Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.

Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.

Abstract: A method for purifying a paraffin from a source material containing a paraffin having 2 to 6 carbon atoms and an olefin having 2 to 6 carbon atoms includes a first step of bringing the source material into contact with a silver ion-containing solution (absorption liquid) at a predetermined temperature and pressure in an absorption column 1 and recovering a non-absorbed gas not absorbed by the absorption liquid while the olefin in the source material is preferentially absorbed by the absorption liquid, and a second step of desorbing and discharging a gas component from the absorption liquid having undergone the first step at a predetermined temperature and pressure in a desorption column 2. The first step and the second step are performed continuously in parallel while the absorption liquid is circulated between the first step and the second step.

Abstract: The present invention relates to a method of purifying olefin, the method comprising removing a small amount of acetylenic compounds contained in olefin by using pyrrolidinium-based or piperidinium-based ionic liquid mixtures comprising copper (I) halide. According to the method of the present invention, copper (I) halide is stabilized by pyrrolidinium-based or piperidinium-based ionic liquids, suppressing the oxidation of Cu(I) into Cu(II), whereby the capacity of removing acetylenic compounds can be maintained for a long time and the selective removal rate of acetylenic compounds to olefin can be significantly improved. In addition, since the ionic liquid mixtures comprising copper (I) halide used in the method of the present invention can be applied to both absorption and extraction processes, it can effectively remove acetylenic compounds from olefin in a more simple and economical way compared to the existing adsorption and membrane separation processes.

Abstract: A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution. Integrated processes for the production of alkyl carboxylate and alkenyl carboxylate, which processes comprise oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid, separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution for use in production of alkyl carboxylate or alkenyl carboxylate.

Abstract: Chitosan membranes chelated with silver or cuprous material may be used to separate olefins from a mixture of olefins and paraffins. The feed stream is humidified, demisted, treated to remove sulfur compounds and passed to a cell having a chitosan membrane containing chelated silver or cuprous compounds. The process has a reasonable flux rate and is operable at reasonable temperatures and pressures. The process could be used in an olefin separation train.

Abstract: The invention relates to a process for the selective recovery of olefins from a mixture of gases by: a) bringing a gaseous mixture having olefins and hydrogen into contact with silver nitrate solution whereby the olefins are absorbed into the silver nitrate solution as a complex; b) separating the solution having complexed olefins from the non-absorbed gases; c) depressurising and heating the olefin complex solution from (b) so as to release the olefins from the complex and regenerate the silver nitrate solution; d) passing the regenerated silver nitrate solution through a bed containing silver oxide so as to maintain the pH value of the silver nitrate at between 3 and 6; and e) recycling the silver nitrate solution regenerated in (d) to step (a).

Abstract: The invention provides novel adsorbents for use in the separation of unsaturated hydrocarbons from a mixture of gases containing such hydrocarbons. The preferred adsorbents comprise metal compounds supported on high surface area carriers. The adsorbents of the invention are usable in pressure swing adsorption or temperature swing adsorption processes.

Abstract: The present invention provides an improved method for deep selective hydrogenation for use in recovering high purity olefins from cracked gas effluents or other paraffin/olefin gaseous mixtures by use of a chemical absorption process.

Abstract: Olefins may be separated from paraffins, particularly those having the same number of carbon atoms, more easily than by fractional distillation by contacting a feed containing both materials with an aqueous solution of silver nitrate and nitric acid. The olefins form water soluble complexes with silver and are recovered by heating the water to decompose the complexes, thereby producing an olefin concentrate. In the absence of nitric acid contaminant hydrogen reduces the silver to metal and causes it to form colloidal solids and acetylenes form explosive solid compounds with silver. The nitric acid prevents the formation of insoluble solids by hydrogen and causes the silver acetylides to decompose during the olefin recovery step. Carrying out multiple stages of extraction and recovery can produce very high purity olefin.

Abstract: A process disclosed for the separation, purification and recovery of an unsaturated hydrocarbon from its mixture with at least one other material using a facilitated transport liquid membrane system.

Abstract: The present invention provides an improved method for recovering high purity olefins from cracked gas effluents or other parafin/olefin gaseous mixtures by use of a chemical absorption process.

