Using Transition Metal-containing Catalyst Patents (Class 585/275)
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Patent number: 10829700Abstract: This invention has as its object a method for selective hydrogenation of a feedstock comprising a pyrolysis gasoline carried out in a three-phase reactor.Type: GrantFiled: June 22, 2017Date of Patent: November 10, 2020Assignee: IFP ENERGIES NOUVELLESInventors: Cyprien Charra, Vincent Coupard, Jeremy Gazarian, Adrien Mekki-Berrada, Jean-Marc Schweitzer
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Patent number: 9040766Abstract: The invention relates to a method for the manufacture of branched saturated hydrocarbons, said method comprising the steps where a feed comprising olefins having at least 10 carbons is simultaneously hydrogenated and isomerized in the presence of hydrogen at a temperature of 100-400° C., under hydrogen partial pressure of 0.01-10 MPa, in the presence of a catalyst comprising a metal selected from the metals of Group VIIIb of the Periodic Table of Elements, a molecular sieve selected from ten member ring molecular sieves, twelve member ring molecular sieves and mesoporous molecular sieves embedded with zeolite, and a carrier, to yield branched saturated hydrocarbons.Type: GrantFiled: May 18, 2010Date of Patent: May 26, 2015Assignee: NESTE OIL OYJInventors: Mika Kettunen, Vaino Sippola, Marja Tiitta
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Patent number: 9040757Abstract: In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.Type: GrantFiled: March 8, 2013Date of Patent: May 26, 2015Assignee: PIONEER ENERGYInventors: John Henri, Jan Zygmunt, Mark Bergren, Robert Zubrin
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Publication number: 20150104364Abstract: The present disclosure is directed to processes using a new crystalline molecular sieve designated SSZ-96, which is synthesized using a 1-butyl-1-methyl-octahydroindolium cation as a structure directing agent.Type: ApplicationFiled: May 21, 2014Publication date: April 16, 2015Applicant: CHEVRON U.S.A. INC.Inventor: Saleh Ali ELOMARI
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Patent number: 8993818Abstract: Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A self-sustainable process was designed to reduce the coke by co-feeding sugars/sugar derivatives with the paraffin products from hydrogenation of sugars/sugar derivatives. Paraffins without complete conversion result in products with less aromatics and relatively low density compared with the products directly from zeolite upgrading. Thus, the process is more economically favorable.Type: GrantFiled: August 22, 2011Date of Patent: March 31, 2015Assignee: Phillips 66 CompanyInventors: Yun Bao, Edward L. Sughrue, II, Jianhua Yao, TiePan Shi, Kristi A. Fjare, Lisa L. Myers
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Patent number: 8975460Abstract: A process is proposed for preparing acetylene by the Sachsse-Bartholomé process by combustion of a natural gas/oxygen mixture in one or more burners to obtain a cracking gas which is cooled in two or more stages in burner columns, each burner having one or more burner columns assigned thereto, and said cracking gas being quenched with pyrolysis oil in the first cooling stage, to obtain a low boiler fraction comprising benzene, toluene and xylene from the one or more burner columns, which is cooled with direct cooling water and separated in a phase separator into an aqueous phase and an organic phase which comprises benzene, toluene and xylene and is fully or partly introduced to the top of the one or more burner columns as a return stream, wherein the organic phase comprising benzene, toluene and xylene from the phase separator, prior to full or partial recycling to the top of the one or more burner columns, is supplied to a selective hydrogenation over a catalyst which comprises at least one platinum group mType: GrantFiled: July 15, 2011Date of Patent: March 10, 2015Assignee: BASF SEInventors: Lucia Königsmann, Maximilian Vicari, Thomas Heidemann, Dirk Groβschmidt, Jürgen Michel
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Patent number: 8962905Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least one hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio.Type: GrantFiled: September 7, 2011Date of Patent: February 24, 2015Assignee: IFP Energies NouvellesInventors: Thierry Chapus, Nathalie Dupassieux, Antoine Daudin
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Publication number: 20150045600Abstract: The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.Type: ApplicationFiled: October 28, 2014Publication date: February 12, 2015Applicant: ExxonMobil Research and Engineering CompanyInventors: Pallassana S. Venkataraman, Gordon F. Stuntz, Jonathan Martin McConnachie, Faiz Pourarian
