Containing Carbonates, Oxides, Sulfates, Or Halides Patents (Class 71/53)
  • Patent number: 9187380
    Abstract: A starter fertilizer product combining manganese with P and Zn creates a previously unknown synergy in early plant growth and plant health.
    Type: Grant
    Filed: July 15, 2014
    Date of Patent: November 17, 2015
    Assignee: Compass Minerals Manitoba, Inc.
    Inventors: Mark Goodwin, Kerry Green
  • Publication number: 20150027042
    Abstract: A fertilizer product for delivering starter fertilizer to crops in soils as an alternative to traditional phosphorus applications to enhance rapid early plant development. Specifically, the fertilizer product comprises a synergistic mixture of: from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.
    Type: Application
    Filed: July 15, 2014
    Publication date: January 29, 2015
    Inventors: Mark Goodwin, Kerry Green
  • Patent number: 8911525
    Abstract: An engineered soilless plant cultivation medium for potting applications includes specific balanced amounts of nutrient additives. Major nutrient cations (Ca, Mg, K, Na, H) are balanced according to optimal base saturation percentage ranges. Nutrient levels, namely, the amount of major nutrient cations, major nutrient anions and minor nutrients satisfy desired ranges for both standard Mehlich III soil extraction tests and saturated paste tests.
    Type: Grant
    Filed: June 10, 2013
    Date of Patent: December 16, 2014
    Assignee: Nano Growth Technologies, LLC
    Inventor: Timothy Ward
  • Publication number: 20140360240
    Abstract: A nutrient composition for biological systems, such as humans, animals, plants or microorganisms includes at least one monometallic or mixed-metallic phosphate of the (M1 M2 M3 . . . Mx)3(PO4)2.aH2O type where 0?a?9, where (M1, M2, M3 . . . Mx) represent the one metal of the monometallic phosphate or the two or more metals of the mixed-metallic phosphate and are selected from Na, K, Mg, Ca, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn and B, with the proviso that at least one of the metals in the phosphate is selected from Mn, Fe, Co and Ni.
    Type: Application
    Filed: December 21, 2012
    Publication date: December 11, 2014
    Applicant: CHEMISCHE FABRIK BUDENHEIM KG
    Inventors: Albertus Wissing, Gunnar Bühler, Christian Graf, Kilian Schwarz, Michael Rapphahn
  • Patent number: 8906451
    Abstract: A method for producing coated water-soluble particles in a manner to form two or more coating layers on surfaces of the water-soluble particles, characterized by including: a step A wherein after supplying a first coating material that contains a polyol component and an isocyanate component, a second coating material is additionally supplied to surfaces of first coating bodies that have coating layers formed of the first coating material that has not been sufficiently cured, so that second coating bodies that are provided with coating layers of the second coating material are obtained.
    Type: Grant
    Filed: October 5, 2010
    Date of Patent: December 9, 2014
    Assignee: Central Glass Company, Limited
    Inventors: Hiroyuki Fujii, Nobuhiro Okada, Hideaki Sueta, Tadashi Tanaka, Kazuyoshi Morita
  • Patent number: 8888887
    Abstract: A controlled release fertilizer material comprising a particulate plant nutrient surrounded by a coating of a mixture including an isocyanate and a polyol, and further comprising a modified wax that may include a polyhydroxyl compound in which the wax and/or the polyhydroxyl compound are cross-linked with a sulfur or oxygen or a peroxide cross-linking moiety. In certain embodiments, the wax and polyhydroxyl compound are cross-linked at unsaturated sites in the wax or polyhydroxyl compound using heat, UV or ionizing radiation.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: November 18, 2014
    Assignee: Agrium Advanced Technologies (U.S.) Inc.
    Inventors: Garrard Lee Hargrove, Sriramakrishna Maruvada, Robert Scott Wilson, Nick Peter Wynnyk, Baozhong Xing
  • Patent number: 8845775
    Abstract: This invention relates to a coating composition for a fertilizer comprising at least 50 wt % of a cross-linked lipid; and less than 0.20 wt %, relative to the total weight of the lipid, of a catalyst for cross-linking an unsaturated lipid. The cross-linked lipid has a viscosity at 20 degree Celsius (° C.) in the range of 110 and 800 mPa·s.
