Using Aluminosilicate Catalyst Patents (Class 585/739)
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Patent number: 6231749Abstract: Petroleum wax feeds are converted to high viscosity index lubricants by a two-step hydrocracking-hydroisomerization process in which the wax feed which exhibits branchingis initially subjected to hydrocracking under mild conditions with a conversion to non-lube range products of no more than about 30 weight percent of the feed. The hydrocracking is carried out at a hydrogen pressure of at least 1000 psig (7000 kPa) using an amorphous catalyst which preferentially removes the aromatic components present in the initial feed. The hydrocracked effluent is then subjected to hydroisomerization in a second step using a low acidity zeolite beta catalyst which effects a preferential isomerization on the paraffin components to less waxy, high VI isoparaffins. The second stage may be operated at high pressure by cascading the first stage product into the second stage or at a lower pressure, typically from 200 to 1000 psig.Type: GrantFiled: November 15, 1999Date of Patent: May 15, 2001Assignee: Mobil Oil CorporationInventors: Thomas F. Degnan, Robert T. Hanlon, Grant G. Karsner, Dominick N. Mazzone
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Patent number: 6204426Abstract: A process for producing a diesel fuel having at least 70% C10+ paraffins, wherein the iso-paraffin to normal paraffin mole ratio is 5:1 and higher. This diesel fuel is produced by from a feed containing at least 40% C10+ normal paraffins and at least 20% C26+ normal paraffins. It is produced by contacting that feed in an isomerization/cracking reaction zone a feed with a catalyst comprising a SAPO-11 and platinum in the presence of hydrogen (hydrogen:feed ratio of from 1,000 to 10,000 SCFB) at a temperature of from 340° C. to 420° C., a pressure of from 100 psig to 600 psig, and a liquid hourly space velocity of from 0.1 hr−1 to 1.0 hr−1.Type: GrantFiled: December 29, 1999Date of Patent: March 20, 2001Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, Arthur John Dahlberg, Kamala R. Krishna, Russell R. Krug
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Patent number: 6198015Abstract: The invention concerns a process for selective hydroisomerization of compounds with an n-alkane chain containing more than 10 carbon atoms, in which the compound to be treated is brought into contact with a catalyst comprising at least one hydro-dehydrogenating element and at least one molecular sieve having a one- or two-dimensional pore network, the accessible pore openings of which are delimited by 10 oxygen atoms, and a distance termed the bridging distance between the pores of less then 0.70 nm, and the zeolite is such that a catalyst which undergoes a standard n-heptadecane isomerization test has, for a conversion of 95%, a selectivity of at least 70% for isomerized products, and the catalyst contains at least 5% by weight of at least one hydro-dehydrogenating element selected from the group formed by non noble GVIII metals, GVIB metals, and niobium, and the catalyst preferably contains phosphorous. The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.Type: GrantFiled: March 4, 1998Date of Patent: March 6, 2001Assignee: Institut Francais du PetroleInventors: Christian Marcilly, Eric Benazzi, Nathalie George-Marchal
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Patent number: 6190532Abstract: Petroleum waxes are converted to high viscosity index lubricants by a hydroisomerization process in which the wax feed is subjected to hydroisomerization over a low acidity molecular sieve isomerization catalyst (the molecular sieve being preferably a zeolite) which effects a preferential isomerization on the paraffin components in the feed to less waxy, high VI isoparaffins. The hydroisomerization is operated at high pressure, at least 1000 psig hydrogen partial pressure (reactor inlet) using a zeolite catalyst, preferably a noble metal containing zeolite beta catalyst which contains boron as a framework component of the zeolite to give a low alpha value, typically below 10. The hydroisomerization is carried out at with a 650° F.+ conversion in the range of 10 to 40 weight percent of the feed. A final dewaxing step to target pour point may be used with relatively low loss, typically no more than 15 weight percent, during this dewaxing.Type: GrantFiled: November 15, 1999Date of Patent: February 20, 2001Assignee: Mobil Oil CorporationInventors: Thomas F. Degnan, Dominick N. Mazzone
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Patent number: 6153548Abstract: The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising NU-85 zeolite and at least one hydro-dehydrogenating element, at a temperature which is in the range 170.degree. C. to 500.degree. C., a pressure in the range 1 to 250 bar and an hourly space velocity in the range 0.05 to 100 h.sup.-1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils and other feeds requiring a reduction of pour point. The invention also concerns a NU-85 zeolite from which a portion of elements T (Al, Ga, Fe or B) have been removed and which has an Si/T atomic ratio of at least 18.Type: GrantFiled: June 25, 1998Date of Patent: November 28, 2000Assignee: Institut Francais du PetroleInventors: Eric Benazzi, Nathalie George-Marchal, Christophe Gueret, Patrick Briot, Alain Billon, Pierre Marion
