Basic (cationic) Dye Containing Strongly Basic Onium Or Alkylene Imine Group Patents (Class 8/654)
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5904739
    Abstract: Storage-stable liquid brightener formulations essentially comprise a basic optical brightener, an aprotic polar organic solvent and an acid.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: May 18, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Petra Rothe
  • Patent number: 5902355
    Abstract: A method for dying-finishing of textile fabrics which contain modified cellulose regenerated fiber capable of dyeing with cationic dyes which contains an insoluble polymer which is obtained by cross-linking a dihydroxydiphenylsulfone-sulfonate condensate with epoxy compounds having at least two epoxy groups in the molecule, and at least one kind of fiber selected from ordinary cellulose regenerated fiber, cotton and wool, the method comprising steps ofdying of the textile fabrics containing modified cellulose regenerated fiber with a dyeing solution containing cationic dyes alone or containing the cationic dyes and dyes other than cationic dyes by one-bath dying method, concentration of the cationic dyes being decided for the modified cellulose regenerated fiber weight and concentration of the dyes other than cationic dyes being decided for the whole weight of the textile fabric,treating the dyed textile fabric sequentially with an aqueous solution of tannic acid for applying tannic acid 1.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: May 11, 1999
    Assignee: Fuji Spinning Co., Ltd.
    Inventors: Ituo Kurahasi, Hiroaki Tanibe, Kikuo Kakizaki, Makoto Kawamura
  • Patent number: 5869731
    Abstract: There has been found1) a method for reducing the toxicity of spent liquors from dyeing with cationic dyes or mixtures thereof, characterized by the step of dyeing with cationic dyes having a computed electrostatic shielding energy (idealized hydration energy) of .gtoreq.50 kcal/mol,2) cationic, generally low toxicity dyes, their preparation and use for dyeing.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: February 9, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Henry Giera, Felix Reichel, Horst Berneth
  • Patent number: 5741338
    Abstract: Biodegradable quaternaries of amidoamines are disclosed for use as dye leveler compounds in the basic dyeing of acrylic and other fibers. The quaternary compounds of the invention have leveling activity equivalent to benzyl trimethyl ammonium chloride, but with much higher biodegradability, and generate low foam.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: April 21, 1998
    Assignee: High Point Chemical Corporation
    Inventor: Terry E. Singleton
  • Patent number: 5725607
    Abstract: There has been found1) a method for reducing the toxicity of spent liquors from dyeing with cationic dyes or mixtures thereof, characterized by the step of dyeing with cationic dyes having a computed electrostatic shielding energy (idealized hydration energy) of .gtoreq.50 kcal/mol,2) cationic, generally low toxicity dyes, their preparation and use for dyeing.
    Type: Grant
    Filed: June 25, 1996
    Date of Patent: March 10, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Henry Giera, Felix Reichel, Horst Berneth, Thomas Bocker, Karin Hassenruck, Karl Lange, Karlheinrich Meisel
  • Patent number: 5674299
    Abstract: The cationic or basic dyes of formulae (1) and (2) cited in claim 1 are particularly suitable for dyeing paper.These dyes dye paper in a yellow, orange or brown shade having good fastness properties.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: October 7, 1997
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5651794
    Abstract: Dyed cellulosic regenerated elongate members such as fibers are produced by dyeing the regenerated members with a cationic direct dye after formation but before first drying. A method of producing the dyed elongate members comprises forming a dope containing cellulose or a cellulose compound in solution in a solvent, extruding the dope through at least one orifice into a bath containing water to form an elongate extrudate from which solvent is dissolved and/or the cellulose compound is converted to cellulose so as to form the elongate member, dyeing the formed but never dried elongate member with a cationic direct dye and optionally also with an anionic direct dye and then drying for the first time the dyed elongate member.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: July 29, 1997
    Assignee: Courtaulds Plc
    Inventor: James Martin Taylor
  • Patent number: 5571898
