Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
Abstract: According to one embodiment, there is provided a method of analyzing antimony contained in glass according to its valency. This method includes milling glass containing antimony into a glass powder, weighing the glass powder and dissolving the glass powder by using hydrofluoric acid and hydrochloric acid to obtain a glass solution, masking hydrofluoric acid by adding aluminum ions to the glass solution, adding sodium borohydride and hydrochloric acid to the glass solution in which hydrofluoric acid is masked to generate a hydride of antimony (III), determining a concentration of antimony (III) contained in the glass solution based on the hydride, determining a total concentration of antimony contained in the glass solution and calculating a difference between the concentration of antimony (III) and the total concentration of antimony to obtain a concentration of antimony (V) from the difference.
Abstract: A method for producing an intermetallic compound, the method comprising: (1) providing components A, B and X; and forming by solid state reaction of components A, B and X an intermetallic compound having a filled skutterudite structure and formula of AaBbXc; (2) melting the intermetallic compound having a filled skutterudite structure produced in step (1) in the presence of additional X; and (3) annealing the intermetallic compound of step (2) in the presence of additional X at a temperature equal to, or greater than the phase formation temperature of the intermetallic compound.
Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
Abstract: The method for processing waste or waste fractions, such as, for example, household refuse, car shredder light fractions or the like, provides for pyrolysis, gasification and/or combustion, whereupon the residues are melted under reducing conditions. The reduced portions are then are subjected to a stepwise oxidation, with chromium being quantitatively separated in a first oxidation stage. After this, a calcium ferrite slag is formed by further oxidation, whereupon the remaining metal bath is further processed in order to recover nonferrous heavy metals.
Abstract: An antimony recovery process is disclosed in which antimony-containing material is leached in a solvent including elemental sulfur and a caustic to preferentially leach antimony. The antimony-containing leach liquor from the leaching step is separated from the insoluble residue by filtration, and the antimony compounds in the separated leach liquor are crystallized to separate the antimony compounds from impurities which are left in solution in the leach liquor. The crystals are then redissolved and treated to create marketable antimony products of high purity, such as antimony metal, sodium hydroxy antimonate, sodium antimonate, antimony pentoxide, and antimony pentasulfide. Alternatively, the crystallized antimony compounds comprising primarily sodium thioantimonate crystals may be recovered and sold without further treatment. Waste products may be treated with soluble iron compounds and lime to render the waste products safe for disposal.
Type:
Grant
Filed:
October 16, 1992
Date of Patent:
March 1, 1994
Assignee:
Sunshine Mining Company
Inventors:
Corby G. Anderson, Suzzann M. Nordwick, Leo E. Krys
Abstract: Fume generated by roasting speiss is contacted with an oxygen-containing gas at an elevated temperature for a sufficient time to product arsenic and antimony products which may be separated from each other by means such as condensation. Further, in the roasting of antimony-containing phases (such as speiss) the presence of arsenic can enhance the volatility of the antimony.
Type:
Grant
Filed:
January 29, 1991
Date of Patent:
May 5, 1992
Assignee:
ASARCO Incorporated
Inventors:
Taie Li, Thomas P. Clement, II, John P. Hager
Abstract: This invention relates to the metallurgy of iron and particularly to the separation and recovery of metals from electric arc furnace (EAF) dusts. While the invention discloses a process for the separation and recovery applicable to zinc, lead, cadmium and antimony contained in such EAF dusts, the invention is particularly applicable to the separation and recovery of zinc. This invention describes a method for reducing the zinc contained in an EAF dust, volatilizing the metallic zinc so produced from the mass of the dust, and reoxidizing the metallic zinc to zinc oxide along with the simultaneous regeneration of hydrogen which can be recycled to treat additional EAF dust.