Heterocyclic Nitrogen Compound Patents (Class 8/189)
  • Patent number: 11041063
    Abstract: A forest fire retardant composition is substantially free of ammonium and includes an organophosphate derived from (i) a phosphorylation agent and (ii) an organic molecule comprising at least two hydroxyl groups. The organophosphate may contain at least one phosphate ester bonded to an organic molecule, wherein the organic molecule comprises at least one monomer unit of about 2 to 40 carbon atoms. Preferably, at least 90% of the functional groups of the organophosphate is a phosphate ester group. The composition may also include a salt, including magnesium salt and/or calcium salt. The anion in the salt may be hydroxide, carbonate or phosphate. The salt may be an anhydrous salt, a salt hydrate, or a combination of both. The composition is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.
    Type: Grant
    Filed: September 24, 2020
    Date of Patent: June 22, 2021
    Assignee: FRS Group, LLC
    Inventors: Dennis Hulbert, Robert J. Burnham, Michael S. Schnarr, Gerald Geissler, David W. Wilkening, Joseph McLellan
  • Publication number: 20120240345
    Abstract: Methods of treating fabrics using sol-gel halamine chemistry to impart antimicrobial properties thereto are described, as well as fabrics produced by the described methods. In one embodiment, the antimicrobial fabrics may be used to fabricate antimicrobial divider curtains for use in hospitals and medical facilities.
    Type: Application
    Filed: March 23, 2012
    Publication date: September 27, 2012
    Applicant: EASTERN MICHIGAN UNIVERSITY
    Inventors: Subhas GHOSH, Vijaykumar MANNARI
  • Publication number: 20120180229
    Abstract: A method for enzymatic treatment of cellulose-containing textiles by means of a solution that comprises at least one cellulase type, characterized in that before the treatment with the cellulase-containing solution, an aqueous solution having a pH below 7 and containing at least one agent raising the swelling capacity of the solution, preferably a neutral salt solution, is applied to only some areas of the textile.
    Type: Application
    Filed: July 15, 2010
    Publication date: July 19, 2012
    Applicant: UNIVERSITAET INNSBRUCK
    Inventors: Thomas Bechtold, Christian Schimper
  • Patent number: 7615503
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain sterically hindered amine salt compounds. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: November 10, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood, Wanda H. Martin
  • Patent number: 7585333
    Abstract: The present invention relates to a fluorescent whitening agent comprising a mixture of two symmetrically and one asymmetrically substituted triazinylaminostilbene disulphonic acids, certain novel derivatives, a process for their preparations and use of the mixture for whitening synthetic or natural organic materials, especially paper and for the fluorescent whitening and improvement of sun protection factors of textile materials.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: September 8, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Fabienne Cuesta, Ted Deisenroth, Peter Rohringer
  • Publication number: 20090044347
    Abstract: The instant invention relates to a process for the finishing of textiles with a non formaldehyde cross-linking agent based on 2-imidazolidinones wherein by certain process parameters in drying and curing the undesired yellowing and unpleasant amine smell is avoided.
    Type: Application
    Filed: September 21, 2006
    Publication date: February 19, 2009
    Applicant: CLARIANT INTERNATIONAL LTD
    Inventors: Jean Kyriazis, Georg Lang
  • Patent number: 7192451
    Abstract: A method of treating finished garments comprising cellulosic material so as to cause cross-linking, which comprises the step of treating fabrics with an effective amount of a blocked cross-linking agent for cellulose, the cross-linking agent being thermally activated.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: March 20, 2007
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Shameem Bhatia, Robert John Carswell, Paul Johnathon Evans, Paul Hugh Findlay
  • Patent number: 6890454
    Abstract: The invention relates to an optical brightener mixture (W) comprising optical brighteners (A) of formula (Ia), and (B) of formula (Ib) and optionally (C) of formula (Ic) as defined herein, their concentrated aqueous solutions (S), their production and their use.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: May 10, 2005
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 6824645
    Abstract: The present invention relates to a cellulose-containing fibrous material, wherein hydroxy groups were oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups, a paper or nonwoven (product) made therefrom, in particular tissue (products) and a process for their manufacture. The paper or nonwoven (products) of the invention display excellent strength properties.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: November 30, 2004
    Assignees: SCA Hygiene Products GmbH, SCA Hygiene Products Zeist B.V.