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Patent number: 6150577Abstract: The invention includes a process of making a lubricating oil composition including: a process for making a high VI lubricating oil composition including the steps of (1) contacting a waste plastics feed including mainly polyethylene in a pyrolysis zone at pyrolysis conditions, whereby at least a portion of the waste plastics feed is cracked, thereby forming a pyrolysis zone effluent including 1-olefins and n-paraffins; (2) passing the pyrolysis zone effluent, including a heavy fraction and a middle fraction, the pyrolysis effluent middle fraction including 1-olefins, to a separations zone; where the pyrolysis effluent heavy fraction portion is separated from the pyrolysis effluent middle fraction; (3) passing the pyrolysis effluent heavy fraction to a hydrogenation zone; and (4) passing at least a portion of the hydrogenation zone effluent to a catalytic isomerization dewaxing zone, where at least a portion of the hydrogenation zone effluent is contacted with a isomerization dewaxing catalyst at isomerizationType: GrantFiled: December 30, 1998Date of Patent: November 21, 2000Assignee: Chevron U.S.A., Inc.Inventors: Stephen J. Miller, Gerald P. Huffman, Naresh Shah
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Patent number: 6140547Abstract: An isomerization process for converting an isomerization feed stream containing alkanes having about 4 carbon atoms to about 10 carbon atoms per molecule and cycloalkanes having about 5 carbon atoms to about 10 carbon atoms per molecule to at least one product hydrocarbon isomer. The isomerization feed stream, which contains at least one feed hydrocarbon and hydrogen, is contacted in an isomerization zone at effective isomerization conditions with a catalyst where deactivation of such catalyst occurs in the isomerization zone. The isomerization process includes the presence of an additive in the isomerization feed stream. The concentration of the additive is sufficient to alleviate or diminish the deactivation of the catalyst and to maintain a substantially constant conversion of the at least one feed hydrocarbon to the at least one product hydrocarbon isomer at effective isomerization conditions.Type: GrantFiled: December 1, 1998Date of Patent: October 31, 2000Assignee: Phillips Petroleum CompanyInventors: Fan-Nan Lin, Edgar D. Davis
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Patent number: 6124516Abstract: A process for isomerizing hydrocarbons is disclosed. The process includes contacting, under reaction conditions, a hydrocarbon-containing fluid containing a saturated hydrocarbon, preferably a normal paraffin containing in the range of from about 4 carbon atoms to about 10 carbon atoms per molecule, with a composition in a single-stage reaction zone. The process includes isomerizing such saturated hydrocarbon to thereby provide a product containing an isomerized hydrocarbon. The composition used in the process contains a zeolite and a metal carbide. The composition can be produced by combining a metal, preferably such metal is in a metal compound, with the zeolite to thereby provide a metal-promoted zeolite. The metal-promoted zeolite is then calcined or steamed followed by contacting the resulting zeolite with a hydrocarbon, preferably in the presence of hydrogen, to thereby provide a carburized metal-promoted zeolite.Type: GrantFiled: January 21, 1999Date of Patent: September 26, 2000Assignee: Phillips Petroleum CompanyInventors: An-hsiang Wu, Charles A. Drake
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Patent number: 6118036Abstract: A process to isomerize at least one normal or mono-methyl-branched alkane to form at least one multi-methyl-branched alkane has been developed. At least one normal or mono-methyl-branched is introduced to a reaction zone to form at least one multi-methyl-branched alkane. The reaction zone is located between a first and a second adsorption zone with the adsorption zones containing an adsorbent effective to selectively adsorb normal and mono-methyl-branched alkanes relative to multi-methyl-branched alkanes. A desorbent is introduced to the first adsorption zone and an effluent containing at least one multi-methyl-branched alkane is withdrawn from the second adsorption zone. After a period of time, the introduction of the desorbent is redirected to the second adsorption zone and concurrently the withdrawal of the effluent is moved to the first adsorption zone.Type: GrantFiled: September 24, 1998Date of Patent: September 12, 2000Assignee: UOP LLCInventor: Herman A. Zinnen