    Type: Grant
    Filed: September 28, 2010
    Date of Patent: September 30, 2014
    Assignee: Stamicarbon B.V.
    Inventor: Stefan Hendrikus Schaafsma
  • Patent number: 8814977
    Abstract: Preferred aspects of the present invention provide ammonium nitrate compositions comprising ammonium nitrate and at least one stabilizing agent, and preferably a third compound. In certain preferred embodiments, the stabilizing agent, together with third compound, is present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition and/or to otherwise improve a desired property of the composition.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: August 26, 2014
    Assignee: Honeywell International Inc.
    Inventors: James A. Kweeder, Richard J. Williams
  • Patent number: 8764873
    Abstract: Animal waste is processed to form a biomaterial that is employed as a coating layer for typical fertilizer particles. The biomaterial coating layer can be used neat or with additives and serves to do one or more or any combination of the following: (a) impart a slow or controlled release property to the fertilizer, (b) prevent or reduce the tendency of the fertilizer particles to cake together, or (c) prevent or reduce the tendency of the fertilizer particles to create dust. The biomaterial coating layer can also release nutrients when used as part of a fertilizer composition.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: July 1, 2014
    Inventor: James E. Nevin
  • Patent number: 8741022
    Abstract: A controlled release fertilizer composition and methods to produce the controlled release fertilizer composition are described. The controlled release fertilizer composition comprises a water soluble fertilizer core that is coated with a polymeric layer, intermediate layer, and a sulfur layer. If desired, the sulfur layer can be coated with an outer water-insoluble layer.
    Type: Grant
    Filed: May 22, 2012
    Date of Patent: June 3, 2014
    Assignee: Agrium Inc.
    Inventors: Jeffrey Michael Ogle, Johnny Duran Sims
  • Patent number: 8685134
    Abstract: The efficiency of applied phosphorus can be improved by applying phosphorus as a coating onto plant growth (roots and shoots) or by applying phosphorus as a coating on prills or granules of other forms of fertilizers. The composition comprises (a) monoammonium phosphate, (b) struvite and (c) magnesium sulphate. The first two ingredients ensure that there is a source of rapidly available phosphorus (MAP) and a source of more slowly available phosphorus (STRUV). The third ingredient is to provide a source of sulphate which will, in the area surrounding the coated product following application thereof to the soil, act to stop ambient calcium from reacting with the phosphate thereby rendering it inactive.
    Type: Grant
    Filed: May 25, 2010
    Date of Patent: April 1, 2014
    Assignee: Wolf Trax Inc.
    Inventor: Mark Goodwin
  • Patent number: 8647406
    Abstract: Multiple-component fertilizer materials and methods of use are provided, wherein the fertilizer materials include first and second fertilizer products respectively including an ammoniacal fertilizer (e.g., urea) in combination with a partial calcium salt of a selected copolymer, and a phosphorous fertilizer (e.g., DAP) in combination with a partial sodium salt of a selected copolymer. The copolymer fractions of the first and second fertilizer products are most preferably copolymers of itaconic acid and maleic anhydride. The fertilizer materials give synergistically enhanced crop yields when applied to soil or growing plants.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: February 11, 2014
    Assignee: Specialty Fertilizer Products, LLC
    Inventor: John Larry Sanders
  • Patent number: 8491692
    Abstract: A water-dispersible particle is provided that includes organic origin potash in an amount ranging from 5% to 99.9% by weight of the total dry weight of the particle. A binder component is present in an amount from 1% to 95% by weight. The organic origin potash and the binder component on that contact with water causes particle dispersion into more than 100 pieces. A process for making a water-dispersible particle includes mechanical aggregation of the potash into a pellet. A binder component is present in the particle in an amount ranging from 1% to 95% by weight. The potash and the binder component are present in a form such that contact with water causes particle dispersion into more than 100 pieces. The pellet is then dried and ready to be applied.
    Type: Grant
    Filed: September 7, 2010
    Date of Patent: July 23, 2013
    Assignee: The Andersons, Inc.
