Using Al Halide Catalyst Patents (Class 585/459)
  • Patent number: 4517075
    Abstract: A process is provided for conducting organic compound conversion over a catalyst comprising a high silica crystalline zeolite which has been treated by contact with aluminum chloride vapor.
    Type: Grant
    Filed: December 28, 1983
    Date of Patent: May 14, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Ralph M. Dessau, George T. Kerr
  • Patent number: 4515682
    Abstract: A process is provided for conducting organic compound conversion over a catalyst composition comprising a specially treated crystalline zeolite having a high initial silica-to-alumina mole ratio, said zeolite having been synthesized from a reaction mixture comprising a diamine as a cation source. The treatment of the zeolite material comprises the sequential steps of reacting the zeolite with a dilute hydrogen fluoride solution, contacting the hydrogen fluoride solution reacted material with aluminum chloride vapor, and then treating the aluminum chloride contacted material to convert it to hydrogen form.
    Type: Grant
    Filed: February 17, 1984
    Date of Patent: May 7, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Clarence D. Chang, Joseph N. Miale
  • Patent number: 4474989
    Abstract: A process for preparing dinitrobenzophenones which comprises reacting benzene with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing unreacted benzene, ethylbenzene, polyethylbenzenes, 1,1-diphenylethane and heavier products, separating benzene, ethylbenzene and polyethylbenzenes from said alkylation product, recovering from the remainder of said alkylation product a fraction whose boiling points fall within the temperature range of about 260.degree. to about 290.degree. C., reacting said fraction with nitric acid at a temperature within the range of about 130.degree. to about 210.degree. C., wherein the molar ratio of nitric acid to said fraction is in the range of about 3:1 to about 8:1, and thereafter reacting the total resulting reaction product with nitric acid in oleum to obtain a nitration product predominating in dinitrobenzophenones.
    Type: Grant
    Filed: July 1, 1982
    Date of Patent: October 2, 1984
    Assignee: Gulf Research & Development Company
    Inventors: Anatoli Onopchenko, Edward T. Sabourin, Charles M. Selwitz
  • Patent number: 4393258
    Abstract: A 1-cyclohexyl-2-cyclohexylphenylethane derivative of the following general formula ##STR1## wherein R.sub.1 and R.sub.2, independently from each other, represent a linear alkyl group having 1 to 7 carbon atoms.
    Type: Grant
    Filed: June 10, 1982
    Date of Patent: July 12, 1983
    Assignee: Dainippon Mk & Chemicals Inc.
    Inventors: Hisato Sato, Haruyoshi Takatsu, Yutaka Fujita, Masayuki Tazume, Kiyohumi Takeuchi, Hiroyuki Ohnishi
  • Patent number: 4368343
    Abstract: A process for producing high-vacuum oils comprises alkylation of condensed and non-condensed aromatic hydrocarbons by means of secondary normal alkylchlorides containing 8 to 12 carbon atoms or mixtures of said chlorides. The alkylchlorides are employed in a molar ratio to the condensed or non-condensed aromatic hydrocarbons of from 2.5:1 to 5:1. The alkylation reaction is conducted at a temperature within the range of from 20.degree. to 100.degree. C. in the presence of from 2 to 15 mol. % of aluminum chloride based on the amount of the employed alkylchlorides until the evolution of hydrogen chloride ceases, whereafter the catalyst is separated from the resulting alkylate. The alkylate is subjected to a vacuum fractionation and the desired fraction is collected which has a boiling temperature within the range of from 220.degree. to 250.degree. C./0.2-0.3 mm Hg, while the preceding fraction is recycled to alkylation stage.
    Type: Grant
    Filed: September 18, 1980
    Date of Patent: January 11, 1983
    Inventors: Izrail L. Kotlyarevsky, Ninel I. Myakina, Mikhail A. Kamkha, Ivan M. Ikryanov, Svetlana A. Glyadinskaya
  • Patent number: 4347393
    Abstract: In a process for producing cumene and/or diisopropylbenzene which comprises, in combination,(I) an alkylating step,(II) a transalkylating step,(III) a catalyst separating step,(IV) a neutralization step, and(V) fractionally distilling step;characterized in that(a) step (I) is carried out at a temperature of about 40.degree. C. to about 85.degree. C. while maintaining the activity coefficient (M) of the catalyst at about 10.times.10.sup.-4 to about 300.times.10.sup.-4 and the concentration of aluminum chloride in the system at 0.005 to 0.15 mole/liter, and(b) step (II) is carried out without removing the catalyst from the reaction product of step (I) and at a temperature of about 40.degree. C. to about 75.degree. C. in the presence of added fresh aluminum chloride in an amount of 2 to 20 parts by weight/hr per 1000 parts by weight/hr of diisopropylbenzene in the reaction system while maintaining the activity coefficient (M) of the catalyst in the system at about 30.times.10.sup.-4 to about 300.times.10.sup.
    Type: Grant
    Filed: August 19, 1981
    Date of Patent: August 31, 1982
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Hisaya Miki
  • Patent number: 4319067
    Abstract: The catalyst activity in the Friedel-Crafts alkylation of aromatic compounds or the transalkylation of monoalkyl or polyalkyl aromatic compounds is increased by the addition of gaseous hydrogen halide directly to the catalyzed alkylation or transalkylation reaction mixture.
    Type: Grant
    Filed: July 31, 1980
    Date of Patent: March 9, 1982
    Assignee: Union Carbide Corporation
    Inventor: Russell L. Kreeger
  • Patent number: 4287074
    Abstract: A water-white, essentially odorless liquid useful as a dieletric oil and as a dye solvent, particularly for a carbonless paper solvent, consisting essentially of about 82% to about 88% by weight of mono-sec-butylbiphenyl and about 12% to about 18% of di-sec-butylbiphenyl prepared by reacting highly pure 1-butene or 2-butene with biphenyl at a mol ratio of butene to biphenyl of from about 0.5 to about 0.9 and at a temperature of about 250.degree. F. to about 475.degree. F. in the presence of an aluminum chloride catalyst, distilling the reaction product under vacuum to remove unreacted biphenyl and distilling off the product mixture at a temperature between about 370.degree. F. and about 440.degree. F. at 30 mm Hg. pressure or the equivalent thereof.
    Type: Grant
    Filed: April 28, 1980
    Date of Patent: September 1, 1981
    Assignee: Sun Oil Company of Pennsylvania
    Inventors: Harold W. Earhart, Donald F. Rugen