Cationic Polymer, E.g., Aminated Polymer Without -coo-, -(o=)s(=o)-, -o (o=)p(=o)-o- Groups, E.g., Polyacrylamide, Etc. Patents (Class 8/554)
-
Patent number: 7060107Abstract: Compositions for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprising, in a dyeing medium, (1) at least one oxidation dye, and (2) a combination comprising at least one cyclohomopolymer of dialkyldiallylammonium and at least one other particular quaternary polyammonium. Processes comprising such oxidation dyeing compositions.Type: GrantFiled: January 2, 2001Date of Patent: June 13, 2006Assignee: L'Oreal S.A.Inventors: Cécile Bebot, Christine Rondeau, François Cottard, Francoise Boudy
-
Patent number: 7048770Abstract: By providing certain quaternary terpolymers as an integral ingredient in hair coloring formulations, substantially improved and enhanced hair conditioning benefits are attained, providing a highly effective, hair coloring composition which also provides conditioning benefits to the hair fibers. In addition, the conditioning benefits and effects are long lasting and capable of being retained by the hair fibers for up to four weeks.Type: GrantFiled: July 21, 2003Date of Patent: May 23, 2006Assignee: Zotos InternationalInventors: Mariana Azizova, Rushi Tasker, Lorraine Takor Oben
-
Patent number: 6997962Abstract: A method for dyeing a cellulosic material, such as cotton or a blend including cotton, in the form of yarn, fabric, or garments, includes: a) preparing a dyebath including particles of indigo and an additive, such as an anionic acrylic copolymer, causing the particles to become charged; b) preparing the cellulosic material by applying an additive, such as a cationic polyamide, forming a substrate with a charge attracting the particles, c) immersing the cellulosic material in the dyebath; d) chemically reducing the particles retained on the cellulosic material to a leuco form; and e) oxidizing the dye material.Type: GrantFiled: February 18, 2004Date of Patent: February 14, 2006Inventor: Melvin Alpert
-
Patent number: 6994734Abstract: An aqueous liquid composition characterized by containing an alkali salt, an alkali metal salt, an alkali earth metal salt or an ammonium salt of a compound represented by the following formula (1). in the form of free acid in an amount of 10–40 mass % and inorganic salt in an amount of 1.1–10 mass % can easily be produced without a desalting process or the like which has been included in a conventional process and it has an excellent storage stability and excellent fluorescent brightening effect.Type: GrantFiled: March 20, 2002Date of Patent: February 7, 2006Assignee: Nippon Kayaku Kabushiki KaishaInventors: Toru Yamaguchi, Nobutaka Yamamoto
-
Patent number: 6858044Abstract: Use of (PA) water-dispersible or colloidally soluble polyamides which contain hydrophilic polyalkylene glycol ether chains in the skeletal structure as wet-acting lubricants in the treatment of textile piece goods in rope or tubular form with a textile treatment agent (T) by exhaust methods from aqueous liquor under conditions which would otherwise in the textile substrate favor the formation of transport folds and/or the occurrence of friction in or on the substrate, particularly as wet-acting lubricants in the dyeing of polyamides in the jet, the corresponding wet-acting lubricants, certain polyamide preparations and certain polyamides, and their production.Type: GrantFiled: September 21, 2000Date of Patent: February 22, 2005Assignee: Clariant Finance (BVI) LimitedInventors: Bernard Danner, Francis Palacin
-
Oxidation dyeing method using N-acetyclysteine as a reducing agent and laccase as an oxidating agent
Patent number: 6840964Abstract: The present invention relates to a method for dyeing keratin fibers especially human keratin fibers such as hair, characterized in that it consists in the following: a dyeing composition (A) is applied to the fibers, whereby said dyeing composition contains at least one oxidation dye precursor in an appropriate medium and optionally one or several couplers in addition to N-acetylcysteine as a reducing agent; the color is revealed in the presence of air in an alkaline, neutral or acidic medium with the aid of laccase, whereby said laccase is incorporated into composition (A) or composition (B); compositions (A) and (B) are immediately mixed before used or applied successively to keratin fibers.Type: GrantFiled: February 24, 2000Date of Patent: January 11, 2005Assignee: L'OrealInventor: Grégory Plos -
