Carbothermic Patents (Class 75/674)
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Patent number: 8388921Abstract: A mass of solid aluminum carbide containing product is produced by a process in which a mixture is formed of an aluminum containing material and a carbonaceous material consisting of, containing or yielding carbon. Then the resulting mixture is heated to a temperature sufficient to react carbon of the carbonaceous material with the aluminum of the aluminum containing material to produce solid aluminum carbide. The solid aluminum carbide then is able to be heated with an aluminum compound selected from Al2O3, Al4CO4, AlO, Al2O and mixtures thereof, to produce aluminum metal and carbon monoxide.Type: GrantFiled: May 8, 2009Date of Patent: March 5, 2013Assignee: Thermical IP Pty Ltd.Inventor: Yaghoub Sayad-Yaghoubi
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Patent number: 8206572Abstract: Systems, methods and apparatus for reducing impurities in electrolysis cells are disclosed. In one approach, a method includes feeding a particulate fines feed stream to a tank, mixing particulate fines (PF) with liquid, the liquid having a first liquid and a second liquid, and separating at least some of the first liquid from at least some of the second liquid. The particulate fines (PF) may include inlet carbon fines (CFI) and inlet recyclable fines (RFI). The first liquid may include a recovered recyclable fines portion (RF1), and the second liquid may include a waste carbon fines portion (CF1). The mass ratio of the recovered recyclable fines portion (RF1) to the inlet recyclable fines (RFI) may be at least about 0.5. The mass ratio of the waste carbon fines portion (CF1) to the inlet carbon fines (CFI) may be at least about 0.1.Type: GrantFiled: April 29, 2009Date of Patent: June 26, 2012Assignee: Alcoa Inc.Inventors: Xiangwen Wang, Gary Tarcy
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Publication number: 20110165332Abstract: A mass of solid aluminium carbide containing product is produced by a process in which a mixture is formed of an aluminium containing material and a carbonaceous material consisting of, containing or yielding carbon. Then the resulting mixture is heated to a temperature sufficient to react carbon of the carbonaceous material with the aluminium of the aluminium containing material to produce solid aluminium carbide. The solid aluminium carbide then is able to be heated with an aluminium compound selected from AI2O3, AI4CO4, AIO, AI2O and mixtures thereof, to produce aluminium metal and carbon monoxide.Type: ApplicationFiled: May 8, 2009Publication date: July 7, 2011Inventor: Yaghoub Sayad-Yaghoubi
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Patent number: 7896945Abstract: A mass of solid aluminium carbide containing product is produced by injecting particulate alumina into a bath (30) of molten aluminium metal; and injecting carbonaceous material, consisting of, containing or yielding carbon, into the bath (30). The bath (30) of molten aluminium metal is maintained at a superheated temperature to heat and react carbon with molten aluminium to produce solid aluminium carbide which mixes with alumina to form a mass (36) containing entrapped gas and entrapped molten aluminium metal and having a bulk or apparent density less than aluminium. The mass is allowed to accumulate as a mass of solid aluminium carbide containing product on the upper surface of the bath. The carbonaceous material is a hydrocarbon material or is produced by pyrolysis, decomposition or cracking of a hydrocarbon material.Type: GrantFiled: December 21, 2007Date of Patent: March 1, 2011Assignee: Thermical IP Pty Ltd.Inventor: Yaghoub Sayad-Yaghoubi
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Patent number: 7854783Abstract: Apparatus, systems and methods for carbothermically producing aluminum are disclosed. The systems may include a reactor and an electrical supply. The reactor may include a plurality of side-entering electrodes and a top-entering electrode. The electrical supply may be operable to supply multiphase current to the side-entering electrodes and/or the top-entering electrodes. The electrodes may be in communication with a molten bath of the reactor, and the multiphase current supplied thereto may be passed through the bath to heat the reactor. The amount of current supplied to various electrode sets may be adjusted to facilitate tailored heating of the molten bath.Type: GrantFiled: March 11, 2010Date of Patent: December 21, 2010Assignees: Alcoa Inc., Elkem ASInventors: Joseph A. Lepish, Gerald E. Carkin
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Patent number: 7829460Abstract: By forming an aluminum nitride layer by a self-limiting process sequence, the interface characteristics of a copper-based metallization layer may be significantly enhanced while nevertheless maintaining the overall permittivity of the layer stack at a lower level.Type: GrantFiled: November 30, 2007Date of Patent: November 9, 2010Assignee: GLOBALFOUNDRIES, Inc.Inventors: Christof Streck, Volker Kahlert
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Publication number: 20100275732Abstract: Systems, methods and apparatus for reducing impurities in electrolysis cells are disclosed. In one approach, a method includes feeding a particulate fines feed stream to a tank, mixing particulate fines (PF) with liquid, the liquid having a first liquid and a second liquid, and separating at least some of the first liquid from at least some of the second liquid. The particulate fines (PF) may include inlet carbon fines (CFI) and inlet recyclable fines (RFI). The first liquid may include a recovered recyclable fines portion (RF1), and the second liquid may include a waste carbon fines portion (CF1). The mass ratio of the recovered recyclable fines portion (RF1) to the inlet recyclable fines (RFI) may be at least about 0.5. The mass ratio of the waste carbon fines portion (CF1) to the inlet carbon fines (CFI) may be at least about 0.1.Type: ApplicationFiled: April 29, 2009Publication date: November 4, 2010Applicant: Alcoa Inc.Inventors: Xiangwen Wang, Gary Tarcy
