With Solid Sorbent Patents (Class 62/480)
  • Patent number: 5505059
    Abstract: A heat driven solid adsorbent bed heat pump system and method of operating same in which the refrigerant is used both to heat and cool the beds and to heat or cool the space to be conditioned.
    Type: Grant
    Filed: January 13, 1994
    Date of Patent: April 9, 1996
    Assignee: Gas Research Institute
    Inventor: David M. Sanborn
  • Patent number: 5503222
    Abstract: A carousel heat exchanger is provided for air conditioning or waste heat recovery applications. The carousel heat exchanger includes a plurality of heater tubes disposed radially about a rotational axis. Each of the heater tubes is sealed and has a hollow bore which is uniformly lined with a solid adsorbent and contains a refrigerant. A baffle is disposed about the rotational axis such that to the heater tubes extend transversely therethrough. The baffle defines an outer zone to the outside of the baffle and an inner zone to the inside of the baffle and divides the heater tubes into a first internal zone of the heater tubes located in the outer zone and a second internal zone of the heater tubes located in the inner zone. A plurality of vanes is disposed radially along the rotational axis. The vanes extend transversely from both sides of the baffle, defining a plurality of axial flow segments that subdivide the inner and outer zones.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: April 2, 1996
    Assignee: UOP
    Inventor: Stephen R. Dunne
  • Patent number: 5497630
    Abstract: The disclosure is directed to an apparatus and method to increase the coefficient of performance (COP) of hydride heat pump systems to compete with the performance of conventional vapor compression and absorption refrigeration systems. The disclosure is particularly directed to hydrides with van't Hoff curves that cross, whereby the regeneration of the refrigerant hydride occurs at a temperature above the crossing, thereby allowing for a major fraction of the energy required for the regeneration to be supplied by the heat of absorption of the refrigerant. Additionally, the COP can be increased by selection of hydrides, and the kinetics of the system can be improved by the use of heat pipes and phase change materials.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: March 12, 1996
    Assignee: Thermal Electric Devices, Inc.
    Inventors: Charles Stein, Edward M. Redding
  • Patent number: 5477706
    Abstract: In a sorption reaction system comprising one or more first reactors in which a refrigerant is alternately adsorbed and desorbed, and one or more second reactors in which a refrigerant is alternately desorbed and adsorbed, respectively, and having a cooling loop for directing heat transfer fluid to and from said reactors, a method of cooling an adsorbing reactor comprises directing liquid phase heat transfer fluid having a phase change from liquid to gas at a temperature at or below the temperature of adsorption to an adsorbing reactor in heat exchange exposure to the adsorbent utilizing vaporized heat transfer fluid for driving the liquid heat transfer fluid in the cooling loop. The refrigerant may be used as the heat transfer fluid. The invention includes apparatus for carrying out the method.
    Type: Grant
    Filed: October 21, 1994
    Date of Patent: December 26, 1995
    Assignee: Rocky Research
    Inventors: Lance D. Kirol, Uwe Rockenfeller
  • Patent number: 5477705
    Abstract: A refrigerating and heating apparatus using a solid sorbent includes at least one compartmentalized reactor having solid sorbents able to fix at least one refrigerating fluid and in contact with a heat exchanger, a mechanism for the alternate circulation of a heat transfer fluid between hot and cold sources, by use of the exchanger, in order to create in the sorbent a temperature front passing through the compartments, a condenser and an evaporator. The thermal conductivity and permeability of the sorbent are lower parallel to the displacement of the heat transfer fluid in the exchanger than perpendicular thereto. Gaseous refrigerating fluid circulating means create a pressure front passing through the compartments with the temperature front.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: December 26, 1995
    Assignee: Societe Anonyme: Elf Aquitaine
    Inventor: Francis Meunier
  • Patent number: 5463879
    Abstract: A simple heat cascading regenerative sorption heat pump process with rejected or waste heat from a higher temperature chemisorption circuit ("HTCC") powering a lower temperature physisorption circuit ("LTPC") which provides a 30% total improvement over simple regenerative physisorption compression heat pumps when ammonia is both the chemisorbate and physisorbate, and a total improvement of 50% or more for LTPC having two pressure stages. The HTCC contains ammonia and a chemisorbent therefor contained in a plurality of canisters, a condenser-evaporator-radiator system, and a heater, operatively connected together. The LTPC contains ammonia and a physisorbent therefor contained in a plurality of compressors, a condenser-evaporator-radiator system, operatively connected together. A closed heat transfer circuit ("CHTC") is provided which contains a flowing heat transfer liquid ("FHTL") in thermal communication with each canister and each compressor for cascading heat from the HTCC to the LTPC.
