Polyster Fiber And Wool Or Silk Fiber Patents (Class 8/533)
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Patent number: 7517369Abstract: The present invention relates to dyes of formula (1) that are soluble in organic solvents, wherein Cat+ is an organic cation, to a process for their preparation and to their use in the production of colored plastics or polymeric color particles, printing colorants, printing pastes and printing inks.Type: GrantFiled: December 19, 2005Date of Patent: April 14, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Thomas Ruch, Ursula Luterbacher
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Patent number: 7279014Abstract: Systems and methods for coloring an article having a polyester portion and at least one portion of a second material where the polyester portion and second material are not blended together in the article. The entire article is dyed a first color, after which the first color is removed from the second material using a post reduction clear process. The entire article is then dyed a second color, which is not absorbed by the polyester portion. The system and process permit the creation of prepared for dye articles having a polyester portion of one color and a portion of a second material that is a different color.Type: GrantFiled: January 6, 2004Date of Patent: October 9, 2007Assignee: Gagwear, Inc.Inventor: John Rusk
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Patent number: 7060807Abstract: Monoazo dyestuffs of the general formula (1) wherein R1, R2, R3 and n are as defined in claim 1, method for their preparation and a method for colouring a synthetic textile material or fiber blend thereof using such dyestuffs.Type: GrantFiled: September 22, 2004Date of Patent: June 13, 2006Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventor: Kiyoshi Himeno
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Patent number: 6802873Abstract: The invention relates to a method for producing dyed textile materials consisting of polyester and polyamide. The textile material is dyed by means of pigments or a disperse dye that stains polyester. Surplus dye is removed. The polyamide portion is dyed using vat dyes, leuco vat dyes, sulphide dyes or soluble sulphide dyes. Said dyes are vatted if this is required for obtaining a solubility and are oxidatively converted into the real dyes after attaching.Type: GrantFiled: July 31, 2002Date of Patent: October 12, 2004Assignee: Carl Freudenberg KGInventors: Heike Bartl, Kurt Jörder
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Patent number: 6641620Abstract: A dye mixture comprises: a) at least one pyrroline type dye of formula (I) wherein R1 is H, C1-20alkyl or C2-20alkenyl; and D is aryl; and b) at least one anthraquinone type dye of formula (II), wherein RB is (CH2)nORB1; RB1 is C1-6alkyl or C1-6alkoxy-C1-6alkyl; n is 1-6; and ZB is O or NH.Type: GrantFiled: April 13, 2001Date of Patent: November 4, 2003Assignee: BASF AktiengesellschaftInventors: Alan Thomas Leaver, David Brierley, James Franklin Bullock
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Patent number: 6589296Abstract: A dye mixture comprises (A) at least one monoazo dye of formula (I) wherein XA is Cl, Br, I, CN or NO2; RA is C1-4alkyl or NHCOQ, where Q is C1-4alkyl; and each of RA1 and RA2, independently, is C1-4alkyl, C2-4akenyl, C1-4alkoxy-C1-4alkyl, aryl-C1-4 alkyl or aryloxy-C1-4alkyl; and (B) at least one pyrroline type dye of formula (II) wherein RB1 is H, C1-20alkyl or C2-20alkenyl; and D is aryl.Type: GrantFiled: November 30, 2000Date of Patent: July 8, 2003Assignee: BASF AktiengesellschaftInventors: Alan Thomas Leaver, David Brierley
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Patent number: 6562082Abstract: A dye mixture comprises (A) at least one dye of formula (I) wherein X is Cl, Br or I; Q is C1-4alkyl; and each of R1 and R2 independently, is C1-4alkyl or C1-4alkenyl; and (B) at least one dye of formula (II) wherein Q1 is C1-4alkyl; and each of R1 and R2 independently, is C1-4alkyl or C1-4alkenyl.Type: GrantFiled: November 1, 2000Date of Patent: May 13, 2003Assignee: BASF AktiengesellschaftInventors: Alan Thomas Leaver, David Brierley