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Patent number: 8946110Abstract: The invention relates to a method of preparing a catalytic composition comprising at least one non-noble metal from group VIII and at least one metal from group VIB of the periodic table. The invention also relates to the catalytic composition thus produced, which has a high specific activity in reactions involving the hydroprocessing of light and intermediate fractions, preferably in reactions involving the hydrotreatment of hydrocarbon streams, including hydrodesulphurization (HDS), hydrodenitrogenation (HDN) and hydro-dearomatization (HDA).Type: GrantFiled: August 22, 2006Date of Patent: February 3, 2015Assignee: Instituto Mexicano del PetroleoInventors: José Antonio Toledo Antonio, Miguel Pérez Luna, María Antonia Cortés Jacome, José Escobar Aguilar, María de Lourdes Mosqueira Mondragón, Carlos Angeles Chávez, Esteban López Salinas, Víctor Pérez Moreno, Gerardo Ferrat Torres, Rodolfo Juventino Mora Vallejo, Marcelo Lozada y Cassou
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Publication number: 20150018201Abstract: The invention is directed to a process for producing carbon nanofibers and/or carbon nanotubes, which process comprises pyrolysing a particulate cellulosic and/or carbohydrate substrate that has been impregnated with a compound of an element or elements, the metal or alloy, respectively, of which is capable of forming carbides, in a substantially oxygen free, volatile silicon compound containing atmosphere, optionally in the presence of a carbon compound.Type: ApplicationFiled: September 12, 2014Publication date: January 15, 2015Applicant: BASF CORPROATIONInventors: Jacobus Hoekstra, John Wilhelm Jenneskens
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Patent number: 8912377Abstract: The present invention relates to a method of producing aromatic products (benzene/toluene/xylene) and olefin products from petroleum fractions obtained by fluid catalytic cracking, and, more particularly, to a method of producing products comprising high-concentration aromatic products and high value-added light olefin products from light cycle oil obtained by fluid catalytic cracking.Type: GrantFiled: October 7, 2009Date of Patent: December 16, 2014Assignee: SK Innovation Co., Ltd.Inventors: Cheol Joong Kim, Tae Jin Kim, Do Woan Kim, Sung Won Kim, Sang Hun Oh, Sam Ryong Pakr, Seung Hoon Oh, Yoon Kyung Lee, Gyung Rok Kim, Hong Seok Jung, Eun Kyoung Kim, Byoung In Lee, Dae Hyun Choo
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Patent number: 8895791Abstract: The present invention relates to a method of regenerating a ruthenium catalyst suitable for hydrogenation, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained. The method is particularly useful for ruthenium catalysts which are used for the hydrogenation of aromatics.Type: GrantFiled: July 18, 2007Date of Patent: November 25, 2014Assignee: BASF SEInventors: Jochem Henkelmann, Michael Becker, Daniela Mirk, Felix Richter, Thomas Schäfer
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Patent number: 8889936Abstract: The present patent application describes a method of regenerating a ruthenium catalyst for the hydrogenation of benzene, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained.Type: GrantFiled: July 27, 2007Date of Patent: November 18, 2014Assignee: BASF SEInventors: Jochem Henkelmann, Michael Becker, Michael Schönherr, Wilhelm Ruppel, Ulrike Wegerle, Bianca Stäck
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Patent number: 8822746Abstract: The present invention relates to a process for the hydrogenation, in particular the selective hydrogenation of unsaturated hydrocarbon compounds, such as the selective hydrogenation of acetylene to ethylene, using a hydrogenation catalyst comprising an ordered intermetallic compound, namely an ordered cobalt-aluminum or iron-aluminum intermetallic compound. According to another aspect, the present invention relates to a catalyst comprising a support and at least one specific ordered cobalt-aluminum and/or iron-aluminum intermetallic compound supported thereon, as well as to the use of specific ordered intermetallic cobalt-aluminum and iron-aluminum intermetallic compounds as catalysts. The ordered cobalt-aluminum and iron-aluminum intermetallic compounds proved to be highly selective and long-term stable catalysts, e.g. in the selective hydrogenation of acetylene to ethylene in a large excess of ethylene.Type: GrantFiled: March 22, 2010Date of Patent: September 2, 2014Assignees: Max-Planck-Gesellschaft zur Foerderung der Wissenschaften E.V., Ludwig-Maximilians-Universitaet Munich, Forschungszentrum Juelich GmbHInventors: Marc Armbruster, Kirill Kovnir, Juri Grin, Robert Schlogl, Peter Gille, Marc Heggen, Michael Feuerbacher