    Type: Grant
    Filed: January 4, 1994
    Date of Patent: November 7, 1995
    Assignee: California Institute of Technology
    Inventor: Jack A. Jones
  • Patent number: 5456093
    Abstract: A desiccant cooling apparatus and process using a solid adsorbent and refrigerant wherein the solid adsorbent is selected from the group consisting of zeolite Y-85, a low cerium rare earth exchanged Y-84 and a rare earth exchanged LZ-210, and the adsorbent is bonded directly to the heat exchange tubes within the device by a novel slip coating process resulted in significant improvements in thermal efficiency and overall performance.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: October 10, 1995
    Assignee: UOP
    Inventors: Stephen R. Dunne, Albert S. Behan
  • Patent number: 5445217
    Abstract: A cooling and heating device using a chemical reaction comprising at least four reactors, each containing a salt capable of chemically reacting with a gas, an enclosure for receiving gas from the reactors and an enclosure for conveying gas to the reactors. The device is arranged so that, during the chemical reaction, two reactors are at the same higher pressure level, while two reactors are at the same lower pressure level. According to the invention, the device also comprises a heat-transporting fluid circuit for transferring heat between the reactors, operating at the same presure level.
    Type: Grant
    Filed: October 7, 1993
    Date of Patent: August 29, 1995
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Jean Castaing, Pierre Neveu
  • Patent number: 5442931
    Abstract: A heat pump system utilizing a simplified configuration having a single adsorbent reactor structure is disclosed. In a preferred embodiment, a carbon-ammonia adsorbent-reactant combination is employed. Heating and cooling of the reactor is accomplished directly by heating and cooling of the ammonia.
    Type: Grant
    Filed: August 2, 1994
    Date of Patent: August 22, 1995
    Assignee: Gas Research Institute
    Inventors: William Ryan, William M. Worek, Weixiang Zheng
  • Patent number: 5440899
    Abstract: The invention concerns a heat accumulator consisting of a vessel having a wall which is at least partially heat conducting, the vessel contains a material which exothermally absorbs and endothermally desorbs a heat transporting substance, the absorbing and desorbing material in particular being sodium sulphide and being adhered to the wall of the vessel by means of a fibrous material such as cellulose. Also provided is a process for the production of such a heat accumulator comprising, applying a fibrous material to the inner wall of a closeable vessel, preferably via conducting protrusions, and subsequently contacting the absorbing and desorbing material being in a molten and/or hydrated state with the fibrous material.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: August 15, 1995
    Assignee: De Beijer Raadgevend Technisch Bureau B.V.
    Inventors: Hendrikus A. De Beijer, Jan W. Klein Horsman
  • Patent number: 5419156
    Abstract: A regenerative sorption compressor assembly for use in a sorption compressor/refrigerator system. The regenerative sorption compressor assembly of the present invention comprises a series of sorption compressor elements connected to a flowing loop of heat transport fluid. The compressor elements are heated and cooled by the heat transport fluid. At some point in the loop the fluid path is broken and the fluid is diverted to a heat source. At another point in the loop the fluid path is broken and the fluid is diverted to a heat sink. The points at which the heating and cooling flows are diverted are switched from compressor element to element in the direction of fluid flow at such a rate that the thermal capacity rate of the fluid in the heat transport loop relative to the moving switch point is equal and opposite to the thermal capacity rate of the compressor assembly relative to the switch point.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: May 30, 1995
    Assignee: Aerojet-General Corporation
    Inventor: Philip H. Sywulka
  • Patent number: 5408847
    Abstract: A rotary sorption heat pump for heating or cooling comprised of a plurality of sorption modules, each of which has at least two different zones of heat and mass transfer. The sorption modules are mounted to a frame which is adapted for rotation. Thermosyphons are used to transfer heat between different zones of sorption modules.
