Metallized Dye, Including Metallization During Dyeing (i.e., Including In Situ Forming Of Metallized Dye) Patents (Class 8/685)
  • Patent number: 4585459
    Abstract: A process is described for separating sodium sulfate from aqueous solutions, containing less than 2% by weight of chloride, of certain fiber-reactive copper-formazan dyestuffs wherein this dyestuff solution is cooled down to a temperature between +5.degree. C. and -15.degree. C. In the course of the cooling the sodium sulfate precipitates in the form of the decahydrate and can be separated off in conventional manner, for example by filtration. The products obtained in this way are liquid low-salt aqueous copper-formazan dyestuff preparations which contain less than 4% by weight of sodium sulfate.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: April 29, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Konrad Opitz, Gunther Schwaiger
  • Patent number: 4568351
    Abstract: A textile finishing process in which there is employed, as a pH regulator, a compound or a mixture of compounds of formula I ##STR1## in which p is from 1 to 20,R is hydrogen, C.sub.1-3 alkyl or C.sub.1-3 alkyl substituted by hydroxyR' has independently one of the significances given for R or is --CO--R andA is --CH.sub.2 CH.sub.2 --; --CH.sub.2 --CH.sub.2 --CH.sub.
    Type: Grant
    Filed: May 17, 1984
    Date of Patent: February 4, 1986
    Assignee: Sandoz Ltd.
    Inventors: Jose M. Palleiro Cardona, Karl-Heinz Weible
  • Patent number: 4563192
    Abstract: The invention relates to a process for dyeing synthetic polyamide fibre material with dyes or dye mixtures in the presence of a mixture of dyeing assistants, which comprises using for the dyeing of these materials an aqueous liquor which contains at least one anionic dye which, under the defined dyeing conditions, has a degree of exhaustion of at least 95% at 1/1 standard depth of shade, and a dyeing assistant mixture containing an anionic compound, a quaternary compound and a non-ionic compound, and wherein the liquor contains an alkali metal salt and an organic acid, and finishing the dyeing at pH 5-7, preferably pH 5.5-6, and at a temperature of 95.degree. to 130.degree. C.The process according to the invention is suitable for dyeing synthetic polyamide materials, producing level dyeings having good fastness properties with all types of dye or mixtures of dyes of identical or different types.
    Type: Grant
    Filed: September 14, 1984
    Date of Patent: January 7, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Salathe, Hermann Flensberg, Harry Schaetzer
  • Patent number: 4563193
    Abstract: The novel asymmetric 1:2 chrome complex dyes of the formula I given in claim 1 are suitable in particular for dyeing wool or polyamide and especially leather.
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: January 7, 1986
    Assignee: Ciba Geigy Corporation
    Inventor: Fabio Beffa
  • Patent number: 4559058
    Abstract: A precondensate obtained by reacting(A) the product of reacting a mono- or polyfunctional primary or secondary amine with cyanamide, dicyandiamide, guanidine or biguanidine and(B) an epihalohydrin is obtained in the form of a stable aqueous dispersion by acidifying the reaction product, optionally in the presence of a water-soluble polymer. The product is useful as an after-treatment agent to improve the fastness of dyeings on cotton, wool or silk.
    Type: Grant
    Filed: June 28, 1984
    Date of Patent: December 17, 1985
    Assignee: Sandoz Ltd.
    Inventors: Brian Bennett, Donald K. Clough
  • Patent number: 4556401
    Abstract: The partly known blue dyestuffs of the formula ##STR1## wherein R.sub.1 denotes hydrogen, alkyl, aralkyl, alkenyl, cycloalkyl or aryl,R.sub.2 denotes hydrogen or alkyl,Me.sup.(+) denotes a cation andn denotes 1 or 2,are highly suitable for the trichromatic dyeing of polyamide fibre materials, producing level dyeings thereon with a good standard of fastness.
    Type: Grant
    Filed: August 3, 1984
    Date of Patent: December 3, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Robert Weitz, Rutger Neeff, Herbert Hugl
  • Patent number: 4553976
    Abstract: The invention describes a process for dyeing or printing natural or synthetic polyamide fibre material by a rapid fixation method, which comprises the use of dyes or mixtures of dyes of the formulae as defined in the description in a continuous dyeing method or printing method, and fixing the dyes or prints by steaming for less than 3 minutes such that at least 95% fixation of the dyes is achieved. The process is particularly suitable for combination dyeing and polyamide carpet printing, and produces level dyeings and prints having excellent fastness properties.