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Patent number: 6527815Abstract: Textiles made of synthetic fibers and synthetic fiber blended fabrics are constructed in the form of a garment then dyed while avoiding setting permanent creases and permanent wrinkles in the garment. The process includes selecting a synthetic or synthetic blended fabric for the dyeing process by determining the fabric's shrinkage in the warp and fill directions, for instance no greater than 6%, constructing a garment from the fabric selected, then dyeing the constructed garment in an aqueous dyebath at a temperature in the range of 220 to 260° F. for a time sufficient to achieve a desired shade and levelness of color followed by drying and optionally pressing the dyed garment.Type: GrantFiled: September 13, 2000Date of Patent: March 4, 2003Assignee: Burlington Industries, Inc.Inventors: Katherine T. Bryant, John E. Newbern, Earl E. Bradsher, III, Terry L. Currans, G. Lewis Best, III, Ashutosh Karnik, John W. McAnulty
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Publication number: 20010054209Abstract: A method for dyeing cellulosic materials with reactive dye by pretreating the fabric with a polycationic polymeric agent which is desirably also polynucleophilic is disclosed. The agent can be a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine, particularly one including nucleophilic sites such as primary amino groups, e.g. polyallylamine/DADMAC copolymers and polyvinylpyridines quaternisied with w-aminoalkyl groups. The dyes can react with the nucleophilic centres so dyebath exhaustion can be driven by dye fixation rather than substantivity to the substrate. The need to use of salts to drive substantivity can be obviated and post dyeing washing to remove unreacted/hydrolysed dye is much simplified. Material dyed by the method has the good wash fastness properties of materials dyed using reactive dyes. A wide variety of cellulosic substrates can be dyed including lyocell fibre materials and blend/union materials with polyamides.Type: ApplicationFiled: August 23, 1999Publication date: December 27, 2001Inventors: GEOFFREY WILLIAM COLLINS, STEPHEN MARTIN BURKINSHAW, ROY GORDON
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Patent number: 6121352Abstract: The present invention relates to dye mixtures comprising at least one compound of the formula (I) ##STR1## and at least one compound of the formula (II) ##STR2## where the substituents are each as defined in the description part, which are highly useful for dyeing and printing hydrophobic synthetic material.Type: GrantFiled: March 18, 1999Date of Patent: September 19, 2000Assignee: Dystar Textifarben GmbH & Co.Inventors: Manfred Hoppe, Kiyoshi Himeno, Ryouichi Sekioka
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Patent number: 6042616Abstract: A method for finishing a cellulose fiber-containing textile fabric comprises treating a cellulose fiber-containing textile fabric with liquid ammonia, applying a resin finishing agent to said fabric, subjecting subsequently to either or both of a hot calendering treatment and a heat treatment, and finally treating the resultant fabric with hot water. The resultant fabric keeps its shape stability including a crease or shrink resistance when washed, without involving any problem on residual formaldehyde.Type: GrantFiled: September 8, 1998Date of Patent: March 28, 2000Assignee: Nisshinbo Industries, Inc.Inventors: Yuichi Yanai, Masayoshi Oba, Kazuhiko Ichimura, Yasushi Takagi, Kazuhiko Harada
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Patent number: 6030419Abstract: A process is described for dyeing polyester-containing fibre materials with disperse dyes, which comprises dyeing the polyester-containing fibre materials by a high-temperature dyeing process with a liquor comprising at least one disperse dye and at least one diffusion accelerator selected from the group of the aliphatic glycol ether derivatives.Type: GrantFiled: September 29, 1998Date of Patent: February 29, 2000Assignee: Ciba Specialty Chemicals CorporationInventor: Ulrich Strahm
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Patent number: 5938796Abstract: Cellullosic textile materials are dyed by a pad or spraying process using a solution which contains 5-100 g/l of inorganic polyphosphate and has a pH of 10-13.5.Type: GrantFiled: May 8, 1998Date of Patent: August 17, 1999Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Daniele Negri, Andreas Schrell