    Type: Grant
    Filed: May 26, 1993
    Date of Patent: April 25, 1995
    Inventor: Donald C. Erickson
  • Patent number: 5404728
    Abstract: A sorption method and sorption medium container arrangement utilizes two sorption medium containers and at least one heat exchanger for use with each sorption medium container for absorbing or emitting heat. Each sorption medium container is filled with a sorption medium that can adsorb an operating medium by releasing heat and can desorb or expel the operating medium by absorbing heat. The sorption medium container arrangement also includes steam sources or steam troughs which are connected to the sorption medium containers. The steam source or trough is designed to provide or receive operating medium steam. A heat carrier medium flows through the heat exchanger of the first sorption medium container during a first partial operation phase wherein the sorption medium is cooled and the first sorption medium container is heated.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: April 11, 1995
    Assignee: Zeo-Tech (Zeolith Technology) GmbH
    Inventor: Peter Maier-Laxhuber
  • Patent number: 5398747
    Abstract: A method and system for preheating one or more auxiliary components of an automotive vehicle having an internal combustion engine or other means for producing hot exhaust gases. The method and system use waste thermal energy extracted from engine exhaust gases produced when the engine is running. This thermal energy is stored in a special thermal storage material in the form of chemical potential by a direct dehydration/hydration process. The thermal energy is released during a cold start and used to warm ambient air, which may then be conveyed to one or more desired auxiliary components, such as the catalytic converter, the passenger cabin or the like.
    Type: Grant
    Filed: September 28, 1992
    Date of Patent: March 21, 1995
    Assignee: Tufts University
    Inventor: Ioannis N. Miaoulis
  • Patent number: 5396775
    Abstract: Apparatus for cooling components or subassemblies of equipment at one or more locations comprises a first reactor located at a remote location from said equipment, and a second reactor located in heat exchange communication with a component or subassembly of said equipment, each of said first or second reactors containing a different complex compound of a polar refrigerant and a metal salt, wherein the equilibrium temperature of the complex compound in said first reactor differs from the equilibrium temperature of the complex compound in said second reactor by between about 10.degree. C. and about 150.degree. C. at the same operating pressure, heating means for heating a complex compound in said first reactor, and conduit means for directing polar refrigerant between said reactors.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: March 14, 1995
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5388637
    Abstract: An integral adsorbent-heat exchanger apparatus for use in ammonia refrigerant heat pump systems. The apparatus has a finned tube heat exchange member. A bonded, pyrolyzed activated carbon adsorbent matrix, formed from a mixture of activated carbon particles and resol bonder, is tightly adjoined to the fins and the tube to form an integral apparatus. The integral apparatus is capable of withstanding repetitive adsorption and desorption cycles without the matrix becoming unbonded and without the matrix becoming unadjoined from the fins and tube. The apparatus permits very high rates of adsorption and desorption of refrigerant and very high rates of heat transfer between the refrigerant and the heat transfer fluid.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: February 14, 1995
    Assignee: California Institute of Technology
    Inventors: Jack A. Jones, Andre H. Yavrouian
  • Patent number: 5388423
    Abstract: Method of and apparatus for heating or cooling a motor vehicle passenger compartment which communicates with a supply air duct for supplying a stream of air to the compartment and a used air duct for exhausting air from the compartment. A heat source in the form of a sorption reactor transfers heat energy to the air stream, with the reactor being provided with a sorbent such as zeolite or the like. The air stream passes through the reaction chamber of the reactor for extracting moisture from the air stream and adding adsorption heat to the air stream. The air stream then passes through an inflow duct before passing through the reactor, and passes from the reactor through an outflow duct at the outlet end of the reactor. A fresh air duct is provided for selectively feeding fresh air into the inflow duct, and an exhaust air duct opening into the atmosphere is provided for selectively communicating the outflow duct with the exhaust air duct.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: February 14, 1995
    Assignee: Behr GmbH & Co.
    Inventor: Noureddine Khelifa
  • Patent number: 5386705
    Abstract: A regenerative adsorbent heat pump process and system for cooling and heating a space. A sorbent is confined in a plurality of compressors of which at least four are first stage and at least four are second stage. The first stage operates over a first pressure region and the second stage over a second pressure region which is higher than the first. Sorbate from the first stage enters the second stage. The sorbate loop includes a condenser, expansion valve, evaporator and the compressors. A single sorbate loop can be employed for single-temperature-control such as air conditioning and heating. Two sorbate loops can be used for two-temperature-control as in a refrigerator and freezer. The evaporator temperatures control the freezer and refrigerator temperatures. Alternatively the refrigerator temperature can be cooled by the freezer with one sorbate loop. A heat transfer fluid is circulated in a closed loop which includes a radiator and the compressors. Low temperature heat is exhausted by the radiator.
