Chemical Patents (Class 8/107)
  • Patent number: 4243391
    Abstract: The invention relates to a process for bleaching washed textiles in the tumbler of a mechanical laundry drier with an aqueous solution of hydrogen peroxide in an amount such that the residual moisture adhering to the textile material before drying contains 0.05 to 1 gm/liter of hydrogen peroxide, the drying being conducted so that the moist textile material assumes a temperature of at least 50.degree. C., preferably 55.degree. C. to 80.degree. C., for a period of at least 10 to 60 minutes. An addition of quaternary ammonium salts improves the bleach result and the softness of the textile material. An addition of a powdered bleaching activator of the N-acyl type also improves the bleach results.
    Type: Grant
    Filed: September 25, 1978
    Date of Patent: January 6, 1981
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Rolf Puchta, Karl Schwadtke, Hans Harder, Rudolf Weber
  • Patent number: 4217105
    Abstract: A process of bleaching cotton fabrics, especially in relation with household laundry, is provided by adsorbing on the fabric sulfonated zinc phthalocyanine photoactivator followed by rinsing and drying of the fabrics in the presence of visible light and oxygen.
    Type: Grant
    Filed: March 22, 1978
    Date of Patent: August 12, 1980
    Assignee: The Procter & Gamble Company
    Inventor: John F. Goodman
  • Patent number: 4215990
    Abstract: Granular peroxygen bleaching and laundering compositions containing a percarbonate as a source of available oxygen are stabilized by the addition of from 0.1 to 2.0 percent of a particulate siliceous matter such as amorphous silica. To prevent caking and promote flowability of the compositions, from 0.05 to 1.0 percent corn starch, diethyl phthalate or mixtures thereof is included.
    Type: Grant
    Filed: April 14, 1978
    Date of Patent: August 5, 1980
    Assignee: Purex Corporation
    Inventors: John H. Barrett, Jr., Elizabeth F. Formeloza
  • Patent number: 4199466
    Abstract: A process for the activation of peroxide-based bleaches comprising conjointly incorporating into an aqueous medium a peroxide-based bleach, sufficient buffering agent to maintain the aqueous medium under alkaline conditions, and a cyanoamine of the general formula ##STR1## as a peroxide activator. Stable peroxide-based bleaching and detergent compositions are also disclosed.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: April 22, 1980
    Assignee: Shell Oil Company
    Inventor: Herbert L. Benson, Jr.
  • Patent number: 4181756
    Abstract: Process and composition for selectively bleaching a polarizer, and particularly a polarizer used in a liquid crystal display, to achieve sharply-defined polarizing areas in accurate registration with the transparent conductive areas of the display. This is achieved by silk-screening a gel, containing a bleaching agent, onto selected areas of a polarizer in place of the display, the gel having a viscosity to permit silk-screening.
    Type: Grant
    Filed: October 5, 1977
    Date of Patent: January 1, 1980
    Inventor: James L. Fergason
  • Patent number: 4166718
    Abstract: A process for bleaching textiles which comprises treating stained textiles in an aqueous bath containing at least one water-soluble aluminium phthalocyanine, under irradiation with light and in the presence of oxygen, while either irradiating the bleaching bath direct or subsequently irradiating the moist textiles outside the bath, as well as water-soluble aluminium phthalocyanines containing detergent compositions are described.
    Type: Grant
    Filed: March 20, 1978
    Date of Patent: September 4, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Gerd Holzle, Andre Pugin
  • Patent number: 4164394
    Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an acylphosphonate.Also described are dry blend compositions containing the bleach bath components.
    Type: Grant
    Filed: October 10, 1978
    Date of Patent: August 14, 1979
    Assignee: FMC Corporation
    Inventors: Gaylen R. Brubaker, Fred R. Scholer
  • Patent number: 4164395
    Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator a sulfonyl oxime.Also described are dry blend compositions containing the bleach bath components.
    Type: Grant
    Filed: October 16, 1978
    Date of Patent: August 14, 1979
    Assignee: FMC Corporation
    Inventors: Joseph H. Finley, John H. Blumbergs
  • Patent number: 4133637
    Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an oxybis(diacyloxyborane) of the formula: ##STR1## wherein the acyloxy is derived from a carboxylic acid selected from the class consisting of saturated aliphatic carboxylic acids of 1 to 18 carbon atoms and aromatic carboxylic acids of the benzene and naphthalene series. Also described are dry blend compositions containing the bleach bath components.
