Abstract: Furnace operation includes consecutive cycles of a heating step, a stopping step and a restarting step. The fuel and/or the oxidizing agent is preheated upstream of the furnace by indirect exchange with the discharged fumes through a medium passing through a chamber. A first wall separates the fumes from the medium in the chamber. The fuel and/or oxidizing agent is separated from the medium in the chamber by a second wall. During restarting, the medium's flow rate Dm is regulated to limit the heating rate of the first wall until it reaches the operational temperature at an end thereof.

Abstract: A glass has a basic soda-lime-silica glass portion, and a colorant portion including total iron as Fe2O3 selected from the group of total iron as Fe2O3 in the range of greater than zero to 0.02 weight percent; total iron as Fe2O3 in the range of greater than 0.02 weight percent to less than 0.10 weight percent and total iron as Fe2O3 in the range of 0.10 to 2.00 weight percent; redox ratio in the range of 0.2 to 0.8, and tin and/or fin compounds, e.g. SnO2 greater than 0.000 to 5.0 weight percent. In one embodiment of the invention, the glass has a fin side and an opposite air side, wherein the tin side of the glass is supported on a molten fin bath during forming of the glass. The tin concentration at the tin side of the glass is greater than, less than, or equal to the fin concentration hi “body portion” of the glass. The “body portion” of the glass extending from the air side of the glass toward the fin side and terminating short of the tin side of the glass.

Abstract: An apparatus and method of refining molten glass are disclosed. An upstream vessel contains molten glass, a downstream vessel is arranged downstream of the upstream vessel, and vacuum refining vessels are located between the upstream vessel and the downstream vessel and are in separate, alternating fluid communication with the upstream vessel and in separate, alternating fluid communication with the downstream vessel.

Abstract: A ceramic electronic component including a ceramic element assembly, an external electrode, and an underlying layer. In this ceramic electronic component, the underlying layer is formed on the ceramic element assembly, the external electrode is formed on the underlying layer, the underlying layer is formed of a metal material and a glass material containing a silicon atom, and the metal material exists in a highly dispersed state in the glass material.

Abstract: There is provided a process for producing molten glass, which is capable of easily increasing the H2O content in glass melt with excessive generation of convection of the glass melt being reduced.

Abstract: Submerged combustion burner panels, submerged combustion melters including one or more of the panels, and methods of using the same. The burner panel includes a panel body including a fluid-cooled portion and a protective non-fluid cooled portion. An exterior surface defined by the fluid-cooled portion, and an interior surface defined by the protective non-fluid cooled portion, exterior and interior referring to an SCM in which the panel is installed. The fluid-cooled portion has at least one burner support passage of diameter (d1) extending from the exterior surface to a seam where the fluid-cooled and protective non-fluid cooled portions meet supporting at least one fluid-cooled SC burner having a fluid-cooled burner tip attached to a burner body protruding away from the seam. The protective non-fluid-cooled portion has a combustion products flow passage of diameter (d2)<(d1). The burner panels promote burner life and melter campaign length.

Abstract: Primary inorganic feedstock material is introduced into the melting region of an SCM melter. The material is heated with a burner to form a turbulent melt matrix. The burner exit is disposed below the top surface of the turbulent melt matrix. A mixture of secondary inorganic material and organic material is introduced into the melting region below the top surface of the turbulent melt mixture. The mixture is heated with the burner to incorporate the secondary inorganic material into the turbulent melt matrix and combust at least some of the organic material to produce heat.

Abstract: The present invention relates to the supplying power to burners for oxy-fuel combustion glass melting furnaces, including a fuel injecting means and a hot oxygen power supplying means, the dispensing of oxygen being carried out so as to develop a staged combustion, a fraction of the oxygen being concurrently injected into the fuel, said oxygen being supplied essentially without heating prior to the supplying thereof into the fuel injecting means.

Abstract: A submerged combustion melter and burner therefor. The burner may include a first tube having a scaled distal end and a second tube concentric to the first tube, the second tube having a partially sealed distal end with an opening for receiving the first tube, where an annular space is defined between the first and second tubes. The burner further includes a first gas port in the sealed distal end of the first tube, the first gas port supplying a first gas, a second gas port in a distal end of the second tube, the second gas port supplying a second gas to the annular space, and a nozzle on the proximate ends of the first and second tubes.