    Type: Grant
    Filed: August 27, 1993
    Date of Patent: February 7, 1995
    Assignee: California Institute of Technology
    Inventor: Jack A. Jones
  • Patent number: 5384101
    Abstract: Reaction rates in chemisorption reactions involving solid reactants and gaseous ligands are improved by maintaining optimized solid density throughout the reaction. Methods and apparatus which restrict volumetric solid expansion, compression of the solid reactant, and mixture with inert solid porous or particulate materials are disclosed.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: January 24, 1995
    Assignee: Rocky Research
    Inventor: Uwe Rockenfeller
  • Patent number: 5369960
    Abstract: A refrigeration system for cooling foodstuffs in an aircraft body having a deck and a space (26) below the deck, uses a surface type heat exchanger (7) positioned for a heat exchange with the environment of the aircraft. A catering container (1) is constructed as a cooler box, and at least one refrigeration device (21) is exchangeably mounted in the space below the deck. The refrigeration device (21) is equipped with at least one modular refrigeration unit (6) connected through respective pipes or conduits (8, 9) to the surface type heat exchanger (7). The refrigeration device (21) is connected by further conduit means (3, 10) to the cooler box (1). The temperature difference between inside and outside of the aircraft is efficiently used for the refrigeration.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: December 6, 1994
    Assignee: Deutsche Aerospace Airbus GmbH
    Inventors: Hans-Juergen Mueller, Ralf Schliwa, Thomas Scherer, Harald Kull
  • Patent number: 5360057
    Abstract: Apparatus for simultaneously supplying heating and cooling or refrigeration comprises first and second reactors each containing a complex compound of a metal salt and a gaseous refrigerant adsorbed thereon, a condenser, refrigerant conduit means for directing the refrigerant to and from the condenser and reactors, and fluid conduit means for directing heat transfer fluid in heat exchange communication with the condenser and selectively with the reactors. In another embodiment each reactor contains a different salt and instead of a condenser, energy is recovered through heat exchange fluid in heat exchange communication with the reactors.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: November 1, 1994
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5359864
    Abstract: A cooling apparatus has a cooling vessel, containing a liquid as a thermal medium which absorbs latent heat by evaporation, and an absorber which absorbs the vapor of the liquid. The cooling vessel further contains one or more units of encapsulated gel refrigerant submerged in the liquid, which impede temperature increase of the liquid when an operation of the cooling apparatus is temporarily suspended. An alternative cooling vessel has one or more upwardly extending members partially submerged in the liquid and covered with liquid soaking material, so that the liquid soaks up in the material by capillary action and accelerates its evaporation. Another alternative cooling vessel has plural liquid tanks, one arranged on another, so that the total area for the evaporation of the liquid is multiplied. An additional alternative cooling vessel has a plurality of rotatable fins, partially submerged in the liquid, for accelerating the evaporation of the liquid.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: November 1, 1994
    Assignee: Sanden Corp.
    Inventor: Yasuo Yamada
  • Patent number: 5351493
    Abstract: This system utilizes three kinds of metal hydrides, MH1, MH2, and MH3, having the highest, an intermediate, and the lowest equilibrium hydrogen pressures, respectively, in the order mentioned, each kind of metal hydrides being enclosed in two sets of respective metal-hydride containers. While hydrogen flows from the metal hydride MH3 to the metal hydrides MH2 and MH1 in one set, hydrogen flows from the metal hydrides MH2 and MH1 metal hydride MH3 in other set such that the cold heat generated by hydrogen dissociation from the metal hydride MH2 in said other set is utilized to cool the metal hydride MH1 of said one set for efficient hydrogen absorption by the metal hydride MH1, and the cold heat generated by hydrogen dissociation from the metal hydride MH1 of said other set is provided for refrigeration.
    Type: Grant
    Filed: December 8, 1992
    Date of Patent: October 4, 1994
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Naoki Hiro, Masato Osumi
  • Patent number: 5347815
    Abstract: A regenerative adsorbent heat pump process and system is provided which can regenerate a high percentage of the sensible heat of the system and at least a portion of the heat of adsorption. A series of at least four compressors containing an adsorbent is provided. A large amount of heat is transferred from compressor to compressor so that heat is regenerated. The process and system are useful for air conditioning rooms, providing room heat in the winter or for hot water heating throughout the year, and, in general, for pumping heat from a low temperature to a higher temperature.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: September 20, 1994
    Assignee: California Institute of Technology
    Inventor: Jack A. Jones
  • Patent number: 5347828
    Abstract: A heat pump that includes organic hydride (12) and metal hydride (2) systems cools a conditioned space (6) by transferring heat from the conditioned space to a metal hydride bed (4), thereby decomposing a metal hydride in the bed to form H.sub.2. The H.sub.2 flows to a vapor space (14) in the liquid hydride system (12) and reacts with a dehydrogenation product at a catalytic surface (32) in the vapor space to form an organic hydride and an exothermic heat of reaction. The heat pump also may be used to upgrade waste heat by transferring heat from a relatively low temperature heat source to decompose the metal hydride. The exothermic heat of reaction may then be removed from the vapor space and used for space heating. In both embodiments, the metal hydride bed (4) may be regenerated by supplying an endothermic heat of reaction to the catalytic surface (32), thereby dehydrogenating the organic hydride to form H.sub.2. The H.sub.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: September 20, 1994
    Assignee: United Technologies Corporation
    Inventor: Arthur S. Kesten
  • Patent number: 5339639
    Abstract: A refrigerator includes a cylinder containing a bed of adsorbent material and a gas, e.g. carbon dioxide. A piston compresses the gas which is adsorbed by the adsorbent material and the heat of adsorption is dissipated by fins to atmosphere. The piston, when retracted, decompresses the gas which desorbs from the adsorbent material. Repeated compression and decompression of the gas causes a cold zone to be created within the material which is thermally linked to a location to be refrigerated.
