Nitrogen-containing Patents (Class 71/49)
  • Patent number: 11999664
    Abstract: Systems and processes for producing ammonia products and/or calcium carbonate products, including but not limited to an organic high sulfur liquid ammonium product and an organic calcium carbonate product from an effluent derived from one or more organic feedstocks. Solids are removed from an organic feedstock that contains a nitrogen compound to produce an organic liquid effluent that contains ammonium and/or ammonia. Ammonia is stripped and concentrated from the organic liquid effluent to produce a gaseous mixture that contains ammonia, and the gaseous mixture is cooled to produce a condensed aqueous ammoniacal nitrogen solution of aqueous ammonia, ammonium bicarbonate, and/or ammonium carbonate. The condensed aqueous ammoniacal nitrogen solution is then contacted with a stabilizing agent to cause a reaction therebetween to produce at least a stabilized ammoniacal nitrogen product.
    Type: Grant
    Filed: November 12, 2020
    Date of Patent: June 4, 2024
    Inventor: Scott Severson
  • Patent number: 8999031
    Abstract: A composite particle and a population of particles comprising a water-insoluble polyphosphate composition, methods of producing, and methods of using the same are provided. The polyphosphate composition may comprise at least one alkaline earth metal selected from calcium and magnesium and optionally at least one nutrient ion selected from the group consisting of potassium, ammonium, zinc, iron, manganese, copper, boron, chlorine, iodine, molybdenum, selenium or sulfur.
    Type: Grant
    Filed: August 8, 2011
    Date of Patent: April 7, 2015
    Assignee: Agtec Innovations, Inc.
    Inventor: Chandrika Varadachari
  • Patent number: 8945392
    Abstract: The invention employs composites of zeolite and ferric oxide hydroxide for removal of inorganic nitrogen and phosphorus wastes from animal environments.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: February 3, 2015
    Assignee: Red Lion Chem Tech, LLC
    Inventors: Michael E. Hickey, Allan D. Pronovost
  • Patent number: 8888887
    Abstract: A controlled release fertilizer material comprising a particulate plant nutrient surrounded by a coating of a mixture including an isocyanate and a polyol, and further comprising a modified wax that may include a polyhydroxyl compound in which the wax and/or the polyhydroxyl compound are cross-linked with a sulfur or oxygen or a peroxide cross-linking moiety. In certain embodiments, the wax and polyhydroxyl compound are cross-linked at unsaturated sites in the wax or polyhydroxyl compound using heat, UV or ionizing radiation.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: November 18, 2014
    Assignee: Agrium Advanced Technologies (U.S.) Inc.
    Inventors: Garrard Lee Hargrove, Sriramakrishna Maruvada, Robert Scott Wilson, Nick Peter Wynnyk, Baozhong Xing
  • Patent number: 8877682
    Abstract: A substantially dry, flowable adjuvant compositions comprising, based on 100 parts by weight (“pbw”) of the adjuvant composition: (a) from about 25 pbw to about 75 pbw of a polysaccharide and (b) from about 75 pbw to about 20 pbw of a salt composition. In one embodiment, the salt composition is diammonium hydrogen phosphate, sodium carbonate or a combination thereof, and the polysaccharide is a derivatized guar. Also disclosed are methods of preparing such agricultural compositions comprising adding, to a heel solution, (a) a water dispersible adjuvant composition, in an amount effective to provide deposition and/or drift control properties, comprising, based on 100 pbw of the adjuvant composition: (i) from about 25 pbw to about 75 pbw of a polysaccharide, and (ii) from about 75 pbw to about 20 pbw of a salt composition, wherein an aqueous solution of the adjuvant composition has a pH value of between about 7 and about 12, and (b) an effective amount of an active.
