Monoazo Patents (Class 8/682)
  • Publication number: 20150037546
    Abstract: A coloring composition for inkjet textile printing, containing water and a dye represented by Formula (I) [R1 represents H, halogen, alkyl, aralkyl, aryl, heteroaryl, alkoxy, or cyano; R2 represents H, halogen, cyano, —COOR6, —COR7, —CONR8R9, or an ionic hydrophilic group; R3 represents alkyl, aralkyl, alkenyl, alkynyl, aryl, or heteroaryl; each of R4 and R5 independently represents H, alkyl, cycloalkyl, aralkyl, alkenyl, alkynyl, aryl, or heteroaryl; R15 represents H or a substituent; X represents alkyl, cycloalkyl, aralkyl, aryl, heteroaryl, —COR12, or —CONR13R14; R6 represents alkyl, aryl, or heteroaryl; each of R7 to R14 independently represents H, alkyl, aryl, or heteroaryl; and a number of ionic hydrophilic groups in one molecule is from 1 to 5].
    Type: Application
    Filed: October 20, 2014
    Publication date: February 5, 2015
    Inventors: Kazunari YAGI, Yasuhiro ISHIWATA, Yutaro NORIZUKI
  • Patent number: 8349029
    Abstract: The present invention relates to azo dyes of the formula (1) in which R, M, and Y are defined as stated in claim 1, to dye mixtures comprising them, to processes for preparing them, and to their use.
    Type: Grant
    Filed: January 30, 2012
    Date of Patent: January 8, 2013
    Assignee: DyStar Colours Deutschland GmbH
    Inventors: Jörg Wörner, Andreas Schrell
  • Patent number: 8328925
    Abstract: The present invention concerns concentrated aqueous solutions of an anionic disazo dye, comprising salts and or the free acids of the anionic dye of the formula (I) and 2-(2-butoxyethoxy)ethanol and the use of these solutions for dyeing and/or printing hydroxyl-containing substrates and for producing inkjet inks.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: December 11, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Ludwig Hasemann
  • Patent number: 8206465
    Abstract: An azo pigment showing excellent coloring characteristics such as tinctorial strength and hue and excellent fastness such as light fastness, and a pigment dispersion containing the azo pigment are provided. An azo pigment represented by the following general formula (1) and a pigment dispersion containing the pigment: Wherein Y, G, X1, X2, R1, R2 and R3 are defined in the claims and in the specification.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: June 26, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Nobuo Seto, Keiichi Tateishi
  • Patent number: 8083811
    Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: December 27, 2011
    Assignee: Huntsman International LLC
    Inventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean Luc Christnacher
  • Publication number: 20110242197
    Abstract: A compound of Formula (1) and salts thereof: wherein: R1 and R2 are independently H or optionally substituted C1-4alkyl; R3 is optionally substituted alkyl, optionally substituted aryl or optionally substituted heteroaryl; R4 and R5 are independently H, optionally substituted alkyl optionally substituted aryl or optionally substituted heteroaryl with the proviso that R4 and R5 do not carry a carboxylic acid substituent; X and Y are independently an acetyl group, an acetate ester group, an amide group, a sulfoxide group, a sulfone group, a phosphonate group, a nitro group, a nitrile group, an isonitrile group, a quaternary amine, a carbonyl group (other than a carboxylic acid), a polyhaloalkyl group or a halogen atom; a+b=0 to 4; n=1 to 6; and m is greater than 0: provided that the compounds of Formula (1) contain at least one substituent selected from the group consisting of —SO3H and —PO3H2. Also compositions, inks, printing processes, printed materials and ink-jet cartridges.
    Type: Application
    Filed: November 26, 2009
    Publication date: October 6, 2011
    Applicants: Fujifilm Imaging Colorants, Limited, Fujifilm Corporation
    Inventors: Clive Edwin Foster, Gavin Wright, Toshiki Fujiwara
  • Patent number: 7909892
    Abstract: The present invention relates storage stable aqueous dye solutions comprising a) 5 to 30% by weight of a dye of the formula in which K is a residue of a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series and M is hydrogen, an alkali metal or alkaline earth metal, ammonium or alkyl ammonium, b) 0.05 to 5% by weight of one or more compounds of the formula or a residue of the formula in which A, X, Y, R, P and Q are defined herein, c) an organic or an inorganic base or mixtures thereof, d) if desired, further additives and e) water, a process for their preparation and the use thereof for the dyeing, in particular of paper.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: March 22, 2011
    Assignee: BASF SE
    Inventors: Holger Lautenbach, Adolf Käser, Michael Heneghan
  • Publication number: 20110027548
    Abstract: Use of the customary dyes for the type of fibre in question and using the customary dyeing and/or printing processes for the type of fibre in question for minimally reducing, retaining or increasing the NIR reflectance, preferably increasing the NIR reflectance, in the region of electromagnetic radiation of wavelength 700 nm to 1100 nm of textile material in relation to the undyed and untreated textile material, characterized in that metal-free dyes are used.