Patent number: 6830593Abstract: There is provided a method for preventing or reducing the fading of color on fabric by means of a divalent salt. Compositions which provide care to the color of fabrics and comprising a dye fixing agent and the divalent salt are also herein provided.Type: GrantFiled: February 1, 2001Date of Patent: December 14, 2004Assignee: The Procter & Gamble CompanyInventor: Christian Leo Marie Vermote
-
Patent number: 6692539Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibers, in particular of human keratin fibers and more particularly the hair, containing, in a medium that is suitable for dyeing, at least one oxidation dye, at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, at least one nonionic surfactant and at least one cationic or amphoteric polymer whose cationic charge density is greater than or equal to 2 meq/gram. The invention also relates to the dyeing devices and processes using the composition.Type: GrantFiled: December 20, 2002Date of Patent: February 17, 2004Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
-
Patent number: 6673124Abstract: The invention relates to an oxidation dyeing process for human keratin fibers, which comprises applying to the fibers a dye composition (A) containing, in a medium which is suitable for dyeing, at least one oxidation dye precursor and optionally one or more couplers; developing the color in alkaline, neutral or acidic medium using an oxidizing composition (B) containing an oxidizing agent, at least one of the compositions (A) and (B) also containing an effective amount of at least one cationic amphiphilic polymer chosen from quaternized celluloses modified with groups containing at least one fatty chain, chosen from alkyl, arylalkyl and alkylaryl groups containing at least 8 carbon atoms, or mixtures thereof, and quaternized hydroxyethylcelluloses modified with groups containing at least one fatty chain, chosen from alkyl, arylalkyl and alkylaryl groups containing at least 8 carbon atoms, or mixtures thereof; the compositions (A) and (B) being mixed together immediately before use or applied one after the othType: GrantFiled: March 8, 1999Date of Patent: January 6, 2004Assignee: L'Oreal S.A.Inventors: Florence Laurent, Roland De La Mettrie
-
Publication number: 20030188392Abstract: The invention relates to an oxidation dyeing process for human keratin fibres, which comprises applying to the fibres a dye composition (A) containing, in a medium which is suitable for dyeing, at least one oxidation dye precursor and optionally one or more couplers; developing the colour in alkaline, neutral or acidic medium using an oxidizing composition (B) containing an oxidizing agent, at least one of the compositions (A) and (B) also containing an effective amount of at least one cationic amphiphilic polymer chosen from quaternized celluloses modified with groups containing at least one fatty chain, chosen from alkyl, arylalkyl and alkylaryl groups containing at least 8 carbon atoms, or mixtures thereof, and quaternized hydroxyethylcelluloses modified with groups containing at least one fatty chain, chosen from alkyl, arylalkyl and alkylaryl groups containing at least 8 carbon atoms, or mixtures thereof; the compositions (A) and (B) being mixed together immediately before use or applied one after the otType: ApplicationFiled: March 8, 1999Publication date: October 9, 2003Inventors: FLORENCE LAURENT, ROLAND DE LA METTRIE
-
Patent number: 6602303Abstract: Compositions for oxidation dyeing of keratinous fibers, for example, human keratinous fibers such as hair, further such as human hair, comprising, in a medium suitable for dyeing, at least one oxidation dye, at least one cationic amphiphilic polymer comprising at least one fatty chain, and a combination comprising: (I) at least one compound chosen from oxyalkylenated and glycerolated fatty alcohols and (II) at least one hydroxylated solvent, wherein the hydroxylated solvent may have a molecular weight of less than 250, and wherein the weight ratio of (I) to (II) is greater than 1:1 and dyeing processes and devices, such as kits, comprising such compositions.Type: GrantFiled: August 13, 2001Date of Patent: August 5, 2003Assignee: L'Oreal S.A.Inventors: Florence Laurent, Delphine Allard
-
Patent number: 6592633Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using the composition.Type: GrantFiled: May 25, 1999Date of Patent: July 15, 2003Assignee: L'Oreal S.A.Inventors: Gérard Lang, Jean Cotteret
-
