: Pier G. Ferrini, Richard Goschke, Alfred Sallmann, Alberto Rossi
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Patent number: 4261922Abstract: Hydroxyalkylphenyl ether compounds are prepared by reaction of cyclic organic carbonate compounds with phenols in the presence of potassium iodide catalyst.Type: GrantFiled: July 26, 1979Date of Patent: April 14, 1981Assignee: The Dow Chemical CompanyInventor: Kenneth M. Kem
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Patent number: 4250294Abstract: A polymer having aromatic or heterocyclic rings as the only structural elements said aromatic or heterocyclic rings containing at least two nitro groups is disclosed as well as a method of preparing the same. The polymers are useful as binding agents for thermo stable propellants and can be easily formed into films. They remain thermally stable up to temperatures of at least 200.degree. C.Type: GrantFiled: November 22, 1978Date of Patent: February 10, 1981Assignee: Dynamit Nobel AktiengesellschaftInventors: Rainer Hagel, Klaus Redecker
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Patent number: 4250115Abstract: Tertiary amines may be prepared by reacting an olefinic compound, carbon monoxide, hydrogen and a nitrogen-containing compound such as ammonia, a primary amine or a secondary amine in the presence of a rhodium or ruthenium-containing catalyst at temperatures in the range of from about 50.degree. to about 350.degree. C. and a pressure in the range of from about 10 to about 300 atmospheres.Type: GrantFiled: December 20, 1978Date of Patent: February 10, 1981Assignee: UOP Inc.Inventor: Tamotsu Imai
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Patent number: 4238407Abstract: A process for the preparation of nitro-diphenyl amines is disclosed by decarboxylation of a urethane in the presence of a base at an elevated temperature using tetramethylene sulphone as reaction medium is disclosed. The urethane can be one formed by the reaction of a nitrophenol with an aromatic isocyanate.Type: GrantFiled: November 19, 1979Date of Patent: December 9, 1980Assignee: Bayer AktiengesellschaftInventors: Rudolf Fauss, Kuno Wagner, Jan Mazanek