Al Patents (Class 585/852)
  • Patent number: 11247194
    Abstract: Provided is a method of producing a porous molded body, the method including: the step of obtaining a molded body by molding a raw material that contains from 1 part by mass to 100 parts by mass of a bicarbonate compound (A) represented by AHCO3 (wherein, A represents Na or K) and from 0 parts by mass to 99 parts by mass of a compound (B) represented by BnX (wherein, B represents Na or K; X represents CO3, SO4, SiO3, F, Cl, or Br; and n represents an integer of 1 or 2 as determined by the valence of X) (provided that a total amount of (A) and (B) is 100 parts by mass); and the step of obtaining a porous molded body by performing a heat treatment of the molded body in a temperature range of from 100° C. to 500° C. and an atmosphere that contains water vapor in an amount of from 1.0 g/m3 to 750,000 g/m3 and thereby thermally decomposing not less than 90% by mass of the bicarbonate compound (A).
    Type: Grant
    Filed: December 21, 2017
    Date of Patent: February 15, 2022
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Masami Murakami, Naoya Takahashi, Ryo Niishiro
  • Patent number: 10214427
    Abstract: A novel synthetic crystalline molecular sieve designated as SSZ-109 is disclosed. SSZ-109 is synthesized using a structure directing agent comprising one or more of N,N,N?,N?-tetramethyl-N,N?-diisobutylhexane-1,6-diammonium cations, N,N,N?,N?-tetramethyl-N,N?-dineopentylhexane-1,6-diammonium cations, and N,N,N?,N?-tetramethyl-N-isobutyl-N?-neopentylhexane-1,6-diammonium cations.
    Type: Grant
    Filed: April 12, 2018
    Date of Patent: February 26, 2019
    Assignee: Chevron U.S.A. Inc.
    Inventor: Dan Xie
  • Patent number: 8969645
    Abstract: We provide a process comprising: a. feeding a chlorinated-hydrocarbon and an ionic liquid catalyst to a treatment unit; b. operating the treatment unit at an elevated temperature to produce dechlorinated-hydrocarbon and HCl; and c. collecting the dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides are removed. A second process comprises: a. creating an ionic liquid catalyst-rich zone in a distillation unit; b. passing chlorinated-hydrocarbon to the distillation unit; c. operating the unit under conditions causing removal of alkyl chloride to produce dechlorinated-hydrocarbon having a final boiling point close to a first final boiling point. A third process comprises: a. feeding alkylate gasoline blending component and ionic liquid catalyst to a treatment unit; b. operating the treatment unit; and c. collecting a dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides have been removed and the dechlorinated-hydrocarbon has a second RON that is close to a first RON.
    Type: Grant
    Filed: December 14, 2012
    Date of Patent: March 3, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Bi-Zeng Zhan, Hye Kyung Cho Timken, Michael Sean Driver
  • Patent number: 8927800
    Abstract: We provide a method for making hydrocarbon products with reduced organic halide contamination, comprising: a. separating an effluent from an ionic liquid catalyzed hydrocarbon conversion reaction into: i. a hydrocarbon fraction comprising an organic halide contaminant and from greater than zero to less than 5000 wppm olefins; and ii. a used ionic liquid catalyst fraction comprising a used ionic liquid catalyst; and b. contacting the hydrocarbon fraction with an aromatic hydrocarbon reagent and an ionic liquid catalyst to reduce a level of the organic halide contaminant to from greater than zero to 20 wppm in a finished hydrocarbon product.
    Type: Grant
    Filed: December 14, 2012
    Date of Patent: January 6, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Cedrick Mahieux, Sven Ivar Hommeltoft
  • Publication number: 20140275595
    Abstract: A method for treating a substrate prior to a metathesis reaction includes treating the substrate with a first agent configured to mitigate potentially adverse effects of one or more contaminants in the substrate on a catalyst used to catalyze the metathesis reaction. The treating reduces a level of the one or more contaminants by an amount sufficient to enable the metathesis reaction to proceed at a substrate-to-catalyst molar ratio of at least about 7,500 to 1. Methods for metathesizing substrates are described.
    Type: Application
    Filed: March 13, 2014
    Publication date: September 18, 2014
    Applicant: ELEVANCE RENEWABLE SCIENCES, INC.
