Nitrogen Is Stripping Gas Patents (Class 95/265)
  • Patent number: 10550013
    Abstract: A water filtration system (100) includes: a raw-water inlet (100a); a pure-water outlet (100b); a purified-water outlet (100c); a waste-water outlet (100d); an integrated filter cartridge (1); and a return flow path (101). The integrated filter cartridge (1) has a first port (10a), a second port (10b), a third port (10c) and a fourth port (10d). The purified-water outlet (100c) and the waste-water outlet (100d) both are connected to the third port (10c), and a water storage device (2) is provided to at least one of the fourth port (10d) and a flow path connected to the pure-water outlet (100b). The return flow path (101) has a first end connected between the first port (10a) and the raw-water inlet (100a) and a second end connected between the waste-water outlet (100d) and the third port (10c).
    Type: Grant
    Filed: January 4, 2018
    Date of Patent: February 4, 2020
    Assignees: FOSHAN SHUNDE MIDEA WATER DISPENSER MFG. CO., LTD., MIDEA GROUP CO., LTD.
    Inventor: Lyu Yang
  • Publication number: 20150122126
    Abstract: A system for deaeration of a liquid comprises a heater for heating the liquid to a well-defined temperature, means for pressurizing the liquid, a first piping for guiding the heated liquid to a separation vessel, a vacuum pump for evacuating deaerated gases from the separation vessel, and a second piping for guiding the deaerated liquid from the separation vessel. The system further comprises an inert-gas supply and a mixer for supplying and mixing in inert gas into the liquid in the first piping. The vacuum pump is controllable to maintain a separation pressure in the separation vessel corresponding to a pressure at or slightly above the saturation pressure.
    Type: Application
    Filed: December 14, 2012
    Publication date: May 7, 2015
    Applicant: Tetra Laval Holdings & Finance S.A.
    Inventor: Christer Lanzingh
  • Patent number: 8882885
    Abstract: A system to purge dissolved gases selectively from liquids can include a first contactor having two first contactor inlets and two first contactor outlets. The first contactor can receive liquid from a liquid source at a first inlet of the first contactor and an inert gas source at a second inlet of the first contactor, the inert gas can purge a first portion of gas from the liquid source. The first portion of purged gas exits the first contactor at a first outlet of the first contactor. The second contactor can receive input from the second outlet of the first contactor and the inert gas, the inert gas purges a second portion of the gas from the liquid source. The second portion of purged gas can exit the second contactor at a first outlet of the second contactor.
    Type: Grant
    Filed: March 15, 2012
    Date of Patent: November 11, 2014
    Assignee: MKS Instruments, Inc.
    Inventors: Ulrich Brammer, Johannes Seiwert, Christiane Gottschalk
  • Patent number: 8574328
    Abstract: A process for reducing free oxygen in a gaseous nitrogen stream comprises the steps of (i) reforming a hydrocarbon to generate a gas mixture containing hydrogen and carbon oxides, (ii) mixing the gas mixture with a nitrogen stream containing free oxygen, and (iii) passing the resulting nitrogen gas mixture over a conversion catalyst that converts at least a portion of the free oxygen present in the nitrogen to steam wherein the hydrocarbon reforming step includes oxidation of a hydrocarbon using an oxygen-containing gas.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: November 5, 2013
    Assignee: Johnson Matthey PLC
    Inventors: Peter John Herbert Carnell, Martin Fowles, Raymond Anthony Hadden, Suzanne Rose Ellis
  • Publication number: 20130284019
    Abstract: A method and apparatus are disclosed for treating process water which is loaded with gaseous compounds and/or possibly with solids and comes from a wet-cleaning installation for cleaning process gas, e.g., from a melt-reduction subassembly or from a direct-reduction subassembly. Process water is introduced in a tank in a first process stage and degassed on the basis of reduced solubility of the dissolved compounds. The tank has, on its upper side, a gas-collecting chamber, in which the separated-off gases are collected and from which these are discharged. Likewise, the treated process water is discharged from the tank via a drainage means.