    Type: Grant
    Filed: October 3, 1977
    Date of Patent: January 9, 1979
    Assignee: FMC Corporation
    Inventors: John H. Blumbergs, Fred R. Scholer
  • Patent number: 4128494
    Abstract: Novel percompound activators having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are the same or different and are hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals, cycloalkyl radicals, or hydrocarbon radicals containing at least one aromatic ring, or R.sub.5 and/or R.sub.6 are COR.sub.7, where R.sub.7 is hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals or hydrocarbon radicals containing at least one aromatic ring, the activators producing more rapid bleaching or oxidation at a given temperature or the same bleaching effect at a lower temperature and being useful for bleaching textile fibers, oils, fats, and waxes; hair and skin treatment; metal surface passivation; or purifying, sterilizing and disinfecting techniques.
    Type: Grant
    Filed: August 5, 1977
    Date of Patent: December 5, 1978
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventors: Jean-Pierre Schirmann, Bernard Dubreux, Michel Bakes, Serge-Yvon Delavarenne, Marie-Christine Daude-Lagrave
  • Patent number: 4120811
    Abstract: A bleaching composition comprising 50 to 99.9 wt.% of an inorganic peroxide and 0.01 to 10 wt.% of a compound having the formula: ##STR1## wherein R.sub.1 is hydrogen or alkyl having 1 to 3 carbon atoms, ##STR2## is a radical of a 5 member or 6 member heterocyclic ring system containing only nitrogen and carbon, or nitrogen, oxygen and carbon, atoms in the ring, which can be fused to a benzene ring or another heterocyclic ring to give a polycyclic radical, R.sub.2 is hydrogen or substituted or unsubstituted alkyl having 1 to 10 carbon atoms, substituted or unsubstituted phenyl, pyridyl or pyrrolidone group, R.sub.3 is hydrogen, substituted or unsubstituted alkyl, phenyl, alkoxy, phenoxy, amino, acyloxy, carbamoyl or acyl group or halogen, or R.sub.3 may form together with R.sub.4 a benzo radical, and R.sub.4 is hydrogen or a monovalent group --R.sub.5 Y in which R.sub.
    Type: Grant
    Filed: August 10, 1977
    Date of Patent: October 17, 1978
    Assignee: Kao Soap Co., Ltd.
    Inventors: Kouichi Yagi, Yunosuke Nakagawa
  • Patent number: 4120812
    Abstract: A coated peroxygen compound having improved storage stability, said peroxygen being coated with about 0.1 to about 3.0 weight percent of a polyethylene glycol product having an average molecular weight greater than about 200.
    Type: Grant
    Filed: June 17, 1977
    Date of Patent: October 17, 1978
    Assignee: FMC Corporation
    Inventor: Charles William Lutz
  • Patent number: 4119486
    Abstract: A wood pulp slurry, at a consistency of 0.1% to 10% by weight and having a pH ranging from 1 to 7, is bleached with ozone in the presence of 0.1% to 1.0% by weight of a cationic surfactant.
    Type: Grant
    Filed: December 2, 1976
    Date of Patent: October 10, 1978
    Assignee: Westvaco Corporation
    Inventor: Robert C. Eckert
  • Patent number: 4118183
    Abstract: A process for the treatment of warp yarns as a row of substantially parallel threads, wherein said yarns are impregnated with excess treating liquor, said excess is removed from the yarns and the treated yarns are finally dried and wound up on a loom beam, the improvement of bringing the linear thread density of the yarns, at least in the excess liquor removal zone, to a value of 2 or higher, said value being the same over the entire width of said yarn row, and reducing said yarn density to the nominal thread count for weaving before said yarns are wound up on at least one loom beam.
    Type: Grant
    Filed: March 31, 1977
    Date of Patent: October 3, 1978
    Assignee: Quikoton AG
    Inventors: Eckhardt Godau, Max Schneider
  • Patent number: 4115057
    Abstract: The present invention concerns a dyeing process with acid dyes for fibrous materials having basic functions, characterized in that amines are used which form salts or complexes with the dyes and have the general formula: ##STR1## wherein: R.sub.1, R.sub.2 and R.sub.3 are aliphatic hydrocarbon radicals, saturated or unsaturated, and having a linear or branched chain;R is either hydrogen or an aliphatic hydrocarbon radical, with either a linear or branched chain, saturated or unsaturated, on the general condition that the sum of the carbon atoms of the radicals R.sub.1, R.sub.2, R.sub.3 and R be a whole number between 11 and 29.
    Type: Grant
    Filed: October 28, 1976
    Date of Patent: September 19, 1978
    Assignee: Montedison S.p.A.
    Inventors: Francesco DeFeo, Vincenzo Gemini, Luigi Floridia
  • Patent number: 4110242
    Abstract: The method of activating aqueous solutions of percompounds utilizing N-acylated uracils and benzouracils as activators; solid activated compositions comprising solid percompounds and N-acylated uracils and benzouracils as activators; and novel diacylated uracils and benzouracils.
