Liquid Recycled Or Reused Patents (Class 95/177)
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Patent number: 11859873Abstract: A fluid cooling apparatus capable of improving liquefaction efficiency of a fluid by appropriately cooling the fluid in various temperature ranges through a simple process.Type: GrantFiled: January 31, 2017Date of Patent: January 2, 2024Assignee: SAMSUNG HEAVY IND. CO., LTDInventors: Donghun Lee, Mungyu Kim, Joonho Min, Hyunki Park, Chihun Lee
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Patent number: 11268063Abstract: Multiple risers are provided to perform different steps in a biogas water wash process. The risers may include absorption risers, flashing risers, and stripping risers. In each riser, the inlets to provide fluids to the riser and outlets to remove fluids from the risers are provided at one end of the riser. Each riser may then be located substantially below grade such that the end with the inlets and outlets is accessible at or just above the ground level. The risers within each step of the water wash process may be connected in series, parallel, or a combination thereof. The risers may also be constructed of a polyethylene material to reduce cost and weight of the water wash system.Type: GrantFiled: December 23, 2019Date of Patent: March 8, 2022Assignee: Energy Tech Innovations, LLCInventor: Bryan R. Johnson
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Patent number: 9908079Abstract: A method for separating natural gas liquids (NGLs) from a hydrocarbon gas mixture containing natural gas liquids and methane, comprising the steps of: i) providing a bed of adsorbent selective for NGLs over methane; ii) passing a hydrocarbon gas mixture containing methane and NGL through the bed of adsorbent to at least partially remove NGLs from the gas mixture to produce: (a) NGL-loaded adsorbent and (b) NGL-depleted hydrocarbon gas mixture; iii) recovering the NGL-depleted hydrocarbon gas mixture; iv) regenerating the NGL-loaded adsorbent by at least partially removing NGLs from the adsorbent; and v) sequentially repeating steps (ii) and (iii) using regenerated adsorbent from step (iv).Type: GrantFiled: January 6, 2016Date of Patent: March 6, 2018Assignee: Dow Global Technologies LLCInventors: Matthew L. Rodgers, Brandon J. Kern, Scott T. Matteucci, H. Robert Goltz, Daryl J. Gisch
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Publication number: 20150075375Abstract: A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.Type: ApplicationFiled: September 16, 2014Publication date: March 19, 2015Inventor: Gerald C. Blount
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Publication number: 20140360369Abstract: An absorption medium comprising water and at least one amine of formula (I) where R2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R2 is an alkyl radical having 1 to 4 carbon atoms, R3 and R5 are each independently alkyl radicals having 1 to 6 carbon atoms and R4 and R6 are each independently hydrogen or alkyl radicals having 1 to 6 carbon atoms where R3 and R4 may combine to form the bridging radical —(CH2)n—, —CH2CH2OCH2CH2— or —CH2CH2NR7CH2CH2— with n=2 to 5 and R2=hydrogen or an alkyl radical having 1 to 6 carbon atoms, brings about an improved CO2 absorption capacity in the absorption of CO2 from a gas mixture by contacting the gas mixture with the absorption medium.Type: ApplicationFiled: November 30, 2012Publication date: December 11, 2014Applicant: Evonik Degussa GmbHInventors: Alexander Schraven, Stefanie Rinker, Benjamin Willy, Jöm Rolker, Rolf Schneider, Daniel Dembkowski, Manfred Neumann, Jochen Niemeyer
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Publication number: 20140336428Abstract: A method of removing CO2 from a gaseous mixture using ionic liquids is described. The ionic liquids can be regenerated by pressure reductions. A method of processing a renewable feedstock using the ionic liquids to remove CO2 is also described.Type: ApplicationFiled: May 10, 2013Publication date: November 13, 2014Applicant: UOP LLCInventors: Soumendra M. Banerjee, Alakananda Bhattacharyya, Erin M. Broderick
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Publication number: 20140329299Abstract: A method for removing carbon dioxide from methane-containing crude gases, especially biogas, by pressure scrubbing, using a physical solvent, includes circulating the contaminated scrubbing solution after regeneration. A plant suitable for carrying out the method considerably reduces the methane loss which arises through methane slippage and improves the overall energy balance of the method. Laden scrubbing solution obtained from the pressure scrubbing is treated at least in one flash stage before the first stripping stage. In addition, a nitrogen, oxygen, carbon dioxide and methane-containing gas mixture drawn off from the flash stage is cleaned in a scrubbing stage by purified scrubbing solution drawn off from the second stripping stage and supplied in countercurrent, forming a high-purity methane gas.Type: ApplicationFiled: December 16, 2011Publication date: November 6, 2014Inventor: Lothar Guenther
