Abstract: There is provided a process for the preparation of a compound of formula (I) as defined herein, wherein said process comprises reacting a compound of formula (II) as defined s herein with one or more suitable Vilsmeier reagent.

Abstract: The mechanical properties of urea formaldehyde resins may be improved by incorporating therein polyvinyl alcohol. The polyvinyl alcohol may be incorporated during pre-mixing, mid mixing, and/or post mixing of the resin components. Resins prepared using polyvinyl alcohol are particularly desirable in articles requiring improved mechanical strength and water resistance, as compared to similar resins prepared without the polyvinyl alcohol such as shingles.

Abstract: A process for isolating at least one target compound, such as manool, geranyl linalool, ethyl guaiacol, eugenol, veratraldehyde, squalene, terpin, cholesterol, beta-sitosterol, campesterol, stigmasterol, stigmastenol and dehydroabietic acid, from biomass, the process including steps of: obtaining a condensate from a recovery evaporator, a reverse osmosis retentate of a condensate of a pulp and paper mill, or both, the condensate, retentate or both being substantially free of higher molecular weight (approximately >1000 Da) cellulose and/or lignin and/or lignin-derived material; optionally pH adjusting and filtering the condensate to collect insoluble material; extracting the condensate, the collected insoluble material, or both, with solid phase extraction (SPE), liquid-liquid extraction or solid-liquid extraction to produce an extract containing the at least one target compound; and optionally purifying the extract containing the at least one target compound by thermal fractionation, chromatographic separ

Abstract: Method of stabilizing high-concentration formaldehyde solutions having a CH2O content of >70% by weight against precipitation of solids, which comprises heating the high-concentration formaldehyde solution at a heating rate of at least 5° C./min to a temperature of from 80° C. to 200° C. immediately after it has been prepared and storing it at a temperature in this range.

Abstract: In an aqueous formaldehyde solution comprising formaldehyde in the form of monomeric formaldehyde, methylene glycol and polyoxymethylene glycols in a total concentration x of ?65% by weight, the mean molar mass M of the polyoxymethylene glycols is, as a function of the formaldehyde concentration, equal to or less than the values given by equation I: ( M _ g ? / ? mol ) = 48 + 6.589 · 10 - 1 · ( x % ? ? by ? ? weight ) + 4.725 · 10 2 · ? ( x % ? ? by ? ? weight ) 2 - 3.434 · 10 - 3 · ( x % ? ? by ? ? weight ) 3 + ? 9.625 · 10 - 5 · ( x % ? ? by ? ? weight ) 4 - 1.172 · 10 6 · ? ( x % ? ? by ? ? weight ) 5 + 5.

Abstract: In a process for preparing formaldehyde from methanol by dehydrogenation in a reactor in the presence of a catalyst at a temperature in the range from 300 to 1000° C., a circulating gas stream comprising by-products of the dehydrogenation is passed through the reactor.

Abstract: A method and composition for quenching formaldehyde fixation of cell and tissue specimens. The composition includes a formaldehyde-reactive agent. The formaldehyde-reactive agent reacts with the formaldehyde to quench the fixation of the cell or tissue specimen. The method involves contacting a formaldehyde fixative solution with the composition.

Abstract: Abstract A process for purifying formaldehyde in which the formaldehyde is scrubbed with alcohol in an absorption unit and in the course of this reacted virtually completely to form the hemiformal and is simultaneously separated off from gaseous impurities in a first purification step. In a desorption unit, the residual impurities are then converted into a gaseous state and separated off from the liquid hemiformal, whereupon the purified hemiformal is thermally cleaved into alcohol and formaldehyde in a pyrolysis unit. The formaldehyde thus prepared is suitable, for example, for preparing oligomers, polymers, dyestuffs and fertilizers, as well as for the treatment of seeds.

Abstract: Aliphatic alkanals with a water content of greater than 300 ppm which are stable in storage, and a method of improving the storage stability of these aliphatic alkanals, especially of substituted, sulfur-containing alkanals. The formation of oligomers, polymers and condensation products from elimination reactions and oxidation and the subsequent reactions of the products formed results in undesired impurities that are largely prevented by the addition of an organic acid that forms metal complexes and, optionally, alkanolamines or trialkanolamines.

Abstract: A process for the heterogeneous exothermic synthesis of formaldehyde, in particular in a reactor of the type comprising a plurality of adiabatic catalytic beds connected in series, provides the step of feeding to the reactor the methanol necessary for the synthesis distributed in at least two portions, each fed to respective distinct catalytic beds.

Abstract: A process for the heterogeneous exothermic synthesis of formaldehyde, in particular in reactors of the type comprising a plurality of adiabatic catalytic beds connected in series, provides the step of flowing the gaseous reagents across at least one of the catalytic beds with substantially radial flow.

Abstract: A stabilizer for an aqueous aliphatic aldehyde solution comprising acetic acid, a halogenated acetic acid or a compound capable of releasing acetic acid or a halogenated acetic acid in water.