    Type: Grant
    Filed: June 2, 2009
    Date of Patent: November 4, 2014
    Assignee: Rhodia Operations
    Inventors: Dan Wu, Michael J. Kisenwether, Krishnamurthy Shanmuganandamurthy
  • Patent number: 8764873
    Abstract: Animal waste is processed to form a biomaterial that is employed as a coating layer for typical fertilizer particles. The biomaterial coating layer can be used neat or with additives and serves to do one or more or any combination of the following: (a) impart a slow or controlled release property to the fertilizer, (b) prevent or reduce the tendency of the fertilizer particles to cake together, or (c) prevent or reduce the tendency of the fertilizer particles to create dust. The biomaterial coating layer can also release nutrients when used as part of a fertilizer composition.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: July 1, 2014
    Inventor: James E. Nevin
  • Publication number: 20140157845
    Abstract: Particulate compositions of reverted superphosphate substantially free of free acid containing at least one nitrification inhibitor and their methods of preparation and use
    Type: Application
    Filed: September 5, 2013
    Publication date: June 12, 2014
    Applicant: Balance Agri-Nutrients Limited
    Inventor: Terrence Smith
  • Patent number: 8741022
    Abstract: A controlled release fertilizer composition and methods to produce the controlled release fertilizer composition are described. The controlled release fertilizer composition comprises a water soluble fertilizer core that is coated with a polymeric layer, intermediate layer, and a sulfur layer. If desired, the sulfur layer can be coated with an outer water-insoluble layer.
    Type: Grant
    Filed: May 22, 2012
    Date of Patent: June 3, 2014
    Assignee: Agrium Inc.
    Inventors: Jeffrey Michael Ogle, Johnny Duran Sims
  • Patent number: 8702834
    Abstract: According to the present invention, there is provided a process for the manufacture of sulphur-containing fertilizer compositions, said process comprising the steps of: a) providing a slurry of at least one phosphate-based fertilizer material selected from the group consisting of ammonium phosphates, ammonium phosphate based nitrogen-phosphorus-potassium (NPK) compounds, super phosphates and partially acidulated phosphate rocks; b} bringing said slurry into contact with at least one surfactant and elemental sulphur; and c) introducing the mixture obtained in step b) into a granulator unit in order to obtain granules of the fertilizer composition, wherein the elemental sulphur is present in an amount in the range of form 1 to 25 wt. %, based on the total weight of the fertilizer composition The present invention also provides a fertilizer composition.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: April 22, 2014
    Assignee: Shell Oil Company
    Inventors: Jany Birgitta Maria Antens, Rafael Alberto Garcia Martinez, Reginald Lambert, Jason Trevor O'Brien, Marinus Johannes Reynhout, Guy Lode Magda Maria Verbist, John Woodruffe
  • Patent number: 8702833
    Abstract: The object of the present invention is to consume raw food cultivated in appropriate soil. The constitution of the health food is: consuming cereals including rices and wheats with or without husk, millets, pulses, tubers, leaf vegetables, fruit vegetables, rosette crops, root vegetables, citrus fruits, fruits, melons, seaweeds, and liverworts etc. as is; or consuming powders thereof, or by soaking in water so as to process to a degree that cell are not destructed (or if cells are destructed, the whole of leaf vegetables including root, stem, and leaf or a portion thereof are consumed as e.g. juice) and consuming without processing treatment including heating, boiling in water, or steaming; or these cereals, millets, or pulses are soaked in water to allow sprouting, and consumed at around the time of sprouting without processing treatment including heating, boiling in water, or steaming.
    Type: Grant
    Filed: December 2, 2011
    Date of Patent: April 22, 2014
    Assignee: Nihon Pack Co.
    Inventor: Chikatsugu Sugiyama
  • Publication number: 20140076013
    Abstract: The invention employs composites of zeolite and ferric oxide hydroxide for removal of inorganic nitrogen and phosphorus wastes from animal environments.