    Type: Application
    Filed: March 27, 2009
    Publication date: February 3, 2011
    Applicants: CLARIANT FINANCE (BVI) LIMITED, SCHOELLER TECHNOLOGIES AG
    Inventors: Rainer Nusser, Martin Leiler, Roland Lottenbach, Hans-Juergen Huebner
  • Patent number: 7713311
    Abstract: The present invention relates to aqueous liquid formulations comprising 5-30% by weight of a dye composition comprising 25-85% by weight of Direct Brown 44 15-75% by weight of Direct Yellow 11 and/or of a dye obtainable by reduction or thermal treatment of Direct Yellow 11 0-15% by weight of one or more blue direct dyes and 0-10% by weight of one or more red direct dyes all based on the dye composition 0.5-15% by weight of one or more alkylamines whose one, two or three alkyl radicals may each be substituted by one or two hydroxyl groups and/or amino groups and/or interrupted by one or two oxygen atoms in ether function, based on the total weight of the aqueous liquid formulation, the sodium content of the liquid formulation not exceeding 0.3% by weight, and also their use for dyeing cellulose material especially paper.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: May 11, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Ingo Klopp, Karl-Heinz Etzbach, Helmut Reichelt
  • Patent number: 7708786
    Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2—Z or —Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: May 4, 2010
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
  • Patent number: 7666232
    Abstract: A reactive trichromatic set comprising (a) at least one of the following reactive red dye of formula (I), wherein R1, R2, R3, X, D, Z, and n are defined the same as in the specification; (b) at least one reactive yellow dye selected from the following Color Index; C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176; and (c) at least one reactive blue dye selected from the following Color Index; C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: February 23, 2010
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Bao-Kun Lai, Te-Chin Sung, Cheng-Hsiang Hsu
  • Patent number: 7637964
    Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (I) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: December 29, 2009
    Assignee: DyStar Textilfarben GmbH & Co.
    Inventors: Stefan Meier, Werner Russ, Joachim Eichhorn
  • Patent number: 7468081
    Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: December 23, 2008
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
  • Patent number: 7455699
    Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: November 25, 2008
    Assignee: DyStar Texilfarben GmbH & Co. Deutschland KG
    Inventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
  • Patent number: 7429279
    Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (i) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: July 26, 2004
    Date of Patent: September 30, 2008
    Assignee: DyStar Textilfarben GmbH + Co. Deutschland KG
    Inventors: Stefan Meier, Werner Russ, Joachim Eichhorn
  • Patent number: 7416593
    Abstract: The invention relates to novel azo dyestuffs of formula (I), the use of such compounds and/or mixtures for printing recording materials, especially paper or papery substrates, textile fiber materials, plastic films and plastic transparencies by the inkjet printing process and also to the recording materials printed thereby
    Type: Grant
    Filed: November 11, 2003
    Date of Patent: August 26, 2008
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Ludwig Hasemann
  • Patent number: 7381228
    Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.