    Type: Grant
    Filed: July 2, 1992
    Date of Patent: August 23, 1994
    Assignee: The BOC Group Plc.
    Inventor: Michael E. Garrett
  • Patent number: 5339649
    Abstract: First and second refrigerating circuits respectively cause first and second adsorbing bodies to alternately adsorb and release first and second coolants. In the first refrigerating circuit, when the first adsorbing body is heated, it releases the first coolant. The released first coolant is cooled, and discharged through an expansion valve so that a part of the first coolant is liquefied. The resultant latent heat of vaporization can be utilized to cool an object to be cooled. Thereafter, the first coolant is adsorbed when the first adsorbing body is cooled. In the second refrigerating circuit, when the second adsorbing body is heated, it releases the second coolant. The released second coolant is cooled by a liquefied-gas-type cooler, and discharged through an expansion valve so that a part of the second coolant is liquefied. The resultant latent heat of vaporization is utilized to cool the first adsorbing body of the first refrigerating circuit.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: August 23, 1994
    Assignee: Kabushikikaisha Equos Research
    Inventors: Masao Kawai, Yoshihiro Kyotani, Hideki Aruga, Toshihiro Shiimado, Yoshihisa Ito, Koji Hori
  • Patent number: 5335510
    Abstract: An improved apparatus for staging solid-vapor complex compounds comprises heat exchange means for transferring heat from super-heated refrigerant vapor from a desorbing reactor to cooled refrigerant vapor directed to an adsorbing reactor. In another embodiment a liquid subcooler is used to cool liquid refrigerant passing from a condenser to an evaporator with cold refrigerant gas directed to an adsorbing reactor from the evaporator.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: August 9, 1994
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5325916
    Abstract: Layered adsorbent-substrate tubes are prepared by a method comprising heating the surface of an aluminum substrate, contacting the surface of the substrate with a slurry containing the adsorbent and a binder, and heating the coatings to form hardened surfaces which can have excellent adsorption and mechanical properties in devices for cooling or heating by adsorption of refrigerating fluid on a solid adsorbent.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: July 5, 1994
    Assignee: UOP
    Inventors: Stephen R. Dunne, Albert S. Behan
  • Patent number: 5309985
    Abstract: Apparatus and process are disclosed for sorption heat pumping at high efficiency in a smooth and continuous manner using a multiplicity of stationary triplex sorption modules. The hermetically sealed trisorption modules, each of which contains at least two solid sorbents, are free of pumps, valves, restrictors, or any similar devices for flow control of refrigerant or sorbent. The apparatus contains no moving parts beyond a small number of control and motive devices for the heat transfer fluids. The preferred refrigerant is ammonia and the preferred sorbents are the solid type with monovariant equilibrium, e.g., BaCl.sub.2, SrCl.sub.2, CaCl.sub.2, MnCl.sub.2, FeCl.sub.2 and SrBr.sub.2.The apparatus is preferably adapted for residential or small-scale commercial space-conditioning applications, and operates at double-effect efficiency in both the heating and cooling modes without inter-module heat transfer.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: May 10, 1994
    Inventor: Donald C. Erickson
  • Patent number: 5295358
    Abstract: An improved apparatus for staging solid-vapor complex compounds comprises heat exchange means for transferring heat from super-heated refrigerant vapor from a desorbing reactor to cooled refrigerant vapor directed to an adsorbing reactor. In another embodiment a liquid subcooler is used to cool liquid refrigerant passing from a condenser to an evaporator with cold refrigerant gas directed to an adsorbing reactor from the evaporator.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: March 22, 1994
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5291753
    Abstract: An improved apparatus for staging solid-vapor complex compounds comprises heat exchange means for transferring heat from super-heated refrigerant vapor from a desorbing reactor to cooled refrigerant vapor directed to an adsorbing reactor. In another embodiment a liquid subcooler is used to cool liquid refrigerant passing from a condenser to an evaporator with cold refrigerant gas directed to an adsorbing reactor from the evaporator.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: March 8, 1994
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5291750
    Abstract: A micro-climate heating/cooling method and apparatus for vests and the like operates with reaction of working fluid, such as water, with an adsorbent material. A lightweight pump is the only moving component needed to provide the desired heating and cooling requirements.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: March 8, 1994
    Assignee: Mainstream Engineering Corporation
    Inventors: Clyde F. Parrish, Robert P. Scaringe
  • Patent number: 5291942
    Abstract: A process and apparatus for multi-stage sorption and desorption of process gas using a multiple concentric tube apparatus having a thermal supply gas pass through the central conduit creating a thermal wave passing through a high temperature sorption/desorption salt in the innermost annular compartment desorbing prior sorbed process gas followed by passing the thermal wave to an outer annular compartment which together with heat of sorption of process gas in an inner annular compartment desorbs process gas in the outer annular compartment. The process is useful in heat pumps and gas evaporative cooling cycles.
