Abstract: A de-hydrogenation catalyst and its use in dehydrogenation of hydrocarbons. The catalyst has low cracking activity and comprises gallium or gallium and platinum on an essentially non-acidic and amorphous alumina-phosphate or silica-alumina-phosphate support with an empirical chemical composition of [Al2O3][SiO2]Y[P2O5]Z, wherein Y is between 0 and 0.2 and Z is between 0.01 and 1.1, with a BET surface area above 50 m2/g, as measured by N2 adsorption experiment.

Abstract: A method of recovering paraxylene in a pressure swing adsorption unit with varying hydrogen purge pressures. The pressure swing adsorption zone is adapted to adsorb and desorb paraxylene based on the cycling of partial pressure in the zone. A first hydrogen purge is fed concurrent to the feed. A second hydrogen purge is countercurrent to the feed.

Abstract: A method of recovering paraxyiene in a pressure swing adsorption unit with varying hydrogen purge pressures. The pressure swing adsorption zone is adapted to adsorb and desorb paraxyiene based on the cycling of partial pressure in the zone. A first hydrogen purge fed to the zone is within 50 psi of the adsorption pressure of paraxyiene in the zone. A second hydrogen purge fed to the zone is within 50 psi of the desorption pressure of paraxyiene in the zone. The overall amount of hydrogen necessary to operate the pressure swing adsorption zone is reduced and heat may be recovered from the effluent leaving the pressure swing adsorption zone.

Abstract: In a process for producing para-xylene, at least one feed comprising C6+ aromatic hydrocarbons is supplied to a dividing wall distillation column to separate the feed into a C7? aromatic hydrocarbon-containing stream, a C8 aromatic hydrocarbon-containing stream and a C9+ aromatic hydrocarbon-containing stream. At least part of the C8 aromatic hydrocarbon-containing stream is then supplied to a para-xylene recovery unit to recover para-xylene from the C8 aromatic hydrocarbon-containing stream and produce a para-xylene depleted stream. The para-xylene depleted stream is contacted with a xylene isomerization catalyst in a xylene isomerization zone under conditions effective to isomerize xylenes in the para-xylene depleted stream and produce an isomerized stream, which is then at least partially recycled to the para-xylene recovery unit.

Abstract: A method for separating an alkyl aromatic hydrocarbon, the method having a step of adding a first diluent and an extractant having a superacid to a mixture comprising the alkyl aromatic hydrocarbon and one or more isomers thereof to carry out an acid-base extraction to thereby form a complex of the alkyl aromatic hydrocarbon with the superacid, and thereafter separating the complex from the mixture, and a step of adding an eliminating agent having a relative basicity in a range of 0.06 to 10 with respect to the alkyl aromatic hydrocarbon and a second diluent to the complex, and carrying out complex exchange of the alkyl aromatic hydrocarbon for the eliminating agent to thereby separate the alkyl aromatic hydrocarbon from the complex.

Abstract: The invention is directed to a process to produce para-xylene and, optionally, ortho-xylene, including coupling two in-series xylenes separation systems with two parallel isomerization systems for energy savings and/or productivity increases.

Abstract: A catalyst for reforming hydrocarbons may include an inorganic oxide and a catalyst metal supported on the inorganic metal oxide. At least a portion of the catalyst metal may be supported in the form of a solid-solution particle. The catalyst metal may include a first metal (selected from cobalt, iron, copper, and manganese); nickel; and magnesium.

Abstract: The invention is directed to a process to produce para-xylene and, optionally, ortho-xylene, including coupling two in-series xylenes separation systems with two parallel isomerization systems for energy savings and/or productivity increases.

