And Solid Sorption Patents (Class 95/41)
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Patent number: 11745163Abstract: A carbon dioxide adsorbent including a hierarchical zeolite. The hierarchical zeolite defines micropores having a pore width between about 0.4 nm and about 2 nm, and at least one of: mesopores having a pore width between about 2 nm and about 50 nm; and macropores having a pore width greater than about 50 nm.Type: GrantFiled: February 22, 2021Date of Patent: September 5, 2023Assignee: Arizona Board of Regents on behalf of Arizona State UniversityInventors: Dong-Kyun Seo, Farid Akhtar
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Patent number: 11460245Abstract: A method of natural gas treatment including introducing a natural gas containing stream into a dryer unit, thereby producing a treated natural gas containing stream. Introducing the treated natural gas containing stream into a nitrogen rejection unit, thereby producing a further treated natural gas stream as a nitrogen rejection unit product. Splitting the nitrogen rejection unit product into at least two portions, introducing the first portion of the further treated natural gas stream into a reformer unit as first part of feed, and introducing a second portion of the further treated natural gas stream into the dryer unit as a regeneration stream, thereby producing a regeneration waste stream. Introducing at least a portion of the regeneration waste stream into the reformer unit as second part of feed.Type: GrantFiled: September 4, 2020Date of Patent: October 4, 2022Assignee: L'Air Liquide, Scoiété Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Yufeng Qian, Jasmin Junger, Elise Renou, Alexander Roesch
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Patent number: 9217398Abstract: In a gas engine 1 that uses a gas having a lower specific gravity than air and has a pre-mixing device before a turbocharger, a pre-mixed gas mixture compressed by a turbocharger 3 is cooled by an intercooler 4 located downstream of the turbocharger 3 in the intake system. Condensed water produced as the gas is cooled and the pre-mixed gas mixture discharged with the condensed water are separated into condensed water, air, and fuel gas in a vapor-liquid separator 7. The fuel gas is returned to the intake system upstream of the turbocharger 3, while the condensed water is discharged to atmosphere.Type: GrantFiled: June 27, 2011Date of Patent: December 22, 2015Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Hideki Nishio, Hajime Suzuki, Yuuichi Shimizu
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Patent number: 9061929Abstract: The present invention relates to a furnace (12) for melting heated glass using burners (13), wherein the combustion energy is at least partially produced by oxy-fuel combustion, and wherein at least a portion of the oxygen used is produced by separation, on a ceramic separation membrane (18), from a gaseous mixture including oxygen.Type: GrantFiled: August 5, 2010Date of Patent: June 23, 2015Inventors: Francois Bioul, Olivier Douxchamps
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Publication number: 20150114223Abstract: An air dryer with a rotor and desiccant positioned within an interior chamber of the rotor. The desiccant is positioned within the interior chamber of the rotor between the inlet and the outlet. The desiccant is configured to adsorb at least some of the water contained within air flowing from an inlet to an outlet of the rotor. As the rotor is rotated at a regeneration speed at least some of the water adsorbed by the desiccant moves to the outer surface of the desiccant and at least some of the water is separated from the outer surface of the desiccant. The rotor directs water separated from the outer surface of the desiccant to at least one opening in the rotor. A method for drying air by sending the air through desiccant and rotating the desiccant at a regeneration speed to separate water from the desiccant.Type: ApplicationFiled: October 31, 2013Publication date: April 30, 2015Applicant: HALDEX BRAKE PRODUCTS CORPORATIONInventor: MICHAEL R. JENKINS
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Publication number: 20140373712Abstract: An off gas purification system provides superior results to other systems for removing volatile organic compounds from off gas, especially off gas from soil, groundwater, industrial processes, pipelines and storage tanks. Off gas is extracted, followed by compression and condensation. Compression and condensation produce an off gas that must be further treated to produce pollutant-free exhaust. A separation device cleans the influent gas/air by separating residual chemical vapor from the gas stream and returning that chemical vapor to the compression and condensation step. After removal of all detectable volatile organic compounds, the air stream may be further separated into segregated gases, and heated gas is used to thermally enhance the desorption or degradation of volatile organic compounds from the off gas source or a separation device.Type: ApplicationFiled: October 20, 2011Publication date: December 25, 2014Inventor: Grant Geckeler
