With Organic Material Patents (Class 8/94.33)
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Patent number: 10815542Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition according to the invention and the method according to the invention are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.Type: GrantFiled: May 13, 2019Date of Patent: October 27, 2020Assignee: TFL Ledertechnik GmbHInventors: Catherine Gabagnou, Nina Schulte-Gauczinski, Grigore Daniel Herta, Jens Fennen
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Patent number: 10745333Abstract: A method for the manufacture of a sulfonated phenol for use as a cumene hydroperoxide decomposition catalyst can comprise: combining phenol and a sulfonating agent at a first temperature that is 1° C. to 15° C. higher than a melting temperature of the phenol, to form a reaction mixture at the first temperature; reducing the first temperature of the reaction mixture to a second temperature that is 10 to 40° C. lower than the first temperature; and forming the sulfonated phenol at the second temperature.Type: GrantFiled: February 5, 2019Date of Patent: August 18, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Mark Erik Nelson, Arkady Samuilovich Dykman, Andrey Vladimirovich Zinenkov, Victor Vladimirovich Pinson, Dmitrij Nikolayevich Zhukov
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Patent number: 10604813Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition and the method are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.Type: GrantFiled: March 29, 2017Date of Patent: March 31, 2020Assignee: TFL Ledertechnik GmbHInventors: Catherine Gabagnou, Nina Schulte, Grigore Daniel Herta, Jens Fennen
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Patent number: 10377882Abstract: A polymer latex composition for dip-molding applications includes the reaction product obtained by free-radical emulsion polymerization in aqueous medium of ethylenically unsaturated monomers including; (a) 19.9 to 90 wt.-% of at least one aliphatic conjugated diene; (b) 9.9 to 80 wt.-% of at least one unsaturated nitrile; (c) 0.1 to 10 wt.-% of at least one ethylenically unsaturated acid; (d) 0 to 19 wt.-% of at least one aromatic vinyl compound, and (e) 0 to 20 wt.-% of at least one further ethylenically unsaturated compound different from any of compounds (a) to (d), the weight percentages being based on the total amount of monomers, wherein the emulsion polymerization is conducted in presence of a degraded polysaccharide having a DE of 2 to 90 measured according to ISO 5377 (Dec.Type: GrantFiled: December 12, 2014Date of Patent: August 13, 2019Assignee: Synthomer Sdn. Bhd.Inventors: Thian Hong Ng, Claudia Eigen, Alexandra Abele, Gareth Simpson
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Patent number: 10301691Abstract: A method for tanning an animal substrate comprising the steps: i) agitating the animal substrate with a chromium-free tanning agent; and ii) agitating the animal substrate with a tanning agent having an oxazolidine group; wherein at least some of the agitation is performed in the presence of a solid particulate material having an average particle size of from 1 to 500 mm.Type: GrantFiled: October 1, 2015Date of Patent: May 28, 2019Assignee: Xeros LimitedInventors: Addis Duki Feyisa, John Edward Steele
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Patent number: 10280474Abstract: Disclosed herein is a dispersing agent composition essentially comprising polyalkylene polyhydric compound, an organic acid and a non-ionic surfactant. The dispersing composition finds application in leather processing industry for tanning without adding any water or any other medium. It finds tremendous application potential in the tanning industry to ensure eco-benign leather processing that does not add to environmental pollution as no effluent is generated. The invention is therefore envisaged to play a crucial role in enhancing the economic and environmental benefits associated with tanning industry. The disclosure also relates to a process for preparing the composition and also the process of eco-benign tanning using the said composition.Type: GrantFiled: July 11, 2016Date of Patent: May 7, 2019Assignee: Council of Scientific & Industrial ResearchInventor: Muralidharan Chellappa