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Patent number: 6103099Abstract: A lubricating base stock useful for forming lubricants such as a multigrade automotive oils, automatic transmission oils, greases and the like is prepared by hydroisomerizing a waxy hydrocarbon feed fraction having an initial boiling point in the 650-750.degree. F. range and an end point of at least 1050.degree. F., synthesized by a slurry Fischer-Tropsch hydrocarbon synthesis process. The hydroisomerization forms a hydroisomerate containing the desired base stock which is recovered, without dewaxing the hydroisomerate. The hydroisomerization is conducted at conditions effective to convert at least 67 wt. % of the 650-750.degree. F.+ waxy feed hydrocarbons to lower boiling hydrocarbons. When combined with a standard lubricant additive package, these base stocks have been formed into multigrade automotive crankcase oils, transmission oils and hydraulic oils meeting the specifications for these oils.Type: GrantFiled: September 4, 1998Date of Patent: August 15, 2000Assignee: Exxon Research and Engineering CompanyInventors: Robert J. Wittenbrink, Daniel F. Ryan, Douglas R. Boate
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Patent number: 6096690Abstract: Discloses environmentally friendly, low temperature base oils and drilling fluids, or drilling mud compositions useful in the production of oil and gas. The drilling fluid is constituted of one or more of weighting agents, emulsifiers, wetting agents, viscosifiers, fluid loss control agents, proppants, and other particulates such as used in a gravel pack, emulsified with a paraffinic solvent composition which forms a continuous oil phase, or water-in-oil invert phase. The solvent composition is constituted of a mixture of C.sub.10- C.sub.24 n-paraffins and isoparaffins having an isoparaffin:n-paraffin molar ratio ranging from about 0.Type: GrantFiled: May 22, 1998Date of Patent: August 1, 2000Assignee: Exxon Research and Engineering Co.Inventors: Robert Jay Wittenbrink, Charles John Mart, Daniel Francis Ryan, Bruce Randall Cook
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Patent number: 6051129Abstract: A dewaxing process for lowering the haze point of a bright stock which includes contacting a bright stock in the presence of added hydrogen gas with a Zeolite EU-1 catalyst in combination with a ZSM-48 and/or SSZ-32 catalyst.Type: GrantFiled: July 24, 1998Date of Patent: April 18, 2000Assignee: Chevron U.S.A. Inc.Inventors: Thomas V. Harris, R. Norm Reynolds, Jr., Roger F. Vogel, Donald S. Santilli
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Patent number: 6027707Abstract: The invention concerns NU-88 zeolite, characterized by:i) a chemical composition with the following formula, expressed in terms of the mole ratios of the oxides for the anhydrous state:100 XO.sub.2, mY.sub.2 O.sub.3, pR.sub.2/n Owherem is 10 or less;p is 20 or less;R represents one or more cations with valency n;X represents silicon and/or germanium;Y represents one or more of the following elements: aluminium, iron, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese; andii) an X ray diffraction diagram, in its as synthesized state, which comprises the results shown in Table 1 of the description.The invention also concerns the preparation of the zeolite, any catalyst containing the zeolite and any catalytic process using such a catalyst.Type: GrantFiled: August 22, 1997Date of Patent: February 22, 2000Assignee: Institut Francais du PetroleInventors: John Leonello Casci, Sheena Maberly, Eric Benazzi, Loic Rouleau, Roland Patrick Henney
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Patent number: 6008427Abstract: A method providing enhanced heat integration in isomerization processes having an isomerization reactor operating at a temperature less than about 232.degree. C. (450.degree. F.) and an adsorption zone operating at a temperature greater than about 260.degree. C. (500.degree. F.) has been developed. The method begins with flowing a fresh feed stream containing normal and non-normal hydrocarbons to either the isomerization reactor or the adsorption zone. A variable mass flow desorption effluent containing at least normal hydrocarbons is flowed to the isomerization reactor to form a reactor effluent containing normal hydrocarbons and isomerized non-normal hydrocarbons. The reactor effluent is cooled and separated into an adsorber feed stream and a hydrogen purge gas which are each conducted to an adsorption zone. In the adsorption zone, the normal hydrocarbons are adsorbed and the non-normal hydrocarbons are withdrawn and collected.Type: GrantFiled: May 4, 1998Date of Patent: December 28, 1999Assignee: UOP LLCInventor: Lynn H. Rice