    Type: Application
    Filed: February 28, 2013
    Publication date: March 20, 2014
    Applicant: Red Lion Chem Tech, LLC
    Inventors: Michael E. HICKEY, Allan D. PRONOVOST
  • Patent number: 8668759
    Abstract: Process for the manufacture of sulphur-containing fertilizer compositions, comprising the steps of: a} providing a slurry of at least one phosphate-based fertilizer material selected from the group consisting of ammonium phosphates, ammonium phosphate based nitrogen-phosphorus-potassium (NPK) compounds, super phosphates and partially acidulated phosphate rocks; b) bringing said slurry into contact with at least one anionic surfactant and elemental sulphur; c) introducing the mixture obtained in step b} into a granulator unit in order to obtain granules of the fertilizer composition, wherein the at least one phosphate-based fertilizer material is present in an amount in the range of at least 50 wt. %, the elemental sulphur is present in an amount in the range of from 1 to 25 wt. % and the anionic surfactant is present in an amount in the range of from 0.001 to 3 wt. % based on the overall weight of the fertilizer composition. The present invention also provides a fertilizer composition.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: March 11, 2014
    Assignee: Shell Oil Company
    Inventors: Jany Birgitta Maria Antens, Sunil Ashtekar, Rafael Alberto Garcia Martinez, Reginald Lambert, Jason Trevor O'Brien, Marinus Johannes Reynhout, Guy Lode Magda Maria Verbist, John Woodruffe
  • Patent number: 8647406
    Abstract: Multiple-component fertilizer materials and methods of use are provided, wherein the fertilizer materials include first and second fertilizer products respectively including an ammoniacal fertilizer (e.g., urea) in combination with a partial calcium salt of a selected copolymer, and a phosphorous fertilizer (e.g., DAP) in combination with a partial sodium salt of a selected copolymer. The copolymer fractions of the first and second fertilizer products are most preferably copolymers of itaconic acid and maleic anhydride. The fertilizer materials give synergistically enhanced crop yields when applied to soil or growing plants.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: February 11, 2014
    Assignee: Specialty Fertilizer Products, LLC
    Inventor: John Larry Sanders
  • Publication number: 20130267416
    Abstract: Abstract Provided is a freely flowing particulate fertilizer essentially consisting of potassium phosphate of the formula K3H3(PO4)2 and of less than 8 wt % water. The stable and not caking fertilizer is characterized by an XRD signal corresponding to 2-theta of about 70°. An economic process for making the fertilizer is also provided.
    Type: Application
    Filed: June 4, 2013
    Publication date: October 10, 2013
    Inventors: Alexander Josef, Itshak Zukerman
  • Patent number: 8506670
    Abstract: A water insoluble micronutrient fertilizer, methods of producing, and methods of using the same are provided. The fertilizer may comprise at least one first micronutrient selected from the group consisting of chromium, cobalt, copper, iron, manganese, and zinc; a polyphosphate; and optionally at least one second micronutrient selected from the group consisting of boron, chlorine, iodine, molybdenum or selenium. The fertilizer compounds are preferably water insoluble, dilute acid soluble, and free-flowing powders.
    Type: Grant
    Filed: February 3, 2010
    Date of Patent: August 13, 2013
    Assignee: Agtec Innovations, Inc.
    Inventor: Chandrika Varadachari
  • Patent number: 8480782
    Abstract: A composition has a core of at least one fertilizer substance and at least one layer of a coating material surrounding the core. The core may contain nitrogen and the coating material may include one or more linear, saturated aliphatic monocarboxylic acids.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: July 9, 2013
    Assignee: Tiger-Sul Products LLC
    Inventors: Danny R. Wright, Richard J. Valagene, Don T. Cherry, Keith D. Cochran, Tim G. Holt, Gregory S. Peeden
  • Patent number: 8461079
    Abstract: A composition which provides bactericidal, fungicidal and insecticidal activity when treating plants with effective amounts. The composition comprises the blending of: (1) an aqueous salicylate solution from salicylic acid reacted in an aqueous media with ammonium hydroxide and potassium hydroxide; (2) a reaction mixture that provides fungicidal activity and fertilizes plants when applied in an effective amount and which comprises potassium phosphates, potassium polyphosphate, potassium phosphites, and potassium polyphosphite and potassium phosphate phosphite copolymers; and, optionally, (3) aqueous potassium acetate.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: June 11, 2013
    Assignee: Plant Food Systems, Inc.
    Inventor: Carl J. Fabry
  • Publication number: 20130143737
    Abstract: A composite particle and a population of particles comprising a water-insoluble polyphosphate composition, methods of producing, and methods of using the same are provided. The polyphosphate composition may comprise at least one alkaline earth metal selected from calcium and magnesium and optionally at least one nutrient ion selected from the group consisting of potassium, ammonium, zinc, iron, manganese, copper, boron, chlorine, iodine, molybdenum, selenium or sulfur.
    Type: Application
    Filed: August 8, 2011
    Publication date: June 6, 2013
    Applicant: AGTEC INNOVATIONS, INC.
    Inventor: Chandrika Varadachari
  • Patent number: 8430943
    Abstract: Multiple-component fertilizer materials and methods of use are provided, wherein the fertilizer materials include first and second fertilizer products respectively including an ammoniacal fertilizer (e.g., urea) in combination with a partial calcium salt of a selected copolymer, and a phosphorous fertilizer (e.g., DAP) in combination with a partial sodium salt of a selected copolymer. The copolymer fractions of the first and second fertilizer products are most preferably copolymers of itaconic acid and maleic anhydride. The fertilizer materials give synergistically enhanced crop yields when applied to soil or growing plants.