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Publication number: 20140360364Abstract: A gas compressing system includes a compressor that provides a flow of compressed gas, a first desiccant tower, and a second desiccant tower separate from the first tower. The system also includes a first separator, a second separator separate from the first separator, an outlet, a first set and second set of no more than three valves each movable between an open position and a closed position. The flow flows along a flow path from the compressor to the first tower, to the first separator, to the second tower and out the outlet when the first set of valves is open and the second set of valves is closed. The flow of compressed gas flows from the compressor to the second tower, to the second separator, to the first tower and out the outlet when the first set of valves is closed and the second set of valves is opened.Type: ApplicationFiled: June 4, 2014Publication date: December 11, 2014Inventors: Charles John Bergh, Henry Y. Mark
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Publication number: 20140326136Abstract: A temperature swing adsorption system includes a first adsorption bed configured to receive a feed stream and adsorb a contaminant from the feed stream to produce a product stream, a second adsorption bed configured to receive a portion of the product stream and a cooling stream to reduce a temperature of the second adsorption bed, a third adsorption bed configured to receive the heated product stream to increase a temperature of the third adsorption bed; a separation system to separate the cooled product stream into a first component stream and a second component stream, and a fourth adsorption bed configured to receive the first component stream and to enrich an adsorptive concentration of the first component stream. The enriched first component stream is directed to the second adsorption bed to provide the cooling stream.Type: ApplicationFiled: May 6, 2013Publication date: November 6, 2014Inventors: Shain-Jer Doong, Christopher B. McIlroy
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Publication number: 20140260967Abstract: Heat generated by the first stage compressor while it is running (either loaded or unloaded in the recycled purge air dryer system is recaptured by a stream of dried, cool system air drawn off of the outlet of a online drying tower in an air compressor system via a purge heat exchanger placed after the first stage compressor. The dried, hot air is used help regenerate the offline tower. This regenerating, pressurized, and heated purge air is then cooled in its passage across or through the desiccant in the regenerating tower. It then reenters the main airflow at the outlet of the first stage air compressor as wet cool pressurized purge air. This process is completely closed loop within the system, achieving zero air loss, and avoiding dew point spikes, increasing the efficiency of the air compressor system.Type: ApplicationFiled: March 7, 2014Publication date: September 18, 2014Applicant: Roger's Machinery Company, Inc.Inventor: Robert Gitschlag
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Patent number: 8747520Abstract: The present invention are methods for removing preselected substances from a mixed flue gas stream characterized by cooling said mixed flue gas by direct contact with a quench liquid to condense at least one preselected substance and form a cooled flue gas without substantial ice formation on a heat exchanger. After cooling additional process methods utilizing a cryogenic approach and physical concentration and separation or pressurization and sorbent capture may be utilized to selectively remove these materials from the mixed flue gas resulting in a clean flue gas.Type: GrantFiled: May 3, 2011Date of Patent: June 10, 2014Assignee: Battelle Memorial InstituteInventors: Mark D. Bearden, Paul H. Humble
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Patent number: 8715394Abstract: Provided herein are methods and apparatus for capturing or otherwise decreasing the amount of CO2 in an exhaust stream. The separation process for removing CO2 from a waste stream preferably operates substantially at atmospheric pressure and at a preselected temperature, and without the need of thermal swing regeneration. This novel elimination of the heat up and cool down periods allows the inventive cycle herein to be run faster, and more efficiently than in previously known systems. Further, in some examples herein, the heat of adsorption is used to provide the heat of regeneration.Type: GrantFiled: November 22, 2011Date of Patent: May 6, 2014Inventors: Hugo S. Caram, Alberto I. LaCava
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Patent number: 8709135Abstract: An off gas extraction system cleans common sources of off gas, such as storage tanks and polluted soils. Off gas is extracted, followed by compression and condensation. Compression and condensation produce an off gas that can be reintroduced as a treated gas into the off gas source. Alternatively, a regenerative absorber cleans the treated gas by adsorbing residual chemical vapor and concentrates the removed chemical vapors and reprocesses them. If the treated gas is not reintroduced into the off gas source, conventional scrubbers may used on the back end of the system to produce a final exhaust as prescribed by environmental regulation. Methods of accomplishing the same are similarly provided, including novel methods for degassing storage tanks and treating polluted soils to meet current environmental regulations, as well as green technology and sustainability initiatives.Type: GrantFiled: August 20, 2010Date of Patent: April 29, 2014Inventor: Carol Diane Krumbholz
