With Another Nonmetal Patents (Class 75/233)
  • Patent number: 5695544
    Abstract: A silicon nitride based sintered product having strength at a high temperature is obtained by sintering a mixture. The mixture comprises a silicon powder or a mixture powder of silicon and silicon nitride added a sintering assistant powder, a compound powder of iron and a compound powder containing at least one of vanadium, niobium and tantalum in 5a group elements of the periodic table. The silicon nitride based sintered product contains silicon, aluminum, yttrium, oxygen, nitrogen, iron and at least one of 5a group element in the periodic table, and when weights at which the elements are present as a compound of silicon nitride, alumina, yttria, a compound powder of iron and 5a group elements in the periodic table are represented by a, b, c, d and e, the following formulae are fulfilled:1.ltoreq.100(b+c+d+e).times.(a+b+c+d+e).ltoreq.15, 1.ltoreq.(b+c)/d0.005.ltoreq.100d/(a+b+c+d+e).ltoreq.7.5, and 0.005.ltoreq.e/(b+c).ltoreq.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: December 9, 1997
    Assignee: Isuzu Ceramics Research Institute Co., Ld.
    Inventor: Toshiyuki Yamada
  • Patent number: 5610347
    Abstract: The invention relates to a material for electric contacts taking silver tin-oxide as basis, consisting of silver or mainly silver-containing alloy, tin oxide and other oxides or carbides of tungsten, molybdenum, vanadium, bismuth, titanium, and/or copper.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: March 11, 1997
    Assignee: Doduco GmbH & Co. Dr. Eugen Durrwachter
    Inventors: Volker Behrens, Thomas Honig, Andreas Kraus, Karl E. Saeger, Rainer Schmidberger, Theodor Staneff
  • Patent number: 5561829
    Abstract: A method of preparing a metal alloy product from a powder blend. The method comprising: (a) cold pressing a blend to form a compact, the metal blend comprising a metal powder phase and at least one reinforcement phase having a hardness greater than the metal phase; (b) heating the compact to form a preheated compact; and (c) hot working the heated compact. In a preferred method, the powder metal blend comprises 50 to 90 vol. % of an aluminum alloy powder and 10 to 50 vol. % of silicon carbide; the heating of the compact perforated in a nitrogen atmosphere to form a preheated compact; and the extruded hot compact is hot worked. Hot working may take the form of forging, rolling, upset forging, exuding, compacting or other processes known in the art.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: October 1, 1996
    Assignee: Aluminum Company of America
    Inventors: Ralph R. Sawtell, Warren H. Hunt, Jr., Thomas J. Rodjom, Erik J. Hilinski, John H. Milsom
  • Patent number: 5520716
    Abstract: An Al.sub.2 O.sub.3 -TiC sintered product comprising Al.sub.2 O.sub.3 as a main component and containing TiC in an amount of from 20 to 40% by weight, wherein the average particle diameter of Al.sub.2 O.sub.3 particles in the sintered product is larger by 5 to 50% than the average particle diameter of TiC particles, the average particle diameter of the sintered product as a whole is not larger than 1 .mu.m, the average particle diameter of TiC particles is not larger than 0.9 .mu.m, and the total amount of the grain boundary phases other than Al.sub.2 O.sub.3 and TiC is not larger than 1.0% by weight. The Al.sub.2 O.sub.3 -TiC sintered product can be used as a substrate 1 for a magnetic head, and has portions such as grooves 4 and stepped portions formed in the surface of the air bearing surface 2 of the slider by being irradiated with ions. The sintered product exhibits excellent surface quality after machined by being irradiated with ions and can be machined at an increased rate.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: May 28, 1996
    Assignee: Kyocera Corporation
    Inventors: Nobuoki Takagi, Hiroki Tokunaga, Shinichiro Masuyama
  • Patent number: 5501728
    Abstract: The present invention relates to a friction material for use in manufacturing various friction bearing components such as brakes, clutches, couplings, transmission systems and the like. The composition of the friction material includes a base friction material and a metal sulfide-iron powder alloy mixture which is added to the base material and further mixed prior to compression molding the desired component.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: March 26, 1996
    Assignee: Brake Pro, Inc.
