With Prior Production Of Matte Or Sulfide Patents (Class 75/645)
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Patent number: 8382879Abstract: A copper smelting method includes: supplying an oxygen-enriched gas, a solvent, and a copper concentrate into a furnace, while not supplying a coke material; and supplying pig iron to slag that is generated in the furnace.Type: GrantFiled: April 29, 2009Date of Patent: February 26, 2013Assignee: Pan Pacific Copper Co., Ltd.Inventors: Tatsuya Motomura, Yoshiaki Suzuki, Masaharu Takahashi, Mitsumasa Hoshi
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Patent number: 8101008Abstract: An anode refinement method for high-sulfur content coarse copper: while high-sulfur coarse copper liquid from a flash converting furnace flows to the anode furnace through a chute, inert gas is continuously added, to stir the copper liquid and improve discharging of the SO2 produced from reaction of the sulfur with oxygen in the liquid and the oxygen absorbed from the atmosphere, so as to remove more than 90% sulfur in the coarse copper liquid. After the coarse copper liquid is fully led to the anode furnace, operations of low-oxidization and low-reduction, non-oxidization and low-reduction or cancel of reduction-oxidization are conducted according to the sulfur content in the copper liquid. The method can resolve the shortages in the fire-refining process, save working time, notably improve production efficiency and capacity, save energy, and settle the pollution problem of black smoke in the atmosphere.Type: GrantFiled: December 20, 2008Date of Patent: January 24, 2012Assignee: Xiangguang Copper Co., Ltd.Inventor: Songlin Zhou
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Publication number: 20100071510Abstract: Process for extracting copper from copper-bearing arsenic sulfide and/or antimony sulfide ores, ore concentrates or minerals, comprising the following steps: converting the ores, ore concentrates or minerals by reaction with sulfur at 300 to 600° C. for at least 5 min; grinding the reaction product; physically separating the arsenic and/or antimony sulfides obtained at least partially from copper-containing sulfides; treating the separated copper-containing sulfides by pyrometallurgical or hydrometallurgical processes to obtain copper.Type: ApplicationFiled: December 18, 2007Publication date: March 25, 2010Inventor: Alexander Beckmann
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Patent number: 6843827Abstract: The method for smelting copper sulfide concentrate essentially consisting of the steps of: adding SiO2 source material and CaO source material for flux to the copper sulfide concentrate, and subjecting the copper sulfide concentrate to oxidation melting to produce slag and at least one selected from the group of white metal and blister copper, so that at least part of Fe in the copper sulfide concentrate is removed to the slag while at least part of S is removed in the form of SO2, and that copper is concentrated in the form of at least one selected from the group of white metal and blister copper, and wherein the composition of the slag is controlled such that the weight ratio CaO/(SiO2+CaO) is in the ramge of 0.6 to 0.85, while the weight ratio Fe/(FeOx+SiO2+CaO) is in the range of 0.5 to 0.6.Type: GrantFiled: August 22, 2001Date of Patent: January 18, 2005Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Yasuo Ojima, Yasuhiro Kondo, Kazunori Kawanaka
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Patent number: 6576040Abstract: All of the air is compressed in a single compressor, which feeds a smelter for smelting ore, a converter for converting matte coming from the smelter and an air separation unit which delivers two oxygen streams for enriching the air. A buffer tank is used to deliver a variable flow of enriched air to the converter.Type: GrantFiled: September 18, 2001Date of Patent: June 10, 2003Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Didier Magnet, Norbert Rieth
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Patent number: 6416565Abstract: A method of oxygen-smelting copper sulfide concentrate to obtain white metal, nearly white metal matte or blister copper by removing most of the Fe in the copper sulfide concentrate into the slag as well as removing part or most of the S therein as SO2 wherein oxygen-smelting is carried out to produce; slag in which a weight ratio of CaO to (SiO2+CaO) is 0.3 to 0.6 and a weight ratio of Fe to (FeOx+SiO2+CaO) is 0.2 to 0.5, and white metal, nearly white metal matte or blister copper, by adding SiO2 material and CaO material to the copper sulfide concentrate as flux.Type: GrantFiled: October 5, 2000Date of Patent: July 9, 2002Assignees: Sumitomo Metal Mining Co., Ltd., Mitsubishi Materials CorporationInventors: Akira Yazawa, Yoichi Takeda, Nozomu Hasegawa, Yoshiaki Mori
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Patent number: 6210463Abstract: Copper matte is processed to anode copper without oxidizing blister copper in an anode furnace. Copper matte, in either molten or solid form, is fed to a continuous copper converting furnace in which it is converted to blister copper and slag. The blister copper and slag collect in the settler region of the furnace and separate into two phases, a blister copper phase and a slag phase (the latter floating upon the former). The converting furnace is equipped with means for stirring or agitating the interface of the blister copper and slag phases such that the sulfur content of the blister copper phase and the copper content of the slag phase are reduced.Type: GrantFiled: February 1, 1999Date of Patent: April 3, 2001Assignee: Kennecott Utah Copper CorporationInventors: David B. George, Philip J. Gabb, John F. Castle, Torstein Utigard
