By Partial Combustion Of Hydrocarbon Patents (Class 585/540)
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Patent number: 8748686Abstract: A process and apparatus are provided to produce acetylene from a feed stream of low hydrogen content hydrocarbons such as coal by: (a) blending the hydrocarbons with methane to provide a blended mixture containing at least about 12.5 wt % atomic hydrogen; (b) partially combusting the blended mixture in a reactor in the presence of a source of oxygen to provide a partially combusted mixture at or above a temperature sufficient to produce methyl radicals; (c) maintaining the partially combusted mixture at or above the temperature for a residence time sufficient to produce a product stream containing enhanced yields of acetylene without significant formation of coke or coke precursors; (d) cooling the product stream to reduce the temperature of the product stream within a time sufficiently brief to substantially arrest any cracking reactions and provide a cooled product stream; and (e) recovering acetylene from the cooled product stream.Type: GrantFiled: November 25, 2008Date of Patent: June 10, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Paul F. Keusenkothen, Frank Hershkowitz
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Publication number: 20140058179Abstract: A pyrolytic reactor comprising a fuel injection zone, a combustion zone adjacent to the fuel injections zone, an expansion zone adjacent to the combustion zone, a feedstock injection zone comprising a plurality of injection nozzles and disposed adjacent to the expansion zone, a mixing zone configured to mix a carrier stream and feed material and disposed adjacent to the feedstock injection zone, and a reaction zone adjacent to the mixing zone. The plurality of injection nozzles are radially distributed in a first assembly defining a first plane transverse to the feedstock injection zone and in a second assembly transverse to the feedstock injection zone.Type: ApplicationFiled: July 22, 2013Publication date: February 27, 2014Inventors: Carl J. Stevens, Antoine Negiz, Vinayender Kuchana
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Publication number: 20130334464Abstract: A process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, is disclosed. The process consists of separately preheating and then mixing a first input stream containing a hydrocarbon and a second input stream containing oxygen, supplying the first input stream and the second input stream via a burner block to a firing space, quenching a cracking gas obtained to produce a process water stream and a product gas stream, cooling the product gas stream in a cooling column by direct heat exchange with cooling water, depleting soot in an electrostatic filter, combining all process water streams and passing through soot channels, subjecting the combined process water stream to a cleaning operation by partial vaporization in a one-stage flash vessel to obtain a cleaned process water stream, and recycling the cleaned process water stream into the process.Type: ApplicationFiled: May 24, 2013Publication date: December 19, 2013Inventors: Maximilian VICARI, Christian WEICHERT, Dirk GROSSSCHMIDT, Michael RUSS, Mirko HAIDER, Horst NEUHAUSER, Michael L. HAYES
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Patent number: 8445739Abstract: A process for converting natural gas from which contaminants have been sufficiently removed to acetylene includes heating the purified gas through a selected range of temperature for adequate time or combustion of the purified gas at adequate temperature within a suitable environment during an adequate reaction time to convert a fraction of the gas stream to acetylene, wherein the acetylene is directed for other processes, reactions, and uses. A process for converting natural gas to liquid hydrocarbons by combusting externally derived hydrogen for heating natural gas to a selected range of temperature. A process for converting natural gas to liquid hydrocarbons by reacting conversion products with externally derived hydrogen to form olefins comprising ethylene, and catalytically forming liquid hydrocarbons from the olefins comprising ethylene.Type: GrantFiled: August 27, 2009Date of Patent: May 21, 2013Assignee: Synfuels International, Inc.Inventor: Edward R. Peterson
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Patent number: 8173853Abstract: A process is proposed for continuously operating a plant for preparing acetylene from hydrocarbons by partial oxidation, cleavage in an arc or pyrolysis of hydrocarbons to obtain a reaction gas mixture which is conducted through one or more compressors, the pressure of the reaction gas mixture on the suction side of the compressor being controlled within a predefined range by means of a conventional controller, which comprises additionally using a higher-level model-supported predictive controller which reacts to abrupt changes in the mass flow rate of the reaction gas mixture.Type: GrantFiled: April 4, 2007Date of Patent: May 8, 2012Assignee: BASF SEInventors: Kai Rainer Ehrhardt, Raymond Poche, William R. Scullin, Michael L. Hayes