    Type: Grant
    Filed: April 30, 2007
    Date of Patent: June 3, 2008
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
  • Patent number: 7351808
    Abstract: Anionic monoazo dyes of the formula (1) in which A represents 1- or 2-naphthyl residue, which is substituted by a total of one or two sulphonic and/or carboxylic acid groups.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: April 1, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Michael Lennartz, Sandra Weiss
  • Patent number: 7282070
    Abstract: A reactive dye composition having satisfactory reproducibility, leveling, washing off and toughness under balanced affinity and reactivity, and improving Right First Time success ratio, for dyeing a cellulose fiber or fiber materials containing the cellulose fiber. The reactive dye composition comprising: (a) at least one reactive red dyestuff selected from the group consisting of the following formulas, the component (a) is present in an amount ranging from 1% to 99% by weight, and (b) at least one yellow reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176, and at least one blue reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222, the component (b) is present in an amount ranging from 99% to 1% by weight.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: October 16, 2007
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Chien-Yu Chen, Bao-Kun Lai, Ya-Chi Tseng
  • Patent number: 7220843
    Abstract: This invention relates to monoazo, disazo and trisazo colorants of the formula (I) where M represents two hydrogen atoms or one metal ion selected from the group consisting of Cu, Co, Ni, Mn, Zn and Al; A is the radical of a substituted naphthyl or pyrazolyl radical.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: May 22, 2007
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dominique Pflieger, Hans Joachim Metz
  • Patent number: 7217803
    Abstract: The present invention relates to azo dyes of formula (1) which are soluble in organic solvents, wherein R1 is —CN, —COOR5, —CONR6R7 or a heterocyclic ring, R2 is unsubstituted or substituted alkyl, unsubstituted or substituted aryl, —CF3, —COOR5, —CONR6R7 or —COR5, R3 is hydrogen, —SO3M, alkyl, alkoxy, alkylcarbonyl, —NO2 or halogen, R4 is substituted aryl, substituted heteroaryl or an aryl-N?N-aryl radical, wherein one or both of the aryl radicals in aryl-N?N-aryl is/are unsubstituted or substituted, or a radical heteroaryl-N?N-heteroaryl, wherein one or both of the heteroaryl radicals in heteroaryl-N?N-heteroaryl is/are unsubstituted or substituted, R5 is hydrogen, alkyl or unsubstituted or substituted aryl, R6 is hydrogen, alkyl or unsubstituted or substituted aryl, R7 is hydrogen, alkyl or unsubstituted or substituted aryl, M+ is a cation, n is a number 1, 2 or 3 and m is a number 1, 2 or 3, to a process for the preparation thereof and to the use thereof in the production of colored plastics or polymeric
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: May 15, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Leonhard Feiler, Thomas Raimann, Thomas Eichenberger, Max Hügin
  • Patent number: 7066969
    Abstract: The present invention relates to novel compounds of the formulae A, D1, D2, R1 and n are as defined in the description the compounds being in an internal or external salt form, or mixtures of compounds (1) and (2), a process for their preparation and preparations containing them used for dyeing paper.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: June 27, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Michael Lennartz, Dölf Käser, Sandra Weiss
  • Patent number: 7056374
    Abstract: An aqueous ink composition which comprises a compound represented by the formula (1) or the salt thereof: (1) wherein R1 and R2 independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkanoylamino group, an alkoxyalkoxy group, a sulfonic acid group, a carboxyl group or an ureido group, m and n independently represent 1 or 2, and M1 represents a cation from a hydrogen atom, an alkali metal, an alkaline earth metal or an organic amine, or an ammonium ion. The composition has a hue and clarity suitable for the ink-jet recording, and can provide a recorded matter which is excellent in light resistance, water resistance and moisture resistance and can be controlled with respect to the degree of the discoloration or fading by the action of ozone.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: June 6, 2006
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Hirokazu Kitayama, Yasuo Shirasaki, Toru Tabei
  • Patent number: 6997978
    Abstract: The present invention is drawn to magenta dye blends and magenta ink-jet inks that can be used in ink sets for creating photo quality images. The dye blend can comprise a nickel-containing azo dye blended with a rhodamine dye at a 1:80 to 125:4 weight ratio.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: February 14, 2006
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Alexey S Kabalnov, Charles G. Dupuy, Patricia A Wang
  • Patent number: 6991676