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Patent number: 8871008Abstract: Capturing a target gas includes contacting a gas mixture including a target species with an aqueous solution including a buffer species, and transferring some of the target species from the gas mixture to the aqueous solution. The target species forms a dissolved target species in the aqueous solution, and the aqueous solution is processed to yield a first aqueous stream and a second aqueous stream, where the equilibrium partial pressure of the target species over the second aqueous stream exceeds the equilibrium partial pressure of the target species over the first aqueous stream. At least some of the dissolved target species in the second aqueous stream is converted to the target species, and the target species is liberated from the second aqueous stream. The target species can be collected and/or compressed for subsequent processing or use.Type: GrantFiled: September 7, 2012Date of Patent: October 28, 2014Assignee: Carbon Engineering Limited PartnershipInventors: Matthew Alex Henderson, David William Keith, Arvinder Pal Singh Kainth, Kenton Robert Heidel, Jane Anne Ritchie
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Patent number: 8779223Abstract: A method for reducing one or more additives in a gaseous hydrocarbon stream (40) such as natural gas, comprising the steps of: (a) admixing an initial hydrocarbon feed stream (10) with one or more additives (20) to provide a multiphase hydrocarbon stream (30); (b) passing the multiphase hydrocarbon stream (30) from a first location (A) to a second location (B2); (c) at the second location (B2), passing the multiphase hydrocarbon stream (30) through a separator (22) to provide one or more liquid streams (50) comprising the majority of the one or more additives, and a gaseous hydrocarbon stream (40) comprising the remainder of the one or more additives; and (d) washing the gaseous hydrocarbon stream (40) in a decontamination unit (24) with a washing stream (60), wherein the washing stream (60) comprises distilled water, to provide an additive-enriched stream (70) and an additive-reduced hydrocarbon stream (80).Type: GrantFiled: April 22, 2013Date of Patent: July 15, 2014Assignee: Shell Oil CompanyInventors: Paul Clinton, Marcus Johannes Antonius Van Dongen, Nishant Gupta
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Patent number: 8696798Abstract: Acid gas is removed from a feed gas using a physical solvent that is regenerated using successive flashing stages after heating of the rich solvent using low-level waste heat that is preferably produced or available within the acid gas removal plant. Especially preferred waste heat sources include compressor discharges of the refrigeration system and/or recompression system for CO2, and/or (low level) heat content from the feed gas.Type: GrantFiled: September 30, 2009Date of Patent: April 15, 2014Assignee: Fluor Technologies CorporationInventor: John Mak
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Publication number: 20140090558Abstract: An absorption medium which comprises water, an amine (A) of formula (I) in which R is an n-alkyl radical having 1 to 4 carbon atoms, and an alkanolamine (B) which is a tertiary amine or a sterically hindered primary or secondary amine has a high absorption capacity for CO2 with a high absorption rate. In the absorption of acid gases from a gas mixture a separation of the absorption medium into two liquid phases or the precipitation of a solid upon absorption of CO2 and regeneration of the absorption medium can be avoided with the absorption medium, even without addition of a solvent.Type: ApplicationFiled: May 25, 2012Publication date: April 3, 2014Applicant: Evonik Degussa GmbHInventors: Jörn Rolker, Matthias Seiler, Rolf Schneider, Thibaut Lenormant
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Publication number: 20130247758Abstract: CO2 is absorbed from a gas mixture by contacting the gas mixture with an absorption medium which comprises at least water as solvent and at least one amine of formula (I) where R1 is an aliphatic radical, having 2 to 6 carbon atoms and at least one amino group, and R2 is hydrogen, a C1-4 alkyl radical or a radical R1.Type: ApplicationFiled: November 10, 2011Publication date: September 26, 2013Applicant: Evonik Degussa GmbHInventors: Matthias Seiler, Rolf Schreider, Jörn Rolker, Daniel Dembkowski, Manfred Neumann, Daniel Witthaut, Michael Keup, Volker Brehme, Muhammad Irfan
