With Plural Indirect Heat Transfer Steps On Solid Sorbent Or Gaseous Fluid Mixture Or Constituent Thereof Patents (Class 95/114)
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Patent number: 12059667Abstract: The present invention relates to a superior carbon adsorbent with or without a core. In one embodiment the carbon adsorbent of the present invention employs carbon adsorbent powder and an organic binding agent which are combined together with an appropriate solvent in an agglomeration step. In another embodiment the invention contemplates a core-in-shell adsorbent comprising an outer shell composed of a carbon and a non-adsorbing inert inner core. Low temperature processing of these agglomerates substantially preserves the binding agent within the final composition and allows one to prepare adsorbent products of high sphericity. The adsorbents of the invention possess superior characteristics such as higher mass transfer rate and CO2 working capacity for use in a H2PSA process.Type: GrantFiled: February 14, 2019Date of Patent: August 13, 2024Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Neil A. Stephenson, Philip A. Barrett, Steven J. Pontonio, Nicholas R. Stuckert, Garrett R. Swindlehurst
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Patent number: 12017204Abstract: The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents. The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.Type: GrantFiled: February 14, 2019Date of Patent: June 25, 2024Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Neil A. Stephenson, Philip A. Barrett, Steven J. Pontonio, Nicholas R. Stuckert
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Patent number: 11378274Abstract: An integrated fuel combustion system with gas separation (adsorptive, absorptive, membrane or other suitable gas separation) separates a portion of carbon dioxide from a combustion gas mixture and provides for recycle of separated carbon dioxide to the intake of a fuel combustor for combustion.Type: GrantFiled: November 29, 2018Date of Patent: July 5, 2022Assignee: Svante Inc.Inventor: Andre Boulet
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Patent number: 11364464Abstract: A system for enhancing adsorption of contaminated vapors to increase treatment capacity of a regenerable, synthetic adsorptive media. The system includes an inlet configured to receive a flow of contaminated vapors. One or more vessels are coupled to the inlet, the one or more vessels each including a regenerable, synthetic adsorptive media therein, are configured to remove contaminants from the vapors by adsorption. A vapor cooling subsystem is coupled to the inlet, and configured to cool the flow of contaminated vapors, thereby increasing the treatment capacity of the regenerable synthetic adsorptive media.Type: GrantFiled: May 11, 2020Date of Patent: June 21, 2022Assignee: Emerging Compounds Treatment Technologies, Inc.Inventors: Steven E. Woodard, Andrew G. Bishop, Michael G. Nickelsen, John C. Berry
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Patent number: 10730005Abstract: A method for continuous pressure swing adsorption separation of a pressurized feed gas stream, including separating hydrocarbons heavier than methane from the pressurized feed gas stream by applying an adsorbent porous material to produce at least two product streams, a first product stream being substantially pure methane suitable for transport by natural gas pipeline, and a second product stream being substantially comprised of components with a greater molecular weight than methane.Type: GrantFiled: February 14, 2020Date of Patent: August 4, 2020Assignee: APACHE CORPORATIONInventors: Jason G. S. Ho, J Calvin Cooper
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Patent number: 10099202Abstract: The present invention provides a water-resistant composition for adsorbing volatile organic compounds (VOCs) derived from organic matter including: a) palladium doped hydrogen-ZSM-5, wherein the Si:AI ratio of the hydrogen-ZSM-5 is less than or equal to 200:1; and b) at least one water-soluble binder. The invention also provides a method for using the water-resistant composition for adsorbing volatile organic compounds (VOCs) derived from organic matter.Type: GrantFiled: June 25, 2014Date of Patent: October 16, 2018Assignee: ANGLO PLATINUM MARKETING LIMITEDInventors: Andrew William John Smith, Elizabeth Rowsell, Stephen Poulston
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Patent number: 9950305Abstract: A solar thermochemical processing system is disclosed. The system includes a first unit operation for receiving concentrated solar energy. Heat from the solar energy is used to drive the first unit operation. The first unit operation also receives a first set of reactants and produces a first set of products. A second unit operation receives the first set of products from the first unit operation and produces a second set of products. A third unit operation receives heat from the second unit operation to produce a portion of the first set of reactants.Type: GrantFiled: July 26, 2012Date of Patent: April 24, 2018Assignee: Battelle Memorial InstituteInventors: Robert S. Wegeng, Paul H. Humble, Shankar Krishnan, Steven D. Leith, Daniel R. Palo, Robert A. Dagle