Abstract: Methods and systems for de-stabilizing foam produced in submerged combustion melters. A molten mass of glass and bubbles is flowed into an apparatus downstream of a submerged combustion melter. The downstream apparatus includes a floor, a roof and a wall connecting the floor and roof, but is devoid of submerged combustion burners and other components that would increase turbulence of the molten mass. The molten mass has foam on at least a portion of a top surface of the molten mass. One method includes directly impinging an impinging composition onto at least a portion of the foam in the downstream apparatus. Systems for carrying out the methods are described.

Abstract: The invention relates to a method of combustion in a furnace provided with a burner comprising an inlet for oxidizer comprising between 10% and 30% of oxygen and an inlet for fuel terminating in the furnace outside the oxidizer inlet and at a distance therefrom of between 0.3 and 4 times the equivalent diameter of the oxidizer inlet, said oxidizer entering the furnace at a speed of between 10 and 60 m/s. This method permits a significant reduction in nitrogen oxide emissions and is suitable for glass furnaces in particular.

Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.

Abstract: Described are a burner and its method of operation that are useful in providing heat within an enclosure such as the forehearth associated with a glassmelting furnace.

Abstract: Ion transport membranes are integrated with a glass melting furnace and a float glass bath. Only feeds of air, steam and hydrocarbon are necessary for producing hot oxygen for the melting furnace and a mixture of nitrogen, carbon dioxide, and hydrogen for the float glass bath.

Abstract: Methods and systems for controlling bubble size and bubble decay rate of glass foams formed during submerged combustion melting. Flowing a molten mass of foamed glass comprising molten glass and bubbles entrained therein into an apparatus downstream of a submerged combustion melter. The downstream apparatus has a floor, a roof, and a sidewall structure connecting the floor and roof. The foamed glass has glass foam of glass foam bubbles on its top surface, and the downstream apparatus defines a space for a gaseous atmosphere above and in contact with the glass foam. The downstream apparatus includes heating components to heat or maintain temperature of the foamed glass. Adjusting composition of the atmosphere above the glass foam, and/or contacting the foam with a liquid or solid composition controls bubble size of the glass foam bubbles, and/or foam decay rate.

Abstract: The object of the invention is a continuous method for obtaining glass, comprising steps consisting of: charging raw materials upstream of a furnace, along which a plurality of burners is disposed, obtaining a mass of molten glass, and then leading said mass of molten glass to a zone of the furnace situated further downstream, at least one burner disposed in the region of this zone being fed with an over-stoichiometric quantity of oxidant, and then, forming a glass sheet, said glass sheet having a chemical composition that comprises the following constituents in an amount varying within the weight limits defined below: SiO2 60-75%? Al2O3 0-10% B2O3 0-5%, preferably 0? CaO 5-15% MgO 0-10% Na2O 5-20% K2O 0-10% BaO 0-5%, preferably 0, SO3 0.1-0.4%? Fe2O3 (total iron) 0 to 0.015%,?? Redox 0.1-0.3.

Abstract: Apparatus includes a first and second conduits configured to form an annulus between them. An adjustable structure includes a body having an upper surface, a lower surface, and a circumferential surface abutting a portion of the internal surface of the second conduit. The structure is adjustable axially in relation to and removably attached to the first conduit via a hub. The hub defines a central passage for fuel or oxidant. The body has one or more non-central through passages configured such that flow of an oxidant or fuel therethrough causes the fuel or oxidant to intersect flow of fuel or oxidant exiting from the central passage in a region above the upper surface of the body.

Abstract: A submerged burner for a glass- or rock-melting furnace, including a plurality of in-line injectors, each injector including a cylinder-shaped mixing chamber, with an ejection orifice, a fuel-supply duct and an oxidant-supply duct opening into the mixing chamber at the cylinder jacket in a direction causing a tangential flow of the fuel and of the oxidant relative to the cylinder jacket, and a duct system making it possible for a coolant to flow inside the burner, and, preferably on either side of the alignment of injectors, placed parallel to and all along the latter, solid metal sides rising from the injectors, and protective partitions situated on the top of the solid metal sides.

Abstract: Glasses are provided that are highly transparent and have very good resistance to solarisation. The resistance to solarisation is favoured to a special extent by the production method. The concentrations of reduced polyvalent ion species are reduced by targeted use of bubbling with an oxidising gas. Methods for producing glasses and to the uses thereof, particularly as core glasses in optical waveguides, are also provided.