    Type: Application
    Filed: December 6, 2011
    Publication date: October 31, 2013
    Inventors: Alois Gstoettenmayr, Hado Heckmann, Kurt Lukschander, Robert Millner, Ulrike Schmidt, Helmut Siegl, Johann Wurm
  • Patent number: 8449656
    Abstract: A process and apparatus is provided for reduction of dissolved oxygen content in seawater from about 8 ppm in the feed seawater to about 10 ppb or less. Significant advantages are achieved by: use of a separator in horizontal alignment to provide high gas-liquid contacting area for separation and de-entrainment within the separator, thereby providing higher throughput; and heating seawater to at least 30° C. and up to 60° C., so as to enhance removal of oxygen from seawater; use of once-through fuel gas as stripping gas and its subsequent combustion for heating the seawater provides for high efficiency and reduction of fouling. The combination of these features allows the amount of residual oxygen in deoxygenated seawater to be reduced to below 10 ppb and as low as 2 ppb.
    Type: Grant
    Filed: November 16, 2010
    Date of Patent: May 28, 2013
    Assignee: AMT International Inc.
    Inventors: Kuang-Yeu Wu, Adam T. Lee, Lindsey Vuong, Edward K. Liu, Karl T. Chuang
  • Publication number: 20130092368
    Abstract: A method of treatment of water in an aquatic environment. Water is first pumped from a reservoir to a first mixing station. An inert gas is introduced into the pumped water at the first mixing station to provide inert gas saturated water, which inert gas saturated water will displace undesired gasses in the water in the reservoir. The inert gas saturated water is then pumped to a sparging column such that the inert gas and undesired gasses will be released from the inert gas saturated water to provide depleted water.
    Type: Application
    Filed: November 16, 2012
    Publication date: April 18, 2013
    Applicant: REVALESIO CORPORATION
    Inventor: REVALESIO CORPORATION
  • Patent number: 8388740
    Abstract: A process is presented for the removal of dissolved oxygen from hydrocarbon streams. The hydrocarbons streams include kerosene and jet fuels. The process includes mixing the hydrocarbons streams with an oxygen free gas to form a gas-liquid mixture. The mixture is allowed to disengage into a gas stream and a liquid stream, thereby removing dissolved oxygen from the hydrocarbon stream.
    Type: Grant
    Filed: October 27, 2010
    Date of Patent: March 5, 2013
    Assignee: UOP LLC
    Inventors: Stephen W. Sohn, Steven P. Lankton, Debarshi Majumder, Brian J. Schiavone
  • Patent number: 8349191
    Abstract: A method of treatment of water in an aquatic environment. Water is first pumped from a reservoir to a first mixing station. An inert gas is introduced into the pumped water at the first mixing station to provide inert gas saturated water, which inert gas saturated water will displace undesired gasses in the water in the reservoir. The inert gas saturated water is then pumped to a sparging column such that the inert gas and undesired gasses will be released from the inert gas saturated water to provide depleted water.
    Type: Grant
    Filed: February 15, 2011
    Date of Patent: January 8, 2013
    Assignee: Revalesio Corporation
    Inventor: Anthony B. Wood
  • Patent number: 8323382
    Abstract: A black water treatment system for a flow of black water. The black water treatment system may include one or more non-vacuum flash drums and a scrub-cooler. The scrub-cooler may include a water pathway with a nitrogen tube and a flow of nitrogen therein.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: December 4, 2012
    Assignee: General Electric Company
    Inventor: Vijayalakshmi Shah
  • Publication number: 20120103194
    Abstract: A process is presented for the removal of dissolved oxygen from hydrocarbon streams. The hydrocarbons streams include kerosene and jet fuels. The process includes mixing the hydrocarbons streams with an oxygen free gas to form a gas-liquid mixture. The mixture is allowed to disengage into a gas stream and a liquid stream, thereby removing dissolved oxygen from the hydrocarbon stream.
