Liquid Recycled Or Reused Patents (Class 95/174)
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Patent number: 11484829Abstract: A flue gas can be cooled for carbon capture purposes with the use of a gas-to-gas exchanger, using air as the cooling media, downstream of a heat recovery process, and optionally upstream of a quenching process; the use of an amine chilling process to reduce the required flue gas cooling duties upstream of the CO2 absorber; the use of a gas-to-gas exchanger, using the absorber overhead as the cooling media, downstream of a heat recovery process, and optionally upstream of the quenching process; and/or the use of a quenching process in which heated water and condensate is cooled by an external cooling loop utilizing treated flue gas condensate in an evaporative cooling process.Type: GrantFiled: May 5, 2022Date of Patent: November 1, 2022Assignee: NEXT CARBON SOLUTIONS, LLCInventors: Ivan Van der Walt, Ben Heichelbech, Alex Thompson, Connor Rivard, Victor Fernandes
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Patent number: 10864477Abstract: A process for removing C5-C8-hydrocarbons and acid gases from a fluid stream is described, where a) the fluid stream is brought into contact with an absorption medium comprising at least one amine in an absorption zone to obtain a deacidified fluid stream and an acid-gases-laden absorption medium, b) the laden absorption medium is heated in a first heat exchanger and decompressed into a decompression zone to a pressure of from 5 to 10 bar to obtain a C5-C8-hydrocarbons-comprising gas phase and a hydrocarbon-depleted laden absorption medium, c) the hydrocarbon-depleted laden absorption medium is heated in an optional second heat exchanger and passed into a stripper in which at a pressure of 1 to 2.5 bar the acid gases are at least partially liberated by supplying heat to obtain a regenerated absorption medium and an acid-gas-comprising stream, and d) the regenerated absorption medium is recycled into the absorption zone.Type: GrantFiled: February 2, 2017Date of Patent: December 15, 2020Assignee: BASF SEInventors: Torsten Katz, Ralf Notz, Andreas Kern
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Patent number: 10449495Abstract: A gas treatment system includes an absorber, a liquid separator, a regenerator, a circulation mechanism and a heat transfer apparatus. The absorber contacts the gas with the treatment liquid. The liquid separator separates the treatment liquid having been in contact with the gas into a first phase portion having a high content of the acidic compound and a second phase portion having a low content of the acidic compound. The regenerator heats the first phase portion to eliminate the acidic compound from the first phase portion. The circulation mechanism recycles the second phase portion and the treatment liquid from which the acidic compound has been eliminated by the regenerator, in the absorber as a treatment liquid with which the gas is to be contacted. The heat transfer apparatus transfers heat from the treatment liquid discharged by the absorber and from the gas having undergone separation of the acidic compound, to the treatment liquid in the regenerator.Type: GrantFiled: August 18, 2016Date of Patent: October 22, 2019Assignee: Kobe Steel, Ltd.Inventors: Akira Kishimoto, Akira Matsuoka, Norihide Maeda, Makoto Nishimura
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Patent number: 9987587Abstract: A method for the treatment of a gas stream, wherein before the combustion of the gas stream, hydrogen sulfide is separated out of the gas stream in a first absorber by an absorption medium, the treated gas stream purified of hydrogen sulfide is burnt in a combustion apparatus, the carbon dioxide contained in the exhaust gas of the burnt gas stream after combustion is separated in a second absorber by an absorption medium, and the separated hydrogen sulfide and carbon dioxide are separated in at least one desorber from the absorption medium for the regeneration of the latter. The same absorption medium separates the hydrogen sulfide out of the gas stream and the carbon dioxide out of the exhaust gas. A corresponding device for the treatment of a gas stream has a first absorber and a second absorber flow-connected to one another for the exchange of absorption medium.Type: GrantFiled: February 3, 2014Date of Patent: June 5, 2018Assignee: SIEMENS AKTIENGESELLSCHAFTInventors: Kevin Brechtel, Bjorn Fischer, Rudiger Schneider, Henning Schramm