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Patent number: 8518155Abstract: A method and apparatus for removing carbon dioxide from a synthesis gas stream containing hydrogen is disclosed. The method includes absorbing the carbon dioxide using a physical solvent under high pressure and then liberating the carbon dioxide in a series of expansion stages where the pressure on the solvent is reduced. The expansion ratio increases with each expansion stage. The apparatus includes expansion stages having throttling devices and expansion tanks operated at increasing expansion ratios. Carbon dioxide is liberated in this manner so as to minimize the energy required compress for transport via a pipe line for sequestration of the gas. Sequestration of the carbon dioxide is preferred to atmospheric venting to curb the release of greenhouse gases.Type: GrantFiled: March 16, 2007Date of Patent: August 27, 2013Assignee: Air Products and Chemicals, Inc.Inventors: John Eugene Palamara, Kevin Boyle Fogash
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Patent number: 8475566Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas stream. The method is a two-step method in which carbon dioxide is compressed in the first step, while the residual carbon dioxide is recovered by an absorption process in a subsequent step. The present invention also relates to the use of the method for the recovery of carbon dioxide and a plant for recovery of carbon dioxide.Type: GrantFiled: June 6, 2005Date of Patent: July 2, 2013Assignee: Union Engineering A/SInventor: Rasmus Find
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Patent number: 8475571Abstract: In one embodiment, a gas purification system is provided. The system includes a first solvent section having a first carbon dioxide (CO2) absorber, a hydrogen sulfide (H2S) absorber, and a first solvent path that routes a first solvent through the first CO2 absorber and the H2S absorber. The gas purification system also includes a second solvent section having a second carbon dioxide (CO2) absorber and a second solvent path that flows a second solvent through the second CO2 absorber. The gas purification system has a gas path though the first and second solvent sections, wherein the first and second solvent paths are separate from one another, and the first and second solvents are different from one another.Type: GrantFiled: April 23, 2010Date of Patent: July 2, 2013Assignee: General Electric CompanyInventors: Judith Pauline Oppenheim, Anindra Mazumdar
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Patent number: 8445737Abstract: A method for reducing one or more additives in a gaseous hydrocarbon stream (40) such as natural gas, comprising the steps of: (a) admixing an initial hydrocarbon feed stream (10) with one or more additives (20) to provide a multiphase hydrocarbon stream (30); (b) passing the multiphase hydrocarbon stream (30) from a first location (A) to a second location (B2); (c) at the second location (B2), passing the multiphase hydrocarbon stream (30) through a separator (22) to provide one or more liquid streams (50) comprising the majority of the one or more additives, and a gaseous hydrocarbon stream (40) comprising the remainder of the one or more additives; and (d) washing the gaseous hydrocarbon stream (40) in a decontamination unit (24) with a washing stream (60), wherein the washing stream (60) comprises distilled water, to provide an additive-enriched stream (70) and an additive-reduced hydrocarbon stream (80).Type: GrantFiled: February 15, 2008Date of Patent: May 21, 2013Assignee: Shell Oil CompanyInventors: Paul Clinton, Marcus Johannes Antonius Van Dongen, Nishant Gupta
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Patent number: 8361424Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions in BS1: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution. According to the invention, an absorbent solution portion circulating in C1 is cooled in E2 in order to prevent demixing of the solution in column C1.Type: GrantFiled: September 23, 2009Date of Patent: January 29, 2013Assignee: IFPInventors: Pierre-Antoine Bouillon, Marc Jacquin, Ludovic Raynal
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Patent number: 8361201Abstract: The hydrogen sulphide content of natural gas obtained from the extraction of sour-gas containing crude oil/ natural gas mixtures, is reduced by reducing the high pressure of a raw crude oil/ natural gas mixture to 70-130 bar, separating an outgassing raw gas from the crude oil, cooling the outgassed raw gas and simultaneously drawing off a liquid medium which condenses from the outgassing raw gas during cooling. The outgassed raw gas is subjected, after pressure reduction, to gas scrubbing by a physically active solvent. The laden solvent is directed to at least one pressure reduction step to obtain H2S outgas from the solvent. The pressure of the crude oil is further reduced in two subsequent steps to 20-40 bar and 2-15 bar and additional H2S rich raw gas streams are separated from the crude oil which outgas therefrom.Type: GrantFiled: May 24, 2006Date of Patent: January 29, 2013Assignee: UHDE GmbHInventors: Johannes Menzel, Georg Saecker
