Using A Catalyst Patents (Class 60/299)
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Patent number: 8202819Abstract: A catalyst system to be used in an automobile exhaust gas purification apparatus which exerts excellent purification capability to a nitrogen oxide, even when hydrocarbon concentration varies, by subjecting exhaust gas discharged from an automotive internal engine to contacting with a catalyst, an exhaust gas purification apparatus using the same, and an exhaust gas purification method. A catalyst system etc.Type: GrantFiled: December 12, 2007Date of Patent: June 19, 2012Assignees: Daiichi Kigenso Kagaku Kogyo Co., Ltd., N.E. Chemcat CorporationInventors: Akira Kohara, Yoshiro Hirasawa, Katsuaki Katoh
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Publication number: 20120144811Abstract: Provided is an exhaust-treatment device for a diesel engine, said device being capable of suppressing engine noise. In a first stage P1 of an exhaust-temperature-raising process, a target engine speed is set to a prescribed first target speed R1 and an intake throttle valve 41 is set to a prescribed first degree of opening O1. In a second stage P2, the target engine speed is maintained at the first target speed R1 and the intake throttle valve 41 is set to a position more closed than the first degree of opening O1. When a set duration T2 for the second stage P2 has come to an end, the intake throttle valve 41 is at a second degree of opening O2, which is maintained in third and subsequent stages P3/P4. In said third and subsequent stages P3/P4, as a set duration T3/T4 for each stage P3/P4 passes, the target engine speed is updated to a target speed R2/R3 higher than the target speed R1/R2 during the immediately prior stage P2/P3, and the temperature of DPF1 upstream exhaust gas 12 is increased.Type: ApplicationFiled: August 3, 2010Publication date: June 14, 2012Applicant: KUBOTA CORPORATIONInventors: Shuichi Yamada, Yasuo Fujii, Katsushi Inoue, Yuuki Ishii, Kenta Mitamura
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Publication number: 20120144809Abstract: A catalytic converter module (16) houses two catalyst units (26,36) which are geometrically arranged in a serial manner. An exhaust gas stream (X) is processed in two parallel sub-streams which follow respective paths: a first path (A) which passes through the first catalyst unit (26) and bypasses the second catalyst unit (36), and a second path (B) which bypasses the first catalyst unit (26) and passes through the second catalyst unit (36). This enables exploitation of a catalyst having an effective area larger than that of the module housing 17 thus allowing the module (16) to be incorporated conveniently into available volumes whilst maintaining a low back pressure.Type: ApplicationFiled: May 20, 2010Publication date: June 14, 2012Applicant: AGCO SAInventor: Fredric Ducroquet
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Publication number: 20120137665Abstract: The present invention relates to a component (1) for a motor vehicle (5), particularly an exhaust system, which can be fastened to a carrier (4) of the motor vehicle (5) by means of at least one fixture (3), with a component housing (2) comprising a housing wall (6), wherein the respective fixture (3) comprises at least one holder (8) having an inner leg (9) extending parallel to the housing wall (6) and an outer leg (10) standing away from the housing wall (6) to the outside. The fatigue strength of the fixture (3) can be improved if the housing wall (6) comprises a passage opening (7), through which the outer leg (10) protrudes, while the inner leg (9) areally bears against the housing wall (6) in the interior (11) of the component housing (2).Type: ApplicationFiled: November 30, 2011Publication date: June 7, 2012Applicant: J. Eberspaecher GmbH & Co. KGInventor: Arnulf Spieth
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Publication number: 20120137664Abstract: The vehicle electrocatalyzer for recycling carbon dioxide to fuel hydrocarbons includes a main tubular member having a plurality of tubular catalytic cells, electrically connected in series disposed inside and separated from one another by semipermeable membranes allowing the passage of fluids, but not solids. The electrocatalyzer can be attached in the exhaust system where hydrogen could be generated by the electrolysis of water. Metallic copper, iron, carbonaceous materials (such as activated carbon, carbon nanomaterials, or graphite), metal oxides, or metal-supported catalysts may be used in each catalytic cell. A DC current connected across the cells is used to initiate reaction of the carbon dioxide with hydrogen gas. The resulting hydrocarbons are recycled back to the vehicle engine and used as a makeup fuel.Type: ApplicationFiled: July 25, 2011Publication date: June 7, 2012Applicants: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY, KING FAHD UNIVERSITY OF PETROLEUM AND MINERALSInventors: REYAD AWWAD KHALAF SHAWABKEH, ABDALLA MAHMOUD ABULKIBASH, MUHAMMAD A. AL-SALEH
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Patent number: 8191357Abstract: A method for use in conjunction with an exhaust gas post-treatment system for metering an ammonia-releasing reducing agent into the exhaust gas stream of an internal combustion engine installed in a motor vehicle and operating with excess air. A control unit meters the quantity of reducing agent as a function of a stored model and, during the operation of the internal combustion engine, determines, by comparison of a value proportional to the nominal emission or the nominal conversion stored in the control unit of the internal combustion engine for the associated operating point of the internal combustion engine and/or of the exhaust gas post-treatment system with a value proportional to the actual emission or the actual conversion metrologically determined by the control unit.Type: GrantFiled: March 8, 2010Date of Patent: June 5, 2012Assignee: Man Truck & Bus AGInventors: Andreas Döring, Florian Walde, Jochen Philipp, Henry Munitzk, Ralf Steinert
