With Another Nonmetal Patents (Class 75/233)
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Patent number: 5695544Abstract: A silicon nitride based sintered product having strength at a high temperature is obtained by sintering a mixture. The mixture comprises a silicon powder or a mixture powder of silicon and silicon nitride added a sintering assistant powder, a compound powder of iron and a compound powder containing at least one of vanadium, niobium and tantalum in 5a group elements of the periodic table. The silicon nitride based sintered product contains silicon, aluminum, yttrium, oxygen, nitrogen, iron and at least one of 5a group element in the periodic table, and when weights at which the elements are present as a compound of silicon nitride, alumina, yttria, a compound powder of iron and 5a group elements in the periodic table are represented by a, b, c, d and e, the following formulae are fulfilled:1.ltoreq.100(b+c+d+e).times.(a+b+c+d+e).ltoreq.15, 1.ltoreq.(b+c)/d0.005.ltoreq.100d/(a+b+c+d+e).ltoreq.7.5, and 0.005.ltoreq.e/(b+c).ltoreq.Type: GrantFiled: April 18, 1996Date of Patent: December 9, 1997Assignee: Isuzu Ceramics Research Institute Co., Ld.Inventor: Toshiyuki Yamada
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Patent number: 5610347Abstract: The invention relates to a material for electric contacts taking silver tin-oxide as basis, consisting of silver or mainly silver-containing alloy, tin oxide and other oxides or carbides of tungsten, molybdenum, vanadium, bismuth, titanium, and/or copper.Type: GrantFiled: February 21, 1995Date of Patent: March 11, 1997Assignee: Doduco GmbH & Co. Dr. Eugen DurrwachterInventors: Volker Behrens, Thomas Honig, Andreas Kraus, Karl E. Saeger, Rainer Schmidberger, Theodor Staneff
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Patent number: 5561829Abstract: A method of preparing a metal alloy product from a powder blend. The method comprising: (a) cold pressing a blend to form a compact, the metal blend comprising a metal powder phase and at least one reinforcement phase having a hardness greater than the metal phase; (b) heating the compact to form a preheated compact; and (c) hot working the heated compact. In a preferred method, the powder metal blend comprises 50 to 90 vol. % of an aluminum alloy powder and 10 to 50 vol. % of silicon carbide; the heating of the compact perforated in a nitrogen atmosphere to form a preheated compact; and the extruded hot compact is hot worked. Hot working may take the form of forging, rolling, upset forging, exuding, compacting or other processes known in the art.Type: GrantFiled: April 27, 1995Date of Patent: October 1, 1996Assignee: Aluminum Company of AmericaInventors: Ralph R. Sawtell, Warren H. Hunt, Jr., Thomas J. Rodjom, Erik J. Hilinski, John H. Milsom
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Patent number: 5520716Abstract: An Al.sub.2 O.sub.3 -TiC sintered product comprising Al.sub.2 O.sub.3 as a main component and containing TiC in an amount of from 20 to 40% by weight, wherein the average particle diameter of Al.sub.2 O.sub.3 particles in the sintered product is larger by 5 to 50% than the average particle diameter of TiC particles, the average particle diameter of the sintered product as a whole is not larger than 1 .mu.m, the average particle diameter of TiC particles is not larger than 0.9 .mu.m, and the total amount of the grain boundary phases other than Al.sub.2 O.sub.3 and TiC is not larger than 1.0% by weight. The Al.sub.2 O.sub.3 -TiC sintered product can be used as a substrate 1 for a magnetic head, and has portions such as grooves 4 and stepped portions formed in the surface of the air bearing surface 2 of the slider by being irradiated with ions. The sintered product exhibits excellent surface quality after machined by being irradiated with ions and can be machined at an increased rate.Type: GrantFiled: March 2, 1995Date of Patent: May 28, 1996Assignee: Kyocera CorporationInventors: Nobuoki Takagi, Hiroki Tokunaga, Shinichiro Masuyama
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Patent number: 5501728Abstract: The present invention relates to a friction material for use in manufacturing various friction bearing components such as brakes, clutches, couplings, transmission systems and the like. The composition of the friction material includes a base friction material and a metal sulfide-iron powder alloy mixture which is added to the base material and further mixed prior to compression molding the desired component.Type: GrantFiled: July 22, 1994Date of Patent: March 26, 1996Assignee: Brake Pro, Inc.Inventors: Christopher C. Shepley, David R. Carter