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Publication number: 20120297978Abstract: A method for removing impurities from a feed air gas stream prior to the stream being fed to a cryogenic distillation unit. The feed air gas stream contacts an ionic liquid which adsorbs the impurities from the air. The method can use one or more beds such as in pressure swing adsorption processes.Type: ApplicationFiled: December 2, 2010Publication date: November 29, 2012Inventors: Suling Zhai, Yaping Lu
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Patent number: 8318114Abstract: This invention provides novel compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.Type: GrantFiled: April 16, 2010Date of Patent: November 27, 2012Inventors: Alan M. Blair, Keith N. Garside, William J. Andrews, Kailas B. Sawant
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Patent number: 8303684Abstract: A pressurized gaseous mixture acidic gas and a useful gas is directly in a first absorption column with a physically acting absorption agent. Then the absorption agent loaded with the acid gas and useful gas is subdivided into first and second streams. The first stream is fed directly to a recycle flash container and there decompressed to reclaim the useful gas, extract the acidic gas from the absorption agent, and form a recycled gas containing the useful gas and acidic gas. The second stream is through a second absorption column to the recycle flash container. Some of the recycled gas from the recycle flash container is compressed and fed through the second absorption column so as to therein directly contact the second stream, and then the recycle gas that has passed through the second absorption column and contacted the second stream is returned to the gaseous mixture.Type: GrantFiled: April 21, 2010Date of Patent: November 6, 2012Assignee: UHDE GmbHInventor: Johannes Menzel
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Publication number: 20120260801Abstract: A CO2 recovery system 10A has a CO2 recovery unit 11, a compression unit 12, and a condensed-water supply line 65A that supplies condensed water 64 to an absorbent regenerator 14. The CO2 recovery unit 11 includes a CO2 absorber 13 and the absorbent regenerator 14. The compression unit 12 has a first compressor 61-1 to an nth compressor 61-n that compress CO2 gas 56 emitted from the absorbent regenerator 14, a first separator 63-1 to an nth separator 63-n that reduce moisture in the CO2 gas 56, and a first heat exchanger 66-1 that performs heat exchange between the CO2 gas 56 emitted from the first compressor 61-1 and the condensed water 64 emitted from the first separator 63-1.Type: ApplicationFiled: March 12, 2012Publication date: October 18, 2012Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventor: Masaki Iijima
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Patent number: 8282899Abstract: Solvent absorption processes for separating components of an impure feed gas are disclosed. The processes involve two stages of gas-liquid contacting, namely a first, absorption stage and a second, stripping stage. In the case of a carbon dioxide (CO2)-containing methane gas as an impure feed gas, contacting, in the stripping stage, the solvent effluent from the absorption stage with a recycled vapor fraction of the solvent effluent from the stripping stage can improve the recovery and purity of not only the methane (and/or other light hydrocarbons in the impure feed gas), but also that of the CO2 contaminant gas.Type: GrantFiled: August 31, 2011Date of Patent: October 9, 2012Assignee: UOP LLCInventors: David A. Bahr, Lamar A. Davis
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Patent number: 8257476Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.Type: GrantFiled: September 17, 2010Date of Patent: September 4, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Patent number: 8252091Abstract: In a system involving CO2 capture having an acid gas removal system to selectively remove CO2 from shifted syngas, the acid gas removal system including at least one stage, e.g. a flash tank, for CO2 removal from an input stream of dissolved carbon dioxide in physical solvent, the method of recovering CO2 in the acid gas removal system including: elevating a pressure of the stream of dissolved carbon dioxide in physical solvent; and elevating the temperature of the pressurized stream upstream of at least one CO2 removal stage.Type: GrantFiled: March 18, 2008Date of Patent: August 28, 2012Assignee: General Electric CompanyInventors: Ashok Kumar Anand, Chetan Madhav Joshi, Jegadeesan Maruthamuthu
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Patent number: 8147787Abstract: Refinery off gases are treated in a plant in two processing steps, wherein the off gases are first scrubbed in a wash column using lean oils for removal of heavy mercaptans and C5+ hydrocarbons, and wherein a hydrotreater is then used for saturating olefinic hydrocarbons and reducing sulfurous compounds. Most preferably, lean recycle oil is used for temperature control of the hydrotreater reactor(s) in configurations where the lean oil from a hydrotreater reactor outlet separator is mixed with the reactor feed to so cool the hydrotreater reactor via evaporation.Type: GrantFiled: February 14, 2008Date of Patent: April 3, 2012Assignee: Fluor Technologies CorporationInventors: John Mak, Robert Henderson
