With Organic Material Patents (Class 8/94.33)
  • Patent number: 10815542
    Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition according to the invention and the method according to the invention are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.
    Type: Grant
    Filed: May 13, 2019
    Date of Patent: October 27, 2020
    Assignee: TFL Ledertechnik GmbH
    Inventors: Catherine Gabagnou, Nina Schulte-Gauczinski, Grigore Daniel Herta, Jens Fennen
  • Patent number: 10745333
    Abstract: A method for the manufacture of a sulfonated phenol for use as a cumene hydroperoxide decomposition catalyst can comprise: combining phenol and a sulfonating agent at a first temperature that is 1° C. to 15° C. higher than a melting temperature of the phenol, to form a reaction mixture at the first temperature; reducing the first temperature of the reaction mixture to a second temperature that is 10 to 40° C. lower than the first temperature; and forming the sulfonated phenol at the second temperature.
    Type: Grant
    Filed: February 5, 2019
    Date of Patent: August 18, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Erik Nelson, Arkady Samuilovich Dykman, Andrey Vladimirovich Zinenkov, Victor Vladimirovich Pinson, Dmitrij Nikolayevich Zhukov
  • Patent number: 10604813
    Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition and the method are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.
    Type: Grant
    Filed: March 29, 2017
    Date of Patent: March 31, 2020
    Assignee: TFL Ledertechnik GmbH
    Inventors: Catherine Gabagnou, Nina Schulte, Grigore Daniel Herta, Jens Fennen
  • Patent number: 10377882
    Abstract: A polymer latex composition for dip-molding applications includes the reaction product obtained by free-radical emulsion polymerization in aqueous medium of ethylenically unsaturated monomers including; (a) 19.9 to 90 wt.-% of at least one aliphatic conjugated diene; (b) 9.9 to 80 wt.-% of at least one unsaturated nitrile; (c) 0.1 to 10 wt.-% of at least one ethylenically unsaturated acid; (d) 0 to 19 wt.-% of at least one aromatic vinyl compound, and (e) 0 to 20 wt.-% of at least one further ethylenically unsaturated compound different from any of compounds (a) to (d), the weight percentages being based on the total amount of monomers, wherein the emulsion polymerization is conducted in presence of a degraded polysaccharide having a DE of 2 to 90 measured according to ISO 5377 (Dec.
    Type: Grant
    Filed: December 12, 2014
    Date of Patent: August 13, 2019
    Assignee: Synthomer Sdn. Bhd.
    Inventors: Thian Hong Ng, Claudia Eigen, Alexandra Abele, Gareth Simpson
  • Patent number: 10301691
    Abstract: A method for tanning an animal substrate comprising the steps: i) agitating the animal substrate with a chromium-free tanning agent; and ii) agitating the animal substrate with a tanning agent having an oxazolidine group; wherein at least some of the agitation is performed in the presence of a solid particulate material having an average particle size of from 1 to 500 mm.
    Type: Grant
    Filed: October 1, 2015
    Date of Patent: May 28, 2019
    Assignee: Xeros Limited
    Inventors: Addis Duki Feyisa, John Edward Steele
  • Patent number: 10280474
    Abstract: Disclosed herein is a dispersing agent composition essentially comprising polyalkylene polyhydric compound, an organic acid and a non-ionic surfactant. The dispersing composition finds application in leather processing industry for tanning without adding any water or any other medium. It finds tremendous application potential in the tanning industry to ensure eco-benign leather processing that does not add to environmental pollution as no effluent is generated. The invention is therefore envisaged to play a crucial role in enhancing the economic and environmental benefits associated with tanning industry. The disclosure also relates to a process for preparing the composition and also the process of eco-benign tanning using the said composition.