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Patent number: 5486222Abstract: Contact materials with the composition AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO have proven themselves, particularly for low-voltage switching devices. These materials can contain an additive of other metal oxides. In addition to the required useful lifetime and suitable excess high temperature behavior, such materials are also supposed to fulfill all the requirements under short-circuit current stress. This is accomplished, according to the invention, in that the additional metal oxide is separately added stannic oxide and/or iron containing at least one element of the sixth sub-group of the periodic system. In the sintered composite material according to the invention, the other metal oxide is particularly ferric tungstate (FeWO.sub.4). Preferably, separately added SnO.sub.2 is present in combination with FeWO.sub.4.Type: GrantFiled: July 18, 1994Date of Patent: January 23, 1996Assignee: Siemens AktiengesellschaftInventor: Franz Hauner
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Patent number: 5460640Abstract: A fully dense ceramic-metal body including 40-88 v/o of an oxide hard phase of, in v/o of the body, 4-88 v/o M-aluminum binary oxides, where the binary oxide has a C-type rare earth, garnet, .beta.-MAl.sub.11 O.sub.18, or perovskite crystal structure, and M is a lanthanide or indium, and 0-79 v/o .alpha.-alumina; about 10-50 v/o of a hard refractory carbide, nitride, or boride as a reinforcing phase; and about 2-10 v/o of a dispersed metal phase combining Ni and Al mostly segregated at triple points of the microstructure. The preferred metal phase contains a substantial amount of the Ni.sub.3 Al ordered crystal structure. In the preferred body, the reinforcing phase is silicon carbide partially incorporated into the oxide grains, and bridges the grain boundaries. The body including a segregated metal phase is produced by densifying a mixture of the hard phase components and the metal component, with the metal component being present in the starting formulation as Ni powder and Al powder.Type: GrantFiled: August 17, 1992Date of Patent: October 24, 1995Assignee: Valenite Inc.Inventor: Sergej-Tomislav Buljan
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Patent number: 5457075Abstract: A sintered ceramic composite comprising 35 to 80 wt. % of aluminum nitride, 2 to 60 wt. % of boron nitride, 0.1 to 25 wt. % of an oxide of magnesium, 0.5 to 20 wt. % of at least one of rare earth oxides including yttrium oxide as an optional component and 25 wt. % or less of aluminum oxide as an optional component is disclosed.Type: GrantFiled: May 11, 1994Date of Patent: October 10, 1995Assignee: Hitachi Metals, Ltd.Inventors: Hideko Fukushima, Yasuo Sawano, Katsuhiko Kojo
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Patent number: 5443615Abstract: A method of producing a molded ceramic article comprises the first step mixing powdery raw materials and a liquid additive, thereby obtaining a mixed raw material, the second step press-molding the mixed raw material obtained in the first step in a hydrostatically applied condition of pressure, thereby removing an excess of the liquid additive to obtain a preform, and the third step calcining the preform obtained in the second step to obtain a molded ceramic article. The molded ceramic article comprises, as a principal component, copper and, as essential components, Cr and Ni within composition ranges of 0.1.ltoreq.Cr<2 wt. % and 0.1.ltoreq.Ni<10 wt. % and further at least one additive component selected from the group consisting of the following composition ratios: the following composition ratios: 0<Fe<5 wt. %, 0.ltoreq.Co<5 wt. %, 0.ltoreq.Al<10 wt. % 0.ltoreq.Ti<20 wt. %, 0.ltoreq.Mo<3 wt. %, 0.ltoreq.Si<3 wt. % 0.ltoreq.V<3 wt. % 0.ltoreq.Mg<1 wt. % and 0.ltoreq.Type: GrantFiled: October 22, 1992Date of Patent: August 22, 1995Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Mitsuo Kuwabara, Kiyoshi Ikegami, Teruaki Yoshida, Koji Takahashi, Tamotsu Harada, Takeshi Komiyama, Fumio Hirai, Masamichi Hayashi
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Patent number: 5439499Abstract: A cermet useful in the fabrication of metal cutting, rockdrilling and mineral tools, as well as wear parts. The cermet comprises (i) a hard phase of a simple boride of a transition metal, a mixture of simple borides of transition metals, or a mixed boride of transition metals; (ii) a binder phase of Fe, Ni, Co, Cr, or alloys thereof; (iii) a dispersion of particles of oxides of transition metals in which the oxygen can be replaced by nitrogen and/or carbon; and (iv) a dispersion of oxides of metals chosen from aluminum and Group IIA and IIIA metals.Type: GrantFiled: February 26, 1993Date of Patent: August 8, 1995Assignee: Sandvik ABInventors: Henri Pastor, Colette Allibert, Laurent Ottavi, Manuel Albajar, Francisco Castro-Fernandez
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Patent number: 5401292Abstract: A carbonyl iron powder (CIP) premix composition suitable for metal injection molding is provided herein. The composition comprises (a) CIP having a particle size in the range of about 0.2-7 microns, preferably about 0.2-5 microns, and a narrow particle size distribution; and (b) an alloying material, having a particle size in the range of about 0.02 to 5 microns, preferably about 0.03 to 3.0 microns, and a narrow particle size distribution, comparable to the CIP, and present in an amount of about 0.1-60% by weight of the composition, preferably 0.5-50%. The alloy material substantially covers the surface of the iron particles and is adhered thereto by attractive forces. Preferably the alloy material includes elemental metal powders which are smaller in particle size than the CIP.The premix composition is prepared by intensive mixing of its powder components, e.g.Type: GrantFiled: August 3, 1992Date of Patent: March 28, 1995Assignee: ISP Investments Inc.Inventor: Joseph E. Japka