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Patent number: 8017823Abstract: A process is proposed for continuously operating a plant for preparing acetylene from hydrocarbons by partial oxidation, cleavage in an arc or pyrolysis of hydrocarbons to obtain a reaction gas mixture which is conducted through one or more compressors, the pressure of the reaction gas mixture on the suction side of the compressor being controlled within a predefined range by means of a conventional controller, which comprises additionally using a high-level model-supported predictive controller which reacts to abrupt changes in the mass flow rate of the reaction gas mixture.Type: GrantFiled: April 11, 2006Date of Patent: September 13, 2011Assignee: BASF, SEInventors: Kai Rainer Ehrhardt, Raymond Poche, William R. Scullin, Michael L. Hayes
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Patent number: 7968759Abstract: In a process for converting methane to aromatic hydrocarbons, a feed containing methane is supplied to one or more reaction zone(s) containing catalytic material operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons; the reaction zone(s) being operated with an inverse temperature profile.Type: GrantFiled: August 5, 2010Date of Patent: June 28, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Larry L. Iaccino, Elizabeth L. Stavens, Neeraj Sangar, Jeremy J. Patt
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Patent number: 7956228Abstract: A process for the preparation of acetylene and synthesis gas by partial thermal oxidation in a reactor which has a burner having passages, wherein the starting materials to be reacted are rapidly and completely mixed only immediately before the flame reaction zone in the passages of the burner, a mean flow rate which exceeds the flame propagation velocities under the given reaction conditions being established in the mixing zone within the passages.Type: GrantFiled: April 21, 2006Date of Patent: June 7, 2011Assignee: BASF AktiengesellschaftInventors: Bernd Bartenbach, Kai Rainer Ehrhardt, Arne Hoffmann, Frank Kleine Jaeger
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Patent number: 7928275Abstract: Process for the preparation of acetylene from hydrocarbons by partial oxidation, arc cleavage or pyrolysis, the material stream comprising the acetylene and soot obtained being fed to a compressor, wherein a liquid which takes up the major part of the soot present in the material stream is sprayed into the compressor.Type: GrantFiled: February 13, 2007Date of Patent: April 19, 2011Assignee: BASF SEInventors: Michael Bachtler, Kai Rainer Ehrhardt, Christopher P Witte, Michael L. Hayes
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Patent number: 7915465Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 8, 2010Date of Patent: March 29, 2011Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7915466Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 8, 2010Date of Patent: March 29, 2011Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7915461Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 8, 2010Date of Patent: March 29, 2011Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7915464Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 8, 2010Date of Patent: March 29, 2011Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7915463Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 8, 2010Date of Patent: March 29, 2011Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7915462Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 8, 2010Date of Patent: March 29, 2011Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Publication number: 20110054231Abstract: A process for converting natural gas from which contaminants have been sufficiently removed to acetylene includes heating the purified gas through a selected range of temperature for adequate time or combustion of the purified gas at adequate temperature within a suitable environment during an adequate reaction time to convert a fraction of the gas stream to acetylene, wherein the acetylene is directed for other processes, reactions, and uses. A process for converting natural gas to liquid hydrocarbons by combusting externally derived hydrogen for heating natural gas to a selected range of temperature. A process for converting natural gas to liquid hydrocarbons by reacting conversion products with externally derived hydrogen to form olefins comprising ethylene, and catalytically forming liquid hydrocarbons from the olefins comprising ethylene.Type: ApplicationFiled: August 27, 2009Publication date: March 3, 2011Applicant: SYNFUELS INTERNATIONAL, INC.Inventor: Edward R. Peterson