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Patent number: 9956518Abstract: The present invention relates to an acid gas capture system and method which can reduce the energy consumption by using the heat from the system itself of an acid gas capture system. The system and method according to the present invention causes heat exchange to occur between an absorbent discharged from the upper part of an absorption tower of the capture system and a mixed gas comprising an acid gas, and a portion of an absorbent solution which has absorbed the acid gas discharged from the lower part of the absorption tower, and additionally, the remaining absorbent solution excluding said portion thereof undergoes heat exchange with the regenerated high-temperature absorbent solution discharged from the reboiler to preheat the absorbent solution supplied to the regeneration tower, thereby reducing the thermal energy required by same.Type: GrantFiled: December 9, 2013Date of Patent: May 1, 2018Assignee: KOREA INSTITUTE OF ENERGY RESEARCHInventors: Il Hyun Baek, Jong Kyun You, Ki-Tae Park
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Patent number: 9314734Abstract: A system and method for recovering a solvent from a decarbonated flue gas in an absorption column, the decarbonated flue gas having had carbon dioxide absorbed and removed by vapor-liquid contact with a carbon dioxide absorbing solution containing the solvent. The system includes an emission control section configured to bring a water stream substantially free of the solvent into contact with the decarbonated flue gas to recover the solvent from the decarbonated flue gas and to form a solvent containing wash water and a reduced solvent containing flue gas and a flue gas cooling section configured to bring cooled wash water into contact with the reduced solvent containing flue gas to cool the reduced solvent containing flue gas and condense water from the decarbonated flue gas thereby forming a cooled flue gas and used wash water.Type: GrantFiled: January 6, 2011Date of Patent: April 19, 2016Assignee: ALSTOM Technology LtdInventors: Barath Baburao, Michael W. Pontbriand
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Patent number: 9163188Abstract: A process is described for separating a gas stream containing hydrogen sulfide (H2S) impurities into a hydrogen (H2) rich vapor stream, a carbon dioxide (CO2) stream and an H2S rich vapor stream in an apparatus that comprises a compression and/or cooling system comprising at least one compressor and/or heat exchanger and a gas-liquid separator vessel, and an H2S recovery unit.Type: GrantFiled: July 23, 2010Date of Patent: October 20, 2015Assignees: BP Alternative Energy international Limited, Mitsubishi Heavy Industries LimitedInventors: Jonathan Alec Forsyth, Yasushi Mori, Kazumasa Ogura
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Patent number: 8900355Abstract: Impure carbon dioxide (“CO2”) comprising a first contaminant selected from the group consisting of oxygen (“O2”) and carbon monoxide (“CO”) is purified by separating expanded impure carbon dioxide liquid in a mass transfer separation column system. The impure carbon dioxide may be derived from, for example, flue gas from an oxyfuel combustion process or waste gas from a hydrogen (“H2”) PSA system.Type: GrantFiled: November 5, 2010Date of Patent: December 2, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Publication number: 20140329299Abstract: A method for removing carbon dioxide from methane-containing crude gases, especially biogas, by pressure scrubbing, using a physical solvent, includes circulating the contaminated scrubbing solution after regeneration. A plant suitable for carrying out the method considerably reduces the methane loss which arises through methane slippage and improves the overall energy balance of the method. Laden scrubbing solution obtained from the pressure scrubbing is treated at least in one flash stage before the first stripping stage. In addition, a nitrogen, oxygen, carbon dioxide and methane-containing gas mixture drawn off from the flash stage is cleaned in a scrubbing stage by purified scrubbing solution drawn off from the second stripping stage and supplied in countercurrent, forming a high-purity methane gas.Type: ApplicationFiled: December 16, 2011Publication date: November 6, 2014Inventor: Lothar Guenther
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Patent number: 8876954Abstract: A natural gas dehydration system and method includes a contactor, a flash tank, and a still interconnected by a desiccant circulation system. A continuously fired reboiler is coupled to the still and the flash tank to burn the flash gas from the flash tank and heat the desiccant.Type: GrantFiled: April 7, 2011Date of Patent: November 4, 2014Assignee: Moneyhun Equipment Sales and Service Co.Inventors: Joe Witherspoon, David H. Moneyhun
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Patent number: 8864887Abstract: A slug-containing vapor recovery system wherein pressure and/or fluid level sensors are provided which monitor for conditions caused by the entry of a slug of hydrocarbon liquid, including that caused by a plunger-lift system. The system can be configured to accommodate virtually any anticipated slug-events.Type: GrantFiled: September 30, 2011Date of Patent: October 21, 2014Inventors: Rodney T. Heath, Forrest D. Heath, Gary Heath
