Carbothermic Patents (Class 75/674)
  • Patent number: 8388921
    Abstract: A mass of solid aluminum carbide containing product is produced by a process in which a mixture is formed of an aluminum containing material and a carbonaceous material consisting of, containing or yielding carbon. Then the resulting mixture is heated to a temperature sufficient to react carbon of the carbonaceous material with the aluminum of the aluminum containing material to produce solid aluminum carbide. The solid aluminum carbide then is able to be heated with an aluminum compound selected from Al2O3, Al4CO4, AlO, Al2O and mixtures thereof, to produce aluminum metal and carbon monoxide.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: March 5, 2013
    Assignee: Thermical IP Pty Ltd.
    Inventor: Yaghoub Sayad-Yaghoubi
  • Patent number: 8206572
    Abstract: Systems, methods and apparatus for reducing impurities in electrolysis cells are disclosed. In one approach, a method includes feeding a particulate fines feed stream to a tank, mixing particulate fines (PF) with liquid, the liquid having a first liquid and a second liquid, and separating at least some of the first liquid from at least some of the second liquid. The particulate fines (PF) may include inlet carbon fines (CFI) and inlet recyclable fines (RFI). The first liquid may include a recovered recyclable fines portion (RF1), and the second liquid may include a waste carbon fines portion (CF1). The mass ratio of the recovered recyclable fines portion (RF1) to the inlet recyclable fines (RFI) may be at least about 0.5. The mass ratio of the waste carbon fines portion (CF1) to the inlet carbon fines (CFI) may be at least about 0.1.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: June 26, 2012
    Assignee: Alcoa Inc.
    Inventors: Xiangwen Wang, Gary Tarcy
  • Publication number: 20110165332
    Abstract: A mass of solid aluminium carbide containing product is produced by a process in which a mixture is formed of an aluminium containing material and a carbonaceous material consisting of, containing or yielding carbon. Then the resulting mixture is heated to a temperature sufficient to react carbon of the carbonaceous material with the aluminium of the aluminium containing material to produce solid aluminium carbide. The solid aluminium carbide then is able to be heated with an aluminium compound selected from AI2O3, AI4CO4, AIO, AI2O and mixtures thereof, to produce aluminium metal and carbon monoxide.
    Type: Application
    Filed: May 8, 2009
    Publication date: July 7, 2011
    Inventor: Yaghoub Sayad-Yaghoubi
  • Patent number: 7896945
    Abstract: A mass of solid aluminium carbide containing product is produced by injecting particulate alumina into a bath (30) of molten aluminium metal; and injecting carbonaceous material, consisting of, containing or yielding carbon, into the bath (30). The bath (30) of molten aluminium metal is maintained at a superheated temperature to heat and react carbon with molten aluminium to produce solid aluminium carbide which mixes with alumina to form a mass (36) containing entrapped gas and entrapped molten aluminium metal and having a bulk or apparent density less than aluminium. The mass is allowed to accumulate as a mass of solid aluminium carbide containing product on the upper surface of the bath. The carbonaceous material is a hydrocarbon material or is produced by pyrolysis, decomposition or cracking of a hydrocarbon material.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: March 1, 2011
    Assignee: Thermical IP Pty Ltd.
    Inventor: Yaghoub Sayad-Yaghoubi
  • Patent number: 7854783
    Abstract: Apparatus, systems and methods for carbothermically producing aluminum are disclosed. The systems may include a reactor and an electrical supply. The reactor may include a plurality of side-entering electrodes and a top-entering electrode. The electrical supply may be operable to supply multiphase current to the side-entering electrodes and/or the top-entering electrodes. The electrodes may be in communication with a molten bath of the reactor, and the multiphase current supplied thereto may be passed through the bath to heat the reactor. The amount of current supplied to various electrode sets may be adjusted to facilitate tailored heating of the molten bath.
    Type: Grant
    Filed: March 11, 2010
    Date of Patent: December 21, 2010
    Assignees: Alcoa Inc., Elkem AS
    Inventors: Joseph A. Lepish, Gerald E. Carkin
  • Patent number: 7829460
    Abstract: By forming an aluminum nitride layer by a self-limiting process sequence, the interface characteristics of a copper-based metallization layer may be significantly enhanced while nevertheless maintaining the overall permittivity of the layer stack at a lower level.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: November 9, 2010
    Assignee: GLOBALFOUNDRIES, Inc.
    Inventors: Christof Streck, Volker Kahlert
  • Publication number: 20100275732
    Abstract: Systems, methods and apparatus for reducing impurities in electrolysis cells are disclosed. In one approach, a method includes feeding a particulate fines feed stream to a tank, mixing particulate fines (PF) with liquid, the liquid having a first liquid and a second liquid, and separating at least some of the first liquid from at least some of the second liquid. The particulate fines (PF) may include inlet carbon fines (CFI) and inlet recyclable fines (RFI). The first liquid may include a recovered recyclable fines portion (RF1), and the second liquid may include a waste carbon fines portion (CF1). The mass ratio of the recovered recyclable fines portion (RF1) to the inlet recyclable fines (RFI) may be at least about 0.5. The mass ratio of the waste carbon fines portion (CF1) to the inlet carbon fines (CFI) may be at least about 0.1.