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Patent number: 8685175Abstract: An apparatus and process for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon which includes a first drier and a second drier; and a reaction zone communicating with at least the first drier. The first drier operates at a first condition to dry the reactant and the second drier operates at a second condition during regeneration. The used regenerant remaining in the second drier after regeneration can (1) pass through a vent-to-flare assembly in a batch-wise manner; (2) pass through a downflow-depressure-to-low-pressure-device assembly in a batch-wise manner; (3) pass through a cross-over piping purge assembly to minimize upsets in the reaction and fractionation zones when the second drier is placed back in operation; or any combination of (1) (2) and/or (3) to minimize upsets in the reaction and fractionation zones when the second drier is placed back in operation.Type: GrantFiled: November 17, 2009Date of Patent: April 1, 2014Assignee: UOP LLCInventors: Bryan S. Garney, Jocelyn C. Daguio, Kurt A. Detrick, David J. Shecterle, John M. Krupczak, Andrew D. Mezera, Douglas A. Becci
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Patent number: 8673056Abstract: The invention is directed to processes and apparatuses for gas treatment, in particular for the purification of methane rich gas streams, such as gas obtained from the conversion from organic matter (“biogas”). In accordance with the present invention there is provided an apparatus and a process for producing a purified methane comprising gas stream (P) from a methane containing gas stream (A), comprising the steps of: (a) pressurising said methane containing gas stream (A) and subsequently cooling it, whereby a stream comprising condensed contaminants (C) and a methane comprising stream (B) are obtained; (b) optionally feeding said methane comprising stream (B) to an adsorption unit and/or a catalytic conversion unit, whereby the concentration of contaminants in stream (B) is further decreased; and (c) cooling the methane comprising stream (B) to a temperature which is sufficient to condensate CO2 from said stream (B), whereby said purified methane comprising gas stream (P) is obtained.Type: GrantFiled: August 17, 2006Date of Patent: March 18, 2014Assignee: Gastreatment Services B.V.Inventors: Mathieu André De Bas, Jacob Kuiper, Jeroen De Pater
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Patent number: 8647409Abstract: An air compression system and method for an air separation plant in which air is compressed in a series of compression stages and a temperature swing adsorption unit adsorbs water vapor and carbon dioxide. The temperature swing adsorption unit is situated at a location of the compression stages such that air pressure upon entry into the adsorbent beds is between about 400 psia and about 600 psia. Each of the adsorbent beds of the unit have a minimum transverse cross-sectional flow area that will set the air velocity of the air to a level below that at which adsorbent bed fluidization would occur. Such operation allows fabrication costs of the adsorbent beds to be reduced because less adsorbent and smaller adsorbent beds are required while power consumption will be at a minimum.Type: GrantFiled: May 24, 2012Date of Patent: February 11, 2014Assignee: Praxair Technology, Inc.Inventors: Mohamed Hashi, Michael C. Johnson, John Royal
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Publication number: 20130312427Abstract: An air compression system and method for an air separation plant in which air is compressed in a series of compression stages and a temperature swing adsorption unit adsorbs water vapor and carbon dioxide. The temperature swing adsorption unit is situated at a location of the compression stages such that air pressure upon entry into the adsorbent beds is between about 400 psia and about 600 psia. Each of the adsorbent beds of the unit have a minimum transverse cross-sectional flow area that will set the air velocity of the air to a level below that at which adsorbent bed fluidization would occur. Such operation allows fabrication costs of the adsorbent beds to be reduced because less adsorbent and smaller adsorbent beds are required while power consumption will be at a minimum.Type: ApplicationFiled: May 24, 2012Publication date: November 28, 2013Inventors: Mohamed Hashi, Michael C. Johnson, John Royal
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Patent number: 8591634Abstract: An apparatus and process for recovering a desired gas such as xenon difluoride, xenon, argon, helium or neon, from the effluent of a chemical process reactor that utilizes such gases alone or in a gas mixture or in a molecule that becomes decomposed wherein the chemical process reactor uses a sequence of different gas composition not all of which contain the desired gas and the desired gas is captured and recovered substantially only during the time the desired gas is in the effluent.Type: GrantFiled: January 19, 2011Date of Patent: November 26, 2013Assignee: Air Products and Chemicals, Inc.Inventors: David Charles Winchester, Matthew John Bosco, Gerald W. Klein, Isaac Patrick West, Richard Linton Samsal, Douglas Paul Dee, Andrew David Johnson, Eugene Joseph Karwacki, Jr.