    Inventors: Keith M. Wampler, Steven A. Cohen, Georg E. Frater, Levente Ondi, Jeno Varga
  • Publication number: 20140179977
    Abstract: We provide an extracted conjunct polymer naphtha (45), comprising a hydrogenated conjunct polymer naphtha, from a used ionic liquid catalyst, having a final boiling point less than 246° C. (475° F.), a Bromine Number of 5 or less, and at least 30 wt % naphthenes. We also provide a blended alkylate gasoline (97) comprising the extracted conjunct polymer naphtha (45), and integrated alkylation processes to make the extracted conjunct polymer naphtha (45) and the blended alkylate gasoline (97). We also provide a method to analyze alkylate products, by determining an amount of methylcyclohexane in the alkylate products (80).
    Type: Application
    Filed: February 28, 2014
    Publication date: June 26, 2014
    Applicant: Chevron U.S.A. Inc.
    Inventors: Hye Kyung Cho Timken, Izadyar Dalvand, Douglas Robert Cyr, Michael Tung-hai Cheng, Huping Luo, Shawn Shlomo Winter, Michael Sean Driver, Donald Henry Mohr
  • Publication number: 20140171720
    Abstract: We provide a process comprising: a. feeding a chlorinated-hydrocarbon and an ionic liquid catalyst to a treatment unit; b. operating the treatment unit at an elevated temperature to produce dechlorinated-hydrocarbon and HCl; and c. collecting the dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides are removed. A second process comprises: a. creating an ionic liquid catalyst-rich zone in a distillation unit; b. passing chlorinated-hydrocarbon to the distillation unit; c. operating the unit under conditions causing removal of alkyl chloride to produce dechlorinated-hydrocarbon having a final boiling point close to a first final boiling point. A third process comprises: a. feeding alkylate gasoline blending component and ionic liquid catalyst to a treatment unit; b. operating the treatment unit; and c. collecting a dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides have been removed and the dechlorinated-hydrocarbon has a second RON that is close to a first RON.
    Type: Application
    Filed: December 14, 2012
    Publication date: June 19, 2014
    Applicant: Chevron U.S.A. Inc.
    Inventors: Bi-Zeng Zhan, Hye Kyung Cho Timken, Michael Sean Driver
  • Patent number: 8669407
    Abstract: Described is an apparatus for, and a method of, recovering linear butenes from a mixed feed comprising providing a first mixed feed comprising linear butenes and isobutene; contacting the first mixed feed with an oligomerization catalyst such as an MWW family zeolite in a first oligomerization reactor to produce a second mixed feed comprising the linear butenes, C8 olefins and higher oligomers, and a reduced amount of isobutene relative to the first mixed feed; and separating the second mixed feed to produce a first effluent of first purified linear butenes, and a second effluent of C8 olefins and higher oligomers. The oligomerization reactor may be a converted isobutene-to-methyl-t-butylether reactor.
    Type: Grant
    Filed: August 28, 2008
    Date of Patent: March 11, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Katherine Sullivan Phillion, Garland B. Brignac, Michael C. Clark, Glenn J. Moloney, Donald J. Norris, Benjamin S. Umansky
  • Publication number: 20130029832
    Abstract: This invention relates to stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 ?m. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more.
    Type: Application
    Filed: March 6, 2012
    Publication date: January 31, 2013
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Wenyih Frank Lai, Robert E. Kay, Jason Wu, Kun Wang, Robert C. Lemon
  • Publication number: 20130030236
    Abstract: The process provided herein is concerned with disposal of oxidized sulfur compounds formed by oxidative desulfurization. The process uses solid base catalyst in the presence of a caustic solution or solid base catalyst pretreated with a base and eliminates the need to separate the sulfones from the hydrocarbon streams and recover the hydrocarbons.
    Type: Application
    Filed: July 25, 2012
    Publication date: January 31, 2013
    Inventors: Omer Refa KOSEOGLU, Abdennour BOURANE
  • Publication number: 20120304822
    Abstract: This invention relates to a method and apparatus for gasifying or liquifying coal. In particular, the method comprises reacting a coal with a molten aluminum or aluminum alloy bath. The apparatus includes a reaction vessel for carrying out the reaction, as well as other equipment necessary for capturing and removing the reaction products. Further, the process can be used to cogenerate electricity using the excess heat generated by the process.
