Boron Containing Catalyst Patents (Class 568/792)
  • Patent number: 8704006
    Abstract: A process for preparing an alkylated hydroxyl aromatic compound comprising reacting (a) a hydroxyl aromatic compound (I), having the following structure; wherein n 1, 2 or 3; m is 0, 1, 2, or 3 and R1 is Hydrogen or hydrocarbyl group; and (b) at least one ?-branched primary alcohol component in the presence of an alkylating catalyst thereby producing an alkylated hydroxyl aromatic compound.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: April 22, 2014
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Cedrick Mahieux
  • Patent number: 8247621
    Abstract: The invention relates to the preparation of alkylated phenols. More specifically, the invention relates to an improved process for the manufacture of 2-secondary-alkyl-4,5-di-normal-alkylphenols.
    Type: Grant
    Filed: October 12, 2009
    Date of Patent: August 21, 2012
    Assignee: Invista North America S.A.R.L.
    Inventors: Joachim C. Ritter, James Michael Garner
  • Patent number: 8207380
    Abstract: An alkylated hydroxyaromatic compound prepared by reacting at least one hydroxyaromatic compound with a branched olefinic oligomer having from about 20 to about 80 carbon atoms in the presence of a acid catalyst. The alkylated hydroxyaromatic compound has been determined to be substantially free of endocrine disruptive chemicals when the effects were quantified on pubertal development and thyroid function in the intact juvenile female rat.
    Type: Grant
    Filed: April 27, 2007
    Date of Patent: June 26, 2012
    Assignee: Chevron Oronite LLC
    Inventors: Curt B. Campbell, James J. Harrison
  • Patent number: 7767748
    Abstract: Aqueous polymer dispersions which are obtainable by emulsion polymerization of ethylenically unsaturated monomers in an aqueous medium in the presence of free radical polymerization initiators and stabilizers, amphiphilic polymers which comprise one or more hydrophobic units (A) and one or more hydrophilic units (B) being used as the stabilizer before, during or after the polymerization, and the hydrophobic units (A) being formed from a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged doubled bonds, processes for the preparation of the aqueous polymer dispersions by polymerizing ethylenically unsaturated monomers in the presence of free radical initiators and said amphiphilic polymers, which are used before, during or after the polymerization, and the use of the resulting aqueous polymer dispersions as associative thickeners in paper coating slips, in textile production, as thickeners for textile print pastes, in the pharmaceutical and cosmetics sector, for
    Type: Grant
    Filed: February 8, 2005
    Date of Patent: August 3, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold J. Leyrer, Ingolf Kuehn, Darijo Mijolovic
  • Patent number: 7750193
    Abstract: The present invention relates to a process for preparing 2-alkylpolyisobutenylphenols and their Mannich adducts, to compositions obtainable by this process and to their use.
    Type: Grant
    Filed: February 1, 2005
    Date of Patent: July 6, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt, Anja Vinckier
  • Patent number: 7435273
    Abstract: Alkoxylated alkylphenols which have at least one long-chain alkyl radical having at least one tertiary or quaternary carbon atom are prepared and are used as fuel or lubricant additives in fuel and lubricant compositions.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: October 14, 2008
    Assignee: Basf Aktiengesellschaft
    Inventors: Arno Lange, Hans Peter Rath, Marc Walter
  • Patent number: 6914163
    Abstract: Polyisobutenylphenols are prepared by alkylating an aromatic hydroxy compound with substantially monoethylenically unsaturated and substantially homopolymeric polyisobutenes in the presence of a Lewis acid alkylation catalyst by a process in which the polyisobutenes have a ? double bond content of at least 35 mol %.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: July 5, 2005
    Assignee: BASF AG
    Inventors: Arno Lange, Hans Peter Rath
  • Patent number: 6875897
    Abstract: Polyisobutenylphenols are prepared by alkylating an aromatic hydroxy compound with substantially monoethylenically unsaturated and substantially homopolymeric polyisobutenes in the presence of a Lewis acid alkylation catalyst by a process in which an ether is additionally used as a cocatalyst, the ether having a molecular weight of at least 102 g/mol in the case of BF3 as the Lewis acid.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: April 5, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Arno Lange, Hans Peter Rath
  • Patent number: 6274777
    Abstract: A method for removing boron from a boron trifluoride-catalyzed polyalkyl hydroxyaromatic reaction product which comprises: (a) diluting the polyalkyl hydroxyaromatic reaction product with an inert solvent to give a polyalkyl hydroxyaromatic reaction product concentration in the range of about 40 to about 80 weight percent; (b) filtering the diluted polyalkyl hydroxyaromatic reaction product in the presence of a filter aid in combination with (1) magnesium silicate, (2) water or (3) a mixture of magnesium silicate and water; wherein the water is present during filtration at a concentration of about 100 to 1,500 ppm, based on the diluted polyalkyl hydroxyaromatic reaction product; with the proviso that when water is used in the absence of magnesium silicate, the filter aid is diatomaceous earth; and (c) recovering a filtrate containing the diluted polyalkyl hydroxyaromatic reaction product having less than about 10 ppm of boron present.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: August 14, 2001
    Assignees: Chevron Chemical Company LLC, Chevron Chemical S.A.