    Type: Application
    Filed: October 27, 2010
    Publication date: May 3, 2012
    Applicant: UOP LLC
    Inventors: Stephen W. Sohn, Steven P. Lankton, Debarshi Majumder, Brian J. Schiavone
  • Patent number: 7625438
    Abstract: A method and device are provided for reducing the oxygen content of seawater, where the seawater is introduced into the upper part (14) of a downcomer (12), particularly for treatment of ballast water in a ballast tank (4) of a ship (1). A seawater intake pipe (6) runs from the outside of the ship to a ballast pump (8) that is designed to pump the water on through a pump pipe (10) and up to the upper part of the downcomer. The downcomer extends mainly vertically down to the ballast compartment of the ship, where the ballast water can be distributed between several ballast compartments by means of distribution headers and valves. One aim of the invention is to neutralize organisms in the ballast water.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: December 1, 2009
    Assignee: Knutsen OAS Shipping AS
    Inventor: Per Lothe
  • Publication number: 20090252836
    Abstract: The prevent invention provides a novel gas treatment method for a fluid, and a method for producing a milk using the same, which is industrially extremely advantageous in terms of cost and efficiency. A gas treatment method for a fluid, comprises, while discharging a fluid from a fluid discharge port 161 of a two-fluid nozzle 160, crushing the discharge flow into fine droplets by a gas stream from a gas injection port 162, and then allowing the droplets to strike against a flow prevention member 190 and thereby agglomerate, so as to perform a gas treatment (gas addition, gas replacement, deaeration, or sterilization (disinfection)). According to the method for producing a milk, nitrogen is used as the gas stream, whereby homogenization and nitrogen replacement of dissolved oxygen can be performed in one and the same process.
    Type: Application
    Filed: April 11, 2007
    Publication date: October 8, 2009
    Applicant: Wingturf Co., Ltd.
    Inventor: Tomohiko Hashiba
  • Patent number: 7503961
    Abstract: A nitrogen sweep stream for use in a deaerator during deaerator operations to disperse and remove oxygen and carbon dioxide from boiler feed water prior to being fed to a boiler. The nitrogen sweep stream substantially reduces the amount of oxygen and carbon dioxide in the water supply system. The water supply system can be sent to a deaerator stripper or can be heated using a heat exchanger. A heat water supply stream can also be sent directly to the deaerator water tank. The nitrogen sweep stream reduces the amount of oxygen contained with the boiler feed water stream to less than 7 ppb and reduces the amount of carbon dioxide to nondetectable levels. The nitrogen sweep may be provided to an existing deaerator, not having been previously provided with a nitrogen sweep, while the deaerator is running without shutting down the deaerator.
    Type: Grant
    Filed: December 6, 2005
    Date of Patent: March 17, 2009
    Assignee: Westlake Chemical Corporation
    Inventors: Ken M. Istre, David C. Payne
  • Patent number: 7488372
    Abstract: The present invention relates to a process for degassing an aqueous solution containing a hydroformylation product and separating a volatile metal species from gaseous stream to inhibit or prevent deposition of a solid material from the gaseous stream. To separate the volatile metal species from the gaseous stream, the gaseous stream is either 1) contacted with a liquid that separates the volatile metal species, or a reaction product thereof, from the gaseous stream; 2) passed through a microfilter having a pore size of 2 ?m or less; or 3) contacted with an adsorbent material.
