Hydrocarbon Sorbed Patents (Class 95/143)
  • Patent number: 6027547
    Abstract: A fluid storage and dispensing system, comprising: a fluid storage and dispensing vessel constructed and arranged for selective dispensing of fluid therefrom; a solid-phase support in the vessel; and an affinity medium on the solid-phase support, wherein the affinity medium reversibly takes up the fluid when contacted therewith, and from which the fluid is disengagable under dispensing conditions. The affinity medium may be a liquid, oil, gel, or solid (porous solid, thin film solid, or bulk solid). The system of the invention may be employed for the storage and dispensing of fluids such as hydride, halide and dopant gases for manufacturing of semiconductor products.
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: February 22, 2000
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Glenn M. Tom, Duncan W. Brown
  • Patent number: 6027549
    Abstract: The present invention is a process for adsorbing carbon dioxide from a carbon dioxide containing gas mixture comprising contacting the gas mixture with an activated carbon adsorbent having a density in the range of approximately 0.56 to 0.61 g/cc (35 to 38 lbs./ft.sup.3) and adsorbing the carbon dioxide on the activated carbon adsorbent.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: February 22, 2000
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Timothy Christopher Golden, Thomas Stephen Farris, Wilbur Clymer Kratz, William Emil Waldron, Charles Henry Johnson
  • Patent number: 6022399
    Abstract: A process for regenerating an adsorber which adsorbs organic substances from the air in which the adsorber is heated by microwave energy to evaporate adsorbed organic substances on the adsorber. The adsorber is provided with enhanced microwave absorption capacity to enable the adsorber to evaporate the adsorbed organic substances. The adsorber can be produced to have itself high microwave energy absorbing capacity or a solid material can be combined with the adsorber to provide the high microwave absorbing capacity. The solid material can be combined with an adsorbing enhancing substance and can be a carrier therefor. In a particular embodiment, the adsorber can be a hydrophobic zeolite and the microwave absorbing material can be a hydrophilic zeolite.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: February 8, 2000
    Assignee: Daimler Chrysler Ag.
    Inventors: Harald Ertl, Sabine Kunz, Johann Gobel
  • Patent number: 6019817
    Abstract: A system for capturing HAPs/VOCs from an existing or planned air stream and destroying the contaminants in the air stream by microbial degradation is disclosed. In general, the system is composed of a reservoir with a filter structure positioned above it. The filter structure contains a capture or filtration media through which contaminated air or vapors must pass. HAPs/VOCs in the air or vapors are filtered out and absorbed by the capture media. The reservoir contains a tank water bath that is inoculated with microorganisms that are selected to degrade the hazardous materials or pollutants removed by the capture media. Sprinkler heads above the filter structure spray the filter structure with a sprayed water bath also inoculated with the microorganisms, whereby contaminants caught in the filter structure are leached out and bioremediated.
    Type: Grant
    Filed: February 25, 1998
    Date of Patent: February 1, 2000
    Assignee: Agri Microbe Sales, L.C.
    Inventor: Edward D. Seagle
  • Patent number: 6019823
    Abstract: Solid-phase physical sorbent medium holding adsorbed fluid is provided in a cartridge, for use in a sorbent-based fluid storage and dispensing system. One or more of such cartridges may be disposed in a fluid storage and dispensing vessel and opened prior or subsequent to sealing of the vessel, to provide desorbable fluid for dispensing from the vessel, e.g., by pressure differential, concentration differential and/or thermal desorption. Use of such cartridges thereby obviates the sorbent bake-out and sorbate gas loading steps necessary in prior practice, thereby simplifying the manufacture of the fluid storage and dispensing system.
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: February 1, 2000
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Michael A. Tischler, Peter S. Kirlin
  • Patent number: 6017508
    Abstract: A process of modifying the porosity of an aluminosilicate or silica whose porosity is not amenable to modification by acid extraction. The process involves contacting said aluminosilicate or silica with an alkali aluminate, and then extracting the aluminate-treated material with an extraction agent so as to form the porosity-modified aluminosilicate or silica. The process is applicable to zeolites which are unreactive under acid extraction conditions, e.g. ferrierite, and applicable to zeolites which are structurally unstable under acid extraction conditions, such as the mineral bikitaite. Mesoporous compositions are disclosed, including a mesoporous ferrierite and a mesoporous zeolite DCM-3.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: January 25, 2000
    Assignee: The Dow Chemical Company
    Inventors: Dean M. Millar, Juan M. Garces
  • Patent number: 6010558
    Abstract: A rooftop grease containment system for absorbing the high viscosity grease carried by the gaseous effluent generated by cooking food and released through a rooftop exhaust vent, comprising 4-8 mm hydrophobic silica particles contained within porous pads, tubes and pillows placed in different positions in proximity to the rooftop exhaust vent is disclosed.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: January 4, 2000
    Assignee: Flame Gard, Inc.