Abstract: A process for separating C.sub.2 -C.sub.4 alkenes from C.sub.1 -C.sub.6 alkanes comprises the presence of water vapor in the alkene/alkane feed and the use of an Ag.sup.+ -exchanged sulfonated copolymer of tetrafluoroethylene and perfluorovinyl ether having been prepared by one of several specific ion-exchange methods.

Abstract: A process for absorbing olefinically-unsaturated hydrocarbon compounds from feedstreams containing such compounds by contacting said feed streams with metal-diketone absorbents of the formula: ##STR1## wherein R.sub.1 is trichloroemthyl or R.sub.F ; R.sub.F is C.sub.n F.sub.2n+1 and n is 1-8; R.sub.2 is H or hydrocarbyl of 2-20 carbon atoms having at least one olefinic unsaturated bond; M.sup.I is Cu.sup.I or Ag.sup.I and R.sub.3 is hydrocarbyl of 2-20 carbon atoms having at least one olefinic unsaturated bond.

Abstract: A process and apparatus for separating monoolefins from diolefins comprising contacting a mixture of monoolefins and diolefins with a complexing agent selected from the group consisting of copper(I) salts of sulfonic acids and copper(I) salts of dialkylphosphates and a suitable hydrocarbon solvent for the complexing agent under such conditions that the monoolefins and diolefins form complexes with the complexing agent. The monoolefin complex can be separated from the diolefin complex based either on the relative solubilities of the two complexes in the hydrocarbon solvent for the complexing agent or based on the relative strengths of the two complexes.

Abstract: A process and apparatus for separating monoolefins from other monoolefins comprising contacting a mixture of different monoolefins with a complexing agent selected from the group consisting of copper (I) salts of sulfonic acids and copper (I) salts of dialkyl phosphates and a suitable hydrocarbon solvent for the complexing agent under such conditions that the monoolefins form different strength complexes with the complexing agent. The different strength of the complexes provides a mechanism by which even closely boiling monoolefin isomers may be separated.

Abstract: A process of removing unsaturated hydrocarbons containing at least one non-aromatic unsaturation from feedstreams which comprises contacting the feedstream with at least one of Cu.sub.2 O or Ag.sub.2 O and a fluorinated acetylacetonate of the formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 fluoroalkyl, C.sub.1 -C.sub.8 alkyl, C.sub.4 -C.sub.6 heterocycle containing O, S or N or C.sub.6 -C.sub.10 aryl, R.sup.2 is H or C.sub.1 -C.sub.6 alkyl with the proviso that R.sup.1 and R.sup.2 together with the carbons to which they are attached may be joined together to form a C.sub.6 ring and n is from 1 to 8, in an inert organic solvent.

Abstract: An improved process for the absorption of an olefin in a silver salt solution and the recovery thereof by desorption is disclosed wherein the silver salt of the silver salt solution is silver trifluoroacetate.

Abstract: There is disclosed a process for the separation of ethylene or propylene from a purified, multi-component gas stream produced from the thermal cracking of hydrocarbons and containing ethylene or propylene and other low molecular weight components comprising the steps of: introducing said multi-component gas stream into an aqueous silver salt solution stream to effect the absorption and/or complexing of said contained ethylene or propylene and reaction of trace acetylenes with the silver metal ions of such solution; venting of the silver salt solution stream at reduced pressure to remove the dissolved other low molecular weight components; treating the resulting silver salt solution stream to separate the absorbed and/or complexed ethylene or propylene from the silver salt stream; further treating the resultant silver salt solution stream to release the contained trace acetylenes therefrom and provide an aqueous silver salt stream; and recycling said aqueous silver salt stream to said introducing step.

Abstract: This invention relates to an improved process for the alkylation of olefins in an alkylation unit feed stream in order to produce a higher yield of alkylate having a higher octane number, a lower acid consumption rate, and a lower energy consumption. Such a process involves passing a feed stream comprised of olefins and paraffins through a membrane so that the olefins are separated from the paraffins. In passing through the membrane, the olefins are facilitated in their transport by an isoparaffin sweep stream and together, the olefin/isoparaffin stream is passed into an alkylation reactor. Within the reactor, the olefins react with the isoparaffins to form alkylate.