Basic Dye, Including Diphenylmethane, Triphenylmethane, Xanthene, Fluorene, Methine, Acridine, Oxazine, Phenazine, Flavylium, Naphthoperinone, Quinophthalone, Etc., Group-containing Patents (Class 8/657)
  • Patent number: 6623531
    Abstract: The invention relates to a hair dye composition having markedly high dyeing power, less color fade over time, and undergoes a small change in the color tone of the dye even after storage.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: September 23, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga
  • Patent number: 6610131
    Abstract: Novel magenta and cyan colorants for utilization within water-based inks are provided which exhibit improved chromatic properties. In particular, such colorants provide magenta or cyan colorations that exhibit increased color space characteristics, high water solubility, excellent compatability with impurities, and correspondingly cost-effectiveness for flexographic printing procedures. The methods of utilizing such colorants within flexographic printing processes are also encompassed within the invention.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: August 26, 2003
    Assignee: Milliken & Co.
    Inventors: Philip G. Harris, Patrick D. Moore
  • Patent number: 6592633
    Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using the composition.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: July 15, 2003
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6551362
    Abstract: A composition for dyeing material of synthetic aromatic polyamide fibers, said composition containing a mixture of (a) a cationic dye and (b) a cyclohexenone as a dye assistant. Preferably, 2-cyclohexen-1-one,3,5,5-trimethyl is the dye assistant.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: April 22, 2003
    Assignee: BGB Stockhausen GmbH
    Inventors: Darrin McBane Guthrie, Harold Kenneth Greeson, Jr., Malcolm S. Haith
  • Patent number: 6533826
    Abstract: Process for preparing aqueous solutions of cationic di- and triarylmethane dyes by the aqueous dye solution, which contains organic solvents, being concentrated by nanofiltration and optionally diluted with water.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: March 18, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Gessner, Gunter-Rudolf Schröder, Robert Reinhardt
  • Patent number: 6524350
    Abstract: Stabilized metachromatic dyes, especially at application concentrations, comprising metachromatic dyes dissolved in one or more non-aqueous solvents, as well as metachromatic dyes dissolved in pH stabilized aqueous solutions. Also, various combinations of treatments are disclosed for stabilizing metachromatic dyes.
    Type: Grant
    Filed: April 17, 2001
    Date of Patent: February 25, 2003
    Assignee: GE Betz, Inc.
    Inventors: Kristin E. Buentello, Larry M. Kye, Elizabeth Yibin Zhang, Victoria Rafalovsky, Alan M. Agree
  • Publication number: 20030019053
    Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, this composition having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using it.
    Type: Application
    Filed: April 6, 1999
    Publication date: January 30, 2003
    Inventor: CHRISTINE RONDEAU
  • Publication number: 20020178517
    Abstract: The object of the present invention is to provide organic dye compounds which exert satisfactory optical absorption properties and thermal resistance when used in high density optical recording media. The above object is solved by specific trimethine cyanine dyes, light absorbents and optical recording media which comprise the cyanine dyes, and preparations for the cyanine dyes comprising either reacting a benzoindolium compound having a compatible leaving group with a pyrazinoimidazolium compound having a reactive methyl group; or reacting a benzoindolium compound having a reactive methyl group with a pyrazinoimidazolium compound having a compatible leaving group.