    Type: Grant
    Filed: March 29, 1977
    Date of Patent: August 29, 1978
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Christian Hase, Brigitte Hase
  • Patent number: 4096029
    Abstract: Efficient lignin removal from cellulosic pulp with decreased cellulose degradation is attained by replacing chlorine with an acidic bromine-chlorine mixture in acidic chlorination of the pulp.
    Type: Grant
    Filed: April 26, 1976
    Date of Patent: June 20, 1978
    Assignee: The Dow Chemical Company
    Inventor: Jack F. Mills
  • Patent number: 4094806
    Abstract: An unbuilt liquid detergent composition containing sulfonated zinc phthalocyanine as a bleach photoactivator is provided for removing stains from textiles. A process for removing stains from textiles by treating the textiles with an aqueous solution of the unbuilt detergent compositions of this invention in the presence of visible light and oxygen is provided. Preferred compositions contain a high proportion of zinc phthalocyanine tri and tetra sulfonates in the bleach photoactivator component.
    Type: Grant
    Filed: October 22, 1976
    Date of Patent: June 13, 1978
    Assignee: The Procter & Gamble Company
    Inventor: Brandon Helmholz Wiers
  • Patent number: 4077768
    Abstract: A process for washing or bleaching textiles in which "dye transfer" is inhibited by the use of an oxidizing bleaching agent together with a catalytic compound, such as iron phorphins, haemin chloride or iron phthalocyanines. Compositions for use in this washing or bleaching process are also taught.
    Type: Grant
    Filed: June 17, 1976
    Date of Patent: March 7, 1978
    Assignee: The Procter & Gamble Company
    Inventors: James Pyott Johnston, John Robert Tate, deceased, by Sidney Alfred Tate, administrator
  • Patent number: 4033718
    Abstract: Detergent compositions containing particular species of sulfonated zinc phthalocyanine were found to be unexpectedly effective bleach photoactivators for removing stains from textiles. These species are principally tri- and tetra-sulfonates, especially the latter, with minor amounts of di-sulfonates permitted.
    Type: Grant
    Filed: September 8, 1975
    Date of Patent: July 5, 1977
    Assignee: The Procter & Gamble Company
    Inventors: Thomas Charles Holcombe, Robert Howard Schultz
  • Patent number: 4025609
    Abstract: Sodium percarbonate is stabilized by a metal chelating agent which will produce a chelate compound insoluble or slightly soluble in water. Such metal chelating agent is dispersed in the reaction mixture with the aid of a surface active agent when sodium carbonate and hydrogen peroxide are reached and the crystals of sodium percarbonate are separated out.
    Type: Grant
    Filed: February 26, 1976
    Date of Patent: May 24, 1977
    Assignee: Kao Soap Co., Ltd.
    Inventor: Kinjiro Matsunaga
  • Patent number: 4006095
    Abstract: Preparation of stable solutions of aluminum hydride in liquid hydrocarbons such as benzene or toluene by a one-step reaction between, for instance, 1 mole of aluminum chloride with 3 moles of lithium hydride in said liquid hydrocarbon medium and in the presence of a weak ether base such as dimethyl ether, an aliphatic tertiary amine such as trimethylamine being added.
    Type: Grant
    Filed: March 31, 1972
    Date of Patent: February 1, 1977
    Assignee: Lithium Corporation of America
    Inventors: Doyt K. Hoffman, Ricardo O. Bach, Conrad W. Kamienski
  • Patent number: 3990843
    Abstract: A method of bleaching cotton is described herein which comprises contacting said cotton with a bleaching solution of chlorine monoxide in an inert liquid solvent (e.g. methyl chloroform). Bleaching occurs very rapidly by this method and the cotton fibers undergo very little if any degradation.
    Type: Grant
    Filed: August 5, 1974
    Date of Patent: November 9, 1976
    Assignee: The Dow Chemical Company
    Inventors: Thomas A. Chamberlin, L. Wayne White
  • Patent number: 3976538
    Abstract: A first portion of bleaching liquid is passed through cellulosic pulp in a bleaching zone at a first level with respect to the pulp feed direction and withdrawn through transversely spaced strainer means located at about said first level so that the passage of the first portion of bleaching liquid through the pulp is in a direction transverse to the feed direction of the pulp and a second portion of bleaching liquid is passed through said cellulosic pulp at a second level with respect to the pulp feed direction and withdrawn through transversely spaced strainer means located at about the second level so that the passage of the second portion of bleaching liquid through the pulp is in a direction transverse to the feed direction of the pulp and opposite from the transverse direction through said first level.
    Type: Grant
    Filed: February 24, 1976
    Date of Patent: August 24, 1976
    Assignee: Kamyr Aktiebolag
    Inventors: Johan E. Gullichsen, Rolf G. Ekholm