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Patent number: 7795490Abstract: In a process for converting methane to aromatic hydrocarbons, a feed containing methane is supplied to one or more reaction zone(s) containing catalytic material operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons; the reaction zone(s) being operated with an inverse temperature profile.Type: GrantFiled: April 18, 2007Date of Patent: September 14, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Larry L. Iaccino, Elizabeth L. Stavens, Neeraj Sangar, Jeremy J. Patt
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Patent number: 7781636Abstract: A process for converting methane to higher hydrocarbon(s) including aromatic hydrocarbon(s) in a reaction zone comprises providing to a hydrocarbon feedstock containing methane and a catalytic particulate material to the reaction zone and contacting the catalytic particulate material and the hydrocarbon feedstock in a substantially countercurrent fashion in the reaction zone, while operating the reaction zone under reaction conditions sufficient to convert at least a portion of said methane to a first effluent having said higher hydrocarbon(s).Type: GrantFiled: April 2, 2007Date of Patent: August 24, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Larry L. Iaccino, Neeraj Sangar, Elizabeth L. Stavens, Matthew J. Vincent
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Patent number: 7772450Abstract: In a process for converting methane to syngas and aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst under conditions effective to convert said methane to aromatic hydrocarbons and produce a first effluent comprising aromatic hydrocarbons and H2, wherein said first effluent comprises at least 5 wt % more aromatic hydrocarbons than said feed. At least part of the H2 from said first effluent is then reacted with an oxygen-containing species, such as carbon dioxide, to produce a second effluent having an increased H2 and CO content compared with said first effluent.Type: GrantFiled: April 26, 2007Date of Patent: August 10, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Larry L. Iaccino, James R. Lattner
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Patent number: 7759535Abstract: In a process for converting methane to higher hydrocarbons including aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst under conditions effective to convert said methane to aromatic hydrocarbons and produce a first effluent stream comprising aromatic hydrocarbons and hydrogen, wherein said first effluent stream comprises at least 5 wt % more aromatic hydrocarbons than said feed. At least part of the hydrogen from said first effluent stream is then reacted with an oxygen-containing species, such as carbon dioxide, to produce a second effluent stream having a reduced hydrogen content compared with said first effluent stream.Type: GrantFiled: December 2, 2005Date of Patent: July 20, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Larry L. Iaccino, Xiaobing Feng, Matthew J. Vincent, Elizabeth L. Stavens
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Patent number: 7667085Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: January 31, 2007Date of Patent: February 23, 2010Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7250449Abstract: A process for converting natural gas to a hydrocarbon liquid wherein a stream of natural gas at a selected pressure is mixed with a hot gas stream which is at a temperature sufficient to affect a chemical reaction and form an intermediate product stream containing reactive hydrocarbons, the intermediate product stream being quenched and the quenched intermediate product stream being reacted in a catalytic liquification zone to produce a hydrocarbon liquid.Type: GrantFiled: October 18, 2002Date of Patent: July 31, 2007Assignee: Bryan Research & Engineering, Inc.Inventors: Keith A. Bullin, Joel G. Cantrell
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Patent number: 7208647Abstract: A process for converting natural gas to reactive gaseous products, comprising heating the gas through a selected range of temperature for sufficient time, or combusting a portion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Unrecovered gaseous products resulting from the reactions may be used to provide heat to the process by which reactive gas components are produced. Recovered gaseous products, together or individually, may be reserved for subsequent use or storage.Type: GrantFiled: May 13, 2004Date of Patent: April 24, 2007Assignee: Synfuels International, Inc.Inventors: Edward R. Peterson, Sean C. Gattis