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Publication number: 20140121427Abstract: The present invention is directed to the activation of metal carbonyl clusters by an oxidative agent to prepare a stable metal cluster catalyst exhibiting catalytic rate enhancement. The activation comprises, for example, using oxygen for decarbonylation of carbonyl ligands and changing the oxidation state of the other ligands. In one aspect, treatment of the metal cluster catalyst under oxidative conditions in a flow reactor leads to removal of CO ligands and oxidation of bound calixarene phosphine ligands, and results in a stable activated open metal cluster that is more active for ethylene hydrogenation catalysis. The resulting metal cluster contains coordinatively unsaturated sites comprising carbonyl vacancies. In one aspect, the resulting activated open metal cluster can be used as a catalyst in a variety of chemical transformations.Type: ApplicationFiled: October 28, 2013Publication date: May 1, 2014Applicant: The Regents of the University of CaliforniaInventors: Alexander Katz, Ron C. Runnebaum, Alexander Okrut, Xiaoying Ouyang, Igor Busygin
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Publication number: 20140066674Abstract: A new family of coherently grown composites of TUN and IMF zeotypes have been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to TNU-9 and IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.Type: ApplicationFiled: November 7, 2013Publication date: March 6, 2014Applicant: UOP LLCInventors: Christopher P. Nicholas, Mark A. Miller
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Patent number: 8664459Abstract: A process for hydrogenating olefins is disclosed. The olefins are present in a feed gas which includes H2 and one or more sulfur compounds. The sulfur compounds may include H2S and organic sulfur compounds. The feed gas is passed through a reactor at an inlet temperature from 100° C. to 250° C. The reactor contains a catalyst which is active at the inlet temperature. The reactor may be adiabatic. Saturated hydrocarbons are formed from the olefins. A temperature gradient may be formed in the reactor due to the exothermic nature of the hydrogenation reaction, causing the temperature to increase downstream in the reactor. At temperatures higher than the inlet temperature, H2S may be formed from organic sulfur compounds. A gas mixture including saturated hydrocarbons, H2S and H2 exits the reactor and may be brought into contact with a chemical adsorbent which removes the H2S. The gas stream may then be passed to a steam methane reformer.Type: GrantFiled: November 4, 2008Date of Patent: March 4, 2014Assignees: Air Products and Chemicals, Inc., Johnson Matthey PLCInventors: Ruth A. Davis, Norman Macleod, Gordon Edward Wilson
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Publication number: 20130310617Abstract: Processes and systems for stabilization and subsequent hydrogenation of an immiscible olefin are described. In certain embodiments, the hydrogenation is conducted in a fixed bed reactor in presence of a hydrogenation catalyst.Type: ApplicationFiled: July 25, 2013Publication date: November 21, 2013Applicant: AMYRIS, INC.Inventors: Nicholas L. Ohler, Roberto Vazquez
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Publication number: 20130281747Abstract: Disclosed herein are manganese, iron, nickel, or cobalt compounds having a bidentate ligand and the use of these compounds for the hydrogenation of alkenes, particularly the asymmetric hydrogenation of prochiral olefins.Type: ApplicationFiled: March 15, 2013Publication date: October 24, 2013Inventors: Paul CHIRIK, Jordan M. Hoyt, Max R. Friedfeld
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Publication number: 20130230721Abstract: A method for producing a catalyst using an additive layer method includes: (i) forming a layer of a powdered catalyst or catalyst support material, (ii) binding or fusing the powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit.Type: ApplicationFiled: August 22, 2011Publication date: September 5, 2013Applicant: JOHNSON MATTHEY PLCInventor: Duncan Roy Coupland