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Patent number: 9815022Abstract: A device for exhausting carbon dioxide includes: at least one carbon dioxide adsorber which is configured to be able to be electrically heated; and a heat radiating part of a heating device for heating an interior space. A carbon dioxide exhausting process is repeatedly performed. The carbon dioxide exhausting process includes: a first process of urging interior air to pass through the carbon dioxide adsorber and then to be introduced into an interior space; a second process of urging interior air to pass sequentially through the carbon dioxide adsorber and the heat radiating part in a state that the carbon dioxide adsorber is electrically heated and to be exhausted to an exterior space; and a third process of urging exterior air to pass sequentially through the heat radiating part and the carbon dioxide adsorber and then to be introduced into an interior space after the second process.Type: GrantFiled: January 28, 2016Date of Patent: November 14, 2017Assignee: SOGANG UNIVERSITY RESEARCH FOUNDATIONInventors: Tae-Soo Lee, Jung-Hyuk Cho
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Patent number: 9505683Abstract: A process for treatment of a natural gas stream, or other methane containing stream that passes through a guard bed for removal of mercury and hydrolysis of COS, followed by treatment with an absorbent unit containing an amine solvent for removal of carbon dioxide and hydrogen sulfide. The gas is then dried by a molecular sieve bed. The regeneration gas for the molecular sieve adsorbent bed is chilled to remove liquid hydrocarbons and sulfur compounds. The process is accomplished without the use of an absorbent unit to remove the sulfur compounds.Type: GrantFiled: May 21, 2014Date of Patent: November 29, 2016
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Patent number: 9240320Abstract: Provided are plasma enhanced chemical vapor deposition methods of depositing smooth and conformal ashable hard mask films on substrates containing raised or recessed features. The methods involve using precursors having relatively high C:H ratios, such as acetylene (C:H ratio of 1), and plasmas having low ion energies and fluxes. According to various embodiments, the methods involve depositing smooth ashable hard mask films using high frequency radio frequency-generated plasmas with no low frequency component and/or relatively high pressures. Also provided are methods of depositing ashable hard mask films having good selectivity and improved side wall coverage and roughness. The methods involve depositing a first ashable hard mask film on a substrate having a feature using a process optimized for selectivity and/or optical properties and then depositing a smoothing layer on the first ashable hard mask film using an HF-only process.Type: GrantFiled: April 3, 2013Date of Patent: January 19, 2016Assignee: Novellus Systems, Inc.Inventors: Pramod Subramonium, Zhiyuan Fang, Shawn Hancock, Mike Pierce, Jon Henri
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Patent number: 9222727Abstract: The invention relates to a process for removing oxygen from liquid argon using a TSA (temperature swing adsorption) cyclical process that includes cooling an adsorbent bed to sustain argon in a liquid phase; supplying the adsorbent bed with a liquid argon feed that is contaminated with oxygen and purifying the liquid argon thereby producing an argon product with less oxygen contaminant than is in the initial liquid argon feed; draining the purified residual liquid argon product and sending purified argon out of the adsorbent bed. Regeneration of specially prepared adsorbent allows the adsorbent bed to warm up to temperatures that preclude the use of requiring either vacuum or evacuation of adsorbent from the bed.Type: GrantFiled: March 1, 2013Date of Patent: December 29, 2015Assignee: Praxair Technology, Inc.Inventors: Persefoni E. Kechagia, Neil A. Stephenson, Philip A. Barrett, Hai Du, Steven J. Pontonio
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Publication number: 20150135951Abstract: A structured adsorbent sheet, is provided including a nano-adsorbent powder, and a binder material, wherein the nano-adsorbent powder is combined with the binder material to form an adsorbent material, and a porous electrical heating substrate, wherein the adsorbent material is applied to the porous electrical heating substrate thereby forming a structured adsorbent sheet. A structured adsorbent module is provided, including a plurality of stacked structured adsorbent sheets, configured to produce a plurality of fluid passages, wherein the plurality of fluid passages have a cross-sectional shape in the direction of a fluid stream. The structured adsorbent module may have a cross-sectional shape that is trapezoidal, rectangle, square, triangular or sinusoidal.Type: ApplicationFiled: November 20, 2013Publication date: May 21, 2015Applicant: L'Air Liquide Societe Anonyme Pour l'Etude et I'Exploitation des Procedes Georges ClaudeInventors: Yudong CHEN, Christian Monereau, Edgar S. Sanders, JR., Pascal Tessier
