Abstract: Norbornadiene [bicyclo(2.2.1)heptadiene-2,5] is dimerized to the exo-exo stereoisomer of the hexacyclic dimer of norbornadiene at both an excellent selectivity and conversion using an effective amount of a three component catalytic system of diethylaluminum chloride, ferric or ferrous or cobaltic or cobaltous acetylacetonate and bis(1,2-diphenylphosphino)ethane. The reaction rate is rapid. After hydrogenation the exo-exo hexacyclic dimer can be used as a component of high energy fuel for either jet or rocket propulsion.
Type:
Grant
Filed:
December 11, 1975
Date of Patent:
June 10, 1980
Assignee:
Suntech, Inc.
Inventors:
George Suld, Abraham Schneider, Harry K. Myers, Jr.
Abstract: A catalyst bed containing alumina pellets on which an active catalyst metal selected from iridium, nickel, niobium, and molybdenium has been deposited is employed to decompose a compound selected from deuterohydrazine, deuteroammonia, hydrazine, and ammonia to yield ammonia free deuterium and nitrogen or hydrogen and nitrogen at a temperature required for immediate use in a DF or HF laser which uses F atoms as the fuel. The decomposition temperature of the catalyst bed is maintained by a hypergolic reaction produced from reacting a fuel selected from the group consisting of hydrazine, methylhydrazine, 1,2-dimethylhydrazine, and blends of the same with an oxidizer selected from the group consisting of inhibited red fuming nitric acid, dinitrogen tetroxide, chlorine trifluoride, and chlorine pentafluoride. A laser employing ammonia free decomposition products of hydrazine and ammonia produced at a temperature between about 500.degree. C. and 900.degree. C. operates at a higher power output. When NH.sub.
Type:
Grant
Filed:
September 12, 1977
Date of Patent:
June 5, 1979
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Pasquale Martignoni, William M. Chew, Orval E. Ayers, James A. Murfree, Jr.
Abstract: A solid boron fuel burning ramjet engine having a cylindrical primary burner located within a ramjet combustion chamber. A portion of the air bypasses the primary burner to provide secondary burning at the outlet of the primary burner. Solid boron fuel pellets are ground to powder in a wire brush fuel mill with the fuel then being carried to the primary burner by air which is passed through the fuel mill.
Type:
Grant
Filed:
October 4, 1974
Date of Patent:
March 9, 1976
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Paul J. Ortwerth, Lowell W. Ormand, David B. Wilkinson