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Patent number: 8945610Abstract: The invention relates to a condensation product obtainable by reaction of a1) at least one bicyclic or polycyclic aromatic or heteroaromatic, where the bicyclic or polycyclic aromatic or heteroaromatic is substituted by at least one carboxyl group (—COOH), and where the carboxyl group can be present in salt form, a2) at least one carbonyl compound, a3) if appropriate at least one sulfonating agent, a4) at least one urea derivative, and a5) if appropriate at least one further aromatic or heteroaromatic, or a physiologically tolerable salt thereof.Type: GrantFiled: November 11, 2008Date of Patent: February 3, 2015Assignee: BASF SEInventors: Sebastien Garnier, Stephan Hüffer, Günter Scherr, Joachim Roser, Ulrich Mrowietz, Hans Wilhelm Doerr, Jindrich Cinatl, Martin Michaelis
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Publication number: 20140259439Abstract: The present invention relates to methods and polymers based upon vinyl type monomers that contain pendant carboxylic acid groups that may be employed for retanning of leather sourced from animal skins or synthetic leather.Type: ApplicationFiled: February 14, 2014Publication date: September 18, 2014Inventors: Lucas PADDOCK, David G. OUELLETTE, John SHAW, Yvon DURANT
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Patent number: 8822589Abstract: Process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated carboxylic acid, (B) at least one heterocyclic comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated dicarboxylic acid or its anhydride are subjected to free radical copolymerization with one another in an aqueous medium and, shortly before the end or after the end of the copolymerization, further ethylenically unsaturated dicarboxylic acid (C-P2) or its anhydride is added.Type: GrantFiled: August 8, 2008Date of Patent: September 2, 2014Assignee: BASF SEInventors: Markus Brym, Stephan Hueffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer, Alexandra Bruhn
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Patent number: 8771374Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.Type: GrantFiled: May 24, 2012Date of Patent: July 8, 2014Assignee: BASF SEInventors: Markus Brym, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schocker, Hubertus Peter Bell, Peter Danisch
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Publication number: 20140182064Abstract: A graft polymer of polysaccharides or polypeptides or its respective derivatives, obtainable by free radical polymerization of A) a monomer selected from or a monomer mixture of (a) from 20 to 100% by weight of acrylic acid or methacrylic acid or of a mixture thereof or of the alkali metal, alkaline earth metal or ammonium salts thereof, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least 2 ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of either B1) polysaccharides, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidized hydrolytically degraded or oxidized enzymatically degraded polysaccharides, or such chemically modified degraded products, chemically modified mono-, oligo-or poly-saccharides or mixtures of the stated compounds and/or B2) polypeptides, their hydrolysates or enzymaticallydegraded and optionally chemiType: ApplicationFiled: May 25, 2012Publication date: July 3, 2014Applicant: LANXESS DEUTSCHLAND GMBHInventor: Ma Song
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Publication number: 20140123399Abstract: Solid particulate material containing a) at least one compound containing carbamoylsulphonate groups and b) at least one organic tanning agent.Type: ApplicationFiled: March 29, 2012Publication date: May 8, 2014Applicant: LANXESS DEUTSCHLAND GMBHInventors: Juergen Reiners, Christopher Tysoe, Holger Luetjens, Rafael Grosch, Franz Heinzelmann, Christopher Henzel
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Patent number: 8642185Abstract: A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and which is free of waxes and oils.Type: GrantFiled: November 30, 2011Date of Patent: February 4, 2014Assignee: BASF SEInventors: Edward Bohres, Peter Danisch