    Type: Application
    Filed: October 23, 2001
    Publication date: December 5, 2002
    Inventors: Chiaki Kasada, Katsumi Orita, Kentaro Yano, Toshio Kawata, Shigeo Yasui
  • Patent number: 6458168
    Abstract: The present invention relates to the use, for dyeing keratin fibers, of at least one aliphatic cationic amine and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, in order to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibers. The invention also relates to dye compositions comprising these compounds and to dyeing agents for using them.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: October 1, 2002
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Hervé Andrean
  • Patent number: 6451071
    Abstract: This invention relates to colorants comprising organic chromophores, in particular reactive dyes, which comprise electrophilic reactive groups, and which are also covalently bonded to fatty amine moieties through amino linking groups. Such colorants provide excellent colorability and long-term stability, both within (or on) colored substrates and upon long-term storage. Such colorants exhibit particularly good coloring and stability within hydrocarbon compositions, such as fuels, mineral oil, and the like, and wax compositions, including candles, crayons, and the like. Methods of making such colorants as well as methods of coloring hydrocarbon and wax compositions are also contemplated within this invention.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: September 17, 2002
    Assignee: Milliken & Company
    Inventor: John D. Bruhnke
  • Patent number: 6451067
    Abstract: The present invention relates to the use, for dyeing keratin fibres, of at least one heterocyclic cationic amine and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, in order to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibres. The invention also relates to dye compositions comprising these compounds and to dyeing agents for using them.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: September 17, 2002
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Hervé Andrean
  • Patent number: 6440177
    Abstract: In the present invention there is provided a single-step process and composition of hair bleach, which can simultaneously lighten the hair up to seven levels and effectively neutralize any undesirable warmth, provide natural tones or deposit fashion shades. This is achieved by including in the bleach mixture a solution containing basic dye molecules, which in the present invention have been found to be both, stable in the bleach, and capable of depositing the desired amount of tone on the hair. The dyes fall into the class of water-soluble basic azo compounds.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: August 27, 2002
    Assignee: Artec Systems Group
    Inventor: Cindy L. Orr
  • Patent number: 6436153
    Abstract: The invention relates to a direct dye composition for keratin fibers, in particular for human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing and which is free of oxidases or oxidoreductases, at least one cationic direct dye of given formula and at least one specific polyol and/or polyol ether. Subjects of the invention are also the dyeing processes and devices/kits using the said composition.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: August 20, 2002
    Assignee: L'Oréal S.A.
    Inventor: Christine Rondeau
  • Publication number: 20020083532
    Abstract: Anionic coloring agents comprising at least one spacer arm bounded to their chemical structure. These anionic coloring agents have the following general formula: CA-BE, wherein, CA is an anionic coloring agent comprising at least a cromophore group; and BE is the spacer arm, which has the following chemical structure: —(X—R—Z)r, wherein X is a direct link or a group having the formula —S(O)s, wherein s is 0, 1 or 2; or —NR1—, wherein, R1 is hydrogen or a C1-C10 alkyl group; R is a C1-C10 straight or branched alkylene group: Z is a polar group; and r is an integer equal or higher than 1.
    Type: Application
    Filed: December 18, 2001
    Publication date: July 4, 2002
    Inventor: Jorge Mazza
  • Patent number: 6413281
    Abstract: 2-(p-sulphophenyl) amino-1,3 5-triazine derivatives [1] and their alkali salts, wherein R1, represents Cl, F; R2 is &agr;- or &bgr;-naphthylamino, or &agr;- or &bgr;-naphthoxy, and the method for preparing the compound are provided. The compound can be used as a cationic dye auxiliary agent in dyeing animal protein fibers (such as wool, cony hair, camel hair and natural silk) and their textile fabric as well as blended yarn or fabric containing the animal protein fiber.
    Type: Grant
    Filed: February 17, 2000
    Date of Patent: July 2, 2002
    Inventor: Zhi Wang
  • Publication number: 20020046432
    Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, this composition having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using it.
    Type: Application
    Filed: April 6, 1999
    Publication date: April 25, 2002
    Inventor: CHRISTINE RONDEAU
  • Patent number: 6371994
    Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, comprising at least one cationic direct dye of given formula and at least glycerol and/or one specific polyol and/or polyol ether. The invention also relates to the dyeing processes and devices using this composition.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: April 16, 2002
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6358286
    Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibers, and in particular human keratin fibers such as the hair, having, in a medium suitable for dyeing, at least one oxidation base and at least one specific cationic dye as direct dye, as well as to the dyeing process using this composition.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 19, 2002
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6287348
    Abstract: This invention relates to colorants comprising organic chromophores, in particular reactive dyes, which comprise electrophilic reactive groups, and which are also covalently bonded to fatty amine moieties through amino linking groups. Such colorants provide excellent colorability and long-term stability, both within (or on) colored substrates and upon long-term storage. Such colorants exhibit particularly good coloring and stability within hydrocarbon compositions, such as fuels, mineral oil, and the like, and wax compositions, including candles, crayons, and the like. Methods of making such colorants as well as methods of coloring hydrocarbon and wax compositions are also contemplated within this invention.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: September 11, 2001
    Assignee: Milliken & Company
    Inventor: John D. Bruhnke
  • Publication number: 20010014989
    Abstract: The present invention provides new compounds having the formula: 1
    Type: Application
    Filed: January 22, 2001
    Publication date: August 23, 2001
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr
  • Patent number: 6277643
    Abstract: The present invention relates to a method for detection of protein using a counter-dye composition, on polyaciylamide gels, and the counter-dye composition for detection of protein on polyacrylamide gels. More specifically, the present invention relates to a method for detection of protein in a high sensitivity on polyacrylamide gels in a rapid and simple manner, comprising the step of staining the polyacrylamide gels with a counter-dye composition containing an acidic organic dye and a basic organic dye, and the counter-dye composition for detection of protein on polyacrylamide gels.