    Inventors: Christopher C. Shepley, David R. Carter
  • Patent number: 5486222
    Abstract: Contact materials with the composition AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO have proven themselves, particularly for low-voltage switching devices. These materials can contain an additive of other metal oxides. In addition to the required useful lifetime and suitable excess high temperature behavior, such materials are also supposed to fulfill all the requirements under short-circuit current stress. This is accomplished, according to the invention, in that the additional metal oxide is separately added stannic oxide and/or iron containing at least one element of the sixth sub-group of the periodic system. In the sintered composite material according to the invention, the other metal oxide is particularly ferric tungstate (FeWO.sub.4). Preferably, separately added SnO.sub.2 is present in combination with FeWO.sub.4.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: January 23, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventor: Franz Hauner
  • Patent number: 5460640
    Abstract: A fully dense ceramic-metal body including 40-88 v/o of an oxide hard phase of, in v/o of the body, 4-88 v/o M-aluminum binary oxides, where the binary oxide has a C-type rare earth, garnet, .beta.-MAl.sub.11 O.sub.18, or perovskite crystal structure, and M is a lanthanide or indium, and 0-79 v/o .alpha.-alumina; about 10-50 v/o of a hard refractory carbide, nitride, or boride as a reinforcing phase; and about 2-10 v/o of a dispersed metal phase combining Ni and Al mostly segregated at triple points of the microstructure. The preferred metal phase contains a substantial amount of the Ni.sub.3 Al ordered crystal structure. In the preferred body, the reinforcing phase is silicon carbide partially incorporated into the oxide grains, and bridges the grain boundaries. The body including a segregated metal phase is produced by densifying a mixture of the hard phase components and the metal component, with the metal component being present in the starting formulation as Ni powder and Al powder.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: October 24, 1995
    Assignee: Valenite Inc.
    Inventor: Sergej-Tomislav Buljan
  • Patent number: 5457075
    Abstract: A sintered ceramic composite comprising 35 to 80 wt. % of aluminum nitride, 2 to 60 wt. % of boron nitride, 0.1 to 25 wt. % of an oxide of magnesium, 0.5 to 20 wt. % of at least one of rare earth oxides including yttrium oxide as an optional component and 25 wt. % or less of aluminum oxide as an optional component is disclosed.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: October 10, 1995
    Assignee: Hitachi Metals, Ltd.
    Inventors: Hideko Fukushima, Yasuo Sawano, Katsuhiko Kojo
  • Patent number: 5443615
    Abstract: A method of producing a molded ceramic article comprises the first step mixing powdery raw materials and a liquid additive, thereby obtaining a mixed raw material, the second step press-molding the mixed raw material obtained in the first step in a hydrostatically applied condition of pressure, thereby removing an excess of the liquid additive to obtain a preform, and the third step calcining the preform obtained in the second step to obtain a molded ceramic article. The molded ceramic article comprises, as a principal component, copper and, as essential components, Cr and Ni within composition ranges of 0.1.ltoreq.Cr<2 wt. % and 0.1.ltoreq.Ni<10 wt. % and further at least one additive component selected from the group consisting of the following composition ratios: the following composition ratios: 0<Fe<5 wt. %, 0.ltoreq.Co<5 wt. %, 0.ltoreq.Al<10 wt. % 0.ltoreq.Ti<20 wt. %, 0.ltoreq.Mo<3 wt. %, 0.ltoreq.Si<3 wt. % 0.ltoreq.V<3 wt. % 0.ltoreq.Mg<1 wt. % and 0.ltoreq.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: August 22, 1995
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Mitsuo Kuwabara, Kiyoshi Ikegami, Teruaki Yoshida, Koji Takahashi, Tamotsu Harada, Takeshi Komiyama, Fumio Hirai, Masamichi Hayashi
  • Patent number: 5439499
    Abstract: A cermet useful in the fabrication of metal cutting, rockdrilling and mineral tools, as well as wear parts. The cermet comprises (i) a hard phase of a simple boride of a transition metal, a mixture of simple borides of transition metals, or a mixed boride of transition metals; (ii) a binder phase of Fe, Ni, Co, Cr, or alloys thereof; (iii) a dispersion of particles of oxides of transition metals in which the oxygen can be replaced by nitrogen and/or carbon; and (iv) a dispersion of oxides of metals chosen from aluminum and Group IIA and IIIA metals.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: August 8, 1995
    Assignee: Sandvik AB
    Inventors: Henri Pastor, Colette Allibert, Laurent Ottavi, Manuel Albajar, Francisco Castro-Fernandez
  • Patent number: 5401292
    Abstract: A carbonyl iron powder (CIP) premix composition suitable for metal injection molding is provided herein. The composition comprises (a) CIP having a particle size in the range of about 0.2-7 microns, preferably about 0.2-5 microns, and a narrow particle size distribution; and (b) an alloying material, having a particle size in the range of about 0.02 to 5 microns, preferably about 0.03 to 3.0 microns, and a narrow particle size distribution, comparable to the CIP, and present in an amount of about 0.1-60% by weight of the composition, preferably 0.5-50%. The alloy material substantially covers the surface of the iron particles and is adhered thereto by attractive forces. Preferably the alloy material includes elemental metal powders which are smaller in particle size than the CIP.The premix composition is prepared by intensive mixing of its powder components, e.g.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: March 28, 1995
    Assignee: ISP Investments Inc.