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Patent number: 8191355Abstract: A method to control valves in a cylinder operating in a multi-stroke cylinder mode. Valves are controlled to improve engine emissions as operating conditions vary.Type: GrantFiled: December 2, 2009Date of Patent: June 5, 2012Assignee: Ford Global Technologies, LLCInventor: Donald Lewis
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Publication number: 20120131911Abstract: An exhaust gas purifying catalyst (1) of the present invention includes anchor/promoter simultaneous enclosure particles (5) including catalyst units (13) which contain: noble metal particles (8); and anchor particles (9) as an anchor material of the noble metal particles (8) supporting the noble metal particles (8); promoter units (14) which are provided not in contact with the noble metal particles (8) and contain first promoter particles (11) having an oxygen storage and release capacity; and an enclosure material (12) which encloses both the catalyst units (13) and the promoter units (14), and separates the noble metal particles (8) and the anchor particles (9) in the catalyst units (13) from the first promoter particles (11) in the promoter units (14). The exhaust gas purifying catalyst (1) further includes second promoter particles (6) which have the oxygen storage and release capacity, and are not enclosed in the anchor/promoter simultaneous enclosure particles (5) by the enclosure material (12).Type: ApplicationFiled: November 15, 2010Publication date: May 31, 2012Applicant: Nissan Motor Co., Ltd.Inventors: Takamasa Nakagawa, Masanori Nakamura, Misaka Fujimoto, Naoki Kachi
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Patent number: 8187995Abstract: This invention relates to a cerium-zirconium-base composite oxide, which is useful, e.g., for the purification of exhaust gas discharged from combustion engines such as internal combustion engines and boilers and can release a high level of oxygen in a low temperature region, a method for producing the same, an oxygen storage/release component using the same, an exhaust gas purification catalyst, and an exhaust gas purification method. The cerium-zirconium-base composite oxide satisfies requirements (1) that the oxygen release initiation temperature is 380° C. or below, (2) that the oxygen release amount is not less than 485 ?mol/g, and further (3) that the oxygen release amount at 400° C. is not less than 15 ?mol/g.Type: GrantFiled: December 9, 2010Date of Patent: May 29, 2012Assignees: Daiichi Kigenso Kagaku Kogyo Co., Ltd., N.E. Chemcat CorporationInventors: Takahiro Wakita, Akira Kohara, Yasuharu Kanno, Hiroaki Omoto
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Patent number: 8186152Abstract: Disclosed is a turbomachine including at least one exhaust pathway along which exhaust is directed and released to ambient and at least one exhaust processor capable of removing regulated substances from the exhaust. One or more ambient air inlets are located at the at least one exhaust pathway upstream of the at least one exhaust processor. The at least one exhaust pathway is configured such that ambient air is capable of being urged into the at least one exhaust pathway through the one or more ambient air inlets by an acceleration of the exhaust along the at least one exhaust pathway. The ambient air urged into the at least one exhaust pathway reduces a temperature of the exhaust to increase effectiveness of the at least one exhaust processor. Further disclosed is a method for releasing turbomachine exhaust to ambient.Type: GrantFiled: July 23, 2008Date of Patent: May 29, 2012Assignee: General Electric CompanyInventors: Hua Zhang, David Wesley Ball, Jr., Thomas Francis Taylor
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Publication number: 20120124976Abstract: Disclosed is a catalytic unit that removes contaminates and particulates, including nitrogen oxides and soot, from diesel engine emissions without the use of chemical agents. The disclosed apparatus comprises a flow through device in fluid communication with a reduction unit, which is in fluid communication with a diesel particulate filter. The flow through device is coated with hematite and bixbyite in a ratio ranging from 1:1 to 9:1. The reduction unit is a catalytic substrate comprising one or more transition metals supported on a molecular sieve coated with an oxide catalyst. The diesel particulate filter has an oxide coating and a noble metal coating. The flow through device converts nitric oxide into nitrogen dioxide. The reduction unit converts most of the nitrogen dioxide into nitrogen, water, carbon monoxide and carbon dioxide. The diesel particulate filter traps remaining soot and coverts it and the carbon monoxide into carbon dioxide.Type: ApplicationFiled: November 24, 2010Publication date: May 24, 2012Applicant: AirFlow Catalyst Systems, Inc.Inventors: Thomas Richard Roberts, Thomas A. Iacubucci
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Publication number: 20120122660Abstract: An oxidation catalyst comprises an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilised ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) a majority of the at least one precious metal is located at a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface; (iii) at least one metal is present throughout the extruded solid body and in a higher concentration at a surface; (iv) at least one metal is present throughout the extruded solid body and in a coating layer(s) on a surface; or (v) a combination of (ii) and (iii).Type: ApplicationFiled: February 1, 2011Publication date: May 17, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Paul Joseph Andersen, Todd Ballinger, David Bergeal, Hsiao-Lan Chang, Hai-Ying Chen, Julian Cox, Ralf Dotzel, Rainer Leppelt, Jörg Werner Münch, Hubert Schedel, Duncan John William Winterborn