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Patent number: 5994607Abstract: The invention concerns a process for isomerising a feed containing essentially hydrocarbons, preferably paraffins containing principally 4 to 8, preferably princiapply to 6 and more principally 5 and/or 6 carbon atoms per molecule, comprising a fractionation zone and at least two isomersation reaction zones, said process comprising carrying out the following steps:(1) sending the feed to a fractionation zone;(2) drawing off at least a portion of the liquid circulating in said zone, via at least two draw-off levels; and(3) sending the major portion of the liquid drawn off in step (2) to at least two isomerisation zones, each isomerisation zone being associated with a draw-off level.Type: GrantFiled: August 4, 1998Date of Patent: November 30, 1999Assignee: Institut Francais du PetroleInventors: Jean-Francois Joly, Pierre Boucot, Michel Thery, Olivler Clause, Jean-Charles Viltard
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Patent number: 5990371Abstract: The invention concerns a process for the selective hydroisomerisation of compounds containing at least one n-alkane chain containing more than 10 carbon atoms, in which the compound to be treated is brought into contact with a catalyst comprising at least one hydro-dehydrogenating element and at least one molecular sieve with a mono- or bidimensional pore network in which the openings of the accessible pores are delimited by 10 oxygen atoms, and the distance termed the bridge width between the pores is less than 0.70 nm, and in which the catalyst, when subjected to a standard n-heptadecane isomerization test, has a selectivity of at least 70% towards isomerized products for a conversion of 95%.The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.Type: GrantFiled: May 5, 1997Date of Patent: November 23, 1999Assignee: Institut Francais du PetroleInventors: Johan Martens, Wim Souverijns, Rudy Parton, Gilbert Froment, Eric Benazzi, Nathalie George Marchal, Christian Marcilly
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Patent number: 5976351Abstract: This invention discloses a process for producing a high Viscosity Index lubricant having a VI of at least 125 from a waxy hydrocarbon feed having a wax content of at least 40 wt %. The process comprises catalytically dewaxing waxy paraffins present in the feed by isomerization in the presence of hydrogen and in the presence of a low acidity large pore zeolite isomerization catalyst. This catalyst has a ratio of SiO.sub.2 /Al.sub.2 O.sub.3, as synthesized, of at least 50:1, and an alpha value of not greater than 20, wherein the catalyst is prepared in the absence of boron. The catalyst further comprises a noble metal hydrogenation component. The feed may be hydrocracked prior to dewaxing with the large pore zeolite. The feed may be solvent dewaxed prior to isomerization. The effluent of the isomerization step may also be further dewaxed by either solvent or catalytic means in order to achieve target pour point.Type: GrantFiled: March 28, 1996Date of Patent: November 2, 1999Assignee: Mobil Oil CorporationInventors: Minas Robert Apelian, William S. Borghard, Thomas Francis Degnan, Jr., Robert Tryon Hanlon, Mae Koenig Rubin
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Patent number: 5977425Abstract: It has been discovered that waxy feeds can be upgraded using a catalyst made by combining powdered dewaxing catalyst with powdered isomerization catalyst said mixture of powdered catalysts being formed into a discrete particle.Type: GrantFiled: February 13, 1998Date of Patent: November 2, 1999Assignee: Exxon Research and Engineering CoInventors: Dee A. Brandes, David N. Zinkie, Sandra Jane Alward, William J. Murphy, Ian A. Cody, Thomas J. Ford
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Patent number: 5968341Abstract: The invention provides an activated silica enriched mazzite having a chemical formula in the anhydrous state, expressed in molar ratios of:a M.sub.2/n O; Al.sub.2 O.sub.3 ; b SiO.sub.2 ;with a variation from 0 to 0.5, M being an alkaline cation of valency n and b being greater than 7, and which has an acid strength corresponding to an amount of heat measured by ammonia absorption microcalorimetry, greater than 190 KJ/mol, and a pore volume, measured by cyclohexane adsorption, greater than 0.09 ml/g. The activated mazzites are useful in the conversion of hydrocarbons, in particular, the isomerization of C.sub.4 to C.sub.8 paraffin, and as molecular sieves in processes for the separation of hydrocarbons.Type: GrantFiled: June 8, 1998Date of Patent: October 19, 1999Assignee: Elf AquitaineInventors: Francesco Di Renzo, Francois Fajula, Fredj Fitoussi, Philippe Schulz
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Patent number: 5951847Abstract: A process for catalytically dehazing lubricating base oils is disclosed, which comprises contacting the lubricating base oil in the presence of hydrogen with a catalyst comprising naturally occurring and/or synthetic ferrierite which ferrierite has been modified to reduce the mole percentage of alumina and a low acidity refractory oxide binder material which is essentially free of alumina.Type: GrantFiled: October 31, 1996Date of Patent: September 14, 1999Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Laurent Georges Huve