Abstract: Methods and systems for separating para-xylene are disclosed. In one exemplary embodiment, a method for separating para-xylene includes the steps of providing a feed stream including para-xylene and other C8 aromatic hydrocarbons to a first adsorbent bed within a radial flow simulated moving bed chamber and providing a desorbent stream to a second bed within the radial flow simulated moving bed chamber. The method further includes circulating the feed stream and the desorbent stream radially within the radial flow simulated moving bed chamber to third and fourth beds within the radial flow simulated moving bed chamber. Still further, the method includes withdrawing an extract stream including the para-xylene from the third bed and withdrawing a raffinate stream including the other C8 aromatic hydrocarbons from the fourth bed.

Abstract: One exemplary embodiment may be a process for producing one or more alkylated aromatics. Generally, the process includes providing a first stream including an effective amount of benzene for alkylating benzene from a fractionation zone, providing a second stream including an effective amount of ethene for alkylating benzene from a fluid catalytic cracking zone, providing at least a portion of the first and second streams to an alkylation zone; and passing at least a portion of an effluent including ethylbenzene from the alkylation zone downstream of a para-xylene separation zone.

Abstract: The subject invention comprises a hydrocarbon-conversion process using a zeolitic catalyst comprising very low concentrations of non-zeolitic material and featuring a gradient in crystallinity decreasing from the outer portion to the center and an intrusion pore volume of at least 0.6 cc/gram. The catalyst is particularly effective in a xylene-isomerization process comprising ethylbenzene conversion.

Abstract: The invention is directed to a process for the removal of olefin impurities from a feedstream comprising greater than equilibrium amounts of paraxylene by contact of the feedstream with a bed of solid acid catalyst to produce a product comprising reduced olefin impurities (when compared with said feedstream), said process comprising at least one of (i) reduced bed temperature on startup, and (ii) reduced flow rate on startup, wherein, in embodiments, there is a reduction in side reactions such as isomerization and/or transalkylation and/or disproportionation of paraxylene, when compared with conventional startup procedures.

Abstract: The xylene isomerization process unit and the transalkylation process units are combined in the present invention. A fractionation column can be shared by the two units, reducing the capital cost of the complex. In some embodiments, a split shell fractionation column and a split separator can be used.

Abstract: This invention relates to a method wherein a high-purity paraxylene can be produced efficiently by using a catalyst having a molecular sieving action (or shape selectivity) and being excellent in the catalytic activity without isomerization and adsorption-separation steps. More particularly, it relates to a method of producing a high-purity paraxylene, characterized in that MFI type zeolite having a primary particle size of not more than 100 ?m, a structure defining agent and silica material having an average particle size of not less than 10 nm but less than 1.0 ?m are used as a starting material, and a synthetic zeolite catalyst produced by subjecting the MFI type zeolite to a coating treatment with an aqueous solution obtained by mixing so as to satisfy X×Y<0.05 (wherein X is a concentration of the silica material (mol %) and Y is a concentration of the structure defining agent (mol %)) is used in the alkylation or disproportionation of at least one of benzene and toluene as a starting material.

Abstract: A process for separating para-xylene from a plurality of aromatic compounds, wherein the process introduces a mixed xylene feed stream comprising a plurality of xylene isomers into a first separation assembly to produce a first para-xylene enriched stream and a first raffinate stream. The process further feeds the raffinate stream into an isomerization unit to convert the raffinate stream into an isomerization reactor product stream, and introduces the isomerization reactor product stream into to a second para-xylene adsorptive separation unit to produce a second para-xylene enriched stream and a second raffinate stream.

Abstract: The invention concerns a xylenes isomerization process for the production of equilibrium or near-equilibrium xylenes. The process utilizes a catalyst comprising HZSM-5 or MCM-49 and process conditions including a temperature of less than 295° C. and a pressure sufficient to maintain the xylenes in liquid phase. In embodiments, the process can be operated in a continuous mode with ppm levels of dissolved H2 in the feed and in other embodiments in a cyclic mode without the H2 in feed but with periodic regenerations using a feed having low ppm levels of H2.

Abstract: A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.

