Abstract: A method of calcination includes providing a raw material including whitlockite Ca9(Mg,Fe2+)[PO3(OH)|(PO4)6], and/or iron phosphate FePO4, and/or aluminum phosphate AlPO4 and/or fluorapatite Ca5(PO4)3F; providing an alkaline-sulfuric compound as an additive; and calcining a mixture of the raw material with the additive to obtain a product, including a citrate soluble phosphate compound.

Abstract: A composite particle and a population of particles comprising a water-insoluble polyphosphate composition, methods of producing, and methods of using the same are provided. The polyphosphate composition may comprise at least one alkaline earth metal selected from calcium and magnesium and optionally at least one nutrient ion selected from the group consisting of potassium, ammonium, zinc, iron, manganese, copper, boron, chlorine, iodine, molybdenum, selenium or sulfur.

Abstract: The present invention relates to a method of converting limestone into tri-calcium phosphate (TCP) and tetra-calcium phosphate (TTCP) powder simultaneously. In particular, the method provides for a method of converting limestone into TCP and CTTCP powder simultaneously having specific particle size and with specific crystallographic structure.

Abstract: A water insoluble micronutrient fertilizer, methods of producing, and methods of using the same are provided. The fertilizer may comprise at least one first micronutrient selected from the group consisting of chromium, cobalt, copper, iron, manganese, and zinc; a polyphosphate; and optionally at least one second micronutrient selected from the group consisting of boron, chlorine, iodine, molybdenum or selenium.

Abstract: Disclosed are a fertilizer containing a sparingly water-soluble phosphatic fertilizer and an urea/aliphatic aldehyde condensation product. The process for controlling inorganizing speed of urea/aliphatic aldehyde condensation product comprises adding to the urea/aliphatic aldehyde condensation product a sparingly water-soluble phosphatic fertilizer having special elution characteristics. The fertilizer of the invention and the process for controlling inorganizing speed of urea/aliphatic aldehyde condensation product of the invention make it possible to control the inorganizing speed of the condensation product without changing the particle size or form. The fertilizers of the invention or the urea/aliphatic aldehyde condensation products can provide nitrogen components to plant in accordance with the periods of culture of desired crops and a pattern of absorbing nutrition. This is effective in saving of the number of additional fertilization or nitrogen components left in soil after the period of culture.

Abstract: The fertilizer of the invention is a fertilizer containing a sparingly water-soluble phosphatic fertilizer and a urea/aliphatic aldehyde condensation product. The process for controlling inoganizing speed of urea/aliphatic aldehyde condensation product of the invention comprises adding to the urea/aliphatic aldehyde condensation product a sparingly water-soluble phosphatic fertilizer having special elution characteristics. The fertilizer of the invention and the process for controlling inoganizing speed of urea/aliphatic aldehyde condensation product of the invention make it possible to control the inorganizing speed of the condensation product without changing the particle size or form, that is, to control development of the efficacy of the condensation product used as a fertilizer.

Abstract: A fertilizer compound having a glass matrix comprises, among the forming oxides of the glass matrix, a phosphorus pentoxide (P2O5) as partial and/or full replacement of silica (SiO2); among the modifier oxides of the said glass matrix, a potassium oxide (K2O) as partial and/or full replacement of sodium oxide (Na2O); and one or more trace elements.

Abstract: Water-buoyant compositions comprising a source of micronutrients for photosynthetic phytoplankton growth are useful for stimulating photosynthetic phytoplankton growth in ocean areas devoid of such growth when deployed on ocean surfaces as floating particles. Iron is the preferred micronutrient.

Abstract: A method and an installation for producing granulated triple superphosphate wherein a premixer for phosphate and a phosphoric acid solution includes unclogging means comprising in combination a flexible axial sleeve of non-vulcanized elastomer for injecting phosphate together with at least one sprayer for spraying the phosphoric acid solution and acting level with the free bottom end of the sleeve. The invention is applicable to the chemical industry.