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Patent number: 5396148Abstract: Ultrafine particles of a composite particulate substance composed of two or more types of inorganic oxides, forming a particle structure in which two or more types of inorganic oxides are mutually mixed or an inorganic oxide of one type is contained in an inorganic oxide of another type, and having an average particle diameter of not more than 0.1 .mu.m, a process for the production of the ultrafine particles, use of the ultrafine particles as a thin film, particularly in an image display face plate and a cathode ray tube, and a process for using the ultrafine particles therefor.Type: GrantFiled: November 16, 1992Date of Patent: March 7, 1995Assignee: Hitachi, Ltd.Inventors: Yoshishige Endo, Takeshi Araya, Masahiko Ono, Takao Kawamura, Hiromitsu Kawamura
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Patent number: 5350628Abstract: A magnetic material is provided which includes a discrete phase including grains made of a first substance which comprises a magnetic metal; and a continuous phase including a thin coating film made of a second substance which comprises a dielectric or insulating substance. The thin coating film is formed on the surface of the grains and has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film.Type: GrantFiled: November 19, 1992Date of Patent: September 27, 1994Assignee: Matsushita Electric Industrial Company, Inc.Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Ken Hirota, Mitsuo Satomi
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Patent number: 5294239Abstract: In section bars and shaped bodies made of nickel-base superalloys having a structure consisting of columnar grains, a complete recrystallization cannot be effected unless the heating-up rate is kept below a maximum heating-up rate T.sub.max, which depends on the ratio V of one or more of the metal carbide-forming elements hafnium, niobium, tantalum, titanium and zirconium to one or both of the metal carbide-forming elements tungsten and molybdenum.Type: GrantFiled: May 6, 1991Date of Patent: March 15, 1994Assignee: PM Hochtemperatur-Metall GmbHInventors: Klaus Zoltzer, Klaus Lempenauer, Hellmut Fischmeister
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Patent number: 5240513Abstract: An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.Type: GrantFiled: October 9, 1990Date of Patent: August 31, 1993Assignee: Iowa State University Research Foundation, Inc.Inventors: R. William McCallum, Kevin W. Dennis, Barbara K. Lograsso, Iver E. Anderson
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Patent number: 5238507Abstract: A magnetic material is provided which includes a discrete phase including grains made of a first substance which comprises a magnetic metal; and a continuous phase including a thin coating film made of a second substance which comprises a dielectric or insulating substance. The thin coating film is formed on the surface of the grains and has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film.Type: GrantFiled: June 8, 1990Date of Patent: August 24, 1993Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Ken Hirota, Mitsuo Satomi
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Patent number: 5217543Abstract: A rare earth-iron magnet consisting of, by atomic percent, 10 to 16% Nd, 5 to 10% B, 0.1 to 1% V, 0.1 to 1% oxygen and the balance being Fe.Type: GrantFiled: May 8, 1992Date of Patent: June 8, 1993Assignee: Seiko Instruments Inc.Inventor: Yoshio Inokoshi
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Patent number: 5209772Abstract: A dispersion-strengthened (DS) alloy, more particularly oxide-dispersion-strengthened (ODS) iron-based alloys which manifest resistant to oxidation at temperatures as high as 1300.degree. C. (approx. 2400.degree. F.) whereby the alloys are useful in the production of advanced aircraft gas turbine engine components and in demanding industrial applications.Type: GrantFiled: October 5, 1988Date of Patent: May 11, 1993Assignee: Inco Alloys International, Inc.Inventors: Raymond C. Benn, Gaylord D. Smith, John J. Fischer
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Patent number: 5194099Abstract: A sinter magnet based on Fe-Nd-B with improved coercive field strength and reduced temperature dependency thereof consists of 25 to 50 wt. % Nd, 0.5 to 2 wt. % B, 0 to 5 wt. % Al, 0.5 to 3 wt. % O, remainder Fe and usual impurities and has an oxygen content which is adjusted by the addition of oxygen or of oxygen-containing compounds, especially of an Al and/or Nd oxide, before the dense sintering. It is obtainable by the melting together of the pure components with formation of a pre-alloy, pulverisation of the pre-alloy, alignment of the powder in a magnetic field and pressing to a green formed body, sintering at 1040.degree. to 1100.degree. C. and subsequent annealing at 600.degree. to 700.degree. C., whereby one adds the oxygen as Al or Nd oxide or via the grinding and/or sintering atmosphere.Type: GrantFiled: May 23, 1990Date of Patent: March 16, 1993Assignees: 501 Max-Planck-Gesellschaft zur Forderung der Wissenschaften E.V., 502 Robert Bosch GmbHInventors: Friedrich Esper, Waldemar Draxler, Gunter Petzow, Andreas Buchel, Klaus-Dieter Durst, Ernst-Theo Henig, Gerhard Schneider, Helmut Kronmuller