    Abstract: The present invention is drawn to dye sets for formulating ink-jet ink sets, and to specific ink sets. The dye set can comprise cyan colorant including a phthalocyanine dye; magenta colorant including a copper- or nickel-containing azo dye; and yellow colorant including at least one of Yellow 1189 dye and Yellow 104 dye yellow colorant having the structure Formula 1: wherein R1 is H, SO3M, COOM, or SO2NH2; and wherein R2 is H, SO3M, COOM, or SO2NH2; and wherein R3 is H or CH3; and wherein n and m are 2, 3, 4, 5 or 6; and wherein M is H, Na, Li, K, ammonium, ammonium substituted with alkyl or combinations thereof. Optionally, a cyan triarylmethine dye such as Acid Blue 9, or another similar cyan dye, can be blended with the phthalocyanine dye; a rhodamine dye can be blended with the copper- or nickel-containing azo dye; and/or Acid Yellow 17 or Acid Yellow 23 can be blended with Formula 1.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: January 31, 2006
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Alexey S Kabalnov, Charles G. Dupuy, Luanne J. Rolly, Naomi Oak, Patricia A Wang
  • Patent number: 6929688
    Abstract: Monoazo dyes of general formula (IV) wherein R1, R2, R3, X, M and n are as described in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and textile materials and especially for the preparation of inks for ink jet printing.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: August 16, 2005
    Assignee: Ilford Imaging Switzerland GmbH
    Inventors: Kurt Baettig, Thomas Stauner
  • Patent number: 6712862
    Abstract: Granular compacts (G) of a mixture of (A) at least one water-soluble dye or optical brightener, and (B) extender and, optionally, (C) at least one hydrophilic surfactant and/or (D) further additives, additionally containing (E) a dust-binding oil, are low-dust dry formulations of high bulk density which feature good dissolution, transportation and storage properties and are outstandingly suitable for the dyeing of the respective substrates.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: March 30, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Roland Grimm, Claude Haldimann, Werner Schumann
  • Patent number: 6709502
    Abstract: Monoazo dyes of formulas (IV) wherein R1, R2, R3, m, n and M are as described in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and especially for the preparation of inks for ink jet printing.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: March 23, 2004
    Assignee: Ilford Imaging Switzerland GmbH
    Inventor: Kurt Baettig
  • Publication number: 20030221588
    Abstract: Monoazo dyes of general formula (IV) 1
    Type: Application
    Filed: May 23, 2003
    Publication date: December 4, 2003
    Applicant: ILFORD IMAGING SWITZERLAND GmbH.
    Inventors: Kurt Baettig, Thomas Stauner
  • Publication number: 20030177944
    Abstract: Compounds of the formula I 1
    Type: Application
    Filed: February 13, 2003
    Publication date: September 25, 2003
    Inventors: Klaus Kunde, Stefan Ehrenberg
  • Patent number: 6583273
    Abstract: This invention relates to dyes of formula wherein R1 is hydrogen, halogen, C1-C8alkyl, —NH—CO—C1-C4alkyl or phenyl, R2 is hydrogen, halogen, C1-C8alkyl, C1-C8alkoxy, —NH—CO—C1-C4alkyl or phenyl, R3 is hydrogen, C1-C8alkyl or phenyl, R4 is hydrogen, halogen or C1-C8alkyl, and X is —CO—, — COO—or —SO2—, and n is the number 1 or 2, to their preparation and to their use for dyeing or printing natural and synthetic materials, in particular synthetic polyamide fibre materials.
    Type: Grant
    Filed: May 4, 2000
    Date of Patent: June 24, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Pierre Bacher, Jean-Marie Adam
  • Publication number: 20030106169
    Abstract: A dye composition for dyeing human keratin fibres, such as hair, comprising at least one monocationic monoazo dye of formula (I)
    Type: Application
    Filed: September 26, 2002
    Publication date: June 12, 2003
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6521032
    Abstract: Inks comprising a dye of formula (1) wherein X is hydroxy, unsubstituted or hydroxy-substituted C1-C4alkyl, vinyl or a radical —CH2—CH2—Z, wherein Z is a group removable under alkaline conditions or is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24alkylamino unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or unsubstituted or further substituted C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino unsubstituted or su
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: February 18, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 6511535
    Abstract: The invention relates to a method for printing fibrous textile materials using the ink-jet printing technique, wherein the fibrous materials are printed with an aqueous ink that comprises at least one acid dye according to claim 1 and that has a viscosity of from 1 to 40 mPa·s.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: January 28, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Roger Lacroix, Peter Scheibli, Mickael Mheidle
  • Patent number: 6365721
    Abstract: Water-soluble monoazo dyes, their preparation and use Dyes of the formula (1): in which M is hydrogen, ammonium, an alkali metal or the equivalent of an alkaline earth metal; X is sulfonyl or —COCH2O—; R1, R2 and R3 independently of one another are hydrogen, halogen, for example fluorine, chlorine or bromine, unsubstituted or chloro- or hydroxy-substituted C1 to C4 alkoxy, for example 2-chloroethoxy or 2-hydroxyethoxy, and the sulfo group is in position 3 or 4 to the NH group, their preparation, and their use for dyeing or printing carboxamido-containing materials.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: April 2, 2002
    Assignee: DyStar Textilfarben GmbH & Co.