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Patent number: 5948948Abstract: The invention concerns a process for isomerising a feed containing essentially hydrocarbons, preferably paraffins preferably containing 5 and/or 6 carbon atoms per molecule, in which said feed is treated in a distillation zone comprising an exhausting zone and a rectification zone associated with an isomerisation reaction zone, in the presence of an isomerisation catalyst and a gas stream containing hydrogen, characterized in that the reaction zone is at least partially internal to the distillation zone, and wherein the hydrogen-containing gas is fed by a dedicated gas distributor to the bottom of at least one catalytic bed within the isomerization reaction zone.Type: GrantFiled: February 4, 1997Date of Patent: September 7, 1999Assignee: Institut Francais du PetroleInventors: Etienne Lebas, Sophie Jullian, Christine Travers, Pierre Capron, Jean-Fran.cedilla.ois Joly, Michel Thery
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Patent number: 5908968Abstract: Process for the hydroisomerization of n-paraffins in the presence of a difunctional catalyst which comprises:(a) a porous crystalline material isostructural with beta-zeolite selected from boro-silicate (BOR-B) and boro-alumino-silicate (Al-BOR-B) in which the molar SiO.sub.2 :Al.sub.2 O.sub.3 ratio is higher than 300:1;(b) one or more metal(s) belonging to Group VIIIA, selected from platinum and palladium, in an amount comprised within the range of from 0.05 to 5% by weight.Type: GrantFiled: November 20, 1997Date of Patent: June 1, 1999Assignees: Eniricerche S. p. A., Agip Petroli S. p. A.Inventors: Angela Carati, Cristina Flego, Vincenzo Calemma
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Patent number: 5905181Abstract: A paraffin isomerization process is described and claimed. The process involves contacting the paraffins with an isomerization catalyst at isomerization conditions. Additionally, the process requires the injection of a nitrogen containing compound such as an amine, e.g., t-butylamine, and raising the operating temperature by about 20.degree. C. to about 150.degree. C. The effect of these modifications is to provide improved selectivity and sulfur resistance to the catalyst.Type: GrantFiled: December 29, 1997Date of Patent: May 18, 1999Assignee: UOP LLCInventor: Leonid B. Galperin
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Patent number: 5885438Abstract: This invention discloses a process for producing a high Viscosity Index lubricant having a VI of at least 125 from a waxy hydrocarbon feed having a wax content of at least 40 wt %. The process comprises catalytically dewaxing waxy paraffins present in the feed by isomerization in the presence of hydrogen and in the presence of a low acidity large pore zeolite isomerization catalyst. This catalyst has a ratio of SiO.sub.2 /Al.sub.2 O.sub.3, as synthesized, of at least 50:1, wherein the catalyst is prepared in the absence of boron. The alpha value of the catalyst is no greater than 20. The catalyst comprises a noble metal hydroisomerization catalyst such as Pt. The feed may be hydrocracked prior to dewaxing with the large pore zeolite. The effluent of the process may also be further dewaxed by either solvent or catalytic means in order to achieve target pour point.Type: GrantFiled: March 28, 1996Date of Patent: March 23, 1999Assignee: Mobil Oil CorporationInventors: Minas R. Apelian, William S. Borghard, Thomas F. Degnan, Jr., Robert T. Hanlon, Mae K. Rubin
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Patent number: 5880324Abstract: A catalyst comprising a modified mordenite zeolite catalyst modified with Pt and a promoter selected from the group consisting of Group IIB, Group IVA, Group VIB and mixtures thereof is effectively used in a process for the simultaneous dehydrogenation and isomerization of paraffins to isoparaffins and isoolefins under controlled conditions. The catalyst is prepared by depositing on the modified mordenite zeolite catalyst sequentially Pt and thereafter the promoter.Type: GrantFiled: June 22, 1998Date of Patent: March 9, 1999Assignee: Intevep, S.A.Inventors: Maria Magdalena de Agudelo, Trino Romero, Jose Guaregua, Marisela Gonzalez
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Patent number: 5866748Abstract: A process for the hydroisomerization of a predominantly C.sub.8 -C.sub.20 n-paraffinic feed to produce a high purity C.sub.8 -C.sub.20 paraffinic solvent composition having superior low temperature properties, and low viscosities. The feed is contacted, with hydrogen, over a dual functional catalyst to hydroisomerize and convert the feed to a product comprising a mixture of n-paraffins and isoparaffins, the isoparaffins component of which contains greater than 50 percent of mono-methyl species, with the molar ratio of isoparaffins:n-paraffins ranging from about 0.5:1 to 9:1.Type: GrantFiled: April 23, 1996Date of Patent: February 2, 1999Assignee: Exxon Research and Engineering CompanyInventors: Robert Jay Wittenbrink, Daniel Francis Ryan, Steven Earl Silverberg