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Patent number: 5910624Abstract: Disperse Dyestuff Mixtures comprising C.I. Disperse Red 82 of the formula (I) ##STR1## and one or more dyestuffs which differ therefrom, of the formula (II) ##STR2## wherein D denotes the radical of a diazo component of the formula ##STR3## or D denotes the radical of a diazo component from the group consisting of 5,6-dichlorobenzothiazol-2-yl, 6,7-dichlorobenzothiazol-2-yl, 6-nitro-benzothiazol-2-yl or 5-nitrothiazol-2-yl, and the other substituents have the meaning given in the description,are stable to spray-drying and have outstanding use properties, in particular in the dyeing of hydrophobic fiber materials.Type: GrantFiled: August 27, 1997Date of Patent: June 8, 1999Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Klaus-Wilfried Wanken, Karl-Ulrich Buhler
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Patent number: 5902356Abstract: The present invention relates to liquid or pulverulent textile dye preparations including one or more dispersants based on an alkoxylated and carboxylic-esterified castor oil of the general formula I ##STR1## where A, X.sup.1, X.sup.2, Z.sup.1, Z.sup.2, Z.sup.3, n.sup.1 and n.sup.2 are each as defined in Claim 1.Type: GrantFiled: July 3, 1997Date of Patent: May 11, 1999Assignee: DyStar Japan Ltd.Inventors: Ulrich Buhler, Hubert Kruse, Rainer Az
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Patent number: 5865857Abstract: A dye of Formula (1): ##STR1## wherein: D is a group of Formula (2): ##STR2## or a group of Formula (3): ##STR3## or a group of Formula (4): ##STR4## The variables are defined in the disclosures. The dyes and dye mixtures produce blue to green shades on synthetic textile materials such as polyester which have good build up and good light- and wet-fastness.Type: GrantFiled: June 19, 1997Date of Patent: February 2, 1999Assignee: Zeneca LimitedInventors: Denise Cavanagh, Mark Robert James, Barry Huston Meyrick, Paul Wight
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Patent number: 5824117Abstract: The present invention relates to the dyestuff of the formula I ##STR1## modifications of this dyestuff which are stable during dyeing, processes for the preparation thereof and their use for dyeing and printing synthetic fiber materials.Type: GrantFiled: June 28, 1996Date of Patent: October 20, 1998Assignee: Dystar Japan Ltd.Inventors: Ulrich Buhler, Jurgen Kuhlwein, Hubert Kruse
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Patent number: 5759211Abstract: A process for colouring a synthetic textile material or fibre blend thereof which comprises applying to the synthetic textile material a compound of Formula (1): ##STR1## wherein: Ring A and Ring D are optionally substituted and at least one of Ring A or Ring D carries at least one --SO.sub.2 F groupexcept for2-?(9,10-dihydro-9,10-dioxo-1-anthracenyl)amino!ethanesulphonylfluoride,2-?(9,10-dihydro-9,10-dioxo-2-anthracenyl)amino!ethanesulphonylfluoride,2,2'-?(9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diimino!bisethane sulphonylfluoride,2,2'-?(9,10-dihydro-9,10-dioxo-1,5-anthracenediyl)diimino!bisethane sulphonylfluoride,2,2'-?(9,10-dihydro-2-methoxy-9,10-dioxo-1,4-anthracenediyl)diimino) bisethanesulphonylfluoride,2-?(4-(benzoylamino)-9,10-dihydro-9,10-dioxo-1-anthracenyl!amino!ethanesulp honylfluoride,2-?(9,10-dihydro-4-(methylamino)-9,10-dioxo-1-anthracenyl!amino!ethane sulphonylfluoride.Type: GrantFiled: August 12, 1996Date of Patent: June 2, 1998Assignee: Zeneca LimitedInventor: Nigel Hall
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Patent number: 5660598Abstract: A dye of Formula (1): ##STR1## wherein: D is a group of Formula (2): ##STR2## or a group of Formula (3): ##STR3## or a group of Formula (4): ##STR4## The variables are defined in the specification. The dyes and dye mixtures produce blue to green shades on synthetic textile materials such as polyester which have good build up and good light- and wet-fastness.Type: GrantFiled: May 3, 1995Date of Patent: August 26, 1997Assignee: Zeneca LimitedInventors: Denise Cavanagh, Mark Robert James, Barry Huston Meyrick, Paul Wight