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Publication number: 20130312200Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least a mixture of compounds of formula (I) and formula (II), wherein Hal signifies fluorine or chlorine, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of formula (III), —(—C2-3 alkylene-O—)q—H??(III) R2 signifies a) phenyl, mono- or di-substituted with SO3M or COOM and optionally substituted also with hydroxyl or C1-4-alkyl or C1-4-alkoxy, or b) naphthyl, mono- or di- or tri-substituted with SO3M and optionally substituted also with hydroxyl, or c) C1-8-alkylene, substituted with (SO3M) or (COOM), or d) a radical of formula (IV), —(—C2-3 alkylene-O—)p—Y??(IV) e) or a radical of formula (IVa), —(C2-3 alkylene-O)p—C2-3 alkylene-SO2CH2CH2O—Y??(IVa) m signifies 1 or 2, p signifies 0 or 1, Y signifies hydrogen or —SO3M, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an amType: ApplicationFiled: October 5, 2011Publication date: November 28, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Publication number: 20130288066Abstract: Aqueous composition containing a) at least one compound containing carbamoylsulphonate groups and b) at least one nonionic alkoxylated polyol containing ester groups and having an HLB value of at least 13 (b1) and/or alkylglycoside (b2).Type: ApplicationFiled: July 28, 2011Publication date: October 31, 2013Applicant: LANXESS DEUTSCHLAND GMBHInventors: Jürgen Reiners, Christopher Tysoe, Jan-Dieter Wiechmann, Claudia Krüger, Rafael Grosch, Franz Heinzelmann, Michael Ebbinghaus, Martin Kleban
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Publication number: 20130239340Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein Hal signifies chlorine or fluorine, X signifies N or CR Y signifies hydrogen, C1-8-alkyl, C1-4-alkyl-carbonyl, C1-4-alkyl-sulphonyl or a radical of formula (Ia), or (Ib) —(—C2-3 alkylene-O—)q—H??(Ib) R signifies hydrogen or chlorine, q is 1 to 10 and M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of the tanning step.Type: ApplicationFiled: October 25, 2011Publication date: September 19, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Publication number: 20130227798Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being a sulpho-group— containing dichloro-diazine selected from compounds of formula (I) of formula (II) and of formula (III) and mixtures of two or more thereof, wherein R1 signifies hydrogen, methyl, methoxy, benzoyl, naphthoyl, mono- or di(C1-4-alkyl)aminocarbonyl, C1-8-alkoxy-carbonyl or oxy-mono- or oligo-(C2-3-alkyleneoxy)-carbonyl R2-(SO3M)n signifies a radical of formula R3 signifies hydrogen, C1-8-alkyl or C1-8-alkoxy, m is 1 or 2, n is 1 or 2 and M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.Type: ApplicationFiled: October 25, 2011Publication date: September 5, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Publication number: 20130227799Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), R—NH—Y—SO2—Z??(I), wherein R signifies a radical of formula wherein Hal signifies fluorine or chlorine, X signifies N or CR1, Y signifies an aliphatic, araliphatic or aromatic hydrocarbonic bridge which may optionally be interrupted by a heteroatom or heteroatomic group, Z signifies vinyl, ?-chloroethyl, ?-phosphatoethyl or ?-sulphatoethyl R1 signifies hydrogen or Cl, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.Type: ApplicationFiled: October 25, 2011Publication date: September 5, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Publication number: 20130219634Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine, chlorine and/or (+NR3)0-1, wherein R is a substituted C1 to C6 alkyl group or an unsubstituted C1 to C6 alkyl group, an unsubstituted C6 to C10 aryl group or a substituted C6 to C10 aryl group or a C5 to C6 heteroaryl group, R1 signifies hydrogen, C1-8 alkyl or an alkyleneoxy radical of formula (Ia), —(—C2-3alkylene-O—)q—H??(Ia) R2 signifies substituted or unsubstituted C2 to C8 alkylenesulphonic acid, substituted or unsubstituted C2 to C8 alkylenecarboxylic acid or an alkyleneoxy radical of formula (Ib), —(—C2-3alkylene-O—)m—Y??(Ib) or an alkylene sulfonyl alkyleneoxy radical of formula (Ic), —(C2-3alkylene-O)p—C2-3alkylene-SO2CH2CH2O—Y??(Ic) m signifies 1 or 2, p signifies 0 or 1, q is of from 1 to 10, Y signifies hydrogen or —SO3M, M signifiesType: ApplicationFiled: October 5, 2011Publication date: August 29, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Publication number: 20130205516Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine, chlorine and/or (+NR3)0-1, wherein R is a substituted C1 to C6 alkyl group or an unsubstituted C1 to C6 alkyl group, an unsubstituted C6 to C10 aryl group or a substituted C6 to C10 aryl group or a C5 to C6 heteroaryl group, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of formula (Ia), -(—C2-3alkylene-O—)q-H??