Abstract: Surface modifications and improvements to piezoelectric-based sensors, such as QCMs and other piezoelectric devices, that significantly increase the sensitivity and the specificity (selectivity). These modifications can comprise mechanical and chemical changes to the surfaces of the sensors, either individually or together. For example, nanosize structures may be provided on the surface to improve sensitivity. Additionally, chemical coatings may be tethered to the surfaces, walls, or crystal to provide targeted sensitivity. Additionally, porous, layered and multiple sensor arrays may be formed to enhance sensitivity and selectivity.

Abstract: A human load of regularly measuring a pH of a position 4 meters from a discharge point during a term of a commissioning of a ship with a scrubber apparatus is reduced. Provided is an apparatus provided inside a ship having a scrubber, including a first pH measuring instrument which measures a pH value of washing water discharged from the scrubber to outboard, a second pH measuring instrument which measures a pH value of washing water supplied from outboard to the scrubber, and a calculating unit which calculates a pH value of water at a predetermined position outboard, based on a dilution ratio which shows a ratio by which the washing water discharged to outboard is diluted at the predetermined position outboard, the pH value measured by the first pH measuring instrument, and the pH value measured by the second pH measuring instrument.

Abstract: Ammonia-adding apparatus and methods for ammonia-based desulfurization use multi-stage control, calculate a theoretical amount of ammonia based on gas amounts provided by an inlet continuous emission monitoring system (CEMS) and an outlet CEMS of the ammonia-based desulfurization device or associated gas amounts, a SO2 concentration provided by the inlet CEMS, and a predetermined SO2 concentration of the outlet CEMS. The apparatus and methods calculate a corrected theoretical amount of ammonia using half of the ratio of the actual amount of added ammonia to the actual amount of removed sulfur dioxide as a correction coefficient for the theoretical amount of ammonia; add an ammonia absorbent equivalent to the corrected theoretical amount of ammonia to the ammonia-based desulfurization device through an ammonia metering means and an ammonia control valve, and automatically control the actual ammonia flow rate based on the actual SO2 concentration and a change trend provided by the outlet CEMS.

Abstract: Ammonia-adding apparatus and methods for ammonia-based desulfurization use multi-stage control, calculate a theoretical amount of ammonia based on gas amounts provided by an inlet continuous emission monitoring system (CEMS) and an outlet CEMS of the ammonia-based desulfurization device or associated gas amounts, a SO2 concentration provided by the inlet CEMS, and a predetermined SO2 concentration of the outlet CEMS. The apparatus and methods calculate a corrected theoretical amount of ammonia using half of the ratio of the actual amount of added ammonia to the actual amount of removed sulfur dioxide as a correction coefficient for the theoretical amount of ammonia; add an ammonia absorbent equivalent to the corrected theoretical amount of ammonia to the ammonia-based desulfurization device through an ammonia metering means and an ammonia control valve, and automatically control the actual ammonia flow rate based on the actual SO2 concentration and a change trend provided by the outlet CEMS.

Abstract: A human load of regularly measuring a pH of a position 4 meters from a discharge point during a term of a commissioning of a ship with a scrubber apparatus is reduced. Provided is an apparatus provided inside a ship having a scrubber, including a first pH measuring instrument which measures a pH value of washing water discharged from the scrubber to outboard, a second pH measuring instrument which measures a pH value of washing water supplied from outboard to the scrubber, and a calculating unit which calculates a pH value of water at a predetermined position outboard, based on a dilution ratio which shows a ratio by which the washing water discharged to outboard is diluted at the predetermined position outboard, the pH value measured by the first pH measuring instrument, and the pH value measured by the second pH measuring instrument.