    Abstract: There are described dyes of the formula ##STR1## where the ring A may be benzofused, R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.8 -alkanoyl, substituted or unsubstituted benzoyl, substituted C.sub.2 -C.sub.4 -alkanoyl, or substituted diaminotriazinyl,R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl or R.sup.1 and R.sup.2 together with the nitrogen atom joining them together are a heterocyclic radical,R.sup.3 and R.sup.4 are each substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkyl or substituted or unsubstituted piperidinyl and R.sup.3 may also be hydrogen,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.2 -C.sub.5 -alkanoylamino, halogen, nitro, cyano, substituted or unsubstituted phenylazo, C.sub.2 -C.sub.4 -alkanoylamino substituted by a quaternizable or quaternary group, or C.sub.2 -C.sub.4 -alkoxy, C.sub.2 -C.sub.4 -alkoxycarbonyl or C.sub.2 -C.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: November 5, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrike Schloesser, Udo Mayer
  • Patent number: 5545724
    Abstract: The invention relates to cationically bridged tetrakisazo compounds, corresponding to formula I, ##STR1## wherein the individual symbols are defined as in claim 1, as well as residues and liquid preparations thereof. The compounds and their preparations are used for dyeing and printing hydroxy-group-containing or nitrogen-containing organic substrates by a known method. Preferred substrates are textile materials which consist of or contain cellulose, especially cotton, or also bast fibres, leather and preferably paper or paper pulp products, especially wood-containing paper.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: August 13, 1996
    Assignee: Sandoz Ltd.
    Inventor: Helmut A. Moser
  • Patent number: 5474578
    Abstract: A hair fiber having a first color is contacted with a dye having the formula I, formula II, formula III or a mixture thereof whereby the fiber has imparted to it a second color, upon subsequent contact with alkaline peroxide the visual appearance of the first color is restored to the fiber.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: December 12, 1995
    Assignee: Clairol, Inc.
    Inventors: Alexander C. Chan, Alice A. Mayer, Jia-Shen Wang, Gottfried Wenke, Mu-Ill Lim
  • Patent number: 5447540
    Abstract: A high heat-resistant synthetic fiber material containing, for example, aramid, PEEK, or PEN fibers, that can be dyed uniformly at a high color density, with a dye dissolved or dispersed in a liquid medium, for example, water, and having a molecular weight of 330 to 400, at a dyeing temperature of 150.degree. C. or more within a closed system.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: September 5, 1995
    Assignee: Teijin Limited
    Inventors: Shigenobu Kobayashi, Tetsuo Okamoto
  • Patent number: 5330540
    Abstract: As a means for applying a random mottled or hammered appearance to a textile material, this invention provides a process which comprises the steps of: (a) applying to the textile material an aqueous solution having a water insoluble dye dispersed therein and an ionic component in the form of a dispersant in sufficient quantities to disperse the dye; (b) subsequently applying to the textile material an aqueous flocculent solution including a counter-ionic component, thereby electro-chemically reacting with the ionic dispersant such that the dye is precipitated from solution in non-uniform concentrations; and (c) fixing the dye to the textile material, preferably by heat. A textile material dyed according to the process is also provided.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: July 19, 1994
    Assignee: Milliken Research Corporation
    Inventors: Daniel T. McBride, William M. Pascoe, John H. Belue
  • Patent number: 5286854
    Abstract: Basic azo dyes useful for dyeing or printing polymeric material have the formula ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkanoylamino,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or a radical of the formula CO-X, andX is hydroxyl, C.sub.1 -C.sub.4 -alkoxy, amino, mono- or di(C.sub.1 -C.sub.6 -alkyl)amino or a radical of the formula ##STR2## where n is 0 or 1,R.sup.3, R.sup.4 and R.sup.5 are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.6 is hydrogen or C.sub.1 -C.sub.4 -alkyl,L is C.sub.2 -C.sub.6 -alkylene, andAn.sup..crclbar. is one equivalent of an anion,with the proviso that at least one basic or quaternary radical is present in the molecule.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: February 15, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Erwin Hahn, Heidi Hengelsberg, Udo Mayer
  • Patent number: 5240780
    Abstract: Light-stable film-forming salts of a sulfonated polymer, especially a sulfonated polyester, and a cationic dye. When these dye-polysalts are coated onto shaped polymeric structures, especially transparent self-supporting films, the resultant products have important optical uses. A polyester film coated with certain red or amber blends of dye-polysalts and provided with a pressure-sensitive adhesive coating is useful as a lithographers' tape.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: August 31, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George V. D. Tiers, Percy C. Hughes, III