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Publication number: 20130291718Abstract: One ozone concentrating chamber is provided therein with a part of a cooling temperature range where ozone can be selectively condensed or an oxygen gas can be selectively removed by transmission from an ozonized oxygen gas, and a part of a temperature range where condensed ozone can be vaporized, and condensed ozone is vaporized by moving condensed ozone with flow of a fluid or by gravitation to the part where condensed ozone can be vaporized, whereby the ozonized oxygen gas can be increased in concentration. Such a constitution is provided that a particle material 13 for condensation and vaporization filled in the ozone concentrating chambers 11 and 12 has a spherical shape of a special shape with multifaceted planes on side surfaces, or an oxygen transmission membrane 130 capable of selectively transmitting an oxygen gas in an ozone gas is provided.Type: ApplicationFiled: April 3, 2013Publication date: November 7, 2013Inventors: Yoichiro TABATA, Tetsuya SAITSU, Yujiro OKIHARA, Nobuyuki ITOH, Ryohei UEDA, Yasuhiro TANIMURA, Koji OHTA
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Patent number: 8465570Abstract: A method for the purification of a feed gas stream containing at least CO2 and at least one impurity with by the incorporation of a purification step, enabling water to be at least partially removed is provided.Type: GrantFiled: July 8, 2008Date of Patent: June 18, 2013Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Bruno Alban, Christophe Claeys, Philippe Court, Arthur Darde, Guillaume De Smedt, Bao Ha, Vladimir Hasanov, Simon Jallais, Christian Monereau, Serge Moreau, Elise Renou, Ivan Sanchez-Molinero, Jean-Pierre Tranier
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Publication number: 20130055891Abstract: The invention relates to a method for treating a gas stream comprising combustion fumes containing CO2 in an initial proportion, water vapor, one or more volatile acid compounds, and one or more additional impurities selected from among oxygen, nitrogen and argon, comprising the steps of: i) compressing the gas stream to a final pressure of 1 bar to 74 bar absolute; ii) cooling the gas stream to a temperature of around ?10° C. to around ?130° C. and eliminating at least one additional impurity; and iii) recovering a CO2-enriched gas stream containing a final proportion of CO2 greater than the initial proportion of CO2 in the stream to be treated. In addition, the method comprises, prior to step i), a step of pre-drying the stream for removing therefrom at least a portion of the water vapor which it contains.Type: ApplicationFiled: February 25, 2011Publication date: March 7, 2013Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Explitation Des Procedes GeorgesInventors: Bruno Alban, Philippe Arpentinier, Alain Briglia, Serge Moreau, Fabrice Del Corso, Benoit Davidian
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Publication number: 20120222549Abstract: Device for compressing and drying gas includes a compressor and a dryer using a drying agent for drying gas connected thereto. The compressor includes two or more compressor elements with an inlet and an outlet which are connected together in series to form a first low-pressure stage. One or more subsequent high-pressure stages are each connected with their inlet to the outlet of a previous compressor element via a pressure pipe and an outlet pipe in which an after cooler is incorporated. The dryer has a drying section and a regeneration section. The drying section is filled with a drying agent for drying the gas and has an inlet connected to the outlet pipe of the compressor device, and an outlet that supplies compressed and dried gas. The regeneration section dries moist drying agent by a regeneration gas which is guided there via an inlet and an outlet with a regeneration pipe connected to the inlet.Type: ApplicationFiled: October 26, 2010Publication date: September 6, 2012Inventor: Constantijn Friso Vermeer
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Patent number: 8252089Abstract: The present invention relates to a method and device for compressing and drying a gas flow rich in carbon dioxide, for example containing more than 50 mol % of carbon dioxide.Type: GrantFiled: November 21, 2008Date of Patent: August 28, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Pierre Tranier, Arthur Darde, Jean-François Rauch, Dominique Antonio, Christophe Michel
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Publication number: 20120125194Abstract: Provided herein are methods and apparatus for capturing or otherwise decreasing the amount of CO2 in an exhaust stream. The separation process for removing CO2 from a waste stream preferably operates substantially at atmospheric pressure and at a preselected temperature, and without the need of thermal swing regeneration. This novel elimination of the heat up and cool down periods allows the inventive cycle herein to be run faster, and more efficiently than in previously known systems. Further, in some examples herein, the heat of adsorption is used to provide the heat of regeneration.Type: ApplicationFiled: November 22, 2011Publication date: May 24, 2012Applicant: LEHIGH UNIVERSITYInventors: Hugo S. Caram, Alberto I. LaCava
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Publication number: 20120085232Abstract: A method for removing contaminants from natural gas streams. The natural gas stream is fed to a dryer, then a membrane module and a multibed, multilayer vacuum swing adsorption process for removal of oxygen, nitrogen and carbon dioxide from the natural gas stream. Alternatively when carbon dioxide is in relatively low concentration in the natural gas stream, the membrane module step is not employed.Type: ApplicationFiled: April 12, 2011Publication date: April 12, 2012Inventors: Rustam H. Sethna, Ramachandran Krishnamurthy