(Ia) R2 signifies hydrogen or hydroxy, m signifies 1, 2 or 3, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.Type: ApplicationFiled: October 5, 2011Publication date: August 15, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Publication number: 20130198974Abstract: Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine or chlorine, and/or (+NR3)0-1, wherein R is a substituted C1 to C6 alkyl group or an unsubstituted C1 to C6 alkyl group, an unsubstituted C6 to C10 aryl group or a substituted C6 to C10 aryl group or a C5 to C6 heteroaryl group.Type: ApplicationFiled: October 5, 2011Publication date: August 8, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Claus Reineking, Roberta Gamarino, Licia Trimarco, Maurizio Quaglierini, Markus Gisler, Rainer Nusser
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Patent number: 8481169Abstract: A leather obtained by a (1) pre-treatment before tanning, (2) tanning process where glutaraldehyde is used as a tanning agent, (3) process where a re-tanning agent is used which is constituted by synthetic tannin, resin and aluminum, of which the synthetic tannin is constituted by (a) condensation product of aromatic sulfonic acid with formaldehyde or mixture of aromatic sulfonic acid and condensation product of aromatic sulfonic acid with formaldehyde, (b) methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound or mixture of aromatic sulfonic acid and methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound and (c) glyoxal, while the resin is constituted by (a) acrylic acid, methacrylic acid, acrylic acid ester or methacrylic acid ester polymer(s) and mixture thereof, and copolymer(s) thereof or mixture thereof and (b) polycondensation product of melamine with formaldehyde, wherein the re-tanning agent having the aforementioned composition is used to performType: GrantFiled: June 27, 2008Date of Patent: July 9, 2013Assignees: Midori Hokuyo Co., Ltd., Honda Motor Co., Ltd.Inventors: Shinji Kashiwagura, Seiji Yamaguchi, Yoshiyuki Ito, Takashi Yamaguchi
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Publication number: 20120227188Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.Type: ApplicationFiled: May 24, 2012Publication date: September 13, 2012Applicant: BASF SEInventors: MARKUS BRYM, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schöcker, Hubertus Peter Bell, Peter Danisch
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Publication number: 20120141815Abstract: A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and which is free of waxes and oils.Type: ApplicationFiled: November 30, 2011Publication date: June 7, 2012Applicant: BASF SEInventors: Edward BOHRES, Peter Danisch
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Publication number: 20100316695Abstract: The invention relates to a condensation product obtainable by reaction of a1) at least one bicyclic or polycyclic aromatic or heteroaromatic, where the bicyclic or polycyclic aromatic or heteroaromatic is substituted by at least one carboxyl group (—COOH), and where the carboxyl group can be present in salt form, a2) at least one carbonyl compound, a3) if appropriate at least one sulfonating agent, a4) at least one urea derivative, and a5) if appropriate at least one further aromatic or heteroaromatic, or a physiologically tolerable salt thereof.Type: ApplicationFiled: November 11, 2008Publication date: December 16, 2010Applicant: BASF SEInventors: Sebastien Garnier, Stephan Hueffer, Guenter Scherr, Joachim Roser, Ulrich Mrowietz, Hans Wilhelm Doerr, Jindrich Cinatl, Martin Michaelis
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Publication number: 20100275380Abstract: Process for the tanning of hides and skins, characterized in that hides and skins are treated with tanning agents containing deglycosylated iridoids and/or deglycosylated secoiridoids, excluding tanning agents containing genipin.Type: ApplicationFiled: November 21, 2008Publication date: November 4, 2010Applicant: N-Zyme Biotec GmbhInventors: Jens Zotzel, Stefan Marx, Heinz-Peter Germann, Alla Sarafeddinov