    Inventors: James A. Gray, Thierry Triconnet
  • Patent number: 5663457
    Abstract: Conventional low vinylidene polyolefins are condensed with hydroxyaromatics under the influence of macroreticular ion exchange resins in acid form to yield alkylated hydroxyaromatics.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: September 2, 1997
    Assignee: The Lubrizol Corporation
    Inventor: Christopher Jay Kolp
  • Patent number: 5345002
    Abstract: The present invention is directed to oil-soluble lubricating oil additives comprising Mannich Base condensates of an alkyl substituted hydroxy aromatic compound with formaldehyde and an amine, wherein the alkyl-moiety of the aromatic compounds is derived from at least one ethylene alpha-olefin copolymer of 300 to 20,000 number average molecular weight, wherein at least about 30% of the polymer's chains contain terminal ethenylidene unsaturation. The Mannich Base condensates of this invention are useful as dispersants.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: September 6, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Won R. Song, Robert D. Lundberg, Antonio Gutierrez, Robert A. Kleist
  • Patent number: 5300701
    Abstract: A process for the preparation of a polyisobutyl hydroxyaromatic compound which comprises alkylating a hydroxyaromatic compound in the presence of an acidic alkylation catalyst with a polyisobutene having a number average molecular weight in the range of about 300 to 5,000 and wherein the polyisobutene contains at least about 70% of a methylvinylidene isomer.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: April 5, 1994
    Assignee: Chevron Research and Technology Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5144082
    Abstract: It is disclosed that aromatic compounds can be alkylated with mono-olefinic HVI-PAO dimer in contact with an acidic catalyst to produce novel alkylated aromatic compositions. It has been found that the novel HVI-PAO dimer alkylated aromatic compositions exhibit an extraordinary combination of properties relating to low viscosity with high viscosity index and low pour point which renders them very useful as lubricant basestock. Further, it has been found that the novel alkylaromatic compositions of the present invention show improved oxidative stability. Depending upon the substituent groups on the aromatic nucleus, useful lubricant additives can be prepared for improved antiwear, antioxidant and other properties. HVI-PAO dimer is prepared as a product or by-product from 1-alkene oligomerization using reduced chromium oxide on solid support. Particularly disclosed are the alkylphenols prepared by the process of alkylation a phenol at the aromatic nucleus with the novel oligomer.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: September 1, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Bruce P. Pelrine
  • Patent number: 4912264
    Abstract: Process for producing hydroxy-containing alkylated aromatic compounds by the liquid phase reaction of an aromatic compound having at least one hydroxyl group with an alkylating agent in the presence of a heteropoly acid and water.
    Type: Grant
    Filed: June 3, 1987
    Date of Patent: March 27, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Akira Takeshita, Shinzaburo Masaki, Takeo Fujii, Tooru Tokumaru, Akira Murakami
  • Patent number: 4385191
    Abstract: Drastic molecular weight degradation of a p-(polybutyl-substituted phenol occurs when it is heated above 65.degree. C. in the presence of BF.sub.3 -phenolate catalyst used in the preparation of said substituted phenol by the alkylation of phenol with a butylene polymer of 500 to 3000 molecular weight. Such molecular weight degradation can be substantially suppressed by providing 20 to 30 weight percent dissolved phenol in the mixture resulting from such catalytic alkylation reaction and then rapidly heating the mixture with such amount of dissolved phenol to a temperature of from 182.degree. C. up to 200.degree. C. at extant atmospheric pressure whereat the catalyst dissociates and liberated BF.sub.3 is stripped out by phenol vapors.
    Type: Grant
    Filed: December 19, 1979
    Date of Patent: May 24, 1983
    Assignee: Standard Oil Company (Indiana)
    Inventors: Dennis G. Petrille, Chester G. Gunter, Frederick S. Jerome
  • Patent number: 4283514
    Abstract: Butylation of a mixture of xylenols and trimethylphenols gives a product which is suitable for use as a stabilizer for polyvinyl chloride. The material can be added to the reactor during polymerization as a shortstopper and retain effectiveness as a stabilizer in the finished polymer.
    Type: Grant
    Filed: August 22, 1979
    Date of Patent: August 11, 1981
    Assignee: Conoco, Inc.
    Inventors: Dean R. Weimer, Charles M. Starks
  • Patent number: 4267394
    Abstract: A process for selectively alkylating a phenolic compound in the ortho-position which comprises reacting a phenolic compound with an alkanol in the presence of a boron trifluoride etherate catalyst and optionally in the presence of a solvent such as aqueous and non-aqueous inorganic acids.
    Type: Grant
    Filed: March 23, 1979
    Date of Patent: May 12, 1981
    Assignee: Phillips Petroleum Company
    Inventor: Robert M. Parlman
  • Patent number: 4238628
    Abstract: Process for the production of undegraded alkylated aromatic compounds by alkylating an aromatic compound with a C.sub.3 or higher olefin polymer having terminal ethylene units.
    Type: Grant
    Filed: September 28, 1978
    Date of Patent: December 9, 1980
    Assignee: Standard Oil Company (Indiana)
    Inventors: Paul J. Cahill, Carl E. Johnson
  • Patent number: 4229598
    Abstract: Butylation of a mixture of xylenols and trimethylphenols gives a product which is suitable for use as a stabilizer for polyvinyl chloride. The material can be added to the reactor during polymerization as a short-stopper and retain effectiveness as a stabilizer in the finished polymer.
    Type: Grant
    Filed: December 14, 1978
    Date of Patent: October 21, 1980
    Assignee: Conoco, Inc.
    Inventors: Dean R. Weimer, Charles M. Starks
  • Patent number: RE34076
    Abstract: Process for producing hydroxy-containing alkylated aromatic compounds by the liquid phase reaction of an aromatic compound having at least one hydroxyl group with an alkylating agent in the presence of a heteropoly acid and water.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: September 22, 1992
    Assignee: Sumitomo Chemical Company Limited
    Inventors: Akira Takeshita, Shinzaburo Masaki, Takeo Fujii, Tooru Tokumaru, Akira Murakami