Patent number: 6537333Abstract: A process for dyeing a fibrous substrate which comprises the steps of: providing a fibrous substrate; providing at least one sulfur dye; providing at least one reduction stable direct dye; and applying said reduction stable direct dye and sulfur dye to said fibrous substrate in the presence of a suitable reducing agent. Further, it has been surprising to find that these reduction stable direct dyes can be processed without a sulfur dye present. This results in a process for dyeing a fibrous substrate which comprises the steps of: providing a fibrous substrate; providing a reduction stable direct dye; and applying said reduction stable direct dye to said fibrous substrate in the presence of a suitable reducing agent.Type: GrantFiled: July 3, 2001Date of Patent: March 25, 2003Assignee: Clariant Finance (BVI) LimitedInventors: J. Michael Hipp, Mark S. Carlough, William T. Sherrill, Peter J. V. Stahala
-
Publication number: 20030019053Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, this composition having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using it.Type: ApplicationFiled: April 6, 1999Publication date: January 30, 2003Inventor: CHRISTINE RONDEAU
-
Patent number: 6494924Abstract: The dyes have an average particle size within the range from 5 nm to 1 &mgr;m and a variance of less than 50%. They are especially useful for ink-jet ink preparations.Type: GrantFiled: October 3, 2000Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Helmut Auweter, Heribert Bohn, Robert Heger, Dieter Horn, Bernd Siegel, Karl Siemensmeyer
-
Patent number: 6471730Abstract: The invention concerns a ready-to-use composition for dyeing human keratinous fibers and more particularly human hair, comprising in support suitable for dyeing keratinous fibers: (a) at least an enzyme such as laccase; (b) at least a cationic substantive or particular amphoteric polymer; (c) at least an oxidation coloring agent, as well as the dyeing methods using said composition.Type: GrantFiled: September 11, 2000Date of Patent: October 29, 2002Assignee: L'OrealInventors: Gérard Lang, Jean Cotteret
-
Patent number: 6402791Abstract: The subject of the invention is novel dimethylenedioxybenzenes comprising at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains comprising at least one quaternized saturated ring, and aliphatic chains comprising at least one quaternized unsaturated ring, their use as oxidation dye precursor for the oxidation dyeing of keratinous fibres, dyeing compositions containing them, as well as the oxidation dyeing methods using them.Type: GrantFiled: November 21, 2000Date of Patent: June 11, 2002Assignee: L'Oreal S.A.Inventors: Alain Genet, Alain Lagrange
-
Publication number: 20020046432Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, this composition having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using it.Type: ApplicationFiled: April 6, 1999Publication date: April 25, 2002Inventor: CHRISTINE RONDEAU
-
Publication number: 20010054209Abstract: A method for dyeing cellulosic materials with reactive dye by pretreating the fabric with a polycationic polymeric agent which is desirably also polynucleophilic is disclosed. The agent can be a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine, particularly one including nucleophilic sites such as primary amino groups, e.g. polyallylamine/DADMAC copolymers and polyvinylpyridines quaternisied with w-aminoalkyl groups. The dyes can react with the nucleophilic centres so dyebath exhaustion can be driven by dye fixation rather than substantivity to the substrate. The need to use of salts to drive substantivity can be obviated and post dyeing washing to remove unreacted/hydrolysed dye is much simplified. Material dyed by the method has the good wash fastness properties of materials dyed using reactive dyes. A wide variety of cellulosic substrates can be dyed including lyocell fibre materials and blend/union materials with polyamides.Type: ApplicationFiled: August 23, 1999Publication date: December 27, 2001Inventors: GEOFFREY WILLIAM COLLINS, STEPHEN MARTIN BURKINSHAW, ROY GORDON
-