    Type: Grant
    Filed: January 6, 2012
    Date of Patent: April 30, 2013
    Assignee: Speciality Fertilizer Products, LLC
    Inventor: John Larry Sanders
  • Publication number: 20110302975
    Abstract: According to the present invention, there is provided a process for the manufacture of sulphur-containing fertilizer compositions, said process comprising the steps of: a) providing a slurry of at least one phosphate-based fertilizer material selected from the group consisting of ammonium phosphates, ammonium phosphate based nitrogen-phosphorus-potassium (NPK) compounds, super phosphates and partially acidulated phosphate rocks; b} bringing said slurry into contact with at least one surfactant and elemental sulphur; and c) introducing the mixture obtained in step b) into a granulator unit in order to obtain granules of the fertilizer composition, wherein the elemental sulphur is present in an amount in the range of form 1 to 25 wt. %, based on the total weight of the fertilizer composition The present invention also provides a fertilizer composition.
    Type: Application
    Filed: January 29, 2010
    Publication date: December 15, 2011
    Inventors: Jany Birgitta Maria Antens, Rafael Alberto Garcia Martinez, Reginald Lambert, Jason Trevor O'Brien, Marinus Johannes Reynhout, Guy Lode Magda Maria Verbist, John Woodruffe
  • Publication number: 20110230353
    Abstract: A water-dispersible particle is provided that includes struvite in an amount ranging from 5% to 99.9% by weight of the total dry weight of the particle. A binder component is present in an amount from 1% to 95% by weight. The struvite and the binder component on that contact with water causes particle dispersion into more than 100 pieces. A process for making a water-dispersible particle includes mechanical aggregation of a struvite into a pellet. A binder component is present in the particle in an amount ranging from 1% to 95% by weight. The struvite and the binder component are present in a form such that contact with water causes particle dispersion into more than 100 pieces. The particle is then dried and ready to be applied.
    Type: Application
    Filed: April 5, 2011
    Publication date: September 22, 2011
    Inventors: Charles W. Anderson, Timothy D. Birthisel
  • Publication number: 20110214465
    Abstract: A fertilizer composition including a base fertilizer granule with a barrier coating and one or more micronutrients. The base fertilizer material is coated with a barrier coating, and then a coating of one or more micronutrients. Alternatively, the base fertilizer material is coated with a barrier coating having discrete particles of micronutrients dispersed throughout. The barrier coating acts to physically and chemically isolate the micronutrient particles from the underlying fertilizer composition such that more of the micronutrient is available to the soil solution, and ultimately to the root zone of the plant.
    Type: Application
    Filed: February 25, 2011
    Publication date: September 8, 2011
    Inventors: Lawrence Alan Peacock, Samuel Stacey, Michael McLaughlin
  • Publication number: 20110120201
    Abstract: A vegetable based fluidic fertilizer derived from concentrated separator by-products (CSB.) The CSB is heat treated and optionally filtered to remove suspended particular matter. The heat treatment is performed in a range of about 150 to 200 degrees F. for about 24 to 96 hours. Filtration is provided using a standard wire mesh size in a range of about 50 to 200. The fertilizer may then be applied at about 25 to 200 gallons per acre. The fertilizer may be applied to agricultural vegetation either directly or by inclusion in an irrigation stream.
    Type: Application
    Filed: January 27, 2011
    Publication date: May 26, 2011
    Applicant: True Organic Products, Inc.
    Inventor: Jake Evans
  • Publication number: 20100311584
    Abstract: Provided is a freely flowing particulate fertilizer essentially consisting of potassium phosphate of the formula K3H3(PO4)2 and of less than 8 wt % water. The stable and not caking fertilizer is characterized by an XRD signal corresponding to 2-theta of about 70°. An economic process for making the fertilizer is also provided consisting in reacting KOH and monopotassium phosphate (KH2PO4) in water, heating the mixture under vacuum and cooling it down, thereby obtaining the particulate fertilizer.
    Type: Application
    Filed: November 13, 2008
    Publication date: December 9, 2010
    Applicant: ROTEM AMFERT NEGEV LTD.