    Type: Grant
    Filed: July 10, 1999
    Date of Patent: August 21, 2001
    Inventors: Jung Kap Choi, Gyoung Hoon Tak, Da-Woon Jung, Gyurng Soo Yoo
  • Patent number: 6255482
    Abstract: The triphendioxazine compounds of the general formula (I) in which the rings labelled A in positions 1,2-, 2,3- or 3,4- and 8,9-, 9,10- or 10,11- carry a linearly or angularly fused heterocyclic ring containing at least one nitrogen atom which is substituted or unsubstituted, with the proviso that compounds with only unsubstituted nitrogen atoms and symmetrically disubstituted compounds with C1-2alkyl and unsubstituted phenyl substituents are excluded, are outstanding pigments and are notable over the closest comparable pigments in particular for better migration, light and solvent fastnesses, better heat stability and enhanced colouring power and also better dispersibility and capability to be brought into pigment form. The invention also relates to a process for preparing these triphendioxazine compounds which is characterized by a cyclization step conducted in the presence of manganese dioxide and concentrated sulphuric acid.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: July 3, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Patrick Boeglin, Bansi Lal Kaul, Peter Kempter
  • Patent number: 6241785
    Abstract: The invention concerns the use of flavylium type compounds, non-substituted in position 3, and substituted by at least a hydroxyl or alcoxy radical, in particular Apigenidin, in pure form or in the form of plant extracts containing them, as coloring agent in or for making compositions for dyeing keratinous fibers, particularly human keratinous fibers such as hair. The invention also concerns the dyeing compositions containing them, particularly cosmetic compositions for direct hair dyeing, and the corresponding dyeing method. The hair dyes resulting from the use of these coloring agents are particularly stable to light and washing.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: June 5, 2001
    Assignee: L'Oreal
    Inventors: Patrick Darmenton, Michel Philippe
  • Patent number: 6241788
    Abstract: Stabilized metachromatic dyes, especially at application concentrations, comprising metachromatic dyes dissolved in one or more non-aqueous solvents, as well as metachromatic dyes dissolved in pH stabilized aqueous solutions. Also, various combinations of treatments are disclosed for stabilizing metachromatic dyes.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: June 5, 2001
    Assignee: BetzDearborn Inc.
    Inventors: Kristin E. Buentello, Larry M. Kye, Elizabeth Yibin Zhang, Victoria Rafalovsky, Alan M. Agree
  • Patent number: 6221113
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: April 24, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Jürgen Geiwiz
  • Patent number: 6152969
    Abstract: The present invention relates to the development of a coloring matter which has a moderately bluish magenta color and an excellent lightfastness and can provide a wide range of color tones in the visible range when used together with yellow and cyan inks. A water-base ink composition or the like is prepared by using a sulfonic acid derivative of an anthrapyridone compound represented by general formula (I) as a magenta dye, wherein R.sub.1 ' represents alkoxycarbonyl, carbonyl or benzoyl; R.sub.2 represents hydrogen or alkyl; and R.sub.3 and R.sub.4 represent each independently hydrogen, halogeno, alkyl or alkoxy.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: November 28, 2000
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Hiroyuki Matsumoto, Yasuo Shirasaki, Katsunori Fujii
  • Patent number: 6121452
    Abstract: The present invention relates to a process for preparing compounds of formula (I) ##STR1## wherein A completes an unsubstituted or substituted heteroaromatic ring andB completes an unsubstituted or substituted aromatic ring, by reacting a heterocyclic compound of formula (II) ##STR2## wherein A completes an unsubstituted or substituted heteroaromatic ring, with an aromatic dicarboxylic acid of formula (III) ##STR3## or an anhydride thereof, wherein B completes an unsubstituted or substituted aromatic ring, in an organic solvent in the presence of an aliphatic or aromatic alcohol that is different from both the organic solvent and compounds (I), (II), and (III).
