Abstract: A method selectively recovers a useful substance from waste including a chlorine-containing synthetic resin and metal copper in a mixed state. Metal copper is recovered from coated copper-wire waste. The method includes the steps of heat-treating the waste in form of coated copper wires, each having a coating material made of a chlorine-containing synthetic resin, in oil or under a non-oxygen condition. Here, the coating material is carbonized and a chlorine content of the coating material is reduced. Then the coating material and the copper wire are separated from each other the copper wire is recovered. The chlorine-containing synthetic resin can be treated without generating dioxin.
Type:
Grant
Filed:
November 21, 2012
Date of Patent:
June 10, 2014
Assignees:
Institute of National Colleges of Technology, Japan, Polytech Kagawa, Co., Ltd.
Abstract: The invention discloses an additive for bioleaching that makes it possible to increase the recovery of copper from sulfide ores. In which this additive is substantially made up of the Licanantase lipoprotein and a solution of sulfuric acid with a pH of 0.8 to 3. The Licanantase lipoprotein that has an amino acid sequence with at least 50% homology regarding the sequence defined in SEQ ID No. 1 or is the product of translation of a nucleotide sequence with at least 50% homology regarding the sequence defined in SEQ ID No. 2. It also protects the improved bioleaching process that includes adding the additive during the ore bioleaching process as defined in the present invention; and continuing with the habitual process, obtaining copper recoveries increased 5 to 20%.
Abstract: The present invention discloses a new recovery of base metals from sulphide ores and concentrates, which comprises mixing the base metal's ore with ferric salts, heating the said mixture; adding water to form a pulp, stirring and filtering the pulp.
Type:
Application
Filed:
July 23, 2013
Publication date:
January 23, 2014
Applicant:
VALE S/A
Inventors:
Tiago Valentim BERNI, Antonio Clareti PEREIRA, Felipe Hilario GUIMARÃES
Abstract: Process for melting scrap metal in a furnace comprising the steps of feeding a charge of solid scrap metal to the furnace, supplying fuel and an oxygen-rich oxidant to the furnace and combusting the fuel with the oxidant to generate heat inside the furnace, melting the charge of solid scrap metal in the furnace by means of the heat, withdrawing the molten metal from the furnace. Following the step of feeding the charge of solid scrap metal to the furnace, the fuel is combusted with the oxidant so as to generate one or more visible flames in the furnace above the charge and before the step of withdrawing the molten metal from the furnace, the fuel is combusted with the oxidant so as to generate flameless combustion in the furnace above the molten metal.
Type:
Application
Filed:
July 28, 2011
Publication date:
May 23, 2013
Applicant:
L'Air Liquide Societe Anonyme Pour L'Elide Et L'Exploitation Des Procedes Georges Claude
Abstract: Copper-manganese alloys, optionally with potentially other alloying elements, whose compositions are at or sufficiently near the congruent (minimum) melting point of the Cu—Mn system to substantially avoid dendritic growth during solidification. Processes for producing such alloys are also provided, as well as products produced from such alloys.
Abstract: In the method for recovering a metal from a target that contains a metal and a metal oxide, the target contains a sintered body of the metal oxide after being heated under a condition of melting the metal without melting or decomposing the metal oxide. The target is heated in an upper crucible of a two-level crucible that includes the upper crucible with a through hole-formed in a bottom surface thereof, and a lower crucible disposed below the through hole, the size of the through hole being set such that it does not allow the sintered body of the metal oxide contained in the target to pass therethrough, and the melted metal is caused to flow into the lower crucible, so that the metal is separated from the metal oxide.
Abstract: The present invention provides a preparation method of a metal matrix composite. The method comprises the following steps of: 1) pulverizing a solid carbon material to a micrometer size; 2) plastic deforming a metal matrix powder and dispersing the pulverized nanometer-sized carbon material into the metal matrix powder during the plastic deformation; 3) integrating the metal/carbon nano-material composite powder obtained in step 2) by using a hot forming process; and 4) heat treating the integrated bulk material at a predetermined temperature to form a composite having a metal-carbon nanophase, a metal-carbon nanoband formed by growth of the metal-carbon nanophase, or a metal-carbon nano-network structure formed by self-coupling of the metal-carbon nanoband.