Patent number: 6302925Abstract: A process for dyeing fibrous substrates which comprises the steps of: providing a fibrous substrate; providing at least one sulfur dye; providing at least one reduction stable direct dye; and applying said reduction stable direct dye and sulfur dye to said fibrous substrate in the presence of a suitable reducing agent. Further, it has been surprising to find that these reduction stable direct dyes can be processed without a sulfur dye present. This results in a process for dyeing fibrous substrates which comprises the steps of: providing a fibrous substrate; providing a reduction stable direct dye; and applying said reduction stable direct dye to said fibrous substrate in the presence of a suitable reducing agent.Type: GrantFiled: November 22, 1999Date of Patent: October 16, 2001Assignee: Clariant Finance (BVI) LimitedInventors: J. Michael Hipp, Mark S. Carlough, William T. Sherrill, Peter Stahala
-
Patent number: 6200354Abstract: A method of dyeing cellulosic fibers or fabrics using pre-metallized acid dye by pretreating the fabric with a cationic agent having a plurality of cationic centers and optionally after treating the dyed material with a cationic polymer is disclosed. The cationic polymer is desirably a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine. Material dyed by the method has a “washed out” appearance similar to fabrics dyed using the “Jarofast” process, but the availability of a wide range of pre-metallized dyes gives a wider color range, and the method enables a wider range of substrates to be dyed successfully, including lyocell fiber materials e.g. those sold under Courtauld's trademark “Tencel” and blend/union materials with polyamides, easier processing and superior wash and light fastness.Type: GrantFiled: August 23, 1999Date of Patent: March 13, 2001Assignee: Imperial Chemical Industries PLCInventors: Geoffrey William Collins, Stephen Martin Burkinshaw, Roy Gordon
-
Patent number: 6139590Abstract: A dyeing and printing system for use in color printing articles or fabrics formed from cellulose prior to dyeing. In the preferred embodiment, the dyeing system composition includes the selective use of a dye blocking print paste, a color binder print paste and a dye enhancing print paste to selectively decrease or increase the shade of the dyed portions of a cellulose article, such as a woven or knitted cotton or cotton/polyester article or fabric while, at the same time, permitting the resisted areas to be colored differently.Type: GrantFiled: March 15, 1999Date of Patent: October 31, 2000Assignee: Burlington Chemical Co., Inc.Inventors: Samuel B. Moore, Yonghua Li, Eric M. Henry
-
Patent number: 6080687Abstract: The present invention is directed to a method for dyeing anionic textile materials such as cellulosic materials with a cationic pigment dispersion. The method comprises padding the textile material with a cationic pigment dispersion comprising a pigment and a cationic dispersant and padding the textile material with a film-forming polymer. The padding steps can occur simultaneously with both the cationic pigment dispersion and the film-forming polymer in the same bath or in consecutive padding steps with the cationic pigment dispersion applied before the film-forming polymer or vice versa. The padded materials are dried and cured to produce the pigment-dyed materials.Type: GrantFiled: March 18, 1999Date of Patent: June 27, 2000Assignee: Zydex IndustriesInventor: Ranka Ajay Ishwarlal
-
Patent number: 6042619Abstract: A hair treatment composition for temporarily coloring the hair is disclosed. A polymer having repeating units of{--CH.sub.2 (CH.sub.3)C[CO.sub.2 (CH.sub.2).sub.2 N.sup.+ (CH.sub.3).sub.3 X.sup.- ]--}.sub.n ; wherein n has a value of about 25 to 1,000 and X is an anion, and a metal containing pigment are combined. The resultant product is applied to the hair to effect temporary coloring of the hair.Type: GrantFiled: October 13, 1997Date of Patent: March 28, 2000Assignee: Bristol-Myers Squibb Co.Inventors: Linda J. Haning, Pamela A. Helms, Coreen Ann Johnson
-
Patent number: 6039768Abstract: A process is described for fixing reactive or substantive dyes on cellulosic fiber material, which process comprises treating the fiber before, during or after dyeing with a liquor comprising a homo- or copolymer containing repeating structures of formula ##STR1## wherein the variables have the meanings claimed in the claims. The dyeings and prints so obtained are distinguished by improved fastness to wet treatments.Type: GrantFiled: June 6, 1997Date of Patent: March 21, 2000Assignee: Ciba Specialty Chemicals CorporationInventor: Philippe Ouziel
-
Patent number: 6001137Abstract: Waterfast ink jet printing onto textiles is performed by treating the textiles with a polymer or copolymer of epihalohydrin prior to the ink jet printing process. A softener such as a tetraalkylammonium salt may also be used, as may be a cationic binder.Type: GrantFiled: March 11, 1998Date of Patent: December 14, 1999Assignee: Encad, Inc.Inventors: Dheya Alfekri, Gary Staley, Bob Chin, Brian Hardin, Cincin Siswanto