    Inventor: Aloys Engel
  • Patent number: 6297362
    Abstract: Compound of the formula (I) wherein R is hydrogen or optionally substituted C1-C6-alkyl, R1 is hydrogen or C1-C6-alkyl, R2 is hydrogen, optionally substituted C1-C6-alkyl or optionally substituted phenyl, the ring D is optionally substituted by one or more identical or different substituents selected from the group consisting of C1-C6-alkyl, C1-C6-alkoxy, halogen, especially F, Cl and Br, and SO3H, m is 0 or 1, n is 1, 2 or 3 and as a function of n X is a mono-, di- or trivalent acyl radical, pyrimidine or 1,3,5-triazine radical which is not fiber-reactive.
    Type: Grant
    Filed: October 1, 1999
    Date of Patent: October 2, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Kunde, Michael-Thomas Jörss, Peter Wild
  • Patent number: 6241789
    Abstract: Process for dyeing or printing paper, films of plastic or fibre material containing hydroxyl groups or containing nitrogen with reactive dyes, which comprises using at least one reactive dye of the formula (1) from the following group a) and at least one reactive dye from the following groups b), c) and d): a) green- or blue-dyeing reactive dyes of the formula (1) b) blue-dyeing reactive dyes of the formula (2) or (3) c) red-dyeing reactive dyes of the formula (4) d) yellow- or orange-dyeing reactive dyes of the formula (5)
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: June 5, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Scheibli, Peter Aeschilmann, Urs Lehmann, Marcel Frick
  • Patent number: 6080209
    Abstract: Stable aqueous dye compositions containing at least one anionic colorant and at least one pigment and a polyanionic thickening agent. The dye compositions may be used to dye leather.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: June 27, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Wiesenfeldt, Johannes Peter Dix, Rudolf Paulus, Manfred Herrmann
  • Patent number: 6045593
    Abstract: The invention is a composition of matter useful as an acid yellow dye having formula (I) ##STR1## wherein: X is hydrogen or SO.sub.3.sup.- M.sup.+ ; M.sup.+ Na.sup.+, Li.sup.+, K.sup.+, NH.sub.4.sup.+, or hydroxyalkylammonium of the formula [H--(OCH.sub.2 CH.sub.2).sub.n ].sub.p NH.sub.m, where n is 1 to 5, p is 1 to 3, and p+m is 4; R.sub.1 is hydrogen, a metal ion, an alkyl or C.sub.1-4, of hydroxyalkyl of C.sub.1-4, and combinations thereof; and R.sub.2 is an unsubstituted aromatic ring or a substituted aromatic ring having at least one substituent, provided that when one of the substituents is SO.sub.3.sup.- M.sup.+, X is hydrogen; and combinations thereof. The invention also includes a process for dyeing a material with this compound and the material so dyed.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: April 4, 2000
    Inventor: Howard L. Smith
  • Patent number: 6042621
    Abstract: The application is concerned with a compound of the formula (I) ##STR1## and a process for making the same. The compound is useful as fiber-reactive dyestuff in dyeing or printing onto hydroxy- or nitrogen-containing substrates. A printing composition comprising this fiber-reactive dyestuff and a copper phthalocyanine allows to obtain dyeings with less catalytic fading.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: March 28, 2000
    Assignee: Clariant Finance (BV) Limited
    Inventors: Roland Wald, Paul Doswald
  • Patent number: 5756690
    Abstract: A red reactive dye having the following formula (I) in its free acid form: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W (wherein W is a group splittable by alkali), A is a C.sub.2-3 alkylene group or a C.sub.2-3 alkylenoxy C.sub.2-3 alkylene group, E is a hydrogen atom, a C.sub.1-3 alkyl group or --A--SO.sub.2 X (wherein A and X are as defined above), n is 0 or 1, l is 1 or 2, m is 0 or 1, and R is a hydrogen atom, --OH, --CN, --CH.sub.3, --CF.sub.3, --SO.sub.3 H, --COOH, --CH.sub.2 SO.sub.3 H or --CH.sub.2 SO.sub.2 X (wherein X is as defined above), provided that a compound of the formula (I) wherein R is a hydrogen atom, each of m and n is 0, l is 1, and --SO.sub.2 X is --SO.sub.2 CH.dbd.CH.sub.2 which is bonded at the ortho position to the azo group, is excluded.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: May 26, 1998
    Assignee: DyStar Japan Ltd.