    Inventor: Phillip Ackland
  • Patent number: 6002019
    Abstract: Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical product is removed from the product gas stream, and part or all of the remaining gas stream is passed through a bed of hydrophobic adsorbent, which adsorbs mainly the unreacted hydrocarbon from the gas stream without adsorbing water vapor. The adsorbed hydrocarbon is purged from the bed with air, and the air-hydrocarbon mixture is recycled to the partial oxidation reactor.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: December 14, 1999
    Assignee: The Boc Group, Inc.
    Inventors: Satish S. Tamhankar, Divyanshu R. Acharya, Sidney Simon Stern
  • Patent number: 6001320
    Abstract: A method for improving the adsorption properties of a hydrocarbon adsorber which involves contacting a molecular sieve hydrocarbon adsorber with an agent for modifying the acid sites of the molecular sieve to impregnate the molecular sieve with the agent. The resulting acid-modified molecular sieve has the ability to retain adsorbed hydrocarbons at higher temperatures than the molecular sieve in the un-modified state. The acid-modified molecular sieve can be used to remove hydrocarbons from a workstream. The workstream is passed through the modified adsorber at atmospheric pressure at a temperature ranging from room temperature to about 150.degree. C. to cause adsorption and retention of the hydrocarbons. The adsorbed hydrocarbons can then be desorbed at a higher temperature than would otherwise occur with an unmodified adsorber.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: December 14, 1999
    Assignee: Corning Incorporated
    Inventor: William P. Addiego
  • Patent number: 5989313
    Abstract: A pressure swing adsorber (PSA) air prepurifier includes at least a first adsorber and a second adsorber and a controller for controlling air feed to the first adsorber and the second adsorber. The invention is a "realtime" method for controlling cycle times for each adsorber and includes the following steps. During a determined time period, flow is measured to an adsorber that is coupled to an air inlet. An actual totalized flow to the on-line adsorber is accumulated, based upon the measured flow values. During this time, air feed conditions (e.g., temperature, pressure, relative humidity) are monitored and periodically, a maximum totalized flow to the adsorber is calculated, determined, at least in part, based upon the monitored air feed conditions.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: November 23, 1999
    Assignee: Praxair Technology, Inc.
    Inventor: James Brian Mize
  • Patent number: 5989314
    Abstract: A pressure swing adsorption air prepurifier is used to remove water, carbon dioxide and hydrocarbons from a feed gas stream, such as a feed air stream, passing to a cryogenic air separation plant. By the incorporation of a regenerative heat exchange as an integral part of the air prepurifier, the cooling effects of the desorption of water are stored and transferred so as to cool the incoming feed air stream passing to the adsorbent material within the air prepurifier. The productive capacity of the adsorbent material is enhanced thereby.
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: November 23, 1999
    Assignee: Praxair Technology, Inc.
    Inventors: Herbert Raymond Schaub, Frederick Wells Leavitt
  • Patent number: 5976221
    Abstract: A macroporous polymeric adsorbent is used to remove oil mist and oil vapors from compressed air produced by an oil-lubricated air compressor prior to feeding the compressed air to an air separation membrane system. The macroporous polymeric adsorbent, previously known only for its ability to extract low molecular weight volatile organic compounds from liquids and gases, retains its ability to extract the oil for extended periods of time and outperforms the commonly used activated carbon of the prior art.
    Type: Grant
    Filed: September 3, 1997
    Date of Patent: November 2, 1999
    Assignee: MG Generon, Inc.
    Inventors: Reid Henry Bowman, H. Robert Goltz
  • Patent number: 5968235
    Abstract: A VOC (volatile organic compounds) adsorbent material is treated with a masking agent to reduce its affinity for VOC's to a level that the material can be regenerated at a predetermined low temperature which will not desorb the masking agent. Preferably, the adsorbent material is a water adsorbent desiccant which is treated with water vapor. The treated adsorbent material is used to adsorb VOC's from gas and is periodically regenerated with heated air. The desorbed VOC's may be destroyed by oxidizing, for example, with a catalyst.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: October 19, 1999
    Assignee: Ransburg Corporation
    Inventors: Thomas E. Grime, Andrew P. Gargac, Larry E. Campbell
  • Patent number: 5958109
    Abstract: Organic solvents are removed from air by adsorption on fixed beds of activated carbon. Each carbon bed is periodically regenerated by heating it in two distinct steps and then by cooling it in two steps with a circulated inert gas stream. During the first step of heating a portion of the water is removed from the inert gas by molecular sieves or preferably by chilling the inert gas to below 10.degree. C. In a second step of heating the essentially water-free liquid solvent is recovered by chilling the inert gas. The first step of cooling of a bed is overlapping with the first step of heating of another bed. The hot gas leaving the cooled bed is used to heat the other bed. Between the two stages of heating the bed is put on "hold" till the final cooling step of another bed is completed.