Abstract: Ammonia-adding apparatus and methods for ammonia-based desulfurization use multi-stage control, calculate a theoretical amount of ammonia based on gas amounts provided by an inlet continuous emission monitoring system (CEMS) and an outlet CEMS of the ammonia-based desulfurization device or associated gas amounts, a SO2 concentration provided by the inlet CEMS, and a predetermined SO2 concentration of the outlet CEMS. The apparatus and methods calculate a corrected theoretical amount of ammonia using half of the ratio of the actual amount of added ammonia to the actual amount of removed sulfur dioxide as a correction coefficient for the theoretical amount of ammonia; add an ammonia absorbent equivalent to the corrected theoretical amount of ammonia to the ammonia-based desulfurization device through an ammonia metering means and an ammonia control valve, and automatically control the actual ammonia flow rate based on the actual SO2 concentration and a change trend provided by the outlet CEMS.

Abstract: This invention proposes a method of removing pollutants from high temperature gases prior to their introduction in to a heat exchanger of a steam generating boiler within a power generation system. The method places a filter system (100) in a hot gas flow path upstream of a waste-heat boiler. The filter system has at least two banks of substantially hollow elongate filters (110), each of which filters particles from the gas flow as it flows from an external surface thereof to an internal surface thereof. Valves (104, 106) enable each bank of filters to be isolated from the hot gas flow path. The method included periodically isolating at least one bank of filters while passing hot gasses through at least another of the banks of filters, and cleaning the isolated bank of filters. After cleaning the filters (110) lime is injected into the flow path so that it coats the outer surface of the filters (110) to produce a loose lime coating thereon.

Abstract: Method for treating impurities contained in exhaust gases of ships to reduce sulphur oxide and other emissions. In order for the method to purify wash water exiting from an exhaust gas scrubber sufficiently enough to be directly dischargeable to sea, and in order for a purification unit used to be small enough to be easily placed onboard a ship, exhaust gases are scrubbed in the exhaust gas scrubber and wash water containing impurities and exiting from the scrubber is supplied to the purification unit, circulated in an effluent circuit, and filtered through a semipermeable membrane of a filter to obtain purified effluent and a residue containing impurities, when necessary, the pH value of the purified effluent is adjusted to be at least 6.5, after which it is discharged into the sea or recycled to the scrubber while the residue containing impurities is led back to the effluent circuit.

Abstract: An apparatus and a method for recovery of sulfur hexafluoride is provided. Sulfur hexafluoride (SF6) may be separated with high-concentration and improved recovery ratio through a multi-stage separation and recovery processes using a plurality of separation membrane modules, and as well, SF6 gas may be concentrated to maximize the SF6 recovery ratio before the separation and recovery processes through the separation membrane modules. Furthermore, sulfur dioxide (SO2) and moisture included in the SF6 waste gas may be removed effectively so as to extend the service life of the separation membrane modules.

Abstract: This invention proposes a method of removing pollutants from high temperature gasses prior to their introduction in to a heat exchanger of a steam generating boiler within a power generation system. The method comprises placing a filter system (100) in a hot gas flow path upstream of a waste-heat boiler. The filter system comprising at least two banks of substantially hollow elongate filters (110), each of which filters particles from the gas flow as it flows from an external surface thereof to an internal surface thereof. Valves (104, 106) enable each bank of filters to be isolated from the hot gas flow path. The method included periodically isolating at least one bank of filters while passing hot gasses through at least another of the banks of filters, and cleaning the isolated bank of filters. After cleaning the filters (110) lime is injected into the flow path so that it coats the outer surface of the filters (110) to produce a loose lime coating thereon.

Abstract: In a method of treating a gas stream, an aqueous scrubbing liquor is circulated through an essentially closed loop (20) comprising an electrochemical unit (48) for reducing the acidity of the liquor. A portion of the circulating liquor is diverted away from the closed loop (20) to a gas scrubbing unit (10). The gas stream enters the scrubbing unit (10), wherein an acid, for example HF and solid particulates, for example SiO2 particulates, within the gas stream dissolve in the diverted liquor. The diverted liquor is subsequently returned to the closed loop (20), and is replenished in the scrubbing unit (10) by fresh liquor diverted from the closed loop (20). A device (46) is provided for monitoring the acidity of the liquor at a location within the closed loop (20). The reduction in the acidity of the liquor by the electrochemical cell (48) is controlled depending on the monitored concentration.