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Publication number: 20120031267Abstract: The present invention provides for a method to cool the recycle gas in a product compressor being used with a cyclic adsorption process. It simplifies the scheme by eliminating need to provide a separate cooler for recycle gas.Type: ApplicationFiled: August 9, 2010Publication date: February 9, 2012Applicant: ADSORPTECH INC.Inventors: APURVA MAHESHWARY, John R. Ambriano, James J. Flaherty, Krishamurti V. Subramanian
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Patent number: 8062613Abstract: An apparatus and process for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon which includes a first drier and a second drier; and a reaction zone communicating with at least the first drier. The first drier operates at a first condition to dry the reactant and the second drier operates at a second condition during regeneration. The used regenerant remaining in the second drier after regeneration can (1) pass through a vent-to-flare assembly in a batch-wise manner; (2) pass through a downflow-depressure-to-low-pressure-device assembly in a batch-wise manner; (3) pass through a cross-over piping purge assembly to minimize upsets in the reaction and fractionation zones when the second drier is placed back in operation; or any combination of (1) (2) and/or (3) to minimize upsets in the reaction and fractionation zones when the second drier is placed back in operation.Type: GrantFiled: November 17, 2009Date of Patent: November 22, 2011Assignee: UOP LLCInventors: Bryan S. Garney, Jocelyn C. Daguio, Kurt A. Detrick, David J. Shecterle, John M. Krupczak, Andrew D. Mezera, Douglas A. Becci
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Publication number: 20110247491Abstract: The invention relates to a process and an apparatus for the treatment of a carbon dioxide-containing gas stream from a large-scale combustion plant, in particular of a power station. The gas stream is separated in a carbon dioxide purification stage R into a gas substream having an increased carbon dioxide content and a gas substream having a reduced carbon dioxide content. The gas substream having an increased carbon dioxide content is fed to a further use and/or storage S. In particular, compression of the carbon dioxide under the ground can reduce the emission of gases which affect the climate. To increase the proportion of compressible CO2, it is proposed that the gas substream having a reduced carbon dioxide content is fed to a pressure swing adsorption stage PSA in which a fraction which is rich in carbon dioxide and a fraction which is low in carbon dioxide are produced.Type: ApplicationFiled: November 26, 2009Publication date: October 13, 2011Applicant: LINDE-KCA-DRESDEN GMBHInventors: Paul Leitgeb, Werner Sebastian Leitmayr, Torsten Stoffregen, Roland Ritter
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Method for removing hydrocarbons from a vapour-gas mixture and a device for carrying out said method
Patent number: 8034159Abstract: A method for cleaning hydrocarbons from a gas-vapor medium ejected to the atmosphere, formed while storing oil or gasoline or filling a container therewith is provided. The medium is pumped out and compressed in a gas-liquid jet apparatus due to energy of oil or gasoline supplied by a pump. The formed mixture is separated in a separator, where a pressure of 0.7 to 2.5 MPa is maintained, and gas from the separator is compressed in a jet apparatus by oil or gasoline supplied by a pump. The gas medium cleaned from the hydrocarbons is outputted and the saturated absorbent is directed to a desorber where a pressure is generated to be lower than the pressure in the separator. The liquid medium is removed from the separators and to a container or to a storage tank from which oil or gasoline is simultaneously supplied to pump inlets or to the separators.Type: GrantFiled: July 24, 2006Date of Patent: October 11, 2011Inventor: Valery Grigorievich Tsegelsky -
Publication number: 20110132191Abstract: An adsorption drying apparatus, in particular for drying a compressed gas, includes an adsorption chamber (11) having a plurality of adsorption conduits (101) containing an adsorption material (123), a first feeding line (106) and a first discharging line (109) disposed at a first end (111) of the adsorption chamber (11), and a second feeding line (108) and a second discharging line (107) disposed at a second end (112) of the adsorption chamber (11). The adsorption chamber (11) is rotatable with respect to the feeding and discharging lines (106, 107, 108, 109) so that the adsorption conduits may be fluidically connected in temporal alternation, wherein the gas is dried in a drying sector (102), and the adsorption material (123) is regenerated in the regeneration sector (103). The first feeding line (106) is configured such that the gas stream to be dried may be fed to the regeneration sector (103) as a full flow.Type: ApplicationFiled: December 1, 2010Publication date: June 9, 2011Applicant: KAESER KOMPRESSOREN GMBHInventors: Andreas FREDENHAGEN, René MARTIN, Michael FEISTHAUER, Michael ROHDENBURG
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Publication number: 20100288121Abstract: The present invention relates to a method and device for compressing and drying a gas flow rich in carbon dioxide, for example containing more than 50 mol % of carbon dioxide.Type: ApplicationFiled: November 21, 2008Publication date: November 18, 2010Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Dominique Antonio, Arthur Darde, Christophe Michel, Jean-Francois Rauch, Jean-Pierre Tranier
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Publication number: 20100263529Abstract: A method for the purification of a feed gas stream containing at least CO2 and at least one impurity with by the incorporation of a purification step, enabling water to be at least partially removed is provided.Type: ApplicationFiled: July 8, 2008Publication date: October 21, 2010Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Bruno Alban, Christophe Claeys, Philippe Court, Arthur Darde, Guillaume De Smedt, Bao Ha, Vladimir Hasanov, Simon Jallais, Christian Monereau, Serge Moreau, Elise Renou, Ivan Sanchez-Molinero, Jean-Pierre Tranier