-
Patent number: 5989299Abstract: Dyestuff compositions are provided which incorporate, as the grinding aid and/or dispersant therefor, amine modified lignin admixed with sulfonated lignin. The disclosed dyestuff compositions exhibit improved heat stability and, as a result of the higher activity of the dispersant mixture of amine modified lignin blended with sulfonated lignin, less dispersant is present in the exhaust liquor and waste treatment demands are thereby reduced. The improved package dyeing grinding aid/dispersant of the invention is prepared by mixing an amine modified lignin with a sulfonated lignin.Type: GrantFiled: May 26, 1998Date of Patent: November 23, 1999Assignee: Westvaco CorporationInventors: Peter Dilling, Gamini S. Samaranayake
-
Patent number: 5989295Abstract: An oxidation dye composition for keratin fibers, in particular for human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one oxidation dye precursor and optionally one or more couplers, which is characterized in that it also contains an anionic amphiphilic polymer containing at least one hydrophilic unit of an unsaturated olefinic carboxylic acid, and at least one hydrophobic unit which is a (C.sub.10 -C.sub.30)alkyl ester of unsaturated carboxylic acid, preferably exclusively of said (C.sub.10 -C.sub.30)alkyl ester of unsaturated carboxylic acid. The oxidation dye compositions are used in dyeing processes and dyeing devices.Type: GrantFiled: September 5, 1997Date of Patent: November 23, 1999Assignee: L'OrealInventors: Roland de la Mettrie, Fran.cedilla.oise Boudy
-
Patent number: 5976196Abstract: An improved method for fixing color of a dyed textile by coating a dyed textile with a mixture of (i) an aminopolyamide-epichlorohydrin resin and (ii) a glyoxylated acrylamide-dimethyl diallyl ammonium chloride resin.Type: GrantFiled: June 15, 1998Date of Patent: November 2, 1999Assignee: Callaway CorporationInventors: Anthony B Cooper, Richard T. Underwood, Geoffrey A. Monteith, Michael D. Wright
-
Patent number: 5948125Abstract: A method of fixing dyes on natural or synthetic polyamide fiber material, wherein the fiber material is treated, before, during or after dyeing, with a liquor comprising a homo- or co-polymer having structural repeating units of at least one of formulae (1), (2) and (3) ##STR1## wherein the variables are as defined in the claims. The resulting dyeings and prints are distinguished by improved fastness to wetting, without the shade and the fastness to light being affected, and by improved fastness to ozone.Type: GrantFiled: May 11, 1998Date of Patent: September 7, 1999Assignee: Ciba Specialty Chemicals CorporationInventor: Philippe Ouziel
-
Patent number: 5908474Abstract: The present invention provides a dye-fixing agent, obtainable by reacting in a first reaction step, either a homopolymer of diallylamine or N-methyl-diallylamine or a copolymer of diallylamine and N-methyl-diallylamine, with an epihalohydrin, the reaction optionally taking place in the presence of an aliphatic amine or polyamine, or reacting the homopolymer or copolymer with a product obtainable by a reaction of epihalohydrin with an aliphatic amine or polyamine, optionally followed by partial quaternization of the reaction product of the first reaction step, characterized in that the end product possesses at least 10 mol % of tertiary amino groups of the following formula (I), based on the total number of amino groups ##STR1## wherein X=halogen, with the provisos that when the homopolymer is an N-methyl-diallylamine, the presence of an aliphatic amine or a polyamine is obligatory in the reaction with the epihalohydrin and when the homopolymer is a homopolymer of diallylamine, partial quaternisation of the reType: GrantFiled: September 15, 1997Date of Patent: June 1, 1999Assignee: Clariant Finance (BVI) LimitedInventors: Bernard Danner, Jurg Heller
-