Abstract: A catalyst is described which comprises at least one IZM-2 zeolite, at least one matrix and at least one metal selected from metals from groups VIII, VIB and VIIB, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2:aY2O3:bM2/nO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal with valency n, a and b respectively representing the number of moles of Y2O3 and M2/nO; and a is in the range 0.001 to 0.5 and b is in the range 0 to 1.

Abstract: A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.

Abstract: This invention relates to a method of efficiently producing a high-purity para-substituted aromatic hydrocarbon while suppressing caulking without requiring isomerization-adsorption separation steps, and more particularly to a method of producing a para-substituted aromatic hydrocarbon, characterized in that a methylating agent and an aromatic hydrocarbon are reacted in the presence of a catalyst formed by coating MFI type zeolite having a particle size of not more than 100 ?m with a crystalline silicate.

Abstract: The invention is directed to purification of an aromatic hydrocarbon stream including selective removal of phenol from a process stream comprising aromatic hydrocarbon mixtures, especially aromatic hydrocarbon mixtures that contain higher-than-equilibrium paraxylene, by contact with suitable adsorbents, to provide a product stream having lower concentration of phenol than said process stream.

Abstract: The invention concerns a process for the production of paraxylene and an apparatus suitable for said process. The process separates the overhead from a xylenes re-run into a xylene-rich stream and a xylene-lean stream. The xylene-lean stream is isomerized under conditions such that the xylenes are in the liquid phase.

Abstract: Liquid phase isomerization technology is employed in a manner to increase efficiency and reduce energy in paraxylene recovery.

Abstract: A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.

Abstract: Embodiments of a system are disclosed that include a heat source, an endothermic process module, and a fuel source configured to supply fuel to the endothermic process module and to receive isomerized fuel from the endothermic process module. A controller includes logic instructions operable to receive information regarding temperature of fuel received by the endothermic process module, and regulate application of heat from the heat source to the fuel at the endothermic process module. The endothermic process module includes a catalyst that increases the thermal carrying capacity of the fuel by isomerizing fuel from the fuel source.

Abstract: Processes for increasing overall aromatics and xylenes yield in an aromatics complex are provided. A C8+ aromatics stream from an aromatics-rich reformate is separated into a C8 aromatics fraction and a C9+ aromatics fraction comprising higher alkyl group-substituted C9 and C10 aromatics. The C9+ aromatics fraction is separated into a lighter boiling, higher alkyl group-substituted C9 or C9/C10 aromatics fraction and a heavier boiling, C10+ or C11+ aromatics fraction. The lighter boiling, higher alkyl group-substituted C9 or C9/C10 aromatics fraction is isomerized to convert a portion of the higher alkyl group-substituted C9 or C9/C10 aromatics therein into methyl-enriched C9 aromatics or methyl-enriched C9/C10 aromatics. The methyl-enriched C9+ aromatics stream comprising the methyl-enriched C9+ aromatics stream or the methyl-enriched C9/C10 aromatics is transalkylated with a toluene-containing stream.

Abstract: The present invention comprises a hydrocarbon-conversion process using an improved MgMxAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.

Abstract: An alkylaromatics isomerisation catalyst, which catalyst comprises at least 50 wt % of an inorganic binder; at least 0.01 wt % of a Group VIII metal and 1-9 wt % ZSM-12 zeolite wherein the silica to alumina molar ratio (SAR) of the ZSM-12 zeolite is in the range of from 60 to 200, and a process for the isomerisation of alkylaromatics to provide a reaction mixture, said process comprising contacting a hydrocarbon stream comprising alkylaromatics with such catalyst.

Abstract: The invention relates to a process for the preparation of m-substituted alkyltoluenes of the formula (I) in which R1 is C1-C5-alkyl, wherein a p-substituted alkyltoluene of the formula (II) in which R1 has the meaning given under formula (I), is isomerized in the presence of ionic liquids to give an m-substituted alkyltoluene of the formula (I). The m-substituted alkyltoluenes obtainable according to the invention are starting compounds for the preparation of fragrances and aroma substances.