    Inventors: Charles W. Anderson, Timothy D. Birthisel
  • Patent number: 8480782
    Abstract: A composition has a core of at least one fertilizer substance and at least one layer of a coating material surrounding the core. The core may contain nitrogen and the coating material may include one or more linear, saturated aliphatic monocarboxylic acids.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: July 9, 2013
    Assignee: Tiger-Sul Products LLC
    Inventors: Danny R. Wright, Richard J. Valagene, Don T. Cherry, Keith D. Cochran, Tim G. Holt, Gregory S. Peeden
  • Patent number: 8163059
    Abstract: A coating oil composition and methods of using the composition for dust control is provided. The coating oil comprises utilizing a by-product from the manufacture of biodiesel and/or fatty alkyl esters, wherein the by-product comprises C6-C24 saturated and unsaturated fatty acids, C6-C24 saturated and unsaturated fatty acid salts, methyl esters, ethyl esters and combinations thereof.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: April 24, 2012
    Assignee: Nalco Company
    Inventors: Bo L. Tran, Theodore C. Arnst, Patrick C. Miller, Dmitri L. Kouznetsov
  • Patent number: 8152890
    Abstract: Kimberlite based fertilizer products are produced by treating micronized Kimberlite with alkali or first acid then alkali or by mixing the micronized kimberlite with DAP or NPK fertilizer.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: April 10, 2012
    Assignee: Bijam Biosciences Private Limited
    Inventor: Durga Yandapalli Prasad
  • Patent number: 8075660
    Abstract: Preferred aspects of the present invention provide ammonium nitrate compositions comprising ammonium nitrate and at least one stabilizing agent, and preferably a third compound. In certain preferred embodiments, the stabilizing agent, together with third compound, is present under conditions and in amounts effective to substantially reduce the detonation sensitivity of the composition and/or to otherwise improve a desired property of the composition.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: December 13, 2011
    Assignee: Honeywell International Inc.
    Inventors: James A. Kweeder, Richard J. Williams
  • Patent number: 7837757
    Abstract: This invention relates to the use of nitrogen- or calcium-containing fertilizers to improve the performance of S-(+)-abscisic acid (S-ABA, ABA) or ABA salts on plants. This invention also relates to the use of ABA to reduce the phytotoxicity of foliar applied fertilizers.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: November 23, 2010
    Assignee: Valent BioSciences Corporation
    Inventors: Xiaozhong Liu, Daniel F. Heiman, Derek D. Woolard, Yueh Wang, Benjamin Belkind, Prem Warrior, Gregory D. Venburg, Peter D. Petracek
  • Patent number: 7771505
    Abstract: A controlled release fertilizer composition and methods to produce the controlled release fertilizer composition are described. The controlled release fertilizer composition comprises a water soluble fertilizer core that is coated with a polymeric layer, intermediate layer, and a sulfur layer. If desired, the sulfur layer can be coated with an outer water-insoluble layer.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: August 10, 2010
    Assignee: Agrium Inc.
    Inventors: Jeffrey Michael Ogle, Johnny Duran Sims
  • Patent number: 7736412
    Abstract: Improved gypsum fertilizer compositions are provided by coating of naturally-occurring or synthesized gypsum with low pH maleic-itaconic copolymers. The preferred copolymers are aqueous dispersions of acid or partial salt maleic-itaconic copolymers, and are applied by spraying or other means onto the surface of gypsum and allowed to dry. The copolymer coatings increase the solubility of sulfate and Ca ions from the gypsum, allowing accelerated plant availability and uptake of such nutrients.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: June 15, 2010
    Assignee: Specialty Fertilizer Products, LLC
    Inventor: John Larry Sanders
  • Patent number: 7731775
    Abstract: Several compositions of matter have been discovered that can be used in the manufacture of slow-release fertilizers that contain all of the essential elements needed by plants and humans. Slow-release fertilizers manufactured with these formulations can be used on mineral stressed soils to increase the quality and production of food crops grown on them. Additives, including phosphogypsum, silica sand, natural gypsum, clay, and coal dust, facilitate the timing of the release of the essential elements into the soil.