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Patent number: 5639282Abstract: The present invention relates to a process for dyeing polyester or polyester-containing textile materials at pH 8 to pH 11, characterized in that one or more monoazo dyestuffs of the general formula I ##STR1## wherein D is a substituted phenyl radical of the general formula II ##STR2## or 5,6-dichlorobenzothiazol-2-yl6,7-dichlorobenzothiazol-2-yl6-chlorobenzothiazol-2-yl5-nitrobenzothiazol-2-yl6-nitrobenzothiazol-2-yl6-methylsulphonylbenzothiazol-2-yl or5-nitrobenzoisothiazol-3-ylandx.sup.1, x.sup.2, x.sup.3, x.sup.4, y.sup.1, y.sup.2, y.sup.3, r.sup.1, r.sup.2 and r.sup.3 are as defined in claim 1, are employed.Type: GrantFiled: December 14, 1995Date of Patent: June 17, 1997Assignee: Dystar Japan, Ltd.Inventor: Ulrich Buhler
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Patent number: 5611820Abstract: The invention relates to a process for dyeing wool-containing fibre materials with anionic dyes, which comprises dyeing said materials in the presence of a wool protective agent containing at least one compound of formula ##STR1## wherein the variables are as claimed in the claims. Rubfast level dyeings with no impairment of wool quality are obtainable by said process.Type: GrantFiled: November 6, 1995Date of Patent: March 18, 1997Assignee: Ciba-Geigy CorporationInventor: Philippe Ouziel
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Patent number: 5599354Abstract: The invention relates to dye mixtures consisting of(a) 0-100% by weight of at least one dye mixture comprising a compound of the formula ##STR1## and a compound of the formula ##STR2## (b) 0-100% by weight of at least one dye mixture comprising a compound of the formula ##STR3## and a compound of the formula ##STR4## in which the variables are as defined in the claims and the sum of (a) and (b) is 100% by weight. The dye mixtures according to the invention are suitable for dyeing or printing hydroxyl-containing or nitrogen-containing fibre materials and give dyeings or prints having good all-round fastness properties.Type: GrantFiled: February 5, 1996Date of Patent: February 4, 1997Assignee: Ciba-Geigy CorporationInventors: Jean-Marie Adam, Peter Sutter, Francine Casi
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Patent number: 5487936Abstract: A woven fabric is made of warp threads and weft threads. The warp threads have a different composition than the weft threads and at least one of the warp threads or weft threads is comprised of a multifilament fibre. The fabric is colored after it is manufactured by preferentially coloring the warp threads with a dyestuff which is preferentially taken up by the warp threads, but substantially repelled by the weft threads, and a different dyestuff which is preferentially taken up by the weft threads and substantially repelled by the warp threads. The resulting fabric can exhibit the shot silk effect.Type: GrantFiled: March 24, 1994Date of Patent: January 30, 1996Assignee: Collier Campbell Ltd.Inventor: Susan J. Collier
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Patent number: 5460630Abstract: Described is a process for dyeing fibrous materials made of or containing wool with anionic dyes, which comprises dyeing these materials in the presence of a wool preservative comprising at least one compound of the formulaR--O--CH.sub.2 --CH(OH)--CH.sub.2 --Y (1),where the variables are each as defined in the claims. The process makes available rub-fast level dyeings without deterioration in the quality of the wool.Type: GrantFiled: July 21, 1994Date of Patent: October 24, 1995Assignee: Ciba-Geigy CorporationInventors: Philippe Ouziel, Martin Kuhn
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Patent number: 5435807Abstract: A process for dyeing wool-containing fibre materials with anionic dyes, which comprises dyeing said materials in the presence of a wool protective agent which is a reaction product of an epihalohydrin and an amine of formulaR--NH.sub.2 (1),wherein R is as defined in the claims. Rubfast, level dyeings without impairment of wool quality are obtainable by the process.Type: GrantFiled: September 24, 1993Date of Patent: July 25, 1995Assignee: Ciba-Geigy CorporationInventor: Martin Kuhn
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Patent number: 5431699Abstract: Dye mixtures containa) one or more azo dyes of the formula I ##STR1## where Y.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted C.sub.1 -C.sub.8 -alkanoylamino or C.sub.3 - or C.sub.4 -alkenylamino orY.sup.2 and Y.sup.3 are each hydrogen or unsubstituted or substituted C.sub.1 -C.sub.6 -alkylb) the azo dye of the formula II ##STR2## where L is allyl which may be partially replaced by or may furthermore be hydrogen andc) optionally, an azo dye of the formula III and/or IV as described in the specification.Type: GrantFiled: January 28, 1994Date of Patent: July 11, 1995Assignee: BASF AktiengesellschaftInventors: Arno Lange, Uwe Nahr, Walter Sieber, Volker Walther