Abstract: A method for regenerating an amine-containing scrubbing solution which is obtained during gas purification and in which CO2 and sulfur compounds are chemically bonded, as well as a system that is suitable for carrying out the method. The contaminated scrubbing solution is heated, compressed, and expanded in several stages such that CO2 and sulfur compounds are separated. The expanded scrubbing solution is subdivided into two partial streams, and one partial stream is recirculated into the process.

Abstract: A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Abstract: A method for regenerating an amine-containing scrubbing solution which is obtained during gas purification and in which CO2 and sulfur compounds are chemically bonded, as well as a system that is suitable for carrying out the method. The contaminated scrubbing solution is heated, compressed, and expanded in several stages such that CO2 and sulfur compounds are separated. The expanded scrubbing solution is subdivided into two partial streams, and one partial stream is recirculated into the process.

Abstract: The present invention provides a system for reducing entrained and dissolved gasses from a well fluid. The system includes a well fluid, at least one process tank into which the well fluid flows, wherein a first process tank comprises a weir arrangement over which the well fluid spills, a mechanical degasser coupled to the at least one process tank and configured to receive the well fluid, and an aeration device disposed in the at least one process tank that generates bubbles in the well fluid. The present invention also provides a method of reducing entrained and dissolved gases from a well fluid that includes flowing a well fluid into a process tank, exerting a centrifugal force on the well fluid, and generating bubbles in the well fluid in the process tank.

Abstract: The subject of the invention is method and envelope structure for handling gas diffusion of airships and other balloons to significantly decrease, respectively fully eliminate envelope diffusion of gases through envelopes of airships and other balloons. During the method according to the invention the gases diffused through the envelope (8, 9) of airships and other balloons are collected into a separator space (2). These gases are separated from the mixture of this separator space by physical and/or chemical action and forwarded back to their sources. The invention is further an envelope structure for handling gas diffusion of airships and other balloons for applying methods according to the invention.

Abstract: The present invention provides a method of treating a process fluid that includes assembling a modular system, flowing the process fluid through the modular system, the flowing the process fluid through the modular system including degassing the process fluid, neutralizing the process fluid, reducing an amount of one of the group consisting of entrained gases, oil and solids in the process fluid, monitoring and analyzing the process fluid for at least one of the group consisting of engrained gases, oil, and solids, and flowing the process fluid out of the modular system for disposal.

Abstract: An embodiment of the present invention measures a sample of the airstream, in real time, for at least one corrosive, before the airstream enters the compressor. An embodiment of the present invention may then initiate an on-line water wash system to reduce the level of the at least one corrosive on the compressor. An embodiment of the present invention also provides an on-line water wash system that may mix a cleaning fluid with at least one chemical agent to form a cleaning solution. The cleaning solution reduces the corrosives on components of a turbomachine compressor. The cleaning solution may be an acidic solution to reduce corrosion of a caustic nature. Alternatively, the cleaning solution may be a basic solution to reduce corrosion of an acidic nature.

Abstract: The present invention relates to a process for purifying a gas mixture G-0 comprising dinitrogen monoxide, at least comprising the contacting of the gas mixture G-0 with a solvent mixture (I) at least comprising 50% by weight of water based on the overall solvent mixture (1), the pH of the solvent mixture (I) being in the range from 3.5 to 8.0, the desorption of a gas mixture G-1 from a composition (A), the contacting of the gas mixture G-1 with a solvent mixture (11) at least comprising 50% by weight of water based on the overall solvent mixture (11), the pH of the solvent mixture (11) being in the range from 2.0 to 8.0, and the desorption of a gas mixture G-2 from a composition (B), the pH being based in each case on a measurement with a glass electrode, and to the use of gas mixtures obtainable by a process according to the invention as oxidizing agents for olefins.