  • Patent number: 5232461
    Abstract: Poly(p-phenylene terephthalamide) (PPD-T) fibers which have been dried are dyed with cationic dyes, or with disperse or acid dyes, by heating the fibers under a high pressure from 29 to 108 psi and at a temperature from 130.degree. to 180.degree. C.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: August 3, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Hamid M. Ghorashi
  • Patent number: 5221699
    Abstract: Printing fluid for printing cellulosic materials comprising (a) water; (b) a cationic polyaminoamide/epichlorohydrin resin; (c) a water soluble cationic dye; and (d) 0 up to about 3 wt. %, based on the weight of the printing fluid, of a bleachable pigment. The fluid preferably also contains up to about 50 wt. %, based on the weight of the fluid, of urea to enhance color strength. The printing fluid has excellent bleed resistance to common household products but is nevertheless bleachable so that printed materials such as paper toweling may be repulped and recycled.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: June 22, 1993
    Assignee: Sun Chemical Corporation
    Inventors: Solomon J. Nachfolger, Timothy C. Vogel
  • Patent number: 5207803
    Abstract: A method for dyeing fibrous material is provided. The method includes contacting a fibrous material with a carrier and a dye soluble or dispersed with the carrier in a dyebath. The carrier comprises an N-substituted aromatic carbonamide or an N,N-disubstituted aromatic carbonamide or mixture thereof. The carrier system of the present can be advantageously utilized for improving dye and flame resistant properties of difficult to dye fibers such as aromatic polyamide fibers, polybenzimidazole fibers and aromatic polyimide fibers.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: May 4, 1993
    Assignee: Springs Industries
    Inventors: John R. Holsten, Nigel E. Neely
  • Patent number: 5163972
    Abstract: Process to dye polyacrylonitrile in blue shades with cationic dye compounds: substituted benzothiazolium azo N-alkyl-N-hydroxyalkyl alkyl-aniline salts.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: November 17, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Wilfried Herter, Josef Koller
  • Patent number: 5160347
    Abstract: Carrier dyeable polyester yarns are space dyed by spraying with water dispersions of disperse dyes without thickeners or carriers followed by a short steaming process and autoclaving to develop the dyes or by a knit-de-knit process of knitting the yarn into socks or tubes which are roller printed with disperse dyestuff, thickener and carrier dissolved in water in various colors followed by steaming, washing, drying and deknitting. The thus produced space dyed yarns are then tufted into area rugs along with undyed yarns of "carrierless" polyester fibers and/or nylon fibers and dyed with a cationic, acid or disperse dye appropriate to the dye receptivity of the undyed yarns while avoiding overdyeing of the space dyed yarns to produce a multicolor piece-dyed area rug.
    Type: Grant
    Filed: January 2, 1992
    Date of Patent: November 3, 1992
    Assignee: Burlington Industries, Inc.
    Inventors: Mark L. Kay, Rodger D. Loveless, Bobby Vinson
  • Patent number: 5096459
    Abstract: Aromatic polyamide fibers, which have been dried and/or crystallized, are steam dyed with a water-soluble dye padded onto the surface of fibers, along with a small amount of a carrier.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: March 17, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Hamid M. Ghorashi
  • Patent number: 5077396
    Abstract: Compounds of the formula ##STR1## wherein each A is independently linear or branched C.sub.2-6 alkylene or linear or branched C.sub.3-6 alkylene substituted by hydroxy,each D is independently the radical of a diazo component of the benzene, azobenzene or naphthalene series, E is a divalent radical attached to each --N.sup..sym. R.sub.3 R.sub.4 -- radical through an aliphatic carbon atom,each R.sub.1 is independently hydrogen, C.sub.1-4 alkyl, cyclohexyl, phenyl or phenyl(C.sub.1-2 alkyl),each R.sub.2 is independently hydrogen, cyano, --COOR.sub.5, --CONR.sub.6 R.sub.7 or ##STR2## wherein R.sub.5 is hydrogen, C.sub.1-4 alkyl or phenyl(C.sub.1-2 alkyl),each of R.sub.6 and R.sub.7 is independently hydrogen or C.sub.1-4 alkyl,each R.sub.8 is independently C.sub.1-4 alkyl, and r is 0, 1, 2 or 3,each R.sub.3 is independently C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl,each R.sub.4 is independently hydrogen, C.sub.1-4 alkyl or C.sub.