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Publication number: 20100223736Abstract: A method for tanning hides and/or furs comprises at least a first step in which a tanning compound is used, in order to tan said hides and/or furs, to which a saline compound is added.Type: ApplicationFiled: May 21, 2010Publication date: September 9, 2010Applicant: PROGETTO IDEA SRLInventor: Olga Jadrova
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Publication number: 20100227186Abstract: A process for the production of leather using one or more reaction products of (a) triamines or higher amines with (b) at least one compound of the general formula I A1-R1??I where R1 is selected from hydrocarbon radicals having 10 to 5000 carbon atoms, straight-chain or branched, saturated or having from one to three C—C double bonds, and A1 from groups capable of reacting with amines.Type: ApplicationFiled: August 8, 2007Publication date: September 9, 2010Applicant: BASF SEInventors: Stephan Hüffer, Sebastien Garnier, Oliver Reese, Günter Scherr, Harald Kiesow
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Publication number: 20100199439Abstract: Process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated carboxylic acid, (B) at least one heterocyclic comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated dicarboxylic acid or its anhydride are subjected to free radical copolymerization with one another in an aqueous medium and, shortly before the end or after the end of the copolymerization, further ethylenically unsaturated dicarboxylic acid (C-P2) or its anhydride is added.Type: ApplicationFiled: August 8, 2008Publication date: August 12, 2010Inventors: Markus Brym, Stephan Hueffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer, Alexandra Bruhn
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Patent number: 7771489Abstract: A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 ?m or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 ?m and a second, coarser fraction whose number average particle diameter is less than 5 ?m, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.Type: GrantFiled: August 8, 2003Date of Patent: August 10, 2010Assignee: BASF AktiengesellschaftInventors: Stephan Hueffer, Stefan Schroeder, Einhard Wagner, Thorsten Raedler, Karl Vill
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Publication number: 20100192307Abstract: Process for the preparation of aqueous formulations, aqueous formulations and their use A process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated mono- or dicarboxylic acid or the anhydride thereof, (B) at least one comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated carboxamide, are subjected to free radical copolymerization with one another in an aqueous medium.Type: ApplicationFiled: August 5, 2008Publication date: August 5, 2010Applicant: BASF SEInventors: Markus Brym, Stephan Hüffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer
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Patent number: 7753964Abstract: A semifinished leather product is produced from an animal hide by pretanning with the use of a chromium-free tanning agent and of a clay mineral which, after stirring for 30 minutes in water at 50° C. at a circumferential rotor speed of from 5 to 25 m/s, has a number average particle diameter of less than 2 ?m or a bimodal particle size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 ?m and a second, coarser fraction whose number average particle diameter is less than 5 ?m, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, a proportion of the first, finely divided fraction being from 10 to 90% by weight, and drying of the pretanned animal hide to a water content of from 5 to 45%, based on the total weight of the semifinished leather product.Type: GrantFiled: November 25, 2003Date of Patent: July 13, 2010Assignee: BASF AktiengesellschaftInventors: Stephan Hueffer, Stefan Schroeder, Juergen Carle, Thorsten Raedler, Volker Bach, Tilman Luedecke Taeger
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Publication number: 20100162490Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.Type: ApplicationFiled: September 3, 2008Publication date: July 1, 2010Applicant: BASF SEInventors: Markus Brym, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schocker, Hubertus Peter Bell, Peter Danisch