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Publication number: 20120117947Abstract: An exhaust gas after treatment system for an engine comprises an oxidation catalyst NOx adsorber wherein an oxidation catalyst compound and a NOx adsorber compound are disposed. A fuel injector is connected to and is in fluid communication with the oxidation catalyst NOx adsorber device for delivery of a hydrocarbon fuel thereto and an air pump is connected to and is in fluid communication with the oxidation catalyst NOx adsorber device for delivery of air thereto. The fuel injector and the air pump supply fuel and air to the oxidation catalyst NOx adsorber device for oxidation thereof and heating of the NOx adsorber compound to a NOx release temperature following shut down of the internal combustion engine.Type: ApplicationFiled: November 15, 2010Publication date: May 17, 2012Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.Inventors: Eugene V. Gonze, Michael J. Paratore, JR., Joshua Clifford Bedford
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Publication number: 20120117949Abstract: The invention relates to an exhaust gas post treatment system for an internal combustion engine, including an intake device for taking hydrocarbons into an exhaust gas pipe carrying the exhaust process gas from the internal combustion engine and a treatment device through which exhaust process gas flows downstream of the intake location and which increases the exhaust process gas temperature by means of oxidation of the hydrocarbons taken in. The invention specifies an exhaust gas post treatment system and a method for operating such an exhaust gas post treatment system which can be implemented cost-effectively.Type: ApplicationFiled: May 28, 2010Publication date: May 17, 2012Inventors: Rolf Miebach, Stephan Schraml, Peter Broll, Andreas Geisselmann, Stefan De Buhr, Stéphanie Frantz, Anke Woerz, Frank-Walter Schuetze
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Publication number: 20120117953Abstract: A three way catalyst comprises an extruded solid body comprising: 10-100% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilised ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on a surface of the extruded solid body; (ii) at least one metal is present throughout the extruded solid body and at least one precious metal is also carried in one or more coating layer(s) on a surface of the extruded solid body; or (iii) at least one metal is present throughout the extruded solid body, is present in a higher concentration at a surface of the extruded solid body and at least one precious metal is also carried in one or more coating layer(s) on the surface of the extruded solid body.Type: ApplicationFiled: February 1, 2011Publication date: May 17, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Paul Joseph Andersen, Ralf Dotzel, Kwangmo Koo, Rainer Leppelt, Jörg Werner Münch, Jeffery Scott Rieck, Hubert Schedel, Duncan John William Winterborn, Todd Howard Ballinger, Julian Peter Cox
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Publication number: 20120117943Abstract: An exhaust gas treating system for a gasoline engine, comprising an exhaust gas manifold comprising an annular reforming catalyst mounted within an annular housing and fuel supply means in direct fluid connection with the catalyst, an outlet for reformed fuel products in direct fluid connection with the catalyst, and means to permit a proportion of the engine-out exhaust gases to enter the annular catalyst to mix with fuel from the fuel supply means and to pass through the catalyst, the annular housing being located such that hot engine-out exhaust gases can flow around and through the centre of the housing, such that heat is transferred from the exhaust gases to the catalyst within the housing. The reformate may be passed to the inlet side of the engine, to improve overall efficiency of the engine, and/or may be mixed with exhaust gas before catalytic aftertreatment, to improve the control of emissions.Type: ApplicationFiled: May 20, 2011Publication date: May 17, 2012Applicant: Johnson Matthey Public Limited CompanyInventor: John Frederick Pignon
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Patent number: 8178063Abstract: The present invention relates to conversion of exhaust gas containing nitrogen oxide (NOx) such as NO, NO2 and N2O into N2 and H2O through catalytic reaction with injection of a reducing agent such as ammonia and urea. A fabrication method of zeolite honeycomb type catalyst for reducing nitrogen oxide of the present invention includes: (a) obtaining an inorganic binder by mixing and uniformly peptizing pseudo-boehmite, distilled water and a pH adjuster; (b) obtaining a paste by mixing and kneading zeolite, the inorganic binder, an organic binder and distilled water; (c) extruding the paste into an extrudate having a through pore of a regular structure; and (d) drying and heat treating the extrudate.Type: GrantFiled: December 24, 2008Date of Patent: May 15, 2012Assignee: SK Innovation Co., Ltd.Inventors: Junseong Ahn, Bongjae Kim, Sangho Lee, Okyoun Kim, Seunghoon Oh
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Publication number: 20120110987Abstract: An internal combustion engine in which an SOx trap catalyst (13) for trapping SOx contained in the exhaust gas contains an oxygen adsorbing and releasing material (54) which can adsorb SO2 contained in the exhaust gas and an SOx storage material (55) which can store SOx in the form of sulfates. The SO2 which is contained in the exhaust gas is chemically adsorbed at the oxygen adsorbing and releasing material (54) without being oxidized. If the temperature of the SOx trap catalyst (13) becomes higher than the start temperature of adsorbed SO2 movement, the SO2 which is chemically adsorbed at the oxygen adsorbing and releasing material (54) is oxidized and stored in the form of sulfates in the SOx storage material (55).Type: ApplicationFiled: July 23, 2009Publication date: May 10, 2012Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takamitsu Asanuma, Yoshihisa Tsukamoto, Kazuhiro Umemoto, Junichi Matsuo, Hiromasa Nishioka