    Type: Grant
    Filed: May 15, 1998
    Date of Patent: September 28, 1999
    Inventor: Andrija Fuderer
  • Patent number: 5948142
    Abstract: A method is provided for separating one or more volatile contaminant components from a gas using a pressure and temperature swing adsorbent filtration filter bed system containing three or more layers of adsorbent materials characterized in that the layers comprise a first layer of adsorbent material, a second layer of dessicant material and a third layer of material capable of adsorbing contaminants that are not retained by the first layer. Preferably the third layer is capable of adsorbing contaminants of relatively low boiling point, e.g. of boiling point less than 50.degree. C., and preferably comprises a microporous adsorbent. The second layer of dessicant material preferably comprises a zeolite.
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: September 7, 1999
    Assignee: The Secretary of State for Defense in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Richard J Holmes, David C Francis
  • Patent number: 5938816
    Abstract: A process for the purification of gases loaded in particular with chemical residues, in particular of the exhaust air from printing equipment, in which process the gas to be purified is drawn off from the regions producing the impurities and led via piping to an arrangement of adsorber-filter cartridges that serve for the separation of the impurities from the gas and are periodically separated in a cyclical manner from the exhaust flow for the carrying out of a regeneration process.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: August 17, 1999
    Assignee: Firma Maul & Co. - Chr. Belser GMBH
    Inventors: Rainer Harle, Winfried Marquardt
  • Patent number: 5922105
    Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: July 13, 1999
    Assignee: Ebara Research Co., Ltd.
    Inventors: Toshiaki Fujii, Tsukuru Suzuki, Hidetomo Suzuki, Kazuhiko Sakamoto
  • Patent number: 5914455
    Abstract: An air prepurification process which includes, as a first step, a pressure swing adsorption process in which the air is passed through a bed of adsorbent which contains activated alumina, thereby effecting removal of substantially all moisture and most carbon dioxide from the feed air and as a second step, a temperature swing adsorption process in which the dried feed air is passed through a bed of carbon dioxide-selective adsorbent, thereby removing substantially all of the carbon dioxide remaining in the feed air. The feed air may be passed through beds of hydrogen oxidation and carbon monoxide oxidation catalysts between the first and second steps to convert any hydrogen and carbon monoxide in the feed air to water vapor and carbon dioxide, respectively, these components being removed from the feed air during the second step.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: June 22, 1999
    Assignee: The BOC Group, Inc.
    Inventors: Ravi Jain, James K. Tseng
  • Patent number: 5912424
    Abstract: Systems and methods for electrical swing natural gas adsorption are described. An apparatus includes a pressure vessel; an electrically conductive gas adsorptive material located within the pressure vessel; and an electric power supply electrically connected to said adsorptive material. The adsorptive material can be a carbon fiber composite molecular sieve (CFCMS). The systems and methods provide advantages in that both a high energy density and a high ratio of delivered to stored gas are provided.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: June 15, 1999
    Assignee: Lockheed Martin Energy Research Corporation
    Inventors: Roddie R. Judkins, Timothy D. Burchell
  • Patent number: 5912422
    Abstract: Process for the separation of the hydrogen contained in a gas mixture contaminated by carbon monoxide and containing at least one other impurity chosen from the group consisting of carbon dioxide and saturated or unsaturated, linear, branched or cyclic C.sub.1 -C.sub.8 hydrocarbons, comprising bringing the gas mixture to be purified into contact, in an adsorption region, with at least:one first adsorbent selective at least for carbon dioxide and for C.sub.1 -C. hydrocarbons andone second adsorbent which is a zeolite of faujasite type exchanged to at least 80% with lithium, the Si/Al ratio of which is less than 1.5, in order to remove at least carbon monoxide (CO).
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: June 15, 1999
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude et L'Exploitation des Procedes Georges Claudes
    Inventors: Olivier Bomard, Jerome Jutard, Serge Moreau, Xavier Vigor
  • Patent number: 5908490
    Abstract: A compact organic solvent recovery system includes a backup treatment apparatus for environmentally safe treatment of an organic solvent leaking into a gas exiting an adsorption tower packed with an adsorbing material such as particulate active charcoal or active carbon fiber. Adsorption treatment of organic solvents includes introducing an organic solvent containing gas to be treated into an organic solvent recovery apparatus including an adsorption tower packed with adsorbing material. By subsequently introducing steam into the adsorption tower, the organic solvents are desorbed. By introducing the treated gas discharged from the organic solvent recovery apparatus into the backup treatment apparatus, the organic solvents leaking into the treated gas are adsorbed, and the gas treated in the backup treatment apparatus is simultaneously discharged as purified gas.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: June 1, 1999
    Assignee: Toho Chemical Engineering and Construction Co., Ltd.