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Patent number: 8979980Abstract: A gas cleaning unit for cleaning a main raw gas stream from a plant comprises a plurality of gas cleaning chambers (34a-c), each gas cleaning chamber (34a-c) equipped with a cleaning chamber inlet (46a-c); an inlet manifold (32), for dividing said main raw gas stream flowing therethrough into a plurality of separate fractional raw gas streams for flow to said cleaning chamber inlets (46a-c); and a plurality of heat exchangers (40a-c), each heat exchanger (40a-c) being located downstream of the inlet manifold (32) for exchanging heat with a respective fractional raw gas stream entering a respective cleaning chamber (34a-c).Type: GrantFiled: June 28, 2011Date of Patent: March 17, 2015Assignee: ALSTOM Technology LtdInventors: Anders Kenneth Sorhuus, Odd Edgar Bjarno
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Publication number: 20150068397Abstract: A method of adsorption allows separation of a first fluid component from a fluid mixture comprising at least the first fluid component in an adsorptive separation system having a parallel passage adsorbent contactor with parallel flow passages having cell walls which include an adsorbent material. The method provides for transferring heat from the heat of adsorption in a countercurrent direction along at least a portion of the contactor during adsorption and transferring heat in either axial direction along the contactor to provide at least a portion of the heat of desorption during a desorption step. A carbon dioxide separation process to separate carbon dioxide from flue gas also includes steps transferring heat from adsorption or for desorption along the parallel passage adsorbent contactor.Type: ApplicationFiled: November 17, 2014Publication date: March 12, 2015Inventors: Andre BOULET, Soheil KHIAVI
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Patent number: 8900347Abstract: A method of temperature swing adsorption allows separation of a first fluid component from a fluid mixture comprising at least the first fluid component in an adsorptive separation system having a parallel passage adsorbent contactor with parallel flow passages having cell walls which include an adsorbent material and axial thermally conductive filaments in direct contact with the adsorbent material. The method provides for transferring heat from the heat of adsorption in a countercurrent direction along at least a portion of the filaments during adsorption and transferring heat in either axial direction along the filaments to provide at least a portion of the heat of desorption during a desorption step. A carbon dioxide TSA separation process to separate carbon dioxide from flue gas also includes steps transferring heat from adsorption or for desorption along axial thermally conductive filaments.Type: GrantFiled: August 26, 2011Date of Patent: December 2, 2014Assignee: Inventys Thermal Technologies Inc.Inventors: Andre Boulet, Soheil Khiavi
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Patent number: 8888895Abstract: A method for the removal of H2O and CO2 from a gaseous stream comprising H2O and CO2, such as a flue gas. The method initially utilizes an H2O removal sorbent to remove some portion of the H2O, producing a dry gaseous stream and a wet H2O removal sorbent. The dry gaseous stream is subsequently contacted with a CO2 removal sorbent to remove some portion of the CO2, generating a dry CO2 reduced stream and a loaded CO2 removal sorbent. The loaded CO2 removal sorbent is subsequently heated to produce a heated CO2 stream. The wet H2O removal sorbent and the dry CO2 reduced stream are contacted in a first regeneration stage, generating a partially regenerated H2O removal sorbent, and the partially regenerated H2O removal sorbent and the heated CO2 stream are subsequently contacted in a second regeneration stage.Type: GrantFiled: September 10, 2013Date of Patent: November 18, 2014Assignee: U.S. Department of EnergyInventors: James C. Fisher, Ranjani V. Siriwardane, David A. Berry, George A. Richards
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Patent number: 8814986Abstract: A protected solid adsorbent is disclosed that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.Type: GrantFiled: July 1, 2013Date of Patent: August 26, 2014Assignee: ExxonMobil Research and Egineering CompanyInventors: Mohsen S Yeganeh, Bhupender S. Minhas, Tahmid I Mizan, Sufang Zhao, Richard W. Flynn
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Publication number: 20140216254Abstract: Provided are apparatus and systems having a rotary valve assembly integrated with a reciprocating valve assembly to perform swing adsorption processes. The rotary valve assembly is utilized with the reciprocating valve assembly to manage the flow of streams through the system in an enhanced manner.Type: ApplicationFiled: February 27, 2012Publication date: August 7, 2014Inventors: Robert F. Tammera, Thomas N. Anderson
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Patent number: 8794237Abstract: An oxygen concentrator may rely on a pressure swing adsorption process to produce an oxygen enriched gas stream from canisters filled with granules capable of separation of oxygen from an air stream. The adsorption process uses a cyclical pressurization and venting of the canisters to generate an oxygen enriched gas stream. The oxygen concentrator system may include one or more flow restrictors to allow controlled release of oxygen enriched gas between the canisters.Type: GrantFiled: August 25, 2010Date of Patent: August 5, 2014Assignee: Inova Labs, Inc.Inventors: William R. Wilkinson, Allan Sten Westersten, H. David Shockley, Jr.