Abstract: A gas cleaning system, which is operative for cleaning a process gas containing carbon dioxide and sulphur dioxide, comprises a combined cooling and cleaning system (16), and a CO2-absorber. The combined cooling and cleaning system (16) comprises a first gas-liquid contacting device (50) located upstream of the CO2-absorber and operative for cooling the process gas by means of a cooling liquid, and for absorbing into the cooling liquid sulphur dioxide of the process gas, such that a cooling liquid containing sulphate is obtained. The combined cooling and cleaning system (16) further comprises a second gas-liquid contacting device (94) located downstream of the CO2-absorber and operative for removing ammonia from the process gas, which has been treated in the CO2-absorber, by means of bringing the process gas containing ammonia into contact with the cooling liquid containing sulphate.

Abstract: The invention concerns a method characterised in that it consists in: determining online at least an ultraviolet spectrum portion of at least one of the compounds present in one or the other of the waste water feeding circuits (7, 13) or of the column (8) waste water output (16); qualitatively and quantitatively determining, by mathematical processing of the measured intensity levels, at least a contaminant present in the samples; on the basis of the results obtained and by comparing with pre-defined setpoint values, in restoring said data in the form of electric signals, which control the waste water supply and the stripping column water vapour flow rates.

Abstract: Disclosed is an improve aeration system. The aeration system of the present invention more efficiently removes contaminates, such as hydrogen sulfide, from water. The increased efficiency is achieved by adjusting the pH level of the water in between sequential mass transfer media stages within the aerator. The present invention also relates to an aeration system wherein the forced or induced air is used to strip contaminants from the processed water is reutilized by one or more aeration towers connected in series.

Abstract: The direct contact liquid air contaminant control system and method to revitalize air by removal of carbon dioxide and other trace gas contaminants use a direct contact air, liquid scrubber element and stripper element. The scrubber element has two rotor elements rotatably mounted in a housing first for centrifugal separation of an air flow and liquid absorbent mixture which liquid absorbent has absorbed carbon dioxide and trace gas contaminants. Then second for centrifugal separation of an air flow and acid water wash mixture which acid water wash has liquid absorbent and other contaminants. The processed air is then passed through a charcoal bed filter for further removal of contaminants. A rotary contact processor may also be used to reprocess contaminated liquid absorbent for reuse.

Abstract: A process and system for purifying an impure gas to produce a purified gas in a gas purification system and protecting the system from damage by a) passing a portion of a first gas stream into a reactor vessel, which exits as a second purified gas stream; b) combining a portion of the second purified gas stream with another portion of the first gas stream to form a combined gas stream; and c) passing the combined gas stream into a sensing device to regulate the flow of the first and second gas streams into the reactor vessel.

Abstract: This method permits the production from a gaseous mixture containing a permeable component of at least two gaseous fluxes enriched in said component, with contents that are considerably different, compared to the gaseous mixture.

Abstract: A treatment system for process exhaust streams containing NOx. The system includes a plurality of sequential scrubbing assemblies that collectively receive and contact a process exhaust stream containing NOx and a water stream to produce a product exhaust stream with a concentration of NOx that is below a determined threshold value. The removed NOx forms a portion of a system waste liquid stream that includes a majority of the NOx removed from the process exhaust stream.

Abstract: A system and method for treating process gas streams containing isopropyl alcohol (IPA) to reduce the concentration of IPA therein. The invented system includes a scrubber unit that receives a process stream containing a concentration of IPA and reduces the concentration of IPA therein to below a determined threshold. The scrubber includes a reverse osmosis assembly that significantly reduces water consumption for the scrubbing process as compared to conventional once-through systems. The system may be operated at an elevated pH to prevent biofouling from inhibiting the operation of the reverse osmosis assembly. The system may contain a softening step on the make up water system to prevent scaling in the reverse osmosis system and a softening step on a sidestream of the scrubber water recirculation loop to reduce scrubber tower salting/scaling and to control the pH of the scrubbing liquid.