    Inventor: Joseph E. Japka
  • Patent number: 5396148
    Abstract: Ultrafine particles of a composite particulate substance composed of two or more types of inorganic oxides, forming a particle structure in which two or more types of inorganic oxides are mutually mixed or an inorganic oxide of one type is contained in an inorganic oxide of another type, and having an average particle diameter of not more than 0.1 .mu.m, a process for the production of the ultrafine particles, use of the ultrafine particles as a thin film, particularly in an image display face plate and a cathode ray tube, and a process for using the ultrafine particles therefor.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: March 7, 1995
    Assignee: Hitachi, Ltd.
    Inventors: Yoshishige Endo, Takeshi Araya, Masahiko Ono, Takao Kawamura, Hiromitsu Kawamura
  • Patent number: 5350628
    Abstract: A magnetic material is provided which includes a discrete phase including grains made of a first substance which comprises a magnetic metal; and a continuous phase including a thin coating film made of a second substance which comprises a dielectric or insulating substance. The thin coating film is formed on the surface of the grains and has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: September 27, 1994
    Assignee: Matsushita Electric Industrial Company, Inc.
    Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Ken Hirota, Mitsuo Satomi
  • Patent number: 5294239
    Abstract: In section bars and shaped bodies made of nickel-base superalloys having a structure consisting of columnar grains, a complete recrystallization cannot be effected unless the heating-up rate is kept below a maximum heating-up rate T.sub.max, which depends on the ratio V of one or more of the metal carbide-forming elements hafnium, niobium, tantalum, titanium and zirconium to one or both of the metal carbide-forming elements tungsten and molybdenum.
    Type: Grant
    Filed: May 6, 1991
    Date of Patent: March 15, 1994
    Assignee: PM Hochtemperatur-Metall GmbH
    Inventors: Klaus Zoltzer, Klaus Lempenauer, Hellmut Fischmeister
  • Patent number: 5240513
    Abstract: An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: August 31, 1993
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: R. William McCallum, Kevin W. Dennis, Barbara K. Lograsso, Iver E. Anderson
  • Patent number: 5238507
    Abstract: A magnetic material is provided which includes a discrete phase including grains made of a first substance which comprises a magnetic metal; and a continuous phase including a thin coating film made of a second substance which comprises a dielectric or insulating substance. The thin coating film is formed on the surface of the grains and has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: August 24, 1993
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Ken Hirota, Mitsuo Satomi
  • Patent number: 5217543
    Abstract: A rare earth-iron magnet consisting of, by atomic percent, 10 to 16% Nd, 5 to 10% B, 0.1 to 1% V, 0.1 to 1% oxygen and the balance being Fe.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: June 8, 1993
    Assignee: Seiko Instruments Inc.
    Inventor: Yoshio Inokoshi
  • Patent number: 5209772
    Abstract: A dispersion-strengthened (DS) alloy, more particularly oxide-dispersion-strengthened (ODS) iron-based alloys which manifest resistant to oxidation at temperatures as high as 1300.degree. C. (approx. 2400.degree. F.) whereby the alloys are useful in the production of advanced aircraft gas turbine engine components and in demanding industrial applications.
    Type: Grant
    Filed: October 5, 1988
    Date of Patent: May 11, 1993
    Assignee: Inco Alloys International, Inc.
    Inventors: Raymond C. Benn, Gaylord D. Smith, John J. Fischer
  • Patent number: 5194099
    Abstract: A sinter magnet based on Fe-Nd-B with improved coercive field strength and reduced temperature dependency thereof consists of 25 to 50 wt. % Nd, 0.5 to 2 wt. % B, 0 to 5 wt. % Al, 0.5 to 3 wt. % O, remainder Fe and usual impurities and has an oxygen content which is adjusted by the addition of oxygen or of oxygen-containing compounds, especially of an Al and/or Nd oxide, before the dense sintering. It is obtainable by the melting together of the pure components with formation of a pre-alloy, pulverisation of the pre-alloy, alignment of the powder in a magnetic field and pressing to a green formed body, sintering at 1040.degree. to 1100.degree. C. and subsequent annealing at 600.degree. to 700.degree. C., whereby one adds the oxygen as Al or Nd oxide or via the grinding and/or sintering atmosphere.