Abstract: Disclosed is a process to produce paraformaldehyde prills having a low dissolution time and low concentration of insoluble formation. The insolubles are believed to lead to stickiness, tackiness, and loss of flowability of the product, loss of handling, and lead to storage problems of the final prill product. To address this problem, a concentrated formaldehyde solution is prepared having a purity ranging from 37%-99% and may be mixed with an amine additive, an amine and alcohol additive, or amine, alcohol, and caustic additive. Alternatively, the final prill may be sprayed with an amine or amine mixture stabilizer.

Abstract: A process for preparing cyclocitral by expoxidizing a pyronene.

Abstract: The method uses a starting material which is a liquid mixture including a formaldehyde proportion between 48 to 55% by weight, a methanol proportion between 20 and 30% by weight and a water proportion between 32 and 15 wt %; the liquid mixture is obtained from a tapping which is effected from a plant for the continuous preparation of urea-formaldehyde resins and glues, immediately after having subjected the methanol to catalytic oxidation via air, condensation of the gases evolving from said catalytic oxidation and separation between condensed products and uncondensed gases. These solutions may be applied to formaldehyde reactions wherein it is of interest to reduce the amount of water present in conventional solutions and also to use the methanol for example as solvent for the final product obtained.

Abstract: The invention relates to a process for preparing dodecamethylenebismelamine (DMB) by reacting 2,4-diamino-6-chloro-1,3,5-triazine with 1,12-diaminododecane in an alkaline aqueous suspension, to which the diamine has been added in a water-miscible solvent. The product is used to stabilize aqueous formaldehye solutions.

Abstract: Novel compositions are disclosed consisting essentially of aldehydes of the structure R--CHO (wherein R is a C.sub.8 -C.sub.30 carbon radical) and about 0.1 to about 5 parts by weight of a triarylphosphine per 100 parts of aldehyde. In addition, a process for the recovery of essentially pure high boiling aldehyde by fractional distillation is provided wherein about 0.1 to about 5 parts by weight of a triarylphosphine per 100 parts of high boiling aldehyde is added to the aldehyde prior to distillation. Further, process for improving the high temperature storage stability of high boiling aldehydes is provided, which comprises adding about 0.1 to about 5 parts by weight of a triarylphosphine per 100 parts high boiling aldehyde to the aldehyde.

Abstract: An amino/phenolic composition effective for enhancing the storage stability of aldehydes, particularly sulfur-containing aliphatic aldehydes of low molecular weight, i.e., those containing from 3 to 10 carbon atoms.

Abstract: Deodorized formalin produced by mixing formalin with additives comprising methyl salicylate and ethanol or methanol. A desired mixing ratio of these components is required.

Abstract: Granular sorbent material comprising a granular high surface area support impregnated with a water soluble, essentially non-volatile primary or secondary amine with equivalent weight less than about 400 and bearing either zero or two carbonyl substituents attached directly to the amino nitrogen atom is disclosed. The resulting material can be used as the filtration media in respirators, powered air purifiers, room air purifiers, ventilation filters, exhaust filters, process gas filters and the like to reduce the formaldehyde content of air.

Abstract: The invention is a composition of matter and method for its use in reducing formaldehyde emission from wood composite panels bonded with aminoplast resins. The preferred composition comprises urea, a carbohydrate based material such as cooked or gelatinized starch, and an acidic catalyst for the resin. The ratio of urea to carbohydrate based material is in the range of 10:1 to 40:1 while the urea forms from 20-60% of the composition. In use, the composition is preferably sprayed on the wood particles, flakes or fiber in the blender at the same time resin is added. Typical usage is 0.4-3 parts, on a urea basis, added to each 100 parts of dry wood substance. Depending on several factors, the reduction in formaldehyde emission ranges from 60-90% without serious deterioration occurring in any other product physical properties.

Abstract: Stable aqueous suspensions of formaldehyde of at least 40% by weight concentration are prepared by heating aqueous formaldehyde solutions to a temperature of from about 40.degree. C. to about 80.degree. C. in the presence of stabilizing agents, in the presence or absence of methanol, and at a pH in the range of from about 0.5 to 1.5 or about 6.0 to about 8.0, cooling the mass to a temperature of from about 10.degree. C. to about 40.degree. C., and adjusting the pH thereof to about 3.0 to 4.0.

Abstract: There are described new bisguanamines of the formula ##STR1## where n is a number from 10 to 20 and their production. The bisguanamines are stabilizers for formaldehyde solutions and have outstanding qualifications and action for this purpose.

Abstract: The tendency of liquid paraformaldehyde containing water and paraformaldehyde in, for example, approximately 80% to approximately 90% concentration to precipitate solid paraformaldehyde therefrom is retarded by the incorporation thereinto of an effective amount of a moderator or stabilizer selected from the group consisting of polyacrylic acid, tartaric acid, dl-malic acid, ethylenediaminetetraacetic acid, and citric acid. The prior-art stabilizers known and used for lower-concentration formaldehyde solutions of, for example, about 50% strength are not effective. Conversely, the present moderators are not effective in the lower-concentration solutions.

Abstract: A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.

Abstract: Aqueous solutions of formaldehyde are stabilized against precipitation by the incorporation therein of 0.1 to 1000 p.p.m. of a low molecular weight vinyl polymer containing acetal, acetate, hydroxyl, and optionally, formal, propional or butyral groups. Preferably, the polymer is added to the formaldehyde solution as a methanol solution.