    Type: Application
    Filed: April 29, 2009
    Publication date: November 4, 2010
    Applicant: Alcoa Inc.
    Inventors: Xiangwen Wang, Gary Tarcy
  • Patent number: 7819937
    Abstract: An agglomerate comprising alumina, carbon, and a binder for use in a vapor recovery reactor of a carbothermic alumina reduction furnace is disclosed. A method for using alumina-carbon agglomerates to capture aluminum vapor species and utilize waste heat from off-gases in a vapor recovery reactor to form a recyclable material is also disclosed.
    Type: Grant
    Filed: January 7, 2010
    Date of Patent: October 26, 2010
    Assignees: Alcoa Inc., Elkem AS
    Inventors: Richard J. Fruehan, David J. Roha, Anders Schei, Mark L. Weaver
  • Publication number: 20100162850
    Abstract: Apparatus, systems and methods for carbothermically producing aluminum are disclosed. The systems may include a reactor and an electrical supply. The reactor may include a plurality of side-entering electrodes and a top-entering electrode. The electrical supply may be operable to supply multiphase current to the side-entering electrodes and/or the top-entering electrodes. The electrodes may be in communication with a molten bath of the reactor, and the multiphase current supplied thereto may be passed through the bath to heat the reactor. The amount of current supplied to various electrode sets may be adjusted to facilitate tailored heating of the molten bath.
    Type: Application
    Filed: March 11, 2010
    Publication date: July 1, 2010
    Applicants: Alcoa Inc., Elkem AS
    Inventors: Joseph A. Lepish, Gerald E. Carkin
  • Publication number: 20100147113
    Abstract: A method of recovering aluminum is provided. An alloy melt having Al4C3 and aluminum is provided. This mixture is cooled and then a sufficient amount of a finely dispersed gas is added to the alloy melt at a temperature of about 700° C. to about 900° C. The aluminum recovered is a decarbonized carbothermically produced aluminum where the step of adding a sufficient amount of the finely dispersed gas effects separation of the aluminum from the Al4C3 precipitates by flotation, resulting in two phases with the Al4C3 precipitates being the upper layer and the decarbonized aluminum being the lower layer. The aluminum is then recovered from the Al4C3 precipitates through decanting.
    Type: Application
    Filed: December 15, 2008
    Publication date: June 17, 2010
    Applicant: Alcoa Inc.
    Inventors: Marshall J. Bruno, Gerald E. Carkin, David H. DeYoung, Ronald M. Dunlap, SR.
  • Patent number: 6849101
    Abstract: In a method for recovering Al from an off-gas (3,4) produced during carbothermic reduction of aluminum utilizing at least one smelter (1,2), the off-gas (3,4) is directed to an enclosed reactor (5) which is fed a supply of wood charcoal (7) having a porosity of from about 50 vol. % to 85 vol. % and an average pore diameter of from about 0.05 ?m to about 2.00 ?m, where the wood charcoal (7) contacts the off-gas (3,4) to produce at least Al4C3 (6), which is passed back to the smelter (1,2).
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: February 1, 2005
    Assignees: Alcoa Inc., Elkem ASA, Carnegie Mellon University
    Inventors: Richard J. Fruehan, Yun Li, Gerald Carkin
  • Patent number: 6827759
    Abstract: The present invention relates to producing cobalt having a low oxygen and a low oxide inclusion content for use as a sputter target thereby reducing the arcing and metal defects during sputtering commonly associated with high-oxygen cobalt sputter targets. Notably, the method for reducing the oxygen content and the oxide inclusion content in cobalt are separate processes which may be combined in successive order to procuce a low-oxygen cobalt sputter target having a low oxide inclusion content. The reduction in oxygen content preferably is performed prior to reducing the oxide inclusion content. Accordingly, the artisan will appreciate that one process can be performed without the other depending upon whether a reduction in oxygen or oxide inclusions is preferred in a desired cobalt sputter target.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: December 7, 2004
    Assignee: Tosoh SMD, Inc.
    Inventor: Hao Zhang
  • Patent number: 6805723
    Abstract: A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: October 19, 2004
    Assignees: Alcoa Inc., Elkem ASA
    Inventors: Jan Arthur Aune, Kai Johansen
  • Patent number: 6530970
    Abstract: A method for aluminum recovery during the carbothermic production of aluminum in a smelting furnace (1,2) is disclosed, where during carbothermic reduction of alumina, aluminum and aluminum suboxide vapors are produced (3, 4), which are reacting with carbon. Reactive carbon is generated in situ by the cracking of hydrocarbon compounds (6) in a separate closed reactor vessel (5) at a temperature greater than about 1955° C. Solid aluminum carbide that formed during the reaction can then be recycled by a conduit (8) to the primary reactor for reduction to aluminum, and reactor gas (10) can be fed to a cooler (9).