    Inventors: Thomas Jaschinski, Susanna Gunnars, Arie Cornelis Besemer, Petter Bragd, Jan Matthijs Jetten, Ronald Van Den Dool, Willem Van Hartingsveldt
  • Patent number: 6793686
    Abstract: This invention relates to a finishing process for cellulosic textiles which provides a textile having a desirable combination of inherent durable press properties, improved moisture content and improved wicking properties.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: September 21, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: A. Levent Cimecioglu, Klein A. Rodrigues
  • Patent number: 6770287
    Abstract: The present invention provides, inter alia, durable and renewable biocidal wooden materials for safe food contact items, such as cutting boards and containers, to be used in home kitchens and the food processing industries. The biocidal food contact surfaces of the present invention reduce and eliminate cross-contamination of diseases and make the surfaces or wood cutting boards safer to use. The biocidal materials inactivate any microorganisms that are deposited and prevent the materials from building up biofilms.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: August 3, 2004
    Assignee: The Regents of the University of California
    Inventors: Gang Sun, Xiangjing Xu, Dean Cliver
  • Patent number: 6695950
    Abstract: Paper comprising aldehyde modified cellulose pulp having selected aldehyde content. Another embodiment involves a method of preparing celullose aldehydes using selective oxidation with a limited amount of oxidant and a nitroxyl radical mediator and defined reaction conditions to provide oxidized cellulose material with effective aldehyde content making it particularly suitable for use in making paper with desirable wet strength, temporary wet strength and dry strength properties, including compressive strength and resistance.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: February 24, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: A. Levent Cimecioglu, Danielle E. Harkins, Michele Merrette, Robert D. Rossi
  • Patent number: 6679922
    Abstract: The present invention provides methods for preparing an article capable of detoxifying a pesticide, such as textiles, comprising: (a) immersing the article in an aqueous treating solution which comprises a catalyst, a wetting agent and a heterocyclic amine; and (b) treating the article with a halogenated aqueous solution, thereby rendering the article capable of detoxifying a pesticide.
    Type: Grant
    Filed: August 23, 2000
    Date of Patent: January 20, 2004
    Assignee: The Regents of the University of California
    Inventors: Gang Sun, Louise L. Ko, Takayuki Shibamoto
  • Patent number: 6620208
    Abstract: A modified polyamide polymer having a high amino end group content, with more than 30 percent of the amino end groups being secondary or tertiary amine, dramatically improves the dye bleed performance. The modified polyamide may be prepared by polymerization of polyamide-forming monomers in the presence of a carboxylic acid and a hindered piperidine derivative in amounts sufficient to achieve the high amino end group content.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: September 16, 2003
    Assignee: Honeywell International Inc.
    Inventors: Ulrike Breiner, Dean R. Gadoury, Harry Y. Hu, Theodore G. Karageorgiou
  • Patent number: 6241783
    Abstract: Improved methods for durable and regenerable antimicrobial finishing of fabrics are disclosed. In certain embodiments, the methods reduce the amount of free-formaldehyde released during processing by using a formaldehyde scavenger such as a polyol. The improved process imparts regenerable antimicrobial functions to cellulose articles including textiles, papers, wood pulp, and any cellulose-containing materials. The treated product acquire antimicrobial properties after being treated with a halogenated solution.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: June 5, 2001
    Assignee: The Regents of the University of California
    Inventor: Gang Sun
  • Patent number: 6228126
    Abstract: Paper comprising aldehyde modified cellulose pulp having selected aldehyde content. Another embodiment involves a method of preparing celullose aldehydes using selective oxidation with a limited amount of oxidant and a nitroxyl radical mediator and defined reaction conditions to provide oxidized cellulose material with effective aldehyde content making it particularly suitable for use in making paper with desirable wet strength, temporary wet strength and dry strength properties.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: May 8, 2001
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: A. Levent Cimecioglu, Danielle E. Harkins
  • Publication number: 20010000085
    Abstract: Improved methods for durable and regenerable antimicrobial finishing of fabrics are disclosed. In certain embodiments, the methods reduce the amount of free-formaldehyde released during processing by using a formaldehyde scavenger such as a polyol. The improved process imparts regenerable antimicrobial functions to cellulose articles including textiles, papers, wood pulp, and any cellulose-containing materials. The treated product acquire antimicrobial properties after being treated with a halogenated solution.