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Patent number: 8845788Abstract: A syngas treatment plant is configured to remove sulfurous compounds from syngas in a configuration having two flash stages for a physical solvent to so enrich the acid gas to at least 40 mol % H2S or higher as required by the Claus unit and to flash and recycle CO2 back to the syngas feed. Contemplated methods and configurations advantageously remove sulfur to less than 10 ppmv while increasing H2S selectivity at high pressure operation to thereby allow production of an H2S stream that is suitable as feed gas to a Claus plant.Type: GrantFiled: August 7, 2012Date of Patent: September 30, 2014Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8845787Abstract: Acid compounds are removed from a gaseous effluent in an absorption method using an aqueous solution of N,N,N?,N?-tetramethylhexane-1,6-diamine formulated with a particular primary or secondary amine, allowing to obtain a single-phase absorbent solution under the absorption conditions of acid gases such as CO2. The method is advantageously applied to the treatment of natural gas and of gas of industrial origin.Type: GrantFiled: July 21, 2009Date of Patent: September 30, 2014Assignee: IFP Energies NouvellesInventors: Marc Jacquin, Julien Grandjean, Thierry Huard
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Patent number: 8821615Abstract: The disclosure relates to a process for treating a gas mixture containing carbon dioxide and hydrogen sulphide, including the following steps: deacidificating the gas mixture by bringing the gas mixture into contact with a first lean absorbent solution stream, delivering a deacidified gas mixture, and a first rich absorbent solution stream; regenerating the first rich absorbent solution stream, delivering the first lean absorbent solution stream and a sour gas stream; distillating the sour gas stream, delivering a first carbon-dioxide-rich stream and a hydrogen-sulphide-rich stream; purifying the first carbon-dioxide-rich stream by bringing the first carbon-dioxide-rich stream into contact with a second lean absorbent solution stream, delivering a second carbon-dioxide-rich stream and a second rich absorbent solution stream, the molar concentration of carbon dioxide in the second carbon-dioxide-rich stream being greater than the molar concentration of carbon dioxide in the first carbon-dioxide-rich stream.Type: GrantFiled: June 25, 2010Date of Patent: September 2, 2014Assignee: Total S.A.Inventors: Claire Weiss, Renaud Cadours, Kamal Bouzalmata
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Publication number: 20140224119Abstract: The present invention relates to a method of removing an absorbate from gases or gas mixtures containing absorbate, in which the gas or gas mixture is contacted by a liquid mixture of absorption agent and absorbate or of liquid absorbate-free absorption agent, wherein the absorbate is absorbed at least partially by the liquid mixture of absorption agent and absorbate and is concentrated therein or is absorbed by the liquid absorbate-free absorption agent while forming a liquid mixture of absorption agent and absorbate. It is characteristic in the method in accordance with the present invention that the absorption agent used and the absorbate used have a miscibility gap.Type: ApplicationFiled: February 8, 2013Publication date: August 14, 2014Applicant: Uhde Inventa-Fischer GmbHInventor: Steffen Kujath
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Patent number: 8795415Abstract: A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange.Type: GrantFiled: May 25, 2010Date of Patent: August 5, 2014Assignees: BASF SE, JGC CorporationInventors: Torsten Katz, Georg Sieder, Koji Tanaka
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Patent number: 8779223Abstract: A method for reducing one or more additives in a gaseous hydrocarbon stream (40) such as natural gas, comprising the steps of: (a) admixing an initial hydrocarbon feed stream (10) with one or more additives (20) to provide a multiphase hydrocarbon stream (30); (b) passing the multiphase hydrocarbon stream (30) from a first location (A) to a second location (B2); (c) at the second location (B2), passing the multiphase hydrocarbon stream (30) through a separator (22) to provide one or more liquid streams (50) comprising the majority of the one or more additives, and a gaseous hydrocarbon stream (40) comprising the remainder of the one or more additives; and (d) washing the gaseous hydrocarbon stream (40) in a decontamination unit (24) with a washing stream (60), wherein the washing stream (60) comprises distilled water, to provide an additive-enriched stream (70) and an additive-reduced hydrocarbon stream (80).Type: GrantFiled: April 22, 2013Date of Patent: July 15, 2014Assignee: Shell Oil CompanyInventors: Paul Clinton, Marcus Johannes Antonius Van Dongen, Nishant Gupta