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Patent number: 5189337Abstract: Ultrafine particles of a composite particulate substance composed of two or more types of inorganic oxides, forming a particle structure in which two or more types of inorganic oxides are mutually mixed or an inorganic oxide of one type is contained in an organic oxide of another type, and having an average particle diameter of not more than 0.1 .mu.m, a process for the production of the ultrafine particles, use of the ultrafine particles as a thin film, particularly in an image display face plate and a cathode ray tube, and a process for using the ultrafine particles therefor.Type: GrantFiled: September 8, 1989Date of Patent: February 23, 1993Assignee: Hitachi, Ltd.Inventors: Yoshishige Endo, Takeshi Araya, Masahiko Ono, Takao Kawamura, Hiromitsu Kawamura
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Patent number: 5181953Abstract: A coated cemented carbide alloy, excellent in toughness as well as wear resistance and which is used for cutting tools and wear resistance tools is provided herein. This coated cemented carbide alloy is composed of a cemented carbide substrate consisting of a hard phase of at least one member selected from carbides, nitrides and carbonitrides of Group IVb, Vb and VIb metals of the Periodic Table and a binder phase consisting of at least one member selected from the iron group metals, and a monolayer or multilayer, provided on the substrate consisting of at least one member selected from carbides, nitrides, oxides and borides of Group IVb, Vb and VIb metals of Periodic Table, solid solutions thereof and aluminum oxide, and wherein a binder phase-enriched layer is provided in a space 0.01 mm and 2 mm below the surface of the substrate with A-type and/or B-type pores inside the binder phase-enriched layer.Type: GrantFiled: December 27, 1990Date of Patent: January 26, 1993Assignee: Sumitomo Electric Industries, Ltd.Inventors: Minoru Nakano, Toshio Nomura
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Patent number: 5173107Abstract: The invention relates to a composite hard metal body of hard material, a binder and embedded reinforcing material, as well as to a process for the production of the composite hard metal body by methods of powder metallurgy.In order to create a composite hard metal body with improved toughness under load, improved hardness and a lower fracture susceptibility, the invention proposes to build in monocrystalline, preferably needle-shaped and/or platelet-shaped reinforcing materials, coated with an inert layer with respect to the binder metal phase and consisting of borides and/or carbides, and/or nitrides and/or carbonitrides of the elements of Groups IVa or Va or mixtures thereof and/or coated monocrystalline reinforcing material of SiC, Si.sub.3 N.sub.4, Si.sub.2 N.sub.2 O, Al.sub.2 O.sub.3, ZrO.sub.2, AlN and/or BN.Type: GrantFiled: June 10, 1991Date of Patent: December 22, 1992Assignee: Krupp Widia GmbHInventors: Klaus Dreyer, Hans Kolaska
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Patent number: 5162064Abstract: A permanent magnet of the neodymium-iron-boron type having improved corrosion resistance imparted by a combination of oxygen, carbon and nitrogen. Oxygen is provided in an amount equal to or greater than 0.6 weight percent in combination with carbon of 0.05-0.15 weight percent and nitrogen 0.15 weight percent maximum. Preferably, oxygen is within the range of 0.6-1.2% with carbon of 0.05-0.1% and nitrogen 0.02-0.15 weight percent or more preferably 0.04-0.08 weight percent. The magnet may be heated in an argon atmosphere and thereafter quenched in an atmosphere of either argon or nitrogen to further improve the corrosion resistance of the magnet.Type: GrantFiled: April 10, 1990Date of Patent: November 10, 1992Assignee: Crucible Materials CorporationInventors: Andrew S. Kim, Floyd E. Camp, Edward J. Dulis
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Patent number: 5160366Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.Type: GrantFiled: March 14, 1991Date of Patent: November 3, 1992Assignees: Sumico Management Planning Company, Ltd., Akira ShibataInventor: Akira Shibata
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Patent number: 5149361Abstract: A cermet alloy having a structure including a hard phase and a bonding phase which is composed of at least one ferrous metal, said bonding phase containing fine hard grains of a mean grain size not greater than 2000 .ANG. dispersed therein. The structure has a composition consisting of 10 to 70 wt % of TiCN, 5 to 30 wt % of WC, 5 to 30 wt % of NbC, 1 to 10 wt % of Mo.sub.2 C, 0.5 to 5 wt% of VC, 0.05 to 3 wt % of ZrC, 5 to 25 wt % of (Ni, Co), and not smaller than 2.5 wt% of total nitrogen and incidental impurities.Type: GrantFiled: December 26, 1989Date of Patent: September 22, 1992Assignees: Hitachi, Ltd., Hitachi Taga Engineering Co., Ltd.Inventors: Yusuke Iyori, Nobuhiko Shima