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Patent number: 8728207Abstract: In the method according to the invention for separating mercury from waste gases of a cement production process, the mercury is sorbed on a sorbent, the sorbent is subsequently discharged from the process and supplied to a discharge reactor which is operated with a carrier gas. The sorbent is heated there to temperatures of more than 250° C. so that the mercury is discharged from the sorbent and changed into the gas phase, the gas of the discharge reactor that has accumulated mercury subsequently having the dust removed from it in a preliminary dust removal device, and only a part-flow of the gas which has been enriched and had the dust removed from it in this manner being drawn off at high temperatures and cleaned in a subsequent sorption stage, whilst the remaining part-flow is brought to the temperature required for the discharge of the mercury in the discharge reactor in a heat transfer system and is again supplied as a carrier gas to the discharge reactor.Type: GrantFiled: August 5, 2010Date of Patent: May 20, 2014Inventors: Dietmar Schulz, Ludger Brentrup, Karl Menzel, Reinhard Beilmann, Detlev Kupper, Mark Terry
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Publication number: 20140083293Abstract: Adsorber for adsorbing a fluid, comprising a cylinder with at least two parallel-passage contactors disposed in series in the direction of flow of the fluid to be adsorbed, and characterised in that each contactor comprises an internal insulation.Type: ApplicationFiled: April 20, 2012Publication date: March 27, 2014Applicant: l' Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges ClaudeInventor: Benoit Davidian
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Patent number: 8673059Abstract: Novel adsorbent contactors and methods are disclosed herein for use in temperature swing adsorption for gas separation applications, as well as for heat exchange applications.Type: GrantFiled: February 27, 2012Date of Patent: March 18, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Daniel P. Leta, Harry W. Deckman, Peter I. Ravikovitch, Bruce A. Derites
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Patent number: 8673056Abstract: The invention is directed to processes and apparatuses for gas treatment, in particular for the purification of methane rich gas streams, such as gas obtained from the conversion from organic matter (“biogas”). In accordance with the present invention there is provided an apparatus and a process for producing a purified methane comprising gas stream (P) from a methane containing gas stream (A), comprising the steps of: (a) pressurising said methane containing gas stream (A) and subsequently cooling it, whereby a stream comprising condensed contaminants (C) and a methane comprising stream (B) are obtained; (b) optionally feeding said methane comprising stream (B) to an adsorption unit and/or a catalytic conversion unit, whereby the concentration of contaminants in stream (B) is further decreased; and (c) cooling the methane comprising stream (B) to a temperature which is sufficient to condensate CO2 from said stream (B), whereby said purified methane comprising gas stream (P) is obtained.Type: GrantFiled: August 17, 2006Date of Patent: March 18, 2014Assignee: Gastreatment Services B.V.Inventors: Mathieu André De Bas, Jacob Kuiper, Jeroen De Pater
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Publication number: 20140060326Abstract: The invention relates to an increased efficiency high-capacity pressure and/or temperature swing adsorption process comprising: contacting a feedstream at a rate of more than 75 MSCFD with an adsorbent material under conditions sufficient for the adsorbent material to selectively adsorb at least one of the component gases in the feedstream, so as to form a first effluent; and selectively desorbing the adsorbed gas from the adsorption material, so as to form a second effluent The adsorption module can contain rotary valves both on the feed end and on the product end and a rotational member defining a central rotational axis, with the adsorption bed(s) oriented circumferentially thereto. The adsorption bed walls can be angled, the feed end cross-sectional area of the adsorption bed(s) can be larger than the product end, and/or the feed end rotary valve diameter of the module(s) can be larger than the product end.Type: ApplicationFiled: September 4, 2012Publication date: March 6, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventor: NARASIMHAN SUNDARAM
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Patent number: 8658120Abstract: Disclosed is a non-thermofusible phenol resin powder having an average particle diameter of not more than 20 ?m and a single particle ratio of not less than 0.7. This non-thermofusible phenol resin powder preferably has a chlorine content of not more than 500 ppm. This non-thermofusible phenol resin powder is useful as an organic filler for sealing materials for semiconductors and adhesives for semiconductors. The non-thermofusible phenol resin powder is also useful as a precursor of functional carbon materials such as a molecular sieve carbon and a carbon electrode material.Type: GrantFiled: February 2, 2012Date of Patent: February 25, 2014Assignee: Air Water Inc.Inventors: Naoto Yoshinaga, Satoshi Ibaraki, Yoshinobu Kodani, Takaomi Ikeda
