By Dehydrogenation Patents (Class 585/440)
  • Patent number: 4207425
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, and a cadmium component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum group component, a cobalt component, a cadmium component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % cadmium and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.
    Type: Grant
    Filed: August 24, 1978
    Date of Patent: June 10, 1980
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4197416
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a nonacidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a rhenium component, a cobalt component, a germanium component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 2 wt. % rhenium, about 0.1 to about 5 wt. % cobalt, about 0.001 to about 1 wt. % germanium and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.
    Type: Grant
    Filed: September 22, 1978
    Date of Patent: April 8, 1980
    Assignee: UOP Inc.
    Inventor: George J. Antos
  • Patent number: 4191846
    Abstract: Dehydrogenatable organic compounds diluted with steam, are dehydrogenated in the absence of free oxygen at high conversion and selectivity to less saturated compounds with a catalyst composite consisting essentially of one or more metals selected from the group consisting of Ni, Pd, Pt, Ir and Os, tin and a metal selected from the group consisting of gold and silver deposited on a support such as alumina, silica or a Group II aluminate spinel.
    Type: Grant
    Filed: January 12, 1976
    Date of Patent: March 4, 1980
    Assignee: Phillips Petroleum Company
    Inventors: Floyd Farha, Jr., Lewis E. Drehman