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Patent number: 8519207Abstract: The present invention relates to a process for the hydrogenation, in particular selective hydrogenation of at least one unsaturated hydrocarbon compound comprising reacting the at least one unsaturated hydrocarbon compound with hydrogen in the presence of a hydrogenation catalyst, wherein the hydrogenation catalyst comprises a mixture of an ordered intermetallic compound and an inert material. According to another aspect, the present invention is concerned with the use of a mixture of at least one ordered intermetallic compound and at least one inert material, as a catalyst. The mixtures for use as a catalyst in the present invention can be prepared easily and achieve a superior activity in relation to the prior art, while preserving the high selectivity to the target compounds, e.g. in the selective hydrogenation of acetylene to ethylene.Type: GrantFiled: September 18, 2008Date of Patent: August 27, 2013Assignee: Max-Planck-Gesellschaft zur Förderung der Wissenschaften E.V.Inventors: Marc Armbruester, Marcus Schmidt, Kirill Kovnir, Matthias Friedrich, Karina Weinhold, Juri Grin, Robert Schloegl
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Publication number: 20130204055Abstract: A selective hydrogenation process that is particularly effective in selectively hydrogenating alkynl compounds, such as acetylene or methyl acetylene, over alkenyl compounds, such as ethylene, is described. The process utilizes a slurry conversion unit for heat efficiency purposes during the conversion of acetylene into ethylene.Type: ApplicationFiled: August 9, 2012Publication date: August 8, 2013Inventors: S. Mark Davis, Paul F. Keusenkothen, Charles J. Mart
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Publication number: 20130184411Abstract: High strength presulfided catalyst for hydrogenating hydrocarbon resins without an in situ sulfiding step. The catalyst particles have a supported metal catalyst structure with presulfided interstitial surfaces with about 20 weight percent of a low molecular weight hydrocarbon resin, based on the weight of the porous supported metal catalyst structure, filling from 90 to 95 percent of the pore volume to improve a crush strength of the catalyst particles. The presulfided catalyst can be stored and/or shipped in an airtight container with an inert atmosphere. The catalyst particles are made by preparing the oxidized catalyst, presulfiding the catalyst, contacting the catalyst with the low molecular weight hydrocarbon resin in an inert atmosphere, sealing the catalyst in a storage/shipping container, loading the reactor with the presulfided, filled catalyst, and contacting the catalyst with an unsaturated hydrocarbon resin under hydrogenation conditions.Type: ApplicationFiled: January 17, 2012Publication date: July 18, 2013Applicant: ExxonMobil Chemical Patents Inc.Inventors: Jose M. Vargas, Thomas R. Barbee, Yuan-Ju Chen
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Patent number: 8487150Abstract: In the process for hydrogenating butadiyne over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as a support, the hydrogenation is performed at a pressure in the range from 1 to 40 bar and a temperature in the range from 0 to 100° C., and from 0.05 to 5% by weight, based on the overall catalyst, of platinum group metal is present on the support.Type: GrantFiled: June 16, 2009Date of Patent: July 16, 2013Assignee: BASF SEInventors: Lucia Koenigsmann, Ekkehard Schwab, Piotr Makarczyk, Kai Rainer Ehrhardt, Maximilian Vicari, Thomas Heidemann, Dirk Grossschmidt, Gerrit Waters
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Patent number: 8450543Abstract: Isobutene, isoprene, and butadiene are obtained from mixtures of C4 and/or C5 olefins by dehydrogenation. The C4 and/or C5 olefins can be obtained by dehydration of C4 and C5 alcohols, for example, renewable C4 and C5 alcohols prepared from biomass by thermochemical or fermentation processes. Isoprene or butadiene can be polymerized to form polymers such as polyisoprene, polybutadiene, synthetic rubbers such as butyl rubber, etc. in addition, butadiene can be converted to monomers such as methyl methacrylate, adipic acid, adiponitrile, 1,4-butadiene, etc. which can then be polymerized to form nylons, polyesters, polymethylmethacrylate etc.Type: GrantFiled: January 7, 2011Date of Patent: May 28, 2013Assignee: Gevo, Inc.Inventors: Matthew W. Peters, Joshua D. Taylor, David E. Henton, Leo E. Manzer, Patrick R. Gruber, Josefa M. Griffith, Yassin Al Obaidi
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Publication number: 20130102819Abstract: This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of ?9 m2/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.Type: ApplicationFiled: October 19, 2011Publication date: April 25, 2013Inventors: Normen Szesni, Alfred Hagemeyer, Frank Grossmann, Richard Fischer, Michael Urbancic, Claus Lugmair, Mingyong Sun, Hongyi C. Hou, David Michael Lowe