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Publication number: 20100024476Abstract: Carbon dioxide-containing gas such as flue gas and a carbon dioxide-rich stream are compressed and the combined streams are then treated to desorb moisture onto adsorbent beds and then subjected to subambient-temperature processing to produce a carbon dioxide product stream and a vent stream. The vent stream is treated to produce a carbon dioxide-depleted stream which can be used to desorb moisture from the beds, and a carbon dioxide-rich stream which is combined with the carbon dioxide-containing gas.Type: ApplicationFiled: July 23, 2009Publication date: February 4, 2010Inventor: Minish Mahendra Shah
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Publication number: 20100000406Abstract: A method and apparatus for reducing discharges into the atmosphere of mercury pollutants associated with dry process, precalciner cement manufacturing is shown. Raw feed meal used in cement production is heated in a special heating chamber to drive off volatile mercury pollutants, such as elemental mercury and mercury oxides. Preferably, the feed meal is heated to a temperature of at least 175° C. The gases that are driven off flow are then cooled to condense the mercury pollutants causing them to be adsorbed on carbon particles injected into the gas flow. The carbon particles containing the condensed mercury pollutants are then filtered out of gas flow, for example, using a fabric filter. The gas flow may be burned to destroy other volatile pollutants such as hydrocarbons and/or ammonia.Type: ApplicationFiled: July 2, 2008Publication date: January 7, 2010Inventors: James J. Schwab, Ronald L. Hawks
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Patent number: 7632337Abstract: The present invention relates to cryogenic air separation processes and systems that employ a pressure swing adsorption (PSA) prepurification process. It is advantageous to operate the PSA process at a pressure comparable to or below the operating pressure of the highest pressure column in the cryogenic separation unit. Following PSA prepurification, the air can be split into at least two fractions, with at least a portion of the air being directed to the cryogenic separation unit and at least a portion of the remaining air being further pressurized in at least one stage of compression.Type: GrantFiled: June 30, 2006Date of Patent: December 15, 2009Assignee: Praxair Technology, Inc.Inventors: Henry Edward Howard, Jeffert John Nowobilski
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Publication number: 20090166173Abstract: Purified SiHCl3 is used as a sweep gas across a permeate side of a gas separation membrane receiving effluent gas from a polysilicon reactor. The combined sweep gas and permeate is recycled to the reactor.Type: ApplicationFiled: March 31, 2008Publication date: July 2, 2009Inventor: Sarang GADRE
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Publication number: 20090049984Abstract: Improved compressor device consisting of a compressor (2) with an inlet (3) and an outlet (4); a compressed air line (5) which connects the outlet (4) of the compressor (2) to a user network (6); a drier (7) which is incorporated in the above-mentioned compressed air line (5) and which comprises at least two air receivers (13-16) which are each provided with an inlet (14) and an outlet (15) and which are filled with desiccant or drying agent, which air receivers (13-16) work alternately, such that while one air receiver (13) is drying the compressed gas, the other air receiver (16) is regenerated; and a blow-off device (28) for blowing off at least a part of the gas compressed by the compressor when the compressor (2) works in no-load or in partial load, characterised in that means are provided which make it possible to guide the part of the compressed gas which is blown off via the blow-off device (28) through the regenerating air receiver (13).Type: ApplicationFiled: July 20, 2005Publication date: February 26, 2009Inventor: Danny Etienne Andree Vertriest
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Publication number: 20080314244Abstract: Adsorption of CO2 from flue gas streams using temperature swing adsorption. The resulting CO2 rich stream is compressed for sequestration into a subterranean formation and at least a portion of the heat of compression is used in the desorption step of the temperature swing adsorption process.Type: ApplicationFiled: May 16, 2008Publication date: December 25, 2008Inventors: Bruce T. Kelley, Harry W. Deckman, Frank Hershkowitz, Paul S. Northrop, Peter I. Ravikovitch
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Patent number: 7258725Abstract: Gas supplying method and system in which effective component gas in exhaust gas can be separated and purified efficiently to be resupplied regardless of variation in the flow rate or composition of the exhaust gas and consumed gas can be replenished efficiently. In a method for collecting exhaust gas discharged from a gas using facility, separating/purifying effective component gas contained in the exhaust gas and supplying the effective component gas thus obtained to the gas using facility, the exhaust gas discharged from the gas using facility is added with a replenishing gas of the same components as the effective component gas before the effective component gas is separated and purified.Type: GrantFiled: December 4, 2002Date of Patent: August 21, 2007Assignee: Taiyo Nippon Sanso CorporationInventors: Tadahiro Ohmi, Yoshio Ishihara, Akihiro Nakamura
