Abstract: A textile coated with a coating having multiphase fluorochemical and a cationic material. A printed image is subsequently placed on the coated textile.
Type:
Grant
Filed:
October 22, 2001
Date of Patent:
May 2, 2006
Assignee:
Milliken & Company
Inventors:
Elizabeth Cates, Daniel T. McBride, William C. Kimbrell, Kirkland W. Vogt
Abstract: The present invention relates to a process for preparing synthetic hair fiber comprising halogen-containing synthetic fiber, in which synthetic hair fiber can be evenly dyed at a low temperature in a short period, maintaining excellent fastness, without abnormal shrinking (frizzing) and embrittlement of the fiber due to swelling. The object is attained by dipping the synthetic hair fiber bundle in a solution containing a dye, a carrier (accelerating agent) and a solvent for halogen-containing fiber, and then dyeing at 60° to 90° C.
Abstract: The present invention provides an animal fibers having improved shrink proofing and pilling resistance properties and method for preparation thereof. An animal fiber having excellent shrink proofing and pilling resistance and retaining its original water repellency is also provided. A method of treating animal fiber in which a surface layer part of animal fiber is primary-oxidized in advance with an oxidizer, and aqueous treatment liquid containing ozone in the form of ultrafine bubbles of 5? or less is allowed to collide against the fiber by blowing the liquid on the fiber in the aqueous treatment solution, and then, the fiber is treated with a reducing agent. Particularly, the above-mentioned method for treating animal fiber in which ultrafine bubbles of ozone are formed by using a line mixer. The method in which an apparatus which collects the ultrafine ozone bubbles in aqueous treatment liquid on the fiber is used so that the bubbles are not scattered out of a treatment reaction bowl.
Abstract: A textile coated with a coating having a multiphase fluorochemical, a cationic material, and a sorbant polymer. A printed image is subsequently placed on the coated textile.
Type:
Grant
Filed:
October 22, 2001
Date of Patent:
August 30, 2005
Assignee:
Milliken & Company
Inventors:
Elizabeth Cates, Daniel McBride, William Kimbrell, Kirkland Vogt
Abstract: Hydroscopic polymer gels can be formed by applying a water soluble or water dispersible polymer on a surface and allowing water to be sequestered from the atmosphere into the polymer. The polymer gels provides for easier next time cleaning. In addition, the surfaces of textiles and related materials can be engineered by the formation of polymer gel films thereon. Polymer gels also provide a vehicle by which sites of chemical reactions can be localized.
Type:
Grant
Filed:
October 2, 2002
Date of Patent:
August 9, 2005
Assignee:
The Clorox Company
Inventors:
David R. Scheuing, Malcolm DeLeo, Sara Morales
Abstract: In a preferred embodiment, the present process involves subjecting a fabric having splittable conjugate yarns both to an acidic treatment and to a basic treatment, each of which erodes a portion of the components of the conjugate yarns. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The basic treatment has a similar effect on the polyester element of the conjugate filament, making it more hydrophilic. The at least partial removal of the polyamide component, coupled with the increased hydrophilicity of the polyester component, results in a fabric having enhanced absorptive properties. In an alternate embodiment, treatments with only acid or only basic solution may be employed.
Type:
Grant
Filed:
February 8, 2002
Date of Patent:
March 8, 2005
Assignee:
Milliken & Company
Inventors:
John Scott McDaniel, Kirkland W. Vogt, Woodrow P. Gilbert
Abstract: A finish for synthetic filament to be processed in friction-texturing, which is applicable to various yarns and in a wide range of texturing speed, having been considered as difficult finish application field, such as low-speed friction texturing (with contact heaters), high-speed friction texturing (with non-contact heaters), coarse denier yarns and fine denier yarns, with satisfactory POY package buildup and POY release from packages, minimum fluffs and loops of POY, and with minimum fluffs of DTY and minimum fume and stain on heaters in texturing; and which contains 50 to 85 weight percent of Component A and 10 to 30 weight percent of Component B, having the following structures and a total ranging from 60 to 95 weight percent: Component A having a structure of R1[O(C2H4O)x.
Type:
Grant
Filed:
May 20, 2002
Date of Patent:
February 22, 2005
Assignee:
Matsumoto Yushi-Seiyaku Co., Ltd.