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Patent number: 8758483Abstract: A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange.Type: GrantFiled: May 25, 2010Date of Patent: June 24, 2014Assignees: BASF SE, JGC CorporationInventors: Torsten Katz, Georg Sieder, Koji Tanaka
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Patent number: 8728209Abstract: A method for reducing energy requirements of a CO2 capture system comprises: contacting a flue gas stream with a CO2 lean absorbent stream in an absorber, thereby removing CO2 from the flue gas and providing a CO2 rich absorbent stream; heating a first portion of the CO2 rich absorbent stream using heat from the CO2 lean absorbent stream, and providing the heated first portion of the CO2 rich absorbent stream to a regenerator; providing a second portion of the CO2 rich absorbent stream to the regenerator, wherein the heated first portion is hotter than the second portion and the heated first portion is provided to the regenerator at a lower elevation in the regenerator relative to that of the second portion.Type: GrantFiled: August 2, 2011Date of Patent: May 20, 2014Assignee: ALSTOM Technology LtdInventors: Joseph P. Naumovitz, Michael Koch
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Publication number: 20140112855Abstract: This invention relates to the separation of components from a gas mixture. Aspects of the invention relate to the separation of components, for example carbon dioxide (CO2) and/or hydrogen sulphide (H2S) from, for example, acid gas, for example natural gas, syngas or process gas although features of the invention may be applied to other source gases. Such a process is sometimes referred to as acid gas removal (AGR). In examples described herein, the source gas mixture contains CO2 and/or H2S in addition to other components and in some examples, the CO2 and/or H2S components of the gas are referred to as acid gas components. In examples of the invention, some or all of the acid gas component is removed using a solvent absorption method; some examples described use a chemical absorption system (for example including N-Methyl diethanolamine (MDEA)), and others use a physical solvent (for example based on methanol (MeOH)).Type: ApplicationFiled: October 22, 2013Publication date: April 24, 2014Applicant: BP ALTERNATIVE ENERGY INTERNATIONAL LIMITEDInventor: Yasushi Mori
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Patent number: 8696798Abstract: Acid gas is removed from a feed gas using a physical solvent that is regenerated using successive flashing stages after heating of the rich solvent using low-level waste heat that is preferably produced or available within the acid gas removal plant. Especially preferred waste heat sources include compressor discharges of the refrigeration system and/or recompression system for CO2, and/or (low level) heat content from the feed gas.Type: GrantFiled: September 30, 2009Date of Patent: April 15, 2014Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8689432Abstract: Modular amine plants and methods of installing modular amine plants are provided. The method includes providing to a site a modular amine plant having a front-end module and a back-end module in fluid communication with each other. The front-end module having pre-fabricated connections for the association of various equipment including: a filter, an absorption tower, and a flash tank. The back-end module having pre-fabricated connections for the association of other various equipment including: a heat exchanger, a distillation tower, and a reboiler. The modular amine plant having moment forces sufficient to withstand wind speeds of about 100 miles per hour.Type: GrantFiled: June 21, 2012Date of Patent: April 8, 2014Assignee: CDM Resource Management LLCInventors: Glen Wind, John Kenton Thompson, Lance Perryman
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Publication number: 20140090558Abstract: An absorption medium which comprises water, an amine (A) of formula (I) in which R is an n-alkyl radical having 1 to 4 carbon atoms, and an alkanolamine (B) which is a tertiary amine or a sterically hindered primary or secondary amine has a high absorption capacity for CO2 with a high absorption rate. In the absorption of acid gases from a gas mixture a separation of the absorption medium into two liquid phases or the precipitation of a solid upon absorption of CO2 and regeneration of the absorption medium can be avoided with the absorption medium, even without addition of a solvent.Type: ApplicationFiled: May 25, 2012Publication date: April 3, 2014Applicant: Evonik Degussa GmbHInventors: Jörn Rolker, Matthias Seiler, Rolf Schneider, Thibaut Lenormant