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: June 8, 2010
    Assignee: University of South Florida
    Inventors: Jay W. Palmer, Heidi Kay
  • Patent number: 7695541
    Abstract: A non-acidic, aqueous fertilizer suspension having a pH equal to or greater than 7 includes at least one water-insoluble calcium salt and at least one water-soluble calcium salt. The water-insoluble salt may be calcium carbonate, calcium phosphate tribasic, and calcium phosphate dibasic while the water soluble salt may be calcium acetate, calcium citrate, calcium chloride, calcium gluconate, calcium hydroxide, calcium lactate, calcium lignosulfate, and calcium iodate. The fertilizer suspension may include a multifunctional surfactant/dispersing agent/thickener, a multifunctional chelator/dispersant/stabilizer, a biocide and at least one plant nutrient selected from the group consisting of boron, copper, iron, magnesium, manganese, and zinc. In the fertilizer compositions, the total calcium salts comprise about 2% to about 70% by weight of the composition and the water-insoluble calcium salt comprises at least about 50% by weight of the total of the water-insoluble and water-soluble calcium salts.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: April 13, 2010
    Inventors: Raymond B. Frizzell, Michael J. Loosemore
  • Patent number: 7686863
    Abstract: Improved gypsum fertilizer compositions are provided by coating of naturally-occurring or synthesized gypsum with low pH maleic-itaconic copolymers. The preferred copolymers are aqueous dispersions of acid or partial salt maleic-itaconic copolymers, and are applied by spraying or other means onto the surface of gypsum and allowed to dry. The copolymer coatings increase the solubility of sulfate and Ca ions from the gypsum, allowing accelerated plant availability and uptake of such nutrients.
    Type: Grant
    Filed: October 5, 2009
    Date of Patent: March 30, 2010
    Assignee: Specialty Fertilizer Products, LLC
    Inventor: John Larry Sanders
  • Patent number: 7635404
    Abstract: Blends of fertilizer granules and highly absorbent cellulosic granules carrying one or more pesticidal or other active ingredients that resist the formation of actives dust or segregation of the granules and that ensure even and efficient application of both the fertilizer and the active ingredients.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: December 22, 2009
    Assignee: Kadant GranTek Inc.
    Inventors: Milenko Devic, Paul A. Dongieux, Jr.
  • Publication number: 20090270257
    Abstract: An extended release fertilizer that includes an absorbent material containing capillaries/voids between 10-200 microns in cross-sectional diameter which is impregnated in an amount of 40-95% of the capillaries/voids volume with an agriculturally beneficial material, or alternatively includes a holding agent retaining an agriculturally beneficial material, wherein the beneficial material at least includes calcium sulfate, and the beneficial material is selected from the group consisting of fertilizers, insecticides, herbicides and fungicides, with the resulting material being agglomerated into granules.
    Type: Application
    Filed: June 25, 2009
    Publication date: October 29, 2009
    Inventors: Taylor Pursell, Arthur R. Shirley, JR., Keith D. Cochran, Timothy G. Holt, Gregory S. Peeden
  • Patent number: 7608126
    Abstract: The present disclosure provides a plant rejuvenating agent using dehydroepiandrosterone (DHEA), or hydrates thereof, to form plant rejuvenating mixtures that may include additional components. The plant rejuvenating mixture including DHEA may be used in typical horticultural applications, including the improvement of soil fertility; the rejuvenation of unhealthy plants by providing both water for increased turgidity and sterols for plant cell repair; enhancing the longevity of growing season of plants; and retarding the senescence of fresh cut flowers.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: October 27, 2009
    Inventor: Robert C. Starcher
  • Patent number: 7494526
    Abstract: A technique is provided for delivering plant supportive materials to plants. The technique utilizes encapsulation of a plant growth facilitator, such as a plant nutrient, water or pesticide, in small structures that may be taken in through the stomata of plants. This enables a more efficient treatment, watering and/or feeding of plants by foliar application.