    Inventors: Mikio Akamatsu, Kenji Seki, Taketo Hata
  • Patent number: 5906675
    Abstract: An air prepurification process carried out in a battery of three adsorption vessels arranged in parallel. The process includes three steps: a first step in which non-steady state PSA is carried out in the first and second vessels operated in alternating adsorption and bed regeneration mode while the adsorbent in the third vessel undergoes thermal regeneration; a second step in which non-steady state PSA is carried out in the second and third vessels operated in alternating adsorption and bed regeneration modes while the adsorbent in the first vessel undergoes thermal regeneration; and a third step in which non-steady state PSA is carried out in the first and third vessels operated in alternating adsorption and bed regeneration modes while the adsorbent in the second vessel undergoes thermal regeneration.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: May 25, 1999
    Assignee: The BOC Group, Inc.
    Inventors: Ravi Jain, James K. Tseng
  • Patent number: 5904750
    Abstract: A new synthetic, pyrolized, spherical adsorbent, with a moving or fluidized bed VOC control/solvent recovery system, also described as a control/solvent recovery system.
    Type: Grant
    Filed: September 17, 1997
    Date of Patent: May 18, 1999
    Inventor: Harold R. Cowles
  • Patent number: 5895769
    Abstract: Applicant has discovered a new zeolite containing composition and a process for preparing the same. The composition is unique in that the zeolite crystals making up one layer of the composition pack in a manner such that the composition is essentially continuous with no large scale voids even when the zeolite layer is <10 .mu.m thick. Thus, the present invention is directed toward a composition comprised of a porous substrate and a layer of zeolite crystals wherein said layer of zeolite crystals is a polycrystalline layer with at least 99% of said zeolite crystals having at least one point between adjacent crystals that is .ltoreq.20 .ANG. and wherein at least 90% of said crystals have widths of from about 0.2 to about 100 microns (preferably about 2 to about 50 microns) and wherein at least 75% of said crystals have a thickness of within 20% of the average crystal thickness. Preferably the composition has at most 1 Volume % voids in the zeolite layer. Use of the composition is also described.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: April 20, 1999
    Assignee: Exxon Research and Engineering Company
    Inventor: Wenyih Frank Lai
  • Patent number: 5863315
    Abstract: Four adsorbers 1 to 4, each operating in a cycle comprising (described for adsorber 2): an adsorption step 1 wherein a feed from adsorber 2 is circulated to adsorber 2; an adsorption step 2 wherein feed is injected to the bottom of adsorber 2 and a product rich in isoparaffins is recovered from the head of adsorber 2; an adsorption step 3 wherein a portion of the fluid leaving adsorber 2 is sent to adsorber 3; an adsorption step 4 wherein the head of adsorber 2 receiving the feed is connected to the bottom of adsorber 3; a first depressurisation step 5 wherein adsorber 2 at high pressure is connected to adsorber 4 at a lower pressure; a second depressurisation step 6 wherein the head of adsorber 2 is closed; a stripping step 7 wherein the bottom of adsorber 2, which receives desorbent overhead, is connected to the top of adsorber 2; two principal stripping steps 8 and 9 wherein adsorber 2 alone is supplied with desorbent; a stripping finishing step 10 wherein adsorber 2 is continued to be supplied with desorb
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: January 26, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Sophie Jullian, Jean-Louis Ambrosino, Alain Chansolme, Valerie Wiss-Henrard
  • Patent number: 5861050
    Abstract: Described are preferred vapor recovery canisters which are useful in on-board vehicle fuel vapor recovery systems. The preferred canisters incorporate thermal management of solid adsorbent with phase change materials to improve both adsorptive and desorptive capacity of the canisters. Also described are preferred encapsulation members for use in the vapor recovery canisters.
    Type: Grant
    Filed: November 8, 1996
    Date of Patent: January 19, 1999
    Assignee: Store Heat and Produce Energy, Inc.