    Type: Application
    Filed: November 30, 2000
    Publication date: April 5, 2001
    Inventor: Gang Sun
  • Patent number: 6153762
    Abstract: Bridged, methylolated bis-4,5-dihydroxyimidazolidin-2-ones conforming to the formula 1 ##STR1## where X=(CH.sub.2).sub.n where n=2, 3, 4, 5, 7, 8, 9 or 10, branched or cyclic alkyl, each with or without hetero atoms such as O,S, N, P in the alkyl chain,CH.sub.2 CH.sub.2 (--OCH.sub.2 CH.sub.2).sub.m,CH.sub.2 CH.sub.2 CH.sub.2 (--OCH.sub.2 CH.sub.2 CH.sub.2).sub.m,CH.sub.2 CH.sub.2 CH.sub.2 (--OCH.sub.2 CH.sub.2).sub.m OCH.sub.2 CH.sub.2 CH.sub.2),CH.sub.2 CH.sub.2 (--OCH.sub.2 CH.sub.2 CH.sub.2).sub.m OCH.sub.2 CH.sub.2,CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 (--OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2).sub.m,CH.sub.2 C(CH.sub.3)H(--OCH.sub.2 C(CH.sub.3)H).sub.m orCH.sub.2 CH.sub.2 CH.sub.2 (--OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2).sub.m OCH.sub.2 CH.sub.2 CH.sub.2,where m=0-7,andR.sup.1,R.sup.2 =H and/or CH.sub.2 OH, are prepared in one or two stages, the one-stage process also providing those where X=(CH.sub.2).sub.6, and are useful in textile finishing.
    Type: Grant
    Filed: February 5, 1999
    Date of Patent: November 28, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Pia Hois, Jurgen Reichert
  • Patent number: 6077319
    Abstract: The present invention provides durable and regenerable microbiocidal textiles and methods for preparing same. Such textiles can be readily prepared using a wet finishing process to covalently attach a hetercyclic N-halamine to a cellulose based material or other polymeric material. Once prepared, the textiles of the present invention have a broad spectrum of biocidal activity against pathogenic microorganisms. Moreover, the biocidal activity of such textiles can be regenerated by washing with a halogenated solution.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: June 20, 2000
    Assignee: The Regents of The University of California
    Inventors: Gang Sun, Xiangjing Xu
  • Patent number: 6048927
    Abstract: A method for forming a fiber treating composition comprising contacting an aminofunctional polysiloxane comprising at least one aminofunctional siloxy unit with a mixture comprising a lactone and an alkylsulfate of benzimidazole thereby effecting formation of an amide-functional polysiloxane in admixture with the alkylsulfate of benzimidazole. The composition formed by the method is particularly useful for treating textiles such as cotton and cotton-synthetic blends to provide good softness and water absorbency and improved whiteness and treatment durability.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: April 11, 2000
    Assignee: Dow Corning Corporation
    Inventor: Howard Edwin Griffin
  • Patent number: 6045587
    Abstract: A method of reducing color and polymerization decay of cellulose viscose includes the step of permeating a 1,3-phenylene-bis 2-oxazoline as a polymerization anti-decay additive during dissolving a cellulose in water and a solvent to form a cellulose viscose, so as to reduce the color and the polymerization decay of the cellulose viscose.
    Type: Grant
    Filed: May 9, 1998
    Date of Patent: April 4, 2000
    Assignee: Acelon Chemical and Fiber Corporation
    Inventors: Meng-Song Cheng, Kun Shan Huang, J. H. Tsai
  • Patent number: 6042615
    Abstract: The invention relates to an indigo-dyed fabric which comprises at least one organopolysiloxane and at least one alkyl polyglycoside.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: March 28, 2000
    Assignee: Wacker-Chemie GmbH
    Inventors: Peter Habereder, Martina Obenhuber, Michael Geck
  • Patent number: 5965466
    Abstract: A method for imparting permanent press properties to a textile containing cellulose fibers. The method involves applying an aqueous solution of a (hydroxyalkyl)urea and/or a .beta.-hydroxyalkyl amide crosslinking agent to a textile, and heating the textile at a sufficient temperature for a sufficient time to react the crosslinking agent with the textile wherein water is removed from the textile, to impart permanent press properties to the textile. The crosslinking agent is free of formaldehyde. The method of the present invention provides permanent press properties to textiles treated therewith and increases the resistance of such textiles to future laundering abrasion. Such treated textiles display a significant reduction in wrinkles compared with nontreated textiles. Moreover, the treated textiles have a tactile sensation of feeling soft and retain their smoothness after laundering.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: October 12, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Klein A. Rodrigues, Michael C. Hazlewood
  • Patent number: 5948120
    Abstract: A process for instilling cellulosic garments with a worn and rumpled appearance without the use of fabric degrading chemicals or device, said process including treating the garments with a casting composition and curing while the garments are positioned on a support means.