    Type: Grant
    Filed: May 24, 1993
    Date of Patent: March 8, 1994
    Assignee: Gas Research Institute
    Inventor: William A. Ryan
  • Patent number: 5289690
    Abstract: The invention disclosed herein relates to an apparatus for being detachably connected to a chemical or refrigeration system for selectively receiving and dispensing a gaseous refrigerant or chemical from and to that system, respectively, including a vessel having a chamber capable of maintaining a pressurized gas therein, gas inlet means for directing the gas: to and from the chamber, and connection means for connecting the gas inlet to a refrigeration or chemical system; a plurality of heat exchange conduits exposed in the chamber for directing heat exchange fluid therethrough and fluid inlet and outlet means communicating exteriorly of the vessel for directing the fluid to and from the conduits, respectively; and a solid adsorbent capable of alternately adsorbing and desorbing the gaseous refrigerant or chemical and positioned in thermal communication with each of the heat exchange conduits.
    Type: Grant
    Filed: August 6, 1992
    Date of Patent: March 1, 1994
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5279359
    Abstract: Apparatus and process are disclosed for sorption heat pumping at high efficiency in a smooth and continuous manner using a multiplicity of intermittent cycle triplex sorption modules. The hermetically sealed trisorption modules, each of which contains at least two solid sorbents, are free of pumps, valves, restrictors, or any similar devices for flow control of refrigerant or sorbent. The preferred refrigerant is ammonia and the preferred sorbents are the solid type with monovariant equilibrium, e.g., BaCl.sub.2, SrCl.sub.2, CaCl.sub.2, MnCl.sub.2, FeCl.sub.2 and SrBr.sub.2. The apparatus is preferably adapted for residential or small-scale commercial space-conditioning applications, and operates at double-effect efficiency in both the heating and cooling modes without inter-module heat transfer.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: January 18, 1994
    Inventor: Donald C. Erickson
  • Patent number: 5272891
    Abstract: Intermittent sorption cycles with fixed heat supply and removal and comprised of a generator/absorber (4), a condenser (2), and a receiver/evaporator (10) are adapted and simplified so as to require at most only two control valves (8) and (15) for their operation. With an integral thermosyphon (6) for absorption heat removal, only a single refrigerant charge is necessary. The two valves are advantageously combined into a single three-way ball valve, and key gravity drains (14) and (17) are provided. Applications include hot water heating, solar refrigeration, and steam generation.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: December 28, 1993
    Inventor: Donald C. Erickson
  • Patent number: 5271239
    Abstract: Apparatus for cooling components or subassemblies of equipment at one or more locations comprises one or more first and one or more second reactors, remote from said equipment, each reactor containing a complex compound of a polar refrigerant and a metal salt a first heater in said first reactor and a second heater in said second reactor for heating the complex compound therein, respectively, a condenser, remote from said equipment, for converting gaseous refrigerant to a liquid phase, and means for cooling said condenser with ambient air, a plurality of one or more evaporators, each in independent heat exchange communication with one or more of said components or subassemblies within said equipment, valve means cooperating with first conduit means for alternately directing polar refrigerant from said first and said second reactors, respectively, to said condenser, and second conduit means for directing ammonia from said condenser to said evaporators and third conduit means for directing ammonia from said eva
    Type: Grant
    Filed: November 19, 1991
    Date of Patent: December 21, 1993
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5263330
    Abstract: An apparatus comprises a plurality of two or more reaction chambers, each having a different compound therein comprising a solid reactant adsorbent and a gaseous reactant adsorbed thereon, each of said compounds having a different gaseous refrigerant vapor pressure, substantially independent of the concentration of the gaseous reactant, and having an ascending order of gaseous reactant vapor pressure wherein the adsorption temperature of a lower vapor pressure compound at adsorption temperature of a lower vapor pressure compound at adsorption pressure is at least 8.degree..degree.C.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: November 23, 1993
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5241831