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Patent number: 6878186Abstract: A pure vacuum swing adsorption/desorption system and method, wherein supplied air feedstock gas is consistently separated to obtain a high-purity oxygen end-product gas mixture, is described. The system and method separate high-purity oxygen product from air by sequenced adsorption and desorption operations occurring exclusively under vacuum pressure conditions. This allows for greatly reduced kilowatt-hours of electric-oxygen power consumption per oxygen ton produced.Type: GrantFiled: September 9, 2003Date of Patent: April 12, 2005Inventor: David Lloyd Neary
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Patent number: 6878185Abstract: The subject of the present invention is a method and a device for the separation of fuel-vapor/air mixtures into their components, in particular for purification of vapor mixtures, such as occur in fuel tanks of motor vehicles. A preseparator is arranged between the fuel tank and the filter. In the preseparator, the hydrocarbons are separated from the mixture and are supplied to the fuel tank again. The remaining mixture is supplied to the filter.Type: GrantFiled: February 15, 2001Date of Patent: April 12, 2005Assignee: Siemens AktiengesellschaftInventors: Stefan Fühling, Knut Meyer, Martin Nockemann
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Patent number: 6755975Abstract: A process for treating liquids containing organic compounds and water. The process includes a pervaporation step in conjunction with a dephlegmation step to treat at least a portion of the permeate vapor from the pervaporation step. The process yields a membrane residue stream, a stream enriched in the more volatile component (usually the organic) as the overhead stream from the dephlegmator and a condensate stream enriched in the less volatile component (usually the water) as a bottoms stream from the dephlegmator. Any of these may be the principal product of the process. The membrane separation step may also be performed in the vapor phase, or by membrane distillation.Type: GrantFiled: June 12, 2002Date of Patent: June 29, 2004Assignees: Membrane Technology and Research, Inc., The United States of America as represented by the Environmental Protection AgencyInventors: Leland M. Vane, Anurag P. Mairal, Alvin Ng, Franklin R. Alvarez, Richard W. Baker
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Patent number: 6576043Abstract: A method for the separation of a gas mixture comprises (a) obtaining a feed gas mixture comprising nitrogen and at least one hydrocarbon having two to six carbon atoms; (b) introducing the feed gas mixture at a temperature of about 60° F. to about 105° F. into an adsorbent bed containing adsorbent material which selectively adsorbs the hydrocarbon, and withdrawing from the adsorbent bed an effluent gas enriched in nitrogen; (c) discontinuing the flow of the feed gas mixture into the adsorbent bed and depressurizing the adsorbent bed by withdrawing depressurization gas therefrom; (d) purging the adsorbent bed by introducing a purge gas into the bed and withdrawing therefrom an effluent gas comprising the hydrocarbon, wherein the purge gas contains nitrogen at a concentration higher than that of the nitrogen in the feed gas mixture; (e) pressurizing the adsorbent bed by introducing pressurization gas into the bed; and (f) repeating (b) through (e) in a cyclic manner.Type: GrantFiled: October 12, 2001Date of Patent: June 10, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Patrick Zwilling, Timothy Christopher Golden, Edward Landis Weist, Jr., Keith Alan Ludwig
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Patent number: 6551380Abstract: A gas separation apparatus and process has a first pressure swing adsorption (PSA) unit (110) receiving feed gas (112), which comprises a first and a second component. First PSA unit (110) produces first product gas (114) pre-dominantly containing the first component, and first off gas (116) containing at least some of the first component and second component. Compressor (120) is coupled to first PSA unit (110) to compress first off gas (116) to form compressed off gas (126), which is passed downstream to absorber unit (130), which employs a solvent to remove at least part of the second component from compressed off gas (126), forming an enriched compressed off gas (136B). Second PSA unit (140) receives enriched compressed off gas (136B) and produces second product gas (142) which predominantly contains the first component and a second off gas that is sent to waste or reformer burner (150).Type: GrantFiled: June 25, 2001Date of Patent: April 22, 2003Assignee: Fluor CorporationInventors: Satish Reddy, Ravi Ravikumar
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Patent number: 6511525Abstract: The present invention provides a method and apparatus for extracting liquid water from moist air using minimal energy input. The method can be considered as four phases: (1) adsorbing water from air into a desiccant, (2) isolating the water-laden desiccant from the air source, (3) desorbing water as vapor from the desiccant into a chamber, and (4) isolating the desiccant from the chamber, and compressing the vapor in the chamber to form liquid condensate. The liquid condensate can be removed for use. Careful design of the dead volumes and pressure balances can minimize the energy required. The dried air can be exchanged for fresh moist air and the process repeated. An apparatus comprises a first chamber in fluid communication with a desiccant, and having ports to intake moist air and exhaust dried air. The apparatus also comprises a second chamber in fluid communication with the desiccant. The second chamber allows variable internal pressure, and has a port for removal of liquid condensate.Type: GrantFiled: June 14, 2001Date of Patent: January 28, 2003Assignee: Sandia CorporationInventors: Barry L. Spletzer, Diane Schafer Callow