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Patent number: 7183451Abstract: A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.Type: GrantFiled: May 13, 2004Date of Patent: February 27, 2007Assignee: Synfuels International, Inc.Inventors: Sean C. Gattis, Edward R. Peterson
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Patent number: 7119240Abstract: A process for converting natural gas to an olefin includes heating the gas to a selected range of temperature to convert a fraction of the gas stream to reactive hydrocarbons, primarily ethylene or acetylene, and reacting with hydrogen in the presence of a catalyst to produce the olefin, usually ethylene. A portion of the incoming natural gas may be used to heat the remainder of the natural gas to the selected range of temperature. Hydrogen resulting from the reactions may be used to make electricity in a fuel cell. Alternatively, hydrogen may be burned to heat the natural gas to the selected range of temperature.Type: GrantFiled: July 1, 2003Date of Patent: October 10, 2006Assignee: The Texas A&M University SystemInventors: Kenneth R. Hall, Jerry A. Bullin, Philip T. Eubank, Aydin Akgerman, Rayford G. Anthony
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Patent number: 6881874Abstract: A process for the production of an olefin comprising partially combusting in a reaction zone a mixture of a hydrocabon and an oxygen-containing gas in the presence of a catalyst which is capable of supporting combustion beyond the fuel rich limit of flammability to produce the olefin. Prior the partial combustion, the mixture of the hydrocabon and the oxygen-containg gas is passed through a heat excahanger, and the heat exchanger provides a pressure drop.Type: GrantFiled: April 30, 2001Date of Patent: April 19, 2005Assignee: BP Chemicals LimitedInventors: Derek Alan Colman, Trevor John Hesketh, Ian Allan Beattie Reid, William Terence Woodfin
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Patent number: 6602920Abstract: A process for converting natural gas to a liquid includes heating the gas to a selected range of temperature to convert a fraction of the gas stream to reactive hydrocarbons, primarily ethylene or acetylene, and reacting methane and the reactive hydrocarbons in the presence of an acidic catalyst to produce a liquid, predominantly naphtha or gasoline. A portion of the incoming natural gas may be used to heat the remainder of the natural gas to the selected range of temperature. Hydrogen resulting from the reactions may be used to make electricity in a fuel cell. Alternatively, hydrogen may be burned to heat the natural gas to the selected range of temperature.Type: GrantFiled: March 9, 2001Date of Patent: August 5, 2003Assignee: The Texas A&M University SystemInventors: Kenneth R. Hall, Jerry A. Bullin, Philip T. Eubank, Aydin Akgerman, Rayford G. Anthony
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Patent number: 6365792Abstract: The invention relates to a process for the preparation of acetylene and synthesis gas by thermal treatment of a starting mixture containing one or more hydrocarbons and in addition molecular oxygen and/or one or more compounds containing the element oxygen, in which the starting mixture is heated, brought to reaction in a reactor and subsequently cooled. The process has the special feature that the starting mixture is heated to a maximum of 1400° C. It is then possible to carry out the process with comparatively little expenditure of energy.Type: GrantFiled: March 20, 2000Date of Patent: April 2, 2002Assignee: BASF AktiengesellschaftInventors: Dieter Stapf, Peter Pässler, Michael Bachtler, Olaf Scheidsteger, Bernd Bartenbach
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Publication number: 20020000085Abstract: A process for converting natural gas to a liquid includes heating the gas to a selected range of temperature to convert a fraction of the gas stream to reactive hydrocarbons, primarily ethylene or acetylene, and reacting methane and the reactive hydrocarbons in the presence of an acidic catalyst to produce a liquid, predominantly naphtha or gasoline. A portion of the incoming natural gas may be used to heat the remainder of the natural gas to the selected range of temperature. Hydrogen resulting from the reactions may be used to make electricity in a fuel cell. Alternatively, hydrogen may be burned to heat the natural gas to the selected range of temperature.Type: ApplicationFiled: March 9, 2001Publication date: January 3, 2002Inventors: Kenneth R. Hall, Jerry A. Bullin, Philip T. Eubank, Aydin Akgerman, Rayford G. Anthony