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Patent number: 8652236Abstract: The present invention describes a method for recovery of high purity carbon dioxide, which is substantially free of nitrogen oxides. This high purity carbon dioxide is obtained by introducing into the method a step in which carbon dioxide absorbed in an absorbing agent is flashed. The present invention also discloses a plant for recovery of said high purity carbon dioxide comprising an absorption column, a flash column, a stripper column, and a down stream purification unit comprising a washing column, a dehydrator, a condenser and a distillation unit.Type: GrantFiled: January 16, 2008Date of Patent: February 18, 2014Assignee: Union Engineering A/SInventors: Rasmus Find, Svend Geleff, Maj Toft Andersen
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Publication number: 20130312607Abstract: The present invention relates to the use of (poly)-oxymethylene dialkyl ethers as agents for capturing carbon oxides, CO and/or CO2. The invention also relates to the process for capturing carbon oxides using at least one absorption agent chosen from said (poly)oxymethylene dialkyl ethers.Type: ApplicationFiled: October 18, 2011Publication date: November 28, 2013Applicant: Arkema FranceInventors: Dominique Plee, Georges Fremy
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Publication number: 20130247758Abstract: CO2 is absorbed from a gas mixture by contacting the gas mixture with an absorption medium which comprises at least water as solvent and at least one amine of formula (I) where R1 is an aliphatic radical, having 2 to 6 carbon atoms and at least one amino group, and R2 is hydrogen, a C1-4 alkyl radical or a radical R1.Type: ApplicationFiled: November 10, 2011Publication date: September 26, 2013Applicant: Evonik Degussa GmbHInventors: Matthias Seiler, Rolf Schreider, Jörn Rolker, Daniel Dembkowski, Manfred Neumann, Daniel Witthaut, Michael Keup, Volker Brehme, Muhammad Irfan
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Patent number: 8540803Abstract: A method and apparatus for drying a natural gas or an industrial gas that contains acidic gas components, wherein gas drying is followed by the removal of the acidic gas components from the dried gas. The same physical solvent is used for both of the process steps of gas drying and of acidic gas removal. The gas to be dried is brought into contact with the physical solvent, which absorbs most of the water contained in the gas. The physical solvent, loaded with water, is transferred into a solvent regenerating device to be heated where the water contained in the solvent is stripped from the solvent in the countercurrent by acidic gas that is removed from the dried useful gas during the acidic gas absorption. The acidic gas being released again in the acidic gas solvent regenerating device, stripped from the solvent, and discharged from the solvent regenerating device.Type: GrantFiled: September 22, 2010Date of Patent: September 24, 2013Assignee: ThyssenKrupp Uhde GmbHInventor: Johannes Menzel
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Patent number: 8535419Abstract: A modular amine plant having a front-end module and a back-end module in fluid communication with each other. The front-end module having pre-fabricated connections for the association of various equipment including: a filter, an absorption tower, and a flash tank. The back-end module having pre-fabricated connections for the association of other various equipment including: a heat exchanger, a distillation tower, and a reboiler. The modular amine plant capable of being installed at a site in less than about 5 days. The modular amine plant further having moment forces sufficient to withstand wind speeds of about 100 miles per hour.Type: GrantFiled: April 1, 2010Date of Patent: September 17, 2013Assignee: Zephyr Gas Services LLCInventors: Glen Wind, John Kenton Thompson, Lance Perryman
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Patent number: 8535428Abstract: To include an absorber (1006) that brings CO2 absorbent that absorbs CO2 contained in flue gas (1002) into contact with the flue gas to remove CO2 from the flue gas, a regenerator (1008) that strips CO2 from CO2 absorbent (rich solution), which is fed from the absorber through a first feed line L1 and has absorbed CO2, to regenerate CO2 absorbent, thereby acquiring regenerated CO2 absorbent (lean solution) (1009), falling film reboilers (1101-1 and 1101-2) that draw off CO2 absorbent (amine solution) (1033) from near the bottom of the regenerator and reheats regenerated CO2 absorbent via steam (1031), a first liquid-vapor separator (1103) that separates the CO2 absorbent reheated by the falling film reboilers into regenerated CO2 absorbent in which CO2 has been removed and vapor containing CO2, and a second feed line L2 for supplying the separated regenerated CO2 absorbent to the absorber.Type: GrantFiled: January 26, 2009Date of Patent: September 17, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsufumi Inoue, Takashi Kamijo, Tsuyoshi Oishi, Takahito Yonekawa, Hiroshi Tanaka