    Type: Grant
    Filed: May 14, 1990
    Date of Patent: December 31, 1991
    Assignee: Sandoz Ltd.
    Inventors: Helmut A. Moser, Roland Wald
  • Patent number: 5030244
    Abstract: Process for the preparation of granules by spray-drying of an aqueous suspension having a solids content of greater than/equal to 30% and containing at least one dye, fluorescent brightener or photoactivator and one condensation product from naphthalenesulfonic acid and formaldehyde and, if necessary, further auxiliaries and/or diluents. The spray-drying is carried out at a feed pressure of 50-150 bar, the residual moisture content of the product is less than 4%, and the granules obtained are in particular very pressure resistant and abrasion resistant.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: July 9, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Konrad Neumann, Angelika Hayer, Wolfgang Rehmann, Horst O. Brucker
  • Patent number: 5019131
    Abstract: A process for redyeing partially bleached fabric or garments to yield sharply-etched multicolored designs comprises the steps of:(a) dyeing the fabric, or purchasing a commercial garment, with a background first color;(b) gathering selected areas of the dyed fabric with ligatures to restrict access of further reagents;(c) bleaching the gathered background dyed to remove the first color from the areas outside the gathered areas; and(d) redyeing the bleached areas with a second color,whereby sharply defined multicolored patterns are formed having from about 0.2 mm to about 2 mm of white gap between each color.
    Type: Grant
    Filed: July 9, 1990
    Date of Patent: May 28, 1991
    Assignee: MMOQ, Ltd.
    Inventor: James L. Nitsch, Jr.
  • Patent number: 5017707
    Abstract: Tetraindolylheptamethine ethers and alcohols of the isomeric formulae ##STR1## and ##STR2## and dyestuffs of the formula ##STR3## in which A, B, D and E denote ##STR4## and D'.sup..sym. denotes ##STR5## and the remaining symbols have the meanings given in the description, are used in pressure- and heat-sensitive recording materials.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: May 21, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Hubert Psaar, Gert Jabs
  • Patent number: 4985046
    Abstract: There is provided by this invention a process for preparing poly(paraphenylene terephthalamide) fibers dyeable with cationic dyes. The process comprises soaking poly(paraphenylene terephthalamide) fibers in sulfuric acid, washing the fibers and dipping the acid soaked fibers or never-dried PPD-T fibers in an aqueous solution of a dye promoting species. The fibers can then be dried and subsequently dyed.