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Patent number: 8395003Abstract: The object of this invention is a suspension of metal nanoparticles with a mean size of between 1 and 20 nanometers, in at least one non-aqueous ionic liquid, whereby said suspension also contains at least one nitrogen-containing ligand, in which said metal nanoparticles comprise at least one transition metal in the zero valence state that is selected from among rhodium, ruthenium, iridium, nickel, and platinum by themselves or in a mixture and in which said nitrogen-containing ligand is selected from the group that is formed by the linear compounds that comprise at least one nitrogen atom, whereby the non-aromatic cyclic compounds comprise at least one nitrogen atom, the non-condensed aromatic compounds comprise at least one nitrogen atom, the condensed aromatic compounds comprise at least one group of two aromatic cycles that are condensed two by two, and at least one nitrogen atom, whereby the condensed aromatic compounds comprise at least 3 aromatic cycles and 1 nitrogen atom, and whereby the condensed arType: GrantFiled: April 14, 2008Date of Patent: March 12, 2013Assignee: IFP Energies NouvellesInventors: Bastien Leger, Alain Roucoux, Helene Olivier-Bourbigou
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Patent number: 8389781Abstract: The catalyst comprises at least a metal component and at least a non-metallic conducting component as supplement component. The metal component generally contains one or more metals of the groups VIb, VIIb or VIIIb of the periodic table. The supplement component is e.g. a conducting carbon material like graphite, a conducting polymer or a conducting metal oxide. Preferably it is hydrophobic or made hydrophobic. The catalyst is used for hydroprocessing of bio-feedstock like vegetable oils to produce fuels, which are aliphatic hydrocarbons comparable to conventional fuel from mineral oil.Type: GrantFiled: June 24, 2009Date of Patent: March 5, 2013Assignee: Aggregate Energy, LLCInventors: Gerd Sandstede, Thomas Lehmann
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Patent number: 8383872Abstract: The disclosed invention relates to a process for conducting a multiphase reaction in a microchannel. The process comprises: forming a multiphase reaction mixture comprising a first reactant and a second reactant; the first reactant comprising at least one liquid; the second reactant comprising at least one gas, at least one liquid, or a combination of at least one gas and at least one liquid; the first reactant forming a continuous phase in the multiphase reaction mixture; the second reactant forming gas bubbles and/or liquid droplets dispersed in the continuous phase; and reacting the first reactant with the second reactant in a process microchannel in the presence of at least one catalyst to form at least one product.Type: GrantFiled: November 16, 2005Date of Patent: February 26, 2013Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, David John Hesse, Paul Neagle, Micheal Jay Lamont, Francis P. Daly, Kai Tod Paul Jarosch, Richard Stevenson, Laura J. Silva
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Patent number: 8338654Abstract: Selective hydrogenation of unsaturated hydrocarbon compounds, e.g. of acetylene to ethylene, uses a hydrogenation catalyst comprising an ordered intermetallic compound. The ordered intermetallic compound comprises at least one metal of type A capable of activating hydrogen, and at least one metal of type B not capable of activating hydrogen. The structure of the ordered intermetallic compound is such that the type A metal is mainly surrounded by atoms of the type B metal.Type: GrantFiled: March 15, 2007Date of Patent: December 25, 2012Assignee: Max-Planck-Gesellschaft zur Foerderung der Wissenschaften E.V.Inventors: Rainer Giedigkeit, Marc Armbruester, Kirill Kovnir, Juri Grin, Robert Schloegl, Juergen Osswald, Thorsten Kessler, Rolf E. Jentoft
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Publication number: 20120238792Abstract: The invention is a process for the production of a hydrocarbon product including contacting an oxygenated aromatic feedstock, in the presence of hydrogen, with a catalyst composition including: a) a metal hydrogenation catalyst and b) a solid acid catalyst which is active for the deoxygenation of oxygenated hydrocarbons. The process is useful for the conversion of pyrolysis oils and other products derived from biomass and plastics recycling etc, into fuels and chemical feedstocks.Type: ApplicationFiled: July 29, 2010Publication date: September 20, 2012Applicant: JOHNSON MATTHEY PLCInventors: Michael John Watson, David Davis, Emily Fairnington Douglas