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: September 19, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dietmar Kalz, Stephan Michaelis, Karl-Heinz Reinhardt
  • Patent number: 6045591
    Abstract: The invention relates to a process for the two-step direct dyeing of keratin fibres, comprising bleaching the keratin fibres; and applying to the keratin fibres a dye composition comprising at least one partially dissolved basic direct dye and an aqueous medium, wherein the dye composition is ready to use or results from mixing, at the time of use, at least one pulverulent composition (P) comprising at least one basic direct dye and an aqueous composition (A).
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: April 4, 2000
    Assignee: L'Oreal
    Inventor: Christelle Deneulenaere
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5929215
    Abstract: Compounds of Formula I ##STR1## wherein the substituents are as defined in the description, a process of manufacture thereof and a process of dyeing employing said compounds.
    Type: Grant
    Filed: July 7, 1998
    Date of Patent: July 27, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Reinhard Pedrazzi
  • Patent number: 5904739
    Abstract: Storage-stable liquid brightener formulations essentially comprise a basic optical brightener, an aprotic polar organic solvent and an acid.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: May 18, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Petra Rothe
  • Patent number: 5891200
    Abstract: Anthraquinone compounds of formula I ##STR1## wherein R.sub.1 and R.sub.2 are methyl and R.sub.3 is propyl, or R.sub.1 and R.sub.2 are ethyl and R.sub.3 is methyl and A is a cosmetically acceptable anion, are combined neutral, with semipermanent direct dyes in hair dyeing compositions.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: April 6, 1999
    Inventors: Mu-Ill Lim, Linas Stasaitis, Yuo-Guo Pan
  • Patent number: 5827330
    Abstract: Water soluble, cationic products useful as hair colorants or for the treatment of skin which are esters or amides formed by reaction of melanin and a quaternary salt containing a reactive amino or hydroxyl group, as well as compositions containing them and methods of using such products to color hair or treat skin are described.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: October 27, 1998
    Assignee: Bristol-Myers Squibb Co.
    Inventors: Gottfried Wenke, Giuseppe Prota
  • Patent number: 5811040
    Abstract: The specification describes a process of making a fiber for a carpet face yarn, the yarn being made of polyolefin/polymer filaments which contain a plurality of longitudinally dispersed relatively small, short polymer fibrils inside the filaments generally concentrated toward the center thereof within the polyolefm matrix. The yarn has the stain resistant properties of polyolefm based yarns and the resiliency of polyamide based yarns at a substantially lower cost than nylon carpet yarns.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: September 22, 1998
    Inventor: William C. Mallonee
  • Patent number: 5766268
    Abstract: A colorant composition which can be liquid in the neat form at 25.degree. C., having the structure ABXYZ, whereA is an organic chromophore;B is an electrophilic reactive group covalently bonded to A directly or through a linking group;X is a nucleophilic linking group covalently bonding B and Y;Y is a poly(oxyalkylene)-containing moiety comprising the formula (C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n where a and b are different and from 1 to 8, m is at least 3, n is 0 to 15; andZ is a terminal group for Y.The colorant composition can be prepared from a reactive dye AB which is reacted with XYZ, a poly(oxyalkylene)-containing moiety containing a nucleophilic group.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 16, 1998
    Assignee: Milliken Research Corporation
    Inventor: John D. Bruhnke
  • Patent number: 5746779
    Abstract: Quaternized blue anthraquinone compounds of Formula I ##STR1## wherein R.sub.1 and R.sub.2 are methyl and R.sub.3 is propyl, or R.sub.1 and R.sub.2 are ethyl and R.sub.3 is methyl and A.sup.- is a cosmetically acceptable anion, when employed in an isatin/amine dye system for the dyeing of hair enable the hair colorist to develop a full range of shades for the isatin/amine dye system. The compound of Formula I wherein R1 and R2 are methyl and R3 is propyl is preferred. Compositions and a method of use employing same are disclosed.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: May 5, 1998
    Assignee: Bristol-Myers Squibb Company
    Inventor: Keith Brown
  • Patent number: 5746778
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autoclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: May 5, 1998
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5733343
    Abstract: Keratin-containing fibres, in particular human hair, are dyed using dyes of formulae (1) to (6) indicated in claim 1. These dyes make it possible to dye by the trichromatic principle even in dark shades.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: March 31, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Peter Mockli
  • Patent number: 5725607
    Abstract: There has been found1) a method for reducing the toxicity of spent liquors from dyeing with cationic dyes or mixtures thereof, characterized by the step of dyeing with cationic dyes having a computed electrostatic shielding energy (idealized hydration energy) of .gtoreq.50 kcal/mol,2) cationic, generally low toxicity dyes, their preparation and use for dyeing.