    Type: Grant
    Filed: June 9, 1989
    Date of Patent: January 15, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Jon D. Hartzler
  • Patent number: 4976744
    Abstract: Concentrated solutions of cationic dyes are prepared by treating the cationic dyes, which contain as the counterions the anions customarily present during their preparation, with alkali metal salts of monocarboxylic acids and with or without complexing agents in an aqueous glycol ether medium, and separating off the organic phase, which contains the dyes in the form of their monocarboxylic acid salts.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: December 11, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes P. Dix, Guenter Hansen, Hellmut Kast
  • Patent number: 4961755
    Abstract: There are disclosed coated active substances and a process for the preparation thereof, wherein said active substances are dyes, fluorescent whitening agent, photoactivators and/or textile microbicides, if appropriate together with extenders, dispersants, buffers, stabilizers and/or other auxiliaries.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: October 9, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Beat Bruttel, Petr Kvita
  • Patent number: 4950303
    Abstract: Water-soluble dyes are loaded on polymer microparticles having a particle size of 0.01 to 50 microns. The carrier polymer microparticles are produced by emulsion polymerizing a mixture of at least one monofunctional monomer with a crosslinking monomer in the presence of a polymerizable amino acid derivative or a hydrophilic oligomer having a plurality of amphoionic groups. Water-soluble dyes are added to the resulting emulsion. Color-loaded polymer microparticles are obtained by removing water from the emulsion followed by resuspending in an organic solvent.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: August 21, 1990
    Assignee: Nippon Paint Co., Ltd
    Inventor: Keizou Ishii
  • Patent number: 4913705
    Abstract: A mixed fabric of hydroxy group-containing fibers and cyano and/or carboxy group-containing fibers, the hydroxy group-containing fibers having been dyed with a reactive dye, is aftertreated with a product of reacting a mono- or polyfunctional amine having one or more primary, secondary and/or tertiary amino groups with cyanamide, dicyandiamide guanidine or bis-guanidine, said product containing at least one reactive hydrogen atom linked to a nitrogen atom, and is then dyed with a basic dye.
    Type: Grant
    Filed: September 2, 1988
    Date of Patent: April 3, 1990
    Assignee: Sandoz Ltd.
    Inventors: Bernhard Schlick, Claudio Artico
  • Patent number: 4872880
    Abstract: A process for the dyeing of polymers of propylene, butene-1 and 4-methyl-pentent-1 is disclosed. The process involves contacting articles of the polymer with an aqueous dyebath containing a basic dye in a concentration of at least 0.4 g/l and at a pH of at least 5.0. The temperature of the aqueous dyebath is at least 90.degree. C. The article is maintained in contact with the dyebath for at least 10 minutes. The polymer of propylene is preferably a blend of 50-99 parts of a homopolymer of propylene or copolymer of propylene and ethylene with 1-50 parts of a zinc ionomer or graft copolymer of a hydrocarbon alpha-olefin with an alpha-olefin having carboxylic acid or carboxylic acid anhydride. Dyed polymers are obtained.
    Type: Grant
    Filed: October 6, 1988
    Date of Patent: October 10, 1989
    Assignee: DuPont Canada Inc.
    Inventor: John R. B. Boocock
  • Patent number: 4861342
    Abstract: Dyeing or finishing process characterized in that textile materials are impregnated in a padding machine with aqueous dyeing or finishing baths which contain, besides graft polymers, which may be obtained from a product of addition of an alkylene oxide to an at least trivalent aliphatic alcohol containing from 3 to 10 carbon atoms and methacrylamide or acrylamide, and in that the fixing of the dyes or of the finish is then performed continuously by a treatment with microwaves for 5 to 30 seconds.The process permits an excess water input on all the textile materials and a rapid fixing by the microwaves.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: August 29, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Paul Danel
  • Patent number: 4813973
    Abstract: Water-soluble, amide group containing polymers such as polyacrylamide are modified, to render them easy to detect, by reacting the polymer in aqueous solution with organic dye molecules which can form stable carbo-cations reversibly in water. The labelled polymers can then be detected spectrophotometrically. An example of a suitable dye molecule is 9-xanthydrol.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: March 21, 1989
    Assignee: The University of Toronto Innovations Foundation
    Inventors: Mitchell A. Winnik, Robert M. Borg
  • Patent number: 4780106
    Abstract: Metal-free compounds of the formula ##STR1## 1:1 and 1:2 metal complexes thereof, and acid addition salts of metal-free compounds of said formula and 1:1 and 1:2 metal complexes thereof, whereinB is hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by C.sub.1-4 alkoxy; C.sub.2-4 alkyl substituted by hydroxy; C.sub.5-6 cycloalkyl; C.sub.5-6 cycloalkyl substituted by 1 to 3 C.sub.1-4 alkyl groups; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) the phenyl group of which is substituted by 1 to 3 substituents selected from C.sub.1-4 alkyl, C.sub.1-4 alkoxy and halo; --A--NH--R.sub.2 ; --A'.sub.4 --N(R.sub.7).sub.2 ; --A.sub.4 --N.sup..sym. (R.sub.8).sub.2 R.sub.9 A.sup..crclbar. or --N(R.sub.7).sub.2,R is hydrogen; C.sub.1-4 alkyl; C.sub.5-6 cycloalkyl; C.sub.5-6 cycloalkyl substituted by 1 or 2 C.sub.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: October 25, 1988
    Assignee: Sandoz Ltd.