    Type: Grant
    Filed: January 12, 1984
    Date of Patent: November 19, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Helmut Raisin, Bernard C. Teutelink
  • Patent number: 4543103
    Abstract: A glass substrate is dyed or printed with a water-soluble polycationic dyestuff in the absence of a size or binding agent. The resulting dyeings have good rubbing fastnesses.
    Type: Grant
    Filed: April 16, 1984
    Date of Patent: September 24, 1985
    Assignee: Sandoz Ltd.
    Inventor: Jurg Troesch
  • Patent number: 4541831
    Abstract: Described is a process for the production of substantially dustless water-soluble dye or optical brightener compositions, which process comprises mixing a dry, solid inorganic salt, heated to at least 50.degree. C., with a mixture of at least one dye or optical brightener, an adhesive as e.g. sorbitol, a dust binding surface active agent and further additives. Such compositions are negligibly dusty to dustfree, and retain these properties even after storage for months, particularly in the case where spray-dried material is used.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: September 17, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Walter Gunther, Kurt Hintermayr
  • Patent number: 4525170
    Abstract: The invention relates to solid formulations of metal complex dyes, which formulations are obtained by dissolving or suspending at least one metal complex dye in water with the addition of an anionic dispersant or mixture of dispersants, and 1 to 20% by weight, based on the final formulation, of a non-ionic ethylene oxide adduct having a molecular weight of 200 to 5000, and optionally further ingredients, subsequently mixing the components and spray drying the solution or suspension.Such formulations are readily wettable and have a cold water dispersibility of .gtoreq.30 g/l.
    Type: Grant
    Filed: May 19, 1983
    Date of Patent: June 25, 1985
    Assignee: Ciba-Geigy Corporation
    Inventor: Paolo Balliello
  • Patent number: 4515599
    Abstract: A process for dyeing paper which comprises the use of dyes of the formula ##STR1## wherein R is hydrogen, hydroxyl or amino, X is the azoxy or azo group, and n is 1 or 2, and the bonds of the complexing oxygen atom in the .alpha.-position and of the azo group in the .beta.-position at the naphthalene nuclei are mutually interchangeable. Dyeings of good wetfastness and lightfastness are obtained.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: May 7, 1985
    Assignee: Ciba Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 4515598
    Abstract: A process for dyeing or printing fiber materials containing hydroxy and/or carbonamide groups, in which process a fiber-reactive, water-soluble dyestuff of the type defined below is applied to the fiber material and is then fixed on the fiber material at an ordinary or elevated temperature, if appropriate in the presence of agents having an alkaline reaction. This water-soluble dyestuff, which contains at least one sulfonic acid group, contains one or more groupings belonging to the group comprising the formulae (1a), (1b) and (1c)--SO.sub.2 --CH.dbd.CH.sub.2 (1a)--SO.sub.2 --CH.sub.2 --CH.sub.2 --Hal (1b)--SO.sub.2 --CH.sub.2 --CH.sub.
    Type: Grant
    Filed: November 10, 1983
    Date of Patent: May 7, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Fritz Meininger, Joachim W. Otten, deceased, by Ursula Otten, heir, by Anna G. Rudolph nee Otten, heir
  • Patent number: 4514188
    Abstract: Use of mono-copper complexes of dyestuffs of the formula ##STR1## wherein X is H or SO.sub.3 H andR is H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, halogen or sulpho,and of mixtures thereof with the bis-copper complexes of (II) in amounts of up to 50% by weight, for dyeing natural and synthetic materials, in particular cellulose materials, leather, wool and polyamide.
    Type: Grant
    Filed: October 3, 1983
    Date of Patent: April 30, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Michna, Hermann Henk
  • Patent number: 4507124
    Abstract: The dyes of the formula I ##STR1## in which Me is cobalt or chromium, A and A' independently of each other are each the radical of an amine of the benzene series which carries the hydroxyl group in the o-position relative to the azomethine group, Ar.sub.1 and Ar.sub.3 independently of each other are each a substituted or unsubstituted phenylene or naphthylene radical, Ar.sub.2 and Ar.sub.4 independently of each other are each a substituted or unsubstituted benzene or naphthalene radical, m and n independently of each other are each 0 or 1, p is an integer from 3 to 6 and Ka.sym. is a cation, are suitable for dyeing polyamides, particularly wool and leather.