    Inventors: Alan Pittel, Alexander P. Rafalovich, John D. Cathcart
  • Patent number: 5858068
    Abstract: Industrial grade carbon dioxide may contain unacceptable amounts of sulfur-containing materials, oxygen, and organic materials particularly detrimental to food-related uses of CO.sub.2. These can be effectively removed by a bed of silver-exchanged faujasite and an MFI-type molecular sieve. This permits an on-site, on-demand method of purifying CO.sub.2 ranging from laboratory to tank car seals.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: January 12, 1999
    Assignee: UOP LLC
    Inventors: James R. Lansbarkis, Jon S. Gingrich
  • Patent number: 5840099
    Abstract: A process is set forth for the selective removal of water, CO.sub.2, ethane and C.sub.3 + hydrocarbons from gas streams, particularly a natural gas stream comprising primarily methane. The process comprises contacting the gas stream with an adsorbent material consisting exclusively of one or more compounds which are basic (i.e. compounds which, when contacted with a pH neutral aqueous solution, cause such solution to have a pH greater than 7.0) and which are mesoporous (i.e. compounds which have moderately small pores providing a surface area less than 500 m.sup.2 /g). The key to the present invention is the use of a single homogenous adsorbent without sacrificing performance. Typical mesoporous adsorbents which are useful in the present invention include zinc oxide, magnesium oxide and, in particular, activated alumina.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: November 24, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Wilbur Clymer Kratz, Timothy Christopher Golden, Mohammad Ali Kalbassi
  • Patent number: 5827355
    Abstract: An electrically regenerable gas filter system includes a carbon fiber composite molecular sieve (CFCMS) filter medium. After a separate medium-efficiency pre-filter removes particulate from the supply airstream, the CFCMS filter sorbs gaseous air pollutants before the air is recirculated to the space. When saturated, the CFCMS media is regenerated utilizing a low-voltage current that is caused to pass through the filter medium.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: October 27, 1998
    Assignee: Lockheed Martin Energy Research Corporation
    Inventors: Kirk A. Wilson, Timothy D. Burchell, Roddie R. Judkins
  • Patent number: 5814132
    Abstract: A VOC (volatile organic compounds) adsorbent material such as an alumino-silicate gel desiccant is treated with a masking agent to reduce its affinity for VOC's to a level that the material can be regenerated at a predetermined low temperature which will not desorb the masking agent. The treated adsorbent material is used to adsorb VOC's and is periodically regenerated with heated air. The treated adsorbent material may be used to adsorb VOC's from recirculated spray booth air while spraying a coating on a workpiece. Subsequent to spraying, the spray booth air is heated to above the VOC regeneration temperature to regenerate the adsorbent material and optionally to cure the applied coating. As the heated spray booth air is circulated through the adsorbent material, the previously adsorbed VOC's are desorbed. The desorbed VOC's may be destroyed by oxidizing, for example, with a catalyst.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: September 29, 1998
    Assignee: Ransburg Corporation
    Inventors: Thomas E. Grime, Andrew P. Gargac, Larry E. Campbell
  • Patent number: 5803953
    Abstract: A process for the treatment of natural gas that contains an odorant at a storage site is described, with this process including a storage phase and a draw-down phase which involve at least two adsorbers A and B and in which, during the storage phase, the odorant is extracted from the gas and, during the draw-down phase; the water and H.sub.2 S that are contained in the gas are extracted.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: September 8, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Alexandre Rojey, Michel Thomas, Sophie Jullian
  • Patent number: 5804155
    Abstract: The present invention relates to a composition comprising at least one zeolite consisting essentially of the zeolites selected from the group of neutral and basic zeolites and at least one platinum group metal component. This composition has been found to be useful in a method of treating gas streams comprising hydrocarbons comprising the steps of adsorbing the hydrocarbons on the recited zeolites at a low adsorption temperature range, releasing the hydrocarbons from the zeolite at a high release temperature range and oxidizing the hydrocarbons.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: September 8, 1998
    Assignee: Engelhard Corporation
    Inventors: Robert J. Farrauto, Michel Deeba
  • Patent number: 5795368
    Abstract: A microtrap sample concentrator useful for concentrating a sample of purged gas containing analytes for delivery to an analytical instrument, including: a tube containing at least one sorbent material which retains or traps analytes; where greater than 30% of all trapped analytes are directly delivered to an analytical instrument at a desorption flow rate of one to three cc/min, without splitting or cryogenic focusing the trapped analytes; where delivery of the trapped analytes to the analytical instrument is achieved by passing the trapped analytes through a passage being selectively connectable between the microtrap and the analytical instrument, the passage connected to a vent; where the temperature of the passage is not lower than ambient room temperature; and where the passage is heated to a temperature sufficient to vaporize water in the passage and to expel the vaporized water out of the vent.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: August 18, 1998
    Assignee: O.I. Corporation
    Inventors: Lowell Wright, Scott M. Abeel, Nathan C. Rawls, Ronald D. Snelling
  • Patent number: 5792239