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Patent number: 7651531Abstract: Conventionally skins/hides are tanned with metal-ions and vegetable tannins. Environmental constraints on the discharge of toxic metal-ions and poor biodegradable vegetable tannins in the wastewater have become a serious issue. In this invention, the pelts are tanned using eco-benign bio-molecules other than vegetable tannins to reduce the pollution loads. Performance of the leathers is on par with conventionally processed leathers.Type: GrantFiled: December 23, 2004Date of Patent: January 26, 2010Assignee: Council of Scientific and Industrial ResearchInventors: Saravanabhavan Subramani, Thanikaivelan Palanisamy, Jonnalagadda Raghava Rao, Balachandran Unni Nair, Ramasami Thirumalachari
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Patent number: 7637961Abstract: An oligomeric composition containing oligomers and at least one stabilizing component is provided. An aqueous dispersion composition containing the oligomeric composition is useful for treating tanned leather to provide leather with increased softness or strength. Also provided are a method of treating tanned leather using the composition and an article containing the treated leather.Type: GrantFiled: February 21, 2003Date of Patent: December 29, 2009Assignee: Rohm and Haas CompanyInventors: Anton Georges El A'mma, Shang-Jaw Chiou, Robert Francis Dougherty
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Publication number: 20090300848Abstract: Leather is prepared by tanning animal skins with a poly(glycidylamine) such as trigycidyl isocyanurate. After retannage with vegetable tannins, it is possible to obtain both a mineral-free and aldehyde-free white leather having Ts >85° C. and suitable for automotive internal trim and a mineral-free and aldehyde-free high thermal stable organic leather having Ts >100° C. and suitable for shoe production.Type: ApplicationFiled: March 26, 2007Publication date: December 10, 2009Applicants: BLC LEATHER TECHNOLOGY CENTRE LTD, UNIVERSITY OF LOUGHBOROUGHInventors: Stuart Booth, Richard Heath, Ying Di
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Publication number: 20090265861Abstract: Method for manufacturing a protein filling agent for leather utilizing animal hairs. The method includes pre-treating the animal hairs to obtain pre-treated animal hairs, wherein the pre-treating comprises soaking the animal hairs in an inorganic acid solution and a reducing agent solution. Next, the pre-treated hairs are hydrolyzed in an alkaline compound to obtain a viscous liquid and then, neutralized and dried to obtain the protein filling agent for leather.Type: ApplicationFiled: April 29, 2009Publication date: October 29, 2009Applicants: SICHUAN UNIVERSITY, FOSHAN CITY NANHAI ZHAOFU LEATHER PRODUCT CO., LTDInventors: Hai-Guang Huang, Hai-Xia Wang, Guo-Ying Li, Wen-Tao Liu
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Publication number: 20090191325Abstract: The invention provides a surface active ingredient composition, which includes a base liquid including water which has dispersed therein in percentages by volume: Sodium Chloride 1 to 3% Magnesium 1 to 2% Calcium 1 to 2% Potassium 1 to 2% Sulphate 1 to 2% Carbon 0.5 to 1% Nitrate 1 to 2% and Phosphate 1 to 2% sodium chloride dissolved in the base liquid; and sodium alkyl ether sulphate dissolved in the base liquid, with the portion of the base liquid to sodium chloride and sodium alkyl ether sulphate being between 1:1:1.5 and 1:1:5. The invention further provides a process for producing same and uses thereof.Type: ApplicationFiled: May 28, 2007Publication date: July 30, 2009Applicant: MARINE 3 TECHNOLOGIES H0LDINGS (PTY) LTD. SUITE8, PANAORAMA OFFICE ESTATEInventor: Andries Du Plessis
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Publication number: 20090139006Abstract: An abcite reinforced leather and a method for producing the abcite reinforced leather for use in making shoes, gloves and garments. Abcite pellets are ground into a fine powder and floated in a carrier so that they penetrate the fiber structure of a tanned skin. The abcite particles bond to the fiber structure and provide enhanced abrasion resistance and tensile strength to the leather. This abcite impregnated leather can be used to make gloves, shoes and garments. Also, abcite powder can be added to the surface to make the surface more durable and abrasion resistant.Type: ApplicationFiled: December 1, 2008Publication date: June 4, 2009Inventor: JOHN D. WIDDEMER