    Type: Grant
    Filed: May 23, 1990
    Date of Patent: March 16, 1993
    Assignees: 501 Max-Planck-Gesellschaft zur Forderung der Wissenschaften E.V., 502 Robert Bosch GmbH
    Inventors: Friedrich Esper, Waldemar Draxler, Gunter Petzow, Andreas Buchel, Klaus-Dieter Durst, Ernst-Theo Henig, Gerhard Schneider, Helmut Kronmuller
  • Patent number: 5189337
    Abstract: Ultrafine particles of a composite particulate substance composed of two or more types of inorganic oxides, forming a particle structure in which two or more types of inorganic oxides are mutually mixed or an inorganic oxide of one type is contained in an organic oxide of another type, and having an average particle diameter of not more than 0.1 .mu.m, a process for the production of the ultrafine particles, use of the ultrafine particles as a thin film, particularly in an image display face plate and a cathode ray tube, and a process for using the ultrafine particles therefor.
    Type: Grant
    Filed: September 8, 1989
    Date of Patent: February 23, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Yoshishige Endo, Takeshi Araya, Masahiko Ono, Takao Kawamura, Hiromitsu Kawamura
  • Patent number: 5181953
    Abstract: A coated cemented carbide alloy, excellent in toughness as well as wear resistance and which is used for cutting tools and wear resistance tools is provided herein. This coated cemented carbide alloy is composed of a cemented carbide substrate consisting of a hard phase of at least one member selected from carbides, nitrides and carbonitrides of Group IVb, Vb and VIb metals of the Periodic Table and a binder phase consisting of at least one member selected from the iron group metals, and a monolayer or multilayer, provided on the substrate consisting of at least one member selected from carbides, nitrides, oxides and borides of Group IVb, Vb and VIb metals of Periodic Table, solid solutions thereof and aluminum oxide, and wherein a binder phase-enriched layer is provided in a space 0.01 mm and 2 mm below the surface of the substrate with A-type and/or B-type pores inside the binder phase-enriched layer.
    Type: Grant
    Filed: December 27, 1990
    Date of Patent: January 26, 1993
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Minoru Nakano, Toshio Nomura
  • Patent number: 5173107
    Abstract: The invention relates to a composite hard metal body of hard material, a binder and embedded reinforcing material, as well as to a process for the production of the composite hard metal body by methods of powder metallurgy.In order to create a composite hard metal body with improved toughness under load, improved hardness and a lower fracture susceptibility, the invention proposes to build in monocrystalline, preferably needle-shaped and/or platelet-shaped reinforcing materials, coated with an inert layer with respect to the binder metal phase and consisting of borides and/or carbides, and/or nitrides and/or carbonitrides of the elements of Groups IVa or Va or mixtures thereof and/or coated monocrystalline reinforcing material of SiC, Si.sub.3 N.sub.4, Si.sub.2 N.sub.2 O, Al.sub.2 O.sub.3, ZrO.sub.2, AlN and/or BN.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: December 22, 1992
    Assignee: Krupp Widia GmbH
    Inventors: Klaus Dreyer, Hans Kolaska
  • Patent number: 5162064
    Abstract: A permanent magnet of the neodymium-iron-boron type having improved corrosion resistance imparted by a combination of oxygen, carbon and nitrogen. Oxygen is provided in an amount equal to or greater than 0.6 weight percent in combination with carbon of 0.05-0.15 weight percent and nitrogen 0.15 weight percent maximum. Preferably, oxygen is within the range of 0.6-1.2% with carbon of 0.05-0.1% and nitrogen 0.02-0.15 weight percent or more preferably 0.04-0.08 weight percent. The magnet may be heated in an argon atmosphere and thereafter quenched in an atmosphere of either argon or nitrogen to further improve the corrosion resistance of the magnet.
    Type: Grant
    Filed: April 10, 1990
    Date of Patent: November 10, 1992
    Assignee: Crucible Materials Corporation
    Inventors: Andrew S. Kim, Floyd E. Camp, Edward J. Dulis
  • Patent number: 5160366
    Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.