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Publication number: 20120110983Abstract: Apparatus for attenuating particulate matter and volatile organic compounds in exhaust gases of diesel engines. The apparatus includes a housing disposed serially relative to exhaust gas flow. The housing encloses mechanical filters having gas orifices of different sizes, and after the filters, a low temperature, low restriction catalytic converter. Pressure may be monitored to infer clogging by particulates. Clogging may be annunciated by an indicating light. Individual filters may be contained within plural separate filter canisters, which may be removed for cleaning. The housing may be substantially of aluminum, having cooling fins and a longitudinally oriented mounting foot. Filters may be arranged such that their orifices are misaligned to promote separation of particulates from the exhaust gases.Type: ApplicationFiled: November 8, 2010Publication date: May 10, 2012Inventor: Charles Anthony Griffith
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Publication number: 20120110982Abstract: An exhaust assembly for a vehicle includes an exhaust pipe through which an exhaust gas flows substantially in a first direction. The exhaust pipe includes a central region. The assembly also includes a sensor in fluid communication with the exhaust pipe and an elongated tube extending from a first end toward a second end and disposed at least partially within the exhaust pipe. The first end of the tube receives at least a portion of the sensor. The tube includes an inlet opening and an outlet opening. The inlet opening generally faces the exhaust gas flowing within the central region in the first direction so that flow of the exhaust gas in the central region substantially directly enters the inlet opening. The tube directs the exhaust gas within the tube toward the sensor, and the exhaust gas within the tube flows out of the tube through the outlet opening.Type: ApplicationFiled: November 10, 2010Publication date: May 10, 2012Inventors: Mark E. McMackin, Raymond J. Sullivan, Richard L. Lewis, William L. Laga, Charles S. Payton
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Publication number: 20120110989Abstract: An exhaust-gas aftertreatment device for an internal combustion engine is contemplated. The device may comprises a catalytic converter, wherein the catalytic converter comprises a tubular member which defines a volume within which a catalytic converter substrate is located, and wherein the volume with the catalytic converter substrate communicates with an inlet portion for receiving exhaust gas emissions from the internal combustion engine and with an outlet portion for discharging the exhaust gas emissions after catalytic conversion thereof in the volume.Type: ApplicationFiled: November 8, 2011Publication date: May 10, 2012Applicant: VOLVO CAR CORPORATIONInventors: Mats Laurell, Jan Dahlgren, Staffan Ovesson
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Publication number: 20120110988Abstract: A NOx absorber catalyst comprising an extruded solid body comprises either: (A) 10-95% by weight of at least one binder/matrix component; and 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof, which catalyst comprising at least one metal comprising (a) at least one precious metal; and (b) at least one alkali metal or at least one alkaline earth metal, wherein (a) and (b) are carried in one or more coating layer(s) on a surface of the extruded solid body; or (B) 10-95% by weight of at least one binder/matrix component; and 5-80% by weight optionally stabilised ceria, which catalyst comprising at least one metal comprising (a) at least one precious metal; and (b) at least one alkali metal or at least one alkaline earth metal.Type: ApplicationFiled: February 1, 2011Publication date: May 10, 2012Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Ralf Dotzel, Rainer Leppelt, Elizabeth Hazel Mountstevens, Jörg Werner Münch, Paul Richard Phillips, Hubert Schedel, Daniel Swallow
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Patent number: 8173087Abstract: Provided are exhaust systems and components suitable for use in conjunction with gasoline direct injection (GDI) engines to capture particulates in addition to reducing gaseous emission such as hydrocarbons, nitrogen oxides, and carbon monoxides. Exhaust treatment systems comprising a three-way conversion (TWC) catalyst located on a particulate trap are provided. An exemplary particulate trap is a soot filter. Additional treatment components can be added downstream of the particulate trap, including NOx traps and SCR catalysts. The TWC catalyst can be coated on both the inlet side and the outlet side of the particulate trap. Alternatively, an oxidation catalyst can be deposited on a particulate trap. Methods of making and using the same are also provided.Type: GrantFiled: February 4, 2009Date of Patent: May 8, 2012Assignee: BASF CorporationInventors: Junmei Wei, Knut Wassermann, Yeujin Li
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Patent number: 8173088Abstract: A method for injection reductant into an exhaust gas and for evaporating and decomposing the reductant at an elevated temperature includes providing an exhaust pipe having an interior surface and disposing the pipe in fluid communication with and upstream of a catalyst. The method includes the steps of disposing an internal cone within the pipe generally parallel to the pipe, mounting an injector to the exterior of the pipe in fluid communication with the cone, injecting the reductant into the cone, and directing the exhaust gas in a passage between the interior surface of the pipe and the cone. The exhaust gas is directed within the cone. The flow of exhaust gas has an elevated temperature compared to an ambient. A further step includes creating a drag force on the injected reductant to increase travel time of the injected reductant from the injector to the catalyst.Type: GrantFiled: February 24, 2010Date of Patent: May 8, 2012Assignee: International Engine Intellectual Property Company, LLCInventors: Andrei Makartchouk, Justin O'Connor, Steve P. Gravante, Emad M. Amin, S. Scott Smith
