Abstract: The invention provides techniques for drawing fibers that include conducting, semiconducting, and insulating materials in intimate contact and prescribed geometries. The resulting fiber exhibits engineered electrical and optical functionalities along extended fiber lengths. The invention provides corresponding processes for producing such fibers, including assembling a fiber preform of a plurality of distinct materials, e.g., of conducting, semiconducting, and insulating materials, and drawing the preform into a fiber.

Abstract: Method and apparatus for producing vitreous optical elements by injection molding, which essentially includes the stages of: melting down a glass material into a molten state in a viscosity at or lower than a working point of the glass material; injecting molten glass under pressure into a mold cavity defined between transfer surfaces of relatively movable mold members of a mold assembly unit in communication with a sprue connecting the mold cavity with an injection port on the outer side of the mold assembly unit; and applying a predetermined pressure on the glass material in the mold cavity while cooling the mold assembly unit down to a temperature in the vicinity of yielding point of the glass material.

Abstract: A process for producing inorganic microspheres (solid spheres or hollow spheres), which comprises pulverizing a material by wet pulverization to an average particle size of at most 5 .mu.m to obtain a slurry of a pulverized powder material, spraying the slurry to form liquid droplets, and heating the liquid droplets to fuse or sinter the powder material to obtain inorganic microspheres.

Abstract: Provided is a method for the efficient preparation of fine hollow spherical glassy bodies having a high strength and excellent whiteness from a volcanic vitreous deposit as the starting material. The fine hollow spherical glassy bodies as desired can be prepared by dispersing 100 parts by weight of a powder of a volcanic vitreous deposit in an aqueous solution containing 1 to 10 parts by weight of aluminum sulfate, adding an aqueous alkaline solution to this liquid suspension to cause deposition of an alumina hydrate onto the surface of the particles of said powder and washing and drying of the solid material followed by a heat treatment for 1 second to 1 minute at a temperature of 900.degree. to 1100.degree. C.

Abstract: Optical glass of cubic, spherical or polygonal shape is fire polished on a graphite or Cr.sub.2 O.sub.3, concave surface with a surface roughness of 100 Angstroms or less. The optical glass having a surface roughness of 400 Angstroms or less is placed on the concave surface and fire polished by heating the optical glass between the yield point and softening point of the glass in a reducing atmosphere if the concave surface is made of graphite. A Cr.sub.2 O.sub.3 concave surface is required for Pb.sup.+2 containing glasses. The molded preform obtained has a surface roughness of 100 Angstroms or less.

Abstract: This invention provides a process wherein hazardous or radioactive wastes in the form of liquids, slurries, or finely divided solids are mixed with finely divided glassformers (silica, alumina, soda, etc.) and injected directly into the plume of a non-transferred arc plasma torch. The extremely high temperatures and heat transfer rates makes it possible to convert the waste-glassformer mixture into a fully vitrified molten glass product in a matter of milliseconds. The molten product may then be collected in a crucible for casting into final wasteform geometry, quenching in water, or further holding time to improve homogeneity and eliminate bubbles.

Abstract: One forms spherical or spheroidal glass particles by entraining a powder of glass particles in a carrier gas and injecting the entrained particles into the center of the flame of an oxygen-fuel burner. Separate conduits carry fuel, such as natural gas, and substantially pure oxygen into the burner to support combustion. The temperature in the burner flame does not exceed about 5000.degree. F. Heat from the flame causes the particles to become spheroidal, due to surface tension, but the particles do not remain in the flame long enough to melt. By adjusting a valve in the line which conveys the carrier gas and glass particles, one varies the time during which the particles reside in the flame. If the pressure becomes too high, the residence time decreases, and the particles may not become entirely spheroidal. If the pressure becomes too low, the residence time increases, and the particles may melt and/or form undesirable filaments.

Abstract: A method and apparatus for the treatment of fiber pieces, with which the fiber pieces (24) in a gas/solid mix are fed through a transport line (11) into a heating device (14). Inside the heating device (14) the exposed ends of the fiber pieces (24) are rounded off and/or thickened. Subsequent to the treatment in the heating device the treated fibers (25) flow into a feed line and from there into a separating device (18), in which the gas/solid mix is separated. The fiber bits produced according to the invented method improve the mechanical quality and characteristics of fiber composite materials considerably. By utilizing the described device the invented method can be carried out most economically. (FIG.