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Patent number: 8500864Abstract: A method for treating crude gas, in particular biogas, containing methane and carbon dioxide, in order to produce methane, and a plant suitable for carrying out the method. The method includes (a) washing the crude gas with an amine-containing washing solution, thereby forming a pure gas stream of methane and water, from which water is separated by subsequent cooling and condensation; (b) compressing and heating the washing solution containing CO2 and sulfur compounds and expanding the washing solution in a first expansion stage, during a secondary reaction time of 280 to 1200 seconds and at a constant reaction temperature; (c) cooling the purified washing solution and expanding it in a second expansion stage to normal pressure, whereupon any residual amounts of soluble CO2 and sulfur compounds are separated and the completely purified washing solution is cooled to normal temperature and returned to the washing stage.Type: GrantFiled: January 25, 2008Date of Patent: August 6, 2013Assignee: MT-Biomethan GmbHInventor: Lothar Günther
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Patent number: 8475566Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas stream. The method is a two-step method in which carbon dioxide is compressed in the first step, while the residual carbon dioxide is recovered by an absorption process in a subsequent step. The present invention also relates to the use of the method for the recovery of carbon dioxide and a plant for recovery of carbon dioxide.Type: GrantFiled: June 6, 2005Date of Patent: July 2, 2013Assignee: Union Engineering A/SInventor: Rasmus Find
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Patent number: 8460431Abstract: A method for regenerating an amine-containing scrubbing solution which is obtained during gas purification and in which CO2 and sulfur compounds are chemically bonded, as well as a system that is suitable for carrying out the method. The contaminated scrubbing solution is heated, compressed, and expanded in several stages such that CO2 and sulfur compounds are separated. The expanded scrubbing solution is subdivided into two partial streams, and one partial stream is recirculated into the process.Type: GrantFiled: August 12, 2008Date of Patent: June 11, 2013Assignee: MT-Biomethan GmbHInventor: Lothar Günther
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Patent number: 8445737Abstract: A method for reducing one or more additives in a gaseous hydrocarbon stream (40) such as natural gas, comprising the steps of: (a) admixing an initial hydrocarbon feed stream (10) with one or more additives (20) to provide a multiphase hydrocarbon stream (30); (b) passing the multiphase hydrocarbon stream (30) from a first location (A) to a second location (B2); (c) at the second location (B2), passing the multiphase hydrocarbon stream (30) through a separator (22) to provide one or more liquid streams (50) comprising the majority of the one or more additives, and a gaseous hydrocarbon stream (40) comprising the remainder of the one or more additives; and (d) washing the gaseous hydrocarbon stream (40) in a decontamination unit (24) with a washing stream (60), wherein the washing stream (60) comprises distilled water, to provide an additive-enriched stream (70) and an additive-reduced hydrocarbon stream (80).Type: GrantFiled: February 15, 2008Date of Patent: May 21, 2013Assignee: Shell Oil CompanyInventors: Paul Clinton, Marcus Johannes Antonius Van Dongen, Nishant Gupta
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Patent number: 8435325Abstract: Disclosed are methods for recovering CO2 and H2S from a feed gas including at least CO2 and H2S.Type: GrantFiled: October 19, 2009Date of Patent: May 7, 2013Assignee: Hitachi, Ltd.Inventor: Tomoko Akiyama
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Patent number: 8425655Abstract: The present invention provides a gas pressurized separation system to strip a product gas from a liquid stream and yield a high pressure gaseous effluent containing the product gas. The system comprises a gas pressurized stripping apparatus, such as a column, with at least one first inlet allowing flow of one or more liquid streams in a first direction and at least one second inlet allowing flow of one or more high pressure gas streams in a second direction, to strip the product gas into the high pressure gas stream and yield through at least one outlet a high pressure gaseous effluent containing the product gas; and two or more heat supplying apparatuses provided at different locations along the column. Processes for separating a product gas from a gaseous mixture to yield a high pressure gaseous effluent containing the product gas, utilize the gas pressurized separation system described above.Type: GrantFiled: July 9, 2010Date of Patent: April 23, 2013Assignee: Carbon Capture Scientific, LLCInventors: Shiaoguo Chen, Zijiang Pan
