Abstract: Disclosed is an exemplary method of purifying lead which includes the steps of placing lead and a fluoride salt blend in a container; forming a first fluid of molten lead at a first temperature; forming a second fluid of the molten fluoride salt blend at a second temperature higher than the first temperature; mixing the first fluid and the second fluid together; separating the two fluids; solidifying the molten fluoride salt blend at a temperature above a melting point of the lead; and removing the molten lead from the container. In certain exemplary methods the molten lead is removed from the container by decanting. In still other exemplary methods the molten salt blend is a Lewis base fluoride eutectic salt blend, and in yet other exemplary methods the molten salt blend contains sodium fluoride, lithium fluoride, and potassium fluoride.
Abstract: A unique pyrometallurgical lead refining process includes adding a Lewis acid component and an Arrhenius base compound to a molten lead bullion. The Lewis acid component and Arrhenius base compound are added in stoichiometric amounts that preferentially remove lighter amphoteric elements from the molten lead bullion, and promote reactions with amphoteric p-block elements in the lead bullion to form over the lead a slag of Lewis bases, thereby forming a slag layer incorporating the metal salts of the amphoteric p-block elements.
Type:
Grant
Filed:
May 23, 2012
Date of Patent:
August 6, 2013
Assignee:
Stannum Group LLC
Inventors:
Miguel Pizzuto, Robert Seebeck, Jerry D. Schulz
Abstract: A method for reducing tin in lead bullion has the steps of adding an Arrhenius base to a kettle containing lead bullion and tin, adding a byproduct of conventional detinning to the kettle, agitating contents of the kettle, and removing a layer of slag from the kettle. The disclosed method removes tin via chemical oxidation, adds lead via chemical reduction of an oxide from the byproduct of conventional detinning, and preserves most of the antimony content of the lead bullion.
Type:
Grant
Filed:
January 20, 2012
Date of Patent:
June 4, 2013
Assignee:
Stannum Group LLC
Inventors:
Jerry D. Schulz, Robert E. Seebeck, Lawrence G. Eagan
Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
Abstract: A unique pyrometallurgical lead refining process includes adding a Lewis acid component and an Arrhenius base compound to a molten lead bullion. The Lewis acid component and Arrhenius base compound are added in stoichiometric amounts that preferentially remove lighter amphoteric elements from the molten lead bullion, and promote reactions with amphoteric p-block elements in the lead bullion to form over the lead a slag of Lewis bases, thereby forming a slag layer incorporating the metal salts of the amphoteric p-block elements.
Type:
Application
Filed:
May 23, 2012
Publication date:
September 13, 2012
Applicant:
Stannum Group LLC
Inventors:
Miguel Pizzuto, Robert Seebeck, Jerry D. Schulz
Abstract: A unique pyrometallurgical lead refining process includes adding a Lewis acid component and an Arrhenius base compound to a molten lead bullion. The Lewis acid component and Arrhenius base compound are added in stoichiometric amounts that preferentially remove lighter amphoteric elements from the molten lead bullion, and promote reactions with amphoteric p-block elements in the lead bullion to form over the lead a slag of Lewis bases, thereby forming a slag layer incorporating the metal salts of the amphoteric p-block elements.
Type:
Grant
Filed:
July 31, 2009
Date of Patent:
July 3, 2012
Assignee:
Stannum Group LLC
Inventors:
Miguel Pizzuto, Robert Seebeck, Jerry D. Schulz
Abstract: A method for reducing tin in lead bullion has the steps of adding an Arrhenius base to a kettle containing lead bullion and tin, adding a byproduct of conventional detinning to the kettle, agitating contents of the kettle, and removing a layer of slag from the kettle. The disclosed method removes tin via chemical oxidation, adds lead via chemical reduction of an oxide from the byproduct of conventional detinning, and preserves most of the antimony content of the lead bullion.
Type:
Grant
Filed:
May 5, 2010
Date of Patent:
January 31, 2012
Assignee:
Stannum Group LLC
Inventors:
Jerry D. Schulz, Robert E. Seebeck, Lawrence G. Eagan
Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
Abstract: A unique pyrometallurgical lead refining process includes adding a Lewis acid component and an Arrhenius base compound to a molten lead bullion. The Lewis acid component and Arrhenius base compound are added in stoichiometric amounts that preferentially remove lighter amphoteric elements from the molten lead bullion, and promote reactions with amphoteric p-block elements in the lead bullion to form over the lead a slag of Lewis bases, thereby forming a slag layer incorporating the metal salts of the amphoteric p-block elements.
Type:
Application
Filed:
July 31, 2009
Publication date:
September 16, 2010
Applicant:
Stannum Group LLC
Inventors:
Miguel Pizzuto, Robert Seebeck, Jerry D. Schulz
Abstract: The Razor Process™ is a unique pyrometallurgical lead refining process. Benefits from the Razor process™ include: lower energy costs; improved working environment; reduced recycling costs; increased refining productivity; reduced cycle time and labor requirements; and production of secondary recyclable products, therefore yielding unique and immediate benefits.
Type:
Application
Filed:
December 5, 2006
Publication date:
June 3, 2010
Inventors:
Miguel Pizzuto, Robert Seebeck, Jerry D. Schulz
Abstract: The invention relates to a process for removing tin, arsenic and antimony from molten lead by means of oxygen or oxygen-containing gas mixtures, which is or are blown into the molten lead by means of at least one gas nozzle (2). To avoid damage to the gas nozzle, at least the oxygen outlet region (13) thereof, located in the molten lead (6), is enveloped by an inert gas.
Type:
Grant
Filed:
July 6, 1994
Date of Patent:
September 19, 1995
Assignee:
Messer Griesheim GmbH
Inventors:
Gerhard Gross, Dietmar Wibck, Karl Hengst, Frank Toubartz
Abstract: The thallium content of lead bullion is decreased in that iron chloride is stirred into the lead bullion so as to form a salt slag which contains thallium.
Abstract: The present invention relates to a method for cleaning a liquid metal bath, in particular a zinc or zinc-aluminum bath intended for the continuous production of a steel strip coated by immersion in a coating zone (5a), according to which method the metal coating bath (2) is cycled continuously between the coating zone (5a) and a cleaning zone (5b), the rise of solid intermetallic compounds contained in the said bath to the surface is brought about in the cleaning zone (5b), the rise of the said compounds in accelerated and the cleaned bath (2), the iron content of which is close to or below the solubility limit, is led back to the zone (5a).The invention also relates to an apparatus for carrying out the method.
Type:
Grant
Filed:
November 21, 1990
Date of Patent:
January 28, 1992
Assignee:
Sollac
Inventors:
Bernard Francois, Robert Haaser, Pierre Commun, Jean-Paul Hennechart