    Type: Application
    Filed: June 4, 2012
    Publication date: December 6, 2012
    Inventors: Ronald G. Presswood, JR., Ian C. Bishop
  • Publication number: 20120123178
    Abstract: A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. M1an+Al(1-x)ExSiy?Oz? where M1 is at least one exchangeable cation selected from the group consisting of alkali, alkaline earth metals, rare earth metals, ammonium ion, hydrogen ion and mixtures thereof, “a” is the mole ratio of M1 to (Al+E), “n” is the weighted average valence of M1, E is an element selected from the group consisting of gallium, iron, boron, and mixtures thereof, “x” is the mole fraction of E, y? is the mole ratio of Si to (Al+E), and z? is the mole ratio of O to (Al+E). These zeolites are similar to MCM-68 but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
    Type: Application
    Filed: January 19, 2012
    Publication date: May 17, 2012
    Applicant: UOP LLC
    Inventors: Jaime G Moscoso, Deng-Yang Jan
  • Publication number: 20120116145
    Abstract: A method of producing a crude product from a hydrocarbon feed is provided. A hydrocarbon feed is contacted with a catalyst containing a Col. 6-10 metal or compound thereof to produce the crude product, where the catalyst has a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?.
    Type: Application
    Filed: January 11, 2012
    Publication date: May 10, 2012
    Applicant: SHELL OIL COMPANY
    Inventors: Opinder Kishan BHAN, Scott Lee WELLINGTON
  • Patent number: 8080156
    Abstract: Methods and apparatus relate to removal of mercury from crude oil. Such removal relies on transferring mercury from a liquid hydrocarbon stream to a natural gas stream upon contacting the liquid hydrocarbon stream with the natural gas stream. Processing of the natural gas stream after used to strip the mercury from the liquid hydrocarbon stream removes the mercury from the natural gas stream.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: December 20, 2011
    Assignee: ConocoPhillips Company
    Inventors: Joseph B. Cross, Probjot Singh, Richard D. Sadok, Howard L. Wilson, John M. Hays
  • Publication number: 20110288359
    Abstract: The invention relates to a process for preparation of a cationic zeolite that is at least partially exchanged with one or more monovalent and/or multivalent cations. The process comprises at least the stages for separate activation of a zeolite that is to be exchanged and an anhydrous salt under a dry, inert gaseous stream, dissolution of the anhydrous salt in an anhydrous organic solvent, ion exchange under dry inert atmosphere, filtering and washing with an anhydrous organic solvent, and calcination in the presence of oxygen and under a dry gaseous stream. The invention also relates to the use of prepared zeolites for the separation or the purification of hydrocarbon feedstocks.
    Type: Application
    Filed: May 5, 2009
    Publication date: November 24, 2011
    Applicant: IFP Energies nouvelles
    Inventors: Karin Barthelet, Patrick Magnoux, Alain Methivier, Vania Santos-Moreau
  • Patent number: 7956230
    Abstract: A method for reducing halide concentration in a hydrocarbon product made by a hydrocarbon conversion process using an ionic liquid catalyst comprising a halogen-containing an acidic ionic liquid comprising: (i) separating at least a portion of the hydrocarbon product from the ionic liquid catalyst used in the hydrocarbon conversion process from the hydrocarbon product; (ii) contacting at least a portion of the separated hydrocarbon product with an ionic liquid catalyst having the same formula as the ionic liquid catalyst used in the hydrocarbon conversion process; (iii) separating at least a portion of the hydrocarbon product from the ionic liquid catalyst of step (ii); and (iv) recovering at least a portion of the separated hydrocarbon product of step (iii) having a halide concentration less than the halide concentration of the hydrocarbon product of step (i) is disclosed.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: June 7, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Hye-Kyung C. Timken, Michael S. Driver, Thomas V. Harris
  • Patent number: 7938955
    Abstract: Provided are a method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm, under relatively mild conditions, without greatly increasing the hydrogen consumption and without remarkably decreasing the aromatic content; and a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm which exhibits a high heating value, is excellent in fuel economy and output power, and is free from an adverse effect on a sealing rubber member or the like used in the fuel injection system and thus does not cause the leakage of a fuel. A method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm is also disclosed.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: May 10, 2011
    Assignee: Japan Energy Corporation
    Inventors: Yasuhiro Araki, Katsuaki Ishida
  • Patent number: 7919665
    Abstract: A process is disclosed for removing mercury from a liquid hydrocarbon stream by contacting the mercury-containing liquid hydrocarbon stream with ferrous halide at moderate temperatures and without preheating the liquid hydrocarbon stream, or subjecting the liquid hydrocarbon stream to a heat treating step, immediately prior to contact with the ferrous halide particles.