    Inventors: Helmut Moser, Manfred Greve, Reinhard Pedrazzi, Roland Wald
  • Patent number: 4780105
    Abstract: A composition for dyeing material of synthetic aromatic polyamide fibers, including a cationic dye and a dye assistant, which is a mixture of N-substituted phthalimide and an emulsifier. The N-substituted phthalimide is preferably a 2:1 mole ratio of N-butyl phthalimide and isopropyl phthalimide. The emulsifier is preferably propylene oxide and ethylene oxide block polymer, and an anionic surfactant blend and an anionic/cationic surfactant blend.
    Type: Grant
    Filed: April 15, 1987
    Date of Patent: October 25, 1988
    Assignee: Stockhausen, Inc.
    Inventors: W. Edward White, Michael W. Ensley, Frank M. Dalton
  • Patent number: 4767421
    Abstract: A method of manufacturing a homogeneous, water-insoluble dye layer on a substrate is provided in which a solution of a cationic or anionic dye in an organic solvent is provided on the substrate, the solvent is removed and the resulting dye layer is treated with an aqueous solution of a salt in which the cation of the anionic dye is exchanged for the cation of the salt or is treated with a salt or acid in which the anion of the cationic dye is exchanged for the anion of the salt or acid. The invention also provides a substrate provided with water insoluble homogeneous dye layer.
    Type: Grant
    Filed: June 2, 1987
    Date of Patent: August 30, 1988
    Assignee: U.S. Philips Corp.
    Inventors: Jan van der Veen, Dirk J. Gravesteijn, Cornelis J. Schoot
  • Patent number: 4765797
    Abstract: Liquid formulations of mixtures of cationic dyes frequently have a very short storage life. As a consequence, these formulations give rise to customer complaints concerning incorrect dyeing strengths and hues and concerning isoluble constituents. It has now been found according to the invention that powder formulations and in particular liquid formulations of cationic dyes or of mixtures of these dyes can be stabilized by adding selected oxidizing agents.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: August 23, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Sierling Ong, Kurt Hohmann
  • Patent number: 4753658
    Abstract: Disclosed is a coloring material including a rubber having a sulfonic acid group or a salt thereof, which is dyed with a basic dye. The coloring material is prepared by adding a solution of an alkali in an alcohol to a solution of a chlorosulfonated polyolefin in an organic solvent and then adding a basic dye to the obtained reaction liquid, or adding a basic dye to a solution of a sulfonated product of a rubber in an organic solvent, and optionally removing the solvent from the obtained solution.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: June 28, 1988
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Shuichi Okuzono, Tatsushi Nakagawa, Takashi Shintani
  • Patent number: 4750936
    Abstract: Stabilized, aqueous dispersions of multivalent metal humates are disclosed as a compatible and functional component in printing ink formulations.
    Type: Grant
    Filed: January 27, 1987
    Date of Patent: June 14, 1988
    Assignee: Union Camp Corporation
    Inventors: James C. West, William C. Firth, Jr.
  • Patent number: 4732573
    Abstract: Dye salts of a mono- or polycationic dye where the anion conforms to a general formula (1) or (2)[Me (XCN).sub.4 ].sup.2(-) (1)[Me (SCN).sub.6 ].sup.n(-) (2)in whichMe in the formula (1) is the divalent zinc cation, the divalent iron cation, the divalent cobalt cation, the divalent tin cation or the divalent copper cation, andMe in the formula (2) stands for the divalent iron cation, the divalent nickel cation or the trivalent iron cation,X stands for an oxygen or sulfur atom andn depending on the valency of the corresponding metal cation, denotes the number 4 or 3.The novel dye salts can be obtained for example from aqueous solution or suspension by reacting the corresponding cationic dye which has a customary anion with a metal cation Me donor compound and an alkali metal thiocyanate or cyanate, alkaline earth metal thiocyanate or cyanate or ammonium thiocyanate or cyanate. They are used in particular in the spin-dyeing of acid-modified polyacrylonitrile and copolymers thereof.