Abstract: A method is described for making hollow aerogel microspheres of 800-1200 .mu. diameter and 100-300 .mu. wall thickness by forming hollow alcogel microspheres during the sol/gel process in a catalytic atmosphere and capturing them on a foam surface containing catalyst. Supercritical drying of the formed hollow alcogel microspheres yields hollow aerogel microspheres which are suitable for ICF targets.

Abstract: In order to prepare particles of a vitreous enamel for use in forming a vitreous enamel body by fusing the particles together to form the body, at least one enamel frit and at least one non-vitreous additive are formed into an agglomerated granular feedstock and passed through a heating chamber whereby such feedstock becomes at least partially molten and rounded, whereafter the resulting rounded vitreous enamel beads are caused or allowed to cool to a temperature below their melting point.

Abstract: Alkali metal-containing glass beads for use as sources in thermionic detectors for gas chromatography are manufactured by a method which produces reproducible beads of preselected sizes. A glass tube of the desired composition is reduced to capillary size. A section having the volume of the desired bead is cut from the capillary tube and threaded onto a support wire. It is then melted and caused to coalesce onto the support wire. The resultant bead and a portion of the support wire are then incorporated into the detector.

Abstract: Material, such as, for example, sealed double bags of asbestos containing waste or ash from infectious waste or toxic material or radioactive waste, is transferred into a glass melt of a furnace. Gas bubbles released into the melt form a gas curtain which causes enhanced mixing of the material to accelerate the dissolution of the components of the added material. The presence of the gas bubbles reduces the cross-section of the molten glass through which current passes, which in turn increases the electrical resistance of the glass melt and therefore increases power generation of the melt or power density at constant current. A highly oxidizing hot region is produced under the location where the material is introduced into the furnace. Drawn off glass is shaped and quenched into at least two sizes of approximate spheres. The spheres are cooled sufficiently fast to be thermally tempered and have a surface compressive strength level above 5000 psi.

Abstract: The invention relates to a method of heat processing particles of glass. A first current of a mixture of a combustible gas and a gas capable of oxidizing the combustible gas is introduced into a substantially cylindrical chamber from its lower end. The combustible gas is ignited to form a flame in which the gases have a speed of less than 10 m/s. The resulting flame creates a heat processing zone in the chamber. A quenching zone is provided by a second current of gas introduced into the chamber adjacent the chamber side wall such that it swirls around the flame. Particles of glass are then introduced at the lower end of the chamber and these particles contact the flame in the heat processing zone and are then directed to the quenching zone where they are hardened and from which they are collected.

Abstract: A process for producing fine powder, which includes entraining a starting powder material in a carrier gas, injecting the starting powder material using the carrier gas into a high temperature jet to form a high velocity stream of molten droplets, fragmenting the resulting high velocity molten droplets by impacting against a substrate wherein the temperature of the substrate is above the melting point of the powder material, to form smaller droplets, and allowing the resulting fragmented smaller droplets to spheroidize and solidify in flight.

Abstract: A method of manufacturing a vitreous enamel body includes forming particles of vitreous material and melting to fuse the particles together to form the body. The particles of vitreous material are spherulized and are selected as to their granulometric properties according to the degree of compaction required in the finished enamel body. From 20% to 40% of the bulk volume of the mixture is a fine particle size fraction. Such a finished enamel body may be a coating, for example a high-compacity enamel coating on a bathtub, or it may be a self-sustaining body, for example a porous vitreous filter element. Porous coatings and compact self-sustaining bodies may also be made.

Abstract: An aggregate is produced from waste glass which is initially crushed to a granular state and is thereafter roughened at its surfaces and rounded at its edges. This result is obtained by a grinding treatment. The aggregate can be used for concrete. It allows an excellent adhering of the cement and it gives practically no rise to the danger of injury during the handling thereof.

Abstract: A process of manufacturing vitreous beads in which particulate feedstock is delivered to a heated chamber and passed along it so that the feedstock is heated and converted to vitreous beads whereafter the beads are collected, characterised in that the chamber is shaped to provide a flow path for the particles which is of elongate cross-section and is arranged so that the particles pass downwardly through it under gravity, and in that the particles passing through the chamber are heated by radiant heating means which emanates from the chamber walls.