    Type: Grant
    Filed: July 11, 2016
    Date of Patent: May 7, 2019
    Assignee: Council of Scientific & Industrial Research
    Inventor: Muralidharan Chellappa
  • Patent number: 8945610
    Abstract: The invention relates to a condensation product obtainable by reaction of a1) at least one bicyclic or polycyclic aromatic or heteroaromatic, where the bicyclic or polycyclic aromatic or heteroaromatic is substituted by at least one carboxyl group (—COOH), and where the carboxyl group can be present in salt form, a2) at least one carbonyl compound, a3) if appropriate at least one sulfonating agent, a4) at least one urea derivative, and a5) if appropriate at least one further aromatic or heteroaromatic, or a physiologically tolerable salt thereof.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: February 3, 2015
    Assignee: BASF SE
    Inventors: Sebastien Garnier, Stephan Hüffer, Günter Scherr, Joachim Roser, Ulrich Mrowietz, Hans Wilhelm Doerr, Jindrich Cinatl, Martin Michaelis
  • Publication number: 20140259439
    Abstract: The present invention relates to methods and polymers based upon vinyl type monomers that contain pendant carboxylic acid groups that may be employed for retanning of leather sourced from animal skins or synthetic leather.
    Type: Application
    Filed: February 14, 2014
    Publication date: September 18, 2014
    Inventors: Lucas PADDOCK, David G. OUELLETTE, John SHAW, Yvon DURANT
  • Patent number: 8822589
    Abstract: Process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated carboxylic acid, (B) at least one heterocyclic comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated dicarboxylic acid or its anhydride are subjected to free radical copolymerization with one another in an aqueous medium and, shortly before the end or after the end of the copolymerization, further ethylenically unsaturated dicarboxylic acid (C-P2) or its anhydride is added.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: September 2, 2014
    Assignee: BASF SE
    Inventors: Markus Brym, Stephan Hueffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer, Alexandra Bruhn
  • Patent number: 8771374
    Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
    Type: Grant
    Filed: May 24, 2012
    Date of Patent: July 8, 2014
    Assignee: BASF SE
    Inventors: Markus Brym, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schocker, Hubertus Peter Bell, Peter Danisch
  • Publication number: 20140182064
    Abstract: A graft polymer of polysaccharides or polypeptides or its respective derivatives, obtainable by free radical polymerization of A) a monomer selected from or a monomer mixture of (a) from 20 to 100% by weight of acrylic acid or methacrylic acid or of a mixture thereof or of the alkali metal, alkaline earth metal or ammonium salts thereof, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least 2 ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of either B1) polysaccharides, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidized hydrolytically degraded or oxidized enzymatically degraded polysaccharides, or such chemically modified degraded products, chemically modified mono-, oligo-or poly-saccharides or mixtures of the stated compounds and/or B2) polypeptides, their hydrolysates or enzymaticallydegraded and optionally chemi
    Type: Application
    Filed: May 25, 2012
    Publication date: July 3, 2014
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventor: Ma Song
  • Publication number: 20140123399
    Abstract: Solid particulate material containing a) at least one compound containing carbamoylsulphonate groups and b) at least one organic tanning agent.
    Type: Application
    Filed: March 29, 2012
    Publication date: May 8, 2014
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventors: Juergen Reiners, Christopher Tysoe, Holger Luetjens, Rafael Grosch, Franz Heinzelmann, Christopher Henzel
  • Patent number: 8642185
    Abstract: A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and which is free of waxes and oils.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: February 4, 2014
    Assignee: BASF SE
    Inventors: Edward Bohres, Peter Danisch
  • Publication number: 20130312200
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least a mixture of compounds of formula (I) and formula (II), wherein Hal signifies fluorine or chlorine, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of formula (III), —(—C2-3 alkylene-O—)q—H??(III) R2 signifies a) phenyl, mono- or di-substituted with SO3M or COOM and optionally substituted also with hydroxyl or C1-4-alkyl or C1-4-alkoxy, or b) naphthyl, mono- or di- or tri-substituted with SO3M and optionally substituted also with hydroxyl, or c) C1-8-alkylene, substituted with (SO3M) or (COOM), or d) a radical of formula (IV), —(—C2-3 alkylene-O—)p—Y??(IV) e) or a radical of formula (IVa), —(C2-3 alkylene-O)p—C2-3 alkylene-SO2CH2CH2O—Y??(IVa) m signifies 1 or 2, p signifies 0 or 1, Y signifies hydrogen or —SO3M, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an am
    Type: Application
    Filed: October 5, 2011
    Publication date: November 28, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Publication number: 20130288066
    Abstract: Aqueous composition containing a) at least one compound containing carbamoylsulphonate groups and b) at least one nonionic alkoxylated polyol containing ester groups and having an HLB value of at least 13 (b1) and/or alkylglycoside (b2).