    Type: Grant
    Filed: November 3, 1998
    Date of Patent: September 7, 1999
    Assignee: Sights Denim Systems, Inc.
    Inventors: James Barton Sights, Shane Smithhart, Richard Gaines, Robin Jourdan
  • Patent number: 5910622
    Abstract: Method for treating fibrous cellulosic materials using an aqueous cationic treating solution containing a cyclic polyhydroxy compound and choline chloride, by which dye uptake of the material, and the environmental effects of the subsequent dyeing process are improved.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: June 8, 1999
    Assignee: DCV, Inc.
    Inventor: George L. Brodmann
  • Patent number: 5882357
    Abstract: The present invention provides, inter alia, durable and regenerable microbiocidal textiles and methods for preparing same. Such textiles can be readily prepared using a wet finishing process to covalently attach a hetercyclic N-halamine to a cellulose based material or other polymeric material. Once prepared, the textiles of the present invention have a broad spectrum of biocidal activity against pathogenic microorganisms. Moreover, the biocidal activity of such textiles can be regenerated by washing with a halogenated solution.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: March 16, 1999
    Assignee: The Regents of The University of California
    Inventors: Gang Sun, Xiangjing Xu
  • Patent number: 5882356
    Abstract: The fibrillation tendency of solvent-spun cellulose fiber is reduced by treating the previously dried fiber with a chemical reagent containing at least two functional groups which are reactive with cellulose and which are electrophilic carbon--carbon double bonds, particularly vinyl sulfone groups, or precursors thereof or electrophilic three-membered heterocyclic rings or precursors thereof. The chemical reagent is preferably colorless and is preferably applied to the fiber from aqueous solution. The fiber may be contained in a woven or knotted fabric.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: March 16, 1999
    Assignee: Courtaulds Fibres (Holdings) Limited
    Inventor: Christopher David Potter
  • Patent number: 5879410
    Abstract: A process for resin finishing textile containing cellulosic fiber comprises the steps of using a resin finishing agent chiefly containing a cellulose-reactive N-methylol compound having two or more functional groups and a reaction catalyst, mainly reacting only one functional group of the cellulose-reactive N-methylol compound with cellulose, water washing, again imparting reaction catalyst, drying, garment making, and heat treating. The process eliminates the conventional postcuring method drawbacks of loss of color fastness and discoloration owing to dye decomposition and formaldehyde increase by unreacted resin and residual reaction catalyst during long storage before heat treatment, and simultaneously achieves high crease-resistant property, shrink resistance, good feeling, excellent pleating property, and anti-puckering property.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: March 9, 1999
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Yuichi Yanai, Masayoshi Oba, Yasushi Takagi, Tadashi Isogai
  • Patent number: 5873909
    Abstract: The application of a treating solution containing polyhydroxy compound and choline chloride to a fibrous cellulosic material is made more uniform and reproducible by including in the treating solution a colorizing amount of a fugitive tint, by which the uniformity of the application can be observed and corrected by appropriate changes to the operating variables.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: February 23, 1999
    Assignee: Ducoa, L.P.
    Inventors: George L. Brodmann, John S. Thackrah
  • Patent number: 5837184
    Abstract: Process for the production of cellulose fibres having a reduced tendency to fibrillation, in which a solution of cellulose in a tertiary amine-oxide is spun into fibres and the freshly spun fibres are contacted with a textile agent comprising at least two reactive groups, and are heat-treated, characterized in that the heat treatment is carried out by means of irradiation with electromagnetic waves.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: November 17, 1998
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Heinrich Firgo, Markus Eibl, Johann Schickermuller
  • Patent number: 5779737
    Abstract: The present invention relates to a method for reducing the fibrillation tendency of lyocell fibre. Never-dried fibre is treated by an inorganic alkali solution and a chemical reagent having an average of greater than 2.1 acrylamido groups, and then heated. This method produces cellulose materials with a smooth white appearance resistant to creasing in the wet state.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: July 14, 1998
    Assignee: Courtaulds Fibres Holdings Limited
    Inventors: Christopher David Potter, Peter Dobson
  • Patent number: 5707404
    Abstract: An improved method of treating a fabric comprising the step of contacting a fabric with the cis isomer of a compound having the general formula; ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and each of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 represent branched or straight chain alkyl, carbocyclic or aryl.