    Type: Grant
    Filed: March 14, 1991
    Date of Patent: November 3, 1992
    Assignees: Sumico Management Planning Company, Ltd., Akira Shibata
    Inventor: Akira Shibata
  • Patent number: 5149361
    Abstract: A cermet alloy having a structure including a hard phase and a bonding phase which is composed of at least one ferrous metal, said bonding phase containing fine hard grains of a mean grain size not greater than 2000 .ANG. dispersed therein. The structure has a composition consisting of 10 to 70 wt % of TiCN, 5 to 30 wt % of WC, 5 to 30 wt % of NbC, 1 to 10 wt % of Mo.sub.2 C, 0.5 to 5 wt% of VC, 0.05 to 3 wt % of ZrC, 5 to 25 wt % of (Ni, Co), and not smaller than 2.5 wt% of total nitrogen and incidental impurities.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: September 22, 1992
    Assignees: Hitachi, Ltd., Hitachi Taga Engineering Co., Ltd.
    Inventors: Yusuke Iyori, Nobuhiko Shima
  • Patent number: 5143540
    Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceamic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and pressing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressures of 60-250 kpsi employed at a rate of 5-250 kpsi/second.
    Type: Grant
    Filed: September 18, 1990
    Date of Patent: September 1, 1992
    Assignee: The Dow Chemical Company
    Inventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Robert R. McDonald, Alexander Pecnenik
  • Patent number: 5125990
    Abstract: A magnetically anisotropic hot-worked magnet made of an R-T-B alloy containing a transition metal T as a main component, a rare earth element R including yttrium, and boron B; the magnet having the fine crystal grains having an average grain size of 0.02 -1.0 .mu.m, and having a carbon content of 0.8 weight % or less and an oxygen content of 0.5 weight % or less. The angular variance of orientation of the crystal grains is within 30.degree. from the C axes of the crystal grains when measured by X-ray. This magnet can be produced by mixing the magnet flakes with an additive composed of at least one organic compound having a boiling point of 50.degree. C. or higher.
    Type: Grant
    Filed: June 1, 1990
    Date of Patent: June 30, 1992
    Assignee: Hitachi Metals
    Inventors: Katsunori Iwasaki, Shigeho Tanigawa, Masaaki Tokunaga
  • Patent number: 5110349
    Abstract: A cutting insert of a sintered carbonitride alloy and with a complicated geometry, the insert having improved efficiency. This is obtained by giving the powder non-uniform compaction during pressing of the powder into a press-body so that the ultimate working edges will have a higher relative density than the surrounding, more "supporting" material in the press-body. By these means are often obtained surface defects in the form of cracks because of dissolved strains during the sintering.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: May 5, 1992
    Assignee: Sandvik AB
    Inventors: Kenneth Westergren, Gerold Weinl, Rolf Oskarsson
  • Patent number: 5110688
    Abstract: The present invention relates to a method of fabricating various types of bearing materials and the bearing materials produced thereby. The processes of the invention may be used to produce porous self-lubricating bearings, laminated composite bearings (babbitt bearings) and bearings for high temperature application. The processes of the invention involve the use of micro-pyretic synthesis to achieve bearing materials with improved bearing properties, including higher bearing capacity and toughness.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: May 5, 1992
    Assignee: University of Cincinnati
    Inventors: Jainagesh A. Sehkar, A. K. Bhattacharya, Hung P. Li
  • Patent number: 5089354
    Abstract: A copper alloy composite material which comprises a copper alloy matrix and at least one additive selected from solid materials having self-lubricity and wear-resistant materials and uniformly dispersed in the alloy matrix is described. The composite material has improved wear resistance and anti-seizing properties.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: February 18, 1992
    Assignee: Chuetsu Metal Works, Co., Ltd.
    Inventors: Kunio Nakashima, Ryouichi Ishigane, Takayuki Tanaka, Ken-ichi Ichida
  • Patent number: 5077246
    Abstract: A method for the preparation of ceramic composites containing at least aluminum oxide and aluminum boride, and the composite materials that result from the method. Intimate mixtures of finely-divided powdered aluminum metal and anhydrous boric oxide, with ratios (by weight) of about 0.5 to twenty parts of aluminum metal to one part of boric oxide, are subjected to a temperature to cause a complete reaction between the starting materials. If the ratio is above about 1.25 parts of aluminum to one part of boric oxide, the resultant product will include aluminum in addition to the aluminum oxide and aluminum boride. The ratio is selected to provide the desired hardness and toughness. Ratios between about 1 and 1.2 provide a composite having the highest hardness, with greater amounts of aluminum metal providing increased toughness. Several compositions are described, with hot pressing typically being used to provide the desired heating cycle.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: December 31, 1991
    Assignee: Apollo Concepts, Inc.