    Type: Grant
    Filed: February 1, 2006
    Date of Patent: February 10, 2009
    Assignee: Shell Oil Company
    Inventors: Joseph Broun Powell, Robert Earl Hammond
  • Patent number: 7374602
    Abstract: The present invention generally offers a system and a method that allows a vessel to treat water while providing corrosion inhibition. An oxygen stripping gas source produces oxygen stripping gas that may be pumped directly to, preferably but optionally, a venturi injector, or may first be pumped into an empty tank and then delivered to the injector means. Water being pumped through the injector via a transfer piping means comes into contact with the oxygen stripping gas, and dissolved oxygen in the water transfers to micro-fine stripping gas bubbles generated by the injector. The water and the micro-fine bubbles are pumped from the injector and into the tank, where the micro-fine bubbles float to the surface, and the oxygen is released into the tank's headspace. The deoxygenated water may be re-circulated through the system for additional deoxygenation or released from the tank into the surrounding waterways.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: May 20, 2008
    Assignee: NEI Treatment Systems, LLC
    Inventor: Peter McNulty
  • Patent number: 7255728
    Abstract: Apparatus and method for degassing liquids particularly cationic monomers. Fluid comprising liquid to be degassed together with sweep gas is admitted tangentially into a column (10) and forced down the column by a tubular baffle (16) which defines, with the inner wall of the column, an annulus (18) that is closed at its top (20). After passing to the bottom of the annulus the fluid forms an even film over the inner surface of the column and gas disengaging from the liquid can rise up the column while liquid accumulates at the bottom of the column. To assist the disengagement of the gas from the liquid the column is preferably of increasing cross section towards the bottom so that the thickness of the film is also reduced.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: August 14, 2007
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Jonathan Heath Veal, Martin David Powell, Simon Broughton, Gareth Ian Naylor
  • Patent number: 7153343
    Abstract: A fuel system for an energy conversion device includes a deoxygenator system with a porous membrane. The deoxygenator includes an oxygen receiving channel separated from the fuel channel by the porous membrane. The capillary forces counteract the pressure differential across the membrane, preventing any leakage of the fuel, while the oxygen concentration differential across the membrane allows for deoxygenation of the fuel through the porous membrane.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: December 26, 2006
    Assignee: United Technologies Corporation
    Inventors: Sergei F. Burlatsky, Mallika Gummalla, Louis J. Spadaccini, Foster Philip Lamm
  • Patent number: 6981997
    Abstract: Liquid such as water is deaerated by dissolving stripping gas such as carbon dioxide into the water while maintaining pressure, reducing the pressure, and then feeding the liquid into a vessel wherein a gas space is maintained over said water, wherein the pressure of said gas space is less than the pressure upstream, and separately withdrawing degassed liquid and evolved gas from said vessel at rates which maintain the pressure of said gas space below the pressure upstream of said means.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: January 3, 2006
    Assignee: Praxair Technology, Inc.
    Inventors: William Robert Williams, Marcilio Paiva Prado, Luis Claudio Dias Nogueira
  • Patent number: 6974546
    Abstract: A method of treatment of water in an aquatic environment. Water is first pumped from a reservoir to a first mixing station. An inert gas is introduced into the pumped water at the first mixing station to provide inert gas saturated water, which inert gas saturated water will displace undesired gasses in the water in the reservoir. The inert gas saturated water is then pumped to a sparging column such that the inert gas and undesired gasses will be released from the inert gas saturated water to provide depleted water. The depleted water is then pumped to a second mixing station, wherein oxygen is introduced into the depleted water to provide oxygen enriched water. The oxygen enriched water is then returned to reservoir.
    Type: Grant
    Filed: March 9, 2004
    Date of Patent: December 13, 2005
    Assignee: Microdiffusion, Inc.
    Inventor: Anthony B. Wood
  • Patent number: 6918950
    Abstract: Apparatus and methods for reducing residual solvent levels in extracted biomass that is contaminated with HFC solvent that includes sparging the biomass extract with a solvent stripping gas such as air or nitrogen are disclosed. Apparatus for carrying out the method include a vessel (12;25) containing extract (26) and a source of the gas. The source may be in the form of a moveable, hollow wand (27) having a sparging gas outlet; or a fixed gas inlet (30) for bubbling the gas through the extract (26).