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Publication number: 20140026750Abstract: For separating carbon dioxide (CO2) from a gas stream, a substantially moisture free gas stream is produced using a first temperature swing adsorption (TSA), a first pressure swing adsorption (PSA), a first vacuum swing adsorption (VSA), membrane separation, a first absorption, or any combination thereof. CO2 is captured from the substantially moisture free gas stream and substantially dry CO2 depleted stream is produced using a second TSA, a second PSA, a second VSA, or a second absorption with a non-aqueous solvent with or without a chemical reaction. Adsorbents and/or absorbents used during moisture removal are regenerated using the substantially dry CO2 depleted stream.Type: ApplicationFiled: September 26, 2013Publication date: January 30, 2014Applicant: Innosepra LLCInventor: Ravi Jain
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Patent number: 8591627Abstract: Disclosed herein is a method and system for separating carbon dioxide (CO2) from a CO2 containing gas stream containing water vapor and additional impurities, for example, nitrogen, oxygen, sulfur oxides, nitrogen oxides, and mercury. The CO2 is captured by subjecting the CO2 gas feed stream to a temperature swing adsorption step. The temperature swing adsorption step comprises an adsorption step for producing a substantially dry carbon dioxide-depleted stream, and an adsorbent regeneration step comprising heating the adsorbent bed to produce a substantially water vapor-free carbon dioxide stream. Moisture from the gas stream containing CO2 is optionally removed by pressure swing adsorption, temperature swing adsorption, membrane separation, or absorption prior to CO2 capture.Type: GrantFiled: April 7, 2009Date of Patent: November 26, 2013Assignee: Innosepra LLCInventor: Ravi Jain
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Patent number: 8574347Abstract: The present invention relates to a pressure swing adsorption process, also known as PSA process, which is modified with a view to utilizing the heat from the post-adsorption stream coming from the molecular sieves to heat/vaporize the pre-adsorption stream containing the hydrated product or the mixture component(s) to be adsorbed in said sieves. The present invention provides alternative arrangements for the heat exchanger system in order to use the thermal potential of the post-adsorption stream with the elimination or minimization of the risk of a slug flow regime in the exchangers, the so-called “gush,” which would be a natural result from the periodic oscillation characteristic of PSA processes. With this, the vapor consumption with the modified process according to the present invention is considerably reduced.Type: GrantFiled: January 22, 2007Date of Patent: November 5, 2013Assignees: Siemens LTDA, Dedini S/A Industrias de BaseInventors: Adler Gomes Moura, Daniel Moozydlower
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Patent number: 8535416Abstract: A method for the purification of a feed gas stream at a pressure ?3 bar, comprising at least 1% by volume of oxygen (O2) and at least 75% by volume of CO2 and mercury, enabling the mercury to be eliminated is provided.Type: GrantFiled: July 8, 2008Date of Patent: September 17, 2013Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Philippe Court, Arthur Darde, Vladimir Hasanov, Christian Monereau, Serge Moreau, Jean-Pierre Tranier
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Publication number: 20130206005Abstract: A gas cleaning unit for cleaning a main raw gas stream from a plant comprises a plurality of gas cleaning chambers (34a-c), each gas cleaning chamber (34a-c) equipped with a cleaning chamber inlet (46a-c); an inlet manifold (32), for dividing said main raw gas stream flowing therethrough into a plurality of separate fractional raw gas streams for flow to said cleaning chamber inlets (46a-c); and a plurality of heat exchangers (40a-c), each heat exchanger (40a-c) being located downstream of the inlet manifold (32) for exchanging heat with a respective fractional raw gas stream entering a respective cleaning chamber (34a-c).Type: ApplicationFiled: June 28, 2011Publication date: August 15, 2013Applicant: ALSTOM TECHNOLOGY LTDInventors: Anders Kenneth Sorhuus, Odd Edgar Bjarno
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Patent number: 8500887Abstract: The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.Type: GrantFiled: February 25, 2011Date of Patent: August 6, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Mohsen S. Yeganeh, Bhupender S. Minhas, Sufang Zhao, Tahmid I. Mizan, Richard W. Flynn
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Patent number: 8500852Abstract: Methods, devices, and systems, and devices for carrying out sorption (adsorption and absorption) for separating and/or purifying fluid mixtures are disclosed. Medical oxygen generators, dehumidifying units, sorptive heat pumps, ozone generators and Peltier devices are also disclosed. The sorption methods involve pressure swing operation of at least two sorption units. Energy from the desorbing and decompressing fluid is substantially recovered and used within the system.Type: GrantFiled: April 30, 2007Date of Patent: August 6, 2013Assignee: Separation Design Group, LLCInventor: S. Douglas Galbraith