    Type: Grant
    Filed: July 11, 2005
    Date of Patent: February 24, 2009
    Inventor: Edward Q. Yavitz
  • Patent number: 6488735
    Abstract: A fertilizer compound having a glass matrix comprises, among the forming oxides of the glass matrix, a phosphorus pentoxide (P2O5) as partial and/or full replacement of silica (SiO2); among the modifier oxides of the said glass matrix, a potassium oxide (K2O) as partial and/or full replacement of sodium oxide (Na2O); and one or more trace elements.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: December 3, 2002
    Inventors: Giuseppe Macchioni, Giovanni Marazzi, Franco Ambri
  • Patent number: 6312493
    Abstract: The present invention relates to a solid water soluble fertilizer composition containing one or more fertilizer materials and a phosphate free, organic acid which is solid at ambient temperatures. The fertilizer materials include primary macro nutrients, secondary macro nutrients, micro nutrients and mixtures thereof. The organic acid has a water solubility of at least 10 g/l (at 25° C.) and an acidifying effect in the range of 0.5 to 1.3 g HCO3−/g acid. The acidifying effect is defined as the amount of HCO3− that can be transformed into H2CO3 per gram of acid and is calculated in accordance with the following formula: 61 ⁢ n M w , acid wherein Mw,acid is the molecular weight of said acid and n represents the number of dissociation constants (i.e., pKa values) of the acid below the value of 6.35.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: November 6, 2001
    Assignee: OMS Investments, Inc.
    Inventors: Michael Gustaaf Eltink, Philip van Roij, Edze Jan Tijsma, Johannes Gijsbertus Antonius Terlingen, Hendrikus Gijsbertus Adrianus van Kaathoven
  • Patent number: 6287356
    Abstract: Mechanically strong, water-disintegrable agglomerates for use as a soil conditioner produced from cement kiln dust and other particulate calcium sources containing CaO or Ca(OH)2 and other calcium-containing compounds having the potential to be hydrated and a process for forming such agglomerates are disclosed. The process comprises combining the particulate calcium source and a water-soluble binder to produce agglomerates which are then subjected to controlled drying such that the dried agglomerates having a size ranging from −7 to +8 Tyler Standard Sieve Series exhibit an average green crush strength of at least about 2 pounds (about 0.9 kg).
    Type: Grant
    Filed: April 27, 1998
    Date of Patent: September 11, 2001
    Assignee: Magic Green Corporation
    Inventors: Greg Wommack, Carl Holley, Eugene Greskovich
  • Patent number: 6217629
    Abstract: Provided herein are novel porous phosphate sulfur fertilizer particles which are in a continuous phase, and have applications in supplying soluble phosphates to plants and crops, thus increasing the yield of such crops. Also provided are novel methods of producing such porous phosphate sulfur fertilizer particles.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: April 17, 2001
    Assignee: Rutgers, The State University of New Jersey
    Inventor: Robert Kunin
  • Patent number: 5997602
    Abstract: The invention relates to a stable, concentrated aqueous fertilizer suspension, which can be diluted with water to provide a working solution. The suspension contains 10 to 60% by weight of water and 40 to 90% by weight of a plant nutrient composition based on at least a calcium, and/or a magnesium and a phosphate ion, and the suspension comprises at least one plant nutrient containing water-insoluble solid particles with a particle size less than 50 .mu.m, the pH of the suspension being in the range of 0.5 to less than 2.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: December 7, 1999
    Assignee: Kemira Agro Oy
    Inventor: Hannu Aijala
  • Patent number: 5851260
    Abstract: The invention relates to a stable aqueous fertilizer suspension suitable for drip irrigation, which suspension contains 5-55% by weight water and 45-95% by weight of one or several plant-nutrient containing substances, of which at least one contains water-insoluble solid particles, the particle size of the solid particles contained in the suspension being less than 50 .mu.m and the pH of the suspension being within the range 2-7. The invention also relates to a process for the preparation of this suspension.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: December 22, 1998
    Assignee: Kemira Agro Oy
    Inventors: Hannu Aijala, Thomas Ahlnas
  • Patent number: 5743934
    Abstract: Mechanically strong, water-disintegrable agglomerates for use as a soil conditioner produced from dust particles emitted from kilns during the manufacture of cement and a process for forming such agglomerates are disclosed. The process comprises combining cement kiln dust and a water-soluble binder to produce agglomerates which are then subjected to controlled drying such that the dried agglomerates having a size ranging from -7 to +8 Tyler Standard Sieve Series exhibit an average green crush strength of at least about 2 pounds (about 0.9 kg).