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Patent number: 5143540Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceamic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and pressing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressures of 60-250 kpsi employed at a rate of 5-250 kpsi/second.Type: GrantFiled: September 18, 1990Date of Patent: September 1, 1992Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Robert R. McDonald, Alexander Pecnenik
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Patent number: 5125990Abstract: A magnetically anisotropic hot-worked magnet made of an R-T-B alloy containing a transition metal T as a main component, a rare earth element R including yttrium, and boron B; the magnet having the fine crystal grains having an average grain size of 0.02 -1.0 .mu.m, and having a carbon content of 0.8 weight % or less and an oxygen content of 0.5 weight % or less. The angular variance of orientation of the crystal grains is within 30.degree. from the C axes of the crystal grains when measured by X-ray. This magnet can be produced by mixing the magnet flakes with an additive composed of at least one organic compound having a boiling point of 50.degree. C. or higher.Type: GrantFiled: June 1, 1990Date of Patent: June 30, 1992Assignee: Hitachi MetalsInventors: Katsunori Iwasaki, Shigeho Tanigawa, Masaaki Tokunaga
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Patent number: 5110349Abstract: A cutting insert of a sintered carbonitride alloy and with a complicated geometry, the insert having improved efficiency. This is obtained by giving the powder non-uniform compaction during pressing of the powder into a press-body so that the ultimate working edges will have a higher relative density than the surrounding, more "supporting" material in the press-body. By these means are often obtained surface defects in the form of cracks because of dissolved strains during the sintering.Type: GrantFiled: November 14, 1990Date of Patent: May 5, 1992Assignee: Sandvik ABInventors: Kenneth Westergren, Gerold Weinl, Rolf Oskarsson
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Patent number: 5110688Abstract: The present invention relates to a method of fabricating various types of bearing materials and the bearing materials produced thereby. The processes of the invention may be used to produce porous self-lubricating bearings, laminated composite bearings (babbitt bearings) and bearings for high temperature application. The processes of the invention involve the use of micro-pyretic synthesis to achieve bearing materials with improved bearing properties, including higher bearing capacity and toughness.Type: GrantFiled: December 3, 1990Date of Patent: May 5, 1992Assignee: University of CincinnatiInventors: Jainagesh A. Sehkar, A. K. Bhattacharya, Hung P. Li
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Patent number: 5089354Abstract: A copper alloy composite material which comprises a copper alloy matrix and at least one additive selected from solid materials having self-lubricity and wear-resistant materials and uniformly dispersed in the alloy matrix is described. The composite material has improved wear resistance and anti-seizing properties.Type: GrantFiled: December 11, 1990Date of Patent: February 18, 1992Assignee: Chuetsu Metal Works, Co., Ltd.Inventors: Kunio Nakashima, Ryouichi Ishigane, Takayuki Tanaka, Ken-ichi Ichida
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Patent number: 5077246Abstract: A method for the preparation of ceramic composites containing at least aluminum oxide and aluminum boride, and the composite materials that result from the method. Intimate mixtures of finely-divided powdered aluminum metal and anhydrous boric oxide, with ratios (by weight) of about 0.5 to twenty parts of aluminum metal to one part of boric oxide, are subjected to a temperature to cause a complete reaction between the starting materials. If the ratio is above about 1.25 parts of aluminum to one part of boric oxide, the resultant product will include aluminum in addition to the aluminum oxide and aluminum boride. The ratio is selected to provide the desired hardness and toughness. Ratios between about 1 and 1.2 provide a composite having the highest hardness, with greater amounts of aluminum metal providing increased toughness. Several compositions are described, with hot pressing typically being used to provide the desired heating cycle.Type: GrantFiled: June 4, 1990Date of Patent: December 31, 1991Assignee: Apollo Concepts, Inc.Inventors: Samuel C. Weaver, Sally G. Padron