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Patent number: 8491705Abstract: A method for capturing CO2 from the ambient air by the use of solid tethered amine adsorbents, where the amine adsorbents are tethered to a substrate selected from the group of silica, metal oxides and polymer resins. The tethered amines are joined to the substrate by covalent bonding, achieved either by the ring-opening polymerization of aziridine on porous and non-porous supports, or by the reaction of mono-, di-, or tri-aminosilanes, with silica or a metal oxide having hydroxyl surface groups. The method includes the adsorption of CO2 from ambient air, the regeneration of the adsorbent at elevated temperatures not above 120° C. and the separation of purified CO2, followed by recycling of the regenerated tethered adsorbent for further adsorption of CO2 from the ambient atmosphere.Type: GrantFiled: August 19, 2010Date of Patent: July 23, 2013Inventors: Sunho Choi, Jeffrey H. Drese, Ronald R. Chance, Peter M. Eisenberger, Christopher W. Jones
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Publication number: 20130152787Abstract: A method of temperature swing adsorption allows separation of a first fluid component from a fluid mixture comprising at least the first fluid component in an adsorptive separation system having a parallel passage adsorbent contactor with parallel flow passages having cell walls which include an adsorbent material and axial thermally conductive filaments in direct contact with the adsorbent material. The method provides for transferring heat from the heat of adsorption in a countercurrent direction along at least a portion of the filaments during adsorption and transferring heat in either axial direction along the filaments to provide at least a portion of the heat of desorption during a desorption step. A carbon dioxide TSA separation process to separate carbon dioxide from flue gas also includes steps transferring heat from adsorption or for desorption along axial thermally conductive filaments.Type: ApplicationFiled: August 26, 2011Publication date: June 20, 2013Applicant: INVENTYS THERMAL TECHNOLOGIES INC.Inventors: Andre Boulet, Soheil Khiavi
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Patent number: 8449650Abstract: Gases are stored, separated, and/or concentrated. An electric field is applied across a porous dielectric adsorbent material. A gas component from a gas mixture may be selectively separated inside the energized dielectric. Gas is stored in the energized dielectric for as long as the dielectric is energized. The energized dielectric selectively separates, or concentrates, a gas component of the gas mixture. When the potential is removed, gas from inside the dielectric is released.Type: GrantFiled: June 15, 2010Date of Patent: May 28, 2013Assignee: Los Alamos National Security, LLCInventors: Robert P. Currier, Stephen J. Obrey, David J. Devlin, Jose Maria Sansinena
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Patent number: 8425660Abstract: A method by which water may be extracted from the air even without a supply of electricity from a power source or even without a supply of fuel, as well as an apparatus therefor, is disclosed. The apparatus used for the method for extracting water from the air comprises at least a rotatably mounted hygroscopic moisture-absorbing rotor having at least one region through which air can pass in the direction of thickness thereof; a passage for regeneration through which air for regeneration is circulated, of which both ends are opened at the opposing two surfaces of a regeneration region, respectively, the regeneration region being a part of the moisture-absorbing rotor, at which the moisture-absorbing rotor that absorbed moisture is regenerated; and a drain hole for taking out condensed water from the passage for regeneration.Type: GrantFiled: October 21, 2010Date of Patent: April 23, 2013Assignee: Kankyo Co., Ltd.Inventors: Hidetoshi Ike, Nao Okuhata
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Patent number: 8388732Abstract: The present invention relates to an integrated membrane/adsorbent process and system for removal of carbon dioxide from natural gas on a ship that houses natural gas purification equipment. Additional membrane units or adsorbent beds are used to reduce the amount of product gas that is lost in gas streams that are used to regenerate the adsorbent beds. These systems produce a product stream that meets the specifications of less than 50 parts per million carbon dioxide in natural gas for liquefaction.Type: GrantFiled: May 11, 2011Date of Patent: March 5, 2013Assignee: UOP LLCInventors: Shain-Jer Doong, Lubo Zhou, Dennis J. Bellville, Mark E. Schott, Leonid Bresler, John M. Foresman
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Patent number: 8361206Abstract: Dessicants employed in dehumidifying moisturized air present within a water-damaged building are themselves dehumidified to liberate collected moisture through the use of heated air vented from an on-site electric generator to be drawn over and about a heat exchanger fired by diesel fuel.Type: GrantFiled: November 22, 2010Date of Patent: January 29, 2013Inventor: Spencer W. Hess