    Abstract: An improved apparatus for staging solid-vapor complex compounds comprises heat exchange means for transferring heat from super-heated refrigerant vapor from a desorbing reactor to cooled refrigerant vapor directed to an adsorbing reactor. In another embodiment a liquid subcooler is used to cool liquid refrigerant passing from a condenser to an evaporator with cold refrigerant gas directed to an adsorbing reactor from the evaporator.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: September 7, 1993
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5237827
    Abstract: The use of molecular sieve zeolite for the effective utilization of low-grade heat sources such as solar energy. A system includes molecular sieve zeolite and a low pressure polar gaseous fluid adapted to be adsorbed by the zeolite which is in a closed container and circuit which includes a condenser and a gas expansion cooler member. When the container is heated, a gas is given off from the zeolite, cooled in a condenser, and thereafter expanded for cooling purposes. In one embodiment, the cooled gas is received in a further container having the zeolite therein and subsequently, upon cooling of the first container, the gaseous fluid may be returned thereto via again a condenser and gas expansion cooler member to provide further cooling. In another embodiment, zeolite is formed by sintering same to form a pressure resistant divider across the container.
    Type: Grant
    Filed: October 2, 1990
    Date of Patent: August 24, 1993
    Inventor: Dimiter I. Tchernev
  • Patent number: 5222375
    Abstract: A cooler for use with gaseous process fluids such as air containing a vapor has a vapor adsorption unit for passing process air through an adsorption media to dry the air, a heat exchanger to control the temperature of the heat adsorption media and process air, a vapor removal system for removing the adsorbed vapor from the adsorption media, and a humidification unit to add a vaporizable liquid to the dried process air, so as to vaporize the liquid into the dried process air. Thus, heat in the process air is utilized for the latent heat of vaporization of the liquid to reduce the temperature in such process air, while maintaining a predetermined humidity level in said air. The vaporizable liquid may be sprayed into the process fluid as a mist. Excess cooled coalesced liquid may be used in a heat exchanger to precool the process fluid before it enters the humidifier.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: June 29, 1993
    Inventors: Wayne E. Conrad, Richard S. Phillips
  • Patent number: 5186020
    Abstract: A portable cooling apparatus comprising a thermally insulated container having a cooling chamber therein, a lid providing access to the chamber, an evaporator including a heat exchange surface exposed in the cooling chamber, a reactor assembly secured adjacent the container comprising one or more reactors containing an ammoniated complex compound or coordinative complex compound of other suitable polar refrigerant, heating means for heating the complex compound, and a valved conduit for directing refrigerant between the reactor and the evaporator assembly. In another embodiment, the cooling apparatus comprises an inside reactor assembly, replacing the evaporator, and an outside reactor assembly each assembly containing a different complex compound.
    Type: Grant
    Filed: July 19, 1991
    Date of Patent: February 16, 1993
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5184669
    Abstract: An improved heat accumulator based on chemical solid/gas storage reactions is provided. A solid/gas reaction storage material resides in a container which can be charged and discharged by means of a heat carrier gas. Thus, through chemical reaction, a reaction component is released or absorbed. In order to provide the simplest structure possible with minimal loss of useful energy, the storage material is arranged in the container in a continuously apportioned configuration and such that the heat carrier gas flows directly around it. The reaction components are released into or drawn from the region through which the heat carrier gas flows.
    Type: Grant
    Filed: October 18, 1990
    Date of Patent: February 9, 1993
    Assignee: Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V.
    Inventors: Rainer Tamme, Herbert Kanwischer
  • Patent number: 5174367
    Abstract: In order to make a thermal utilization system operable in a stable and efficient condition regardless the variation of the operating heat source used, the system is provided with three hydrogen absorbing alloys having different pressure-temperature characteristics, wherein absorption/desorption of hydrogen gas is performed in two steps, i.e. the hydrogen gas desorbed from a first alloy is absorbed by a second alloy at a predetermined pressure, and is absorbed by the third alloy at a higher pressure after it is desorbed from the second alloy in a case when the temperature of the operating heat source is low, while the hydrogen gas desorbed from the first alloy is directly transported from the first alloy to the third alloy to be absorbed there when the temperature of the operating heat source is high.