Abstract: The present invention relates to a glass melting furnace, comprising a channel-shaped melting tank, the batch material being charged at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which 80% of the combustion energy is produced by oxycombustion, oxygen being supplied continuously from a production plant located nearby or via a gas pipe from remotely located plants, characterized in that the furnace is fitted with oxygen storage means such that, should continuous supply cease, the furnace can operate at least in a temperature-maintaining mode for a maximum time of eight hours.

Abstract: In a method for producing a fluorophosphate optical glass comprising melting a glass raw material to give a molten glass, and refining, homogenizing and then quickly quenching the molten glass to produce the fluorophosphate optical glass, even if the glass is flown from a refining tank that is set to a high temperature to an operation tank that is set to a low temperature, bubbles are not generated in the glass. The content of Fe in terms of Fe2O3 and the content of Cu in terms of CuO is controlled so that the total of the contents of Fe and Cu is 20 ppm or more, and the obtained fluorophosphate optical glass has such transmittance property that the internal transmittance in terms of a thickness of 10 mm becomes 98% or more at a wavelength region of at least from 400 to 500 nm.

Abstract: Low-carbon monolithic refractories are provided. Methods of manufacturing glass employing low-carbon monolithic refractories are also provided. Methods and apparatuses for glass manufacture for reducing the formation of carbon dioxide blisters during glass manufacture are also provided.

Abstract: Methods and systems for controlling bubble size and bubble decay rate of glass foams formed during submerged combustion melting. Flowing a molten mass of foamed glass comprising molten glass and bubbles entrained therein into an apparatus downstream of a submerged combustion melter. The downstream apparatus has a floor, a roof, and a sidewall structure connecting the floor and roof. The foamed glass has glass foam of glass foam bubbles on its top surface, and the downstream apparatus defines a space for a gaseous atmosphere above and in contact with the glass foam. The downstream apparatus includes heating components to heat or maintain temperature of the foamed glass. Adjusting composition of the atmosphere above the glass foam, and/or contacting the foam with a liquid or solid composition controls bubble size of the glass foam bubbles, and/or foam decay rate.

Abstract: Methods and systems for de-stabilizing foam produced in submerged combustion melters. A molten mass of glass and bubbles is flowed into an apparatus downstream of a submerged combustion melter. The downstream apparatus includes a floor, a roof and a wall connecting the floor and roof, but is devoid of submerged combustion burners and other components that would increase turbulence of the molten mass. The molten mass has foam on at least a portion of a top surface of the molten mass. One method includes directly impinging an impinging composition onto at least a portion of the foam in the downstream apparatus. Systems for carrying out the methods are described.

Abstract: Corrosion of the inner surface of the crown of a glassmelting furnace is reduced or avoided by directing at low velocity along that surface a gaseous stream comprising water vapor, or comprising the combustion products of an oxy-fuel burner operated at a stoichiometric ratio of at least 1.0, or the combustion products of a burner operated at a stoichiometric ratio less than 1.0, or by injecting into the furnace interior a gaseous reactant which reacts with alkali species in said space.

Abstract: Corrosion of the inner surface of the crown of a glassmelting furnace is reduced or avoided by directing at low velocity along that surface a gaseous stream comprising water vapor, or comprising the combustion products of an oxy-fuel burner operated at a stoichiometric ratio of at least 1.0, or the combustion products of a burner operated at a stoichiometric ratio less than 1.0, or by injecting into the furnace interior a gaseous reactant which reacts with alkali species in said space.

Abstract: The present invention relates to a glass melting furnace, comprising a channel-shaped melting tank, the batch material being charged at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which 80% of the combustion energy is produced by oxycombustion, oxygen being supplied continuously from a production plant located nearby or via a gas pipe from remotely located plants, characterized in that the furnace is fitted with oxygen storage means such that, should continuous supply cease, the furnace can operate at least in a temperature-maintaining mode for a maximum time of eight hours.

Abstract: Injecting one or opposed gaseous streams into the atmosphere over molten glassmaking materials in a glassmelting furnace, in a region of the refining zone, and combusting fuel in the refining zone, improve the quality of the glassmelt and lessen the risk of crown corrosion.

Abstract: A method for fining a glass melt comprises providing a glass melt in a melting vessel, moving the glass melt to a fining vessel via a first channel, and physically introducing gas bubbles to the glass melt in the fining vessel to form a fined glass, wherein the melting vessel and the fining vessel are in a horizontal orientation with respect to each other.