Patent number: 5873911Abstract: Polymeric, water soluble, quaternary ammonium compounds (F) obtainable by quaternization of(a) at least one amino-group-containing urea compound that contains one or more groups of the formula--NH--CO--NH--G--L-- (.alpha.)in which G signifies a bridging groupand L signifies a tertiary, quaternizable amino groupwith(b) (b.sub.1) an epihalohydrin and optionally(b.sub.2) at least one further quaternizing agentto a quaternized product (q)and reaction of the quaternized product (q) with(c) a dialdehyde of formula (I) ##STR1## in which Z signifies methylene or the direct bond, or a urea derivative thereof, are suitable as fixing adjuvants in particular in continuous processes under nearly neutral to acidic conditions especially for the improvement of wet fastnesses of dyeings on hydrophilic fibrous material.Type: GrantFiled: August 14, 1997Date of Patent: February 23, 1999Assignee: Clariant Finance (BVI) LimitedInventors: Bernard Danner, Francis Palacin
-
Patent number: 5851239Abstract: Process for preparing colored regenerated-cellulose fiber, which comprises adding a formulation comprising a cationized polysaccharide and an anionic dye to a viscose dope, an alkali cellulose or a cellulose solution and spinning fiber by a viscose spinning process or from the cellulose solution.Type: GrantFiled: November 21, 1997Date of Patent: December 22, 1998Assignee: Dystar Textilfarben GmbH & Co.Inventors: Andreas Von Der Eltz, Andreas Schrell
-
Patent number: 5735908Abstract: The invention relates to an oxidation dye composition for keratin fibers, in particular for human keratin fibers such as hair, of the type comprising, in a medium which is suitable for dyeing, at least one oxidation dye precursor and optionally one or more couplers, and which is characterized in that it contains (i) as oxidation dye precursor, at least one para-phenylenediamine substituted in the 2-position on the benzene ring with a C.sub.1 -C.sub.4 hydroxyalkyl or hydroxyalkoxy radical, and/or at least one of the addition salts thereof with an acid, and (ii) at least one cationic or amphoteric substantive polymer. The invention also relates to the use of this composition for dyeing keratin fibers, especially hair.Type: GrantFiled: July 26, 1996Date of Patent: April 7, 1998Assignee: L'OrealInventors: Jean Cotteret, Marie-Pascale Audousset
-
Patent number: 5733344Abstract: The present invention provides a temporary hairdye which is excellent in dispersion stability of a pigment even after storage over a long period of time by dispersing titanium black, which is safe to a human body, in alcohol having 4 or less carbon atoms, primarily ethanol by using an N-methacryloylethyl-N,N-dimethylammonium..alpha.-N-methylcarboxybetain.but yl methacrylate copolymer. Further, there can be prepared a temporary hairdye which increases dispersion stability of the pigments and provides a different hue by subjecting titanium black and other pigments, particularly iron oxide type pigments such as iron oxide red, black iron oxide and yellow iron oxide to dispersion treatment together.Type: GrantFiled: November 27, 1996Date of Patent: March 31, 1998Assignee: Mitsubishi Pencil Kabushiki KaishaInventors: Katsuhiko Shiraishi, Kiyokazu Sakurai, Tetsuo Kosaka, Tomoko Hasegawa, Kazuhiro Ami, Takashi Umeno
-
Patent number: 5725604Abstract: The present invention relates to a process for dyeing or printing organic material, which comprises applying at last one dye selected from those containing a chromophore radical from the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, naphthoquinone, pyrenequinone or perylenetetracarbamide series which contains an acrylamide, methacrylamide, bromoacrylamide or chloroacrylamide reactive group, at least one colourless cationic compound containing at least one polymerizable double bond, and at least one polymerization initiator and then subjecting it to thermofixation. Further auxiliaries to the organic material may optionally may optionally be included.Type: GrantFiled: March 14, 1996Date of Patent: March 10, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Katharina Fritzsche, Alex Kanzig
-
Patent number: 5679114Abstract: A hair treatment composition for temporarily coloring the hair is disclosed. A polymer having repeating units of{--CH.sub.2 (CH.sub.3)C?CO.sub.2 (CH.sub.2).sub.2 N.sup.+ (CH.sub.3).sub.3 X.sup.- !--}.sub.n ;wherein n has a value of about 25 to 1,000 and X is an anion, and a metal containing pigment are combined. The resultant product is applied to the hair to effect temporary coloring of the hair.Type: GrantFiled: September 22, 1995Date of Patent: October 21, 1997Assignee: Redmond Products, Inc.Inventors: Linda J. Haning, Pamela A. Helms, Coreen Ann Johnson
-