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Patent number: 5425785Abstract: The present invention relates to a process for dyeing polyester or polyester-containing textile materials at pH 8 to pH 11 with one or more monoazo dyestuffs of the general formula I ##STR1## in which A, R and X.sup.1 to X.sup.3 are as defined in claim 1.Type: GrantFiled: August 17, 1994Date of Patent: June 20, 1995Assignee: Hoechst Mitsubishi Kasei Co.Inventors: Ulrich Buhler, Ralf Zerrer
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Patent number: 5368612Abstract: Water-insoluble naphthalic acid imide dyestuffs of the following formula: ##STR1## wherein D is ##STR2## wherein R.sup.1 is C.sub.1 -C.sub.8 alkyl which may be substituted, R.sup.2 is hydrogen, halogen, lower alkyl, lower alkoxy or cyano, X is oxygen or sulfur, and m is 0 or 1; A is phenylene, alkylene, aralkylene or --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 --; B is oxygen, sulfur or ##STR3## wherein R.sup.3 is hydrogen or lower alkyl; Y is a 6-membered nitrogen-containing heterocyclic ring having at least one active halogen atom; and n is 0 or 1.Type: GrantFiled: August 2, 1993Date of Patent: November 29, 1994Assignee: Hoechst Mitsubhishi Kasei Co., Ltd.Inventors: Kiyoshi Himeno, Toshio Hihara
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Patent number: 5330543Abstract: Azo dyes having the formula ##STR1## wherein the substituents are as defined in the specification and are useful for dyeing or printing textile materials.Type: GrantFiled: October 27, 1993Date of Patent: July 19, 1994Assignee: BASF AktiengesellschaftInventors: Guenter Hansen, Gunther Lamm, Hermann Loeffler, Helmut Reichelt, Helmut Degen, Arno Lange, Clemens Grund
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Patent number: 5288680Abstract: The present invention relates to a process for the preparation of finished dyeings of high fastness to thermomigration on fibre materials consisting completely or partly of polyester, characterized in that the material is dyed with one or more dyestuffs of the general formula I ##STR1## wherein R denotes linear (C.sub.1 -C.sub.3)-alkyl or (C.sub.3 -C.sub.6)-alkyl which is interrupted by an oxygen atom andR.sup.1 denotes (C.sub.1 -C.sub.4)-alkyl,and the dyeing thus obtained is then finished.Type: GrantFiled: May 22, 1992Date of Patent: February 22, 1994Assignee: Cassella AktiengesellschaftInventors: Rudolf Binder, Ulrich Buhler, Friedrich Schophoff, Margareta Boos, Reinhard Kuhn
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Patent number: 5279621Abstract: The present invention relates to a process for the HT dyeing of polyester or polyester-containing textile materials at pH 8 to pH 11, characterized in that one or more monoazo dyes are used of the general formula I ##STR1## wherein X, Y, R.sup.1 and R.sup.2 are each as defined in Claim 1.Type: GrantFiled: February 18, 1992Date of Patent: January 18, 1994Assignee: Cassella AGInventor: Ulrich Buhler
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Patent number: 5218095Abstract: The novel dispersion dyes of the formula ##STR1## in which R.sub.1 is a C.sub.2 -C.sub.8 alkyl radical which is substituted by hydroxyl, halogen, a radical --X--C.sub.1 -C.sub.8 alkyl or --X--phenyl, in which X is a bridging member of the formula --O--, ##STR2## and R.sub.2 and R.sub.3, independently of one another, are each an unsubstituted C.sub.1 -C.sub.8 alkyl radical or a C.sub.2 -C.sub.8 alkyl radical which is substituted as mentioned for R.sub.1, or in which R.sub.1 and R.sub.2 together with the nitrogen atom linking them are a heterocyclic radical, are suitable in particular for the dyeing of polyester textile material.Type: GrantFiled: February 15, 1991Date of Patent: June 8, 1993Assignee: Ciba-Geigy CorporationInventor: Martin Trottmann