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Patent number: 7479164Abstract: Non-glutaraldehyde fixation of an organ or a prosthesis for implantation in a mammal is based upon carbodiimide treatment. An aqueous solution containing a coupling agent, such as EDC, in combination with a coupling enhancer, such as sulfo-NHS, and a high concentration of a diamine cross-linking agent is used. As a result, only minimal surface reduction occurs during fixation, and the resultant products show a dramatic increase in resistance to calcification.Type: GrantFiled: July 16, 2004Date of Patent: January 20, 2009Assignee: Biomedical Design, Inc.Inventors: Jean-Marie Girardot, Marie-Nadia Girardot
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Publication number: 20080276378Abstract: Compositions comprising a) 5 to 50% by weight of an aliphatic dialdehyde having 2 to 10 carbon atoms; b) 2-5 to 20% by weight of at least one reductive saccharide having a dextrose equivalent of 10 to 100; c) 2.5 to 20% by weight of at least one water-soluble, optionally monoetherified polyoxaalkylene glycol having a molecular weight of more than 100 and not more than 2000; and d) 90 to 10% by weight of water, 0.05 to 0.19 mole of the components b) and c) being added per mole of the component a), outstandingly suitable for the pretanning of pelts and subsequent production of leathers free of heavy metals.Type: ApplicationFiled: October 7, 2004Publication date: November 13, 2008Applicant: TFL Ledertechnik GmbHInventor: Jens Fennen
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Publication number: 20080248322Abstract: Process for the production of leather using products obtainable by reacting (A) at least one cyclic organic carbonate with (B) at least one compound having at least two nucleophilic groups per molecule, selected from sulfo, hydroxyl, primary or secondary amino or mercapto groups.Type: ApplicationFiled: October 12, 2006Publication date: October 9, 2008Applicant: BASF SEInventors: Oliver Reese, Stephan Huffer, Gunter Scherr, Bernhard Albert
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Publication number: 20080229511Abstract: Generally, the tanned leathers are retanned with a combination of synthetic tanning agents to enhance the properties such as fullness, grain tightness, grain smoothness and roundness. Many of the chemicals that go into the preparation of such synthetic tanning agents are toxic and slow biodegradable. Further, in industrial practice, several synthetic tanning agents are combined to obtain a desired property. In the present invention, a synthetic tanning agent using natural and proteinous waste materials is disclosed, which provides to the leather the properties such as better fibre lubrication, filling of looser ends, softness, shape retention and fabrication comforts without combining with other synthetic tanning agents is reported.Type: ApplicationFiled: October 24, 2007Publication date: September 25, 2008Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCHInventors: Natraj Rajendran, Saravanabhavan Subramani, Aravindhan Rathinam, Janardhanan Sreeram Kalarical, Raghava Rao Jonnalagadda, Unni Nair Balachandran, Ramasami Thirumalachari
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Patent number: 7410504Abstract: Adducts are obtained by reacting carbonyl compounds of the formula I where R1 and R2 are as defined, with cyclic compounds of the formula II where X is selected from oxygen, sulfur and N—R8, R3-R8 are as defined, and n is an integer from 1 to 4, which adducts are useful as tanning agents and preservatives.Type: GrantFiled: January 21, 2004Date of Patent: August 12, 2008Assignee: BASF AktiengesellschaftInventors: Stephan Hueffer, Oliver Reese, Walter Gramlich, Stefan Schroeder, Guenter Scherr, Volker Bach
