Abstract: To make and use nitrogenous fertilizer on a farm, nitrogen dioxide is prepared in a continuous process from air or from ammonia in a reactor, with the ammonia either being transported to the farm or being prepared on the farm in a continuous process from water and air. The nitrogen dioxide is mixed with a continuous flow of water to form a dilute solution of nitric acid, which may be applied to the field through the irrigation system as top dressing or mixed within the irrigation system with ammonia or other cations to form ammonium nitrate or other desired nitrogen solutions for application to the fields in a continuous process or concentrated without requiring storage of large amounts of gas or creating heat exchange problems in the manufacturing process. In the embodiment which burns ammonia, the nitrogen oxides are fixed on an 8 percent nickel stainless steel mesh in a column 10 feet high and one foot in diameter and oxidized while fixed to nitrogen dioxide.

Abstract: A method is provided for reducing ammonia volatilization loss from ammoniated fertilizers and urea-containing fertilizers which have been applied to the surface of the soil. The fertilizer is applied in the presence of a water soluble compound that (a) has a saturated solution pH between about 5.0 to about 8.0 and (b) in a hydrolyzing system with the soil and the fertilizer will form carbonates having a solubility above about 10.sup.-10 grams per liter. The amount of the water soluble compound is that which is sufficient to suppress the formation of hydroxyl ions that otherwise would be produced in the soil according to the reactionYCO.sub.3 +H.sub.2 O.revreaction.Y(OH).sub.2 +CO.sub.2with Y=calcium or magnesium.

Abstract: The effectiveness of a potassium polyphosphate fertilizer is enhanced resulting in higher intake of phosphorus and potassium into plant tissues and higher crop yields by the foliar application to growing plants of a composition comprising a blend of potassium and ammonium polyphosphates which also contains an effective amount of a protein hydrolysate.

Abstract: The present invention provides a stabilized fertilizer solution, especially a nitrogen fertilizer solution, with a content of dicyandiamide as nitrification inhibitor, wherein, for retarding dicyandiamide crystallization, the solution contains at least one water-soluble organic polymeric compound as stabilizer.

Abstract: The present invention relates to new azulmic acids stabilized by condensation with carbonyl compounds, several processes for their preparation and their use for various purposes.

Abstract: A homogeneous, zinc-containing liquid fertilizer concentrate is prepared by mixing, in aqueous solution, ammonium thiosulfate and zinc oxide. This zinc-containing concentrate is suitable for mixing with a liquid fertilizer preparation such as aqueous ammonium polyphosphate to prepare a complete zinc-containing fertilizer solution. The nutrient value of the concentrate and the fertilizer can be enhanced by the addition of a potassium salt or nitrogen solution. The long-term stability of the fertilizer solution can be improved by the addition of attapulgus clay.

Abstract: A process of producing a potassium sulfate salt comprising reacting sulfuric acid with potassium chloride at an equivalent ratio of sulfuric acid to potassium chloride of 1.07 to 1.40 at a temperature of from the melting point of potassium bisulfate to about 500.degree. C. while allowing the resulting solid-liquid mixture at the final reaction stage to be substantially in a state of wet cake, said potassium bisulfate being present in the reaction system until the termination of the reaction because of the excess sulfuric acid. In such a process, the reaction proceeds smoothly at a relatively low temperature and is completed in an extremely shortened period of time to produce a potassium sulfate salt with an extremely low chlorine content which is useful as a raw material for the production of potassium-containing chemical manures to be suitably applied onto the farmland of tobacco etc. which are apt to have their growth hampered by chlorine values.

Abstract: An improved method of producing potassium sulfate from langbeinite. The improved method employs a "salting out" step to remove additional KCl from the mother liquor resulting from K.sub.2 SO.sub.4 crystallization. NaCl is added to the mother liquor to cause precipitation of KCl crystals. The amount of NaCl added is controlled to an amount below the saturation point for NaCl in the solution to avoid contaminating the KCl with solid NaCl. The KCl crystals are recycled back to the K.sub.2 SO.sub.4 reactors as a source of KCl. The "salting out" step eliminates an energy-intensive submerged combustion evaporation step from the K.sub.2 SO.sub.4 recovery process and consequently reduces atmospheric emissions.

Abstract: Micronutrient fertilizer consisting of iron, manganese, copper, boron, and zinc in which the manganese-to-iron ratio is 8 to 20%, the copper-to-iron ratio is 5 to 10%, the boron-to-iron ratio is 0.4 to 1.0%, and the zinc-to-iron ratio is 6 to 12%.

Abstract: A dispersion of up to about 70 weight percent elemental sulfur in an aqueous ammonia solution of at least one metal compound selected from the group consisting of soluble zinc and magnesium compounds has reduced corrosive activity toward ferrous metal. The atomic ratio of zinc and/or magnesium to sulfur is from about 0.0002 to about 0.1 and the mole ratio of ammonia to metal compound is from about 0.1 to about 200.