Abstract: A depot fertilizer composition comprising an inorganic matrix and another inorganic and/or organic component of the formulaX Me(II)O.[(1-x)/2]Me(III).sub.2 O.sub.3.YA.zI.aqin whichMe (II) is at least one divalent metal,Me(III) is at least one trivalent metal,A is at least one inorganic acid or anhydride of an inorganic acid,I is at least one organic compound,aq is 0-9,X is from 0 to 1,Y is from 0.5 to 0.7, andZ is from 0 to 20,at least one of the components containing a plant nutrient element. The compositions are suited for fertilizing the leaves or full systems of plants growing in soil or in water.

Abstract: A continuous process for the production of a granulated fertilizer wherein comminuted phosphate rock, phosphoric acid and water are introduced into a pre-reactor where they are heated. The mixture is continuously withdrawn and transferred to a digester where heating is continued resulting in formation of a slurry. The slurry is continuously withdrawn and is split into two streams, one of which is recycled to either the pre-reactor or to the digester while the other stream is delivered to a granulator where it is mixed with other fertilizer ingredients and dried to form the granulated fertilizer.

Abstract: Method for production of granular ammonium polyphosphate fertilizer in which ammonium polyphosphate melt is prepared in a simple inline reactor and distributed onto a bed of solids in a drum granulator to bind smaller fertilizer particles into granules. The desired polyphosphate content can be obtained in the granular product by adjusting the total heat input of the feed reactants to the reactor by means of energy conservation modifications to the system. Energy losses are controlled by use of a predetermined quantity of insulation so that varying amounts of the maximum theoretical heat input can be utilized to produce products of polyphosphate contents as desired.

Abstract: A granular fertilizer and insecticide carrier-filler material which is produced from phosphatic clays is disclosed along with its method of production. The granular carrier-filler material is water-degradable, and is prepared from waste phosphatic clays by tilling the source material, allowing it to dry, crushing the dried material into granules, heating the granules at a temperature of about 450.degree. F. to less than 1600.degree. F. to obtain a granular carrier-filler material having a moisture content of no more than about 15% by weight. Depending upon end use applications, the granular carrier-filler material may be sized as by screening.

Abstract: Method and apparatus for producing high grade phosphate rock from low grades, slime or tailings by subjecting the low grade rock, slime or tailings to a calcination treatment at a temperature within the range from 1000.degree. F. to 1600.degree. F., and preferably from 1400.degree. F. to 1600.degree. F., until a fraction of said rock, slime or tailings becomes magnetically attractable, and subjecting the treated material to a high strength magnetic field to separate the same magnetically into at least two fractions, one of increased BPL and one of decreased BPL.

Abstract: A slow release fertilizer composition providing to a plant a controlled amount of plant primary nutrients and micronutrients over a prolonged period of time is described. The solubility and concentration of each of the plant nutrients is determined by the addition to the fertilizer composition of specified fertilizer constituents or components which on going into solution coact to control at an optimum concentration each of the plant nutrients. The slow release fertilizer composition comprises the plant primary nutrients nitrogen, phosphorous, calcium, sulfur, magnesium, and potassium and the plant micronutrients iron, manganese, zinc, copper and boron. A single application of the fertilizer composition of the present invention provides sufficient plant nutrients for a full growing season or one or more growing seasons.

Abstract: A one vessel process for manufacturing stable ammonium phosphate fertilizer utilizes a spray reactor in which phosphoric acid is reacted with ammonia to form ammonium phosphate. The ammoniation is conducted under conditions which form sufficient ammonium polyphosphate to stabilize the solution in the liquid condition. The liquid may be stored and transported without substantial solidification or crystalization so that the product may be subsequently used as an ammonium phosphate fertilizer.