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: July 19, 2005
    Assignee: Ineos Fluor Holdings Limited
    Inventors: Stuart Corr, Paul A. Dowdle, Robert E. Low, Frederick Thomas Murphy, James David Morrison
  • Patent number: 6846422
    Abstract: A method and system for removing volatile organic compounds (VOCs) from sludge advantageously utilizes a stripper for removing the VOCs directly from the sludge to convert the sludge into a non-hazardous material. Preliminary steps of mixing may include addition of a liquid to improve flowability. Then the sludge is moved through the stripper in which the VOCs are carried away in a gas provided in the stripper for the purpose of carrying the VOCs away. Any of a variety of strippers may be utilized for VOC removal. Subsequently, the liquid is separated from the sludge material in, for example, a dewaterer, and each of the liquid and the sludge is either recycled or dumped as a non-hazardous material or waste. The system may be configured in a variety of ways and still function properly in carrying out the method of the invention.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: January 25, 2005
    Assignee: K2M Mobile Treatment Services, Inc.
    Inventor: Paul W. Anderson
  • Patent number: 6840983
    Abstract: The present invention generally offers a system and a method that allows a vessel to treat water while providing corrosion inhibition. An oxygen stripping gas source produces oxygen stripping gas that may be pumped directly to, preferably but optionally, a venturi injector, or may first be pumped into an empty tank and then delivered to the injector means. Water being pumped through the injector via a transfer piping means comes into contact with the oxygen stripping gas, and dissolved oxygen in the water transfers to micro-fine stripping gas bubbles generated by the injector. The water and the micro-fine bubbles are pumped from the injector and into the tank, where the micro-fine bubbles float to the surface, and the oxygen is released into the tank's headspace. The deoxygenated water may be re-circulated through the system for additional deoxygenation or released from the tank into the surrounding waterways.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: January 11, 2005
    Assignee: NEI Treatment Systems, LLC
    Inventor: Peter Drummond McNulty
  • Patent number: 6719823
    Abstract: The invention encompasses polishing systems for polishing semiconductive material substrates, and encompasses methods of cleaning polishing slurry from semiconductive substrate surfaces. In one aspect, the invention includes a method of cleaning a polishing slurry from a substrate surface comprising: a) providing a substrate surface having a polishing slurry in contact therewith; b) providing a liquid; c) injecting a gas into the liquid to increase a total dissolved gas concentration in the liquid; and d) after the injecting, providing the liquid against the substrate surface to displace the polishing slurry from the substrate surface.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: April 13, 2004
    Assignee: Micron Technology, Inc.
    Inventors: Dan G. Custer, Aaron Trent Ward, Shawn M. Lewis
  • Patent number: 6716273
    Abstract: A continuous process for removing oxygen from aqueous monomer solutions, including flowing an inert gas and a monomer solution in a column-shaped apparatus as a countercurrent, wherein the monomer solution is added at the head of the apparatus, flows through the apparatus as a liquid column, and is withdrawn slightly above the bottom, at least one section of the liquid column is mixed in radial flow direction and in a turbulent fashion, and the at least one section of the liquid column is mixed using at least one stirring element which is one of a turbine disk and a dispersing disk.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: April 6, 2004
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Juergen Schulte, Detlef Albin
  • Publication number: 20040000234
    Abstract: Methods and systems are provided that allow the reduction of the oxygen concentration and/or a concentration of other natural gases in process liquids used in the processing of substrates, preferably substrates that receive and/or contain exposed metal surfaces, such as copper surfaces. By introducing an inert gas in a water system or in a chemical storage tank for process liquids, already dissolved oxygen will be removed and the further dissolving of oxygen may be substantially prevented. Thus, the probability for the formation of corrosion and discoloration on copper surfaces is significantly reduced.