    Type: Application
    Filed: July 28, 2011
    Publication date: October 31, 2013
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventors: Jürgen Reiners, Christopher Tysoe, Jan-Dieter Wiechmann, Claudia Krüger, Rafael Grosch, Franz Heinzelmann, Michael Ebbinghaus, Martin Kleban
  • Publication number: 20130239340
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein Hal signifies chlorine or fluorine, X signifies N or CR Y signifies hydrogen, C1-8-alkyl, C1-4-alkyl-carbonyl, C1-4-alkyl-sulphonyl or a radical of formula (Ia), or (Ib) —(—C2-3 alkylene-O—)q—H??(Ib) R signifies hydrogen or chlorine, q is 1 to 10 and M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of the tanning step.
    Type: Application
    Filed: October 25, 2011
    Publication date: September 19, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Publication number: 20130227798
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being a sulpho-group— containing dichloro-diazine selected from compounds of formula (I) of formula (II) and of formula (III) and mixtures of two or more thereof, wherein R1 signifies hydrogen, methyl, methoxy, benzoyl, naphthoyl, mono- or di(C1-4-alkyl)aminocarbonyl, C1-8-alkoxy-carbonyl or oxy-mono- or oligo-(C2-3-alkyleneoxy)-carbonyl R2-(SO3M)n signifies a radical of formula R3 signifies hydrogen, C1-8-alkyl or C1-8-alkoxy, m is 1 or 2, n is 1 or 2 and M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
    Type: Application
    Filed: October 25, 2011
    Publication date: September 5, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Publication number: 20130227799
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), R—NH—Y—SO2—Z??(I), wherein R signifies a radical of formula wherein Hal signifies fluorine or chlorine, X signifies N or CR1, Y signifies an aliphatic, araliphatic or aromatic hydrocarbonic bridge which may optionally be interrupted by a heteroatom or heteroatomic group, Z signifies vinyl, ?-chloroethyl, ?-phosphatoethyl or ?-sulphatoethyl R1 signifies hydrogen or Cl, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
    Type: Application
    Filed: October 25, 2011
    Publication date: September 5, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Publication number: 20130219634
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine, chlorine and/or (+NR3)0-1, wherein R is a substituted C1 to C6 alkyl group or an unsubstituted C1 to C6 alkyl group, an unsubstituted C6 to C10 aryl group or a substituted C6 to C10 aryl group or a C5 to C6 heteroaryl group, R1 signifies hydrogen, C1-8 alkyl or an alkyleneoxy radical of formula (Ia), —(—C2-3alkylene-O—)q—H??(Ia) R2 signifies substituted or unsubstituted C2 to C8 alkylenesulphonic acid, substituted or unsubstituted C2 to C8 alkylenecarboxylic acid or an alkyleneoxy radical of formula (Ib), —(—C2-3alkylene-O—)m—Y??(Ib) or an alkylene sulfonyl alkyleneoxy radical of formula (Ic), —(C2-3alkylene-O)p—C2-3alkylene-SO2CH2CH2O—Y??(Ic) m signifies 1 or 2, p signifies 0 or 1, q is of from 1 to 10, Y signifies hydrogen or —SO3M, M signifies
    Type: Application
    Filed: October 5, 2011
    Publication date: August 29, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Publication number: 20130205516
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine, chlorine and/or (+NR3)0-1, wherein R is a substituted C1 to C6 alkyl group or an unsubstituted C1 to C6 alkyl group, an unsubstituted C6 to C10 aryl group or a substituted C6 to C10 aryl group or a C5 to C6 heteroaryl group, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of formula (Ia), -(—C2-3alkylene-O—)q-H??(Ia) R2 signifies hydrogen or hydroxy, m signifies 1, 2 or 3, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
    Type: Application
    Filed: October 5, 2011
    Publication date: August 15, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Publication number: 20130198974
    Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine or chlorine, and/or (+NR3)0-1, wherein R is a substituted C1 to C6 alkyl group or an unsubstituted C1 to C6 alkyl group, an unsubstituted C6 to C10 aryl group or a substituted C6 to C10 aryl group or a C5 to C6 heteroaryl group.