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Patent number: 5846400Abstract: The present invention relates to new crystalline zeolite SSZ-42 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using an organic templating agent selected from the group consisting of N-benzyl-1,4-diazabicyclo?2.2.2!octane cations and N-benzyl-1-azabicyclo?2.2.2!octane cations.Type: GrantFiled: April 8, 1997Date of Patent: December 8, 1998Assignee: Chevron U.S.A. Inc.Inventors: Stacey I. Zones, Andrew Rainis
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Patent number: 5831139Abstract: A process combination is disclosed to selectively upgrade naphtha in accordance with expected trends leading to more-aliphatic gasolines. Such gasolines contain lower concentrations of aromatics and have lower end points with concomitant reduced harmful automotive emissions. The present process combination converts the higher-boiling portion of the naphtha, yields isobutane and other isoparaffins which are particularly suitable for upgrading or blending, and reduces cyclics in intermediate processing steps.Type: GrantFiled: March 26, 1997Date of Patent: November 3, 1998Assignee: UOP LLCInventors: Robert J. Schmidt, Paula L. Bogdan, Leonid B. Galperin, Jennifer S. Holmgren
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Patent number: 5831140Abstract: The invention concerns a process for isomerizing a feed containing essentially hydrocarbons, preferably paraffins containing principally 4 to 8, preferably principally 4 to 6 and more preferably principally 5 and/or 6 carbon atoms per molecule, comprising a fractionation zone and at least two isomerization reaction zones, said process comprising carrying out the following steps:(1) sending the feed to a fractionation zone;(2) drawing off at least a portion of the liquid circulating in said zone, via at least two draw-off levels;(3) sending the major portion of the liquid drawn off in step (2) to at least two isomerization zones, each isomerization zone being associated with a draw-off level;(4) sending the major portion of the effluents from step (3) to the fractionation zone, substantially adjacent to the draw-off levels;(5) recovering an effluent from the fractionation zone.Type: GrantFiled: February 4, 1997Date of Patent: November 3, 1998Assignee: Institut Francais du PetroleInventors: Jean-Fran.cedilla.ois Joly, Pierre Boucot, Michel Thery, Olivier Clause, Jean-Charles Viltard
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Patent number: 5811630Abstract: A process is disclosed for the production of a high octane product from a feed mixture comprising C.sub.5 -C.sub.6 normal paraffins in which an equilibrium reaction to produce mono and dimethyl branched paraffins is achieved by conducting the reaction and the product separation in a pressure swing adsorption and reaction zone containing a uniformly distributed adsorbent for the selective adsorption of normal paraffins and a catalyst for the equilibrium conversion of normal paraffins to mono and dimethyl branched paraffins. More specifically, the process achieves the isomerization of the normal paraffins by the reaction of the normal paraffins in the presence of hydrogen with the simultaneous removal of the mono and dimethyl branched paraffin product at the same temperature and pressure. In one embodiment, the passing of the feed mixture to the bed is terminated and the bed is purged with one of the reactants which in turn further reacts to displace heavier paraffin and enhance the overall product octane.Type: GrantFiled: April 29, 1996Date of Patent: September 22, 1998Assignee: UOP LLCInventors: Hemant W. Dandekar, Gregory A. Funk
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Patent number: 5770040Abstract: The present invention relates to a zeolite catalyst, a process for using the catalyst for conversion of hydrocarbons, especially naphtha and LPG feedstock, and a process for preparing the catalyst.Type: GrantFiled: January 5, 1996Date of Patent: June 23, 1998Assignee: Intevep, S.A.Inventors: Jorge Tejada, Juan Lujano, Yilda Romero
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Patent number: 5770783Abstract: A process to isomerize at least one normal or mono-methyl-branched alkane containing from about 6 to about 8 carbon atoms to form at least one multi-methyl-branched alkane has been developed. The normal or mono-methyl-branched alkane is introduced to a reaction and adsorption zone operating under conditions effective to isomerize the normal or mono-methyl-branched alkane and containing a catalyst effective to isomerize the normal or mono-methyl-branched alkane and an adsorbent effective to selectively adsorb normal and mono-methyl-branched alkanes relative to multi-methyl-branched alkanes. Hydrogen and a desorbent comprising at least one alkane having from about 4 to about 8 carbon atoms is introduced to a first portion of the reaction and adsorption zone and an effluent containing at least one multi-methyl-branched alkane is withdrawn from a second portion of the reaction and adsorption zone.Type: GrantFiled: February 3, 1997Date of Patent: June 23, 1998Assignee: UOP LLCInventors: Herman A. Zinnen, Charles P. McGonegal