    Type: Grant
    Filed: June 25, 1996
    Date of Patent: March 10, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Henry Giera, Felix Reichel, Horst Berneth, Thomas Bocker, Karin Hassenruck, Karl Lange, Karlheinrich Meisel
  • Patent number: 5711765
    Abstract: A process for the direct dyeing of keratin fibers, characterized in that it comprises in placing keratin fibers, to which a dye composition containing at least one cationic direct dye has been applied, in contact with a gas containing water vapor, the temperature of the gas preferably being above 75.degree. C., the contact time between the gas and the fibers to be dyed preferably not exceeding two minutes. According to the invention, the hair is dyed uniformly, from the roots to the tips, regardless of the state of the hair.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: January 27, 1998
    Assignee: L'Oreal
    Inventor: Marie-Pascale Audousset
  • Patent number: 5651794
    Abstract: Dyed cellulosic regenerated elongate members such as fibers are produced by dyeing the regenerated members with a cationic direct dye after formation but before first drying. A method of producing the dyed elongate members comprises forming a dope containing cellulose or a cellulose compound in solution in a solvent, extruding the dope through at least one orifice into a bath containing water to form an elongate extrudate from which solvent is dissolved and/or the cellulose compound is converted to cellulose so as to form the elongate member, dyeing the formed but never dried elongate member with a cationic direct dye and optionally also with an anionic direct dye and then drying for the first time the dyed elongate member.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: July 29, 1997
    Assignee: Courtaulds Plc
    Inventor: James Martin Taylor
  • Patent number: 5587118
    Abstract: The specification describes a conjugate carpet face yarn including trilobal or delta cross-section polyolefin filaments and a plurality of generally co-linear smaller polyamide fibrils embedded within the polyolefin filaments. This yarn has the stain resistant properties of polyolefin based yarns and the resiliency of polyamide based yarns.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: December 24, 1996
    Inventor: William C. Mallonee
  • Patent number: 5582621
    Abstract: Bulk dyeing of plastics using dyestuffs of the formula (I) ##STR1## wherein n denotes 1 or 2, preferably 1,R.sub.o for n=1, denotes aryl, hetaryl or heterocyclylidenemethyl, or for n=2, denotes a direct bond or arylene andthe ring A is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, C.sub.1 -C.sub.4 -alkyloxy, C.sub.6 -C.sub.10 -aryloxy, C.sub.6 -C.sub.10 -aryl- or C.sub.1 -C.sub.4 -alkylsulphonyl, cyano, halogen, in particular chlorine or bromine, or a radical of the formula --COR.sub.1, wherein R.sub.1 represents C.sub.1 -C.sub.4 -alkoxy, amino, C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.6 -C.sub.10 -arylamino, C.sub.1 -C.sub.4 -alkyl or C.sub.6 -C.sub.10 -aryl, or contains a fused-on aromatic or cycloaliphatic ring,the plastics used being, in particular, thermoplastics, preferably vinyl polymers, polyesters or polyamides.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: December 10, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roschger, Stephan Michaelis, Hauke Furstenwerth
  • Patent number: 5567206
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group, consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autioclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions. A method for staining wood includes placing the wood into an autoclave composed of non-rust-resistant steel; submerging the wood in the wood stain; and staining the wood under pressure and temperature conditions effective therefor.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: October 22, 1996
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5530130