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Publication number: 20120209042Abstract: The invention provides a process for selective hydrogenation of alkynes and other unsaturated hydrocarbons, such as acetylene and diolefins, with a catalyst comprising Pd and, optionally, at least one metal from the IA, IB, IIIA, IIIB, VB, or VIIIB Groups, where the metals are supported on a porous material, such as titania. If the process is in the absence of carbon monoxide (CO) in the feed, at least one metal from the IA, IB or IIIA Groups should be present in the catalyst, e.g., potassium, boron or silver. If the carbon monoxide (CO) is present in the feed, the catalyst consists essentially of Pd supported on a porous material, such as titania.Type: ApplicationFiled: February 10, 2011Publication date: August 16, 2012Applicant: Saudi Basic Industries CorporationInventors: Edouard Mamedov, Jillian Horn, Jim Allman, Armando Araujo, Meghann Simmons
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Patent number: 8242318Abstract: Catalytic hydrogenation of a double bond, notably a C?C or C?N double bond, is carried out using a homogenous catalyst which is a complex of rhodium or other transition metal containing at least one ligand which is a nitrogenous organic base. Preferably the complex is phosphorus-free and the ligand is a bicyclic base having formula where R1 and R4 are hydrocarbon chains. R1 preferably is a saturated chain of two carbon atoms and R4 preferably is a saturated chain of three to five carbon atoms.Type: GrantFiled: December 3, 2009Date of Patent: August 14, 2012Assignee: Schlumberger Technology CorporationInventors: Li Jiang, Timothy Jones, Fenglou Zou
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Patent number: 8207386Abstract: Rubber-like or rubber-like-material-containing articles contain or are made from hydrogenated natural polyisoprenoids or modified products thereof. These rubber-like or rubber-like-material-containing articles include a rubber-like elastic article made from a hydrogenated natural polyisoprenoid or a modified product thereof. A polymer obtained by reacting a natural polyisoprenoid with hydrogen in a solvent in the presence of a hydrogenation catalyst, for example, can be used as the hydrogenated natural polyisoprenoid. The hydrogenated natural polyisoprenoid preferably has a degree of hydrogenation of 50% or more. The hydrogenated natural polyisoprenoid preferably has a weight-average molecular weight of 20×104 or more and a molecular-weight distribution of 2.0 or more. The rubber-like or rubber-like-material-containing articles have excellent heat resistance and weather resistance, and are also excellent in view of resources and environment, because they use plant-derived raw materials.Type: GrantFiled: December 1, 2004Date of Patent: June 26, 2012Assignees: Nitta Corporation, Shinichi InoueInventors: Shinichi Inoue, Tomohiro Nishio, Haruhiko Ito, Kenichi Horiuchi, Toshiaki Kasazaki
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Publication number: 20120142984Abstract: This invention relates to a method for processing oxygenated hydrocarbons to form a hydroisomerized and/or dewaxed hydrocarbon product having a reduced oxygen content, an increased iso-paraffin content, a low n-paraffin content, and good cold flow properties. Advantageously, the method can utilize a zeolitic base catalyst, optionally but preferably containing at least one activated metal component, and a hydrothermally-stable binder such as titania.Type: ApplicationFiled: November 22, 2011Publication date: June 7, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Virginia M. ROBERTS, Michel DAAGE, William J. NOVAK
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Patent number: 8178735Abstract: A process for the treatment of an olefinic fraction, using a catalyst prepared by a process comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 by the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air.Type: GrantFiled: April 25, 2011Date of Patent: May 15, 2012Assignee: IFP Energies nouvellesInventors: Vincent Coupard, Denis Uzio, Carine Petit-Clair, Lars Fischer, Frederic Portejole
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Patent number: 8163171Abstract: The invention relates to hydrocarbon fluids having high purity with respect to at least one of sulfur species, nitrogen species, oxygenated species, and unsaturated species, particularly hydrocarbon fluids low in aromatics, a method of making said hydrocarbon fluids, a catalyst for use in said method, an apparatus whereby said method may be practiced, and uses of said fluids.Type: GrantFiled: December 19, 2005Date of Patent: April 24, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Thomas Andrew Gribschaw, Sylvain Hantzer, Stephen John McCarthy, Steven E. Silverberg, Vijay Swarup