Abstract: The present invention comprises a hydrocarbon-conversion process using an improved MgAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve has a specific combination of crystal configuration, being limited in diameter and length, specified crystallinity as measured by an X-Ray Diffraction Index (XRDI), and a narrow range of magnesium content.

Abstract: A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.

Abstract: A method for forming a functionalized latex polymer includes polymerizing a heterogeneous dispersion of water insoluble monomers in water, thereby forming a latex polymer. An at least partially water soluble halogenated non-ionic group is reacted with the latex polymer, whereby a halogen is displaced from the non-ionic group, thereby forming an at least partially water soluble non-ionic group that attaches to the latex polymer.

Abstract: One exemplary embodiment can be a process for the isomerization of a non-equilibrium alkylaromatic feed mixture. The process can include contacting the non-equilibrium alkylaromatic feed mixture in a C8 isomerization zone. The C8 isomerization zone may include a first isomerization stage and a second isomerization stage. At the first isomerization stage, at least a portion of the non-equilibrium alkylaromatic feed mixture can be contacted at a first isomerization condition in a liquid phase in the substantial absence of hydrogen to obtain an intermediate stream. At the second isomerization stage, at least part of the intermediate stream and at least a part of a stream rich in at least one naphthene can be contacted at a second isomerization condition to obtain a concentration of at least one alkylaromatic isomer that is higher than a concentration of that at least one alkylaromatic isomer in the non-equilibrium feed mixture.

Abstract: Disclosed are a novel NU-85 molecular sieve having a specific surface area ranging from about 405 m2/g to about 470 m2/g and a pore volume ranging from about 0.27 cm3/g to about 0.35 cm3/g, and processes for preparing the NU-85 molecular sieve.

Abstract: This invention relates to a process for converting a hydrocarbon feedstock, comprising the steps of (A) feeding the feedstock to a reactor or adsorption unit; (B) contacting the feedstock in the reactor or adsorption unit with a solid particulate material useful for converting the feedstock under conversion conditions; (C) withdrawing converted feedstock from the reactor; and (D) removing, under the conversion conditions for a fractional time of step (B), at least a portion of the solid particulate material while the feedstock is being fed to the reactor or adsorption unit, wherein the portion is more than 0.1 wt. % of the solid particulate material in the reactor or adsorption unit and wherein the fractional time is less than 95% of the time of step (B).

Abstract: Xylene isomerization processes, especially those processes in which ethylbenzene is also converted, are beneficially affected by adding benzene to the feed.

Abstract: A process of making p-xylcne comprising processing a mixed feedstock containing benzene, toluene, C8 aromatic hydrocarbons, C9 and higher aromatic hydrocarbons, and non-aromatic hydrocarbons through a series of operations and various units, including a C9 and higher aromatic hydrocarbon dealkylation unit, a toluene selective disproportionate unit, an adsorption separation unit, an isomerization unit, and a crystallization separation unit.

Abstract: One exemplary embodiment can be an apparatus for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon. The apparatus can include: a first drier and a second drier adapted to receive a fluid including at least one reactant; and a reaction zone communicating with the first drier to receive the fluid including at least one reactant and with the second drier to receive the regenerant. Generally, the first drier operates at a first condition to dry the fluid including at least one reactant and the second drier operates at a second condition during regeneration with a regenerant. The regenerant is displaced from the drier using a down-flow regenerant displacement assembly.

Abstract: The invention concerns a xylenes isomerization process for the production of equilibrium or near-equilibrium xylenes. The process utilizes a catalyst comprising HZSM-5 or MCM-49 and process conditions including a temperature of less than 295° C. and a pressure sufficient to maintain the xylenes in liquid phase. In embodiments, the process can be operated in a continuous mode with ppm levels of dissolved H2 in the feed and in other embodiments in a cyclic mode without the H2 in feed but with periodic regenerations using a feed having low ppm levels of H2.