Abstract: A particulate filter medium for collecting finely dispersed particles from a circulating gas stream. The filter medium comprises a gas flow zone consisting essentially of gas permeable particles of the same material as the finely dispersed solid particles to be collected. The finely dispersed particles are generated by granular product blending operations of dry granular materials such as fertilizers, chemicals, animal feeds and clays.A substantial saving in filter material renewal costs is realized by adding the spent filter medium to the product stream, and simply replacing the spent filter medium with fresh, granular particles of the product having a capacity to collect finely dispersed solid particles from the circulating gas stream.

Abstract: A process for producing a citric acid soluble potassium silicate fertilizer comprises a step for kneading a mixture consisting essentially of potassium carbonate, fly ash, pulverized coal, other necessary starting materials and a caustic potash solution as a binder and then granulating the kneaded mixture, a step for drying the granulated product to a nearly absolutely dry state, and a step for calcining the dried granular product, whereby a chemical reaction takes place between the potassium and the silicon present in fly ash to convert them into a citric acid soluble potassium silicate.

Abstract: Cold anhydrous ammonia, preferably cold liquid anhydrous ammonia at substantially ambient or atmospheric pressure is applied to feed grains, forages and anaerobically fermentable plant material to supply thereto and provide therein non-protein nitrogen (NPN). The cold anhydrous ammonia is obtained by supplying a stream of ambient temperature, pressurized anhydrous liquid ammonia to an expansion chamber for expansion therein to provide the cold anhydrous ammonia. Cold anhydrous ammonia, preferably substantially only cold liquid anhydrous ammonia, is recovered from the expansion chamber operated under substantially adiabatic conditions, at a temperature in the range -30.degree. F. to about -17.degree. F. and at substantially ambient or atmospheric pressure, such as at a pressure in the range 1 pound per square inch below atmospheric pressure up to about 5 pounds per square inch atmospheric pressure.

Abstract: Ammonium sulfate in dissolved form is dried in a gas current to obtain the ammonium sulfate in finely divided form. Thereafter the ammonium sulfate is quickly placed into a pelletizing device, subjected to a fine water spray, pelletized to substantially uniform grain size, and dried if necessary and/or desired.

Abstract: A free-flowing granular fertilizer composition and a process for its preparation in which the granules comprise expanded, substantially oil-free coffee grounds as a carrier coated and impregnated with a urea-formaldehyde condensation product. The condensation product has from 1 to 3 moles of urea for each mole of formaldehyde and the composition has at least 15% of the total nitrogen in cold water insoluble form.

Abstract: The preparation of dry, stable granular material from water-soluble potassium and ammonium salts and a mixture thereof by subjecting a dispersion of crystals of the salt in an aqueous liquid to the action of a granulating device in the presence of calcium sulphate hemihydrate and a hydrophilic surface active agent to effect agglomeration of said crystals, and thereafter subjecting the agglomerated crystals to a drying operation.

Abstract: Method for the production of a liquid fertilizer and respectively fertilizer concentrate, starting from an aqueous suspension and solution, respectively, of Haselgebirge and respectively or Werklaist, by addition of calcium carbide with stirring.

Abstract: An aqueous manganese micronutrient solution comprising between 0.1 and 2.0 wt. % of ferrous ion, about 5 wt. % manganous ion, between 1 and 1.5 moles of citric acid anion per mole of manganous ion and ammonia in an amount to maintain the pH of the solution between 7.5 and 12.

Abstract: A process for granulating crystalline fertilizer borate to produce a product with exceptionally satisfactory physical and chemical properties in regard to bulk blending with other fertilizer blend materials and also in regard to storage and handling properties. The process involves specialized procedures in processing the solid feedstock and granulating the solids with use of a small amount of acid solution. Product drying is not required.

Abstract: A dispersion of up to about 70 weight percent elemental sulfur in an aqueous ammonia solution of at least one metal compound selected from the group consisting of soluble zinc and magnesium compounds has reduced corrosive activity toward ferrous metal. The atomic ratio of zinc and/or magnesium to sulfur is from about 0.0002 to about 0.1 and the mole ratio of ammonia to metal compound is from about 0.1 to about 200.

Abstract: A procedure is disclosed for preparing nitrogen-potassium fertilizer residing in interaction of potassium hydrogen sulfate with calcium nitrate, barium nitrate or strontium nitrate in an aqueous medium, followed by treatment of the reaction mass with ammonia, separation of the resulting slightly soluble sulfate and isolation of the desired product.

Abstract: An aqueous solution of ammonium thiosulfate, ammonia and at least one metal compound selected from the group consisting of the oxides and salts of copper, zinc and manganese provides a source of sulfur, nitrogen and micronutrient metals for fertilizer use.