Inventors:
Yo Shingai, Ikuya Ujino, Hirohumi Ishida, Tatsuo Harada
Abstract: This invention is directed to APE-free polymer binders formed by emulsion polymerization and having specific peel and cure properties. The APE-free polymeric binders have a peel value, when adhered to a heated metal surface, of 35% to 200% of the peel value shown by a standard APE-based polymer binder control (i.e., AIRFLEX® 105 vinyl acetate-ethylene polymer emulsion) and exhibit a cure profile such that at least 55% cure is achieved within 30 seconds at a temperature required for cure. Wet tensile strength is used as a measure of cure. The peel value is determined by a modified release and adhesion test. Binders having the peel and cure properties described herein can be considered for use in crepe processes, especially DRC processes.
Type:
Grant
Filed:
December 19, 2001
Date of Patent:
November 30, 2004
Assignee:
Air Products Polymers, L.P.
Inventors:
Joel Erwin Goldstein, Ronald Joseph Pangrazi
Abstract: Nylon fibers are protected from colorant staining by treating them with at least 2% we/wt (weight dry SAC/weight dry nylon fiber) of sulfonated aromatic aldehyde condensation product. The treated fibers are then fixed by the wet heat method.
Abstract: In a preferred embodiment, the present process involves subjecting a fabric comprised of conjugate yarns to an acidic treatment, which degrades a portion of one component of the conjugate yarns and to dyeing. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The at least partial removal of the polyamide component results in a fabric has enhanced dyed appearance, especially when dyed a dark shade. In an alternate embodiment, the fabric may also be treated with a basic solution to improve its moisture transport properties.
Type:
Grant
Filed:
February 12, 2002
Date of Patent:
November 2, 2004
Assignee:
Milliken & Company
Inventors:
Heather J. Hayes, Crystal A. Garner, Kirkland W. Vogt, Kaushal Gandhi
Abstract: A textile coated with a coating having a multiphase fluorochemical, an organic cationic material, and a sorbant polymer. A printed image is subsequently placed on the coated textile.
Type:
Grant
Filed:
October 22, 2001
Date of Patent:
June 15, 2004
Assignee:
Milliken & Company
Inventors:
Elizabeth Cates, Daniel MaBride, William Carl Kimbrell, Jr., Kirkland Vogt
Abstract: The present invention provides fiber and fiber products for topsheet of diapers and sanitary napkins having superior surface properties attained by a fiber-treating agent. The surface properties attained by the fiber-treating agent include decreased wet-back of excreted liquid through topsheet, which has been attained by modifying the structure of disposable diapers or sanitary napkins, improved durable hydrophilicity of topsheet and minimized time-dependent reduction of the durable hydrophilicity of topsheet.
Abstract: The present invention refers to a process and a composition, containing latex, for the manufacturing of rubbery tissue sheets. The process of the present invention consists of the following steps: formulation of the composition, consecutive impregnation and smoking cycles; and maturation. Also, it is part of the scope of the present invention, a impregnation composition which is essentially an aqueous solution comprising latex, a sulfur source and a vulcanization accelerator. The rubbery tissue sheets obtained by the present invention can be submitted to the manufacturing of: suitcases, bags, purses, travelling bags, clothes, diaries, wallets, shoes and other objects usually made of leather.
Abstract: An oil tone artificial leather sheet having a blend of an oily substance of viscosity 50-10,000 mPa·s at 30° C. and a supporting polymer on part or all of a nap surface of a napped sheet comprising a non-woven fabric of microfine fibers and polyurethane existing in the non-woven fabric, wherein raised fibers comprising the microfine fibers are present in part or all of at least one surface and are forming the nap surface, and which has a high-quality appearance, and the soft hand touch and touch of natural leather. The sheet is useful in, for example, the manufacture of shoes or the like.
Abstract: The present invention relates to a nonwoven fabric having a relatively low level of ionic contaminates which is achieved by exposing the fabric to a deionized water wash, preferably, in-line with the nonwoven production process, thereby eliminating, or at least reducing, the need for an expensive and time consuming cleanroom laundering. The fabric is primarily comprised of continuous filament fibers and may be manufactured into such end-use products as cleaning wipes and protective clothing for cleanrooms and surface coating operations, such as automotive paintrooms. Also encompassed within this invention is a method for producing a nonwoven fabric having a relatively low level of ionic contaminates.