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Patent number: 8419843Abstract: In one embodiment, a system includes a hydrogen sulfide (H2S) absorber, a first flash tank, a flash gas treatment column, and a CO2 absorber. The system also includes a first fluid path extending sequentially through the H2S absorber, the first flash tank, the flash gas treatment column, the H2S absorber, and the CO2 absorber.Type: GrantFiled: May 18, 2010Date of Patent: April 16, 2013Assignee: General Electric CompanyInventors: Arnaldo Frydman, Pradeep Stanley Thacker, Sachin Suhas Naphad
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Patent number: 8388747Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: August 22, 2008Date of Patent: March 5, 2013Inventor: Donald Leo Stinson
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Patent number: 8333828Abstract: Various embodiments of the present invention are directed to degassing and cleaning of hydrocarbon fuel. Degassing of hydrocarbon fuel is a way to remove the dissolved gases which aid in the oxidation of the fuel as well as the removal of sulfur, water and other particulate matter through radial cavitation. This process allows for both improvements in efficiency as well as decrease in emissions of standard fuel and the re-refining of fuels which have broken down. University of Idaho did a study on the breakdown of diesel fuel and found out that 26% of the efficiency is lost by the 28th day after fuel processing. In one embodiment, the fuel is subjected to fluid-shear forces and cavitation.Type: GrantFiled: November 19, 2009Date of Patent: December 18, 2012Assignee: Donnelly Labs LLCInventor: Joseph L. Donnelly
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Patent number: 8318114Abstract: This invention provides novel compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.Type: GrantFiled: April 16, 2010Date of Patent: November 27, 2012Inventors: Alan M. Blair, Keith N. Garside, William J. Andrews, Kailas B. Sawant
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Patent number: 8303684Abstract: A pressurized gaseous mixture acidic gas and a useful gas is directly in a first absorption column with a physically acting absorption agent. Then the absorption agent loaded with the acid gas and useful gas is subdivided into first and second streams. The first stream is fed directly to a recycle flash container and there decompressed to reclaim the useful gas, extract the acidic gas from the absorption agent, and form a recycled gas containing the useful gas and acidic gas. The second stream is through a second absorption column to the recycle flash container. Some of the recycled gas from the recycle flash container is compressed and fed through the second absorption column so as to therein directly contact the second stream, and then the recycle gas that has passed through the second absorption column and contacted the second stream is returned to the gaseous mixture.Type: GrantFiled: April 21, 2010Date of Patent: November 6, 2012Assignee: UHDE GmbHInventor: Johannes Menzel
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Publication number: 20120260801Abstract: A CO2 recovery system 10A has a CO2 recovery unit 11, a compression unit 12, and a condensed-water supply line 65A that supplies condensed water 64 to an absorbent regenerator 14. The CO2 recovery unit 11 includes a CO2 absorber 13 and the absorbent regenerator 14. The compression unit 12 has a first compressor 61-1 to an nth compressor 61-n that compress CO2 gas 56 emitted from the absorbent regenerator 14, a first separator 63-1 to an nth separator 63-n that reduce moisture in the CO2 gas 56, and a first heat exchanger 66-1 that performs heat exchange between the CO2 gas 56 emitted from the first compressor 61-1 and the condensed water 64 emitted from the first separator 63-1.Type: ApplicationFiled: March 12, 2012Publication date: October 18, 2012Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventor: Masaki Iijima
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Patent number: 8287626Abstract: A method for treating a gas mixture containing acid gases, including: contacting the gas mixture with an absorbing solution, to obtain a de-acidified gas mixture and an absorbing solution with acid gases. To regenerate the absorbing solution with acid gases, the absorbing solution is passed into a first regenerator at a first pressure, then the solution is passed into a second regenerator at a second pressure, and finally to a third regenerator at a third pressure, the third pressure being less than the second pressure which is less than the first pressure. The gases from the second and third regenerator are compressed and recycled to the first and second regenerator, respectively. Gases from the second and/or the third regenerator are drawn off to provide a gas mixture rich in hydrogen sulfide. Gases from the first regenerator are drawn off to provide a gas mixture rich in carbon dioxide.Type: GrantFiled: January 18, 2008Date of Patent: October 16, 2012Assignee: Total S.A.Inventors: Viep Hoang-Dinh, Damien Roquet, Kenza Habchi-Tounsi, Olivier Chazelas, Claire Weiss