Patent number: 5653772Abstract: A method of fixing cellulose fibers dyed with a reactive dye, which comprises a homopolymer containing a vinylamine structural unit, a copolymer containing from 5 to 90% by weight of a vinylamine structural unit and from 5 to 90% by weight of a diallylamine structural unit, a copolymer containing from 5 to 90% by weight of a vinylamine structural unit, from 5 to 90% by weight of structural unit of a vinyl compound copolymerizable with the vinylamine, or copolymer containing from 5 to 90% by weight of a vinylamine structural unit, from 5 to 90% weight of a diallylamine structural unit and from 5 to 90% by weight of a structural unit of a vinyl compound copolymerizable with vinylamine and diallylamine, and/or a salt of the homopolymer or copolymers.Type: GrantFiled: July 17, 1996Date of Patent: August 5, 1997Assignee: Nicca Chemical Co., Ltd.Inventors: Yasuharu Mori, Nobuhiko Ueno, Kouji Midori, Juji Uchida, Masayuki Maeno
-
Patent number: 5632781Abstract: The present invention provides a cationic polycondensate dye fixing agent prepared by reacting (a) a mono- or polyfunctional amine having at least one reactive --NH or --NH.sub.2 group, or a salt thereof, with (b) a polycondensate-forming cyano compound at a temperature of at least about 260.degree. C.The present invention also provides a process of improving the fastness of dyed materials using the cationic polycondensate dye fixing agent of the present invention.Type: GrantFiled: September 30, 1994Date of Patent: May 27, 1997Assignees: NICCA U.S.A., Inc., NICCA Chemical Co., LtdInventors: Shinichi Morinaga, Kouji Midori
-
Patent number: 5575820Abstract: A process for the dyeing and printing of organic material, in particular fibre material, which comprises applying dyes containing at least one polymerisable double bond together with at lease one colourless cationic compound containing at least one polymerisable double bond and, if desired, one or more colourless nonionic compounds containing at least one polymerisable double bond and, if desired, further auxiliaries to the organic material, in particular fibre material, and then fixing them by means of ionizing radiation.Type: GrantFiled: December 2, 1994Date of Patent: November 19, 1996Assignee: Ciba-Geigy CorporationInventor: Katharina Fritzsche
-
Patent number: 5484457Abstract: Process for the continuous production of surface dyeings on cellulose fiber textile materials, characterized in that the textile materials are treated with an aqueous liquor containing at least 5 g/l of benzyl halide quaternized condensation products of precondensates of trialkanolamines and ureas, cyclic carbonates and/or epihalohydrins and/or benzyl chloride quaternized condensation products of piperazine and epichloronydrin, and 0.02 to 1 g/l of a phosphoric triester whose alcohol component has 6 to 18 carbon atoms, the textile materials thus treated are then dyed in another bath with reactive dyes in an aqueous medium and the dyes are fixed by treatment with an alkaline aqueous liquor and the dyeing finished in conventional manner. The individual cellulose fibers of the textile material are not completely penetrated by the dye but, on the contrary, exhibit ring dyeing.Type: GrantFiled: October 31, 1994Date of Patent: January 16, 1996Assignee: BASF AktiengesellschaftInventors: Joerg Schulze, Harald Schlueter, Kurt Bacher, Wolfgang Schrott, Erich Kromm
-
Patent number: 5478361Abstract: The invention provides the following dyeing method: A method of dyeing a cellulosic textile article characterized by immersing the article in an aqueous dispersion containing a cation-treated coloring agent in the first place and, then, immersing it in an aqueous solution or dispersion of an anionic compound.Type: GrantFiled: February 7, 1994Date of Patent: December 26, 1995Assignee: Sakura Color Products CorporationInventors: Masaaki Sumii, Yasuyuki Yoshimura
-
Patent number: 5454841Abstract: Compositions comprising chemically synthesized or biosynthetic water-soluble melanin and at least one water dispersible cationic material which, when combined with the melanin, forms a composition that is suitable for use as a temporary haircolor. A process for temporarily coloring hair using those compositions.Type: GrantFiled: March 15, 1994Date of Patent: October 3, 1995Assignee: Clairol, Inc.Inventors: L. Wolfram, G. Wenke
-
Patent number: 5417724Abstract: The cold water bleed propensity of acid and premetallized acid dyed cationic dyeable nylon fibers is substantially reduced by treating the fibers with both a nylon fixing agent and a cotton fixing agent. Colorfastness of acid and premetallized acid dyed nylon fibers, other than CD nylon fibers, is also enhanced by treating the fibers with both a cotton fixing agent and a nylon fixing agent.Type: GrantFiled: May 17, 1993Date of Patent: May 23, 1995Assignees: Joseph A. Pacifici, Daniel G. SimsInventors: Joseph A. Pacifici, Daniel G. Sims