    Type: Grant
    Filed: January 14, 1994
    Date of Patent: January 13, 1998
    Assignee: WestPoint Stevens, Inc.
    Inventors: George A. Andrews, Joseph Peterson, William Hough
  • Patent number: 5700295
    Abstract: The invention relates to compounds of formula ##STR1## wherein the variables have the meanings given in the claims. The compounds are suitable for use as UV absorbers for the photochemical stabilisation of undyed, dyed or printed textile fiber materials and for enhancing the sun protection factor thereof.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: December 23, 1997
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Francesco Fuso, Gerhard Reinert
  • Patent number: 5695529
    Abstract: A 5% strength by weight to saturated aqueous solution of N-(2-sulfatoethyl)piperazine sulfate, having a pH of between 4 and 0, can be used to modify fiber material.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: December 9, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Michael Meier, Heinz Georg Kautz
  • Patent number: 5662858
    Abstract: Process for the production of cellulose fibres having a reduced tendency to fibrillation, in which a solution of cellulose in a tertiary amine-oxide is spun into fibres and the freshly spun fibres are contacted with a textile agent comprising at least two reactive groups, and are heat-treated, characterized in that the heat treatment is carried out by means of irradiation with electromagnetic waves.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: September 2, 1997
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Heinrich Firgo, Markus Eibl, Johann Schickermuller
  • Patent number: 5575821
    Abstract: A process for the dyeing of fiber materials with water-soluble anionic dyes, in particular those having a fiber-reactive group, is described, according to which dyeing is carried out using low-electrolyte or entirely electrolyte-free and/or low-alkali or entirely alkali-free dye solutions (dye liquors, printing pastes) and in which a fiber material is used which was modified by means of a saturated straight-chain or branched aliphatic or cycloaliphatic compound which is unsubstituted or substituted by one or more hydroxy groups and contains at least one primary, secondary or tertiary amino group or quaternary ammonium group and at least one hydrolyzable ester group, it also being possible for the aliphatic radical in this compound to be interrupted by one or more hetero groups.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 19, 1996
    Assignee: Hoechst AG
    Inventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
  • Patent number: 5565007
    Abstract: Modified rayon is produced by adding a modifier to a cellulose solution and spinning fibers from the solution, or by adding a modifier to an alkali cellulose solution or material, xanthating and spinning fibers by the viscose spinning process, wherein the modifier is an amine of the formula (1a), (1b), (1c), (1d) or (1e) ##STR1## The modified rayon produced in this way can be dyed with reactive dyes without addition of electrolyte salt or alkali and have significantly more affinity than conventional viscose fibers.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: October 15, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ, Bernd Huber
  • Patent number: 5542954
    Abstract: A process for the production of aminated cotton fibers by subjecting a raw cotton or cotton-polyester mixture to a modification with a saturated aliphatic compound of 3 to 15 carbon atoms which contains at least one primary, secondary, tertiary, or quaternary amino group and at least one hydrolyzable ester group, in which the saturated radical is straight chain, branched, or cyclic, and may be interrupted by one or more hetero groups and may be substituted by one or more hydroxyl groups. The modification occurs simultaneously with scouring, kiering, or dry mercerizing.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: August 6, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ
  • Patent number: 5484457
    Abstract: Process for the continuous production of surface dyeings on cellulose fiber textile materials, characterized in that the textile materials are treated with an aqueous liquor containing at least 5 g/l of benzyl halide quaternized condensation products of precondensates of trialkanolamines and ureas, cyclic carbonates and/or epihalohydrins and/or benzyl chloride quaternized condensation products of piperazine and epichloronydrin, and 0.02 to 1 g/l of a phosphoric triester whose alcohol component has 6 to 18 carbon atoms, the textile materials thus treated are then dyed in another bath with reactive dyes in an aqueous medium and the dyes are fixed by treatment with an alkaline aqueous liquor and the dyeing finished in conventional manner. The individual cellulose fibers of the textile material are not completely penetrated by the dye but, on the contrary, exhibit ring dyeing.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: January 16, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Joerg Schulze, Harald Schlueter, Kurt Bacher, Wolfgang Schrott, Erich Kromm
  • Patent number: 5366591
    Abstract: A method of forming a crosslinked cellulose product is disclosed wherein cellulose fibers are exposed to a solution that includes a catalyst and a crosslinking agent selected from the group consisting of a cyclic N-sulfatoimide or cyclic N-phosphatoimide; a dimethoxyethanal; a mixture of glyoxal and imidazolidone; a diethanol; or a periodate. Specific examples of the crosslinking agents of the present invention include pyridinium N-sulfatosuccinimide; 2,2'-sulfonyldiethanol; sodium periodate; a mixture of dimethoxyethanal and urea; and a mixture of glyoxal and 2-imidazolidone. An acid or base catalyst, as appropriate, may be used with the crosslinking agent to increase the crosslinking reaction rate. In especially preferred embodiments, cellulose fibers are exposed to the crosslinking agent and catalyst, then separated into individualized fibers in a fiberizer.