    Type: Application
    Filed: November 27, 2002
    Publication date: January 1, 2004
    Inventors: Axel Preusse, Gerd Marxsen, Johannes Groschopf
  • Publication number: 20030205136
    Abstract: The present invention generally offers a system and a method that allows a vessel to treat water while providing corrosion inhibition. A nitrogen source produces nitrogen gas that may be pumped directly to, preferably but optionally, a venturi injector, or may first be pumped into an empty tank and then delivered to the injector means. Water being pumped through the injector via a transfer piping means comes into contact with the nitrogen, and dissolved oxygen in the water transfers to micro-fine nitrogen bubbles generated by the injector. The water and the micro-fine bubbles are pumped from the injector and into the tank, where the micro-fine bubbles float to the surface, and the oxygen is released into the tank's headspace. The deoxygenated water may be re-circulated through the system for additional deoxygenation or released from the tank into the surrounding waterways.
    Type: Application
    Filed: May 2, 2002
    Publication date: November 6, 2003
    Inventor: Peter Drummond McNulty
  • Patent number: 6521022
    Abstract: Apparatus and methods for reducing residual solvent levels in extracted biomass that is contaminated with HFC solvent that includes sparging the biomass extract with a solvent stripping gas such as air or nitrogen are disclosed. Apparatus for carrying out the method include a vessel (12;25) containing extract (26) and a source of the gas. The source may be in the form of a moveable, hollow wand (27) having a sparging gas outlet; or a fixed gas inlet (30) for bubbling the gas through the extract (26).
    Type: Grant
    Filed: September 5, 2000
    Date of Patent: February 18, 2003
    Assignee: Ineos Fluor Holdings Limited
    Inventors: Stuart Corr, Paul A. Dowdle, Robert E. Low, Frederick Thomas Murphy, James David Morrison
  • Publication number: 20020144598
    Abstract: It has been discovered that a mechanical device may be used to effectively displace a first undesired gas from within a liquid with a second desired or at least inert gas. The device is a vessel that receives the liquid containing the first gas and passes the liquid through a series of gasification chambers. Each gasification chamber has at least one mechanism that ingests and mixes a second gas into the liquid thereby physically displacing at least a portion of the first gas into a vapor space at the top of each gasification chamber from which it is subsequently removed. There is an absence of communication between the vapor spaces of adjacent chambers. The ingesting and mixing mechanisms may be a dispersed air flotation mechanism, and may be a conventional depurator. The liquid now containing the second gas and very little or none of the first gas is removed from the vessel for use.
    Type: Application
    Filed: April 4, 2002
    Publication date: October 10, 2002
    Inventors: Melvin Stacy, James Chen
  • Publication number: 20020139248
    Abstract: A subsea passive flash gas compression system that includes a first separator that removes high pressure flash gas from a hydrocarbon product, a second separator that removes low pressure flash gas from the hydrocarbon product after the high pressure flash gas has been removed, and an ejector. The ejector includes a high pressure input that is coupled to a high pressure flash gas output of the first separator. The ejector also includes a low pressure input that is coupled to a low pressure flash gas output of the second separator. An output of the ejector is coupled to an outlet pipeline that extends from proximate the sea bottom to the sea surface.
    Type: Application
    Filed: March 27, 2001
    Publication date: October 3, 2002
    Inventors: Michael S. Choi, James N. Collins
  • Patent number: 6344588
    Abstract: In the present process for the preparation of urea, an off-gas stream released during the synthesis of melamine in a high-pressure melamine process which consists predominantly of ammonia and carbon dioxide, is introduced into at least one high-pressure section of a urea stripping plant and is used in the synthesis of urea. The off-gas stream can be used directly without any further treatment.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: February 5, 2002
    Assignee: DSM, N.V.
    Inventor: Julius G. T. Van Wijck
  • Patent number: 6193786
    Abstract: The present invention provides methods and devices for reducing the concentration of combustible gases in oils. The methods and devices of the invention are of particular use in reducing the concentration of combustible gases in insulating oils used in electrical devices such as transformers.