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Publication number: 20110165663Abstract: A device and a method for producing a fine liquid mist and injecting the said mist into a gas stream to capture and remove very fine particulate pollutants. The pressurized gas stream is passed into a droplet generator (20) into which the liquid is sprayed and atomised into a mist which captures particulates and then into a droplet separator (30) to produce a separated liquid/particulate mixture and a gas stream with a reduced concentration of particulates. The main application is the removal of fine particulates from vehicle exhaust streams. Optionally a degassing stage (90) is provided for the removal of residual gases and vapours. The preferred liquid to form the mist is water.Type: ApplicationFiled: July 11, 2005Publication date: July 7, 2011Inventor: Howard P. Davis
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Patent number: 7967896Abstract: The invention provides a process and system for regenerating a solvent used to remove carbon dioxide from feed gases, such as natural gas and synthesis gas. The invention employs one or more hydraulic turbochargers to transfer energy from a higher energy solvent stream to a lower energy solvent stream. This provides for a significant reduction in operating expenses.Type: GrantFiled: March 26, 2008Date of Patent: June 28, 2011Assignee: UOP LLCInventors: William J. Lechnick, Nagaraju Palla, Paul A. Sechrist, Lamar A. Davis, Michael R. Van de Cotte
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Patent number: 7935178Abstract: The invention provides a process and system for regenerating a solvent used to remove carbon dioxide from feed gases, such as natural gas and synthesis gas. The process and system employ a biphasic turbine to recover energy following pressure let down.Type: GrantFiled: March 26, 2008Date of Patent: May 3, 2011Assignee: UOP LLCInventors: William J. Lechnick, Paul A. Sechrist, Douglas E. Kuper, Lamar A. Davis
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Patent number: 7819951Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.Type: GrantFiled: January 23, 2007Date of Patent: October 26, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Patent number: 7811361Abstract: One exemplary embodiment can be a process for increasing an efficiency of an acid gas removal zone. The process can include sending a sour gas stream including at least one gas to a first absorber providing an overhead stream absorbing the at least one gas; withdrawing a side-stream from the first absorber and passing the side-stream through a holding tank, a side-stream fluid transfer device, and a side-stream chiller before returning the side-stream to the absorber; and passing the first absorber overhead stream to a pump-around circuit for a second absorber. Usually, the pump-around circuit may include a flash drum, a pump-around fluid transfer device and a pump-around chiller before providing a slipstream to the first absorber and another portion to the second absorber.Type: GrantFiled: June 30, 2009Date of Patent: October 12, 2010Assignee: UOP LLCInventors: William J. Lechnick, Lamar A. Davis, David Alden Bahr, Carla F. Roberts
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Patent number: 7749309Abstract: Disclosed is a method for deacidifying a fluid stream containing acidic gases as contaminants, according to which the fluid stream is brought into intimate contact with a washing liquid in at least one absorption step. Said washing liquid represents an aqueous solution containing a) tertiary aliphatic alkanolamines (alkanolamine A), at least 30 percent by weight of said tertiary aliphatic alkanolamines being 3-dimethylamino-1-propanol, and b) secondary aliphatic amines (activator B), at least 20 percent by weight of said secondary aliphatic amines being piperazin. The fluid stream which has been essentially purified of the acidic gases is then separated from the washing liquid that is loaded with acidic gases.Type: GrantFiled: March 4, 2003Date of Patent: July 6, 2010Assignee: BASF AktiengesellschaftInventors: Norbert Asprion, Christoph Grossmann
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Patent number: 7699914Abstract: A method of using a triple-effect absorption system to recover methane from landfill gas contaminated with CO2 and trace contaminates such as chlorinated hydrocarbons and aromatics involves processing the landfill gas with three absorbers and a flash system. One absorber uses a solvent to absorb the trace contaminants from the landfill gas, the second absorber in conjunction with the flash system extracts CO2 from the gas, and just a first portion of that CO2 is used for stripping the trace contaminates from the solvent in the third absorber. The rest of the extracted CO2 is vented to atmosphere to prevent dampening the combustion of the trace contaminants absorbed by the first portion of CO2.Type: GrantFiled: December 9, 2005Date of Patent: April 20, 2010Inventors: Luke N. Morrow, Paul D. Morrow, David C. Morrow