    Abstract: A natural gas feed stream containing significant quantities of nitrogen and/or carbon dioxide can be increased to a content of greater than 95 percent by volume of natural gas, and preferably greater than about 98 percent, by passing the natural gas feed stream sequentially through three adsorbent beds that are cycled through seven phases comprising: an adsorption phase to adsorb a first gas, a first depressurization phase to remove feed gas from the voids in the adsorbent bed, a recycle phase to remove a second gas from the adsorbent by the passage of a second depressurization gas therethrough and to produce a recycle gas, a second depressurization phase to reduce the adsorbent bed pressure to about ambient and to produce the second depressurization gas, an evacuation phase where the pressure in the adsorbent is further reduced and an enriched primary gas product stream recovered, a pressurization phase where the pressure in the adsorbent bed is increased using secondary product gas from a bed in an adsorpti
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: August 11, 1998
    Assignee: Nitrotec Corporation
    Inventors: Herbert Edward Reinhold, III, Kent S. Knaebel, Mark Huber, David R. King
  • Patent number: 5769928
    Abstract: The invention comprises a PSA gas prepurifier for the removal of contaminants present in a feed gas stream. The prepurifier of the invention has a bed of adsorbent material which comprises at least two discrete layers of adsorbents, at least one of the adsorbents being comparatively strong and at least another of the adsorbents being comparatively weak.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 23, 1998
    Assignee: Praxair Technology, Inc.
    Inventor: Frederick Wells Leavitt
  • Patent number: 5759238
    Abstract: In a vent arrangement comprising a heating cylinder 1 containing therein a screw and provided with a vent hole 3 and a reduced pressure exhaust path 4 provided with a vacuum pump and connected to the vent hole 3 for draining volatile fractions of a material to be molded from the heating cylinder by reducing the pressure in the vent hole by means of the vacuum pump, said volatile fractions are removed by arranging in the exhaust path a filter unit 7 filled with a granular filtering material 8. The material to be molded is used for the filtering material 8. According to the above construction, it can be achieved to efficiently remove volatile matters by using the molded material as the filtering material of the filter unit arranged in the reduced pressure exhaust path of a vent arrangement.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: June 2, 1998
    Assignee: A.K. Technical Laboratory, Inc.
    Inventors: Yukio Yanagimachi, Hideaki Koda
  • Patent number: 5759236
    Abstract: A process for separating organic compounds, such as solvents, from gases, e.g. waste gases of paint shops. The gases to be treated are conducted in an adsorber over a sorbent which is composed of particulate activated carbon in an oxidic carrier. The charged sorbent is regenerated by passing therethrough, preferably according to the countercurrent principle, a heated regeneration gas, the regeneration gas charged with desorbate is cooled so that organic compounds condense and can then be separated, whereupon the regeneration gas is reheated and reused for the desorption of the charged sorbent. Heating of the regeneration gas as well as cooling of the regeneration gas charged with desorbate are, at least partially, effected by a heat pump. It will be expedient to provide at least two adsorbers which are charged and regenerated alternately. An apparatus for carrying out the process is additionally described.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: June 2, 1998
    Assignee: Engelhard Process Chemicals GmbH
    Inventors: Heinrich Thomas Bruck, Leo Vondenhoff, Michael Hoffmeister, Torsten Schmidt
  • Patent number: 5753010
    Abstract: A method for increasing product recovery or reducing the size of steam methane reformer and pressure swing adsorption systems utilized for hydrogen production. A significant portion of the hydrogen in the PSA depressurization and purge effluent gas, which is otherwise burned as fuel in the reformer, is recovered and recycled to the PSA system to provide additional high purity hydrogen product. This is accomplished by processing selected portions of the depressurization and purge effluent gas in adsorbent membrane separators to increase hydrogen content for recycle to the PSA system. Remaining portions of the depressurization and purge effluent gas which contain lower concentrations of hydrogen are utilized for fuel value in the reformer.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: May 19, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Shivaji Sircar, William Emil Waldron, Madhu Anand, Madhukar Bhaskara Rao
  • Patent number: 5746788
    Abstract: Described is a process for the simultaneous sorption of water and organic compounds from gases selected from the group comprising natural gas and process gases (e.g. waste gases of maleic acid or terephthalic acid (anhydride) production or phthalic acid anhydride production or of steam reforming). The gas to be treated is contacted with a sorbent comprising particulate activated carbon in an oxidic carrier on a basis of silicon dioxide, aluminum oxide, aluminum phosphate or aluminosilicate. When natural gas is treated, water and C5+ hydrocarbons, for example, can be separated simultaneously. In steam reforming, with appropriate process management, C2+ hydrocarbons, CO.sub.2 and water can be absorbed simultaneously.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: May 5, 1998
    Assignee: Engelhard Process Chemicals GmbH
    Inventors: Torsten Schmidt, Michael Hoffmeister
  • Patent number: 5738710
    Abstract: The invention provides a method and apparatus for recovering a target material including using an adsorbent such as activated charcoal, the target material recovered in a continuous manner, as well as a method and an apparatus for recovering a solvent based on such a method and apparatus. The adsorbent for the target material is rotated to move the adsorbed material in direction of centrifugal force while the target material is attracted to the adsorbent. The excess target material is detached from a peripheral edge of the adsorbent by centrifugal force. The detached material is recovered by a recovery device provided in corresponding relation to the adsorbent.