    Type: Application
    Filed: October 5, 2011
    Publication date: August 8, 2013
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
  • Patent number: 8481169
    Abstract: A leather obtained by a (1) pre-treatment before tanning, (2) tanning process where glutaraldehyde is used as a tanning agent, (3) process where a re-tanning agent is used which is constituted by synthetic tannin, resin and aluminum, of which the synthetic tannin is constituted by (a) condensation product of aromatic sulfonic acid with formaldehyde or mixture of aromatic sulfonic acid and condensation product of aromatic sulfonic acid with formaldehyde, (b) methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound or mixture of aromatic sulfonic acid and methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound and (c) glyoxal, while the resin is constituted by (a) acrylic acid, methacrylic acid, acrylic acid ester or methacrylic acid ester polymer(s) and mixture thereof, and copolymer(s) thereof or mixture thereof and (b) polycondensation product of melamine with formaldehyde, wherein the re-tanning agent having the aforementioned composition is used to perform
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: July 9, 2013
    Assignees: Midori Hokuyo Co., Ltd., Honda Motor Co., Ltd.
    Inventors: Shinji Kashiwagura, Seiji Yamaguchi, Yoshiyuki Ito, Takashi Yamaguchi
  • Publication number: 20120227188
    Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
    Type: Application
    Filed: May 24, 2012
    Publication date: September 13, 2012
    Applicant: BASF SE
    Inventors: MARKUS BRYM, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schöcker, Hubertus Peter Bell, Peter Danisch
  • Publication number: 20120141815
    Abstract: A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and which is free of waxes and oils.
    Type: Application
    Filed: November 30, 2011
    Publication date: June 7, 2012
    Applicant: BASF SE
    Inventors: Edward BOHRES, Peter Danisch
  • Publication number: 20100316695
    Abstract: The invention relates to a condensation product obtainable by reaction of a1) at least one bicyclic or polycyclic aromatic or heteroaromatic, where the bicyclic or polycyclic aromatic or heteroaromatic is substituted by at least one carboxyl group (—COOH), and where the carboxyl group can be present in salt form, a2) at least one carbonyl compound, a3) if appropriate at least one sulfonating agent, a4) at least one urea derivative, and a5) if appropriate at least one further aromatic or heteroaromatic, or a physiologically tolerable salt thereof.
    Type: Application
    Filed: November 11, 2008
    Publication date: December 16, 2010
    Applicant: BASF SE
    Inventors: Sebastien Garnier, Stephan Hueffer, Guenter Scherr, Joachim Roser, Ulrich Mrowietz, Hans Wilhelm Doerr, Jindrich Cinatl, Martin Michaelis
  • Publication number: 20100275380
    Abstract: Process for the tanning of hides and skins, characterized in that hides and skins are treated with tanning agents containing deglycosylated iridoids and/or deglycosylated secoiridoids, excluding tanning agents containing genipin.