    Type: Grant
    Filed: July 5, 1996
    Date of Patent: April 28, 1998
    Assignee: Magic Green Corporation
    Inventors: Greg Wommack, Carl Holley, Eugene Greskovich
  • Patent number: 5653782
    Abstract: The invention relates to a process for obtaining sulfur-containing fertilizers. According to the invention, a substrate containing fertilizer particles is heated to a temperature above the melting point of sulfur and subsequently by admixing with the sulfur, the latter is melted by the heat provided by said preheated fertilizer particles, producing a homogeneous coating on the fertilizer particles. According to a preferred embodiment the temperature at which the fertilizer particles are heated will be in the range of 140.degree. C. to 280.degree. C. Other materials may be added either into the phosphate or to the resulted mixture, having the purpose to modify the physical nature of the sulfur. The sulfur availability from the coated fertilizer particles may be adjusted by varying the temperature at which the fertilizer particles are heated. Typical examples of fertilizers useful for the process are: phosphate rock, superphosphate, monopotassium phosphate, triple superphosphate and potassium chloride.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: August 5, 1997
    Assignee: Rotem Amfert Negev Ltd.
    Inventors: Shmuel Stern, Eli Ben-Yoseph
  • Patent number: 5571303
    Abstract: A particulate sulfur-based fertilizer comprising a uniform dispersion of sulfur and at least one member selected from the group consisting of ammonium sulfate, ammonium phosphate and mixtures thereof, the sulfur having an average particle size of less than about 100 .mu.m. A process for producing a sulfur-based fertilizer is also described.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: November 5, 1996
    Assignee: Cominco Fertilizers Ltd.
    Inventor: Stewart G. Bexton
  • Patent number: 5451242
    Abstract: A synthetic soil/fertilizer for horticultural application having all the agronutrients essential for plant growth is disclosed. The soil comprises a synthetic apatite fertilizer having sulfur, magnesium and micronutrients dispersed in a calcium phosphate matrix, a zeolite cation exchange medium saturated with a charge of potassium and nitrogen cations, and an optional pH buffer. Moisture dissolves the apatite and mobilizes the nutrient elements from the apatite matrix and the zeolite charge sites.
    Type: Grant
    Filed: May 2, 1994
    Date of Patent: September 19, 1995
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Douglas W. Ming, Donald L. Henninger, Earl R. Allen, Dadigamuwage C. Golden
  • Patent number: 5433766
    Abstract: A synthetic apatite containing agronutrients and a method for making the apatite are disclosed. The apatite comprises crystalline calcium phosphate having agronutrients dispersed in the crystalline structure. The agronutrients can comprise potassium, magnesium, sulfur, iron, manganese, molybdenum, chlorine, boron, copper and zinc in amounts suited for plant growth. The apatite can optionally comprise a carbonate and/or silicon solubility control agent. The agronutrients are released slowly as the apatite dissolves.
    Type: Grant
    Filed: May 2, 1994
    Date of Patent: July 18, 1995
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Douglas W. Ming, Dadigamuwage C. Golden
  • Patent number: 5158594
    Abstract: Process for converting phospho-gypsum waste product from the wet process of manufacturing phosphoric acid from phosphate rock by ammoniating said product at a pH of 6.5 or less and adjusting the phosphorus and potassium values of said ammoniated product by addition of one or more sources of potassium and phosphorus.
    Type: Grant
    Filed: October 25, 1982
    Date of Patent: October 27, 1992
    Inventor: Ronald E. Oxford
  • Patent number: 5041153
    Abstract: Synthetic inorganic chemical fertilizers are treated with lignosulfonate to harden and provide anti-caking and anti-dusting properties to the fertilizer particles. The fertilizer/lignosulfonate mixture includes up to about 5.0% by weight lignosulfonate on fertilizer. An improved method of treating inorganic fertilizers with lignosulfonate is also disclosed.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: August 20, 1991
    Assignee: Daishowa Chemicals Inc.