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Patent number: 5053074Abstract: A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.Type: GrantFiled: December 20, 1990Date of Patent: October 1, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5045278Abstract: An aluminum based metal matrix composite is produced from a charge containing a rapidly solidified aluminum alloy, a carbidiferous agent and particles of a reinforcing material present in an amount ranging from about 0.1 to 50% by volume of the charge. The charge is ball milled energetically to uniformly mix the carbidiferous agent within the aluminum matrix, and to enfold metal matrix material around each of the particles while maintaining the charge in a pulverulent state. Upon completion of the ball milling step, the charge is hot consolidated at suitable temperatures to decompose the carbidiferous agent and result in the formation of carbide and oxide particles, and to provide a powder compact having a formable, substantially void-free mass. The compact is especially suited for use in aerospace, automotive, electronic, wear resistance critical components, and the like, which often encounter service temperatures approaching 500.degree. C.Type: GrantFiled: November 9, 1989Date of Patent: September 3, 1991Assignee: Allied-Signal Inc.Inventors: Sontosh K. Das, Michael S. Zedalis, Paul S. Gilman
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Patent number: 5041261Abstract: A method for manufacturing a dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal binder phase. The hard phase is (a) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, borides, and mixtures thereof of the elements selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and B, or (b) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, and carboxynitrides, and mixtures thereof of a cubic solid solution of Zr--Ti, Hf--Ti, Hf--Zr, V--Ti, Nb--Ti, Ta--Ti, Mo--Ti, W--Ti, W--Hf, W--Nb, or W--Ta. The binder phase is a combination of Ni and Al having a Ni:Al weight ratio of from about 85:15 to about 88:12, and 0-5% by weight of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Co, B, and/or C. The method involves presintering the hard phase/binder phase mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then HIPing at about 1575.degree.-1675.degree. C.Type: GrantFiled: December 21, 1990Date of Patent: August 20, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5011798Abstract: A chromium additive of the formula: Cr.sub.x C.sub.y O.sub.z where 0.04.ltoreq.y.ltoreq.0.35, and 0.03.ltoreq.z.ltoreq.0.30 for x=1, said additive having an X ray diffraction peak at d=3.32 .ANG. (2.theta.=26.8.degree.).Type: GrantFiled: September 28, 1989Date of Patent: April 30, 1991Assignee: Tosoh CorporationInventors: Minoru Sasabe, Masao Imamura, Yasunobu Yoshida, Shinya Andoh, Hiroshi Miyake
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Patent number: 5006163Abstract: A novel, nickel-base, high temperature alloy body preferably containing about 20% chromium, 6 to 7% aluminum to provide phase, 1.5 to 2.5% molybdenum, 3 to 4.5% tungsten, additional strengthening elements and oxidic yttrium in finely dispersed form. The alloy body has an elongated crystal structure and is characterized by high strength along with excellent hot corrosion and oxidation resistance.Type: GrantFiled: May 8, 1989Date of Patent: April 9, 1991Assignee: Inco Alloys International, Inc.Inventors: Raymond C. Benn, Jeffrey M. Davidson, Kenneth R. Andryszak
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Patent number: 5004498Abstract: A dispersion strengthened copper alloy containing a copper matrix, and dispersion particles dispersed in the copper matrix within a range of 0.5 to 6 vol %. In this alloy, an average diameter of a matrix region where the dispersion particles are not present is 0.3 .mu.m or less, and the total amount of solid solution elements contained in the copper matrix is determined such that, when this amount of the solid solution elements is added to pure copper, the electric conductivity of the matrix is lowered by 5% IACS or less.Type: GrantFiled: October 10, 1989Date of Patent: April 2, 1991Assignee: Kabushiki Kaisha ToshibaInventors: Keizo Shimamura, Kagetaka Amano, Tatsuyoshi Aisaka, Satoshi Hanai, Kohsoku Nagata
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Patent number: 4999336Abstract: There is provided a substantially fully dense powdered metal composite comprising a highly conductive metal or metal alloy matrix having dispersed therein discrete microparticles of a refractory metal oxide and discrete macroparticles of a mechanical or physical property-conferring additive material. The respective components undergo minimal alloying or interdispersion because sintering is not utilized in forming the composite. These composites are characterized by high thermal or electrical conductivity and a desired property (controlled thermal expansion, high strength, wear and arc erosion resistance, or magnetic) attributable to the composite forming material, like refractory metal, alloy, or compound. The composites are useful in forming lead frames for integrated circuit chips, electric lamp lead wires, electrical contact members, and discrete component leads.Type: GrantFiled: June 17, 1988Date of Patent: March 12, 1991Assignee: SCM Metal Products, Inc.Inventors: Anil Nadkarni, Prasan K. Samal, James E. Synk