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Patent number: 8158837Abstract: The present invention relates to a method for selective hydrogenation of acetylene to ethylene, comprising the steps of: i) introducing a feed comprising acetylene and hydrogen into a reactor containing a supported catalyst, wherein the reactor is a fixed bed reactor containing the supported catalyst additionally diluted with a solid diluent, or the reactor being a wash coated reactor wherein the supported catalyst is coated on reactor walls; and ii) hydrogenating of acetylene to ethylene in the presence of the supported catalyst.Type: GrantFiled: April 6, 2006Date of Patent: April 17, 2012Assignee: Saudi Basic Industries CorporationInventors: Agaddin Mamadov, Saeed Al-Wahabi, Akram Al-Alwan
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Patent number: 8128805Abstract: A catalyst for the hydrogenation, hydroisomerisation, hydrocracking and/or hydrodesulfurisation, of hydrocarbon feedstocks, the catalyst consisting of a substantially binder free bead type support material obtained through a sol-gel method, and a catalytically active component selected from precious metals, the support comprising 5 to 50 wt. % of at least one molecular sieve material and 50 to 95 wt. % of silica-alumina.Type: GrantFiled: April 18, 2001Date of Patent: March 6, 2012Assignee: BASF CorporationInventor: Marius Vaarkamp
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Publication number: 20110250122Abstract: The present invention provides a core-shell nanoparticle that includes a metal-oxide shell and a nanoparticle. Pores extend from an outer surface to an inner surface of the shell. The inner surface of the shell forms a void, which is filled by the nanoparticle. The pores allow gas to transfer from outside the shell to a surface of the nanoparticle. The present invention also provides a method of making a core-shell nanoparticle includes forming a metal-oxide shell on a colloidal nanoparticle, which forms a precursor core-shell nanoparticle. A capping agent is removed from the precursor core-shell nanoparticle, which produces the core-shell nanoparticle. The present invention also provides a method of using a nanocatalyst of the present invention includes providing the nanocatalyst, which is the core-shell nanoparticle. Reactants are introduced in a vicinity of the nanocatalyst, which produces a reaction that is facilitated or enhanced by the nanocatalyst.Type: ApplicationFiled: November 3, 2009Publication date: October 13, 2011Applicant: The Regents of the University of CaliforniaInventors: Sang Hoon Joo, Jeong Young Park, Chia-Kuang Tsung, Peidong Yang, Gabor A. Somorjai
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Patent number: 8026402Abstract: A high shear mechanical device incorporated into a process and system for the production of cyclohexane is capable of decreasing mass transfer limitations, thereby enhancing the cyclohexane production process. A system for the production of cyclohexane from benzene and hydrogen, the system comprising a reactor, solid catalyst, and a high shear device, the outlet of which is fluidly connected to the inlet of the reactor; the high shear device capable of providing an emulsion of hydrogen gas bubbles within a liquid comprising benzene, the bubbles having an average bubble diameter of less than about 100 ?m.Type: GrantFiled: June 12, 2008Date of Patent: September 27, 2011Inventors: Abbas Hassan, Ebrahim Bagherzadeh, Rayford G. Anthony, Gregory Borsinger, Aziz Hassan
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Patent number: 8013197Abstract: A method for the absorption of alkynes and diolefins from an ethylene or propylene containing stream with conversion to alkenes by catalytic hydrogenation in a solvent over a fixed bed comprising a supported catalyst.Type: GrantFiled: February 2, 2006Date of Patent: September 6, 2011Assignee: Synfuels International, Inc.Inventors: Edward R. Peterson, Sean C. Gattis
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Publication number: 20110201857Abstract: The invention relates to a process for the preparation of a catalyst comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 that consists in the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air. The invention also relates to a process for the treatment of an olefinic fraction that uses the catalyst prepared said preparation process.Type: ApplicationFiled: April 25, 2011Publication date: August 18, 2011Inventors: Vincent Coupard, Denis Uzio, Carine Petit-Clair, Lars Fischer, Frederic Portejoie
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Publication number: 20110190557Abstract: In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.Type: ApplicationFiled: December 14, 2010Publication date: August 4, 2011Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Chris E. Kliewer, Stuart L. Soled, Sabato Miseo, Jeffrey S. Beck