    Type: Grant
    Filed: January 13, 1992
    Date of Patent: November 22, 1994
    Inventor: Richard A. Jewell
  • Patent number: 5348557
    Abstract: There is described a process for dyeing sheetlike fiber materials, in particular those made of or containing cellulose fibers, with anionic dyes, in particular those having fiber-reactive groups, which comprises applying an alkali-free and preferably low-electrolyte or completely electrolyte-free aqueous solution of the anionic dye by the inkjet printing spray technique to a fiber material which has been pretreated and modified with a compound that contains one or more primary, secondary or tertiary amino groups or quaternary ammonium groups, which amino/ammonium groups may be part of a heterocycle. There is generally no need for an aftertreatment by washing. The costly treatment of wastewaters resulting from the excess dyeing liquors otherwise obtained is eliminated. If fiber-reactive dyes are used, fixation by means of alkali is not necessary; it is generally effected by a short heat treatment.
    Type: Grant
    Filed: September 23, 1993
    Date of Patent: September 20, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas von der Eltz, Andreas Schrell, Werner H. Russ
  • Patent number: 5344620
    Abstract: Water-soluble crosslinkable compounds obtainable by reaction of reactive products which contain halogenohydrin groups and have been obtained by reacting polyamines and epihalogenohydrin or 1,3-dihalogeno-2-hydroxy-propane with inorganic bases and subsequently reacting the resulting products with inorganic acids and/or organic acids, can be used as pigment binders and/or crosslinking agents in textile printing pastes.
    Type: Grant
    Filed: January 16, 1992
    Date of Patent: September 6, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Reiners, Herbert Wigger, Fritz Puchner
  • Patent number: 5310424
    Abstract: A process is disclosed for providing a solvent-spun cellulose fiber with a reduced fibrillation tendency. The fiber is treated with a chemical reagent, preferably substantially colorless, having 2 to 6 functional groups reactive with cellulose, suitably dissolved in an aqueous solution.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: May 10, 1994
    Assignee: Courtaulds PLC
    Inventor: James M. Taylor
  • Patent number: 5242463
    Abstract: Anionically dyeable smooth-dry crosslinked cellulose is produced by modifying cellulose-containing material with the combination of a hydroxyalkylamine or a hydroxyalkyl quaternary ammonium salt, a methylolamide crosslinking agent and one or more reactively inert glycol ether swelling agents. The reaction is typically catalyzed with salts such as zinc nitrate or magnesium chloride used either alone or in conjunction with citric acid. Types of usable anionic dyes include acid, direct, and reactive dyes. The cellulose-containing material may be in the form of fibers, threads, linters, roving, fabrics, yarns, slivers and paper.