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Patent number: 8172038Abstract: A silencer for a two-stroke engine includes a first chamber and a second chamber, wherein a flow channel is provided between an outlet of a combustion chamber and the first chamber. A high charge degree of the combustion chamber has a pressure ratio in the region of the outlet which reduces or prevents an escape of fresh gas from the combustion chamber. The flow channel between the outlet and the first chamber is flow-favorably shaped in such a manner that the exhaust gas that flows out of the outlet because of its mass inertia predominantly flows into the first chamber and following charging of the first chamber flows back again and as a result a back pressure is formed in the direction of the combustion chamber.Type: GrantFiled: April 13, 2009Date of Patent: May 8, 2012Assignee: DOLMAR GmbHInventor: Christian Kellermann
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Publication number: 20120102930Abstract: A system and method for desulfurizing an oxidation catalyst enhances fuel economy and reduces noxious exhaust gas emission as a consequence of increasing desulfurization period of the oxidation catalyst or shortening desulfurization time by reflecting desulfurization history consisting of natural desulfurization occurrence. The method may include detecting an inlet temperature of the oxidation catalyst, estimating natural desulfurization according to the inlet temperature of the oxidation catalyst, and resetting desulfurization time or desulfurization period by reflecting the estimated natural desulfurization.Type: ApplicationFiled: July 13, 2011Publication date: May 3, 2012Applicant: Hyundai Motor CompanyInventor: Jun Sung Park
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Publication number: 20120102928Abstract: An exhaust gas aftertreatment unit (1) having an encapsulated design is constructed in a modular manner from disk-shaped components (2), which each receive exhaust gas aftertreatment units (3) and which are connected to supply connections (24, 25) on the encapsulated side with the flow occurring in the direction of the disk plane, wherein the components (2) are surrounded by frames (5) that are consecutively, in particular elastically, connected and clamped to each other transversal to the disk plane.Type: ApplicationFiled: April 12, 2010Publication date: May 3, 2012Applicant: MTU Friedrichshafen GmbHInventors: Marc Hehle, Hans Sudmanns
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Publication number: 20120096854Abstract: An engine exhaust treatment system includes an upstream turbocharger fluidly coupled with an engine and disposed downstream from the engine along a flow path of exhaust gas generated by the engine, a downstream turbocharger fluidly coupled with the upstream turbocharger and disposed downstream from the upstream turbocharger along the flow path, and an after-treatment receptacle fluidly coupled with and disposed between the upstream and downstream turbochargers along the flow path. The after-treatment receptacle is configured to receive a first filter medium that removes at least one of particulates or a gas constituent from the exhaust gas generated by the engine. In an embodiment, the exhaust gas can flow through the upstream turbocharger prior to flowing through the after-treatment receptacle and can flow through the after-treatment receptacle prior to flowing through the downstream turbocharger along the flow path.Type: ApplicationFiled: October 21, 2010Publication date: April 26, 2012Inventor: Shashi KIRAN
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Patent number: 8161730Abstract: Various embodiments of an apparatus, system, and method are disclosed for reducing NOx emissions on an SCR catalyst. For example, according to one representative embodiment, an apparatus for reducing NOx emissions in an engine exhaust includes a NOx reduction target module that is configured to determine a NOx reduction requirement that includes an amount of NOx in the exhaust gas stream to be reduced on a selective catalytic reduction (SCR) catalyst. The apparatus also includes an ammonia target module that is configured to determine an ammonia addition requirement that includes an amount of ammonia added to the exhaust gas stream to achieve the NOx reduction requirement. The apparatus also includes a reductant target module that is configured to determine a reductant injection requirement that includes an amount of reductant added to the exhaust gas stream to achieve the ammonia addition requirement.Type: GrantFiled: April 30, 2008Date of Patent: April 24, 2012Assignee: Cummins IP, Inc.Inventors: John N. Chi, Weiwen Wang, Phanindra Garimella, Joan M. Wills, Joe V. Hill, Lisa A. Farrell, Abdul R. Ofoli
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Publication number: 20120090298Abstract: Features relating to engine efficiency and emissions controls are described. Systems, methods, articles or manufacture and the like can include features relating to integrated muffler and emissions controls for engine exhaust, water-injected internal combustion engine with an asymmetric compression and expansion ratio, controlled combustion durations for HCCI engines, piston shrouding of sleeve valves, low element count bearings, improved ports, and premixing of fuel and exhaust.Type: ApplicationFiled: October 11, 2011Publication date: April 19, 2012Inventor: James M. Cleeves