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Publication number: 20080168606Abstract: The present invention is related to the use of a new conditioning agent for treating pelts for tanning. This conditioning agent consists in a composition of modified aldehydes, carboxylic acids or polycarboxylic acids and additives. The conditioning agent is used for replacing the steps of deliming and pickling in the pelts treatment. The action of the product can eliminate the step of basification when the tanning is made with chromium salts. The objective of the present invention is the use of a novel composition that can replace the steps of deliming, step 6, and pickling, step 8, described before for one just step called conditioning The proposed system, neutralizes the alkalinity and hence removes the solubility of Calcium from the liming operation attached in the pelt.Type: ApplicationFiled: February 21, 2006Publication date: July 17, 2008Inventors: Renato Augusto Konrath, Francisco Jose Fava, Jose Everton Braun
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Publication number: 20080104767Abstract: In a tanning process for tanning animal skins the skin is subjected to a pre-oxidation step.Type: ApplicationFiled: September 30, 2004Publication date: May 8, 2008Inventors: Alberto Santori, Giancarlo Recanati
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Patent number: 7282066Abstract: A process for the preparation of aqueous formulations, and aqueous formulations so prepared, the process comprising heating at least one cyclic compound of the formula I in the presence of water and of an acidic catalyst and, during or after the heating, H—X—R3 is at least partially separated off, where, in formula I, X is selected from oxygen, sulfur and N—R6, R1-R6 are as defined, and n is an integer from 1 to 4.Type: GrantFiled: January 22, 2004Date of Patent: October 16, 2007Assignee: BASF AktiengesellschaftInventors: Stephan Hueffer, Guenter Scherr, Oliver Reese
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Patent number: 7169191Abstract: A novel synthetic aluminium tanning agent as an alternative for chromium based tanning salts without using formaldehyde was prepared by using aromatic polymeric matrix and aluminium (III) salts as raw materials with suitable masking agents. The preparation of the syntan consists of sulphonation of aromatic molecule, which is incorporated with a polymeric network along with ligands specially designed for the complexation of aluminium (III) salts. The complex can be used as a self-tanning agent in leather industry with fairly good filling behavior. The tanned leathers exhibit shrinkage temperature about 85° C. Due to the higher precipitation point of the product, it can be used for tanning directly after deliming thus eliminating the pickling process. This product, unlike the conventional phenol based products, does not undergo photo-oxidation thereby preventing the discoloration of the tanned leathers.Type: GrantFiled: March 20, 2003Date of Patent: January 30, 2007Assignee: Council of Scientific and Industrial ResearchInventors: Mookandi Kanthimathi, Palanisamy Thanikaivelan, Jonnalagadda Raghava Rao, Balachandran Unni Nair, Thirumalachari Ramasami
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Patent number: 7160480Abstract: A method of treating leather for imparting soil resistance to the leather by contacting the leather with a fluorinated hydrophobic additive comprising at least one fluorinated urethane or a mixture of at least one fluorinated urethane with at least one fluorinated ester, and the resulting treated leather having soil resistance are disclosed.Type: GrantFiled: February 22, 2005Date of Patent: January 9, 2007Assignee: E. I. du Pont de Nemours and CompanyInventors: Andrew Hen Liu, Kai-Volker Schubert
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Patent number: 7157017Abstract: The invention relates to control fungal growth on tanned hides, using cyanodithiocarbimates of formula (I): X is a halogen; R is a substituted or unsubstituted C1–C14 alkyl group, a substituted or unsubstituted C2–C14 alkenyl group, a substituted or unsubstituted C2–C14 alkynyl group, a substituted or unsubstituted group defined by Y—Ar—(CH2)m— or by Z—(CH2)n—; Ar is a substituted or unsubstituted aryl group selected from phenyl, or naphthyl; Y is H, halogen, NO2, R1, R1O, R1R2N; Z is NC, R1O, R1OC(O), R1OCH2CH2(OCH2CH2)p m ranges from 0 to 3; n ranges from 0 to 3; p ranges from 0 to 3; and R1 and R2 are independently H, substituted or unsubstituted C1–C5 alkyl.Type: GrantFiled: November 26, 2003Date of Patent: January 2, 2007Assignee: Buckman Laboratories International, Inc.Inventors: Joseph G. E. Fenyes, Thomas E. McNeel, Stephen D. Bryant, Marilyn S. Whittemore, Zoltan G. Csuros, Mark L. Zollinger, Robert H. Miller, Naim B. Miguel