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Patent number: 6130260Abstract: A process for converting natural gas to a liquid includes heating the gas to a selected range of temperature to convert a fraction of the gas stream to reactive hydrocarbons, primarily acetylene, and reacting methane and the reactive hydrocarbons in the presence of an acidic catalyst to produce a liquid, predominantly pentane. Hydrogen resulting from the reactions is used to heat the incoming natural gas, either with a hydrogen furnace or by electrical energy generated from the hydrogen. Little or no use of methane is required to supply energy for the process.Type: GrantFiled: November 25, 1998Date of Patent: October 10, 2000Assignee: The Texas A&M University SystemsInventors: Kenneth R. Hall, Jerry A. Bullin, Philip T. Eubank, Aydin Akgerman, Rayford G. Anthony
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Patent number: 5824834Abstract: The invention relates to a process for the production of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, wherein the gaseous reactants are separately preheated, intimately mixed in a mixing zone, reacted after passing a burner block and rapidly quenched with an aqueous quench medium after reaction, further characterized in that the aqueous quench medium is recirculated in a closed system. Preferably the ratio of the gaseous reactants is selected in such a way that acetylene and soot produced in the reaction are obtained in a weight ratio of 50 to 500.Type: GrantFiled: October 19, 1995Date of Patent: October 20, 1998Assignee: BASF AktiengesellschaftInventors: Michael Bachtler, Rudolf R. Schnur, Peter Passler, Olaf Scheidsteger, Werner Kastenhuber, Gerd Schlindwein, Rainer Konig
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Patent number: 5804689Abstract: For recovering acetylene from hydrocarbons, the hydrocarbons are thermally cracked in the presence of CO.sub.2 as a diluent gas. Suitable for thermal cracking for acetylene generation is a ratio, by weight, of CO.sub.2 to hydrocarbon, of between 3:1 and 1:3, and preferably between 2:1 and 1:2. It is preferred for the CO.sub.2 to be mixed with the hydrocarbons before thermal cracking which is thereafter conducted at average reaction temperatures of between 800.degree. and 1200.degree. C., preferably between 900.degree. and 1100.degree. C. An average residence time of between 5 and 500 milliseconds (ms) of the hydrocarbons during thermal cracking has proven to be effective. As the hydrocarbon feedstock for the thermal cracking, basically C.sub.2+ alkanes, especially ethane, propane and/or butane, can be used advantageously. After the cracked gas is cooled, higher alkynes are removed from the cracked gas, then the acetylene is separated preferably by scrubbing with an absorption agent selective for acetylene.Type: GrantFiled: January 30, 1996Date of Patent: September 8, 1998Assignee: Linde AktiengesellschaftInventors: Nicole Schodel, Eberhard Lassmann, Holger Hackner
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Patent number: 5789644Abstract: In the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, the feedstock gases are first separately preheated, then intensively mixed in a mixing zone, reacted after flowing through a burner block and then rapidly cooled.The burner block has a number of continuous ducts. According to the invention the ducts of the burner block are covered on the inlet side by plates furnished with perforations.Type: GrantFiled: June 6, 1995Date of Patent: August 4, 1998Assignee: BASF AktiengesellschaftInventors: Peter Passler, Rainer Feser, Hans-Gunter Thelen
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Patent number: 4983783Abstract: Reduction of carbon oxides products in oxidative pyrolysis of halogenated methanes in gas phase halogen-catalyzed oxidative-pyrolytic, non-flame, conversion of methane to higher molecular weight hydrocarbons is carried out in the presence of oxygen-containing gas which is primarily introduced in a latter portion of the process sequence reducing the oxygen requirement for effective suppression of formation of carbonaceous deposits thereby reducing carbon oxides product. Conversion of halogenated methanes to high yields of ethylene by conduct of the reaction in the presence of methane further reduces oxygen requirements and results in insignificant solid carbonaceous deposit formation.Type: GrantFiled: July 25, 1989Date of Patent: January 8, 1991Assignee: Illinois Institute of TechnologyInventor: Selim M. Senkan