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Patent number: 5207799Abstract: A process is described for fibre- and surface-level dyeing of wool and blends thereof with other fibers using a compound of formula (1) ##STR1## in which n is 0 or 1, and if n is 1, A is a radical of the formula ##STR2## and B is an alkylene or alkenylene group or a direct bond, or if n is zero, A is a compound of the formula ##STR3## Fibre- and surface-level dyeings, in particular in light to medium color shades are obtained by the dyeing process according to the invention. The dyeing aid according to this invention can be used to substitute formaldehyde containing wool dyeing aids.Type: GrantFiled: August 27, 1991Date of Patent: May 4, 1993Assignee: Ciba-Geigy CorporationInventors: Gerhard Back, Klaus Hannemann, Josef Koller
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Patent number: 5174791Abstract: Process for dyeing and printing blended fabrics made from polyester and natural fibre materials, characterized in that the dye baths, padding liquors or printing pastes contain compounds of general formula (I). Dye preparations containing one or more compounds of general formula (I).Type: GrantFiled: August 5, 1991Date of Patent: December 29, 1992Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Hubert Kruse, Jurgen Kuhlwein, Willi Steckelberg
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Patent number: 5174792Abstract: The invention relates to mixtures of monoazo dyes, which are characterized in that they consist of one or more dyes of the general formula I ##STR1## and one or more dyes of the general formula II ##STR2## where R.sup.1 is methyl, ethyl, n-propyl or i-propyl,R.sup.2 is ethyl or n-propyl,m is 2 or 3 andn is 1 or 2, with the proviso that m+n is 4,processes for preparing same and the use thereof for dyeing and printing hydrophobic fibre materials and blends thereof with natural fibre materials.Type: GrantFiled: August 12, 1991Date of Patent: December 29, 1992Assignee: Cassella AktiengesellschaftInventors: Hirotsugu Tsumura, Ulrich Buhler, Reinhard Kuhn, Margareta Boos
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Patent number: 5114431Abstract: A disperse dye mixture comprising a red disperse dye of the following formula (A): ##STR1## and at least one red disperse dye of the following formula (B): ##STR2## wherein R.sup.1 is C.sub.2 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy C.sub.2 -C.sub.3 alkyl or C.sub.1 -C.sub.4 alkoxyethoxyethyl, in a weight ratio of (B)/(A) of from 0.1 to 5.Type: GrantFiled: February 12, 1991Date of Patent: May 19, 1992Assignee: Hoechst Mitsubishi Kasei Co., Ltd.Inventors: Riyouichi Sekioka, Kouichi Seto
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Patent number: 5114427Abstract: Method for dyeing of cellulose fibers by means of reactive dyeing agents according to the exhaust method. According to the present method one adds the alkali necessary for the fixation of the dyeing agent continuously or substantially continuously over a predetermined time interval so, that an adding process with predetermined progression is not brought to the end, but after a predetermined time is followed by an addition process with a different progression.Type: GrantFiled: October 11, 1990Date of Patent: May 19, 1992Assignee: Hoechst AktiengesellschaftInventor: Sture Damm
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Patent number: 5102425Abstract: The present invention relates to a process for the dyeing and printing of blended fabrics made of polyester and natural fibre materials, characterized in that the polyester portion of the blended fabric is dyed and printed using one or more disperse dyes of the general formula I ##STR1## in which R is methyl, ethyl or alkyl having 2 or 3 C atoms, which is substituted by alkoxy having 1 to 3 C atoms, andR.sup.1 is alkyl having 1 to 3 atoms.Type: GrantFiled: January 22, 1991Date of Patent: April 7, 1992Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Margareta Boos, Reinhard Kuhn
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Patent number: 5032141Abstract: Method of producing a shot effect in dyed woollen fabrics and items of clothing, using a dyeing method having the following stages: (a) dyeing the products in a rotary vat in a bath of water to which are added, in successive steps and at different, increasing temperatures, firstly a size or glue and secondly a colorant diluted with a dispersing agent, and then cooling the dye bath, draining the dye bath from the dyeing vat, and rinsing the dyed product; (b) placing the product in clean water for a second bath, with the dyeing vat in motion and adding to the second bath in successive steps an elastomer and a catalyst which creates a pH of between 2 and 3 in the bath and activates the elastomer, thus fixing the dye to the body of the product fibers and not to the surface filaments of the fibers, and finally draining the second bath from the dyeing vat, rinsing and drying the dyed products.Type: GrantFiled: April 10, 1990Date of Patent: July 16, 1991Assignee: R. Silli, S.p.A.Inventor: Alessandro Silli