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Patent number: 5763730Abstract: A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected.Type: GrantFiled: June 18, 1996Date of Patent: June 9, 1998Assignee: UOPInventors: Hemant W. Dandekar, Gregory A. Funk, Ralph D. Gillespie, Herman A. Zinnen, Charles P. McGonegal, Masami Kojima, Simon H. Hobbs
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Patent number: 5744683Abstract: A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected.Type: GrantFiled: June 18, 1996Date of Patent: April 28, 1998Assignee: UOPInventors: Hemant W. Dandekar, Gregory A. Funk, Simon H. Hobbs, Masami Kojima, Ralph D. Gillespie, Herman A. Zinnen, Charles P. McGonegal
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Patent number: 5744684Abstract: A process for isomerizing a mixture of alkanes containing pentanes and at least one alkane having from 6 to about 8 carbon atoms and no more than one methyl branch has been developed.Type: GrantFiled: June 18, 1996Date of Patent: April 28, 1998Assignee: UOPInventors: Herman A. Zinnen, Charles P. McGonegal, Hemant W. Dandekar, Gregory A. Funk, Ralph D. Gillespie
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Patent number: 5723716Abstract: It has been discovered that waxy feeds can be upgraded using a catalyst made by combining powdered dewaxing catalyst with powdered isomerization catalyst said mixture of powdered catalysts being formed into a discrete particle.Type: GrantFiled: August 27, 1996Date of Patent: March 3, 1998Assignee: Exxon Research and Engineering CompanyInventors: Dee Anne Brandes, David N. Zinkie, Sandra J. Alward
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Patent number: 5705730Abstract: A process for the isomerization of hydrocarbons using a chloride promoted catalyst wherein an adsorption zone arrangement operates to maintain chloride compounds in the reaction zone and to prevent contamination of product streams with chloride compounds removes normal paraffins from the desorbent stream to extend the capacity and life of a clinoptilolite molecular sieve. The invention preferably uses isoparaffins recovered from the isomerization zone as a desorbent. A gaseous fraction of the isomerization zone effluent can be recovered to provide a desorbent containing a low concentration of normal paraffins.Type: GrantFiled: November 20, 1996Date of Patent: January 6, 1998Assignee: UOPInventors: Andrew S. Zarchy, Lawrence Tucker Kass
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Patent number: 5689024Abstract: This invention relates to use of a new and improved form of crystalline material identified as having the structure of SUZ-9 as a sorbent or a catalyst for organic compound, e.g., hydrocarbon compound, conversion.Type: GrantFiled: December 1, 1994Date of Patent: November 18, 1997Assignee: Mobil Oil CorporationInventor: Kirk D. Schmitt
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Patent number: 5685973Abstract: The present invention relates to new crystalline zeolite SSZ-42 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using an organic templating agent selected from the group consisting of N-benzyl-1,4-diazabicyclo?2.2.2!octane cations and N-benzyl-1-azabicyclo?2.2.2!octane cations.Type: GrantFiled: May 24, 1996Date of Patent: November 11, 1997Assignee: Chevron U.S.A. Inc.Inventors: Stacey I. Zones, Andrew Rainis
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Patent number: 5656149Abstract: The present invention relates to new crystalline zeolite SSZ-41 which comprises oxides of (1) silicon or a mixture of silicon and germanium, and (2) zinc, said zinc being present in an amount from about 2 wt % to about 5 wt % of zinc metal based on the total weight of metals in said zeolite. Zeolite SSZ-41 may also optionally contain oxides of aluminum, iron, gallium or mixtures thereof. Zeolite SSZ-41 has the X-ray diffraction lines of Table I and has an argon adsorption capacity of at least about 0.06 cc/gm at 87.degree. K. Also disclosed are methods of making and using zeolite SSZ-41.Type: GrantFiled: May 21, 1996Date of Patent: August 12, 1997Assignee: Chevron U.S.A. Inc.Inventors: Stacey I. Zones, Donald S. Santilli
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Patent number: 5648590Abstract: Acyclic hydrocarbons having 4 to 7 carbon atoms per molecule are isomerized in the liquid phase by contact with a solid superacid catalyst comprising sulfated oxide or hydroxide of a metal selected from the group consisting of Group III and Group IV metals, to obtain high octane number blending components for motor fuel and/or valuable chemical and fuel intermediates.Type: GrantFiled: August 17, 1994Date of Patent: July 15, 1997Assignee: Sun Company, Inc. (R&M)Inventors: Chao-Yang Hsu, Vasant K. Patel, David H. Vahlsing, James T. Wei, Harry K. Myers, Jr.