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Patent number: 7927480Abstract: A process for the desulfurization of a fluid catalytically cracked naphtha wherein the valuable olefins are retained and recombinant mercaptans are prevented from forming, resulting in a low sulfur naphtha. Embodiments disclosed herein may allow for more flexibility in varying the end point of the naphtha used in gasoline blending.Type: GrantFiled: January 29, 2008Date of Patent: April 19, 2011Assignee: Catalytic Distillation TechnologiesInventor: Gary G. Podrebarac
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Publication number: 20110046423Abstract: Conversion of renewable hydrocarbons to transportation fuels is required to reduce carbon emission, limit the use of fossil fuels, and develop renewable energy sources. Sorbitol, xylitol and trehelose are polyalcohols generated from the liquefaction of various sugars and carbohydrates in biomass from algae, corn, sugarcane, switchgrasses, and biological wastes. Mixtures of aqueous polyols and fuel feedstocks are catalyzed over metal catalysts to produce hexanes, pentanes, and lighter hydrocarbons. By managing the catalyst, reaction conditions and sulfur content, the octane value of the product fuel is dramatically increased.Type: ApplicationFiled: August 3, 2010Publication date: February 24, 2011Applicant: CONOCOPHILLIPS COMPANYInventors: Edward L. SUGHRUE, Jianhua YAO
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Publication number: 20110021852Abstract: A hydrogenation catalyst system is provided. The catalyst system includes a metal complex of Formula (I), an organic lithium compound and an organic compound having a cyclic structure including at least one double bond. In Formula (I), M is transition metals. R1, R2, R3, R4 and R5 are the same or different, including hydrogen, C1-8 alkyl, and C1-8 alkoxy, or two of R1, R2, R3, R4 and R5 are linked together to form a ring. X1, X2 and X3 are a cyclic group, hydrogen, chlorine, bromine, alkyl or alkoxy, wherein when one of X1, X2 and X3 is a cyclic group, and the others are the same or different, including hydrogen, chlorine, bromine, alkyl or alkoxy. The invention also provides a selective hydrogenation process utilizing the catalyst system.Type: ApplicationFiled: July 23, 2010Publication date: January 27, 2011Inventors: Kuo-Chen SHIH, Hung-Yu Chen, Mao-Lin Hsueh, Yi-Zhen Chen
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Patent number: 7816571Abstract: The use of a layered catalyst composition to selectively hydrogenate C5-C11 diolefins in a hydrocarbon mixture to one or more respective C5-C11 monoolefins is disclosed. The layered catalyst comprises an inner core having a first inorganic oxide and an outer layer bonded to the inner core. The outer layer has a non-refractory second inorganic oxide with at least one Group 1-2 metal and at least one Group 8-10 metal dispersed thereon.Type: GrantFiled: December 11, 2007Date of Patent: October 19, 2010Assignee: UOP LLCInventors: Antoine Negiz, Gregory J. Gajda
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Patent number: 7795166Abstract: A functional group-selective hydrogenation catalyst is provided, which is capable of selectively hydrogenating an aliphatic carbon-carbon double bond, aliphatic carbon-carbon triple bond, aromatic formyl group or aromatic nitro group contained in an organic compound. The catalyst includes a carrier, and palladium and an organic sulfur compound supported jointly thereon.Type: GrantFiled: December 1, 2006Date of Patent: September 14, 2010Assignee: N.E. Chemcat CorporationInventors: Hironao Sajiki, Tomohiro Maegawa, Kosaku Hirota
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Patent number: H2290Abstract: High strength presulfided catalyst for hydrogenating hydrocarbon resins without an in situ sulfiding step. The catalyst particles have a supported metal catalyst structure with presulfided interstitial surfaces with about 20 weight percent of a low molecular weight hydrocarbon resin, based on the weight of the porous supported metal catalyst structure, filling from 90 to 95 percent of the pore volume to improve a crush strength of the catalyst particles. The presulfided catalyst can be stored and/or shipped in an airtight container with an inert atmosphere. The catalyst particles are made by preparing the oxidized catalyst, presulfiding the catalyst, contacting the catalyst with the low molecular weight hydrocarbon resin in an inert atmosphere, sealing the catalyst in a storage/shipping container, loading the reactor with the presulfided, filled catalyst, and contacting the catalyst with an unsaturated hydrocarbon resin under hydrogenation conditions.Type: GrantFiled: January 17, 2012Date of Patent: April 1, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jose M. Vargas, Thomas R. Barbee, Yuan-Ju Chen