    Type: Grant
    Filed: May 13, 1996
    Date of Patent: April 14, 1998
    Assignee: Morikawa Industries Corporation
    Inventors: Kazuo Omata, Katsumi Shibata, Yukio Shirai
  • Patent number: 5733515
    Abstract: The present invention discloses an improved method for filtration of air within enclosed spaces. Improvement is achieved by the use of a high-temperature carbonaceous char that is catalytically active for the removal of certain undesirable constituents from contaminated air under ambient temperature conditions. This carbonaceous char is used as an air filtration medium and incorporated into an air filtration device by any of a number of technologies. Such devices may be used for removal of contaminants such as NO.sub.x, NO.sub.2, SO.sub.x, SO.sub.2, H.sub.2 S, mercaptans, light aliphatic gases such as butane and propane and other compounds such as benzene, hexane, toluene, xylene, amines and the like from enclosed or confined structures such as buildings or vehicles including automobiles, aircraft, trucks, farm equipment, and the like.
    Type: Grant
    Filed: February 28, 1996
    Date of Patent: March 31, 1998
    Assignee: Calgon Carbon Corporation
    Inventors: David T. Doughty, Richard A. Hayden, John W. Cobes, III, Thomas M. Matviya
  • Patent number: 5725635
    Abstract: Method to remove organic halogenated molecules from gaseous currents arriving as a residue of industrial working processes or not, the gaseous current being delivered into a reactor (16) containing a fluid bed consisting of at least one solid adsorbent element after having undergone at least one filtration followed by a cooling, the gaseous current cooperating with the solid particles with exchange by adsorption between the gaseous current and the solid particles, the reactor (16) achieving a time of contact between the gaseous current and the solid particles at least longer than 3 seconds, the gaseous current which enters the reactor (16) having a temperature lower than 80.degree. C., but advantageously between 30.degree. and 70.degree. C., the cooling of the gaseous current upstream of the reactor (16) being followed by a gas/water or gas/air heat exchanger (13).
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: March 10, 1998
    Assignee: Danieli & C. Officine Meccaniche SpA
    Inventors: Fulvio Zubini, Iginio Colussi, Vittorino Gallo, Matteo Vittorio Losciale
  • Patent number: 5713985
    Abstract: A multi-function separator provides a coalescing section for removal of entrained impurities in a process stream; an adsorbent section for removal of vapor contaminants; and a filter section for removal of particulate impurities. A process stream flows into longitudinal hollow centers of porous coalescer robes and radially out; through holes in a baffle; into an adsorbent section; through a redistribution baffle; into filters; and out through another redistribution baffle. The multi-function separator is designed so that the process stream flows transverse to the longitude of an elongate vessel. The fluid velocity within the coalescer section is equal throughout, so that localized high-velocity areas are avoided, thus preventing re-entrainment of a coalesced contaminant.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: February 3, 1998
    Inventor: Boyd Lynn Hamilton
  • Patent number: 5707425
    Abstract: The present process is directed to the efficient recovery of helium gas from gas streams which contain about 25 percent by volume or more helium. The process comprises two stages of pressure swing adsorption, each stage being comprised of a plurality of interconnected adsorbent beds. In the first stage of pressure swing adsorption which is comprised of about five phases, the helium content of the gas stream is increased to 95 percent by volume or more. A secondary product gas stream from the first stage of pressure swing adsorption is fed to the second stage of pressure swing adsorption. The second stage of pressure swing adsorption increases the helium content of this primarily non-helium product gas to more than about 50 percent by volume. This gas now with a helium content of more than about 50 percent by volume is fed along with the gas stream as the input gas to the first stage of pressure swing adsorption.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: January 13, 1998
    Assignee: Nitrotec Corporation
    Inventors: Joseph S. D'Amico, Herbert Edward Reinhold, III, Kent S. Knaebel
  • Patent number: 5704965
    Abstract: An adsorption-desorption apparatus, for storage and dispensing of a sorbable gas, wherein a carbon physical sorbent medium bearing the adsorbed gas to be selectively dispensed is delivered by pressure differential desorption and/or thermal desorption of the sorbate gas from the sorbent material. The carbon sorbent material preferably comprises a material which is characterized by a Sorbent Working Capacity, measured for arsine at 40 Torr and at 650 Torr, of at least 100 grams arsine per liter of bed of the sorbent material, e.g., a carbon sorbent material having the adsorption isotherm characteristic of curve A in FIG. 1 herein.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: January 6, 1998