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Patent number: 7674321Abstract: A process for the removal of sour gas from pressurized natural gas which is polluted by sulphur compounds and other sour gas compounds includes initially feeding natural gas into a sour gas absorption unit, in which the sulphur components and any other components are absorbed by a physically acting solution yielding a sour gas rich absorbent. The absorbant is heated and fed into a high-pressure flash unit, in which the desorbed sour-gas is separated yielding a sour gas poor absorbent. The desorbed sour gas is cooled and the vaporized absorbent is condensed out of the sour gas stream. The sour-gas poor absorbent from the high-pressure flash unit is freed from residual sour gas in a gas stripping unit by stripping gas. The absorbent obtained in the sour gas unit is cooled and recycled permitting the desorbed sour gas to be condensed by cooling water or cooling air.Type: GrantFiled: May 28, 2004Date of Patent: March 9, 2010Assignee: Uhde GmbHInventor: Johannes Menzel
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Publication number: 20100011957Abstract: The invention relates to a method for depleting hydrogen sulphide in natural gas from the exploitation of crude oil/natural gas mixtures containing acid gas, during which the pressure of highly pressurized crude oil/natural gas mixture is firstly reduced to a pressure of 70 to 130 bar, preferably 90 bar, the outgassing crude gas is separated from the crude oil and crude gas is cooled, whereby the liquid phase condensing during the cooling of the crude gas is removed, the outgassed crude gas is, after cooling and without further measures of reducing pressure, subjected to a gas scrubbing, which absorbs a large portion of the H2S contained in the crude gas by means of a physically acting solvent whereby cleaning the crude gas. The loaded solvent is led into at least one pressure reducing stage, and the heat dissipated during the cooling of the crude gas is fed to the loaded solvent.Type: ApplicationFiled: May 24, 2006Publication date: January 21, 2010Inventors: Johannes Menzel, Georg Saecker
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Publication number: 20090241778Abstract: The invention provides a process and system for regenerating a solvent used to remove carbon dioxide from feed gases, such as natural gas and synthesis gas. The process and system employs an eductor or ejector as an alternative to the prior art's vacuum compressor that is placed on the vapor stream from a vapor flash. This process and system saves substantial capital and operating costs over the prior art.Type: ApplicationFiled: March 26, 2008Publication date: October 1, 2009Inventors: William J. Lechnick, Lamar A. Davis, Michael R. Van de Cotte, John P. Brady
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Patent number: 7563307Abstract: A process for separating the components of a multi-component gas stream is disclosed. The multi-component gas stream is contacted with a solvent in an extractor to produce an overhead stream enriched with unabsorbed component(s) and a rich solvent bottoms stream enriched with absorbed component(s). The rich solvent bottoms stream is then flashed at reduced pressure to regenerate lean solvent and to recover the absorbed component(s) as an overhead stream. The regenerated solvent is recycled to the extractor. A portion of the circulating solvent comprises external solvent added to the system. A second portion of the circulating solvent comprises internal solvent contained in the feed gas.Type: GrantFiled: August 23, 2005Date of Patent: July 21, 2009Assignee: Advanced Extraction Technologies, Inc.Inventor: Thomas K. Gaskin
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Patent number: 7192468Abstract: A plant includes an absorber (103) that operates in a gas phase supercritical region and removes an acid gas from a feed stream (9) at high recovery of the feed stream (10) while producing a high purity acid gas stream (36). Particularly preferred plants include gas purification plants that receive a feed gas with at least 5 mol % carbon dioxide at a pressure of at least 3000 psi.Type: GrantFiled: April 15, 2002Date of Patent: March 20, 2007Assignee: Fluor Technologies CorporationInventors: John Mak, Curt Graham, Richard Nielsen