    Type: Grant
    Filed: March 9, 1990
    Date of Patent: December 29, 1992
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Kenji Nasako, Takahiro Yonesaki, Akio Furukawa, Ikuo Yonezu, Masakazu Moroto, Naoki Hiro, Toshihiko Saito
  • Patent number: 5165247
    Abstract: The invention disclosed herein relates to an apparatus for being detachably connected to a chemical or refrigeration system for selectively receiving and dispensing a gaseous refrigerant or chemical from and to that system, respectively, including a vessel having a chamber capable of maintaining a pressurized gas therein, gas inlet means for directing the gas to and from the chamber, and connection means for connecting the gas inlet to a refrigeration or chemical system; a plurality of heat exchange conduits exposed in the chamber for directing heat exchange fluid therethrough and fluid inlet and outlet means communicating exteriorly of the vessel for directing the fluid to and from the conduits, respectively; and a solid adsorbent capable of alternately adsorbing and desorbing the gaseous refrigerant or chemical and positioned in thermal communication with each of the heat exchange conduits.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: November 24, 1992
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5161389
    Abstract: An apparatus capable of rapidly cooling or freezing a composition comprising a walled housing member having a cooling chamber and a door for accessing the cooling chamber from the exterior of the housing, an evaporator and a blower for circulating cold air from the evaporator to the cooling chamber, first and second reactors each containing a complex compound consisting of a metal salt and ammonia adsorbed thereon, heaters in the reactors for heating the complex compound, and valves and conduits for directing ammonia from the evaporator to the reactors, from the reactors to the condenser, and from the condenser to the evaporator, and control means for sequentially operating the heaters for alternately heating the complex compounds in the reactors, operating the air handling means and one or more of the valves, and switching means for turning the apparatus on and off.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: November 10, 1992
    Assignee: Rocky Research
    Inventors: Uwe Rockenfeller, Lance D. Kirol
  • Patent number: 5154067
    Abstract: A portable cooler for cooling an article by utilizing the endothermic and exothermic phenomenon pertaining to a chemical reaction is disclosed, in which an adsorbent and a working medium are sealed in a reaction chamber defined between an inner wall and an outer wall, a working medium retaining member is disposed on the inner wall inside the reaction chamber for holding therein the working medium, the working medium retaining member being spaced from the adsorbent disposed on the outer wall, and a heater is held in contact with the adsorbent for regenerating the same, at least a part of said outer wall constituting a heat radiating portion.
    Type: Grant
    Filed: December 13, 1991
    Date of Patent: October 13, 1992
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Takeshi Tomizawa, Koji Arita
  • Patent number: 5127470
    Abstract: An apparatus for heat recovery from an exhaust gas with waste heat from a heat machinery unit, which comprises a pair of first and second chemical heat-storing units, each comprising a vessel containing a reactant material capable of releasing a reaction-susceptible material upon heating with an exhaust gas and emitting the heat of reaction upon combination with the reaction-susceptible material and a heat exchanger piping provided in the vessel and through which a heat transfer medium is passed. The high temperature gas from the heat machinery unit is applied to the vessel in one of the first and second chemical heat-storing units, thereby resulting in a reaction for leasing the reaction-susceptible material.
    Type: Grant
    Filed: August 9, 1990
    Date of Patent: July 7, 1992
    Assignees: Hitachi Ltd., Hitachi Engineering Co., Ltd.
    Inventors: Yoshiaki Inaba, Kenji Tokunaga, Akihiro Shimizu, Tetsuzo Kuribayashi
  • Patent number: 5111668
    Abstract: A relatively lightweight cooling device and method utilizing adsorption of perspirated water vapor to permit evaporative cooling of a person wearing a sealed suit for defined time periods. The device can be constructed in the form of a rectangular pad or the like having an open cell foam adjacent the person's skin to permit static transport of perspirated water vapor to an adsorbent layer. The open cell foam or a separate material acts as a thermal insulator to prevent heat flow back toward the skin resulting from the exothermic heat of adsorption produced by the adsorbent layer. In lieu of static movement of the water vapor, a small fan can be operatively associated with the fan for actively moving the water vapor to a single point to enhance the evaporative cooling, particularly where a smaller amount of adsorbent material is used.
    Type: Grant
    Filed: February 26, 1991
    Date of Patent: May 12, 1992
    Assignee: Mainstream Engineering Corp.
    Inventors: Clyde F. Parrish, Robert P. Scaringe