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: March 11, 2003
    Assignees: Alcoa Inc., Elkem ASA
    Inventor: Tor Lindstad
  • Patent number: 6475260
    Abstract: A process for producing aluminum metal by carbothermic reduction of alumina ore. Alumina ore is heated in the presence of carbon at an elevated temperature to produce an aluminum metal body contaminated with about 10-30% by wt. aluminum carbide. Aluminum metal or aluminum alloy scrap then is added to bring the temperature to about 900-1000° C. and precipitate out aluminum carbide. The precipitated aluminum carbide is filtered, decanted, or fluxed with salt to form a molten body having reduced aluminum carbide content.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: November 5, 2002
    Assignee: Alcoa Inc.
    Inventor: Alfred F. LaCamera
  • Patent number: 6440193
    Abstract: The present invention relates to a process for carbothermic production of aluminum where molten bath aluminum carbide and aluminum oxide are produced in a low temperature compartment (2), and continuously flow into a high temperature compartment (3) where the aluminum carbide is reacted with alumina to produce a top aluminum layer (31), where the aluminum layer (31) forms a layer on the top of a molten slag layer and is tapped from the high temperature compartment (3) at outlet (5), and where off-gases from the two compartments are treated in reactors fed by one or more columns (9, 19). According to the invention the low temperature compartment (2) and the high temperature compartment (3) are located in a common reaction vessel (1) where the low temperature compartment is separated from the high temperature compartment by an underflow partition wall (4).
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: August 27, 2002
    Assignees: Alcoa Inc., Elken ASA
    Inventors: Kai Johansen, Jan A. Aune
  • Patent number: 6361580
    Abstract: A continuous process for the production of elemental aluminum is described. Aluminum is made from aluminum oxide and a reducing gas such as a light hydrocarbon gas or other reducing gas, for example hydrogen. In the process, a feed stream of the aluminum oxide and the reducing gas is continuously fed into a reaction zone. There the aluminum oxide and reducing gas are reacted at a temperature of about 1500° C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental aluminum. The product stream is continuously quenching after leaving the reaction zone, and the elemental aluminum is separated from the other reaction products.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: March 26, 2002
    Assignee: Massachuetts Institute of Technology
    Inventors: Sven Plahte, Bjorn Lillebuen, Alexander F. Diaz, Jack B. Howard, Anthony J. Modestino, William A. Peters
  • Patent number: 6086655
    Abstract: A thermo-mechanical process for producing aluminum or other metals from aluminium or metal compounds, is described, whereby aluminum oxide or similar aluminium compounds or similar other metal compounds, are heated by friction generated by mechanical forces from a rotating and/or agitating means within a process chamber together with either free water or waterforming constituents in the aluminium-or-metal compounds and a hydrogen- and carbon delivering material such as oil or natural gas, such as methane, and carbon in such a manner that material in the reactor chamber behaves like a hot mechanical fluidized bed whereby the water can be split into hydroxyl and hydrogen radicals making hydrogen radicals react, with the oxygen in the hot and now unstable aluminum or metal compound and thus releasing aluminum or metal atoms, and the hydroxyl radical reacting back to water and if carbon is used, the surplus of oxygen reacting with carbon to CO or CO.sub.2.
    Type: Grant
    Filed: April 22, 1998
    Date of Patent: July 11, 2000
    Assignee: Industrikontakt, Ing. O Ellingsen & Co.
    Inventors: Olav Ellingsen, Liv S.o slashed.reb.o slashed. Ellingsen, Bjarte S.o slashed.reb.o slashed. Ellingsen
  • Patent number: 5316565
    Abstract: Method and apparatus for reducing the quantity of carbon dioxide emitted to the atmosphere from carbothermic processes producing metals are described. The method involves rejecting carbon from the process system or using carbon as a reagent to be recycled within the boundaries of the process system as a result of reactions of hydrogen with the carbon monoxide produced by the carbothermic process. Examples of the application of the method are given for the production of aluminum and for the production of a portion of the iron content of steel.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: May 31, 1994
    Inventor: Robert M. Kibby
  • Patent number: 5286274
    Abstract: This is a method for treatment of spent potlining from aluminium reduction cells including the refractory material in order to transfer the spent potlining to a form in which it can be used as a filler or as a raw material. The spent potlining is crushed and supplied to a closed electrothermic smelting furnace optionally together with a SiO.sub.2 source, wherein the spent potlining is melted at a temperature between 1300.degree. and 1750.degree. C. An oxidation agent is supplied to the furnace in order to oxidize carbon and other oxidizable components contained in the spent potlining such as metals, carbides and nitrides. Further, a source of calcium oxide is supplied to the smelting furnace in an amount necessary to react with all fluoride present to form CaF.sub.2 and to form a calcium aluminate or calcium aluminate silicate slag containing CaF.sub.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: February 15, 1994
    Assignee: Elkem Technology a/s
    Inventors: Jon G. Lindkvist, Terje Johnsen