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Patent number: 8317902Abstract: A process for removing polar components from a process stream in a refinery process without cooling the process stream. The process stream is fed to a first adsorber unit to remove contaminants containing sulfur at substantially the same elevated temperature by exposing the process stream to a metal oxide and/or a mixed metal oxide to remove the sulfur containing contaminants and produce a metal sulfide and a desulfurized process stream. The metal sulfide may be regenerated by exposing it to a stream of oxygen and the desulfurized process stream exposed to the regenerated metal/mixed metal oxide to remove moisture from the stream. The stream is then processed within a second adsorber unit to remove nitrogen containing contaminants at substantially the same elevated temperature by exposing the stream to a molecular sieve and/or zeolite.Type: GrantFiled: August 7, 2009Date of Patent: November 27, 2012Assignee: ExxonMobil Research & Engineering CompanyInventors: Bhupender S Minhas, Frederick Y. Lo, Ian A Cody, Donald E Stratton
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Patent number: 8282707Abstract: The present invention relates to an integrated membrane/absorbent/adsorbent process and system for removal of mercury and sulfur compounds from natural gas on a ship that houses natural gas purification equipment. First mercury and most of the sulfur compounds are removed by an adsorbent bed and then the natural gas stream passes through a membrane unit to produce a partially purified natural gas residue stream to be dried and then liquefied and a carbon dioxide permeate stream that can be used as a fuel gas.Type: GrantFiled: May 19, 2011Date of Patent: October 9, 2012Assignee: UOP LLCInventors: Leonid Bresler, John M. Foresman, William I. Echt, Mark E. Schott
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Patent number: 8282787Abstract: A system and process for gasification of a carbonaceous feedstock uses pyrolysis to produce a gas product, which may include methane, ethane, and other desirable hydrocarbon gases, and a solids product, which includes activated carbon or carbon. The gas product may then be filtered using at least a portion of the activated carbon from the solids product as a filtering medium. In an embodiment, at least some of the noxious chemicals are sequestered or removed from the gas product in one or more filtering steps using the activated carbon as a filtering medium. In a further embodiment, the filtering steps are performed in stages using activated carbon at different temperatures. A high-temperature pyrolysis system that produces activated carbon may be combined with another high-temperature pyrolysis system that does not produce activated carbon to provide filtering of noxious compounds using activated carbon from the first high-temperature pyrolysis system.Type: GrantFiled: March 14, 2008Date of Patent: October 9, 2012Inventor: Richard D. Tucker
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Patent number: 8262773Abstract: An improved method is provided for removing contaminants from a hydrocarbon stream, such as a stream of raw natural gas. The contaminated hydrocarbon stream is passed through a first adsorbent bed containing molecular sieves to adsorb contaminants on the molecular sieves, thereby removing at least some of the contaminants from the hydrocarbon stream. The contaminated hydrocarbon stream may optionally be passed through a second adsorbent bed containing a desiccant material other than molecular sieves. The molecular sieves are regenerated using a wet regeneration process in which both the water content and temperature of the regeneration fluid stream are staged.Type: GrantFiled: May 23, 2006Date of Patent: September 11, 2012Assignee: ExxonMobil Upstream Research CompanyInventors: P. Scott Northrop, Francis S. Wu, Margaret Wu, legal representative, Narasimhan Sundaram
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Publication number: 20120222554Abstract: Novel adsorbent contactors and methods are disclosed herein for use in temperature swing adsorption for gas separation applications, as well as for heat exchange applications.Type: ApplicationFiled: February 27, 2012Publication date: September 6, 2012Applicant: ExxonMobil Research and Engineering CompanyInventors: Daniel P. Leta, Harry W. Deckman, Peter I. Ravikovitch, Bruce A. Derites
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Patent number: 8257474Abstract: The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO2 from flue gas.Type: GrantFiled: February 24, 2012Date of Patent: September 4, 2012Assignees: Georgia Tech Research Corporation, ExxonMobil Research and Engineering CompanyInventors: Ryan Lively, Ronald R. Chance, William J. Koros, Harry W. Deckman, Bruce T. Kelley
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Patent number: 8252089Abstract: The present invention relates to a method and device for compressing and drying a gas flow rich in carbon dioxide, for example containing more than 50 mol % of carbon dioxide.Type: GrantFiled: November 21, 2008Date of Patent: August 28, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Pierre Tranier, Arthur Darde, Jean-François Rauch, Dominique Antonio, Christophe Michel