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Patent number: 6383257Abstract: An apparatus and process for separating perfluorocarbon compounds from a gas mixture passes an incoming stream of a gas into a cold trap, the gas stream including a plurality of perfluorocarbon compounds. The gas mixture is cooled within the cold trap to a temperature below −100° C. to produce a condensate that is enriched in at least one perfluorocarbon compound and a non-condensed stream from which the condensate was separated. The condensate is withdrawn from the cold trap. The condensate may be withdrawn by warming the cold trap to vaporize the condensate and thereafter flowing the vaporized condensate into a storage vessel. The non-condensed stream may be vented to the atmosphere, re-circulated into the cold trap or flowed through subsequent separation processes to extract additional perfluorocarbon compounds.Type: GrantFiled: April 4, 2000Date of Patent: May 7, 2002Assignee: Air Products and Chemicals, Inc.Inventors: Wayne Thomas McDermott, Richard Carl Ockovic, Alexander Schwarz, Rakesh Agrawal
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Patent number: 6350371Abstract: An improved process and process train for catalytic reforming of hydrocarbons. In its most simple form, the invention includes four unit operations or steps: the reforming itself usually carried out in a series of reactors; one or more steps to separate the reformate liquid product from overhead gases, predominantly C1-C6 hydrocarbons and hydrogen; one or more treatment steps to recover hydrogen from the overhead gases, and one or more treatment steps, including a membrane gas separation step, for the waste gas from the hydrogen recovery step. The process provides improved recovery of hydrogen and LPG, and reduces the amount of gas sent to the fuel line.Type: GrantFiled: March 19, 1999Date of Patent: February 26, 2002Assignee: Membrane Technology and Research, Inc.Inventors: Kaaeid A. Lokhandwala, Richard W. Baker
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Patent number: 6224677Abstract: A CVD device A is provided which is equipped with a gas introduction part A3 having an inert gas supply part G1 for supplying a diluting inert gas and a cleaning gas supply path G2 for supplying a cleaning gas, each connected therewith, and equipped with an exhaust gas discharge part A4 for releasing an exhaust gas; an exhaust gas circulation part D1 for circulating an exhaust gas from the CVD device, a cooling part D4 for cooling down and liquefying the cleaning gas in the exhaust gas, and a recovery part 4 for recovering the cleaning gas liquefied in said cooling part D4; the diluting inert gas is composed of a gas having a boiling point lower than that of the cleaning gas; a supply part 6 for supplying a cooling inert gas having the same composition as the diluting inert gas in a liquid state, an inert gas circulation part D3 which is cooled down by heat of evaporation of the cooling inert gas, and an inert gas discharge part 7 for discharging the cooling inert gas evaporated in the inert gas circulation pType: GrantFiled: July 12, 1996Date of Patent: May 1, 2001Assignee: Teisan Kabushiki KaishaInventors: Shigeyoshi Nozawa, Shinji Tomita
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Patent number: 6221130Abstract: A method and apparatus for compressing and drying a gas, typically air, are provided in which a multistage compressor is employed to produce interstage and final stage compressed gas. Regenerative adsorbent is employed to dry the final stage compressed gas. Interstage gas is used to regenerate the saturated adsorbent. Preferably, two beds of regenerable adsorbent are provided, each operable in a drying mode and a regeneration mode. In the drying mode, final stage compressed gas is passed through the bed of adsorbent in order to be dried, until the adsorbent is saturated. In the regeneration mode, moisture is removed from the saturated adsorbent by a stream of interstage compressed gas. The two beds are preferably alternately operated in the drying mode and the regeneration mode, in order to provide a continuous process.Type: GrantFiled: August 9, 1999Date of Patent: April 24, 2001Assignee: Cooper Turbocompressor, Inc.Inventors: Robert M. Kolodziej, Edward S. Czechowski
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Patent number: 6071326Abstract: The production of naphtha gas from landfill gas is preferably accomplished through a gas purification step, a catalytic conversion of methane gas to hydrogen gas, and a blending step in which various process streams are blended to produce the naphtha gas stream. The landfill gas stream is first treated through a gas purification/separation procedure to produce a substantially pure methane stream. The purified methane stream is then split into at least two portions. The first portion is fed into a hydrogen reformer and a shift reactor, where the methane gas is converted into a hydrogen-bearing stream which includes hydrogen and carbon dioxide. The second portion of the stream is preferably fed into a mixer. In the mixer, the pure methane stream, the hydrogen-bearing stream and a portion of the purified landfill gas stream are preferably blended together to form a naphtha gas stream.Type: GrantFiled: July 16, 1998Date of Patent: June 6, 2000Assignee: Ecogas CorporationInventor: Thomas Lee Hall
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Patent number: RE39122Abstract: A system for drying a gas, such as air, includes a source of gas to be dried, a multistage compressor having an inlet connected to the source, and a dryer connected interstage to the compressor and to the outlet of the compressor. The dryer is connected interstage to the compressor between a compression stage and a heat exchanger of one of the compressor stages for regenerating a first desiccant filled tower. The dryer is also connected to the outlet of the compressor for drying the gas using a second desiccant filled tower. A communication structure can be activated to connect the first tower to the outlet of the compressor for drying the gas using the first tower, and to connect the second tower interstage to the compressor for regeneration of the second tower.Type: GrantFiled: September 5, 2001Date of Patent: June 13, 2006Assignee: Henderson Engineering Co., Inc.Inventors: Charles A. Henderson, Terry D. Henderson