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Patent number: 8257476Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.Type: GrantFiled: September 17, 2010Date of Patent: September 4, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Patent number: 8080089Abstract: A method of treating gas, such as flue gas, is provided. Flue gas is received into a vessel. The flue gas in the vessel is cooled by at least 17 degrees F. to a temperature of 120 F or lower. Also in the vessel, SOx compounds are removed such that the concentration of SOx remaining in the flue gas is between 0 ppmv and 10 ppmv. After the flue gas is cooler and SOx compounds are removed in the vessel, the flue gas is transmitted to a flue gas carbon dioxide scrubbing unit.Type: GrantFiled: April 14, 2009Date of Patent: December 20, 2011Assignee: Bechtel Power CorporationInventors: Harvey W. Wen, Charles L. Kimtantas
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Patent number: 8007569Abstract: The invention relates to a method for removing hydrogen sulphide and other acidic gas components from pressurized technical gases by means of a physical detergent and for obtaining sulphur from hydrogen sulphide by using a Claus system. The hydrogen sulphide and the other acidic gas components are removed in an absorbent manner from the physical detergent, the physical detergent undergoes multi-step regeneration, said multi-step regeneration comprising at least one device for CO enrichment, a device for H2S enrichment, a device for CO2 stripping and a device for thermal regeneration. The various regeneration steps consist of various pressure steps and have a lower pressure than that of the absorption. A hydrogen sulphide rich Claus gas is withdrawn from one of the regeneration steps and is guided to a Claus system where sulphur is produced. The residual gas exiting from the Claus system is hydrated and is condensed under pressure, corresponding to one of the regeneration steps.Type: GrantFiled: July 12, 2004Date of Patent: August 30, 2011Assignee: Uhde GmbHInventors: Georg Saecker, Johannes Menzel
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Patent number: 7909914Abstract: The present invention relates to a method of removing acid gases, notably carbonyl sulfide, contained in gaseous effluents, comprising: an acid gas absorption stage by contacting the gaseous effluent with an aqueous solution comprising 2-[2-amino-1-(aminomethyl)ethoxy]ethanol, and possibly another alkanolamine and an organic compound, and at least one aqueous solution regeneration stage. The method can comprise a second aqueous solution regeneration stage. The regeneration stages are carried out by expansion and/or thermal regeneration.Type: GrantFiled: July 11, 2008Date of Patent: March 22, 2011Assignee: IFPInventors: Renaud Cadours, Julia Magne-Drisch, Bruno Delfort
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Patent number: 7850763Abstract: Impure carbon dioxide (“CO2”) comprising a first contaminant selected from the group consisting of oxygen (“O2”) and carbon monoxide (“CO”) is purified by separating expanded impure carbon dioxide liquid in a mass transfer separation column system. The impure carbon dioxide may be derived from, for example, flue gas from an oxyfuel combustion process or waste gas from a hydrogen (“H2”) PSA system.Type: GrantFiled: January 23, 2007Date of Patent: December 14, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Publication number: 20100282074Abstract: A method for regenerating an amine-containing scrubbing solution which is obtained during gas purification and in which CO2 and sulfur compounds are chemically bonded, as well as a system that is suitable for carrying out the method. The contaminated scrubbing solution is heated, compressed, and expanded in several stages such that CO2 and sulfur compounds are separated. The expanded scrubbing solution is subdivided into two partial streams, and one partial stream is recirculated into the process.Type: ApplicationFiled: August 12, 2008Publication date: November 11, 2010Applicant: DGE DR.-ING. GÜNTHER ENGINEERING GMBHInventor: Lothar Günther
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Patent number: 7819951Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.Type: GrantFiled: January 23, 2007Date of Patent: October 26, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Publication number: 20100154637Abstract: The invention relates to a process for the purification of a gaseous mixture containing mercaptans and other acid gases comprising a stage of bringing said gaseous mixture into contact with an absorbent solution comprising an alkanolamine, a C2-C4 thioalkanol and water.Type: ApplicationFiled: January 16, 2007Publication date: June 24, 2010Inventor: SERGE CAPDEVILLE