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Patent number: 4952743Abstract: The invention relates to a process and to an apparatus for the conversion of hydrocarbons. According to the invention, at least one first gas containing at least 20% oxygen by volume and a type of hydrocarbon are first of all circulated in separate streams which are parallel to each other, without their being mixed, according to a spatial distribution such that the first gas is surrounded by the hydrocarbon; these substances are introduced into a mixing/reaction chamber, at a first given circulation level, and while the substances are then allowed to mix, the oxygen and the hydrocarbon are ignited so as to give rise to the conversion reaction and then, at a second given circulation level situated downstream of the first, a quenching of the resultant mixture is performed in a chamber; whereupon, the resultant quenched conversion products are recovered. The invention applies particularly to the manufacture of conversion products such as acetylene and ethylene.Type: GrantFiled: December 1, 1988Date of Patent: August 28, 1990Assignee: Gaz de FranceInventor: Guy-Marie Come
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Patent number: 4832822Abstract: The steam and thermal cracking of hydrocarbons is facilely carried out by in situ generating a stream of hot combustion gases including steam, advantageously in the configuration of a downstream axially extending, axially symmetrical helical flowstream, by combustion of steam-producing reactants in a combustion first reaction zone, and serially directly contacting and intimately admixing a liquid hydrocarbon feedstock with said gas of combustion in a downstream isodistribution, non-multi-tubular second reaction zone, advantageously first at a zone of reduced pressure thereof, the momentum of said gas of combustion at the point of direct contact being such as to provide all of the thermal and mechanical energy and heat transfer required to autogenously vaporize, entrain and effect cracking therein of said liquid hydrocarbon feedstock.Type: GrantFiled: June 10, 1988Date of Patent: May 23, 1989Assignee: Rhone-Poulenc Chimie de BaseInventors: Philippe Bernard, Francois Prudhon
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Patent number: 4788379Abstract: The process relates to the recovering of essentially pure acetylene from the gaseous out-put stream from a coal to acetylene conversion process. A plasma arc generator or other high energy type reactor can be used for the conversion to coal. The gaseous out-put stream is initially treated in an acid gas removal stage by absorbing HCN and H.sub.2 S in an organic solvent such as N-methyl pyrrolidone and scrubbing with a caustic agent such as NaOH to remove CO.sub.2. In a second stage, the gaseous out-put stream is scrubbed with the organic solvent to provide a sweet gas treatment and remove essentially pure acetylene as a product. In a third stage, the second stage gases are first hydrogenated, then desulfurized and then methanated. The out-put from the third stage is recycled to the coal to acetylene conversion process. In a fourth stage, the organic solvent from said second stage is refined and recycled to the first stage and/or second stage.Type: GrantFiled: October 1, 1982Date of Patent: November 29, 1988Assignee: GAF CorporationInventors: Michael Katz, Frank Carluccio, Gil Mallari, Kevin FitzPatrick, Ashok Desai, Robert Casciano, Jane Tsai
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Patent number: 4767569Abstract: Process for the production of synthesis gas and higher hydrocarbons in which a saturated hydrocarbon and an oxygen containing gas having a ratio of hydrocarbon to oxygen of greater than the stoichiometric ratio for complete combustion are introduced into a bed of an inert particulate material. The upward flow rate of the hydrocarbon/oxygen containing gas stream is sufficient to fluidize or to produce a spouting action of the bed material, whereby the particulate material is thrown up above the bed surface and subsequently falls back into the bed. The hydrocarbon and oxygen containing gas are ignited reacted together, and the products of the reaction withdrawn.Type: GrantFiled: July 6, 1987Date of Patent: August 30, 1988Assignee: The British Petroleum Company p.l.c.Inventors: John H. Brophy, Felix J. Weinberg
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Patent number: 4726913Abstract: Process for the production of synthesis gas and hydrocarbons in which a saturated hydrocarbon and an oxygen containing gas having a ratio of hydrocarbon to oxygen of greater than the stoichiometric ratio for complete combustion are introduced together with hydrogen into a bed of particulate material. The upward flow rate of the gases is sufficiently large to fluidize or to cause a spouting action of the bed material. The hydrocarbon, oxygen containing gas and hydrogen are ignited and reacted together and the products of the reaction are withdrawn.Type: GrantFiled: July 6, 1987Date of Patent: February 23, 1988Assignee: The British Petroleum Company p.l.c.Inventors: John H. Brophy, Richard P. Manning