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Patent number: 5641393Abstract: A crystalline zeolite high-silica SSZ-37 is prepared using a N,N-dimethyl-4-azoniatricyclo [5.2.2.0.sup.(2,6) ] undec-8-ene cation as a template wherein said zeolite is used in hydrocarbon conversion processes.Type: GrantFiled: August 8, 1995Date of Patent: June 24, 1997Assignee: Chevron U.S.A. Inc.Inventor: Yumi Nakagawa
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Patent number: 5608134Abstract: An improved process for preparing a difunctional catalyst active in the hydroisomerization of long-chain normal paraffins is disclosed, which is constituted by an amorphous silica-alumina gel and one or more metals belonging to Group VIIIA,Type: GrantFiled: June 1, 1995Date of Patent: March 4, 1997Assignee: Eniricerche S.p.A.Inventors: Carlo Perego, Giuseppe Bellussi, Vincenzo Calemma
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Patent number: 5591322Abstract: A crystalline zeolite SSZ-25 is prepared using an adamantane quaternary ammonium ion as a template.Type: GrantFiled: June 7, 1995Date of Patent: January 7, 1997Assignee: Chevron U.S.A. Inc.Inventors: Stacey I. Zones, Dennis L. Holtermann, Robert A. Innes, Theresa A. Pecoraro, Donald S. Santilli, James N. Ziemer
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Patent number: 5578195Abstract: Synthetic crystalline aluminosilicate of the pentasil type and method for using the same as catalysts or catalyst components in petrochemical processes for the catalytic conversion of hydrocarbons and their derivatives into useful organic compounds and intermediates.Type: GrantFiled: April 13, 1995Date of Patent: November 26, 1996Assignee: Ecolith - Zeolithe GmbHInventors: Arno Tissler, Roland Thome, Karl Becker, Hans-Dieter Neubauer, Hans-Heino John
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Patent number: 5557029Abstract: In a process for isomerizing saturated C.sub.4- C.sub.10 hydrocarbons (preferably n-pentane) in the presence of a platinum/zeolite catalyst, wherein sulfur compounds are present in the feed as impurities and cause catalyst deactivating, at least one volatile chlorine compound (preferably tetrachloroethylene or carbon tetrachloride) is added to the feed in an amount sufficient to counteract the catalyst deactivation. A correlation between effective amounts of chloride additive(s) required to counteract the catalyst deactivating effect caused by specific sulfur compound(s) and a specific parameter of various sulfur compounds has been established. The water content in the isomerization feed is not to exceed about 60 ppm H.sub.2 O (based on the weight of the at least one feed hydrocarbons.Type: GrantFiled: September 6, 1995Date of Patent: September 17, 1996Assignee: Phillips Petroleum CompanyInventors: Fan-Nan Lin, Nak J. Sung, Stephen L. Ege, Thomas A. Lessard
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Patent number: 5534656Abstract: This invention relates to use of synthetic porous crystalline MCM-58 as a catalyst component in catalytic conversion of organic compounds.Type: GrantFiled: April 28, 1995Date of Patent: July 9, 1996Assignee: Mobil Oil CorporationInventor: Ernest W. Valyocsik
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Patent number: 5530172Abstract: A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected.Type: GrantFiled: November 3, 1994Date of Patent: June 25, 1996Assignee: UOPInventors: Gregory A. Funk, Hermant W. Dandekar, Masami Kojima, Simon H. Hobbs
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Patent number: 5530173Abstract: A process for isomerizing a mixture of alkanes containing pentanes and at least one alkane having from 6 to about 8 carbon atoms and no more than one methyl branch has been developed.Type: GrantFiled: November 3, 1994Date of Patent: June 25, 1996Inventors: Gregory A. Funk, Hemant W. Dandekar
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Patent number: 5522984Abstract: This invention relates to a novel zeolite which has the crystal structure of zeolite beta. The novel zeolite SN-beta has a unique infrared absorbance spectrum, shows enhanced activity for transalkylation of di-isopropyl-benzene and shows less deactivation for cumene synthesis. The zeolite beta is prepared by taking an as-synthesized zeolite beta, steam treating it and then ammonium ion treating it to give a zeolite SN-beta with enhanced catalytic properties.Type: GrantFiled: May 30, 1995Date of Patent: June 4, 1996Assignee: UOPInventors: Gregory J. Gajda, Richard T. Gajek