    Type: Application
    Filed: November 21, 2008
    Publication date: November 4, 2010
    Applicant: N-Zyme Biotec Gmbh
    Inventors: Jens Zotzel, Stefan Marx, Heinz-Peter Germann, Alla Sarafeddinov
  • Publication number: 20100223736
    Abstract: A method for tanning hides and/or furs comprises at least a first step in which a tanning compound is used, in order to tan said hides and/or furs, to which a saline compound is added.
    Type: Application
    Filed: May 21, 2010
    Publication date: September 9, 2010
    Applicant: PROGETTO IDEA SRL
    Inventor: Olga Jadrova
  • Publication number: 20100227186
    Abstract: A process for the production of leather using one or more reaction products of (a) triamines or higher amines with (b) at least one compound of the general formula I A1-R1??I where R1 is selected from hydrocarbon radicals having 10 to 5000 carbon atoms, straight-chain or branched, saturated or having from one to three C—C double bonds, and A1 from groups capable of reacting with amines.
    Type: Application
    Filed: August 8, 2007
    Publication date: September 9, 2010
    Applicant: BASF SE
    Inventors: Stephan Hüffer, Sebastien Garnier, Oliver Reese, Günter Scherr, Harald Kiesow
  • Publication number: 20100199439
    Abstract: Process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated carboxylic acid, (B) at least one heterocyclic comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated dicarboxylic acid or its anhydride are subjected to free radical copolymerization with one another in an aqueous medium and, shortly before the end or after the end of the copolymerization, further ethylenically unsaturated dicarboxylic acid (C-P2) or its anhydride is added.
    Type: Application
    Filed: August 8, 2008
    Publication date: August 12, 2010
    Inventors: Markus Brym, Stephan Hueffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer, Alexandra Bruhn
  • Patent number: 7771489
    Abstract: A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 ?m or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 ?m and a second, coarser fraction whose number average particle diameter is less than 5 ?m, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.
    Type: Grant
    Filed: August 8, 2003
    Date of Patent: August 10, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Hueffer, Stefan Schroeder, Einhard Wagner, Thorsten Raedler, Karl Vill
  • Publication number: 20100192307
    Abstract: Process for the preparation of aqueous formulations, aqueous formulations and their use A process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated mono- or dicarboxylic acid or the anhydride thereof, (B) at least one comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated carboxamide, are subjected to free radical copolymerization with one another in an aqueous medium.
    Type: Application
    Filed: August 5, 2008
    Publication date: August 5, 2010
    Applicant: BASF SE
    Inventors: Markus Brym, Stephan Hüffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer
  • Patent number: 7753964
    Abstract: A semifinished leather product is produced from an animal hide by pretanning with the use of a chromium-free tanning agent and of a clay mineral which, after stirring for 30 minutes in water at 50° C. at a circumferential rotor speed of from 5 to 25 m/s, has a number average particle diameter of less than 2 ?m or a bimodal particle size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 ?m and a second, coarser fraction whose number average particle diameter is less than 5 ?m, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, a proportion of the first, finely divided fraction being from 10 to 90% by weight, and drying of the pretanned animal hide to a water content of from 5 to 45%, based on the total weight of the semifinished leather product.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: July 13, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Hueffer, Stefan Schroeder, Juergen Carle, Thorsten Raedler, Volker Bach, Tilman Luedecke Taeger
  • Publication number: 20100162490
    Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
    Type: Application
    Filed: September 3, 2008
    Publication date: July 1, 2010
    Applicant: BASF SE
    Inventors: Markus Brym, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schocker, Hubertus Peter Bell, Peter Danisch
  • Patent number: 7651531
    Abstract: Conventionally skins/hides are tanned with metal-ions and vegetable tannins. Environmental constraints on the discharge of toxic metal-ions and poor biodegradable vegetable tannins in the wastewater have become a serious issue. In this invention, the pelts are tanned using eco-benign bio-molecules other than vegetable tannins to reduce the pollution loads. Performance of the leathers is on par with conventionally processed leathers.