    Inventors: Samuel C. Weaver, Sally G. Padron
  • Patent number: 5053074
    Abstract: A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: October 1, 1991
    Assignee: GTE Laboratories Incorporated
    Inventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
  • Patent number: 5045278
    Abstract: An aluminum based metal matrix composite is produced from a charge containing a rapidly solidified aluminum alloy, a carbidiferous agent and particles of a reinforcing material present in an amount ranging from about 0.1 to 50% by volume of the charge. The charge is ball milled energetically to uniformly mix the carbidiferous agent within the aluminum matrix, and to enfold metal matrix material around each of the particles while maintaining the charge in a pulverulent state. Upon completion of the ball milling step, the charge is hot consolidated at suitable temperatures to decompose the carbidiferous agent and result in the formation of carbide and oxide particles, and to provide a powder compact having a formable, substantially void-free mass. The compact is especially suited for use in aerospace, automotive, electronic, wear resistance critical components, and the like, which often encounter service temperatures approaching 500.degree. C.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: September 3, 1991
    Assignee: Allied-Signal Inc.
    Inventors: Sontosh K. Das, Michael S. Zedalis, Paul S. Gilman
  • Patent number: 5041261
    Abstract: A method for manufacturing a dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal binder phase. The hard phase is (a) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, borides, and mixtures thereof of the elements selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and B, or (b) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, and carboxynitrides, and mixtures thereof of a cubic solid solution of Zr--Ti, Hf--Ti, Hf--Zr, V--Ti, Nb--Ti, Ta--Ti, Mo--Ti, W--Ti, W--Hf, W--Nb, or W--Ta. The binder phase is a combination of Ni and Al having a Ni:Al weight ratio of from about 85:15 to about 88:12, and 0-5% by weight of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Co, B, and/or C. The method involves presintering the hard phase/binder phase mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then HIPing at about 1575.degree.-1675.degree. C.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: August 20, 1991
    Assignee: GTE Laboratories Incorporated
    Inventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
  • Patent number: 5011798
    Abstract: A chromium additive of the formula: Cr.sub.x C.sub.y O.sub.z where 0.04.ltoreq.y.ltoreq.0.35, and 0.03.ltoreq.z.ltoreq.0.30 for x=1, said additive having an X ray diffraction peak at d=3.32 .ANG. (2.theta.=26.8.degree.).
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: April 30, 1991
    Assignee: Tosoh Corporation
    Inventors: Minoru Sasabe, Masao Imamura, Yasunobu Yoshida, Shinya Andoh, Hiroshi Miyake
  • Patent number: 5006163
    Abstract: A novel, nickel-base, high temperature alloy body preferably containing about 20% chromium, 6 to 7% aluminum to provide phase, 1.5 to 2.5% molybdenum, 3 to 4.5% tungsten, additional strengthening elements and oxidic yttrium in finely dispersed form. The alloy body has an elongated crystal structure and is characterized by high strength along with excellent hot corrosion and oxidation resistance.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: April 9, 1991
    Assignee: Inco Alloys International, Inc.
    Inventors: Raymond C. Benn, Jeffrey M. Davidson, Kenneth R. Andryszak
  • Patent number: 5004498
    Abstract: A dispersion strengthened copper alloy containing a copper matrix, and dispersion particles dispersed in the copper matrix within a range of 0.5 to 6 vol %. In this alloy, an average diameter of a matrix region where the dispersion particles are not present is 0.3 .mu.m or less, and the total amount of solid solution elements contained in the copper matrix is determined such that, when this amount of the solid solution elements is added to pure copper, the electric conductivity of the matrix is lowered by 5% IACS or less.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 2, 1991
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Keizo Shimamura, Kagetaka Amano, Tatsuyoshi Aisaka, Satoshi Hanai, Kohsoku Nagata
  • Patent number: 4999336
    Abstract: There is provided a substantially fully dense powdered metal composite comprising a highly conductive metal or metal alloy matrix having dispersed therein discrete microparticles of a refractory metal oxide and discrete macroparticles of a mechanical or physical property-conferring additive material. The respective components undergo minimal alloying or interdispersion because sintering is not utilized in forming the composite. These composites are characterized by high thermal or electrical conductivity and a desired property (controlled thermal expansion, high strength, wear and arc erosion resistance, or magnetic) attributable to the composite forming material, like refractory metal, alloy, or compound. The composites are useful in forming lead frames for integrated circuit chips, electric lamp lead wires, electrical contact members, and discrete component leads.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: March 12, 1991
    Assignee: SCM Metal Products, Inc.