Abstract: A composition is disclosed consisting essentially of substantially spherical glass particles having a diameter of less than about 25 micrometers.A process is disclosed for producing substantially spherical particles. The process involves providing irregularly shaped glass particles having a predetermined particle size, entraining the particles in a carrier gas, feeding the entrained particles into a high temperature zone having a temperature sufficiently above the softening point of the glass to allow surface tension to subsequently spheroidize the particles and having a temperature below the vaporization temperature of the glass.

Abstract: A spherulizing furnace for manufacturing vitreous beads includes feed means for delivering particulate feedstock, a spherulizing zone in which the feedstock particles may be heated and converted to vitreous beads, and means for collecting the resulting beads, wherein the feed means includes a reservoir adapted to hold a fluidized bed of feedstock particles, the reservoir having at least one overflow feed outlet opening over which fluidized particles flow under gravity for delivery to the spherulizing zone. A process of manufacturing vitreous beads, and vitreous beads made thereby, includes delivering feedstock to a spherulizing zone of a spherulizing furnace, passing the feedstock through the spherulizing zone so that the feedstock is heated and converted to vitreous beads, and collecting the beads. The feedstock particles are delivered under gravity by fluidized overflow from a fluidized bed reservoir to the spherulizing zone.

Abstract: A spherulizing furnace for manufacturing vitreous beads, including a chamber; means for heating the chamber; feed means for delivering a particulate feedstock to one end of the chamber; and means for collecting vitreous beads from another end of the chamber, wherein the chamber includes a pair of opposed walls which are spaced apart by a distance less than their breadth and which are angled to the horizontal so that the chamber has an upper end and a lower end, the feed means is arranged to deliver feedstock to the upper end of the chamber so that the feedstock can pass through the chamber under gravity, and the means for heating the chamber is arranged to heat at least one wall of the pair of opposed walls so that feedstock passing between the pair of opposed walls is heated by radiant heat.

Abstract: A process is disclosed for producing fine spherical particles from a fine powder feed material which comprises entraining the powder feed material in a carrier gas, introducing the feed material and carrier gas through a powder port into a high temperature zone and maintaining the powder feed material in the high temperature zone for a sufficient time to melt at least about 50% by weight of the particles of the powder and to form droplets therefrom while at the same time allowing one or more streams of gas to come into contact intermittently with any powder which has accumulated in the vicinity of the powder port to keep the vicinity clear of powder to allow the powder feed to pass unobstructively through the powder port into the high temperature zone. The droplets are then cooled to form spherical particles.

Abstract: A process is disclosed for producing spherical glass particles. The process involves forming a high velocity stream of molten droplets of glass, directing said stream toward a repellent surface, impacting the molten droplets against the surface to form fragmented portions, and cooling the fragmented portions to form a glass powder consisting essentially of particles the major portion of which are glass spheres.

Abstract: Sintered particles of pulverulant glass and cellulating agent are coated with a parting agent and introduced into a fluidizing vessel. Gas is passed upwardly through the fluidizing vessel at a velocity sufficient to form a fluidized bed of these sintered particles within the fluidizing vessel. The gas and fluidized bed of sintered particles are heated within the fluidizing vessel to a cellulation temperature of the sintered particles to cause the sintered particles within the fluidized bed to form discrete cellular glass nodules of uniform size. The cellular glass nodules formed within the fluidized bed of sintered particles, having a density less than the density of the sintered particles, migrate to the top of the fluidized bed to float on the top surface of the fluidized bed. The discrete cellular glass nodules floating on the top surface of the fluidized bed are withdrawn from the fluidizing vessel.

Abstract: An apparatus for spheridizing irregularly shaped minute particles, and the spheres produced thereby, in which a thin carbonaceous coating is applied to the particles in a unique manner, and in a preferred embodiment the particles are then advanced through successive fluidizing beds. The first bed has an inert atmosphere and is maintained at an elevated temperature sufficiently high to allow surface tension to shape the particles into spherical form while in a fluidized condition in the first bed. The spherical particles are then advanced through successive additional beds where they are cooled to an intermediate temperature sufficient to solidify the particles, are subjected to an oxidizing atmosphere which completely removes the coating, and are then further cooled while being maintained in a fluidized condition. The inert gaseous atmosphere within the first bed is continuously withdrawn and recycled through the system.