    Type: Grant
    Filed: December 23, 2004
    Date of Patent: January 26, 2010
    Assignee: Council of Scientific and Industrial Research
    Inventors: Saravanabhavan Subramani, Thanikaivelan Palanisamy, Jonnalagadda Raghava Rao, Balachandran Unni Nair, Ramasami Thirumalachari
  • Patent number: 7637961
    Abstract: An oligomeric composition containing oligomers and at least one stabilizing component is provided. An aqueous dispersion composition containing the oligomeric composition is useful for treating tanned leather to provide leather with increased softness or strength. Also provided are a method of treating tanned leather using the composition and an article containing the treated leather.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: December 29, 2009
    Assignee: Rohm and Haas Company
    Inventors: Anton Georges El A'mma, Shang-Jaw Chiou, Robert Francis Dougherty
  • Publication number: 20090300848
    Abstract: Leather is prepared by tanning animal skins with a poly(glycidylamine) such as trigycidyl isocyanurate. After retannage with vegetable tannins, it is possible to obtain both a mineral-free and aldehyde-free white leather having Ts >85° C. and suitable for automotive internal trim and a mineral-free and aldehyde-free high thermal stable organic leather having Ts >100° C. and suitable for shoe production.
    Type: Application
    Filed: March 26, 2007
    Publication date: December 10, 2009
    Applicants: BLC LEATHER TECHNOLOGY CENTRE LTD, UNIVERSITY OF LOUGHBOROUGH
    Inventors: Stuart Booth, Richard Heath, Ying Di
  • Publication number: 20090265861
    Abstract: Method for manufacturing a protein filling agent for leather utilizing animal hairs. The method includes pre-treating the animal hairs to obtain pre-treated animal hairs, wherein the pre-treating comprises soaking the animal hairs in an inorganic acid solution and a reducing agent solution. Next, the pre-treated hairs are hydrolyzed in an alkaline compound to obtain a viscous liquid and then, neutralized and dried to obtain the protein filling agent for leather.
    Type: Application
    Filed: April 29, 2009
    Publication date: October 29, 2009
    Applicants: SICHUAN UNIVERSITY, FOSHAN CITY NANHAI ZHAOFU LEATHER PRODUCT CO., LTD
    Inventors: Hai-Guang Huang, Hai-Xia Wang, Guo-Ying Li, Wen-Tao Liu
  • Publication number: 20090191325
    Abstract: The invention provides a surface active ingredient composition, which includes a base liquid including water which has dispersed therein in percentages by volume: Sodium Chloride 1 to 3% Magnesium 1 to 2% Calcium 1 to 2% Potassium 1 to 2% Sulphate 1 to 2% Carbon 0.5 to 1% Nitrate 1 to 2% and Phosphate 1 to 2% sodium chloride dissolved in the base liquid; and sodium alkyl ether sulphate dissolved in the base liquid, with the portion of the base liquid to sodium chloride and sodium alkyl ether sulphate being between 1:1:1.5 and 1:1:5. The invention further provides a process for producing same and uses thereof.
    Type: Application
    Filed: May 28, 2007
    Publication date: July 30, 2009
    Applicant: MARINE 3 TECHNOLOGIES H0LDINGS (PTY) LTD. SUITE8, PANAORAMA OFFICE ESTATE
    Inventor: Andries Du Plessis
  • Publication number: 20090139006
    Abstract: An abcite reinforced leather and a method for producing the abcite reinforced leather for use in making shoes, gloves and garments. Abcite pellets are ground into a fine powder and floated in a carrier so that they penetrate the fiber structure of a tanned skin. The abcite particles bond to the fiber structure and provide enhanced abrasion resistance and tensile strength to the leather. This abcite impregnated leather can be used to make gloves, shoes and garments. Also, abcite powder can be added to the surface to make the surface more durable and abrasion resistant.