Type:
Application
Filed:
October 22, 2010
Publication date:
September 27, 2012
Applicant:
Industry-Academic Cooperation Foundation, Yonsei University
Abstract: The present invention relates to the use of liquid-crystal displays (LCDs), and to processes for the recycling thereof. The processes according to the invention are characterised in that the LCDs are employed at least partly as replacement for other raw materials. In general, the LCDs are thermally treated here at a temperature in the range from 900 to 1700° C.
Abstract: A simple, compact burner achieves a more optimal melting of a solid charge followed by performance of combustion under distributed combustion conditions. The burner achieves this by fluidically bending the flame towards the solid charge during a melting phase with an actuating jet of oxidant, redirecting the flame in a direction away from the charge, and staging injection of oxidant among primary and secondary portions during a distributed combustion phase.
Type:
Application
Filed:
December 31, 2010
Publication date:
January 12, 2012
Inventors:
Vivek GAUTAM, Kenneth KAISER, Luc JARRY, Remi Pierre TSIAVA
Abstract: In the method for recovering a metal from a target that contains a metal and a metal oxide, the target contains a sintered body of the metal oxide after being heated under a condition of melting the metal without melting or decomposing the metal oxide. The target is heated in an upper crucible of a two-level crucible that includes the upper crucible with a through hole-formed in a bottom surface thereof, and a lower crucible disposed below the through hole, the size of the through hole being set such that it does not allow the sintered body of the metal oxide contained in the target to pass therethrough, and the melted metal is caused to flow into the lower crucible, so that the metal is separated from the metal oxide.
Abstract: Provided is a high-purity copper or high-purity copper alloy sputtering target of which the purity is 6N or higher and in which the content of the respective components of P, S, O and C is 1 ppm or less, wherein the number of nonmetal inclusions having a particle size of 0.5 ?m or more and 20 ?m or less is 30,000 inclusions/g or less. As a result of using high-purity copper or high-purity copper alloy from which harmful inclusions of P, S, C and O system have been reduced as the raw material and controlling the existence form of nonmetal inclusions, the present invention addresses a reduction in the percent defect of wirings of semiconductor device formed by sputtering a high-purity copper target so as to ensure favorable repeatability.
Abstract: In producing high-quality steel with use of copper-containing steel scraps as an iron source, the copper-containing steel scraps are melted with addition of carbon to produce hot metal for steelmaking, then, copper contained in the hot metal is removed by sulfur-containing flux, and sulfur contained in the hot metal is removed. With this method, the copper in the steel scraps can be removed efficiently and without the need for large facilities. Preferably, the sulfur-containing flux used is flux having Na2S as the main component. The treatment for removing copper in the hot metal is preferably carried out with use of refining equipment with mechanical stirrer or by the flux injecting method. Besides, it is preferable that a shaft furnace having a coke bed formed inside is used to produce hot metal having a higher concentration of sulfur for the copper removal treatment.
Abstract: The present invention provides a process for treating a exhaust gas which is generated when slag discharged from a smelting furnace for non-ferrous metal is water-granulated. There is provided a process for treating an exhaust gas, which is generated during water granulation of slag discharged from a smelting furnace for non-ferrous metal, containing the water vapor as a major component and metal fumes, the process comprising a step of treating the exhaust gas by a wet electrostatic precipitator.
Abstract: Methods and systems for removing copper from ferrous scrap are described. Some amounts of copper in ferrous scrap are removed by oxidation and subsequent mechanical impact of the oxidized scrap. Further removal of copper from the solid scrap can be achieved by fluxing the copper oxide below the melting point of ferrous scrap using CaO—SiO2—B2O3— and Na2O—SiO2—B2O3-based slags. Using the invention, copper can be removed from ferrous scrap in a natural, cost-effective, and environmental-friendly manner.
Abstract: Dried copper concentrate is introduced to a smelter/converter that utilizes oxygen enrichment in the smelter/convert process. The copper concentrate was previously dried in a gas suspension or fluid bed dryer by contact with nitrogen gas that was a byproduct from the oxygen plants utilized to support the smelter.