    Type: Grant
    Filed: June 20, 1983
    Date of Patent: March 26, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Alois Puntener, Fabio Beffa
  • Patent number: 4502860
    Abstract: Dyes of the formula I ##STR1## in which A, B, C, D, E, F, Z, Z', X, X', n, n.sub.1, n.sub.2 and n.sub.3, p and Ka.sup..sym. are as defined in claim 1, are particularly suitable for dyeing wool or polyamide and especially leather.
    Type: Grant
    Filed: June 20, 1983
    Date of Patent: March 5, 1985
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerhard Back
  • Patent number: 4502865
    Abstract: Novel chromium complex dyes are disclosed which have the formula ##STR1## wherein S.sub.1 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical, an acylamino or arylazo group,S.sub.2 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical,S.sub.3 represents a hydrogen atom, a nitro group or a halogen atom,P is 1 or 2,R represents a fluorochloropyrimidyl or fluorotriazinyl radical, a chloroacetyl, bromoacetyl, .alpha.-chloro- or .alpha.-bromoacryloyl radical or an .alpha.,.beta.-dichloro- or .alpha.,.beta.-dibromopropionyl radical, andK.sup..sym. represents a cation.
    Type: Grant
    Filed: December 2, 1983
    Date of Patent: March 5, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Back, Fabio Beffa, Hans-Ulrich Sch/u/ tz
  • Patent number: 4496364
    Abstract: A process for dyeing a voluminous flat form polyamide substrate with anionic dyestuffs according to the cold pad-batch method, which process comprises the step of selecting the initial pH of the dyeing liquor within a range depending on the affinity of the substrate for anionic dyestuffs and the molecular weight of the anionic dyestuffs so as to give a substantial linear exhaustion of the dyeing liquor, the dyeing liquor being free from a thickening, swelling or foaming agent.
    Type: Grant
    Filed: April 25, 1983
    Date of Patent: January 29, 1985
    Assignee: Sandoz Ltd.
    Inventor: Hans-Peter Stakelbeck
  • Patent number: 4469485
    Abstract: Disclosed are the 1:2 chromium complex of the formula ##STR1## and the alkali metal salts thereof which are useful for the coloration of oxide layers produced on aluminum and alloys thereof and for dyeing natural and synthetic polyamides.
    Type: Grant
    Filed: August 22, 1983
    Date of Patent: September 4, 1984
    Assignee: Sandoz Ltd.
    Inventor: Hans Grossmann
  • Patent number: 4465490
    Abstract: A process for the continuous dyeing of fabric webs, in which the fabric web is impregnated at a temperature between 20.degree. and 95.degree. C. with an aqueous liquor which contains dissolved and/or dispersed dyestuffs and squeezed, and the dyestuffs are fixed in a steam/air mixture, which comprises fixing the dyestuff without the impregnated fabric having been dried at an intermediate stage, keeping the dry temperature of the steam/air mixture between 110.degree. and 140.degree. C., adjusting the steam content of the steam air mixture in such a way that the wet temperature of the moist fabric web is between 50.degree. and 95.degree. C., and fixing the dyestuffs for at least 20 seconds.
    Type: Grant
    Filed: February 16, 1983
    Date of Patent: August 14, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hans-Ulrich von der Eltz
  • Patent number: 4453942
    Abstract: The dyes of the formula I given in claim 1 are suitable for dyeing furs and in particular leather.They are preferably used in admixture with a blue dye and a red dye for the trichromatic dyeing of leather.