    Type: Grant
    Filed: December 11, 1998
    Date of Patent: February 27, 2001
    Assignee: Pacific Gas and Electric Company
    Inventor: J Henderson
  • Patent number: 6176899
    Abstract: A method of degassing a volume of supersaturated liquid is provided which comprises introducing a plurality of microbubbles of gas substantially near the bottom of the volume of supersaturated liquid so that the microbubbles percolate up through the volume of supersaturated liquid to thereby effect removal of dissolved gas in the volume of the supersaturated liquid at the top of the volume. In one embodiment, the step of introducing microbubbles comprises introducing the microbubbles by recirculating deionized water through a hollow fiber microfiltration membrane. In another embodiment, the step of introducing microbubbles comprises introducing the microbubbles through a pipe from the turbine of a dam. In most applications, the volume of supersaturated liquid is water and the microbubbles of gas comprise air. The volume of supersaturated water advantageously comprises a volume of a river, lake or stream which is near a dam with a turbine.
    Type: Grant
    Filed: September 17, 1998
    Date of Patent: January 23, 2001
    Assignee: The United States of America as represented by the Secretary of the Interior
    Inventors: Andrew P. Murphy, Robert Lee Riley, Scott Roy Irvine
  • Patent number: 6174506
    Abstract: A process for recovering carbon dioxide from a gas containing both carbon dioxide and oxygen wherein a carbon dioxide and oxygen containing gas is first contacted with an alkanolamine solution to produce an alkanolamine loaded with carbon dioxide and oxygen, the oxygen is separated from the absorption solution, such as by stripping with a scavenging gas, such as the carbon dioxide containing fluid obtained from the separation of carbon dioxide from the alkanolamine solution or nitrogen, prior to any heating of the absorption solution, and carbon dioxide is steam stripped from the absorption solution and recovered. By stripping the oxygen out of the alkanolamine solution, oxidative degradation of the alkanolamine can be reduced.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: January 16, 2001
    Assignee: Praxair Technology, Inc.
    Inventors: Shrikar Chakravarti, Amitabh Gupta
  • Patent number: 5855861
    Abstract: A method of forming an aqueous chlorine dioxide solution is disclosed which includes reacting in a reaction vessel an acid reaction solution containing a hydroxy carboxylic acid and a companion acid with an alkali metal salt of a chlorite ion. In accordance with the process, the hydroxy carboxylic acid serves to temporarily transfer chlorine from and does not form a salt with the alkali metal salt of a chlorite ion. The aqueous chlorine dioxide solution produced is substantially free of chlorous acid and preferably is free of other by-products such as sodium chloride and free chlorine. The method further includes maintaining the reaction vessel at a pH of less than 5 and/or withdrawing at least a portion of the chlorine dioxide from the aqueous chlorine dioxide solution. The method enables rapid, efficient, compact and safe generation of chlorine dioxide. A method of disinfecting water, and apparatus for making chlorine dioxide and for disinfecting water also are provided.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: January 5, 1999
    Assignee: Water Technologies Limited
    Inventor: Sunggyu Lee
  • Patent number: 5772731
    Abstract: A process of removing carbon dioxide from a liquor in a vessel comprises the step of continuously passing a portion of the liquor into a sidestream and introducing discrete bubbles of between 0.005 mm and 1.0 mm diameter of nitrogen rich gas into the liquor before returning it to the vessel in which the nitrogen acts to adsorb carbon dioxide from the liquor and is then expelled from the liquor as an off-gas. The process also includes introducing a gas to be dissolved in the liquor into the sidestream as discrete bubbles having a diameter of between 0.005 mm and 1.0 mm.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: June 30, 1998
    Assignee: The BOC Group plc
    Inventor: Stephen B. Harrison
  • Patent number: 5766321