    Type: Grant
    Filed: March 6, 1991
    Date of Patent: September 7, 1993
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Eugene J. Blanchard, Robert M. Reinhardt
  • Patent number: 5021263
    Abstract: An aqueous textile treatment agent is based on 1,3-dialkyl-4,5-dihydroxy-imidazolidinones and selected polyhydric alcohols, in particular 1,6-hexanediol or 1,1,1-tris(hydroxymethyl)-ethane and is used for the formaldehyde-free finishing of textile material which consists at least partly of cellulose or regenerated cellulose fibers in order to confer crease and shrink resistance thereon, the textile material so treated being notable for appreciably improved whiteness, compared with the prior art, as well as good crease and shrink resistance.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: June 4, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Xaver Kastele, Michael Bernheim, Erich Rossler
  • Patent number: 5021264
    Abstract: An aqueous textile treatment agent is based on 1,3-dialkyl-4,5-dihydroxy-imidazolidinones and 1,1,1-trimethylolpropane (TMP) and is used for the formaldehyde-free finishing of textile material which consists at least partly of cellulose or regenerated cellulose fibers in order to confer crease and shrink resistance thereon, the textile material so treated being notable for appreciably improved whiteness, compared with the prior art, as well as good crease and shrink resistance.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: June 4, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Xaver Kastele, Michael Bernheim, Erich Rossler
  • Patent number: 4964872
    Abstract: Fabrics, particularly cellulosic fabrics is resin finished with a combination of 1,3-dimethylglyoxalmonourein and trimethylolpropane, whereby the fabrics has improved crease resistance and shrink-proofing and generates no unpleasant odor.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: October 23, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takashi Ikeda, Hisao Takagishi, Terumasa Saka
  • Patent number: 4877413
    Abstract: The invention relates to a process for the end-to-end dyeing of cellulosic materials, or blends that contain cellulose, with direct and/or reactive dyes by the pad dyeing process, which comprises using an aqueous liquor that contains at least one water-soluble direct or reactive dye and at least one water-soluble anionic, colorless organic compound having an affinity factor A, at a concentration of 0.2 to 0.3 g/l, for mercerized cotton of 1.1 to 4, said factor A being the quotient of the concentration of the water-soluble, colorless organic compound in a liquor without addition of dye, before impregnation, divided by the concentration of the water-soluble, colorless organic compound in the residual liquor without dye after impregnation. The process of this invention is suitable for dyeing textile cellulosic materials or blends containing cellulose to give end-to-end dyeings of good fastness properties.
    Type: Grant
    Filed: March 26, 1987
    Date of Patent: October 31, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Marie Sire, Peter Scheibli
  • Patent number: 4865614
    Abstract: The reaction of 2-alkylimidazolines with ethylene oxide or propylene oxide gives quaternary 2-alkyl-2-imidazolinium salts corresponding to the following general formula ##STR1## wherein R.sup.1 represents a straight-chain or branched-chain substituted or unsubstituted alkyl or alkenyl radical containing from 7 to 21 carbon atoms,R.sup.2 represents one of the following radicals ##STR2## R.sup.3 represents hydrogen or methyl, R.sup.4 represents hydrogen or methyl,X.sup..crclbar. represents the anion of a non-oxidizing and non-corrosive inorganic acid or of an organic mono- or polycarboxylic acid,n statistically represents a whole or fraction number of from 1 to 20, andm represents an integer of from 1 to 3, which may be used for softening laundered fabrics.
    Type: Grant
    Filed: June 3, 1987
    Date of Patent: September 12, 1989
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Uwe Ploog, Guenter Uphues
  • Patent number: 4854934
    Abstract: They have the formula: ##STR1## where either R.sub.1 and R.sub.2 are identical and represent --CH.sub.2 R where R=H or a C.sub.1 to C.sub.4 alkyl group or R.sub.1 and R.sub.2 together form the --CH.sub.2 (CR.sub.4 R.sub.4).sub.n --CH.sub.2 group where n=0 or 1, R.sub.4 =H or --CH.sub.3, R.sub.3 =H or --CH.sub.2 R.sub.5 where R.sub.5 =H or a C.sub.1 to C.sub.4 alkyl group. A and A.sub.1 are either identical and represent H or A and A.sub.1 together form an ethylene, trimethylene or --CH(OCH.sub.2 R.sub.6)--CH(OCH.sub.2 R.sub.6)-- radical where R.sub.6 =H or a C.sub.1 to C.sub.4 alkyl group or, when R.sub.3 =H, a 1,2 dihydroxy-ethylene group.They are obtained by reacting a disubstituted ethanal ##STR2## with a urea ANH--CO--NHA, followed if required by etherification with an alcohol R.sub.5 CH.sub.2 OH.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: August 8, 1989
    Assignee: Societe Francaise Hoechst
    Inventors: Didier Wilhelm, Antonio Gelabert, Alain Blanc