    Type: Grant
    Filed: December 10, 1982
    Date of Patent: June 12, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Alois Puntener
  • Patent number: 4444564
    Abstract: The invention relates to a process for the non-skittery and level dyeing of fibre material made of natural polyamides, with dyes or mixtures of dyes in the presence of a mixture of dyeing assistants, which comprises using for dyeing these materials an aqueous liquor which contains at least one anionic wool dye which, under the defined dyeing conditions at 1/1 standard depth, exhausts to at least 95%, and a dyeing assistant mixture containing an anionic compound of the formula ##STR1## in which R is an alkyl or alkenyl radical having 12 to 22 carbon atoms, M is hydrogen, an alkali metal or ammonium, and m and n are integers such that the sum of m and n is 2 to 14, a quaternary compound of the formula ##STR2## in which R', independently of R, is what R has been defined as, A is an anion, Q is a substituted or unsubstituted alkyl radical, and p and q are integers such that the sum of p and q is 20 to 50 , and a non-ionic compound of the formula ##STR3## in which R", independently of R, is what R has been defined
    Type: Grant
    Filed: March 11, 1983
    Date of Patent: April 24, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Salathe, Hermann Flensberg, Harry Schaetzer
  • Patent number: 4417898
    Abstract: The invention relates to a process for continuous dyeing a cellulosic fibrous substrate with a direct or reactive dye comprising the steps of(a) applying to the substrate an aqueous dyeing liquor containing an alkanolamine, followed by(b) fixing the dyeings, and finally(c) after-treating the dyed substrate with a fixing agent,the resulting dyeings having improved wet fastnesses.
    Type: Grant
    Filed: September 8, 1982
    Date of Patent: November 29, 1983
    Inventors: Rolf Hasler, Francis Palacin
  • Patent number: 4400504
    Abstract: The invention relates to new dioxazine reactive dyestuffs of the formula ##STR1## a process for their preparation and their use in dyeing and printing fibre materials which contain hydroxyl groups or amide groups.In formula (I):D denotes a radical of the dioxazine system of the formula ##STR2## the radicals Y, Z, A, X.sub.1 and X.sub.2 as well as m and n having the meaning indicated in the text of the application.The invention further relates to a process for the preparation of these new dioxazine reactive dyestuffs as well as their use in dyeing and printing fibre materials which contain hydroxyl groups or amide groups.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: August 23, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Klaus Wunderlich
  • Patent number: 4383835
    Abstract: The light fastness of polyamide dyeings can be improved by treating polyamide fibre materials, before, during or after dyeing, with copper complexes of the reaction products of salicylaldehydes with amines (for example cyclohexylamine), or with copper complexes of o-hydroxybenzophenones.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: May 17, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reinhard Preuss, Joachim Grutze, Ulrich Beck, Hellmuth Pantke, Karl Vogel
  • Patent number: 4371371
    Abstract: A process is provided for dyeing textile materials in a solid shade with a jet injection dyeing apparatus, including conveying means for transporting the textile, jet orifices for delivering dye to said textile material, and control means for supplying data to control the operation of the application of dye from the jet orifices to the textile material, which comprises the steps of: modifying the textile material prior to dyeing of same by applying to said textile material an aqueous admixture containing an effective minor amount of a thickening agent to maintain the viscosity of said aqueous admixture at from about 150 to about 750 centipoises, preferably about 200 to about 400 centipoises, to thoroughly wet said textile material; dyeing said textile material in a solid shade with an acid dye composition having a viscosity of from about 150 to about 750 centipoises, preferably from about 200 to about 400 centipoises, by applying said dye composition by means of said jet injection dyeing apparatus in an amoun
    Type: Grant
    Filed: June 15, 1981
    Date of Patent: February 1, 1983
    Assignee: Milliken Research Corporation
    Inventor: Joseph J. Smrekar
  • Patent number: 4358287
    Abstract: 1:2 Metal complexes of the formula ##STR1## in which each of X.sub.1 and X.sub.2, independently, is --COO-- or --O--,each of B.sub.1 and B.sub.2, independently, is a radical of a coupling component of the benzene or oxyquinoline series,M is a metal capable of forming a 1:2 complex and,each of ##STR2## independently, is the radical of a diazo component of the benzene series, with the proviso that at most one of such diazo component radicals contains a single sulpho group,and mixtures thereof with one or more of the corresponding symmetrical 1:2 metal complexes,which complexes and mixtures of complexes are in free acid or salt form and are useful as anionic dyes for dyeing and printing substrates such as natural and regenerated cellulose, natural and synthetic polyamides, polyurethanes and polymers modified to contain basic groups, especially leather.