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Patent number: 4724272Abstract: A method of controlling temperature during a pyrolysis reaction wherein the predominant pyrolysis reactions are endothermic. A fuel and oxidizer are combusted in a combustion zone to produce a hot gas stream at a superatmospheric pressure. The hot gas stream is then passed through a converging-diverging nozzle to accelerate the hot gas stream to a velocity of at least about mach 2. The reactant to be pyrolyzed is injected into the supersonic hot gas stream to produce a reaction mixture flowing at supersonic velocity and initiate the endothermic pyrolysis reactions. Substantially immediately thereafter the velocity of the reaction mixture is reduced over a predetermined reaction time to convert the kinetic energy of the reaction mixture to thermal energy in an amount sufficient to substantially offset the endothermic reactions taking place while maintaining supersonic flow. At the end of the predetermined reaction time the velocity of the reaction mixture is reduced to subsonic flow and the reaction quenched.Type: GrantFiled: April 17, 1984Date of Patent: February 9, 1988Assignee: Rockwell International CorporationInventors: Frederick D. Raniere, Merlin D. Schuman
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Patent number: 4672144Abstract: Methane is converted to higher, more reactive, hydrocarbon products by a diffusion flame. Methane is converted to C.sub.2 + products by pyrolysis in the interior of the flame with oxidizing gas flowing outside of the flame. More reactive products are withdrawn from the center of the flame by a probe tube and cooled by the flowing oxidizing gas to stop the reaction.Type: GrantFiled: November 8, 1985Date of Patent: June 9, 1987Assignee: Mobil Oil CorporationInventor: Gary J. Green
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Patent number: 4672143Abstract: A diffusion flame reactor for cracking hydrocarbon gas has an oxygen-deficient zone in the center of the flame or in the center of an array of flames. Propane, n-octane, iso-octane and decalin are cracked to ethylene, acetylene, propylene, butenes, and butadienes which are withdrawn from the flame.Type: GrantFiled: November 8, 1985Date of Patent: June 9, 1987Assignee: Mobil Oil CorporationInventors: Gary J. Green, Tsoung-Y Yan
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Patent number: 4575383Abstract: A method for converting methane to acetylene is disclosed wherein a hydrocarbon fuel is compressed, an oxygen-containing gas is introduced into a portion of the compressed hydrocarbon fuel and ignited to produce heat which causes the remaining portion of the hydrocarbon fuel to react to form a product gas containing acetylene.Type: GrantFiled: April 20, 1984Date of Patent: March 11, 1986Assignee: Atlantic Richfield CompanyInventors: Frank E. Lowther, Frederick L. Voelz
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Patent number: 4570028Abstract: A method is disclosed for converting methane to acetylene wherein a mixture of oxygen-containing gas and hydrocarbons is compressed and ignited to react the mixture to form a product gas containing acetylene, ethylene and C.sub.2 + hydrocarbons, and the reacted mixture is rapidly expanded and cooled. The mixture contains a mole ratio of hydrocarbons to oxygen-containing gas ranging from about 0.75:1 to about 1.65:1.Type: GrantFiled: April 6, 1984Date of Patent: February 11, 1986Assignee: Atlantic Richfield CompanyInventors: Frederick L. Voelz, Frank Lowther
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Patent number: 4367363Abstract: The process relates to the recovering of essentially pure acetylene from the gaseous out-put stream from a coal to acetylene conversion process. A plasma arc generator or other high energy type reactor can be used for the conversion to coal. The gaseous out-put stream is initially treated in an acid gas removal stage by absorbing HCN and H.sub.2 S in an organic solvent such as N-methyl pyrrolidone and scrubbing with a caustic agent such as NaOH to remove CO.sub.2. In a second stage, the gaseous out-put stream is scrubbed with the organic solvent to provide a sweet gas treatment and remove essentially pure acetylene as a product. In a third stage, the second stage gases are first hydrogenated, then desulferized and then methanated. The out-put from the third stage is recycled to the coal to acetylene conversion process. In a fourth stage, the organic solvent from said second stage is refined and recycled to the first stage and/or second stage.Type: GrantFiled: December 23, 1980Date of Patent: January 4, 1983Assignee: GAF CorporationInventors: Michael Katz, Frank Carluccio, Gil Mallari, Kevin FitzPatrick, Ashok Desai, Robert Casciano, Jane Tsai