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Patent number: 4973355Abstract: The invention relates to sintered hard metals having high cutting properties, particularly plastic deformation resistance at high temperatures, crater resistance and the like, suitable for use as cutting tools, wear resistant tools and materials for dies, and the method for producing the same. The invention has for an object to obtain both sintered hard metals having the aforesaid high properties by sintering metallic components comprising IVa group metals, VIa group metals or metals of both groups substituted by Va group metals up to 60 mol % respectively, a B-1 type solid solution hard phase consisting of non-metallic components of C, N and O, and a metallic bonding phase, in a CO gas atmosphere, and to sintered hard metals in which an uniform hardness is imparted to the surface and interior thereof by the method of sintering the said sintered hard metal in a CO gas atmosphere.Type: GrantFiled: October 31, 1988Date of Patent: November 27, 1990Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kunihiro Takahashi, Toshio Nomura, Takaharu Yamamoto
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Patent number: 4973356Abstract: The present invention relates to a method of preparing an alloy for use as a cutting tool material comprising hard principles and binder phase by which a uniform distribution of the hard principles in the binder phase is obtained, and the resulting product.Type: GrantFiled: October 23, 1989Date of Patent: November 27, 1990Assignee: Sandvik ABInventors: Peder von Holst, Hakan Morberg, Rolf Oskarsson
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Patent number: 4961778Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceramic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and presssing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressure of 60-250 kpsi employed at a rate of 5-250 kpsi/second.Type: GrantFiled: January 13, 1988Date of Patent: October 9, 1990Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Alexander Pechenik, Robert R. McDonald
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Patent number: 4954170Abstract: High density compacts are made by providing a compactable particulate combination of Class 1 metals selected from at least one of Ag, Cu and Al, with material selected from at least one of CdO, SnO, SnO.sub.2, C, Co, Ni, Fe, Cr, Cr.sub.3 C.sub.2, Cr.sub.7 C.sub.3, W, WC, W.sub.2 C, WB, Mo, Mo.sub.2 C, MoB, Mo.sub.2 B, TiC, TiN, TiB.sub.2, Si, SiC, Si.sub.3 N.sub.4, usually by mixing powders of each, step (1); uniaxially pressing the powders to a density of from 60% to 95%, to provide a compact, step (2); hot densifying the compact at a pressure between 352 kg/cm.sup.2 (5,000 psi) and 3,172 kg/cm.sup.2 (45,000 psi) and at a temperature from 50.degree. C. to 100.degree. C. below the melting point or decomposition point of the lower melting component of the compact, to provide densification of the compact to over 97% of theoretical density; step (3); and cooling the compact, step (4).Type: GrantFiled: June 30, 1989Date of Patent: September 4, 1990Assignee: Westinghouse Electric Corp.Inventors: Maurice G. Fey, Natraj C. Iyer, Alan T. Male, William R. Lovic
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Patent number: 4939038Abstract: A light metallic composite material containing therein fine granular additives dispersed in a matrix of a light metallic material, which composite material has a light weight, high mechanical strength, and excellent characteristics such as high damping ability. The additives each have a density less than that of the matrix and heat resistance enough to withstand a heating temperature at which they are composited with the matrix. Preferably, the additives are each formed with a coating which increases mechanical strength and provides an electromagnetic characteristic different from that of the matrix. Preferably, the composite material is produced by heating a mixture of matrix powders and additives up to a temperature where only part of the mixture including no microspheres is softened but the mixture is adequately composited, an amount of additives being equal to 10% to 70% by volume of the matrix, and by forming the composited mixture into a desired shape and solidifying same.Type: GrantFiled: November 30, 1987Date of Patent: July 3, 1990Assignee: Inabata Techno Loop CorporationInventor: Tadao Inabata
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Patent number: 4931213Abstract: A process for producing a ceramic material which is electrically conductive by reacting titanium dioxide with intercalated graphite under conditions which effect the reduction of the titanium dioxide, said product comprising an electrically conductive, corrosion-resistant, substoichiometric titanium dioxide combined chemically with an intercalant or residue thereof, for example, a metal such as copper or nickel, and the use thereof in thermal, electrical and electro-chemical applications.Type: GrantFiled: January 23, 1987Date of Patent: June 5, 1990Inventor: Richard B. Cass