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Patent number: 6964696Abstract: An apparatus and method for recovering a clean liquid condensate from a synthesis gas at elevated temperatures and pressures. The apparatus includes at least one heat exchanger for reducing the temperature of the synthesis gas down to below 200° F. (93° C.) so as to form a syngas condensate at elevated pressure. The syngas condensate is flashed so that it separates into a liquid phase condensate and a gas phase. The liquid phase condensate comprises water, dissolved ammonia and particulates. The gas phase contains carbon monoxide, carbon dioxide, various sulfur containing compounds and trace amounts of other compounds that may have been dissolved in the syngas condensate. The gas phase is removed from the flash tank and sent to a sour gas treatment unit and/or flare. The liquid phase condensate is then filtered so as to remove larger sized particulates. Clean liquid condensate is reused in the gasification process.Type: GrantFiled: December 4, 2002Date of Patent: November 15, 2005Assignee: Texaco, Inc.Inventors: William A. Malatak, Brad X. Pan
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Patent number: 6793712Abstract: A pretreatment system for natural gas liquefaction employing heat integration for more efficient and effective natural gas temperature control. The pretreatment system expands the natural gas prior to acid gas removal. After acid gas removal, the natural gas is cooled by indirect heat exchange with the expanded natural gas located upstream of the acid gas removal system.Type: GrantFiled: November 1, 2002Date of Patent: September 21, 2004Assignee: ConocoPhillips CompanyInventor: Wesley R. Qualls
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Patent number: 6740226Abstract: In a hydrocracking unit, the flash gases from the high-pressure separator are fed to the bottom of an absorption zone where the entering gases are counter-currently contacted with a lean solvent. The lean solvent absorbs away the contained methane, ethane, propane, butanes and pentanes (C1+) from the contained hydrogen. The overhead gas stream from the absorption zone typically contains hydrogen at a purity of 90 to 98 mol %, or even higher, which is fed to the recycle gas stream to provide hydrogen purity in the range of 96 to 99 mol %, thereby providing an increase in the overall efficiency of the hydroprocessor unit. The process can also be employed with hydrotreating, hydrodesulfurization, hydrodenitrogenation and hydrodealkylation reactors.Type: GrantFiled: January 16, 2002Date of Patent: May 25, 2004Assignee: Saudi Arabian Oil CompanyInventors: Yuv Raj Mehra, Ali Hassan Al-Abdulal
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Patent number: 6726747Abstract: An improved methane wash cycle is disclosed wherein a reduced amount of methane wash is required, thereby allowing for savings in energy costs in operation of the cycle and capital costs in constructing the cycle. Further embodiments allow for an energy recovery and an enhanced recovery of a carbon monoxide and/or hydrogen product.Type: GrantFiled: December 26, 2001Date of Patent: April 27, 2004Assignee: American Air LiquideInventor: Francois Granier
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Patent number: 6666908Abstract: Within the scope of a process using two absorption sections for treating a natural gas containing CO2 and/or H2S, as well as mercaptans, COS and/or CS2, the present invention aims to wash the gaseous hydrocarbons desorbed upon expansion of the solvent from the first absorption section with the solvent from the second absorption section.Type: GrantFiled: January 29, 2002Date of Patent: December 23, 2003Assignee: Institut Francais du PetroleInventors: Renaud Cadours, Fabrice Lecomte, Pascal Mougin
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Patent number: 6607585Abstract: An improved method and structure for purification of an acid gas stream by using raw fuel gas as a stripper to remove the BTEX and VOCs from the liquid amine stream. The improved method is particularly useful for purification of acid gas streams with BTEX contaminant levels in excess of environmentally acceptable levels for standard processing. Raw fuel gas is utilized at moderate temperatures and pressures, the uptake of BTEX and VOCs reduces the level of these compounds in the waste amine stream to environmentally acceptable levels, and the remaining contaminants may then be dealt with by ordinary means. Levels of H2S and CO2. in the liquid amine stream are also reduced.Type: GrantFiled: December 20, 2000Date of Patent: August 19, 2003Inventor: David Morrow
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Publication number: 20030132138Abstract: In a hydrocracking unit, the flash gases from the high-pressure separator are fed to the bottom of an absorption zone where the entering gases are counter-currently contacted with a lean solvent. The lean solvent absorbs away the contained methane, ethane, propane, butanes and pentanes (C1+) from the contained hydrogen. The overhead gas stream from the absorption zone typically contains hydrogen at a purity of 90 to 98 mol %, or even higher, which is fed to the recycle gas stream to provide hydrogen purity in the range of 96 to 99 mol %, thereby providing an increase in the overall efficiency of the hydroprocessor unit. The process can also be employed with hydrotreating, hydrodesulfurization, hydrodenitrogenation and hydrodealkylation reactors.Type: ApplicationFiled: January 16, 2002Publication date: July 17, 2003Inventors: Yuv Raj Mehra, Ali Hassan Al-Abdulal