    Type: Grant
    Filed: February 17, 2009
    Date of Patent: April 5, 2011
    Assignee: ConocoPhillips Company
    Inventors: John M. Hays, Erin E. Tullos, Joseph B. Cross
  • Publication number: 20100312035
    Abstract: Disclosed are dehydrogenation catalyst composites and methods of making the dehydrogenation catalyst composites. The dehydrogenation catalyst composites contain alumina, lithium oxide, alkaline earth metal oxide, chromium oxide, and sodium oxide. Also disclosed are methods of dehydrogenating a dehydrogenatable hydrocarbon involving contacting the dehydrogenatable hydrocarbon with a dehydrogenation catalyst composite containing alumina, lithium oxide, alkaline earth metal oxide, chromium oxide, and sodium oxide to provide a dehydrogenated hydrocarbon, such as an olefin.
    Type: Application
    Filed: June 5, 2009
    Publication date: December 9, 2010
    Applicant: BASF CATALYSTS LLC
    Inventors: Wolfgang Ruettinger, Michael Joseph Breen, Richard Jacubinas, Saeed Alerasool
  • Publication number: 20100274067
    Abstract: The invention relates to regeneration of catalysts used in the purification of aromatics streams. It has been surprisingly found that retaining small amount of coke on the catalyst reduces regeneration costs and improves regeneration effectiveness.
    Type: Application
    Filed: April 12, 2010
    Publication date: October 28, 2010
    Inventors: Stephen H. Brown, Terry E. Helton
  • Publication number: 20090118559
    Abstract: Oxidic composition consisting essentially of oxidic forms of a first metal, a second metal, and optionally a third metal, the first metal being either Fe or Zn and being present in the composition in an amount of from about 5 to about 80 wt %, the second metal being Al and being present in the composition in an amount of from about 5 to about 80 wt %, the third metal being selected from the group consisting of Mo, W, Ce, and V, and being present in an amount of from 0 to about 17 wt %—all weight percentages calculated as oxides and based on the weight of the oxidic composition, the oxidic composition being obtainable by (a) preparing a physical mixture comprising solid compounds of the first, the second, and the optional third metal, (b) optionally aging the physical mixture, without anionic clay being formed, and (c) calcining the mixture.
    Type: Application
    Filed: June 2, 2006
    Publication date: May 7, 2009
    Applicant: ALBEMARLE NETHERLANDS B.V.
    Inventors: Dennis Stamires, Paul O'Connor, William Jones
  • Publication number: 20090076317
    Abstract: A process for producing ZSM-48 comprises crystallizing an aqueous reaction mixture comprising at least one source of silica, at least one source of alumina, at least one source of hydroxyl ions, at least one source of diquaternary alkylammonium, R2+, ions having the formula: (CH3)3N+(CH2)5N+(CH3)3 and optionally ZSM-48 seed crystals, wherein said reaction mixture has a composition including the following molar ratios: R2+:SiO2 less than 0.1 SiO2:Al2O3 less than 100 OH?:SiO2 less than 0.2.