    Type: Grant
    Filed: December 23, 1986
    Date of Patent: March 22, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Kurt Hohmann, Peter Mischke, Wolfgang Teige
  • Patent number: 4732571
    Abstract: A process for the dyeing of polymers of ethylene is disclosed. The process involves contacting articles of the polymer with an aqueous dyebath containing a basic dye in a concentration of at least 0.5 g/l and at a pH of at least 5.0. The temperature of the aqueous dyebath is at least 35.degree. C., especially at least 55.degree. C. The article is maintained in contact with the dyebath for at least 20 seconds. The polymer of ethylene is a blend of 65-99 parts of a homopolymer of ethylene or copolymer of ethylene and at least one C.sub.3 -C.sub.10 higher alpha-olefin with 1-35 parts of a direct or graft copolymer of an alpha-olefin having carboxylic acid, carboxylic acid anhydride, ionomeric or --OH groups. Dyed polymers of ethylene are obtained.
    Type: Grant
    Filed: December 30, 1986
    Date of Patent: March 22, 1988
    Assignee: Du Pont Canada Inc.
    Inventors: John R. B. Boocock, Vaclav G. Zboril
  • Patent number: 4718918
    Abstract: Polymeric compounds (A) obtained by the reaction of epihalo-hydrin with a polyalkylene polyamine are useful as textile treatment agents. As pretreatment agents they improve the color yield of the subsequent dyeing, as aftertreatment agents they improve fastness properties. Certain of the products (A) are novel.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: January 12, 1988
    Assignee: Sandoz Ltd.
    Inventors: Jurg Heller, Bruno Kissling, Tibor Robinson, Salvatore Valenti
  • Patent number: 4713083
    Abstract: A coloring material comprising a solution of an alcohol-soluble resin having a sulfonic acid group or a salt thereof, which is dyed with a basic dye, in a solvent comprising an alcohol as a main component. The coloring material is prepared either by (a) polymerizing an ethylenically unsaturated sulfonic acid or a salt thereof in water and adding a basic dye to the obtained aqueous liquid of the formed polymer or (b) carrying out said polymerization in the presence of a basic dye, and dissolving (i) the obtained aqueous liquid of the formed colored polymer of (ii) a colored polymer obtained by removing water from the obtained aqueous liquid of the formed colored polymer in a solvent comprising an alcohol as a main component; or, (a') carrying out said polymerization in a solvent comprising an alcohol as a main component and then adding a basic dye to the obtained polymer solution, or (b') carrying out said polymerization in the presence of a basic dye.
    Type: Grant
    Filed: July 3, 1985
    Date of Patent: December 15, 1987
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Shuichi Okuzono, Tetsuo Tanaka, Yasuhiro Oda, Takashi Shintani, Noriaki Emura
  • Patent number: 4705527
    Abstract: A process of printing a predetermined pattern on a poly(m-phenyleneisophthalamide)-containing textile fabric comprises the successive steps of: (a) applying a print paste, composed of a highly polar solvent selected from the group consisting of dimethylsulfoxide, N,N-dimethylacetamide, N-methyl-2-pyrrolidone, and mixtures thereof, the polar solvent adapted to swell the aramid fiber and introduce a dyestuff therein, at least one organic dyestuff that is soluble in the polar solvent, a print paste thickening agent compatible with both the polar solvent and the dyestuff and water in a predetermined pattern onto the surface of the aramid textile; and (b) drying and curing the thus printed fabric at an elevated temperature sufficient to permeate and fix the dyestuff molecules inside the aramid fibers.