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Patent number: 6551380Abstract: A gas separation apparatus and process has a first pressure swing adsorption (PSA) unit (110) receiving feed gas (112), which comprises a first and a second component. First PSA unit (110) produces first product gas (114) pre-dominantly containing the first component, and first off gas (116) containing at least some of the first component and second component. Compressor (120) is coupled to first PSA unit (110) to compress first off gas (116) to form compressed off gas (126), which is passed downstream to absorber unit (130), which employs a solvent to remove at least part of the second component from compressed off gas (126), forming an enriched compressed off gas (136B). Second PSA unit (140) receives enriched compressed off gas (136B) and produces second product gas (142) which predominantly contains the first component and a second off gas that is sent to waste or reformer burner (150).Type: GrantFiled: June 25, 2001Date of Patent: April 22, 2003Assignee: Fluor CorporationInventors: Satish Reddy, Ravi Ravikumar
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Publication number: 20020059865Abstract: Process for treating a gas containing acid gases, wherein:Type: ApplicationFiled: September 24, 2001Publication date: May 23, 2002Inventors: Eric Lemaire, Jean-Charles Viltard
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Patent number: 6352414Abstract: The invention pertains to the field of jet technology and relates to an operating process of a multiple-stage pump-ejector-separator system which essentially includes bypassing a motive liquid from a second-stage separator into a first-stage one and subsequent delivery of the motive liquid from the first-stage separator to the suction port of a pump. The invention also relates to a device for realizing the process which essentially constitutes a multiple-stage pump-ejector-separator system, wherein the suction side of a pump is connected to a first-stage separator, the first-stage and second-stage separators are interconnected by a vertical U-tube acting as a hydro seal, where the height of the U-tube above the motive liquid level in the second-stage separator is not less than the height of the liquid column created in the U-tube by the motive liquid from the second-stage separator under a pressure difference between the two separators.Type: GrantFiled: March 3, 2000Date of Patent: March 5, 2002Inventor: Serguei A. Popov
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Publication number: 20010006021Abstract: It is an object of the present invention to provide a water-based paint recycling method with which there is no need to set up the water-based paint application booth close to the condensing separator, which affords greater freedom in installation. The present invention is a water-based paint recycling method in which, in a water-based paint application booth in the bottom of which booth water is pooled, the paint mist produced when a water-based paint is applied is trapped by this booth water, the booth water containing this trapped paint mist is treated by the condensing separator, and the resulting concentrate and filtrate are reused, wherein this water-based paint recycling method is characterized in that the water-based paint application booth and the condensing separator are independent, not being connected by piping.Type: ApplicationFiled: December 21, 2000Publication date: July 5, 2001Inventors: Masahiro Yamauchi, Kageki Fujimoto
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Patent number: 6248154Abstract: The invention relates to the field of jet technology. A gas-liquid mixture is fed from a jet apparatus into a jet converter where the flow of the gas-liquid mixture first undergoes expansion and thus is transformed into a supersonic gas-liquid flow. This supersonic gas-liquid flow is then decelerated in a shaped flow-through channel section t of the converter. A pressure jump is generated there and partial transformation of kinetic energy of the flow into potential energy of pressure takes place. In order to implement this operational process, the system is furnished with a jet converter, which includes an expansion chamber and a shaped flow-through section, the inlet of the expansion chamber is connected to the jet apparatus outlet, and the outlet of the shaped flow-through section is connected to a separator.Type: GrantFiled: June 28, 1999Date of Patent: June 19, 2001Inventor: Serguei A. Popov