    Inventors: Anil Nadkarni, Prasan K. Samal, James E. Synk
  • Patent number: 4973355
    Abstract: The invention relates to sintered hard metals having high cutting properties, particularly plastic deformation resistance at high temperatures, crater resistance and the like, suitable for use as cutting tools, wear resistant tools and materials for dies, and the method for producing the same. The invention has for an object to obtain both sintered hard metals having the aforesaid high properties by sintering metallic components comprising IVa group metals, VIa group metals or metals of both groups substituted by Va group metals up to 60 mol % respectively, a B-1 type solid solution hard phase consisting of non-metallic components of C, N and O, and a metallic bonding phase, in a CO gas atmosphere, and to sintered hard metals in which an uniform hardness is imparted to the surface and interior thereof by the method of sintering the said sintered hard metal in a CO gas atmosphere.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: November 27, 1990
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kunihiro Takahashi, Toshio Nomura, Takaharu Yamamoto
  • Patent number: 4973356
    Abstract: The present invention relates to a method of preparing an alloy for use as a cutting tool material comprising hard principles and binder phase by which a uniform distribution of the hard principles in the binder phase is obtained, and the resulting product.
    Type: Grant
    Filed: October 23, 1989
    Date of Patent: November 27, 1990
    Assignee: Sandvik AB
    Inventors: Peder von Holst, Hakan Morberg, Rolf Oskarsson
  • Patent number: 4961778
    Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceramic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and presssing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressure of 60-250 kpsi employed at a rate of 5-250 kpsi/second.
    Type: Grant
    Filed: January 13, 1988
    Date of Patent: October 9, 1990
    Assignee: The Dow Chemical Company
    Inventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Alexander Pechenik, Robert R. McDonald
  • Patent number: 4954170
    Abstract: High density compacts are made by providing a compactable particulate combination of Class 1 metals selected from at least one of Ag, Cu and Al, with material selected from at least one of CdO, SnO, SnO.sub.2, C, Co, Ni, Fe, Cr, Cr.sub.3 C.sub.2, Cr.sub.7 C.sub.3, W, WC, W.sub.2 C, WB, Mo, Mo.sub.2 C, MoB, Mo.sub.2 B, TiC, TiN, TiB.sub.2, Si, SiC, Si.sub.3 N.sub.4, usually by mixing powders of each, step (1); uniaxially pressing the powders to a density of from 60% to 95%, to provide a compact, step (2); hot densifying the compact at a pressure between 352 kg/cm.sup.2 (5,000 psi) and 3,172 kg/cm.sup.2 (45,000 psi) and at a temperature from 50.degree. C. to 100.degree. C. below the melting point or decomposition point of the lower melting component of the compact, to provide densification of the compact to over 97% of theoretical density; step (3); and cooling the compact, step (4).
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: September 4, 1990
    Assignee: Westinghouse Electric Corp.
    Inventors: Maurice G. Fey, Natraj C. Iyer, Alan T. Male, William R. Lovic
  • Patent number: 4939038
    Abstract: A light metallic composite material containing therein fine granular additives dispersed in a matrix of a light metallic material, which composite material has a light weight, high mechanical strength, and excellent characteristics such as high damping ability. The additives each have a density less than that of the matrix and heat resistance enough to withstand a heating temperature at which they are composited with the matrix. Preferably, the additives are each formed with a coating which increases mechanical strength and provides an electromagnetic characteristic different from that of the matrix. Preferably, the composite material is produced by heating a mixture of matrix powders and additives up to a temperature where only part of the mixture including no microspheres is softened but the mixture is adequately composited, an amount of additives being equal to 10% to 70% by volume of the matrix, and by forming the composited mixture into a desired shape and solidifying same.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: July 3, 1990
    Assignee: Inabata Techno Loop Corporation
    Inventor: Tadao Inabata
  • Patent number: 4931213
    Abstract: A process for producing a ceramic material which is electrically conductive by reacting titanium dioxide with intercalated graphite under conditions which effect the reduction of the titanium dioxide, said product comprising an electrically conductive, corrosion-resistant, substoichiometric titanium dioxide combined chemically with an intercalant or residue thereof, for example, a metal such as copper or nickel, and the use thereof in thermal, electrical and electro-chemical applications.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: June 5, 1990
    Inventor: Richard B. Cass
  • Patent number: 4909841
    Abstract: A process of hot pressing of materials to form articles or compacts is characterized by the steps: (A) providing a compactable particulate mixture; (B) uniaxially pressing the particles without heating to provide article or compact (22); (C) placing at least one article or compact (22) in an open pan (31) having an insertable frame (32) with edge surfaces (34) that are not significantly pressure deformable, where the inside side surfaces of the frame are parallel to the central axis B--B of the open pan, and where each article or compact is surrounded by fine particles of a separating material; (D) evacuating air from the container and sealing the articles or compacts inside the container by means of top lid (36); (E) hot pressing the compacts at a pressure from 352.5 kg/cm.sup.2 to 3,172 kg/cm.sup.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: March 20, 1990
    Assignee: Westinghouse Electric Corp.