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Patent number: 6042632Abstract: Solidified copper matte is used as a coolant to moderate or reduce the temperature of a bath of molten blister copper resident within a continuous, top-blown converter. In one embodiment, the addition of solidified copper matte to a bath of molten blister copper resident within a continuous, top-blown converter increases the throughput of the converter.Type: GrantFiled: September 24, 1997Date of Patent: March 28, 2000Assignee: Kennecott Holdings CompanyInventor: David B. George
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Patent number: 5888270Abstract: A process for converting a copper sulphide matte and/or a copper sulphide concentrate to blister copper is described which comprises the steps of adding the matte and/or concentrate together with a suitable flux to an agitated molten bath containing molten slag phase and a molten metal phase; injecting by means of a submerged lance an oxidizing gas capable of reacting with the matte or concentrate to form a low sulphur blister copper phase, slag and sulphur dioxide; controlling the injection of the oxidizing gas such that a substantial portion of the gas contracts the blister copper phase; and separating blister copper from the bath. It is possible to obtain an amount of sulphur in the blister copper which is within a factor of two of the equilibrium value for a given percentage of copper in the slag.Type: GrantFiled: December 13, 1996Date of Patent: March 30, 1999Assignees: Mount Isa Mines Ltd., Commonwealth Scientific and Industrial Research OrganisationInventors: James Scott Edwards, Shafi Jahanshahi
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Patent number: 5849061Abstract: A process for refining high-impurity blister copper to anode quality copper is disclosed. In an oxidation step of a blister copper refining stage, soda ash fluxing removes antimony and arsenic while also removing sulfur and iron. In a deoxidation step of the blister copper refining stage, sulfur hexafluoride is injected at a controlled oxygen concentration to remove bismuth while reducing the oxygen content. Slag is continuously or periodically skimmed from the surface of the molten blister copper to prevent re-entry of impurities. The process may be carried out in batch operation or, in a preferred embodiment, in continuous flow-through operation.Type: GrantFiled: September 20, 1996Date of Patent: December 15, 1998Assignee: The Trustees of Columbia University in the City of New YorkInventors: Nickolas J. Themelis, Baozhong Zhao
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Patent number: 5449395Abstract: Fire-refined blister copper is produced from copper concentrate by a process comprising:A. melting and oxidizing the copper concentrate in a smelting furnace to produce molten matte and slag, and to separate one from the other;B. removing the molten matte from the smelting furnace;C. solidifying the molten matte;D. injecting the solidified matte into a converting furnace in which the matte is converted to blister copper and slag; andE. transferring the blister copper from the converting furnace to an anode furnace to produce fire-refined blister copper.After the fire-refined blister copper is produced in the anode furnace, it is typically transferred to an anode casting wheel on which it is converted to copper anodes suitable for subsequent electrolytic refining to cathode copper.Type: GrantFiled: July 18, 1994Date of Patent: September 12, 1995Assignee: Kennecott CorporationInventor: David B. George
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Patent number: 5374298Abstract: There is disclosed a copper smelting process. At first, blister copper is produced in a blister copper-producing facility. Then, the blister copper is caused to flow through blister copper launders into one of anode furnaces, and refined into copper of higher quality in the anode furnace. In the refining operation at the anode furnace, the receiving step and the oxidizing step are carried out at least partly in an overlapping fashion.Type: GrantFiled: March 31, 1993Date of Patent: December 20, 1994Assignee: Mitsubishi Materials CorporationInventors: Moto Goto, Nobuo Kikumoto, Osamu Iida
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Patent number: 5374299Abstract: A process of pyrometallurgically treating a feed material such as a sulphide ore or concentrate is provided. The process includes the steps of:(a) producing a liquid body of feed material;(b) creating a first reaction zone and a second reaction zone which is in contact with the first reaction zone and is in the liquid body;(c) introducing feed material in particulate form and an oxidising gas into the first reaction zone;(d) allowing in-flight oxidation of feed material to take place in the first reaction zone;(e) allowing at least some of the reaction products of the in-flight oxidation to pass into a second reaction zone; and(f) allowing sulphidation or reduction of the reaction products to take place in the second reaction zone.Type: GrantFiled: November 8, 1993Date of Patent: December 20, 1994Assignee: Johannesburg Consolidated Investment Company LimitedInventors: Johannes J. Bodenstein, Krause L. Ehlers, Kevin P. D. Perry