    Type: Application
    Filed: December 1, 2008
    Publication date: June 4, 2009
    Inventor: JOHN D. WIDDEMER
  • Patent number: 7479164
    Abstract: Non-glutaraldehyde fixation of an organ or a prosthesis for implantation in a mammal is based upon carbodiimide treatment. An aqueous solution containing a coupling agent, such as EDC, in combination with a coupling enhancer, such as sulfo-NHS, and a high concentration of a diamine cross-linking agent is used. As a result, only minimal surface reduction occurs during fixation, and the resultant products show a dramatic increase in resistance to calcification.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: January 20, 2009
    Assignee: Biomedical Design, Inc.
    Inventors: Jean-Marie Girardot, Marie-Nadia Girardot
  • Publication number: 20080276378
    Abstract: Compositions comprising a) 5 to 50% by weight of an aliphatic dialdehyde having 2 to 10 carbon atoms; b) 2-5 to 20% by weight of at least one reductive saccharide having a dextrose equivalent of 10 to 100; c) 2.5 to 20% by weight of at least one water-soluble, optionally monoetherified polyoxaalkylene glycol having a molecular weight of more than 100 and not more than 2000; and d) 90 to 10% by weight of water, 0.05 to 0.19 mole of the components b) and c) being added per mole of the component a), outstandingly suitable for the pretanning of pelts and subsequent production of leathers free of heavy metals.
    Type: Application
    Filed: October 7, 2004
    Publication date: November 13, 2008
    Applicant: TFL Ledertechnik GmbH
    Inventor: Jens Fennen
  • Publication number: 20080248322
    Abstract: Process for the production of leather using products obtainable by reacting (A) at least one cyclic organic carbonate with (B) at least one compound having at least two nucleophilic groups per molecule, selected from sulfo, hydroxyl, primary or secondary amino or mercapto groups.
    Type: Application
    Filed: October 12, 2006
    Publication date: October 9, 2008
    Applicant: BASF SE
    Inventors: Oliver Reese, Stephan Huffer, Gunter Scherr, Bernhard Albert
  • Publication number: 20080229511
    Abstract: Generally, the tanned leathers are retanned with a combination of synthetic tanning agents to enhance the properties such as fullness, grain tightness, grain smoothness and roundness. Many of the chemicals that go into the preparation of such synthetic tanning agents are toxic and slow biodegradable. Further, in industrial practice, several synthetic tanning agents are combined to obtain a desired property. In the present invention, a synthetic tanning agent using natural and proteinous waste materials is disclosed, which provides to the leather the properties such as better fibre lubrication, filling of looser ends, softness, shape retention and fabrication comforts without combining with other synthetic tanning agents is reported.
    Type: Application
    Filed: October 24, 2007
    Publication date: September 25, 2008
    Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Natraj Rajendran, Saravanabhavan Subramani, Aravindhan Rathinam, Janardhanan Sreeram Kalarical, Raghava Rao Jonnalagadda, Unni Nair Balachandran, Ramasami Thirumalachari
  • Patent number: 7410504
    Abstract: Adducts are obtained by reacting carbonyl compounds of the formula I where R1 and R2 are as defined, with cyclic compounds of the formula II where X is selected from oxygen, sulfur and N—R8, R3-R8 are as defined, and n is an integer from 1 to 4, which adducts are useful as tanning agents and preservatives.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: August 12, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Hueffer, Oliver Reese, Walter Gramlich, Stefan Schroeder, Guenter Scherr, Volker Bach
  • Publication number: 20080168606
    Abstract: The present invention is related to the use of a new conditioning agent for treating pelts for tanning. This conditioning agent consists in a composition of modified aldehydes, carboxylic acids or polycarboxylic acids and additives. The conditioning agent is used for replacing the steps of deliming and pickling in the pelts treatment. The action of the product can eliminate the step of basification when the tanning is made with chromium salts. The objective of the present invention is the use of a novel composition that can replace the steps of deliming, step 6, and pickling, step 8, described before for one just step called conditioning The proposed system, neutralizes the alkalinity and hence removes the solubility of Calcium from the liming operation attached in the pelt.