Abstract: The present invention relates to a nonwoven fabric having a relatively low level of ionic contaminates which is achieved by exposing the fabric to a deionized water wash, preferably, in-line with the nonwoven production process, thereby eliminating, or at least reducing, the need for an expensive and time consuming cleanroom laundering. The fabric is primarily comprised of continuous filament fibers and may be manufactured into such end-use products as cleaning wipes and protective clothing for cleanrooms and surface coating operations, such as automotive paintrooms. Also encompassed within this invention is a method for producing a nonwoven fabric having a relatively low level of ionic contaminates.
Abstract: A modified polyamide polymer having a high amino end group content, with more than 30 percent of the amino end groups being secondary or tertiary amine, dramatically improves the dye bleed performance. The modified polyamide may be prepared by polymerization of polyamide-forming monomers in the presence of a carboxylic acid and a hindered piperidine derivative in amounts sufficient to achieve the high amino end group content.
Type:
Grant
Filed:
March 30, 2001
Date of Patent:
September 16, 2003
Assignee:
Honeywell International Inc.
Inventors:
Ulrike Breiner, Dean R. Gadoury, Harry Y. Hu, Theodore G. Karageorgiou
Abstract: A modified polyamide polymer having a high amino end group content, with more than 30 percent of the amino end groups being secondary or tertiary amine, dramatically improves the dye bleed performance. The modified polyamide may be prepared by polymerization of polyamide-forming monomers in the presence of a carboxylic acid and a hindered piperidine derivative in amounts sufficient to achieve the high amino end group content.
Type:
Application
Filed:
March 30, 2001
Publication date:
November 28, 2002
Inventors:
Ulrike Breiner, Dean R. Gadoury, Harry Y. Hu, Theodore G. Karageorgiou
Abstract: This invention relates to antimicrobial fabrics which are treated with a specific durable and regenerable halamine/chlorine system and methods of removing residual active chlorine from the target textile surface without reducing the antimicrobial activity of the textile. Such methods comprise contacting an amine-treated fabric first with a halogen-based bleach (or other halogenated liquid) to produce halamines at the fabric surface, and subsequently washing the resultant halogenated fabric with a reducing agent which removes the residual, unbonded halogen (such as chlorine) from the fabric surface but does not, surprisingly, remove the halamine halogen. The remaining halamine halogen thus provides the desired antimicrobial activity.
Abstract: The present invention provides compositions, useful for making lyocell fibers, having a high hemicellulose content, a low lignin content and including cellulose that has a low average degree of polymerization (D.P.). Further, the present invention provides processes for making compositions, useful for making lyocell fibers, having a high hemicellulose content, a low lignin content and including cellulose that has a low average degree of polymerization. The present invention also provides lyocell fibers containing a high proportion of hemicellulose. Further, the lyocell fibers of the present invention have enhanced dye-binding properties and a reduced tendency to fibrillate.
Type:
Grant
Filed:
January 23, 2001
Date of Patent:
October 29, 2002
Assignee:
Weyerhaeuser Company
Inventors:
Mengkui Luo, Vincent A. Roscelli, Amar N. Neogi, James E. Sealey, II, Richard A. Jewell
Abstract: Textile fibers are treated with enzymes in the absence of surfactants, with the effect of increasing the wettability and absorbency of the fibers. The enzymes are pectinases, cellulases, proteases, lipases or combinations thereof. The wetting properties of cotton fibers are found to be most substantially improved by treatment with a mixture of cellulase and pectinase. The effects of five hydrolyzing enzymes on improving the hydrophilicity of several polyester fabrics have been studied. Four out of the five lipases studied improve the water wetting and absorbent properties of the regular polyester fabrics more than alkaline hydrolysis under optimal conditions (3N NaOH at 55° C. for 2 hours). Compared to aqueous hydrolysis, the enzyme reactions have shown to be effective under more moderate conditions, including a relatively low concentration (0.01 g/L), a shorter reaction time (10 minutes), at an ambient temperature (25° C.).