Abstract: A granulation process for the production of high purity granules of salt material comprising:(a) a wet blend formed by intensively mixing together(i) particles of soluble fine water-soluble salt having a relatively wide size distribution over the range of from about -30 to about +325 screen size (Tyler mesh),(ii) water insoluble particles of about -150 screen size (Tyler mesh) with surface area above 1 M.sup.2 /gr, and(iii) sufficient water or saturated water solution to provide a moisture content of up to about 20% and preferably in the range of from about 5 to 15% by weight of the mixture,(b) granulating the wet blend from (a), preferably by pan granulation, and(c) drying and recovering the granular product.The product comprises a granular salt product which has the properties of high purity (up to 99% salt), uniform size distribution in the range of from about 2 to 4 mm, a crush strength of greater than about 3 lb/granule and generally in the range of from about 5 to 10 lbs.

Abstract: Plant growth media are described as composed of various combinations of vermiculite, perlite, and clay and having superior properties for use as potting soil for container-grown plants. Such media are characterized by greater moisture capillarity and available moisture retention. There is also less danger of plant injury through nutrient deficiencies, over-fertilization, of pH changes. Such media are also characterized by their dry state physical properties in the form of non-compacting, light weight, non-vitreous, rigid foam structures. The dry state media have plant nutrients uniformly distributed throughout and fixed in place. These properties make the media superior for wet-casting into plant containers or extruding into pellets. After filling and upon drying, the media-containers can be inverted without dislodging their contents and the media can be repeatedly wetted and dried while maintaining the desired foam structure.

Abstract: Fertilizers and kerogen materials are extracted from crushed oil shale utilizing a low temperature dekerosing (kerogen removal) solvent phase followed by a second fertilizer extraction phase using water as solvent. Process control factors are effective in producing delamination of the crushed oil shale resulting in high yield of kerogen and fertilizer values. The dross shale residue is not disintegrated and constitutes an ecologically acceptable soil conditioner and land restoration residuum. Proper blending of the various extracts and residues result in a wide variety of commercial fertilizer products. Bitumens and fertilizer materials may also be extracted from tar sands of both the hard, stony and soft variety and again a non-petroleum solvent, low temperature extraction process is used in a first step to recover the bitumen fraction. The solvent is totally recovered and recycled. Thermal energies are also recycled resulting in high overall efficiency.

Abstract: Cold ammonia, preferably cold liquid anhydrous ammonia at substantially ambient or atmospheric pressure is applied (1) to the soil as a fertilizer and (2) to feed grains, forages and anaerobically fermentable plant material to supply thereto and provide therein non-protein nitrogen (NPN). The cold ammonia is obtained by (1) introducing a stream of ambient temperature, pressurized liquid ammonia at a velocity of at least about 5000 feet per minute into an expansion chamber, (2) imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia formed in the chamber. Cold ammonia, which is predominantly in the liquid form, is recovered from the expansion chamber operated under substantially adiabatic conditions, at a temperature of about -28.degree. F.

Abstract: This invention relates to a method of promoting the flowering of grape vines.

Abstract: This invention relates to a composition for promoting the flowering of mango trees which comprises:A. from about 7 to 15% by weight of a salt of calcium selected from the group consisting of Ca(OH).sub.2 and CaCO.sub.3B. from about 0.06 to 0.08% by weight of KOHC. from about 0.05 to 0.07% by weight of H.sub.3 PO.sub.4D. from about 15.00 to 25% by weight HNO.sub.3E. from about 0.005 to 0.0007% by weight NH.sub.4 OHF. from about 0.001 to 0.006% by weight of MnSO.sub.4G. from about 0.006 to 0.10% by weight of FeSO.sub.4H. from about 0.00002 to 0.003% by weight of ZnSO.sub.4I. from about 0.15 to 0.35% by weight of MgSO.sub.4J. balance water.

Abstract: A fertilizer concentrate and process for making same in which a sulfuric acid solution contacts an ammonia containing gas to produce a liquid non-crystalline ammonium sulfate. The reaction takes place in an absorber wherein the reactants are maintained at about 120.degree.F., the outlet stream from the reactor being split into two streams, one of which is recycled to the absorber and the other of which is recycled to a circulation tank for sulfuric acid make-up. The weight percent of ammonium sulfate in the final solution is in the range of about 35% to about 42% by weight.

Abstract: Lawn moss is controlled with an herbicidally effective amount of granular ferric ammonium sulfate-ammonium sulfate double salts of the empirical formula (NH.sub.4).sub.3 Fe(SO.sub.4).sub.3.xH.sub.2 O wherein x is 0 to 12. The double salts also provide excellent greening of the treated lawn.

Abstract: The caking tendency of ammonium salt compositions during storage is reduced by coating the compositions with a minor amount of a hydroxy-aluminum polymer.