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Patent number: 4909841Abstract: A process of hot pressing of materials to form articles or compacts is characterized by the steps: (A) providing a compactable particulate mixture; (B) uniaxially pressing the particles without heating to provide article or compact (22); (C) placing at least one article or compact (22) in an open pan (31) having an insertable frame (32) with edge surfaces (34) that are not significantly pressure deformable, where the inside side surfaces of the frame are parallel to the central axis B--B of the open pan, and where each article or compact is surrounded by fine particles of a separating material; (D) evacuating air from the container and sealing the articles or compacts inside the container by means of top lid (36); (E) hot pressing the compacts at a pressure from 352.5 kg/cm.sup.2 to 3,172 kg/cm.sup.Type: GrantFiled: June 30, 1989Date of Patent: March 20, 1990Assignee: Westinghouse Electric Corp.Inventors: Natraj C. Iyer, Alan T. Male, William R. Lovic
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Patent number: 4904302Abstract: Disclosed is a roller for use in a rotary compressor, which roller comprising a sintered body consisting essentially of 0.5-2.0% by weight of C, 1.0-5.0% by weight of Cu, 1.2-3.0% by weight of Mo and a balance of Fe and unavoidable impurities. In the sintered alloy, hard particles of Fe-Mo alloy are dispersed in one of pearlitic and tempering martensitic matrix, and sintered pores of the sintered body is sealed with tri-iron tetroxide. Resultant sintered body has high wear resistance and scuffing resistance capable of being used as an inverter type compressor.Type: GrantFiled: November 14, 1988Date of Patent: February 27, 1990Assignee: Nippon Piston Ring Co., Ltd.Inventor: Soichi Shimomura
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Patent number: 4894273Abstract: Bonding additives for refractory metallization compositions allow for circuit traces having good resistivities and adhesion values in excess of 6 kpsi, generally between about 10 and 20 kpsi. The inks are provided in formulations devoid of a glass component, and are suitable for co-sintering circuit traces and vias with 96% alumina substrates, and especially for 99% alumina substrates. Suitable bonding additives are the oxides of molybdenum, tungsten, niobium, manganese, yttrium, and titanium, or mixtures of such oxides.Type: GrantFiled: June 16, 1988Date of Patent: January 16, 1990Assignee: Ceramics Process Systems Corp.Inventors: Sheldon I. Lieberman, Eric A. Barringer, Brian C. Foster
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Patent number: 4861372Abstract: Disclosed is a roller for use in a rotary compressor, which roller comprising a sintered body consisting essentially of 0.5-2.0% by weight of C, 1.0-5.0% by weight of Cu, 0.5-3.5% by weight of Cr, 0.1-1.0% by weight of Co, 0.1-1.0% by weight of W and a balance Fe and unavoidable impurities. Hard particles of Cr-Co-W alloy are dispersed in one of pearlitic and tempering martensitic matrix, and sintered pores of the sintered body are sealed with tri-iron tetroxide. Resultant sintered body has high wear resistance and scuffing resistance capable of being used as an inverter type compressor.Type: GrantFiled: November 14, 1988Date of Patent: August 29, 1989Assignee: Nippon Piston Ring Co., Ltd.Inventor: Soichi Shimomura
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Patent number: 4859238Abstract: Electrical contacts are formed from a silver-iron material which contains 3 to 30% by weight of iron and one or more of the components manganese, copper, zinc, antimony, bismuth oxide, molybdenum oxide, tungsten oxide or chromium nitride in amount totalling 0.05 to 5 weight percent, the balance being silver. These materials are suitable for forming electrical contacts of a wide variety. Tantalum is an optional component which may also be utilized particularly when 0.2 percent to 2 percent zinc is present.Type: GrantFiled: June 3, 1988Date of Patent: August 22, 1989Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Roger Wolmer, Peter Braumann
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Patent number: 4834942Abstract: An aluminum-titanium alloy and a process of making it, the alloy consisting ssentially of aluminum, 4-6 wt. % titanium, 1-2 wt. % carbon, and 0.1-0.2 wt % oxygen. The alloy is an aluminum matrix supersaturated with titanium, and having throughout a fine, homogeneous dispersion of Al.sub.3 Ti particles. It is fine grained and has grain boundary dispersoids of carbides and oxides, predominantly of aluminum. An aluminum-titanium melt is rapidly solidified and then mechanically alloyed in the presence of a carbon-bearing agent. The resulting powder is degassed and hot consolidated to form articles which exhibit high strength, ductility, and creep resistance at temperatures greater than 200.degree. C.Type: GrantFiled: January 29, 1988Date of Patent: May 30, 1989Assignee: The United States of America as represented by the Secretary of the NavyInventors: William E. Frazier, Michael J. Koczak