Abstract: A scrubber assembly for removal of water soluble and/or alkaline gases from an exhaust stream uses a scrubber mixture contained within at least one scrubber vessel. Preferably the scrubber mixture include a liquid phase including an aqueous acid solution, and solid phase including a solid organic acid. Preferably, the scrubber mixture includes a solid carboxylic acid having low toxicity and low corrosiveness to system components. In one embodiment, a plurality of scrubber vessels, each containing the scrubber mixture are connected in series. The scrubber assembly may further include an indicator tank containing an indicator mixture. The pH of the scrubber mixture and/or indicator mixture may be monitored, thereby making operation of the system not only simpler and more reliable, but also more efficient. A method for removal of water soluble and/or alkaline gases from an exhaust stream is also disclosed.

Abstract: A process of removing carbon dioxide from a liquor in a vessel comprises the step of continuously passing a portion of the liquor into a sidestream and introducing discrete bubbles of between 0.005 mm and 1.0 mm diameter of nitrogen rich gas into the liquor before returning it to the vessel in which the nitrogen acts to adsorb carbon dioxide from the liquor and is then expelled from the liquor as an off-gas. The process also includes introducing a gas to be dissolved in the liquor into the sidestream as discrete bubbles having a diameter of between 0.005 mm and 1.0 mm.

Abstract: An apparatus for removing a contaminant from a gas effluent. The apparatus comprises an absorption tower in which is placed a suitable packing where the gas effluent and contaminant-absorbing liquid contact one another. A recirculation path transfers spent contaminant-absorbing liquid to the top of the tower allowing the liquid to effect a new contaminant-removal cycle. Reagent is introduced in the recirculation path to refresh the contaminant-absorbing liquid. A dual-controller system dynamically varies the amount of reagent introduced in the recirculation path in accordance with the amount of contaminant in the gas effluent. A master controller calculates a reagent concentration set-point. The set-point is communicated to a slave controller that meters reagent in the recirculation path according to the set-point value.

Abstract: The method of continuously controlling pH of an acid scrubbing liquid includes continuously withdrawing a constant partial stream from the scrubbing liquid; continuously measuring a pH in the partial stream with a glass electrode; adding base at a first rate to the partial stream upstream of the glass electrode and continuing the adding until the measured pH is in a pH set-point range of from 2.5 to 11.5; after the pH is in the pH set-point range, changing the first rate of adding base to the constant partial stream to compensate any subsequently occurring pH deviations; during the changing of the first rate of base addition, measuring the first rate of base addition to obtain a measured first rate; and automatically controlling a pH of the acid scrubbing liquid using the measured first rate as a controlling parameter by selecting a rate set-point range of the first rate of adding base to the constant partial stream so that the measured pH can be brought into the pH set-point range of from 2.5 to 11.

Abstract: An air pollution control system incorporating a venturi scrubber and a method of cleansing a particulate-laden, contaminated gas flow are disclosed. Spray nozzles are used to introduce optimized droplets of a scrubbing liquid into the venturi to maximize particle collection efficiency. Due to the very small size of the spray droplets they absorb gases in quantities in excess of the amount predicted by Henry's law. After passing through the venturi the spray droplets are reconsolidated and flow to an enclosed container. Due to the applicability of Henry's law to the relatively large reconsolidated volume of scrubbing liquid, the liquid is naturally effervescent. Bubbles formed in the liquid volume cause suspended particles in the liquid to rise to the surface where they form an easily collected surface scum. The effervescent gases, at least some of which may be noxious, are then incinerated or otherwise treated.

Abstract: The acid scrubbing liquid which has a pH value below 3 and is used in a scrubbing zone to remove acid components from a gas. At least part of the scrubbing liquid is circulated. A partial stream of the scrubbing liquid at a constant rate is mixed with an alkaline solution stream which has a constant concentration and is supplied at a constant volume rate, the pH value of the resulting mixture is continually measured, a setpoint in the range from 5 to 9 is selected for the pH value of the mixture, and a neutral or alkaline correcting liquid is added to the scrubbing liquid in response to a decrease of the measured pH value below said setpoint. The scrubbing liquid may mainly consist of water.