Abstract: A fertilizer rich in calcium metaphosphate is produced by reacting phosphorite or other calcium phosphate-bearing mineral, with ammonium bisulphate to produce a precipitate of calcium sulphate and an aqueous solution rich in ammonium mono- and biphosphates. The latter is then heated in a furnace in the presence of further calcium phosphate-bearing mineral, to produce calcium metaphosphate. The calcium sulphate can be converted to calcium carbonate by reaction with ammonium carbonate, to produce ammonium sulphate. The ammonium sulphate can be heated with the furnace gases from the production of calcium metaphosphate, to produce the required ammonium bisulphate for reaction with phosphorite and the required ammonium carbonate for a conversion of the calcium sulphate to calcium carbonate.

Abstract: Liquid ammonia, a reactant with superphosphoric acid in the process for fertilizer production, is passed through an annular jacket surrounding a tubular reaction zone where reaction occurs to maintain the interior surface of the tubular reactor at a temperature sufficiently low to prevent the formation of scale on interior reactor surfaces.

Abstract: An improved process is described for preparing defluorinated phosphate rock (DPR) granules from fluorine-containing phosphate rock.

Abstract: A process for granulating ammonium phosphate containing composition for use as a fertilizer which comprises feeding a slurry or melt of ammonium phosphate, wherein said slurry or melt is capable of further reaction with ammonia, into a kneading mill, feeding recycled particles from the subsequent classification and crushing procedure into said kneading mill, wherein the said slurry or melt added to the mill is from 5 to 95% wt.

Abstract: A process for the production of highly citrate-soluble calcined phosphate fertilizers is disclosed. The process comprises calcinating a mixture which comprises appropriate amounts of calcium phosphates, silicic acid and an alkaline decomposing agent whereby the naturally occurring mineral trona is used as an alkaline decomposing agent. The process is effected in a rotary kiln; the maximum temperature is about 1300.degree. C.

Abstract: An improved process is described for preparing defluorinated phosphate rock from fluorine-containing phosphate rock which contains acid insoluble impurities in excess of about 6 percent by weight. The improvement is particularly useful in the fluidized bed technique for preparing defluorinated phosphate rock wherein fluorine-containing phosphate rock, a sodium compound such as sodium carbonate, phosphoric acid and water are admixed to form granules. The resulting granules are dried and heated in a fluidized bed calciner at a temperature within the range of from about 980.degree. to about 1,350.degree. C to evolve sufficient fluorine to produce defluorinated phosphate rock graules having less than 1 part of fluorine per 100 parts of phosphorus by weight. The resulting defluorinated granules are colled and stored for use as an animal feed which contains at least 18 percent by weight of phosphorus.

Abstract: Ammonium phosphate solutions free of precipitates are prepared from wet-process phosphoric acid containing incidental metallic impurities such as iron, aluminum and magnesium by concentration of the phosphoric acid to an anhydrous state and the formation of acyclic polyphosphoric acids therein which prevent the precipitation of the metallic impurities upon neutralization. The acid is heated to a temperature greater than 120.degree. C. at atmospheric or subatmospheric pressures while removing the volatile impurities and thereafter is neutralized with ammonia. The neutralization step can be performed at elevated temperatures with anhydrous ammonia or the acid can be cooled and neutralized at ambient temperatures. The resulting ammonium phosphate is diluted with water to obtain an ammonium phosphate solution which is clear and free of precipitates.

Abstract: Method for production of granular ammonium polyphosphate fertilizer in which ammonium polyphosphate melt is prepared in a simple inline reactor and distributed onto a bed of solids in a drum granulator to bind smaller fertilizer particles into granules. The desired polyphosphate content can be obtained in the granular product by adjusting the total heat input of the feed reactants to the reactor by means of energy conservation modifications to the system. Energy losses from the reaction system are controlled by use of a predetermined quantity of insulation so that varying amounts of the maximum theoretical heat input can be utilized to produce products of polyphosphate contents as desired.

Abstract: The present invention relates to methods and implementation, including apparatus comprising a two-stage, single-unit, and energy-efficient rotary drum-type granulator-dryer device having a granulator section and a separate dryer section in a new and novel combination designed for continuously granulating and/or ammoniating, and subsequently drying, respectively, a variety of materials together with specific processes for effecting such granulating and/or ammoniating, and subsequent drying.