    Inventors: Alexander Josef, Itshak Zukerman
  • Patent number: 7837757
    Abstract: This invention relates to the use of nitrogen- or calcium-containing fertilizers to improve the performance of S-(+)-abscisic acid (S-ABA, ABA) or ABA salts on plants. This invention also relates to the use of ABA to reduce the phytotoxicity of foliar applied fertilizers.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: November 23, 2010
    Assignee: Valent BioSciences Corporation
    Inventors: Xiaozhong Liu, Daniel F. Heiman, Derek D. Woolard, Yueh Wang, Benjamin Belkind, Prem Warrior, Gregory D. Venburg, Peter D. Petracek
  • Patent number: 7771505
    Abstract: A controlled release fertilizer composition and methods to produce the controlled release fertilizer composition are described. The controlled release fertilizer composition comprises a water soluble fertilizer core that is coated with a polymeric layer, intermediate layer, and a sulfur layer. If desired, the sulfur layer can be coated with an outer water-insoluble layer.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: August 10, 2010
    Assignee: Agrium Inc.
    Inventors: Jeffrey Michael Ogle, Johnny Duran Sims
  • Patent number: 7731775
    Abstract: Several compositions of matter have been discovered that can be used in the manufacture of slow-release fertilizers that contain all of the essential elements needed by plants and humans. Slow-release fertilizers manufactured with these formulations can be used on mineral stressed soils to increase the quality and production of food crops grown on them. Additives, including phosphogypsum, silica sand, natural gypsum, clay, and coal dust, facilitate the timing of the release of the essential elements into the soil.
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: June 8, 2010
    Assignee: University of South Florida
    Inventors: Jay W. Palmer, Heidi Kay
  • Patent number: 7291199
    Abstract: The invention relates to a process for the production of plant growth stimulator from fly ash, comprising treating fly ash with effluent NOx gases in a reactor under agitation at a temperature in the range of 60 to 100 degree celsius, for a time period in the range of 2 to 5 hours and treating the resulting material with effluent ammonia gas in the same reactor under ambient conditions for time period in the range of 20 to 50 minutes.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: November 6, 2007
    Assignee: Council of Scientific and Industrial Research
    Inventors: Sukuru Ramakrishna Rao, Swapan Kumar Ghosh, Gulab Singh, Sushanta Kumar Hazra
  • Patent number: 6541421
    Abstract: This invention relates to a buffered phosphorus containing solution comprising at least one phosphorus compound selected from the group consisting of phosphorous acid, hypophosphorous acid, polyphosphorous acid polyhypophosphorous acid, and salts thereof. The solution also contains a buffer including an organic base in the form of a nitrogen containing compound and its conjugate acid. The solution may be used as a fertilizer or as a fungicide. The invention also relates to a method of preparing such a solution.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: April 1, 2003
    Inventors: Alastair James Forsyth, Tomasz Antoni Modro
  • Patent number: 6358294
    Abstract: The invention relates to free-flowing, powder fertilizer compositions characterized by having enhanced aqueous dissolution rates and being able to produce drift reduced aqueous agricultural spray medium. Specifically, the compositions are water-soluble, nitrogen-containing fertilizers physically blended with a guar gum drift reduction agent and a silicone defoaming agent either encapsulated or absorbed in an agricultural carrier.
    Type: Grant
    Filed: August 10, 1999
    Date of Patent: March 19, 2002
    Assignee: Rosen's
    Inventor: John Alvis Latting
  • Patent number: 6312493
    Abstract: The present invention relates to a solid water soluble fertilizer composition containing one or more fertilizer materials and a phosphate free, organic acid which is solid at ambient temperatures. The fertilizer materials include primary macro nutrients, secondary macro nutrients, micro nutrients and mixtures thereof. The organic acid has a water solubility of at least 10 g/l (at 25° C.) and an acidifying effect in the range of 0.5 to 1.3 g HCO3−/g acid. The acidifying effect is defined as the amount of HCO3− that can be transformed into H2CO3 per gram of acid and is calculated in accordance with the following formula: 61 ⁢ n M w , acid wherein Mw,acid is the molecular weight of said acid and n represents the number of dissociation constants (i.e., pKa values) of the acid below the value of 6.35.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: November 6, 2001
    Assignee: OMS Investments, Inc.