    Type: Application
    Filed: September 18, 2007
    Publication date: March 19, 2009
    Inventors: Wenyih Frank Lai, Wieslaw J. Roth, Robert E. Kay, Christine N. Elia
  • Patent number: 7473815
    Abstract: A method is disclosed for reducing levels of residual halogen and Group IIIb metals in a crude poly(?-olefin) polymerized in the presence of a catalyst comprising the halogen and Group IIIb metals, wherein the method comprises: A) washing the crude poly(?-olefin) with water; B) separating the aqueous and organic phases; C) then adding an adsorbent selected from the group consisting of magnesium silicates, calcium silicates, aluminum silicates, aluminum oxides, and clays to the organic phase to form a slurry; D) heating the slurry under reduced pressure at a temperature of at least about 180° C. for at least about thirty minutes; and then E) separating the adsorbent from the slurry.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: January 6, 2009
    Assignee: Crompton Corporation
    Inventors: Timothy L. Lambert, Werner A. Thuring
  • Patent number: 6184315
    Abstract: The polymerization process is carried out starting from a monomer that is introduced via pipe (1) and a comonomer that is introduced via pipe (2); the comonomer that is used, which is an alpha-olefin, is introduced into polymerization reactor P in the form of an approximately pure compound. The polymerization effluent is then separated in separator S1 into two fractions: a heavy fraction that is evacuated via pipe (5) and that contains at least one polymer, and a light fraction that is evacuated via pipe (4) and that comprises the monomer that has not reacted, the comonomer that has not reacted, as well as isomers of this comonomer. At least a portion of the light fraction is then treated during an ethenolysis stage E in the presence of an addition of fresh ethylene that is introduced via line (9). The effluent that is produced in the ethenolysis stage is subjected to at least two separations in separation train S2.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: February 6, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Alain Forestiere, François Hugues
  • Patent number: 6033556
    Abstract: The present invention relates to a capture mass comprising an essentially alumina-based extruded support, and constituted by a plurality of juxtaposed agglomerates, optionally at least one oxide or a sulphide of a metal constituted by copper, molybdenum, tungsten, iron, nickel or cobalt in which the sum S of metals from the group constituted by copper, molybdenum, tungsten, iron, nickel and cobalt is in the range 0 to 70% by weight, and characterized in that each of these agglomerates is present partly in the form of packs of flakes and partly in the form of needles being uniformly dispersed both around the packs of flakes and between the flakes.The invention also relates to its use in a fixed bed reactor to eliminate heavy metals from a hydrocarbon-containing feed.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: March 7, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Blaise Didillon, Slavik Kazstelan, Virgine Harle
  • Patent number: 5866749
    Abstract: Sulfur and mercaptans in reactive hydrocarbon streams are removed by contacting the hydrocarbons at mild temperatures with a hydrogen reduced metal oxide such as a hydrogen reduced copper, zinc and/or aluminum oxide.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: February 2, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Di-Yi (John) Ou
  • Patent number: 5789646
    Abstract: Medium-chain olefins containing as impurities 2-alkyl substituted isomers having a close boiling point are purified by (i) passing over a solid acid catalyst under mild conditions to selectively double-bond isomerise said impurities, and (ii) separating said isomerised olefins by distillation.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: August 4, 1998
    Assignee: Fina Research S.A.
    Inventors: Eric Romera, Christian Lamotte, Philippe Bodart
  • Patent number: 5463154
    Abstract: A method for acetylene hydrogenation which involves adding a member selected from the group consisting of arsine and phosphine to moderate the activity of acetylene hydrogenation catalysts while maintaining acceptable catalyst activity and avoiding the risk of product quality contamination by the acetylene converter moderator. The acetylene hydrogenation process involves adding arsine at a concentration level within the range of about 1 wppb-3 wppb to the gas, such as ethylene, containing acetylene to prevent temperature runaway during the exothermic acetylene hydrogenation reaction. By controlling the presence of arsine levels to such a relatively low level, temperature runaway during the highly exothermic acetylene hydrogenation reaction is prevented while maintaining acceptable catalyst activity levels for purposes of the acetylene hydrogenation reaction.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: October 31, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David R. Slim, Edgar L. Mohundro, Stephen M. Mayo
  • Patent number: 5396022
    Abstract: An alkane/fluoroalkane feed is treated with an acidic alumina to reduce the amount of fluoroalkane(s) in the feed. In a particularly preferred embodiment, the feed is treated with a sulfur-containing alumina so as to convert a major portion of fluoroalkane(s) to higher alkane(s).