Abstract: A process is disclosed for producing finely divided spherical glass powders. The process comprises forming a coating of a surface active agent which can be of the nonionic or anionic type on the surfaces of the particles of a glass powder, feeding the coated particles and a carrier gas into a high temperature zone and maintaining the particles in the zone for a sufficient time to melt at least about 50% by weight of the particles and to form droplets therefrom, and cooling the droplets to form glass particles having essentially a spherical shape with the majority of the particles having an average particle size of less than about 25 micrometers in diameter which is essentially the same size as the starting glass particles.

Abstract: The invention is directed to a method of filling an evacuated metal vessel ith a radioactive glass melt from a glass melting furnace. The metal vessel is equipped with a suction tube mounted at the bottom of the vessel. The steps of filling and sealing the metal vessel are carried out faster and with the furnace atmosphere properly sealed off. For this purpose the vessel is placed in a holding device which is positioned over a closable suction port of the glass melting furnace. The suction port is hermetically sealed off from the atmosphere of the cell and is then opened. The vessel is lowered vertically until the suction tube dips into the glass melt. After the vessel has been filled, the glass in the suction tube is frozen thereby forming a plug. The vessel is moved upwardly in the vertical direction until the suction tube is drawn out of the furnace. The suction port is closed and a sealing cover for the vessel is put into position over the port.

Abstract: A process and apparatus for spheridizing irregularly shaped minute particles, and the spheres produced thereby, in which a thin carbonaceous coating is applied to the particles in a unique manner, and in a preferred embodiment the particles are then advanced through successive fluidizing beds. The first bed has an inert atmosphere and is maintained at an elevated temperature sufficiently high to allow surface tension to shape the particles into spherical form while in a fluidized condition in the first bed. The spherical particles are then advanced through successive additional beds where they are cooled to an intermediate temperature sufficient to solidify the particles, are subjected to an oxidizing atmosphere which completely removes the coating, and are then further cooled while being maintained in a fluidized condition. The inert gaseous atmosphere within the first bed is continuously withdrawn and recycled through the system.

Abstract: A device is described for the production of glass drops from a glass melt ntained in a melting furnace and containing radioactive waste. The device comprises a horizontally extending pipe adapted at one end to be connected to the melting furnace so as to serve as glass melt overflow. The other end of the pipe is formed with a pocket-like extension, in the base of which the drip nozzles are arranged. The overflow tube, together with pocket-like extension, is surrounded by a heating device and by an insulated housing. The pipe is connected to a bore in the wall of the melting furnace, and the device is simple to manufacture and install.

Abstract: A method of forming rounded vitreous beads in which particles of bead forming material entrained in a gas stream having comburent and combustible components are projected from a burner head and the gas is burnt. A first component of the combustible gas mixture with entrained particles is propelled along a passageway leading to the burner head, a second gas component is forced transversely into that passageway through at least one orifice in its peripheral wall and the mixed gases in which the particles are entrained are subjected to forces further promoting intimate mixture thereof before reaching the burner head.

Abstract: A vortex combustion furnace (1) for the production of glass beads or the like is generally cylindrical and has an outlet flue (24) at its upper end. A burner (13) at the lower end burns a gas/air mixture. Secondary air is introduced into the chamber through tangential air inlets (16) and creates a vortex (71) within the chamber. Tertiary air is introduced through a ring of angled nozzles (71) surrounding the burner further to swirl the flame. The vortex has a top-hat temperature profile with a central heating region with a temperature in excess of 1000.degree. C. and a surrounding cooling region with a temperature not much above ambient. Glass cullet is supplied to a fluidized bed (53) and then entrained in a pipe (44) to be injected into the chamber. The cullet follows a spiral path in the vortex, is heated, melts to form glass beads, is then cooled and finally is collected after striking the wall of the chamber.

Abstract: There is disclosed a method of producing a cellular ceramic body of high mechanical strength and exhibiting a density less than 15 lbs/ft.sup.3. A crystal-containing gel, prepared from a selected, synthetic, lithium and/or sodium, water-swelling mica, is ion exchanged with a large cation to flocculate the gel and the floc is drained and provided with a gas producing agent. The floc is then molded to desired shape and subjected to gas-producing radiation to cellulate the molded body. The cellulating agent may be retained water, one or more chemical blowing agents, a combustible substance or a vaporizable substance. The floc, in slurry form, may have a thickener added to produce a paste prior to molding. It may also have a plasticizer and/or a binder added as modifiers.