    Inventors: Toshio Hihara, Yousuke Takahashi
  • Patent number: 5746778
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autoclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: May 5, 1998
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5725606
    Abstract: Dye mixtures comprising at least one dye of formula ##STR1## together with at least one dye of formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 -alkanoylamino, halogen or sulfo,R.sub.3 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or sulfo, andY is C.sub.1 -C.sub.4 alkyl or phenyl or naphthyl, each of which is unsubstituted or substituted byC.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or sulfo, which dye mixtures contain at least 10% by weight of one or more than one dye of formula (1), based on the total amount of the dyes of formulae (1) and (2), dye nitrogen-containing or hydroxyl group-containing fiber materials with good properties.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: March 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Guido Jordine
  • Patent number: 5693103
    Abstract: A single bath process for exhaust dyeing polyester and cotton fiber blends by the use of a fiber reactive, vinyl sulfone dye in admixture with a disperse dye under alkaline pH conditions.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: December 2, 1997
    Assignee: Dystar, L.P.
    Inventors: Thomas Van Chambers, Christine Feuchtner
  • Patent number: 5690698
    Abstract: A dye mixture of azo dyes having fiber-reactive groups of the vinylsulfone series, comprising one or more navy-blue disazo dyes with the bivalent 1-amino-8-hydroxy-3,6-disulfo-naphthylene coupling component, one or more red-dyeing mono azo dyes, containing a phenylamino-chlorotriazinylamino-disulfo-naphthol-coupling component and one or more orange-dyeing monoazo dyestuffs with an amino-sulfonaphthol-coupling component, which dye mixtures are suitable for dyeing hydroxy- and/or carboxamido-groups containing materials, in particular fiber materials, such as cellulose fibers, for example cotton, wool and synthetic polyamide fibers.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: November 25, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Von Der Eltz, Werner Hubert Russ, Dirk Buchwald
  • Patent number: 5611821
    Abstract: A black reactive dye composition comprising a black reactive dye of the formula (I) and multiple mono ##STR1## azo reactive dye. The black reactive dye composition is suitable for exhaust dyeing, printing, discharge printing and continuous dyeing.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: March 18, 1997
    Assignee: Everlight USA, Inc.
    Inventors: Huei C. Huang, Sheue R. Lee
  • Patent number: 5607502
    Abstract: A process has been found for dyeing and printing pater, wood, plastic or metal, in which dyestuffs which, in the form of the free acid, correspond to the formula (I) ##STR1## wherein A denotes a phenol radical which is optionally substituted by alkyl or cycloalkyl andn represents 0 or 1,are employed.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: March 4, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karin Hassenruck, Peter Wild, Martin Michna
  • Patent number: 5567206
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group, consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autioclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions. A method for staining wood includes placing the wood into an autoclave composed of non-rust-resistant steel; submerging the wood in the wood stain; and staining the wood under pressure and temperature conditions effective therefor.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: October 22, 1996
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5556435
    Abstract: Mixtures of fiber-reactive dyes in brilliant orange to red shades comprise one or more disazo dyes of the formula ##STR1## and one or more monoazo dyes of the formula ##STR2## in which: D.sup.1 D.sup.2 and D.sup.3, which are identical to or different from one another, are phenyl or 2-naphthol substituted by vinylsulfone, vinylsulfone, M is hydrogen or an alkali metal, m, n and p are zero or 1, X is chlorine, fluorine, hydroxy, cyanoamino or lower alkylamino, with W being a 2-chloro- or 2-fluoro-s-triazin-6-yl radical which is substituted in position 4 by chlorine, hydroxy, phenoxy, morpholino or by a radical corresponding to one of the definitions of D.sup.1 or by a phenyl radical, which may be substituted by sulfo, carboxy, methyl, ethyl, methoxy, ethoxy and/or hydroxy, or D.sup.3 and W are as further described in the specification.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: September 17, 1996
    Assignee: Hoechst AG
    Inventors: Werner H. Russ, Kurt Hussong, Karl Krieger, Uwe Mrotzeck
  • Patent number: 5496381
    Abstract: Novel dye mixture comprising three to seven fiber-reactive dyes selected from dyes of the below-indicated and defined formulae (1) to (7) with the proviso that the dye mixture contain at least one representative of the formulae (1) and/or (2), at least one representative of the formulae (3) and/or (4) and at least one representative of the formulae (5) and/or (6) and/or (7): ##STR1##
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: March 5, 1996
    Assignee: Hoechst AG
    Inventors: Werner H. Russ, Kurt Hussong