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Patent number: 8158551Abstract: Catalyst compositions for the treatment of vehicular exhaust gases are based on zirconium and cerium oxides, have a cerium oxide content of at most 50% by weight, a level of reducibility of at least 95% after calcination in air at 600°, and a specific surface area after calcination for 4 hours at 1100° of at least 15 m2/g; such compositions are prepared by forming an aqueous mixture containing zirconium and cerium compounds, by heating this mixture to at least 100° and, after the heating, adjusting it to a basic pH, by adding a surfactant additive to the precipitate obtained from this mixture and by calcinating the precipitate in an inert gas or under vacuum at a temperature of at least 900° and then in an oxidizing atmosphere at a temperature of at least 600°.Type: GrantFiled: March 19, 2007Date of Patent: April 17, 2012Assignee: Rhodia OperationsInventors: Stephan Verdier, Olivier Larcher, Emmanuel Rohart, Bernard Pacaud, Hirofumi Takemori, Eisaku Suda
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Patent number: 8151558Abstract: An exhaust system for use with an engine is disclosed. The exhaust system may have an exhaust passageway, a reduction catalyst located within the exhaust passageway, and a particulate filter located within the exhaust passageway upstream of the reduction catalyst. The exhaust system may also have an oxidation catalyst located within the exhaust passageway upstream of the reduction catalyst to provide a desired ratio of NO:NO2 to the reduction catalyst, and an exhaust gas recirculation loop. The exhaust gas recirculation loop may be situated to receive exhaust from the exhaust passageway at a location upstream of the oxidation catalyst and downstream of the particulate filter.Type: GrantFiled: January 31, 2008Date of Patent: April 10, 2012Assignee: Caterpillar Inc.Inventors: Wade J. Robel, James J. Driscoll
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Patent number: 8153089Abstract: An exhaust filter system, adapted for removing substances entrained in an exhaust gas from a nonroad engine, includes a casing having a filter cavity for communicating with an exhaust outlet of the generator and a filter core which includes a plurality of filtering loops, each having a plurality of air pores, coaxially received in the filter cavity, a plurality of filtering spacers each having a plurality of air meshes and positioned between each two filtering loops to define a plurality of air passages therebetween, and a catalyzing element for chemically reacting with the substances of the exhaust gas. Therefore, when the exhaust gas passes through the air passages of the filter core, the exhaust gas is evenly diffused to the filter cavity through the air pores and the air meshes so as to enhance a chemical reaction of the exhaust gas with the catalyzing element.Type: GrantFiled: December 21, 2009Date of Patent: April 10, 2012Inventor: Guo Xiang Fan
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Patent number: 8151561Abstract: A multi-cylinder internal combustion engine, wherein exhaust gas outlets of a first portion of the cylinders of the engine communicate with a first exhaust gas manifold section, and the exhaust gas outlets of the remaining cylinders communicate with a second exhaust gas manifold section. An oxidation catalytic converter is disposed in the first exhaust gas manifold section for converting nitric oxide into nitrogen dioxide. A hydrolysis catalytic converter is disposed in the second exhaust gas manifold section, wherein downstream of the catalytic converters the first and second exhaust gas manifold sections discharge into a common main exhaust gas manifold, in which is disposed a further catalytic converter. Upstream of the hydrolysis catalytic converter, a reduction agent can be introduced into the second exhaust gas manifold section; ammonia is adapted to be produced from the reduction agent via the hydrolysis catalytic converter.Type: GrantFiled: May 4, 2007Date of Patent: April 10, 2012Assignee: MAN Truck & Bus Österreich AGInventor: Christian Stiebinger
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Publication number: 20120079817Abstract: A diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC) and carbon monoxide (CO) is described. Also described is a novel washcoat composition including a surface-coated zeolite coated with at least one of zirconia and alumina, and a platinum group metal supported on a high surface area alumina.Type: ApplicationFiled: September 26, 2011Publication date: April 5, 2012Applicant: BASF CorporationInventors: Xinyi Wei, Stanley A. Roth
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Patent number: 8146351Abstract: An exhaust control system includes a temperature sensor, a temperature estimation module, and an exhaust condition adjustment module. The temperature sensor measures an outlet temperature of an exhaust gas downstream from an emission reduction device. The temperature estimation module estimates a highest temperature of the emission reduction device. The exhaust condition adjustment module controls operation of the exhaust control system based on the highest temperature of the emission reduction device.Type: GrantFiled: June 5, 2009Date of Patent: April 3, 2012Inventors: Jianwen Li, Michael Christopher Luckham, Paul Jasinkiewicz, Rebecca J Darr, Rahul Mital
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Publication number: 20120073273Abstract: An exhaust purification system of an internal combustion engine including an ammonia oxidation catalyst device and an ammonia holding device arranged immediately upstream of the ammonia oxidation catalyst device is provided. The ammonia holding device has a solid acid, holds ammonia to restrain the ammonia from flowing into the ammonia oxidation catalyst device when a temperature of the ammonia oxidation catalyst device is within a N2O producing temperature range, and releases the held ammonia to make the ammonia flow into the ammonia oxidation catalyst device when the temperature of the ammonia oxidation catalyst device is out of the N2O producing temperature range.Type: ApplicationFiled: June 16, 2009Publication date: March 29, 2012Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takamitsu Asanuma, Kazuhiro Umemoto