-
Patent number: 5403955Abstract: Novel mordants based upon a polyethyleneimine backbone and either pendant phosphonium or quaternized-nitrogen compounds are disclosed. The mordants find use in stopping or controlling ink-bleeding into ink-jet receptors and photographic films.Type: GrantFiled: April 28, 1994Date of Patent: April 4, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventor: Omar Farooq
-
Patent number: 5393305Abstract: A two part aqueous composition for coloring and providing durable conditioning to human hair which forms a gel on mixing of an alkaline aqueous lotion first part having a pH of from about 7 to about 11 containing from about 0.005% by weight to about 5% by weight of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from about 0.1% to about 5% of a cationic polymer, from about 0.5% to about 15% by weight of an anionic or amphoteric surfactant or mixture thereof and at least 70% by weight water, and an aqueous developer second part having a pH of from about 2 to about 6 containing from about 0.5% by weight to about 40% by weight of a peroxide oxidizer and from about 0.1% by weight to about 20% by weight of an anionic polymer, the anionic polymer being characterized in that it is insoluble in the developer and dissolves in the gel which forms when the lotion and developer are mixed.Type: GrantFiled: August 26, 1993Date of Patent: February 28, 1995Assignee: Bristol-Myers Squibb CompanyInventors: David Cohen, Elizabeth Hitchcock, Stanley Pohl
-
Patent number: 5350422Abstract: A process which comprises submitting a polyamide textile material, which has been dyed with an acid dye and subsequently treated with an acidic syntan, to treatment with a cationic agent having a plurality of cationic centers.Type: GrantFiled: February 4, 1993Date of Patent: September 27, 1994Assignee: Imperial Chemical Industries, PLCInventors: Steven M. Burkinshaw, Roy Gordon, David J. Marfell, Kakoma D. Maseka
-
Patent number: 5330540Abstract: As a means for applying a random mottled or hammered appearance to a textile material, this invention provides a process which comprises the steps of: (a) applying to the textile material an aqueous solution having a water insoluble dye dispersed therein and an ionic component in the form of a dispersant in sufficient quantities to disperse the dye; (b) subsequently applying to the textile material an aqueous flocculent solution including a counter-ionic component, thereby electro-chemically reacting with the ionic dispersant such that the dye is precipitated from solution in non-uniform concentrations; and (c) fixing the dye to the textile material, preferably by heat. A textile material dyed according to the process is also provided.Type: GrantFiled: October 12, 1993Date of Patent: July 19, 1994Assignee: Milliken Research CorporationInventors: Daniel T. McBride, William M. Pascoe, John H. Belue
-
Patent number: 5320647Abstract: Fluent dye preparations useful for dyeing leather or wool containa) at least 15% of the weight of the dye preparation of one or more polyazo dyes in salt form which have one or more hydroxysulfonyl and/or carboxyl groups and may be present in the form of a 1:1 or 1:2 metal complex,b) from 2 to 15% of the weight of the dye preparation of a surfactant, andc) water.Type: GrantFiled: August 14, 1992Date of Patent: June 14, 1994Assignee: BASF AktiengesellschaftInventors: Georg Henning, Georg Zeidler, Ortwin Schaffer
-
Patent number: 5298035Abstract: A process for preparing a thermosensitive fibrous structure which includes adding a fibrous substrate mainly composed of cellulosic fiber, microcapsules including a thermochromic material, a cationic surfactant and a nonionic surfactant to a dye bath maintained at a temperature of not higher than 90.degree. C. and then adding an agent for imparting exhaustion property in the bath at a pH not more than 7, thereby causing the fibrous substrate to exhaust the microcapsules from the bath. According to this process, there can be obtained a thermosensitive fibrous structure wherein microcapsules are almost completely exhausted and uniformly provided.Type: GrantFiled: December 24, 1992Date of Patent: March 29, 1994Assignees: OG Kabushiki Kaisha, Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventor: Masao Okamoto