    Type: Application
    Filed: February 21, 2006
    Publication date: July 17, 2008
    Inventors: Renato Augusto Konrath, Francisco Jose Fava, Jose Everton Braun
  • Publication number: 20080104767
    Abstract: In a tanning process for tanning animal skins the skin is subjected to a pre-oxidation step.
    Type: Application
    Filed: September 30, 2004
    Publication date: May 8, 2008
    Inventors: Alberto Santori, Giancarlo Recanati
  • Patent number: 7282066
    Abstract: A process for the preparation of aqueous formulations, and aqueous formulations so prepared, the process comprising heating at least one cyclic compound of the formula I in the presence of water and of an acidic catalyst and, during or after the heating, H—X—R3 is at least partially separated off, where, in formula I, X is selected from oxygen, sulfur and N—R6, R1-R6 are as defined, and n is an integer from 1 to 4.
    Type: Grant
    Filed: January 22, 2004
    Date of Patent: October 16, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Hueffer, Guenter Scherr, Oliver Reese
  • Patent number: 7169191
    Abstract: A novel synthetic aluminium tanning agent as an alternative for chromium based tanning salts without using formaldehyde was prepared by using aromatic polymeric matrix and aluminium (III) salts as raw materials with suitable masking agents. The preparation of the syntan consists of sulphonation of aromatic molecule, which is incorporated with a polymeric network along with ligands specially designed for the complexation of aluminium (III) salts. The complex can be used as a self-tanning agent in leather industry with fairly good filling behavior. The tanned leathers exhibit shrinkage temperature about 85° C. Due to the higher precipitation point of the product, it can be used for tanning directly after deliming thus eliminating the pickling process. This product, unlike the conventional phenol based products, does not undergo photo-oxidation thereby preventing the discoloration of the tanned leathers.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: January 30, 2007
    Assignee: Council of Scientific and Industrial Research
    Inventors: Mookandi Kanthimathi, Palanisamy Thanikaivelan, Jonnalagadda Raghava Rao, Balachandran Unni Nair, Thirumalachari Ramasami
  • Patent number: 7160480
    Abstract: A method of treating leather for imparting soil resistance to the leather by contacting the leather with a fluorinated hydrophobic additive comprising at least one fluorinated urethane or a mixture of at least one fluorinated urethane with at least one fluorinated ester, and the resulting treated leather having soil resistance are disclosed.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: January 9, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Andrew Hen Liu, Kai-Volker Schubert
  • Patent number: 7157017
    Abstract: The invention relates to control fungal growth on tanned hides, using cyanodithiocarbimates of formula (I): X is a halogen; R is a substituted or unsubstituted C1–C14 alkyl group, a substituted or unsubstituted C2–C14 alkenyl group, a substituted or unsubstituted C2–C14 alkynyl group, a substituted or unsubstituted group defined by Y—Ar—(CH2)m— or by Z—(CH2)n—; Ar is a substituted or unsubstituted aryl group selected from phenyl, or naphthyl; Y is H, halogen, NO2, R1, R1O, R1R2N; Z is NC, R1O, R1OC(O), R1OCH2CH2(OCH2CH2)p m ranges from 0 to 3; n ranges from 0 to 3; p ranges from 0 to 3; and R1 and R2 are independently H, substituted or unsubstituted C1–C5 alkyl.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: January 2, 2007
    Assignee: Buckman Laboratories International, Inc.
    Inventors: Joseph G. E. Fenyes, Thomas E. McNeel, Stephen D. Bryant, Marilyn S. Whittemore, Zoltan G. Csuros, Mark L. Zollinger, Robert H. Miller, Naim B. Miguel