Abstract: Process for extracting copper and precious metals from copper and iron bearing ores, ore concentrates or minerals, comprising the following steps: converting the copper and iron bearing ores, ore concentrates or minerals to copper-containing sulfides and iron sulfides by reaction with sulfur at 300 to 600° C. for at least 5 min; grinding the reaction product; physically separating the copper-containing sulfides at least partially from iron sulfides; treating the separated copper-containing sulfides by pyrometallurgical or hydrometallurgical processes to obtain copper.
Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
Abstract: The method relates to a pyrometallurgical and hydrometallurgical process for the recovery and recycling of lithium and vanadium compounds from a material comprising spent rechargeable lithium batteries, particularly lithium metal gel and solid polymer electrolyte rechargeable batteries. The method involves providing a mass of the material, hardening it by cooling at a temperature below room temperature, comminuting the mass of cooled and hardened material, digesting with an acid its ashes obtained by incineration, or its solidified salts obtained by molten salt oxidation, or the comminuted mass itself, to give a mother liquor, extracting vanadium compounds from the mother liquor, separating heavy metals and aluminium therefrom, and precipitating lithium carbonate from the remaining solution.
Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
Abstract: A system is described for forming a recycled copper product from at least one copper scrap feedstock source containing at least one contaminant. A pre-determined maximum weight percentage of the contaminant in the recycled copper product is initially established. The weight percentage of the contaminant in the copper scrap feedstock source is then determined. A determination is then made as to whether the weight percentage of the contaminant in the copper scrap feedstock source will exceed the established maximum weight percentage of the contaminant in the recycled copper product. If so, another copper scrap feedstock source is then added to the first copper feedstock source so as to cause the combined copper scrap feedstock sources to have an average weight percentage of the contaminant that does not exceed the established maximum weight percentage of the contaminant in the recycled copper product.
Type:
Grant
Filed:
September 10, 2002
Date of Patent:
June 17, 2003
Assignee:
Mueller Industries, Inc.
Inventors:
Tommy Jamison, Paul D. Babin, Glenn Dennis, Allen Popetz
Abstract: There is provided conductive paste wherein conductive fillers composed of copper micro-fibers are mixed into thermoplastic resin or thermosetting resin.
Abstract: A system is described for forming a recycled copper product from at least one copper scrap feedstock source containing at least one contaminant. A pre-determined maximum weight percentage of the contaminant in the recycled copper product is initially established. The weight percentage of the contaminant in the copper scrap feedstock source is then determined. A determination is then made as to whether the weight percentage of the contaminant in the copper scrap feedstock source will exceed the established maximum weight percentage of the contaminant in the recycled copper product. If so, another copper scrap feedstock source is then added to the first copper feedstock source so as to cause the combined copper scrap feedstock sources to have an average weight percentage of the contaminant that does not exceed the established maximum weight percentage of the contaminant in the recycled copper product.
Type:
Grant
Filed:
August 31, 2001
Date of Patent:
November 12, 2002
Assignee:
Mueller Industries, Inc.
Inventors:
Tommy Jamison, Paul D. Babin, Glenn Dennis, Allen Popetz
Abstract: The invention relates to a method for the extraction of metals from copper sulphide and/or copper iron sulphide ores with microbiological- and chemical-type leaching steps for dissolution of the metals, which comprises the following steps: 1) In a conversion step, prior to the leaching steps, the ores are converted to covellite, pyrites and admixed sulphides by the addition of sulphur, and 2) copper and other metals, noble metals and rare earths contained in the reaction product are extracted.
Abstract: There is provided a process of recovering copper from winding composed of an enameled copper wire having a polyester and/or a polyurethane based insulating coating thereon, and the process includes the steps of immersing the winding into an alkali solution, removing alkali attaching to the winding, and melting the winding using high frequency heating.
Type:
Grant
Filed:
April 8, 1997
Date of Patent:
May 22, 2001
Assignee:
Matsushita Electric Industrial Co., Ltd.