Abstract: In a method for producing and refining a glass melt in a glass melting end, a mixture is fed to the glass melting end, the mixture is transformed into the glass melt under the action of heat in the glass melting end, and fuel is combusted with air and/or oxygen being supplied above the glass melt in order to generate heat in the glass melting end. In order to improve the thermal conditions inside the glass melting end, according to the invention wood dust is introduced as fuel into the combustion space present above the glass melt in the glass melting end and is combusted there, with air and/or oxygen being supplied.

Abstract: A melting furnace includes a gas supplying unit configured to protrude inwardly of the melting furnace to supply a gas to the melting furnace, the gas supplying unit including a gas supplying pipe configured to penetrate the melting furnace to protrude inwardly of the melting furnace and configured to have a nozzle hole formed at a front end thereof; and a cooling passage pipe provided outside the gas supplying pipe to include a second cooling passage through which a cooling liquid flows, the second cooling passage being directly connected to a first cooling passage through which the cooling liquid is circulated along a wall of the melting furnace.

Abstract: Injecting one or opposed gaseous streams into the atmosphere over molten glassmaking materials in a glassmelting furnace, in a region of the refining zone, improves the quality of the glassmelt and lessens the risk of crown corrosion.

Abstract: A method and a device are provided for melting meltable stock, such as glass, wherein a melting furnace is heated via a burner flame generated by means of a burner port, to which fuel and oxidizer are supplied, a fuel-rich fuel-oxygen mixture being introduced into the furnace downstream from the burner port via at least one substoichiometrically operated burner and/or a fuel or fuel mixture being introduced into the furnace downstream from the burner arrangement via at least one fuel nozzle, and a gas stream containing oxygen being introduced into the furnace downstream from the at least one substoichiometrically operated burner and/or the at least one fuel nozzle.

Abstract: The present invention relates to a glass meting furnace comprising a channel-shaped melting tank, the batch materials being introduced at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which the combustion energy is produced by oxy-fuel combustion in respect of at least 65% thereof, the burners being distributed on the walls along the length of the furnace, in which flue gas discharge is mostly localized close to the upstream end near the openings through which the batch materials are introduced, the rest of the flue gas being removed close to the downstream part so as to maintain dynamic sealing with respect to the surrounding atmosphere.

Abstract: A method for melting meltable stock, such as glass includes a melting furnace (10) heated via a burner flame (25,29) generated by a burner port, through which fuel and oxidizer are supplied, a fuel-rich gas stream introduced into the furnace downstream from the burner port via at least one substoichiometrically operated burner (20,22) and/or a fuel or fuel mixture being introduced into the furnace downstream from the burner arrangement via at least one fuel nozzle, and a oxygen containing gas stream being introduced into the furnace downstream from the at least one substoichiometrically operated burner and/or the at least one fuel nozzle. A furnace device is also provided.

Abstract: Apparatus includes a first and second conduits configured to form an annulus between them. An adjustable structure includes a body having an upper surface, a lower surface, and a circumferential surface abutting a portion of the internal surface of the second conduit. The structure is adjustable axially in relation to and removably attached to the first conduit via a hub. The hub defines a central passage for fuel or oxidant. The body has one or more non-central through passages configured such that flow of an oxidant or fuel therethrough causes the fuel or oxidant to intersect flow of fuel or oxidant exiting from the central passage in a region above the upper surface of the body.

Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.

Abstract: In the method and system for producing glass reduction of reduction-sensitive ingredients in the glass is reduced or preferably is avoided during the melting and fining processes. The glass preferably has a high refractive index. During the process an oxidizing agent is inducted into a fining vessel and preferably also into a melt crucible made of a slit skull that is cooled by a cooling agent. The oxidizing agent is preferably oxygen. Furthermore a system for conducting the method is also described.

Abstract: In the apparatus for producing glass reduction of reduction-sensitive components in the glass melt is reduced or preferably is prevented during the melting and/or fining processes by introducing an oxidizing agent into the glass melt. The apparatus has a melt crucible, a fining vessel, and a device for conducting oxygen and/or ozone into the glass melt in the melt crucible and/or fining vessel, in order to suppress reduction of reduction-sensitive components of the glass melt. A preferred embodiment of the apparatus has a metallic skull crucible, which includes the melt crucible and/or the fining vessel. The apparatus preferably includes a homogenization unit connected to the fining vessel to receive glass melt from the fining vessel in order to further process the glass melt after refining.