    Abstract: Phthaloperinone dyestuffs of the general formula (I) ##STR1## wherein Z denotes SO.sub.2 or CO,A represents optionally substituted alkyl or aryl,and the other substituents have the meanings given in the description, are prepared by condensation of corresponding phthalic acids or functional derivatives thereof and optionally substituted 1,8-naphthalene-diamines.The dyestuffs according to the invention have very good fastnesses and are employed in processes for bulk dyeing plastics.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: June 25, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roschger, Volker Hederich, Stephan Michaelis
  • Patent number: 5520707
    Abstract: Anthraquinone compounds of formula I ##STR1## wherein R.sub.1 and R.sub.2 are methyl and R.sub.3 is propyl, or R.sub.1 and R.sub.2 are ethyl and R.sub.3 is methyl and A.sup.- is a cosmetically acceptable anion, are useful for the dyeing of hair. Compounds of formula I may advantageously be employed with direct dyes. Compositions and a method of use employing same are disclosed.
    Type: Grant
    Filed: August 7, 1995
    Date of Patent: May 28, 1996
    Assignee: Clairol, Inc.
    Inventors: Mu-Ill Lim, Linas Stasaitis, Yuo-Guo Pan
  • Patent number: 5516338
    Abstract: An aqueous dye composition is based upon a mixture of a water-soluble titanium salt, preferably titanium potassium oxalate and a tannin substance, preferably Myrobalan extract. This dye composition may be used to dye either natural fibers, synthetic fibers or blends thereof. The composition is particularly advantageous for either bottom dyeing denim fabric which can then be overdyed with indigo blue dye to provide blue-green hues or as a mordant for a basic dye.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: May 14, 1996
    Inventor: Panemangalore S. Pai
  • Patent number: 5493011
    Abstract: Water-insoluble azo colorants, their preparation and use The invention relates to monoazo and disazo compounds of the formula (I) ##STR1## in which D is the radical of a carbocyclic or heterocyclic diazo or bisdiazo component, R.sup.1 and R.sup.2, independently of one another, are each a substituted or unsubstituted aryl or heteroaryl radical, X.sup.1 and X.sup.2, independently of one another, are each ring-forming ether oxygen or a substituted or unsubstituted imide grouping and n has the value 0 or 1, in which rings A and B, independently of one another, can each be additionally substituted and/or carry substituted or unsubstituted fused rings.These new compounds of the formula (I) are obtained by coupling diazotized amines or diamines of the type D--NH.sub.2 or H.sub.2 N--D--NH.sub.2 with (benzoxazol-2-yl)- or (benzimidazol-2-yl)-arylacetamides.Depending on the presence and length of alkyl chains, the compounds of the formula (I) are suitable for use as pigments, disperse dyes or oil-soluble dyes.
    Type: Grant
    Filed: November 6, 1992
    Date of Patent: February 20, 1996
    Assignee: Hoechst AG
    Inventors: Rudiger Jung, Reinhold Deubel
  • Patent number: 5474578
    Abstract: A hair fiber having a first color is contacted with a dye having the formula I, formula II, formula III or a mixture thereof whereby the fiber has imparted to it a second color, upon subsequent contact with alkaline peroxide the visual appearance of the first color is restored to the fiber.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: December 12, 1995
    Assignee: Clairol, Inc.
    Inventors: Alexander C. Chan, Alice A. Mayer, Jia-Shen Wang, Gottfried Wenke, Mu-Ill Lim
  • Patent number: 5468848
    Abstract: The new basic azo dyestuffs of the formula ##STR1## wherein the symbols have the meaning given in the description, are suitable for dyeing synthetic and naturally occurring substrates which can be dyed with basic dyestuffs.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: November 21, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karin Hassenruck, Peter Wild