    Type: Grant
    Filed: May 14, 1986
    Date of Patent: November 10, 1987
    Assignee: Burlington Industries, Inc.
    Inventor: Samir Hussamy
  • Patent number: 4664671
    Abstract: A thermal transfer printing sheet comprising a substrate having a coating comprising a dye of the formula:D--AwhereinD is a cationic chromophore andA is a soft anionic base,suitable for use in a thermal transfer printing process.
    Type: Grant
    Filed: October 10, 1985
    Date of Patent: May 12, 1987
    Assignee: Imperial Chemical Industries PLC
    Inventor: Peter Gregory
  • Patent number: 4661116
    Abstract: Textile fabrics formed at least partially of cationic dyeable polyester fibers are dyed in a continuous process with an aqueous dyebath comprising(a) 0 to 5 g/l of thickener;(b) cationic dyestuffs in an amount sufficient to dye the cationic dyeable polyester fibers to the desired depth of color;(c) 2 to 100 g/l of a partially sulfated adduct of ethylene oxide with an alkyl phenol or C.sub.8 to C.sub.16 fatty alcohols;(d) 2 to 60 g/l of nonionic or anionic surfactants; and(e) 5 to 50 g/l of at least one organic compound selected from the group consisting of aromatic nitrile ethers and ethoxylated chlorophenols.The fabrics are continuously dyed by padding, immersing, spraying or otherwise applying the dyestuffs, steaming the fabrics in their wet condition, and subsequently washing and drying.
    Type: Grant
    Filed: January 31, 1985
    Date of Patent: April 28, 1987
    Assignee: Collins & Aikman Corporation
    Inventors: Frederick E. Barwick, III, Kyle R. Pearce
  • Patent number: 4645510
    Abstract: The invention provides a process for the exhaust dyeing with a reactive dyestuff of a textile material comprising cellulosic fibres, which process comprises the step of adding to the dyebath containing the reactive dyestuff, simultaneously the salt and the alkali in specified quantities metered per unit time so as to give a substantially linear exhaustion of the dyebath.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: February 24, 1987
    Assignee: Sandoz Ltd.
    Inventors: Rolf Hasler, Francis Palacin
  • Patent number: 4629465
    Abstract: The invention relates to a process for exhaust dyeing a textile fibre substrate to obtain level dyeings, which process comprises the step of adding to the dyebath the effective amount of dyestuff or electrolyte or dyestuff and electrolyte either simultaneously or one after the other in specified quantities per cycle of the dyeing machine, metered according to a mathematical function.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: December 16, 1986
    Assignee: Sandoz Ltd.
    Inventors: Rolf Hasler, Francis Palacin
  • Patent number: 4624678
    Abstract: The invention describes a process for the preparation of granular dye formulations by mixing a (preferably water-soluble) dye, water, and optionally further assistants with a polyethylene glycol that melts in the range from 40.degree. to 150.degree. C., and drying the resultant solution or suspension in a spray drier or fluidized bed drier. The granular formulations so obtained are permanently dust-free, dissolve rapidly in an aqueous dyebath, and do not cause foaming during dyeing.
    Type: Grant
    Filed: April 29, 1985
    Date of Patent: November 25, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Dieter Schneider
  • Patent number: 4607071
    Abstract: Improvement of a process for spin-dyeing acid-modified polymers or copolymers of acrylonitrile in which cationic quaternary dyestuffs are added to the spinning mass and spun according to the wet-spinning procedure. The improvement is characterized by using dyestuffs characterized by a migration factor M of 20 or less than 20, by a combination index K of less than 2.5 and a cation weight of more than 310. Migration factor M and combination index K are known values in the dyestuff field or can be determined. The dyestuff to be used according to the invention can belong to the most different classes of dyestuffs; they fix rapidly on the polymer, and thus they do not color, or color only to a minor extent, the coagulation, stretching and washing baths although they are soluble in water and aqueous solutions of these baths.
    Type: Grant
    Filed: May 15, 1985
    Date of Patent: August 19, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Reinhard Mohr, Kurt Hohmann