Abstract: The invention relates to a method for melting vitrifiable materials in a low-capacity oven, wherein at least part of the melting energy is supplied by two oxy-burners projecting into the melting chamber through the upstream wall and arranged on opposite sides of a vertical plane in which a longitudinal axis of the melting chamber is situated, in such a way as to create two flames, the respective injection axes thereof crossing at a distance from the upstream wall, between ? and ¾ of the length L of the melting chamber.

Abstract: The present invention relates to a novel process for coarse decarburization of a silicon melt, and to the use thereof for production of silicon, preferably solar silicon or semiconductor silicon.

Abstract: The invention concerns a method for preparing glass from raw materials in powder form in a furnace comprising three side walls, a roof, an upstream pinion and at least one air injector associated with a gas or liquid fuel injector, at least one of said injectors being arranged in said side walls, in said roof or in said upstream pinion. Said method includes the following steps: injecting air and gas or liquid fuel through said injectors, at least one flame being generated immediately proximate the zone where said raw materials in powder form cover the glass solution.

Abstract: The invention relates to a method for producing mineral wool, wherein a mineral base material is melted in a cupola furnace having a shaft to hold the base material, the lower section of said shaft being provided with a grate, and beneath said grate there is a combustion chamber. The combustion chamber is heated by one or a plurality of burners, the burner or burners being run on liquid or gaseous fuel and an oxygen-containing gas. The burners are operated such that the length of the flames occurring during combustion of the fuel with the oxygen-containing gas is between 60% and 100% of the combustion chamber diameter.

Abstract: Heat in a stream of combustion products obtained from a glassmelting furnace heated by oxy-fuel combustion is passed to incoming glassmaking materials in a heat exchanger without requiring reduction of the temperature of the stream yet without causing softening of the glassmaking material.

Abstract: This application relates to methods of making glass compositions, and glasses resulting from these methods. More particularly, the disclosure relates to a method of making a glass having high total solar transmittance and high light transmittance in the visible and near infrared ranges with the use of oxygen-fuel burners in a furnace. Such glass compositions are useful, for example, in glass-based solar cells.

Abstract: Corrosion of the inner surface of the crown of a glassmelting furnace is reduced or avoided by directing at low velocity along that surface a gaseous stream comprising water vapor, or comprising the combustion products of an oxy-fuel burner operated at a stoichiometric ratio of at least 1.0, or the combustion products of a burner operated at a stoichiometric ratio less than 1.0, or by injecting into the furnace interior a gaseous reactant which reacts with alkali species in said space.

Abstract: The subject of the invention is a continuous process for preparing glass comprising the successive steps of charging of pulverulent batch materials, and of obtaining a glass bath by melting, of refining then of cooling. The process is characterized in that an oxidizing gas is bubbled within said glass bath after the refining step.

Abstract: Methods and apparatus for refining and delivering a supply of molten glass include melting a supply of glass in a melter and discharging a stream of molten glass. A refining section is provided to refine the molten glass discharged by the melter and to deliver the molten glass downstream to a glass forming apparatus. The refining section is mounted for movement into and out of contact with the stream of molten glass to connect and disconnect the glass forming apparatus with the stream of molten glass.

Abstract: The present invention relates to a glass meting furnace comprising a channel-shaped melting tank, the batch materials being introduced at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which the combustion energy is produced by oxy-fuel combustion in respect of at least 65% thereof, the burners being distributed on the walls along the length of the furnace, in which flue gas discharge is mostly localized close to the upstream end near the openings through which the batch materials are introduced, the rest of the flue gas being removed close to the downstream part so as to maintain dynamic sealing with respect to the surrounding atmosphere.

Abstract: The present invention relates to a glass melting furnace, comprising a channel-shaped melting tank, the batch material being charged at an upstream end, the molten glass being recovered at the downstream end, said furnace being heated by means of burners, in which 80% of the combustion energy is produced by oxycombustion, oxygen being supplied continuously from a production plant located nearby or via a gas pipe from remotely located plants, characterized in that the furnace is fitted with oxygen storage means such that, should continuous supply cease, the furnace can operate at least in a temperature-maintaining mode for a maximum time of eight hours.