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Publication number: 20120210871Abstract: Systems and methods for processing methane and other gases are disclosed. A representative method in accordance with one embodiment includes directing a first portion of a gas stream through a first adsorbent while exchanging heat between a second adsorbent and a third adsorbent. The method can further include directing a second portion of the gas stream through the third adsorbent while exchanging heat between the first and second adsorbents. The method can still further include directing a third portion of the gas stream through the second adsorbent while exchanging heat between the first and third adsorbents. In further particular aspects, the adsorbent can be used to remove carbon dioxide from a flow of methane. In other particular aspects, a heat exchange fluid that is not in direct contact with the adsorbents is used to transfer heat among the adsorbents.Type: ApplicationFiled: September 22, 2011Publication date: August 23, 2012Applicant: Prometheus Technologies, LLCInventors: John A. Barclay, Michael A. Barclay
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Patent number: 8241399Abstract: A method of generating heat from a gas stream includes providing a first gas stream having a first temperature and a moisture content approximately saturating the gas stream, removing the moisture content from the first gas stream to form a second gas stream having a second temperature greater than the first temperature of the first gas stream, and heat exchanging the second gas stream having the second temperature greater than the first temperature of the first gas stream.Type: GrantFiled: May 16, 2009Date of Patent: August 14, 2012Inventor: Walter Albers
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Patent number: 8226746Abstract: Systems and processes are provided that relate to the recovery of sorbates in processes utilizing temperature controlled adsorption. Sorbate recovery can include providing a temperature controlled adsorber that is undergoing a regeneration cycle after undergoing an adsorption cycle. The temperature controlled adsorber can have one or more adsorption flow passages and one or more heat transfer flow passages. The one or more adsorption flow passages can contain an adsorptive material coating with a sorbate adsorbed thereto. A heating fluid can be provided to the one or more heat transfer flow passages of the temperature controlled adsorber. A regeneration stream can be provided to the one or more adsorption flow passages of the temperature controlled adsorber. The adsorptive material coating can be regenerated by removing the sorbate from the temperature controlled adsorber to produce a regeneration effluent stream.Type: GrantFiled: September 8, 2009Date of Patent: July 24, 2012Assignee: UOP LLCInventors: Stephen R. Dunne, David A. Wegerer
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Patent number: 8221526Abstract: The invention relates to a method for purifying or separating a supply gas flow containing at least one impurity, in which: a) said supply gas flow is contacted with a first adsorbent for the adsorption-removal of at least one said impurity; b) recovering said purified or separated gas; c) heating a regeneration gas containing at least hydrogen (H2) and carbon monoxide (CO) using a heater having a skin temperature (T1) of between 150° C. and 200° C. during the gas heating phase; and d) periodically regenerating the adsorbent of step a) with the regeneration gas heated during step c) at a regeneration temperature (T2) such that: T2=T1??T with 5° C.<?T<50° C.Type: GrantFiled: December 11, 2007Date of Patent: July 17, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Christian Monereau, Guillaume Rodrigues, Simon Jallais
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Publication number: 20120118151Abstract: In the method according to the invention for separating mercury from waste gases of a cement production process, the mercury is sorbed on a sorbent, the sorbent is subsequently discharged from the process and supplied to a discharge reactor which is operated with a carrier gas. The sorbent is heated there to temperatures of more than 250° C. so that the mercury is discharged from the sorbent and changed into the gas phase, the gas of the discharge reactor that has accumulated mercury subsequently having the dust removed from it in a preliminary dust removal device, and only a part-flow of the gas which has been enriched and had the dust removed from it in this manner being drawn off at high temperatures and cleaned in a subsequent sorption stage, whilst the remaining part-flow is brought to the temperature required for the discharge of the mercury in the discharge reactor in a heat transfer system and is again supplied as a carrier gas to the discharge reactor.Type: ApplicationFiled: August 5, 2010Publication date: May 17, 2012Inventors: Dietmar Schulz, Ludger Brentrup, Karl Menzel, Reinhard Beilmann, Detlev Kupper, Mark Terry