    Type: Grant
    Filed: April 13, 1981
    Date of Patent: November 9, 1982
    Assignee: Sandoz Ltd.
    Inventors: Heinz Wicki, Claude Vogel
  • Patent number: 4343620
    Abstract: A propylene oxide polyadduct containing carboxyl groups, or a salt thereof, obtained from(a) an adduct of propylene oxide and an aliphatic alcohol having 3 to 10 carbon atoms which is at least trihydric,(b) an aliphatic dicarboxylic acid or the anhydride thereof having 2 to 10 carbon atoms or a mono- or di-lower alkylester of said dicarboxylic acids,(c) an aliphatic diol having an average molecular weight of at most 2,000,(d) a fatty acid having 8 to 22 carbon atoms and(e) an aromatic dicarboxylic acid or the anhydride thereof having 8 to 12 carbon atoms; it is in particular useful as dyeing assistant for the dyeing of fibrous material made of or containing wool with anionic dyes.
    Type: Grant
    Filed: December 22, 1980
    Date of Patent: August 10, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Abel, Paul Schafer
  • Patent number: 4295852
    Abstract: Polyamide fibre materials are dyed with acid dyestuffs and/or metal complex dyestuffs in the presence of compounds of the formula ##STR1## in which R represents a C.sub.4 -C.sub.12 -alkyl, C.sub.1 -C.sub.12 -alkoxy, phenyl, cyclohexyl or C.sub.2 -C.sub.10 -hydroxyalkoxy radical,R.sub.1 represents hydrogen or a C.sub.1 -C.sub.4 -alkyl radical,n represents an integer from 1 to 10 andm represents a number from 1 to n+1,or water-soluble salts thereof.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: October 20, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Walz, Joachim Fiegel
  • Patent number: 4268668
    Abstract: An acid monomethine-metal complex dyestuff of the formula ##STR1## wherein M, Z, R, A, Y, n, a and b have the meaning given in the description.The acid metal complex dyestuffs of the formula I are valuable dyestuffs which are outstandingly suitable for dyeing and printing wool, silk and especially synthetic polyamides, such as NYLON and PERLON, in very clear shades ranging from yellow to blue, and are distinguished by high tinctorial strength, good build-up capacity and affinity and very good fastness characteristics, especially fastness to light.
    Type: Grant
    Filed: October 19, 1979
    Date of Patent: May 19, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Peter Rasche
  • Patent number: 4252529
    Abstract: Water-soluble copper, cobalt and chromium complex monoazo compounds of which the metal-free monoazo compound contains as diazo component an aminophenol or aminonaphthol compound subtituted by a fiber-reactive radical of the vinyl sulfone series, the aminophenol possibly being substituted by a lower alkyl, lower alkoxy, nitro, sulfonic acid group, or a chlorine or bromine atom and the naphthol possibly being substituted by a sulfo group, and as coupling component a 6-sulfonaphthol(8) which may be substituted by a sulfo group in the adjacent aromatic nucleus and must be substituted by the monoamide radical of succinic acid, glutaric acid or adipic acid.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: February 24, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hans H. Steuernagel
  • Patent number: 4231749
    Abstract: Dyeing with a dyestuff containing a metal or from a bath in the presence of one or more metallic elements, especially alkaline-earth or heavy metals, is carried out in the presence of a sequestrating agent or sequestrant. According to the invention the sequestrant is a derivative of a phosphonic acid having no effect on the physical-chemical characteristics of the dyestuff which is used and is preferably a salt of a hydroxy-lower-alkane-phosphonic acid.
    Type: Grant
    Filed: April 24, 1979
    Date of Patent: November 4, 1980
    Assignee: Manufacture de Produits Chimiques Protex Societe Anonyme
    Inventor: Jean Balland
  • Patent number: 4219332
    Abstract: A process for dyeing wool or wool/synthetic blends with 1:1 metal complex dyes or acid metal-free wool dyes from a strongly acid aqueous bath, which comprises dyeing said material in the presence of(a) a quaternization product of a polyalkylene oxide adduct of a fatty amine containing at least 16 carbon atoms and 15 to 100 moles of alkylene oxide, and(b) a free or etherified N-methylolurea or N-methylolmelamine.
    Type: Grant
    Filed: September 29, 1978
    Date of Patent: August 26, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Abel, Charles Soiron