    Inventors: Michael Gustaaf Eltink, Philip van Roij, Edze Jan Tijsma, Johannes Gijsbertus Antonius Terlingen, Hendrikus Gijsbertus Adrianus van Kaathoven
  • Patent number: 5997602
    Abstract: The invention relates to a stable, concentrated aqueous fertilizer suspension, which can be diluted with water to provide a working solution. The suspension contains 10 to 60% by weight of water and 40 to 90% by weight of a plant nutrient composition based on at least a calcium, and/or a magnesium and a phosphate ion, and the suspension comprises at least one plant nutrient containing water-insoluble solid particles with a particle size less than 50 .mu.m, the pH of the suspension being in the range of 0.5 to less than 2.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: December 7, 1999
    Assignee: Kemira Agro Oy
    Inventor: Hannu Aijala
  • Patent number: 5964917
    Abstract: The invention relates to free-flowing, powder fertilizer compositions characterized by having enhanced aqueous dissolution rates and being able to produce drift reduced aqueous agricultural spray medium.Specifically, the compositions are water-soluble, nitrogen-containing fertilizers physically blended with a guar gum drift reduction agent and a silicone defoaming agent either encapsulated or absorbed in an agricultural carrier.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: October 12, 1999
    Inventor: John Alvis Latting
  • Patent number: 5851260
    Abstract: The invention relates to a stable aqueous fertilizer suspension suitable for drip irrigation, which suspension contains 5-55% by weight water and 45-95% by weight of one or several plant-nutrient containing substances, of which at least one contains water-insoluble solid particles, the particle size of the solid particles contained in the suspension being less than 50 .mu.m and the pH of the suspension being within the range 2-7. The invention also relates to a process for the preparation of this suspension.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: December 22, 1998
    Assignee: Kemira Agro Oy
    Inventors: Hannu Aijala, Thomas Ahlnas
  • Patent number: 5679128
    Abstract: A method for producing a dry bonded solid nonionic surfactant/fertilizer adjuvant system comprising spray-coating dry water-soluble, nitrogen-containing fertilizer particles, preferably diammonium sulfate with the surfactant composition and the coated compositions produced thereby.
    Type: Grant
    Filed: January 31, 1995
    Date of Patent: October 21, 1997
    Inventors: John Alvis Latting, Ivan Russell Wells, Brett Lee Randol
  • Patent number: 5085681
    Abstract: An agricultural fertilizer material is provided which is resistant to agglomeration, powdering and burning of plant life and which is made up of lightweight blast furnace slag having a water content in the range of about 3% to 5% and mixed with about 10% to 35% by weight of a mixture of nitrogen, phosphoric acid and potash as conventional nutrient salts, said salts and nitrogen being present in amounts sufficient to provide at least 1% by weight of nitrogen on the total mix and said slag having a CaO equivalent of about 20% to 25%.
    Type: Grant
    Filed: January 9, 1989
    Date of Patent: February 4, 1992
    Inventor: Nicholas A. Boukidis
  • Patent number: 4515615
    Abstract: To make non-pressure nitrogenous fertilizer solutions, nitrogen oxides are prepared in a continuous process by burning ammonia in contact with a cobalt oxide catalyst started by an electric arc without preheating the gases. This burning forms nitrogen oxides which are reacted under negative pressure in a two-stage system. Nitric acid is formed in the first stage from a portion of the oxides by oxidizing them to nitrogen dioxide and reacting the nitrogen dioxide with water. In the second stage, the remaining nitrogen oxides are reacted at a pH between 8.0 and 8.4 in a gas-liquid contacting apparatus with an ammonium hydroxide reaction liquid, formed by mixing ammonia and water. The ammonium nitrite solution formed in the second stage is mixed with the nitric acid at a pH below 0.2, resulting in a solution of acidic ammonium nitrate to be flowed to the fields with irrigation water.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: May 7, 1985
    Inventor: John A. Eastin
  • Patent number: 4512794
    Abstract: To make non-pressure nitrogenous fertilizer solutions, nitrogen oxides are prepared in a continuous process by burning ammonia in contact with a cobalt oxide catalyst started by an electric arc without pre-heating the gases. This burning forms nitrogen oxides which are reacted under negative pressure in a two-stage system. Nitric acid is formed in the first stage from a portion of the oxides by oxidizing them to nitrogen dioxide and reacting the nitrogen dioxide with water. In the second stage, the remaining nitrogen oxides are reacted at a pH between 8.0 and 8.4 in a gas-liquid contacting apparatus with an ammonium hydroxide reaction liquid, formed by mixing ammonia and water. The ammonium nitrite solution formed in the second stage is mixed with the nitric acid at a pH below 0.2, resulting in a solution of acidic ammonium nitrate to be flowed to the fields with irrigation water.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: April 23, 1985