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Glenn M. Tom, James V. McManus, W. Karl Olander
  • Patent number: 5702505
    Abstract: A method for collecting volatile organic substances from an off-gas containing moisture and volatile organic substances. The organic substances are removed from the gas containing the organic substances and the moisture by introducing the gas into an adsorbing tower filled with the adsorbents and being in the adsorbing process under a relatively low temperature condition. The gas is discharged outside the system as the gas containing the moisture but from which the organic substances have been removed. The organic substances are desorbed under a relatively high temperature condition in the regenerating process for the regeneration. The moisture is removed from the desorbed gas discharged from the adsorbent regenerating process in a dehumidifying tower filled with the moisture absorbent by the temperature swing method or pressure swing method.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: December 30, 1997
    Assignee: Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Jun Izumi, Akinori Yasutake, Hiroyuki Tsutaya, Takayuki Harada, Kenichi Hamada
  • Patent number: 5700436
    Abstract: The present invention discloses an improved method for filtration of air within enclosed spaces. Improvement is achieved by the use of a high-temperature carbonaceous char that is catalytically active for the removal of certain undesirable constituents from contaminated air under ambient temperature conditions. This carbonaceous char is used as an air filtration medium and incorporated into an air filtration device by any of a number of technologies. Such devices may be used for removal of contaminants such as NO.sub.x, NO.sub.2, SO.sub.x, SO.sub.2, H.sub.2 S, mercaptans, light aliphatic gases such as butane and propane and other compounds such as benzene, hexane, toluene, xylene, amines and the like from enclosed or confined structures such as buildings or vehicles including automobiles, aircraft, trucks, farm equipment, and the like.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: December 23, 1997
    Assignee: Calgon Carbon Corporation
    Inventors: David T. Doughty, Richard A. Hayden, John W. Cobes, III, Thomas M. Matviya
  • Patent number: 5700310
    Abstract: A macroporous polymeric adsorbent is used to remove oil mist and oil vapors from compressed air produced by an oil-lubricated air compressor prior to feeding the compressed air to an air separation membrane system. The macroporous polymeric adsorbent, previously known only for its ability to extract low molecular weight volatile organic compounds from liquids and gases, retains its ability to extract the oil for extended periods of time and outperforms the commonly used activated carbon of the prior art.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: December 23, 1997
    Assignee: MG Generon, Inc.
    Inventors: Reid Henry Bowman, H. Robert Goltz
  • Patent number: 5695546
    Abstract: A method for collecting volatile organic substances from off-gas containing moisture and volatile organic substances. After the moisture has been removed by a dehumidifying tower filled with moisture absorbent for selectively adsorbing the moisture from the gas containing the organic substances and the moisture, the organic substances are adsorbed and removed under a relatively low temperature condition. The organic substances is desorbed under a relatively high temperature condition from the adsorbing tower which is saturated with the organic substances. The desorbed organic substances are liquefied and collected under a low temperature and/or pressurizing condition. The dry gas from which the organic substances have been removed and made harmless is heated if necessary.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: December 9, 1997
    Assignee: Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Jun Izumi, Akinori Yasutake, Hiroyuki Tsutaya, Takayuki Harada, Kenichi Hamada
  • Patent number: 5681369
    Abstract: An apparatus is provided for recovering volatile liquid vapor from an air-volatile liquid vapor mixture. The apparatus includes first and second reaction vessels. Each of these reaction vessel includes a bed of adsorbent having an affinity for the volatile liquid vapor. The apparatus also includes a pump and an absorber for regenerating either bed of adsorbent. Further, the apparatus includes a polisher including a polisher bed of adsorbent having an affinity for the volatile liquid vapor. This polisher bed adsorbs volatile liquid vapor and substantially clean air is exhausted when initially regenerating one of the two beds of adsorbent in the first and second reaction vessels. Still further, the apparatus also includes a cooperating valve and conduit system for interconnecting the other components. Further, the invention relates to a related process for recovering volatile liquid vapor and a method of reducing backpressure in a volatile liquid vapor recovery system or unit.
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: October 28, 1997
    Assignee: Jordan Holding Company
    Inventor: John B. Osborne