    Inventors: Natraj C. Iyer, Alan T. Male, William R. Lovic
  • Patent number: 4904302
    Abstract: Disclosed is a roller for use in a rotary compressor, which roller comprising a sintered body consisting essentially of 0.5-2.0% by weight of C, 1.0-5.0% by weight of Cu, 1.2-3.0% by weight of Mo and a balance of Fe and unavoidable impurities. In the sintered alloy, hard particles of Fe-Mo alloy are dispersed in one of pearlitic and tempering martensitic matrix, and sintered pores of the sintered body is sealed with tri-iron tetroxide. Resultant sintered body has high wear resistance and scuffing resistance capable of being used as an inverter type compressor.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: February 27, 1990
    Assignee: Nippon Piston Ring Co., Ltd.
    Inventor: Soichi Shimomura
  • Patent number: 4894273
    Abstract: Bonding additives for refractory metallization compositions allow for circuit traces having good resistivities and adhesion values in excess of 6 kpsi, generally between about 10 and 20 kpsi. The inks are provided in formulations devoid of a glass component, and are suitable for co-sintering circuit traces and vias with 96% alumina substrates, and especially for 99% alumina substrates. Suitable bonding additives are the oxides of molybdenum, tungsten, niobium, manganese, yttrium, and titanium, or mixtures of such oxides.
    Type: Grant
    Filed: June 16, 1988
    Date of Patent: January 16, 1990
    Assignee: Ceramics Process Systems Corp.
    Inventors: Sheldon I. Lieberman, Eric A. Barringer, Brian C. Foster
  • Patent number: 4861372
    Abstract: Disclosed is a roller for use in a rotary compressor, which roller comprising a sintered body consisting essentially of 0.5-2.0% by weight of C, 1.0-5.0% by weight of Cu, 0.5-3.5% by weight of Cr, 0.1-1.0% by weight of Co, 0.1-1.0% by weight of W and a balance Fe and unavoidable impurities. Hard particles of Cr-Co-W alloy are dispersed in one of pearlitic and tempering martensitic matrix, and sintered pores of the sintered body are sealed with tri-iron tetroxide. Resultant sintered body has high wear resistance and scuffing resistance capable of being used as an inverter type compressor.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: August 29, 1989
    Assignee: Nippon Piston Ring Co., Ltd.
    Inventor: Soichi Shimomura
  • Patent number: 4859238
    Abstract: Electrical contacts are formed from a silver-iron material which contains 3 to 30% by weight of iron and one or more of the components manganese, copper, zinc, antimony, bismuth oxide, molybdenum oxide, tungsten oxide or chromium nitride in amount totalling 0.05 to 5 weight percent, the balance being silver. These materials are suitable for forming electrical contacts of a wide variety. Tantalum is an optional component which may also be utilized particularly when 0.2 percent to 2 percent zinc is present.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: August 22, 1989
    Assignee: Degussa Aktiengesellschaft
    Inventors: Wolfgang Weise, Roger Wolmer, Peter Braumann
  • Patent number: 4834942
    Abstract: An aluminum-titanium alloy and a process of making it, the alloy consisting ssentially of aluminum, 4-6 wt. % titanium, 1-2 wt. % carbon, and 0.1-0.2 wt % oxygen. The alloy is an aluminum matrix supersaturated with titanium, and having throughout a fine, homogeneous dispersion of Al.sub.3 Ti particles. It is fine grained and has grain boundary dispersoids of carbides and oxides, predominantly of aluminum. An aluminum-titanium melt is rapidly solidified and then mechanically alloyed in the presence of a carbon-bearing agent. The resulting powder is degassed and hot consolidated to form articles which exhibit high strength, ductility, and creep resistance at temperatures greater than 200.degree. C.
    Type: Grant
    Filed: January 29, 1988
    Date of Patent: May 30, 1989
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: William E. Frazier, Michael J. Koczak