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Patent number: 7819937Abstract: An agglomerate comprising alumina, carbon, and a binder for use in a vapor recovery reactor of a carbothermic alumina reduction furnace is disclosed. A method for using alumina-carbon agglomerates to capture aluminum vapor species and utilize waste heat from off-gases in a vapor recovery reactor to form a recyclable material is also disclosed.Type: GrantFiled: January 7, 2010Date of Patent: October 26, 2010Assignees: Alcoa Inc., Elkem ASInventors: Richard J. Fruehan, David J. Roha, Anders Schei, Mark L. Weaver
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Publication number: 20100162850Abstract: Apparatus, systems and methods for carbothermically producing aluminum are disclosed. The systems may include a reactor and an electrical supply. The reactor may include a plurality of side-entering electrodes and a top-entering electrode. The electrical supply may be operable to supply multiphase current to the side-entering electrodes and/or the top-entering electrodes. The electrodes may be in communication with a molten bath of the reactor, and the multiphase current supplied thereto may be passed through the bath to heat the reactor. The amount of current supplied to various electrode sets may be adjusted to facilitate tailored heating of the molten bath.Type: ApplicationFiled: March 11, 2010Publication date: July 1, 2010Applicants: Alcoa Inc., Elkem ASInventors: Joseph A. Lepish, Gerald E. Carkin
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Publication number: 20100147113Abstract: A method of recovering aluminum is provided. An alloy melt having Al4C3 and aluminum is provided. This mixture is cooled and then a sufficient amount of a finely dispersed gas is added to the alloy melt at a temperature of about 700° C. to about 900° C. The aluminum recovered is a decarbonized carbothermically produced aluminum where the step of adding a sufficient amount of the finely dispersed gas effects separation of the aluminum from the Al4C3 precipitates by flotation, resulting in two phases with the Al4C3 precipitates being the upper layer and the decarbonized aluminum being the lower layer. The aluminum is then recovered from the Al4C3 precipitates through decanting.Type: ApplicationFiled: December 15, 2008Publication date: June 17, 2010Applicant: Alcoa Inc.Inventors: Marshall J. Bruno, Gerald E. Carkin, David H. DeYoung, Ronald M. Dunlap, SR.
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Patent number: 6849101Abstract: In a method for recovering Al from an off-gas (3,4) produced during carbothermic reduction of aluminum utilizing at least one smelter (1,2), the off-gas (3,4) is directed to an enclosed reactor (5) which is fed a supply of wood charcoal (7) having a porosity of from about 50 vol. % to 85 vol. % and an average pore diameter of from about 0.05 ?m to about 2.00 ?m, where the wood charcoal (7) contacts the off-gas (3,4) to produce at least Al4C3 (6), which is passed back to the smelter (1,2).Type: GrantFiled: December 4, 2003Date of Patent: February 1, 2005Assignees: Alcoa Inc., Elkem ASA, Carnegie Mellon UniversityInventors: Richard J. Fruehan, Yun Li, Gerald Carkin
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Patent number: 6827759Abstract: The present invention relates to producing cobalt having a low oxygen and a low oxide inclusion content for use as a sputter target thereby reducing the arcing and metal defects during sputtering commonly associated with high-oxygen cobalt sputter targets. Notably, the method for reducing the oxygen content and the oxide inclusion content in cobalt are separate processes which may be combined in successive order to procuce a low-oxygen cobalt sputter target having a low oxide inclusion content. The reduction in oxygen content preferably is performed prior to reducing the oxide inclusion content. Accordingly, the artisan will appreciate that one process can be performed without the other depending upon whether a reduction in oxygen or oxide inclusions is preferred in a desired cobalt sputter target.Type: GrantFiled: January 29, 2003Date of Patent: December 7, 2004Assignee: Tosoh SMD, Inc.Inventor: Hao Zhang
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Patent number: 6805723Abstract: A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.Type: GrantFiled: March 6, 2003Date of Patent: October 19, 2004Assignees: Alcoa Inc., Elkem ASAInventors: Jan Arthur Aune, Kai Johansen
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Patent number: 6530970Abstract: A method for aluminum recovery during the carbothermic production of aluminum in a smelting furnace (1,2) is disclosed, where during carbothermic reduction of alumina, aluminum and aluminum suboxide vapors are produced (3, 4), which are reacting with carbon. Reactive carbon is generated in situ by the cracking of hydrocarbon compounds (6) in a separate closed reactor vessel (5) at a temperature greater than about 1955° C. Solid aluminum carbide that formed during the reaction can then be recycled by a conduit (8) to the primary reactor for reduction to aluminum, and reactor gas (10) can be fed to a cooler (9).Type: GrantFiled: May 21, 2001Date of Patent: March 11, 2003Assignees: Alcoa Inc., Elkem ASAInventor: Tor Lindstad