    Inventor: William J. Detroit
  • Patent number: 5037470
    Abstract: A vitreous product which can be used in agriculture is disclosed. With the exception of nitrogen, this vitreous product contains all the major and minor mineral elements which are essential for the nutrition of plants.The vitreous products can contain the following constituents, taken in the following proportions by weight:______________________________________ SiO.sub.2 25 to 65% Fe.sub.2 O.sub.3 1 to 15% P.sub.2 O.sub.5 1 to 15% B.sub.2 O.sub.3 0.01 to 2% K.sub.2 O 5 to 35% MnO 0.01 to 3% CaO 11 to 35% ZnO 0.01 to 3% MgO 1 to 10% CuO 0.01 to 2% SO.sub.3 0.01 to 1% MoO.sub.3 0.01 to 3% Na.sub.2 O 0 to 2% Al.sub.2 O.sub.3 0 to 25%.
    Type: Grant
    Filed: March 28, 1989
    Date of Patent: August 6, 1991
    Assignee: Isover Saint-Gobain
    Inventors: Guy Matzen, Denise Blanc, Maryse Montarone
  • Patent number: 4846871
    Abstract: Synthetic inorganic chemical fertilizers are treated with lignosulfonate to harden and provide anticaking and anti-dusting properties to the fertilizer particles. The fertilizer/lignosulfonate mixture includes up to about 5.0% by weight lignosulfonate on fertilizer. An improved method of treating inorganic fertilizers with lignosulfonate is also disclosed.
    Type: Grant
    Filed: March 10, 1987
    Date of Patent: July 11, 1989
    Assignee: Reed Lignin Inc.
    Inventor: William J. Detroit
  • Patent number: 4547213
    Abstract: A fertilizer composition which provides high soil mobility of phosphorus comprising an intimate mixture of 1 to 100 micron size ground rock phosphate and sufficient sulfur of 1 to 5 micron size in a weight ratio of P.sub.2 O.sub.5 :S in the range of 1:0.5 to 1:2.0 to convert said rock phosphate to a soluble form of phosphorus when said sulfur is oxidized by soil bacteria to sulfuric acid.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: October 15, 1985
    Assignee: Stoller Enterprises, Inc.
    Inventor: Jerry H. Stoller
  • Patent number: 4515615
    Abstract: To make non-pressure nitrogenous fertilizer solutions, nitrogen oxides are prepared in a continuous process by burning ammonia in contact with a cobalt oxide catalyst started by an electric arc without preheating the gases. This burning forms nitrogen oxides which are reacted under negative pressure in a two-stage system. Nitric acid is formed in the first stage from a portion of the oxides by oxidizing them to nitrogen dioxide and reacting the nitrogen dioxide with water. In the second stage, the remaining nitrogen oxides are reacted at a pH between 8.0 and 8.4 in a gas-liquid contacting apparatus with an ammonium hydroxide reaction liquid, formed by mixing ammonia and water. The ammonium nitrite solution formed in the second stage is mixed with the nitric acid at a pH below 0.2, resulting in a solution of acidic ammonium nitrate to be flowed to the fields with irrigation water.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: May 7, 1985
    Inventor: John A. Eastin
  • Patent number: 4512794
    Abstract: To make non-pressure nitrogenous fertilizer solutions, nitrogen oxides are prepared in a continuous process by burning ammonia in contact with a cobalt oxide catalyst started by an electric arc without pre-heating the gases. This burning forms nitrogen oxides which are reacted under negative pressure in a two-stage system. Nitric acid is formed in the first stage from a portion of the oxides by oxidizing them to nitrogen dioxide and reacting the nitrogen dioxide with water. In the second stage, the remaining nitrogen oxides are reacted at a pH between 8.0 and 8.4 in a gas-liquid contacting apparatus with an ammonium hydroxide reaction liquid, formed by mixing ammonia and water. The ammonium nitrite solution formed in the second stage is mixed with the nitric acid at a pH below 0.2, resulting in a solution of acidic ammonium nitrate to be flowed to the fields with irrigation water.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: April 23, 1985
    Inventor: John A. Eastin
  • Patent number: 4511389
    Abstract: To make and use nitrogenous fertilizer on a farm, nitrogen dioxide is prepared in a continuous process from air or from ammonia in a reactor, with the ammonia either being transported to the farm or being prepared on the farm in a continuous process from water and air. The nitrogen dioxide is mixed with a continuous flow of water to form a dilute solution of nitric acid, which may be applied to the field through the irrigation system as top dressing or mixed within the irrigation system with ammonia or other cations to form ammonium nitrate or other desired nitrogen solutions for application to the fields in a continuous process or concentrated without requiring storage of large amounts of gas or creating heat exchange problems in the manufacturing process. In the embodiment which burns ammonia, the nitrogen oxides are fixed on an 8 percent nickel stainless steel mesh in a column 10 feet high and one foot in diameter and oxidized while fixed to nitrogen dioxide.