    Inventor: John A. Eastin
  • Patent number: 4511389
    Abstract: To make and use nitrogenous fertilizer on a farm, nitrogen dioxide is prepared in a continuous process from air or from ammonia in a reactor, with the ammonia either being transported to the farm or being prepared on the farm in a continuous process from water and air. The nitrogen dioxide is mixed with a continuous flow of water to form a dilute solution of nitric acid, which may be applied to the field through the irrigation system as top dressing or mixed within the irrigation system with ammonia or other cations to form ammonium nitrate or other desired nitrogen solutions for application to the fields in a continuous process or concentrated without requiring storage of large amounts of gas or creating heat exchange problems in the manufacturing process. In the embodiment which burns ammonia, the nitrogen oxides are fixed on an 8 percent nickel stainless steel mesh in a column 10 feet high and one foot in diameter and oxidized while fixed to nitrogen dioxide.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: April 16, 1985
    Inventor: John A. Eastin
  • Patent number: 4277459
    Abstract: Organic reaction mixtures, particularly of mixtures containing contaminant organic phosphorus compounds and/or sulfur, are worked up by introducing the mixture into water which has been made alkaline and has a temperature of from -10.degree. to +50.degree. C., a pH value of at least 10 being maintained in the resulting mixture, separating the aqueous phase from the sulfur which separates out; and contacting the aqueous phase or the sulfur which has separated out with nitric acid at an elevated temperature and a pH of below 3.
    Type: Grant
    Filed: February 13, 1980
    Date of Patent: July 7, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Otto Berendes, Karl-Heinz Vopel
  • Patent number: 4177052
    Abstract: There is disclosed a process for preparing fertilizers containing dicalcium phosphate from phosphates of mineral origin by mechanical activation. According to the invention grains larger than 5 mm of the sized or unsized starting phosphate compound of mineral origin are granulated up to a grain size of 1 to 4 mm, the granulated phosphate obtained is admixed with monocalcium phosphate and the phosphate crystals are activated by colliding the grains of the mixture at a speed of 70 to 120 m/sec.The fertilizer prepared according to the invention possesses numerous advantages over the known phosphate fertilizers from technological and applicational point of view as well.
    Type: Grant
    Filed: May 5, 1978
    Date of Patent: December 4, 1979
    Inventors: Karl Entzmann, Gyorgy Kalman, Janos Varga, Miklos Vecsei, Gabor Jankovics, Laszlone Kozicz
  • Patent number: 4175943
    Abstract: A water soluble mixed fertilizer composition in solid form and a method of producing the fertilizer composition. The fertilizer comprises a mixture of urea, phosphoric acid and at least one potassium salt selected from the class comprising potassium sulphate, potassium nitrate and potassium chloride. Ammonium salts selected from the class comprising ammonium nitrate and ammonium sulphate may optionally also be added to the mixtures. Solid fertilizer compositions possible according to this invention include compositions which contain between 5 and 42% nitrogen, between 2 and 15% phosphorus and between 1 and 38% potassium, these values being elemental mass as a percentage relative to the total mass of the composition.
    Type: Grant
    Filed: January 18, 1978
    Date of Patent: November 27, 1979
    Assignee: Triomf Fertilizers
    Inventors: Pieter J. Jordaan, Jacobus P. van Deventer
  • Patent number: 4123248
    Abstract: A biologically active slow release medium consisting of vitreous matrix including one or more water soluble biologically active constituents together with phosphorus pentoxide which vitreous matrix may include one or more dispersed phases, the vitreous matrix having a slow rate of solution in water, such that when the medium is immersed in water biologically active constituents are slowly released into solution. Nitrogen releasing material is also incorporated into the vitreous (glass) matrix, using an inorganic material that can be added to a melt of the glass to be formed.
    Type: Grant
    Filed: August 25, 1977
    Date of Patent: October 31, 1978
    Assignee: International Standard Electric Corporation
    Inventor: Cyril F. Drake