Type:
Application
Filed:
December 27, 1999
Publication date:
August 22, 2002
Inventors:
YOU-LO HSIEH, MARY MICHELLE HARTZELL, MATTHEW G. BOSTON, KATHLEEN A. CLARKSON, KATHERINE D. COLLIER, THOMAS P. GRAYCAR, EDMUND A. LARENAS
Abstract: Textile fibers are treated with enzymes in the absence of surfactants, with the effect of increasing the wettability and absorbency of the fibers. The enzymes are pectinases, cellulases, proteases, lipases or combinations thereof. The wetting properties of cotton fibers are found to be most substantially improved by treatment with a mixture of cellulase and pectinase. The effects of five hydrolyzing enzymes on improving the hydrophilicity of several polyester fabrics have been studied. Four out of the five lipases studied improve the water wetting and absorbent properties of the regular polyester fabrics more than alkaline hydrolysis under optimal conditions (3N NaOH at 55° C. for 2 hours). Compared to aqueous hydrolysis, the enzyme reactions have shown to be effective under more moderate conditions, including a relatively low concentration (0.01 g/L), a shorter reaction time (10 minutes), at an ambient temperature (25° C.).
Type:
Grant
Filed:
December 27, 1999
Date of Patent:
August 20, 2002
Assignees:
The Regents of the University of California, Genencor International, Inc.
Inventors:
You-lo Hsieh, Mary Michelle Hartzell, Matthew G. Boston, Kathleen A. Clarkson, Katherine D. Collier, Thomas P. Graycar, Edmund A. Larenas
Abstract: This invention relates to antimicrobial fabrics which are treated with a specific durable and regenerable halamine/chlorine system and methods of removing residual active chlorine from the target textile surface without reducing the antimicrobial activity of the textile. Such methods comprise contacting an amine-treated fabric first with a halogen-based bleach (or other halogenated liquid) to produce halamines at the fabric surface, and subsequently washing the resultant halogenated fabric with a reducing agent which removes the residual, unbonded halogen (such as chlorine) from the fabric surface but does not, surprisingly, remove the halamine halogen. The remaining halamine halogen thus provides the desired antimicrobial activity.
Abstract: A process for imparting long-lasting antimicrobial properties to fabrics is disclosed which entails the diffusion of triclosan esters within each individual fiber of a textile. One preferred method is performed in a standard jet dye bath which requires a high range of temperatures to effectively color fabrics. Dyeing in this manner also involves diffusing compounds within individual fibers; thus, this manner of incorporating dyestuffs and colorants within textile fabrics provides a compatible and effective vehicle for simultaneously introducing triclosan esters within such textile fibers, also. A dye bath application is not required, however, as any procedure which allows contact between a triclosan ester derivative and a fabric at a sufficient temperature and for a sufficient time to effectuate diffusion of the ester within each individual fiber of the fabric is also contemplated within this invention.
Abstract: A method is provided for improving the uptake of a cationic compound onto a polyester article starting material, comprising the steps of: (a) obtaining a polyesterase enzyme; (b) contacting said polyesterase enzyme with said polyester article starting material under conditions and for a time suitable for said polyesterase to produce surface modification of said polyester article starting material and produce a surface modified polyester; (c) contacting said modified polyester article, subsequently or simultaneously with said step (b) with a cationic compound whereby adherence of said cationic compound to said modified polyester is increased compared to said polyester starting material. Also disclosed is a method for increasing the hydrophilicity of a polyester to improve fabric characteristics such as stain resistance, wettability and/or dyeability.
Type:
Grant
Filed:
November 5, 1999
Date of Patent:
July 3, 2001
Assignee:
Genencor International, Inc.
Inventors:
James T. Kellis, Jr., Ayrookaran J. Poulose, Mee-Young Yoon
Abstract: A process for imparting long-lasting antimicrobial properties to fabrics is disclosed which entails the diffusion of triclosan esters within each individual fiber of a textile. One preferred method is performed in a standard jet dye bath which requires a high range of temperatures to effectively color fabrics. Dyeing in this manner also involves diffusing compounds within individual fibers; thus, this manner of incorporating dyestuffs and colorants within textile fabrics provides a compatible and effective vehicle for simultaneously introducing triclosan esters within such textile fibers, also. A dye bath application is not required, however, as any procedure which allows contact between a triclosan ester derivative and a fabric at a sufficient temperature and for a sufficient time to effectuate diffusion of the ester within each individual fiber of the fabric is also contemplated within this invention.