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: March 7, 1995
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Marvin M. Johnson, Bruce B. Randolph
  • Patent number: 5378783
    Abstract: A highly polymerizable dicyclopentadiene (DCPD) monomer composition is obtained. The dicyclopentadiene so obtained is highly suitable for ring-opening polymerization by metathesis catalysts. The active DCPD yields articles with excellent physical properties upon in-mold polymerization.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: January 3, 1995
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Kin-ichi Okumura, Masao Torii, Hirotoshi Tanimoto, Motoyuji Yamato
  • Patent number: 5371313
    Abstract: A process is provided for the removal of tertiary butyl chloride from a hydrocarbon stream, wherein the hydrocarbon stream is contacted at a temperature of from about 130.degree. to about 170.degree. C. with a particulate calcium oxide containing from 1 to 10 mole % of a Group 3 or 4 compound and the hydrocarbon stream is recovered containing a reduced level of tertiary butyl chloride.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: December 6, 1994
    Assignee: Polysar Rubber Corporation
    Inventor: Andreas B. Ostrowicki
  • Patent number: 5336835
    Abstract: Impregnated carbon adsorbents for the removal of mercury from liquid hydrocarbons are used in a variety of applications. The activated carbon impregnated adsorbents in the present invention remain effective in removing mercury. Generally, these activated carbons are comprised of an activated carbon adsorbent impregnated with a composition containing metal halide or other reducing halide, supplemented according to the desired characteristics with other elements. The formulation of the impregnants in the present invention can be varied to adjust the performance characteristics so as to meet the desired mercury removal performance criteria, to achieve enhanced removal of organic bound mercury from liquid hydrocarbon, and to have other advantages useful in a variety of applications. These impregnated carbon adsorbents possess desirable qualities regarding their ability to remove even trace levels of mercury from liquid hydrocarbon without a leaching effect of the impregnants used.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: August 9, 1994
    Assignee: Calgon Carbon Corporation
    Inventor: James D. McNamara
  • Patent number: 5322927
    Abstract: Polyolefins are produced by a process which includes the steps of: polymerizing an olefin in a reaction zone; removing unreacted olefin from the polymer in a flash chamber and recycling the unreacted olefin to the reaction zone; stripping unreacted olefin from the polymer by passing a stripping gas through the polymer in a stripping zone; passing the unreacted olefin from the stripping zone at superatmospheric pressure through an adsorbent which selectively adsorbs olefins; depressurizing the adsorbent to produce a substantially pure olefin and recycling the substantially pure olefin to the reaction zone; purging the adsorbent bed with a nonadsorbable gas to remove residual unreacted olefin from the adsorbent; and passing the purge gas-unreacted olefin to the stripping zone to be used as stripping gas.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: June 21, 1994
    Assignee: The BOC Group, Inc.
    Inventors: Ramakrishnan Ramachandran, Virginia Malik
  • Patent number: 5302771
    Abstract: The present invention is directed to a process for removing impurities from hydrocarbon streams, preferably light ends, such as propylene and ethylene, which is preferably in the liquid phase, by contacting the hydrocarbon stream containing an initial amount of an impurity with a chemical adsorbent which is composed of a modified alumina having a surface area within the range of about 10 m.sup.2 /g to about 300 m.sup.2 /g and a pore volume within the range of about 0.1 mL/g to about 1 mL/g under contacting conditions effective to result in a purified hydrocarbon stream containing a reduced amount of impurities, i.e., less than about 0.5% relative to the initial amount of the acid impurity present in the hydrocarbon stream, and more preferably within the 10 ppb range.
    Type: Grant
    Filed: February 8, 1993
    Date of Patent: April 12, 1994
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Ramdas Venkatram, George E. Milliman
  • Patent number: 5292992
    Abstract: Conjugated diene impurities are removed from linear alpha-olefin products by contacting the linear alpha-olefin product with an acid treated montmorillonite clay which is effective to reduce the conjugated diene content of the linear alpha-olefin product, preferably to less than about 100 ppm, without substantial isomerization of the linear alpha-olefins to internal olefins.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: March 8, 1994
    Assignee: Ethyl Corporation
    Inventors: Stephen E. Belmont, Patrick G. Simms, Keith G. Anderson
  • Patent number: 5292991
    Abstract: A process of using a catalyst system for the oxidation of hydrocarbons, carbon monoxide, and the reduction of nitrogen oxides is provided. The unique synergy of the catalyst system, a combination of molecular sieves and noble metals, provides a system that partially or entirely replaces the need for rhodium as a catalyst in three way catalyst systems.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: March 8, 1994
    Assignee: Corning Incorporated
    Inventors: Irwin M. Lachman, Mallanagouda D. Patil, Louis S. Socha, Jr., Srinivas H. Swaroop, Raja R. Wusirika
  • Patent number: 5220100
    Abstract: A process for separating an alkali metal or alkali metal compound from a polymer comprising a conjugated diolefin and/or an alkenyl aromatic hydrocarbon monomer wherein a polymer and one or more alkali metal compounds is contacted with a suitable solid adsorbent. Preferably, the solid adsorbent will be selected from the group consisting of alumina, silica-alumina, silica and mixtures thereof.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: June 15, 1993
    Assignee: Shell Oil Company
    Inventors: Stephen N. Massie, Jaroslav G. Balas, Loralee A. Logan
  • Patent number: 5191143
    Abstract: A method for the preparation of isobutylene substantially free from tertiary butyl formate and peroxides from a tertiary butyl alcohol feedstock contaminated with tertiary butyl formate and peroxides wherein the feedstock is continuously brought into contact with a bed of a catalyst consisting essentially of sulfuric acid impregnated alumina under reaction conditions including a temperature of about 150.degree. to about 400.degree. C. and a pressure of about 0 to about 3000 psig. at the rate of about 0.5 to about 10 g of feedstock per hour per cc of catalyst, to form a reaction product substantially completely free from tertiary butyl formate and peroxides.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: March 2, 1993
    Assignee: Texaco Chemical Company
    Inventors: Wei-Yang Su, William A. Smith, Roya Tooloian
  • Patent number: 5157204
    Abstract: A process for removing carbon monoxide and free oxygen from hydrocarbon-containing fluids comprises contacting the fluid feed with at least one of several supported platinum-containing catalyst compositions so as to convert carbon monoxide and free oxygen to carbon dioxide, essentially without oxidizing the hydrocarbon(s).