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Patent number: 6475260Abstract: A process for producing aluminum metal by carbothermic reduction of alumina ore. Alumina ore is heated in the presence of carbon at an elevated temperature to produce an aluminum metal body contaminated with about 10-30% by wt. aluminum carbide. Aluminum metal or aluminum alloy scrap then is added to bring the temperature to about 900-1000° C. and precipitate out aluminum carbide. The precipitated aluminum carbide is filtered, decanted, or fluxed with salt to form a molten body having reduced aluminum carbide content.Type: GrantFiled: August 27, 2001Date of Patent: November 5, 2002Assignee: Alcoa Inc.Inventor: Alfred F. LaCamera
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Patent number: 6440193Abstract: The present invention relates to a process for carbothermic production of aluminum where molten bath aluminum carbide and aluminum oxide are produced in a low temperature compartment (2), and continuously flow into a high temperature compartment (3) where the aluminum carbide is reacted with alumina to produce a top aluminum layer (31), where the aluminum layer (31) forms a layer on the top of a molten slag layer and is tapped from the high temperature compartment (3) at outlet (5), and where off-gases from the two compartments are treated in reactors fed by one or more columns (9, 19). According to the invention the low temperature compartment (2) and the high temperature compartment (3) are located in a common reaction vessel (1) where the low temperature compartment is separated from the high temperature compartment by an underflow partition wall (4).Type: GrantFiled: May 21, 2001Date of Patent: August 27, 2002Assignees: Alcoa Inc., Elken ASAInventors: Kai Johansen, Jan A. Aune
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Patent number: 6361580Abstract: A continuous process for the production of elemental aluminum is described. Aluminum is made from aluminum oxide and a reducing gas such as a light hydrocarbon gas or other reducing gas, for example hydrogen. In the process, a feed stream of the aluminum oxide and the reducing gas is continuously fed into a reaction zone. There the aluminum oxide and reducing gas are reacted at a temperature of about 1500° C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental aluminum. The product stream is continuously quenching after leaving the reaction zone, and the elemental aluminum is separated from the other reaction products.Type: GrantFiled: August 21, 2000Date of Patent: March 26, 2002Assignee: Massachuetts Institute of TechnologyInventors: Sven Plahte, Bjorn Lillebuen, Alexander F. Diaz, Jack B. Howard, Anthony J. Modestino, William A. Peters
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Patent number: 6086655Abstract: A thermo-mechanical process for producing aluminum or other metals from aluminium or metal compounds, is described, whereby aluminum oxide or similar aluminium compounds or similar other metal compounds, are heated by friction generated by mechanical forces from a rotating and/or agitating means within a process chamber together with either free water or waterforming constituents in the aluminium-or-metal compounds and a hydrogen- and carbon delivering material such as oil or natural gas, such as methane, and carbon in such a manner that material in the reactor chamber behaves like a hot mechanical fluidized bed whereby the water can be split into hydroxyl and hydrogen radicals making hydrogen radicals react, with the oxygen in the hot and now unstable aluminum or metal compound and thus releasing aluminum or metal atoms, and the hydroxyl radical reacting back to water and if carbon is used, the surplus of oxygen reacting with carbon to CO or CO.sub.2.Type: GrantFiled: April 22, 1998Date of Patent: July 11, 2000Assignee: Industrikontakt, Ing. O Ellingsen & Co.Inventors: Olav Ellingsen, Liv S.o slashed.reb.o slashed. Ellingsen, Bjarte S.o slashed.reb.o slashed. Ellingsen
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Patent number: 5316565Abstract: Method and apparatus for reducing the quantity of carbon dioxide emitted to the atmosphere from carbothermic processes producing metals are described. The method involves rejecting carbon from the process system or using carbon as a reagent to be recycled within the boundaries of the process system as a result of reactions of hydrogen with the carbon monoxide produced by the carbothermic process. Examples of the application of the method are given for the production of aluminum and for the production of a portion of the iron content of steel.Type: GrantFiled: April 26, 1993Date of Patent: May 31, 1994Inventor: Robert M. Kibby
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Patent number: 5286274Abstract: This is a method for treatment of spent potlining from aluminium reduction cells including the refractory material in order to transfer the spent potlining to a form in which it can be used as a filler or as a raw material. The spent potlining is crushed and supplied to a closed electrothermic smelting furnace optionally together with a SiO.sub.2 source, wherein the spent potlining is melted at a temperature between 1300.degree. and 1750.degree. C. An oxidation agent is supplied to the furnace in order to oxidize carbon and other oxidizable components contained in the spent potlining such as metals, carbides and nitrides. Further, a source of calcium oxide is supplied to the smelting furnace in an amount necessary to react with all fluoride present to form CaF.sub.2 and to form a calcium aluminate or calcium aluminate silicate slag containing CaF.sub.Type: GrantFiled: November 3, 1992Date of Patent: February 15, 1994Assignee: Elkem Technology a/sInventors: Jon G. Lindkvist, Terje Johnsen