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Publication number: 20120073274Abstract: Internal combustion engine according to the invention comprises an exhaust treatment apparatus provided in an exhaust passage, a burner apparatus provided upstream of the exhaust treatment apparatus for increasing exhaust temperature, and a variable mechanism for varying valve timing of an exhaust valve. The variable mechanism is controlled in such a manner that, when a flow amount of exhaust gas passing through the burner apparatus is equal to or more than a predetermined value, the exhaust valve opens in the middle of piston descending during an expansion stroke. When the exhaust valve is opened at this timing, high-temperature exhaust or combustion gas existing in combustion chamber at this time is sent to the burner apparatus, making it possible to increase atmosphere gas temperature of the burner apparatus. Therefore, even when flow amount of exhaust gas is increased to the predetermined value or more, sufficient ignition performance can be ensured.Type: ApplicationFiled: April 29, 2010Publication date: March 29, 2012Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Koki Uno, Eiji Hashimoto, Taiichi Mori, Masahiro Fujiwara, Shunichi Hanada, Chika Kanba
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Publication number: 20120077669Abstract: Described is a process for the preparation of a catalyst comprising the steps of: (i) providing one or more support materials; (ii) providing one or more polymers on the support material; and (iii) providing one or more metals on the one or more supported polymers; wherein in step (ii) the one or more polymers do not comprise cross-linked polymers and/or polymers which have been reacted with a cross-linking agent. Also described is a catalyst obtained or obtainable according to said process, as well as the use of the catalyst, in particular in a method for the treatment of automobile engine exhaust gas.Type: ApplicationFiled: September 28, 2011Publication date: March 29, 2012Applicants: BASF Corporation, BASF SEInventors: Torsten Müller-Stach, Attilio Siani, Torsten Neubauer, Xinyi Wei
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Patent number: 8141342Abstract: In a region where the engine load is less than a first predetermined value, only a second exhaust valve that opens and closes a second exhaust passageway that bypasses a turbine of a supercharger is opened. In a region where the engine load is greater than or equal to the first predetermined value and less than a second predetermined value, both the second exhaust valve and a first exhaust valve that opens and closes a first exhaust passageway that leads to the turbine are opened. In a region where the engine load is greater than or equal to the second predetermined value, only the first exhaust valve is opened. A predetermined value for the time of lean combustion is set lower than a predetermined value for the time of stoichiometric combustion.Type: GrantFiled: June 12, 2008Date of Patent: March 27, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hiroyuki Hokuto, Naoya Kaneko
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Patent number: 8141340Abstract: According to one representative embodiment, an apparatus for determining the degradation of a selective catalytic reduction (SCR) catalyst of an engine exhaust aftertreatment system includes a system properties module configured to store at least one system dynamics property value of the exhaust system at a first time and receive the at least one system dynamics property value of the exhaust aftertreatment system at a second time subsequent to the first time. The apparatus also includes a system dynamics module configured to determine a storage capacity of the SCR catalyst based on a comparison between the at least one system dynamic property value at the first time and the at least one system dynamic property value at the second time. Additionally, the apparatus includes an SCR catalyst degradation factor module configured to determine an SCR catalyst degradation factor based at least partially on the storage capacity of the SCR catalyst.Type: GrantFiled: April 30, 2009Date of Patent: March 27, 2012Assignee: Cummins IP, IncInventors: Phanindra Garimella, Joan M. Wills, John N. Chi, Neal W. Currier, Aleksey Yezerets
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Patent number: 8141351Abstract: A pre-catalyst device configured to be disposed upstream of a main aftertreatment device of an engine exhaust system. An oxidizing material is disposed on an inlet face of the pre-catalyst device, where the oxidizing material is configured to oxidize engine exhaust before the engine exhaust reaches the main aftertreatment device of the engine exhaust system.Type: GrantFiled: April 25, 2008Date of Patent: March 27, 2012Assignee: Cummins Filtration IP, Inc.Inventors: Chetan Ponnathpur, Thomas M. Yonushonis, Javier Franco
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Patent number: 8136350Abstract: A catalytic muffler that treats the exhaust gases of an internal combustion engine. The catalytic muffler includes a catalyst chamber, a catalyst disposed in the catalyst chamber, an upstream chamber disposed upstream of the catalyst, an exhaust inlet configured to receive exhaust gases, an exhaust outlet configured to discharge converted gases converted by the catalyst to the atmosphere, and further configured to receive secondary air, and a passageway communicating between the exhaust outlet and the upstream chamber, and configured to provide the secondary air received by the exhaust outlet to the upstream chamber.Type: GrantFiled: May 28, 2008Date of Patent: March 20, 2012Assignee: Briggs & Stratton CorporationInventors: David Duch, Gary Gracyalny, John Thiermann