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: October 20, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Scott H. Brown, John H. Kolts
  • Patent number: 5146041
    Abstract: Disclosed is a two-step method for separating isobutylene from a C-4 hydrocarbon fraction comprising:a) Reacting the C-4 fraction with a glycol in the presence of an acidic montmorillonite catalyst at a temperature of about 60.degree. to 160.degree. C. to yield the corresponding glycol mono-t-butyl ether, and subsequentlyb) reacting the intermediate glycol ether product over the same class of catalyst at a temperature of about 100.degree. to 220.degree. C. to regenerate the isolatable isobutylene.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: September 8, 1992
    Assignee: Texaco Chemical Company
    Inventor: John F. Knifton
  • Patent number: 5130109
    Abstract: A catalyst composition suitable for three-way conversion of internal combustion engine, e.g., automobile gasoline engine, exhaust gases, includes a catalytic material disposed in two discrete coats on a carrier. The first coat includes a stabilized alumina support on which a first platinum catalytic component is dispersed and bulk ceria, and may also include bulk iron oxide, a metal oxide (such as bulk nickel oxide) which is effective for the suppression of hydrogen sulfide emissions, and one or both of baria and zirconia dispersed throughout the first coat as a thermal stabilizer. The second coat, which may comprise a top coat overlying the first coat, contains a co-formed (e.g., co-precipitated) rare earth oxide-zirconia support on which a first rhodium catalytic component is dispersed, and a second activated alumina support having a second platinum catalytic component dispersed thereon.
    Type: Grant
    Filed: August 6, 1991
    Date of Patent: July 14, 1992
    Inventor: Chung-Zong Wan
  • Patent number: 5106484
    Abstract: The present invention is directed to a process for treating hydrotreated naphtha which involves treating the naphtha over massive nickel catalyst followed by treating the naphtha over a metal oxide under conditions effective for removing impurities from said naphtha to result in substantially purified naphtha, wherein the metal oxide is selected from the group of metal oxides having a free energy of formation of sulfide which exceeds said free energy of formation of platinum sulfide, such as manganous oxide. In so doing, naphtha in the gas phase in the presence of hydrogen is passed over the manganous oxide at a temperature within the range of about 800.degree. F. and 1100.degree. F., a hydrogen to oil molar ratio between about 1:1 and 6:1, a whsv between about 2 and 8, and pressure between about 50 and 300 psig; and the naphtha in the liquid phase at a temperature between about 300.degree. F. and about 350.degree. F., and whsv less than about 5 is passed over the massive nickel.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: April 21, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Murray Nadler, John F. Walsh, David S. Brown
  • Patent number: 5057644
    Abstract: This invention relates to a process for the purification of an alpha olefinic feedstock contaminated with internal olefins which process comprises contacting said alpha olefinic feedstock with ethylene in the presence of a catalyst comprising an organoborane promoted alkali metal doped molybdenum and/or rhenium oxide supported on an inorganic oxide support.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: October 15, 1991
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, Randall T. De Pue, Keith M. Kreitman
  • Patent number: 5035794
    Abstract: A method for removing a tertiary halide from an olefin hydrocarbon stream which comprises contacting the hydrocarbon stream with activated alumina at a temperature of about -40.degree. to about 120.degree. C.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: July 30, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Harvey E. Atwood
  • Patent number: 5025112