    Type: Grant
    Filed: June 23, 1983
    Date of Patent: April 16, 1985
    Inventor: John A. Eastin
  • Patent number: 4482372
    Abstract: A fluid fertilizer composition based essentially on potassium chloride and an ammonium phosphate prepared by a process which comprises comminuting a solid substance containing potassium chloride and ammonium phosphate by grinding in the presence of a saturated solution of solid in a liquid in which the solid has a solubility greater than 1% by weight, the mixture of the solution and the solid being in fluid condition with the solid being a separate phase during grinding and the solution having dissolved therein an additive which is a crystal growth inhibitor for the solid whereby crystal growth is inhibited at both existing crystal surfaces and new crystal surfaces created by the breaking down of relatively coarse particles.
    Type: Grant
    Filed: December 23, 1982
    Date of Patent: November 13, 1984
    Assignee: Imperial Chemical Industries PLC
    Inventors: Derek A. Palgrave, Frederick A. Waite, James D. Birchall, John Cooper, James A. Enever
  • Patent number: 4478633
    Abstract: The method comprises processing slime and off-gases resulting from the production of phosphorus with an aqueous solution of copper sulphate having a concentration of from 15 to 50% at a temperature within the range of from 20.degree. to 80.degree. C. As a result, two products are obtained, i.e. a liquid product and a solid one.The solid product containing mainly copper phosphide as well as fluorides and chlorides of alkali metals and silicon, and silicates of calcium and aluminium, is used as a modifying and refining agent for hypereutectic silumines and for the manufacture of a copper-phosphorus alloy.The liquid product containing phosphoric acid, sulphuric acid and copper sulphate is used as starting product for the preparation of a copper-containing fertilizer.The method according to the present invention makes it possible to modify the production of phosphorus so as to eliminate the formation of secondary wastes and improve the evnironmental control.
    Type: Grant
    Filed: June 15, 1982
    Date of Patent: October 23, 1984
    Inventors: Vasily B. Chernogorenko, Tleubai M. Alzhanov, Kima A. Lynchak, Simon V. Muchnik, Evgeny S. Ishkhanov, Vladimir Y. Sergienko, Vladimir G. Sapian, Vladimir M. Koverya, Mendel E. Pobortsev, Evgeny A. Markovsky, Valentina V. Dmitrenko, Vladimir I. Bykov, Alexandr D. Kipchakvaev, Alexandr N. Vopilov
  • Patent number: 4470839
    Abstract: Solid particles of metal peroxide are coated by means of a coating agent containing a water-soluble condensed phospahte.
    Type: Grant
    Filed: April 27, 1982
    Date of Patent: September 11, 1984
    Assignee: INTEROX (Soci/e/ t/e/ Anonyme)
    Inventor: Ignace Gago
  • Patent number: RE48377
    Abstract: A starter fertilizer product combining manganese with P and Zn creates a previously unknown synergy in early plant growth and plant health.
    Type: Grant
    Filed: April 30, 2019
    Date of Patent: January 5, 2021
    Assignee: Compass Minerais Manitoba Inc.
    Inventors: Mark Goodwin, Kerry Green