Abstract: This invention is drawn to a process for isomerizing a non-equilibrium mixture of xylenes and ethylbenzene using a catalyst comprising a zeolite having specific particle-size characteristics, a platinum-group metal and a silica binder. A relatively minimal amount of hydrogen is supplied to the process on a once-through basis, resulting in low saturation of aromatics while achieving effective xylene isomerization with reduced processing costs.

Abstract: The invention relates to a process for the preparation of m-substituted alkyltoluenes of the formula (I) in which R1 is C1-C5-alkyl, wherein a p-substituted alkyltoluene of the formula (II) in which R1 has the meaning given under formula (I), is isomerized in the presence of ionic liquids to give an m-substituted alkyltoluene of the formula (I). The m-substituted alkyltoluenes obtainable according to the invention are starting compounds for the preparation of fragrances and aroma substances.

Abstract: A catalyst is described which comprises at least one IZM-2 zeolite, at least one matrix and at least one metal selected from metals from groups VIII, VIB and VIIB, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2:aY2O3:bM2/nO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal with valency n, a and b respectively representing the number of moles of Y2O3 and M2/nO; and a is in the range 0.001 to 0.5 and b is in the range 0 to 1.

Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.

Abstract: One exemplary embodiment can be an ion-exchanged xylene isomerization catalyst. The ion-exchanged xylene isomerization catalyst can include: about 1-about 99%, by weight, of at least one of MFI, MEL, EUO, FER, MFS, MTT, MTW, TON, MOR, and FAU zeolite; about 1-about 99%, by weight, of a binder having an aluminum phosphate; and no more than about 350 ppm, by weight, of a noble metal based on the weight of the catalyst. Generally, the catalyst has a quotient of (CO area)/(weight % of the noble metal) of no more than about 0.10.

Abstract: One exemplary embodiment can be a process for the isomerization of a non-equilibrium alkylaromatic feed mixture. The process can include contacting the non-equilibrium alkylaromatic feed mixture in a C8 isomerization zone. The C8 isomerization zone may include a first isomerization stage and a second isomerization stage. At the first isomerization stage, at least a portion of the non-equilibrium alkylaromatic feed mixture can be contacted at a first isomerization condition in a liquid phase in the substantial absence of hydrogen to obtain an intermediate stream. At the second isomerization stage, at least part of the intermediate stream and at least a part of a stream rich in at least one naphthene can be contacted at a second isomerization condition to obtain a concentration of at least one alkylaromatic isomer that is higher than a concentration of that at least one alkylaromatic isomer in the non-equilibrium alkylaromatic feed mixture.

Abstract: A process for producing para-xylene from a hydrocarbon feed is described in which an adsorption column operating as a simulated moving bed with at least five zones delivers an extract, a 2-raffinate and an intermediate raffinate. The extract is distilled and the distillate is optionally re-crystallized to recover para-xylene with a purity of at least 99.7%. The 2-raffinate is distilled then isomerized in a reactor preferably operating in the liquid phase and at a low temperature. The intermediate raffinate with an enriched ethylbenzene content is distilled then isomerized in the vapour phase.

Abstract: A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.

Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

Abstract: One exemplary embodiment can be an extruded C8 alkylaromatic isomerization catalyst. The extruded catalyst can include: about 2-about 20%, by weight, of an MTW zeolite; about 80-about 98%, by weight, of a binder including an alumina; about 0.01-about 2.00%, by weight, of a noble group metal calculated on an elemental basis; and about 100 ppm-less than about 1000 ppm, by weight, of at least one alkali metal calculated on an elemental basis. Generally, the weight percents of the MTW zeolite, the binder, the noble group metal, and the at least one alkali metal are based on a weight of the extruded catalyst.

Abstract: The present invention comprises a hydrocarbon-conversion process using an improved MgAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve has a specific combination of crystal configuration, being limited in diameter and length, specified crystallinity as measured by an X-Ray Diffraction Index (XRDI), and a narrow range of magnesium content.