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Patent number: 8137648Abstract: A diesel engine exhaust treatment system and method is provided which includes a platinum group metal trapping device (16) comprising cerium oxide or a perovskite material positioned between a diesel oxidation catalyst and an SCR catalyst. The platinum group metal trapping device traps trace amounts of platinum group metals which may be released from the diesel oxidation catalyst during engine operation and prevents them from accumulating on the SCR catalyst, preventing potential contamination of the SCR catalyst as well as ensuring that the performance of the SCR catalyst is uninhibited.Type: GrantFiled: October 12, 2010Date of Patent: March 20, 2012Assignee: Ford Global Technologies, LLCInventors: Hungwen Jen, Giovanni Cavataio, James W. Girard
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Patent number: 8137635Abstract: An exhaust gas purification device for an internal combustion engine, provided in an exhaust passage of the internal combustion engine, includes: a filter-shape carrier adapted to trap particulate matter in exhaust gas; and an oxidation catalyst supported on the filter-shape carrier and comprising: a particulate oxygen storage material; and an oxygen ion conductive material supported around the oxygen storage material in surface contact therewith.Type: GrantFiled: November 25, 2008Date of Patent: March 20, 2012Assignee: Mitsubishi Jidosha Kogyo Kabushiki KaishaInventors: Hiroshi Tanada, Maynko Suwa, Koichi Taniyama
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Patent number: 8137636Abstract: A catalyst composition for facilitating the oxidation of soot from diesel engine exhaust is provided. The catalyst composition includes a catalytic metal selected from Pt, Pd, Pt—Pd, Ag, or combinations thereof, an active metal oxide component containing Cu and La, and a support selected from alumina, silica, zirconia, or combinations thereof. The platinum group metal loading of the composition is less than about 20 g/ft3. The catalyst composition may be provided on a diesel particulate filter by impregnating the filter with an alumina, silica or zirconia sol solution modified with glycerol and/or saccharose, impregnating the filter with a stabilizing solution, and impregnating the filter with a solution containing the active metal oxide precursor(s) and the catalytic metal precursor(s). The resulting catalyst coated diesel particulate filter provides effective soot oxidation, exhibits good thermal stability, has a high BET surface area, and exhibits minimal backpressure.Type: GrantFiled: May 20, 2010Date of Patent: March 20, 2012Assignee: Ford Global Technologies, LLCInventors: Albert Chigapov, Alexei Dubkov, Brendan Carberry
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Patent number: 8136344Abstract: At the start-up of an engine, the ignition timing and the air-fuel ratio are controlled to prevent overload onto the volume of ISC air and decreased torque and torque difference. The fuel condition based on the amount of ignition timing correction to inhibit rotational fluctuation during idling is determined and the fuel quantity based on the result is corrected. Right after an engine has started and until a pilot burner is created in the heat spot of the catalyst, the ignition retard control is mainly executed, and at the time when it is determined that a pilot burner has been created in the catalyst's heat spot, the lean air-fuel ratio control is to be executed instead of the ignition retard control. Furthermore, when the ignition retard control changes to the lean air-fuel ratio control, the state transition control is executed along the equivalent ISC air volume line so as not to cause torque fluctuation.Type: GrantFiled: November 27, 2007Date of Patent: March 20, 2012Assignee: Hitachi, Ltd.Inventors: Seiji Asano, Hisahiro Ooba, Masahiro Osato, Kenji Takada, Mitsuru Nagase, Hiroshi Sekine
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Publication number: 20120060472Abstract: An exhaust aftertreatment system that receives an exhaust flow from a lean-burn engine and a method for treating the exhaust flow are described. The exhaust aftertreatment system may include a three-way-catalyst, an oxidation catalyst, and a NH3—SCR catalyst. The three-way-catalyst passively generates NH3 from native NOX contained in the exhaust flow when an A/F mixture supplied to the engine is cycled from lean to rich. The generated NH3 is then stored in the NH3—SCR catalyst to facilitate NOX reduction when the A/F mixture supplied to the engine is cycled back to lean. The oxidation catalyst is located upstream of the NH3—SCR catalyst and operates to lower the NO to NO2 molar ratio of the NOX fed to the NH3—SCR catalyst. The oxidation catalyst comprises perovskite oxide particles.Type: ApplicationFiled: September 14, 2010Publication date: March 15, 2012Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.Inventors: Wei Li, Chang H. Kim, Kevin L. Perry, Paul M. Najt, Kushal Narayanaswamy
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Publication number: 20120060474Abstract: An internal combustion engine is coupled to an electric power generator. An exhaust manifold for the engine includes an exhaust gas conduit. A housing includes a catalyst in fluid communication with the conduit to receive exhaust produced by the engine. The catalyst is operable to reduce one or more constituents of the exhaust.Type: ApplicationFiled: May 5, 2011Publication date: March 15, 2012Inventors: Mark E. Turpin, Clayton Smith, Gary A. Salmonson, Brian G. Haupt, Shawn John Kipka, Kurt Butz, Lee Severtson, David W. Strombeck
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Patent number: 8133842Abstract: A method of manufacturing an emissions treatment device for an internal combustion engine includes disposing washcoated fibers between layers of a porous substrate to form multiple substantially parallel layers with a first group of layers at least partially open along the entire length of the layer. The porous substrate may be a stainless steel mesh with the method further including washcoating the substrate prior to disposing the washcoated fibers between the layers.Type: GrantFiled: October 21, 2010Date of Patent: March 13, 2012Assignee: Ford Global Technologies, LLCInventors: Ray Willey, Bret A. Zimmerman, David J. Kubinski, Diana D. Brehob