    Abstract: Disclosed is a dissolved oxygen reducing apparatus which enables supplying a liquid containing very small amounts of dissolved oxygen. The dissolved oxygen reducing apparatus includes a bubbling vessel (24) having a liquid charge inlet (21), a liquid discharge outlet (22) and an inert gas discharge port (23), an inert gas sparger (25) provided within the bubbling vessel (24), and a liquid discharge pipe (26) connected to the liquid discharge outlet (22). The bubbling vessel (24) and the liquid discharge pipe (26) have a coefficient of oxygen permeability of not higher than 10.sup.-9 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.atm at 25.degree. C.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: June 16, 1998
    Assignee: Nippon Sanso Corporation
    Inventors: Yoshio Ishihara, Hiroshi Yamazaki, Sumiyo Yamane, Koh Matsumoto
  • Patent number: 5565108
    Abstract: A method of retarding the growth of algae in aqueous solution is disclosed. An aqueous medium is moved along a flow path in a direction terminating at an aqueous solution into which the aqueous medium is added. Before adding said aqueous medium into the aqueous solution, a gas stream having a nitrogen content in excess of 90% is injected into the aqueous solution in the same direction in which the aqueous solution is moved along the flow path. The gas stream is injected into the aqueous medium at a flow rate of at least 0.01 cubic feet per hour and said gas stream and said aqueous medium continue to intermix along said flow path prior to reaching the termination of the flow path at the aqueous solution.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: October 15, 1996
    Inventors: Robert S. Dimesky, Francis X. Hursey
  • Patent number: 5458789
    Abstract: Apparatus and process for removing relatively low levels of components, particularly organic components found in an aqueous stream in one or more stripping zones located in a process unit. An eductor means extending into each stripping zone is used to provide micro-fine gas bubbles which will dissolve the volatile components and carry them from the aqueous stream.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: October 17, 1995
    Inventors: J. Rodney Dickerson, Paul C. Broussard, Sr.
  • Patent number: 5389126
    Abstract: A process for removing components from liquid is disclosed. This process involves batchwise gas-stripping followed by membrane separation treatment of the stripping gas. The stripping step can be carried out by circulating the batch repeatedly around the loop formed by the tank and the stripper for sufficient time until the desired degree of component removal is achieved. An additional tank can also be used to avoid mixing treated and untreated liquid streams. The membrane separation step can be carried out using a single-stage membrane unit or a multistage unit. The process is particularly suited for treatment of industrial streams that are small intermittent streams and vary in composition and concentration.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: February 14, 1995
    Assignee: Membrane Technology and Research, Inc.
    Inventors: Richard W. Baker, Harmohinder S. Bedi
  • Patent number: 5314613
    Abstract: A process and apparatus for the decontamination of oil includes providing a jet compressor having a converging section in which high velocity liquid oil compresses a source of atmospheric pressure gas, a central mixing section that intimately mixes the liquid oil with the gas for providing a large gas and oil surface area for the mass transfer of water from the liquid oil, and a diverging section in which the liquid oil and gas are further mixed during pressure recovery. A tubular member is connected to the diverging section to provide a residence time chamber immediately downstream of the diverging section to increase the efficiency of the rate of transfer of water from the liquid oil to the gas.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: May 24, 1994
    Inventor: Gaetano Russo
  • Patent number: 5273572
    Abstract: A process for removing organic compounds from water is disclosed. The process involves gas stripping followed by membrane separation treatment of the stripping gas. The stripping step can be carried out using one or multiple gas strippers and using air or any other gas as stripping gas. The membrane separation step can be carried out using a single-stage membrane unit or a multistage unit. Apparatus for carrying out the process is also disclosed. The process is particularly suited for treatment of contaminated groundwater or industrial wastewater.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: December 28, 1993
    Assignee: Membrane Technology and Research, Inc.
    Inventors: Richard W. Baker, Jurgen Kaschemekat, Johannes G. Wijmans, Henky D. Kamaruddin