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Patent number: 5320662Abstract: There is disclosed a process for continuous copper smelting. At first, a smelting furnace, a separating furnace, a converting furnace, melt launders for connecting the smelting furnace, the separating furnace and the converting furnace in series, a plurality of anode furnaces and blister copper launders for connecting the converting furnace and the anode furnaces are provided. Then, copper concentrate is introduced in the smelting furnace, and melted and oxidized into a mixture of matte and slag. The mixture is received in the separating furnace and the matte is separated from the slag. Subsequently, the matte separated from the slag is oxidized to produce blister copper. Subsequently, the blister copper is caused to flow through the blister copper launders into one of the anode furnaces, and refined into copper of higher quality in the anode furnace. In the refining operation at the anode furnace, the receiving step and the oxidizing step are carried out at least partly in an overlapping fashion.Type: GrantFiled: May 4, 1993Date of Patent: June 14, 1994Assignee: Mitsubishi Materials CorporationInventors: Moto Goto, Nobuo Kikumoto, Osamu Iida
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Patent number: 5217527Abstract: There is disclosed a process for continuous copper smelting. At first, a smelting furnace, a separating furnace, a converting furnace, melt launders for connecting the smelting furnace, the separating furnace and the converting furnace in series, a plurality of anode furnaces and blister copper launders for connecting the converting furnace and the anode furnaces are provided. Then, copper concentrate is introduced in the smelting furnace, and melted and oxidized into a mixture of matte and slag. The mixture is received in the separating furnace and the matte is separated from the slag. Subsequently, the matte separated from the slag is oxidized to produce blister copper. Subsequently, the blister copper is caused to flow through the blister copper launders into one of the anode furnaces, and refined into copper of higher quality in the anode furnace. In the refining operation at the anode furnace, the receiving step and the oxidizing step are carried out at least partly in an overlapping fashion.Type: GrantFiled: November 20, 1991Date of Patent: June 8, 1993Assignee: Mitsubishi Materials CorporationInventors: Moto Goto, Nobuo Kikumoto, Osamu Iida
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Patent number: 5194213Abstract: A system for continuous smelting of sulfidic copper concentrate in which an oxygen flash furnace is operatively connected with a continuous converter and the continuous converter is operatively connected with a finishing furnace.Type: GrantFiled: April 28, 1992Date of Patent: March 16, 1993Assignee: Inco LimitedInventors: Carlos M. Diaz, Malcolm C. E. Bell
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Patent number: 5171357Abstract: In the particular embodiments described in the specification, a vacuum furnace includes a hearth having a melting region and a refining region and a particulate metal supply tube for conveying particulate metal to one side of the melting region. Three water-cooled shield members surround the other sides of the melting region so that metal ejected from the particulate metal deposited in the melting region by explosive vaporization of inclusions in the metal is intercepted by the shield members.Type: GrantFiled: December 16, 1991Date of Patent: December 15, 1992Assignee: Axel Johnson Metals, Inc.Inventors: Carlos E. Aguirre, Howard R. Harker
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Patent number: 5007959Abstract: A process for the production of blister copper from high-grade copper matte or similar copper sulphide comprises the steps of solidifying and cooling molten copper matte produced in a primary smelting furnace followed by crushing of the solidified matte if necessary to produce a coarse solid matte less than about fifteen centimeters in size, heating a bath smelting reactor to a temperature at which converting reactions take place and providing a bath of molten copper, continuously feeding measured quantities of coarse solid matte and flux into the bath smelting reactor, continously introducing sufficient quantities of oxygen or oxygen enriched air through submerged fluid protected tuyeres such that the iron and sulphur present in the copper matte are oxidized, and periodically withdrawing molten blister copper, liquid slag and continously withdrawing off-gas from the bath smelting reactor.Type: GrantFiled: February 23, 1989Date of Patent: April 16, 1991Assignee: Noranda Inc.Inventors: Marc Reist, Hans Persson, Daniel Poggi
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Patent number: RE36598Abstract: Fire-refined blister copper is produced from copper concentrate by a process comprising:A. melting and oxidizing the copper concentrate in a smelting furnace to produce molten matte and slag, and to separate one from the other;B. removing the molten matte from the smelting furnace;C. solidifying the molten matte;D. injecting the solidified matte into a converting furnace in which the matte is converted to blister copper and slag; andE. transfering the blister copper from the converting furnace to an anode furnace to produce fire-refined blister copper.After the fire-refined blister copper is produced in the anode furnace, it is typically transferred to an anode casting wheel on which it is converted to copper anodes suitable for subsequent electrolytic refining to cathode copper.Type: GrantFiled: September 11, 1997Date of Patent: March 7, 2000Assignee: Kennecott Holdings CorporationInventor: David B. George