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Patent number: 5019133Abstract: A method for dyeing polyester-containing fibers by using a disperse dye, wherein said dyeing is conducted under an alkaline condition in an aqueous medium in the presence of at least one amino acid member selected from the group consisting of an amino acid, an amino acid derivative having at least one hydrogen atom of its amino group replaced with an organic group, and an alkali metal salt of such an amino acid or amino acid derivative, in the dyeing bath, and a dyeing assistant useful for the method.Type: GrantFiled: November 17, 1989Date of Patent: May 28, 1991Assignee: Mitsubishi Kasei CorporationInventors: Kiyoshi Himeno, Kazuhisa Konishi
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Patent number: 5013328Abstract: A substrate to which a dyestuff or optical brightener has been applied is aftertreated with a cationic or protonatable polymeric Product P selected from:(A) a polymeric reaction product, Product A, of a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups with cyanamide, dicyanamide, guanidine or bisguanidine in which up to 50 mole percent of the cyanamide, dicyanamide, guanidine or bisguanidine may be replaced by a dicarboxylic acid or a mono- or di-ester thereof, with the splitting off ammonia, optionally in the presence of a catalyst; Product A containing at least one free hydrogen atom linked to a nitrogen atom; or(B) the polymeric reaction product, Product B, of Product A with(a) epichlorohydrin or a precursor thereof; or(b) an N-methylol derivative of a urea, melamine, guanamine, triazinone, urone, carbamate or acid amine optionally in the presence of a catalyst for crosslinking N-methylol compounds; or(c) a water-soluble homo- or co-polymer, PrType: GrantFiled: November 15, 1989Date of Patent: May 7, 1991Assignee: Sandoz Ltd.Inventors: Oskar Annen, Bernhard Schlick
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Patent number: 4994089Abstract: The carrier mixture contains N-alkylphthalimides and compounds of the general formula ##STR1## in which R is C.sub.1 -C.sub.7 -alkyl; phenyl, benzyl or phenylethyl, which can be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.3 -alkylcarbonyloxy, hydroxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,m is 0 or 1,n is 0 or 1, m and n not being 0 at the same time.Type: GrantFiled: September 28, 1989Date of Patent: February 19, 1991Assignee: Bayer AktiengesellschaftInventors: Frank Bartkowiak, Hans Schulze, Wolf-Dieter Schroer, Gunther Boehmke, Karlhans Jakobs, Willi Schossler
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Patent number: 4985044Abstract: Since anthraquinonoid disperse dyes of the dark blue and navy region give only a low color strength on synthetic fibers, there was an urgent need for their coloristically advantageous substitution by high performance blue azo dyes which are suitable for being used in the carrier dyeing process.According to the invention, the systematic development of multi-component mixtures based on selected blue azo dyes from the dicyano azo series makes it possible to avoid most of the disadvantages mentioned.Type: GrantFiled: June 7, 1989Date of Patent: January 15, 1991Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Reinhard Kuhn, Ulrich Buhler
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Patent number: 4960435Abstract: A crystalline form of the dye represented by the following formula (1): ##STR1## characterized by an X-ray diffraction pattern having a strong peak at the angle of diffraction (2.theta.) of 23.2.degree. and relatively strong peaks respectively at the angles of diffraction (2.theta.) of 8.3.degree., 12.3.degree., 20.8.degree., 21.9.degree., 25.0.degree., 27.1.degree., 29.2.degree. and 30.8.degree. according to X-ray powder diffractometry through the use of a Cu-K.alpha. line and a process for preparing the same by heat-treating a heat-instable crystalline form of the dye represented by the formula (1) in water, water containing a water-soluble organic solvent, or water containing an anionic or nonionic surfactant at a temperature of 40.degree. C. or above.It withstands dyeing at high temperature, e.g. 130.degree. C. or higher, to provide dyed fibers having excellent fastness properties.Type: GrantFiled: December 5, 1989Date of Patent: October 2, 1990Assignee: Nippon Kayaku Kabushiki KaishaInventors: Mituaki Tunoda, Nobuharu Suzuki