Abstract: A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

Abstract: A sonic levitation apparatus (A) is disclosed which includes a sonic transducer (14) which generates acoustical energy responsive to the level of an electrical amplifier (16). A duct (B) communicates with an acoustical chamber (18) to deliver an oscillatory motion of air to a plenum section (C) which contains a collimated hole structure (D) having a plurality of parallel orifices (10). The collimated hole structure converts the motion of the air to a pulsed, unidirectional stream providing enough force to levitate a material specimen (S).

Abstract: A process of forming glass balls by treatment of particulate vitreous material and a second material comprising carbon material and a carbonated salt. The process is carried out at a temperature, for the particular particulate vitreous material, which corresponds to a viscosity of from about 10.sup.6 to about 10.sup.3.5 poises with mixing and agitation.The apparatus includes a furnace having a tube (4) adapted to rotate about an horizontal or inclined axis, delivery means (10, 12, 14) to the tube for the materials to be treated, and heating means (8, 20) for heating the tube and the bed of material from both an external and internal location.

Abstract: Cellular ceramic bodies are produced by frothing a crystal-containing, ion-exchanged gel and setting the gel. An aqueous gel is prepared from a water-swelling mica and is blended in conjunction with a large cation donor, e.g., a potassium salt or silicate glass, and a surfactant to effect frothing of the gel by a shearing action and exchange of large cations with lithium and/or sodium ions from the mica to produce an ion-exchanged gel that sets in controllable manner.

Abstract: A method is disclosed for producing low density, ceramic bodies in the nature of hollow or solid beads which may be used as such or bonded into a unitary mass. The bodies are composed of ion-exchanged, synthetic mica crystals wherein large cations, such as K.sup.+, have been exchanged for lithium and/or sodium ions from the mica. The method involves forming a gel by dissolution of a synthetic mica in a polar liquid, releasing droplets of the gel into a fluid to form shaped bodies, effecting the indicated ion exchange, and drying the beads thus formed.

Abstract: A small object (12, FIG. 2) is coated by holding it in the pressure well (20) of an acoustic standing wave pattern, and then applying a mist of liquid coating material (42) at low velocity into the pressure well. The pressure gradient within the well forces the mist particles to be pushed against the object. A lower frequency acoustic wave (for oscillator 28, FIG. 4) also can be applied to the coated object, to vibrate it so as to evenly distribute the coated material. The same lower frequency vibrations can be applied to an object in the shape of a hollow sphere, to center the inner and outer surfaces of the sphere while it remains suspended.

Abstract: A system is provided for forming small accurately-spherical objects. Preformed largely-spherical objects (18) are supported at the opening of a conduit (16) on the update of hot gas emitted from the opening, so the object is in a molten state. The conduit is suddenly jerked away at a downward incline, to allow the molten object to drop in free fall, so that surface tension forms a precise sphere. The conduit portion that has the opening, lies in a moderate-vacuum chamber 40, and the falling sphere passes through the chamber and through a briefly-opened valve (30) into a tall drop tower (32) that contains a lower pressure, to allow the sphere to cool without deformation caused by falling through air.

Abstract: A vortex combustion furnace (1) for the production of glass beads is generally cylindrical and has an outlet flue (24) at its upper end. A burner (13) at the lower end burns a gas/air mixture. Secondary air is introduced to the chamber through tangential air inlets (16) and creates a vortex within the chamber. The vortex has a top-hat temperature profile with a central heating region with a temperature in excess of 1000.degree. C. and a surrounding cooling region with a temperature not much above ambient. Glass cullet injected into the chamber follows a spiral path in the vortex, is heated, melts to form glass beads, is then cooled and finally is collected after striking the wall of the chamber.

Abstract: A method and apparatus for encapsulating or embedding highly radioactive waste in glass within an ultimate storage container in which molten glass is transferred from a melting furnace to the container by means of suction. The container is evacuated, and a sealed suction tube connecting to the container is immersed in the molten glass containing the waste, whereupon the seal is broken and the molten glass flows under the force of atmospheric pressure into the container. The operation may be carried out by remote controls.