    Abstract: A method for purifying a cumene recycle stream by removing 2-phenyl-2-propanol and cumene hydroperoxide before the cumene is distilled and recycled to the peroxidation reactor which comprises reacting the recycle cumene in the presence of an acid treated montmorillonite clay of the formula:M.sub.x/n.sup.n+.sub..y H.sub.2 O(Al.sub.4-x Mg.sub.x) (Si.sub.8)O.sub.20 (OH).sub.4or in the presence of a catalyst comprising phosphoric acid on silica.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: June 18, 1991
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, Edward T. Marquis, John F. Knifton
  • Patent number: 4571445
    Abstract: A process is disclosed for reducing the level of sulfur compounds from liquid conjugated diolefin hydrocarbons by contacting said sulfur compound-bearing hydrocarbon liquids with sorbents prepared by combining particulate alumina with at least one compound decomposable to of sodium oxide, barium oxide, calcium oxide or a salt decomposable to potassium oxide, but excluding potassium carbonate and potassium bicarbonate and calcining. The process is particularly useful for removal of hydrogen sulfide and carbon disulfide from butadiene and isoprene.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: February 18, 1986
    Assignee: Shell Oil Company
    Inventor: Lynn H. Slaugh
  • Patent number: 4547620
    Abstract: A process for removing a halogen component from a halogen-containing organic compound, which comprises contacting an organic compound in the liquid state which is produced by using a halogen containing catalyst selected from the group consisting of Friedel-Crafts catalysts and Ziegler catalysts and contains the halogen component derived from said catalyst, with a hydrotalcite compound represented by the formulaM.sub.1-x.sup.2+ M.sub.x.sup.3+ (OH).sub.2+x-ny A.sub.y.sup.n-.mH.sub.2 OwhereinM.sup.2+ represents a divalent metal ion selected from the group consisting of Mg.sup.2+, Zn.sup.2+, Ca.sup.2+, Ni.sup.2+, Co.sup.2+, Mn.sup.2+ and Cu.sup.2+,M.sup.3+ represents a trivalent metal ion selected from the group consisting of Al.sup.3+, Fe.sup.3+ and Cr.sup.3+,A.sup.n- represents an anion having a valence of n selected from the group consisting of HCO.sub.3.sup.-, OH.sup.- and CO.sub.3.sup.2-, andx, y and m are each a positive number and satisfy the following conditions 0.1<x<0.5, 0.1<y<0.4, 0.ltoreq.
    Type: Grant
    Filed: February 24, 1984
    Date of Patent: October 15, 1985
    Assignee: Kyowa Chemical Industry Co. Ltd.
    Inventors: Shigeo Miyata, Noriko Iizima
  • Patent number: 4511710
    Abstract: Unwanted halogen values are removed from liquid resin, organic or hydrocarbon material by adding particulate crystalline lithium aluminate compounds to the liquid material to act as a halogen scavenger, then separating the crystalline aluminate compound from the liquid material.
    Type: Grant
    Filed: June 11, 1984
    Date of Patent: April 16, 1985
    Assignee: The Dow Chemical Company
    Inventors: Chun S. Wang, Kyle B. Benkendorfer, John L. Burba, III
  • Patent number: 4491516
    Abstract: The reaction rate for the hydrolysis of carbonyl sulfide in liquid petroleum hydrocarbons over alumina, such as propylene, is greatly increased by maintaining water in the hydrocarbons in an amount of one mole of water per mole of carbonyl sulfide to an upper limit of about ten moles of water per mole of carbonyl sulfide or about 30% of saturation of the hydrocarbons, whichever upper limit provides the lesser amount of water.
    Type: Grant
    Filed: November 22, 1983
    Date of Patent: January 1, 1985
    Assignee: Sun Refining and Marketing Company
    Inventors: Richard E. Polleck, Kenneth A. Scott, Robert E. Ledley
  • Patent number: 4423278
    Abstract: Color may be removed from colored polyphenylated alkane by contacting this material with certain adsorbants. The adsorbants provided comprise certain crystalline zeolites in a silica alumina matrix and bauxite clay having at least one material selected from the group consisting of ferric oxide, titanium oxide, and zirconium oxide, which is activated by sulfuric acid and then calcined to provide the effective adsorbant.
    Type: Grant
    Filed: January 17, 1983
    Date of Patent: December 27, 1983
    Assignee: Conoco Inc.
    Inventors: Kang Yang, James D. Reedy, S. E. McGuire, O. C. Kerfoot