Abstract: The method for processing waste or waste fractions, such as, for example, household refuse, car shredder light fractions or the like, provides for pyrolysis, gasification and/or combustion, whereupon the residues are melted under reducing conditions. The reduced portions are then are subjected to a stepwise oxidation, with chromium being quantitatively separated in a first oxidation stage. After this, a calcium ferrite slag is formed by further oxidation, whereupon the remaining metal bath is further processed in order to recover nonferrous heavy metals.
Abstract: The charge well of a metal melting furnace is provided with an internal cavity having a circular cross section when viewed from the top, preferably a cavity of cylindrical or conical configuration, and with a peripheral exit port located tangentially with respect to said cavity at a lower level thereof for exit of molten metal into the main chamber of the furnace. An inert gas bubble-actuated molten metal pump brings molten metal from a hotter section of the furnace, advantageously directly from the main chamber, and has its exit port located tangentially to the periphery of the cavity at an upper level thereof, thereby creating vortical flow of molten metal within the charge well for the more rapid and efficient melting of metal chips and scraps into the molten metal therein and for circulation of hotter molten metal throughout the furnace.
Abstract: A method for treating a brass fixture having a fluid-contacting surface with lead dispersoids exposed thereon to reduce lead leaching into a fluid supply by contacting the brass fixture with a liquid metal solution selected from the group consisting of a liquid sodium solution, a liquid potassium solution and a liquid metal alloy solution to dissolve lead dispersoids from the fixture, wherein the metal alloy comprises a metal selected from the group consisting of sodium and potassium.
Abstract: A process for refining high-impurity blister copper to anode quality copper is disclosed. In an oxidation step of a blister copper refining stage, soda ash fluxing removes antimony and arsenic while also removing sulfur and iron. In a deoxidation step of the blister copper refining stage, sulfur hexafluoride is injected at a controlled oxygen concentration to remove bismuth while reducing the oxygen content. Slag is continuously or periodically skimmed from the surface of the molten blister copper to prevent re-entry of impurities. The process may be carried out in batch operation or, in a preferred embodiment, in continuous flow-through operation.
Type:
Grant
Filed:
September 20, 1996
Date of Patent:
December 15, 1998
Assignee:
The Trustees of Columbia University in the City of New York
Abstract: A processing method by which metals may be recovered at a high purity from metal-containing waste materials.The method for processing metal-containing waste materials comprises crushing a metal-containing waste material to a particle size of 1-50 mesh, separating and recovering the metal-containing particles from the crushed portion, introducing the metal-containing particles into a vacuum heating furnace, pre-heating the furnace while under suction evacuation, and then raising the temperature of the furnace in stages while continuing the vacuum suctioning, recovering the metal and non-metal vapor produced at each temperature level using a condensing and adsorbing means, and recovering the liquated metals as melts. The method may be used to process waste batteries, copper-containing waste materials and the like in the same manner to recover high-purity metals.
Abstract: In situ formation of metal-ceramic oxide microstructures is carried out on a starting oxide phase containing at least a most noble metallic component (e.g., iron) and a least noble metallic component (e.g. manganese) and subjecting the starting oxide phase to a temperature and oxygen partial pressure and for a time period to cause reduction of only part of the most noble metallic component to elemental metal.
Abstract: The invention is a process for the removal of high concentrations of impurities including antimony (Sb), bismuth (Bi), arsenic (As), lead (Pb), zinc (Zn), cadmium (Cd), selenium (Se) and tellurium (Te) contained in flue dusts produced during the smelting of copper. To effect the separation, the flue dust is slurried to about 10-30 weight percent solids. Then slurry is fed to gravity separation equipment, where the lighter impurities fraction segregates from the heavier revenue metals fraction. The segregated high copper concentrate is then washed while the tailings are neutralized by lime milk, dewatered and recovered as tailings cake. The wash solution together with the thickener overflow is subjected to copper cementation to recover the dissolved copper in the solution. The lighter impurities fraction can be subjected to acid leaching in order to further recover copper therefrom.
Type:
Grant
Filed:
February 14, 1990
Date of Patent:
July 16, 1991
Assignee:
Philippine Associated Smelting and Refining Corporation
Inventors:
Simon C. Raborar, Marcial B. Campos, Alex H. Penaranda