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Patent number: 4881941Abstract: A textile substrate is dyed by immersing it in a gathered configuration into an oil medium containing a dissolved or dispersed dye for a sufficient time to allow the oil medium to come into contact with part but not all of the surface of the substrate and the thus-treated substrate is then preferably immersed in an aqueous medium having another dye dissolved or dispersed therein.Type: GrantFiled: July 12, 1988Date of Patent: November 21, 1989Assignee: Sandoz Ltd.Inventor: Michael W. Dixon
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Patent number: 4872883Abstract: The mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another denote linear or branched alkyl with 1 to 6 carbon atoms and R denotes linear or branched alkyl with 1 to 3 carbon atoms, is outstandingly suitable for dyeing and printing hydrophobic materials a deep blue color.Type: GrantFiled: January 27, 1988Date of Patent: October 10, 1989Assignee: Bayer AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Manfred Hahnke
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Patent number: 4852991Abstract: The invention relates to a process for dyeing synthetic or natural polyamide fibers with anionic dyestuffs, comprising (i) bringing the polyamide fibers into contact with an aqueous dyeing liquor which contains in addition to one or more dyestuffs a cationic dyeing assistant having affinity for anionic polyamide dyestuffs, and dyeing the polyamide fibers at a temperature of from 60.degree. to 105.degree. C., and (ii) adding an anionic dyeing assistant to the dyeing liquor 15 to 60 minutes after reaching the dyeing temperature, to complete the dye exhaustion. Surface and fibre level dyeings with a good dye penetration are thus obtained.Type: GrantFiled: March 3, 1988Date of Patent: August 1, 1989Assignee: Sandoz Ltd.Inventors: Josef Frauenknecht, Dieter Schwer
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Patent number: 4844710Abstract: Aqueous textile assistants of high storage stability and hard water resistance comprising at least (a) a partial phosphoric ester, (b) a nonionic surfactant, (c) an anionic surfactant and (d) an alkali metal hydroxide. They can be used for wetting and deaerating fibre materials.Type: GrantFiled: November 30, 1987Date of Patent: July 4, 1989Assignee: Ciba-Geigy CorporationInventors: Christian Guth, Jorg Haase, Albert Stehlin
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Patent number: 4820312Abstract: Because the high dyeing temperatures employed necessitate the use of formaldehyde as customary wool-protecting agent and because of the resulting sealing problems on jet-dyeing machines, an HT dyeing of polyester fibre/wool blends cannot be carried out without polluting the environment. If, however, to achieve this purpose, lower temperatures are employed and the consequently required carriers are added directly to the dyeing liquor, this in turn gives rise to levelness problems and fastness reductions on the wool portion of the textile material.It has now been found according to the invention that by metering the carrier under isothermal conditions into the dyeing after 10-20 minutes via the gas stream driving the textile material it is possible to obtain a homogeneous distribution thereof and its full effectiveness without fastness losses. The dyeing can be completed 10-30 minutes later. All the advantages of jet dyeing are fully retained in this process.Type: GrantFiled: August 27, 1987Date of Patent: April 11, 1989Assignee: Hoechst AktiengesellschaftInventor: Hans-Ulrich von der Eltz
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Patent number: RE33908Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.Type: GrantFiled: February 19, 1991Date of Patent: May 5, 1992Assignee: Cassella AktiengesellschaftInventors: Horst Tappe, Hubert Kruse, Reinhard Kuhn, Albert Bode, Margareta Boos